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Journal articles on the topic 'Triptycen'

Author: Grafiati

Published: 4 June 2021

Last updated: 11 February 2022

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1

Chakraborty, Sourav, Snehasish Mondal, Rina Kumari, Sourav Bhowmick, Prolay Das, and Neeladri Das. "Synthesis, characterization and DNA interaction studies of new triptycene derivatives." Beilstein Journal of Organic Chemistry 10 (June 5, 2014): 1290–98. http://dx.doi.org/10.3762/bjoc.10.130.

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A facile and efficient synthesis of a new series of triptycene-based tripods is being reported. Using 2,6,14- or 2,7,14-triaminotriptycenes as synthons, the corresponding triazidotriptycenes were prepared in high yield. Additionally, we report the transformation of 2,6,14- or 2,7,14-triaminotriptycenes to the corresponding ethynyl-substituted triptycenes via their tribromo derivatives. Subsequently, derivatization of ethynyl-substituted triptycenes was studied to yield the respective propiolic acid and ethynylphosphine derivatives. Characterization of the newly functionalized triptycene deriva

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2

Daub, Jörg, Lothar Jakob, and Josef Salbeck. "Chirale Elektronentransfer-aktive Chinone mit Triptycen-Teilstrukturen: Synthesekonzeption und Eigenschaften." Chemische Berichte 121, no. 12 (1988): 2187–94. http://dx.doi.org/10.1002/cber.19881211218.

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3

Pei, Bao-Jian, Wing-Hong Chan, and Albert W. M. Lee. "Oxadisilole Fused Triptycene and Extended Triptycene: Precursors of Triptycyne and Extended Triptycyne." Journal of Organic Chemistry 75, no. 21 (2010): 7332–37. http://dx.doi.org/10.1021/jo1016025.

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4

McGlinchey, Michael J., and Kirill Nikitin. "Palladium-Catalysed Coupling Reactions En Route to Molecular Machines: Sterically Hindered Indenyl and Ferrocenyl Anthracenes and Triptycenes, and Biindenyls." Molecules 25, no. 8 (2020): 1950. http://dx.doi.org/10.3390/molecules25081950.

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Pd-catalysed Stille and Suzuki cross-couplings were used to prepare 9-(3-indenyl)-, 6, and 9-(2-indenyl)-anthracene, 7; addition of benzyne led to the 9-Indenyl-triptycenes, 8 and 9. In 6, [4 + 2] addition also occurred to the indenyl substituent. Reaction of 6 through 9 with Cr(CO)6 or Re2(CO)10 gave their M(CO)3 derivatives, where the Cr or Re was complexed to a six- or five-membered ring, respectively. In the 9-(2-indenyl)triptycene complexes, slowed rotation of the paddlewheel on the NMR time-scale was apparent in the η5-Re(CO)3 case and, when the η6-Cr(CO)3 was deprotonated, the resulting

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5

Elbert, Sven M., Tobias Kirschbaum, Frank Rominger, and Michael Mastalerz. "Proving Triptycene Homoconjugation with the Same Chromophore but Different Connectivity to the Core." Organic Materials 03, no. 02 (2021): 097–102. http://dx.doi.org/10.1055/s-0041-1726304.

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Homoconjugation is a phenomenon discussed for various π-systems where classical conjugation is broken by e.g. methylene units but still a stabilization by electronic communication exists. In this respect, triptycene with its rigid C3 symmetric geometry is an ideal scaffold to study this phenomenon. Although several studies based on triptycene strengthen the hypothesis of homoconjugation, in all described cases the electronic communication through space relies on different π-blades. Here, two triptycenes are presented having the exact same π-extended chromophore, but differently annulated to th

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6

Ebersberger, Sabine. "Das Triptychon in der Kunsttherapie." Musik-, Tanz- und Kunsttherapie 24, no. 3 (2013): 128–34. http://dx.doi.org/10.1026/0933-6885/a000123.

