Academic literature on the topic 'Trimethylsilane'

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Journal articles on the topic "Trimethylsilane"

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Vuong, Thi. "(Trifluoromethyl)trimethylsilane." Synlett 23, no. 09 (2012): 1409–10. http://dx.doi.org/10.1055/s-0031-1290686.

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Krishnamoorthy, Sankarganesh, and G. Prakash. "Silicon-Based Reagents for Difluoromethylation and Difluoromethylenation Reactions." Synthesis 49, no. 15 (2017): 3394–406. http://dx.doi.org/10.1055/s-0036-1588489.

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There have been significant developments in the area of perfluoroalkyl group transfer using silicon reagents, specifically in nucleo­philic trifluoromethylation. The mild and versatile activation conditions bestow significant synthetic prowess to the silicon reagents in the area of fluoroalkylations. Owing to the importance of difluoromethylene (CF2) containing compounds in pharmaceuticals, materials, and agrochemicals, several CF2 group transfer methods using related silicon reagents have been developed and studied in detail. This review summarizes the recent developments and trends in this a
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Wang, Fei, Lingchun Li, Chuanfa Ni, and Jinbo Hu. "Deoxygenative gem-difluoroolefination of carbonyl compounds with (chlorodifluoromethyl)trimethylsilane and triphenylphosphine." Beilstein Journal of Organic Chemistry 10 (February 6, 2014): 344–51. http://dx.doi.org/10.3762/bjoc.10.32.

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Background: 1,1-Difluoroalkenes cannot only be used as valuable precursors for organic synthesis, but also act as bioisosteres for enzyme inhibitors. Among various methods for their preparation, the carbonyl olefination with difluoromethylene phosphonium ylide represents one of the most straightforward methods. Results: The combination of (chlorodifluoromethyl)trimethylsilane (TMSCF2Cl) and triphenylphosphine (PPh3) can be used for the synthesis of gem-difluoroolefins from carbonyl compounds. Comparative experiments demonstrate that TMSCF2Cl is superior to (bromodifluoromethyl)trimethylsilane
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Sakurai, Hideki, Soichiro Kyushin та Yasuhiro Nakadaira. "(2-Cyanoallyl)trimethylsilane and (2-Cyanoethyl)trimethylsilane. Unique σπ Captodative Systems". Chemistry Letters 16, № 2 (1987): 297–300. http://dx.doi.org/10.1246/cl.1987.297.

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YOSHIDA, Yasuo. "((1-ethoxycyclopropyl)oxy) trimethylsilane." Journal of Synthetic Organic Chemistry, Japan 57, no. 12 (1999): 1116–17. http://dx.doi.org/10.5059/yukigoseikyokaishi.57.1116.

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Werstiuk, Nick Henry, and Wojciech Sokol. "Density functional theory computational study on Diels–Alder reactions of cyclopentadiene with selected vinylsilanes and methylenecyclopropane." Canadian Journal of Chemistry 89, no. 3 (2011): 409–14. http://dx.doi.org/10.1139/v10-167.

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Aimed at predicting relative reactivities, density functional theory (DFT) calculations were carried out on a series of Diels–Alder reactions involving silylvinyl derivatives reacting with cyclopentadiene as part of a synthetic research project. Using three reactions for which experimental rate data are available to calibrate our calculations, we computationally pinpointed the best synthetic route to bicyclo[2.2.1]hept-5-ene-2,2-diylbis(trimethylsilane) (1). The synthesis begins with the Diels–Alder reaction of cyclopentadiene (2) with commercially available (1-bromovinyl)trimethylsilane (6).
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Fraser, Stewart, and Simon Parsons. "(Chloromethyl)trimethylsilane at 160 K." Acta Crystallographica Section E Structure Reports Online 60, no. 4 (2004): o564—o565. http://dx.doi.org/10.1107/s1600536804005276.

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Trifonov, Alexey L., Artem A. Zemtsov, Vitalij V. Levin, Marina I. Struchkova, and Alexander D. Dilman. "Nucleophilic Difluoromethylation Using (Bromodifluoromethyl)trimethylsilane." Organic Letters 18, no. 14 (2016): 3458–61. http://dx.doi.org/10.1021/acs.orglett.6b01641.

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Jiao, C. Q., A. Garscadden, and P. D. Haaland. "Ionization of trimethylsilane, (CH3)3SiH." International Journal of Mass Spectrometry 184, no. 1 (1999): 83–88. http://dx.doi.org/10.1016/s1387-3806(98)14270-7.

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Yasuda, Hirotsugu, and Qingsong Yu. "Cathode glow polymerization of trimethylsilane." Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 22, no. 3 (2004): 472. http://dx.doi.org/10.1116/1.1690776.

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Dissertations / Theses on the topic "Trimethylsilane"

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Ding, Luying. "Kinetic Studies of the Reactions of Cl and Br with Silane and Trimethylsilane." Thesis, University of North Texas, 1992. https://digital.library.unt.edu/ark:/67531/metadc500233/.

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The temperature dependence of the reactions of halogen atoms Cl and Br with SiH4 and (CH3)3SiH have been investigated with the flash photolysis-resonance fluorescence technique. CCI4 and CH2Br2 were used as precursors to produce Cl and Br atoms, respectively. Experiments gave {k(Cl + SiH4) (295 - 472 K)} = (1.56 +0.11) x 10-1 exp[(2.0 + 0.2) kJ mol'/RT] cm3 s4, {k(Br + SiH4)(295 - 575 K)} = (9.0 + 1.5) x 10-" exp[-(17.0 + 0.6) Id mol'/RT] cm3 s', {k(Cl + (CH3)3SiH)(295 - 468 K)} = (1.24 0.35) x 104 exp[(1.3 + 0.8) Id mol4/RT] cm3 s', and {k(Br + (CH3)3SiH)(295 - 456 K)} = (7.6 + 3.3) x 1010 ex
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Scott, Paul Robert Wieliczka David Michael. "An in situ x-ray photoelectron spectroscopy analysis of thin films created through physical vapor deposition of aluminum and plasma enhanced chemical vapor deposition of trimethylsilane." Diss., UMK access, 2007.

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Thesis (M.S.)--Dept. of Physics. University of Missouri--Kansas City, 2007.<br>"A thesis in physics." Typescript. Advisor: David M. Wieliczka. Vita. Title from "catalog record" of the print edition Description based on contents viewed May 23, 2008. Includes bibliographical references (leaves 69-70). Online version of the print edition.
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Bertounesque, Emmanuel. "Aldolisation dirigee : reactivite des bis (trimethylsilyl)-acetals de cetenes et des esters de trimethylsilyle -trimethylsilyles." Paris 7, 1987. http://www.theses.fr/1987PA077287.

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Dans un premier temps, la reactivite des composes du titre est etudiee. Ces composes reagissent ainsi avec des aldehydes pour donner des -hydroxyacides. La seconde partie traite de la synthese des esters de trimethylsilyle -trimethylsilyles. Enfin, la synthese de -chloroacides a partir des bis-trimethylsilyl acetals de cetenes est realisee
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"Chemistry of 3,4-furandiylbis [trimethylsilanes] (3,4-bis(trimethylsilyl) furans)." Chinese University of Hong Kong, 1989. http://library.cuhk.edu.hk/record=b5886155.

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Book chapters on the topic "Trimethylsilane"

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Steiner, G., and C. Zimmerer. "Poly(vinyl trimethylsilane) (PVTMS)." In Polymer Solids and Polymer Melts – Definitions and Physical Properties I. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-32072-9_102.

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Kemp, Richard A., Alan H. Cowley, Harmut Schulz, and Malcolm H. Chisholm. "(Chloromethylene)Bis[Trimethylsilane] [Bis(Trimethylsilyl)Chloromethane]." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132623.ch20.

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Pornet, J. "Coupling with (Halomethyl)trimethylsilane." In Compounds of Groups 15 (As, Sb, Bi) and Silicon Compounds. Georg Thieme Verlag KG, 2002. http://dx.doi.org/10.1055/sos-sd-004-00881.

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Kawęcki, R. "Addition of (Trifluoromethyl)trimethylsilane." In Sulfur, Selenium, and Tellurium. Georg Thieme Verlag KG, 2011. http://dx.doi.org/10.1055/sos-sd-139-00067.

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Prakash, G. K. S., and J. Hu. "Reaction of (Chlorodifluoromethyl)trimethylsilane and Related Compounds." In Three Carbon-Heteroatom Bonds: Amides and Derivatives; Peptides; Lactams. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-022-00778.

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Comasseto, J. V., and A. S. Guarezemini. "Reaction of Arsenic(III) Fluoride with (-Butylsulfanyl)trimethylsilane." In Sulfur, Selenium, and Tellurium. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-039-00460.

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Comasseto, J. V., and A. S. Guarezemini. "Reaction of Antimony(III) Fluoride with (-Butylsulfanyl)trimethylsilane." In Sulfur, Selenium, and Tellurium. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-039-00463.

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Comasseto, J. V., and A. S. Guarezemini. "Reaction of Bismuth(III) Fluoride with (-Butylsulfanyl)trimethylsilane." In Sulfur, Selenium, and Tellurium. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-039-00467.

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Sarkar, T. K. "From Mixed Vinylcuprates and (Iodomethyl)trimethylsilane or Related Reagents." In Compounds of Groups 15 (As, Sb, Bi) and Silicon Compounds. Georg Thieme Verlag KG, 2002. http://dx.doi.org/10.1055/sos-sd-004-00956.

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Polo, A., and J. Real. "Reaction of a Metal Salt with an (Alkyltellanyl)trimethylsilane." In Sulfur, Selenium, and Tellurium. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-039-01556.

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Conference papers on the topic "Trimethylsilane"

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Myronov, M., S. D. Rhead, G. Colston, and D. R. Leadley. "RP-CVD growth of high carbon content Si1−xCx epilayers using disilane and trimethylsilane precursors." In 2014 7th International Silicon-Germanium Technology and Device Meeting (ISTDM). IEEE, 2014. http://dx.doi.org/10.1109/istdm.2014.6874653.

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Colston, Gerard, Maksym Myronov, Stephen Rhead, and David Leadley. "Disilane and trimethylsilane as precursors for RP-CVD growth of Si1−yCy epilayers on Si(001)." In 2015 Joint International EUROSOI Workshop and International Conference on Ultimate Integration on Silicon (EUROSOI-ULIS). IEEE, 2015. http://dx.doi.org/10.1109/ulis.2015.7063814.

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Swminathan, V. P., Ronghua Wei, and David W. Gandy. "Erosion Resistant Nano Technology Coatings for Gas Turbine Components." In ASME Turbo Expo 2007: Power for Land, Sea, and Air. ASMEDC, 2007. http://dx.doi.org/10.1115/gt2007-27027.

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Solid particle and liquid particle erosion in the compressor section of gas turbines and steam turbine vanes and blades lead to significant reduction in turbine efficiency over time. This results in increased downtime and operating cost of the power plants. Some of the conventional coatings and erosion protection shields used by the currently available commercial processes have limitations in their temperature and erosion protection capabilities. Under a project funded by the Electric Power Research Institute (EPRI), nano coatings with thickness within 40 microns (about 1.5 mils) have been pro
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