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Der vorliegende Beitrag widmet sich dem Triptychon als therapeutische Methode in der Kunsttherapie. Triptychen sind dreiteilige Gemälde, die als sogenannte Flügelaltäre im 15. und 16. Jahrhundert Bekanntheit erlangten. In der Auseinandersetzung mit den therapeutischen Wirkfaktoren (vgl. Grawe, 2000 ; 2004 ) diskutiert der Beitrag die methodischen Stärken des Triptychons als Bildformat und zeigt auf, wie diese in der kunsttherapeutischen Arbeit praktisch nutzbar gemacht werden können. Exemplarische Bildbeispiele verdeutlichen diese Methode.

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7

Tomioka, Hideo, and Junichi Nakajima. "Thermolysis and photolysis of 1-substituted triptycenes. Divergent fragmentation pathways of the triptycyl skeleton." Journal of the Chemical Society, Perkin Transactions 1, no. 6 (1996): 563. http://dx.doi.org/10.1039/p19960000563.

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8

Martens, Didier. "Un disciple tardif de Rogier de la Pasture: Maître Johannes (alias Johannes Hoesacker?)." Oud Holland - Quarterly for Dutch Art History 114, no. 2-4 (2001): 79–106. http://dx.doi.org/10.1163/187501701x00406.

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AbstractThe triptych which has hung above the main altar of Our Lady of the Immaculate Conception at Maria-ter-Heide (Brasschaat, near Antwerp) since the nineteenth century unfolds a highly unusual iconographical programme. The representation on the central panel is a 'Holy Kinship' with Saint Anne; the left and right shutters show a 'Tree of Jesse', and the 'Kinship of Effra and Ismeria' respectively. This unusual combination of themes, and the coat of arms of the abbey at Tongerlo on the staff of the kneeling donor on the left shutter, enable us to identify the triptych from an old descripti

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9

Bonaccorsi, Paola, Maria Luisa Di Gioia, Antonella Leggio, et al. "Synthesis of enantiopure sugar-decorated six-armed triptycene derivatives." Beilstein Journal of Organic Chemistry 9 (November 8, 2013): 2410–16. http://dx.doi.org/10.3762/bjoc.9.278.

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A new class of molecules with a triptycene rigid core surrounded by six monosaccharide residues was synthesized. Hexakis(bromomethyl) substituted triptycene was converted into a six-armed triptycene azide (2,3,6,7,14,15-hexakis(azidomethyl)-9,10-dihydro-9,10-[1’,2’]benzenoanthracene). The key step of the synthesis was the cycloaddition of the azide to 2-propyn-1-yl β-D-gluco- or galactopyranosides. All products were isolated in good yields and were fully characterized.

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10

Locke, Gemma M., Keith J. Flanagan, and Mathias O. Senge. "Towards triptycene functionalization and triptycene-linked porphyrin arrays." Beilstein Journal of Organic Chemistry 16 (April 17, 2020): 763–77. http://dx.doi.org/10.3762/bjoc.16.70.

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Herein, 9,10-diethynyltriptycene is investigated for its use as a rigid isolating unit in the synthesis of multichromophoric arrays. Sonogashira cross-coupling conditions are utilized to attach various porphyrins and boron dipyrromethenes (BODIPYs) to the triptycene scaffold. While there are previous examples of triptycene porphyrin complexes, this work reports the first example of a linearly connected porphyrin dimer, linked through the bridgehead carbons of triptycene. Symmetric and unsymmetric examples of these complexes are demonstrated and single crystal X-ray analysis of an unsymmetrical

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11

Chakraborty, Sourav, Snehasish Mondal, Sourav Bhowmick, et al. "Triptycene based organometallic complexes: a new class of acceptor synthons for supramolecular ensembles." Dalton Trans. 43, no. 35 (2014): 13270–77. http://dx.doi.org/10.1039/c4dt01298d.

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New triptycene based organometallic complexes have been synthesized and subsequently used for design of the triptycene motif containing nanoscalar trigonal prisms. Flexible 3,3′-bipyridine is employed as a donor unit.

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12

Shindo, Mitsuru, Takayuki Iwata, and Tatsuro Yoshinaga. "Flow Synthesis of Triptycene via Triple Cycloaddition of Ynolate to Benzyne." Synlett 31, no. 19 (2020): 1903–6. http://dx.doi.org/10.1055/s-0040-1706417.

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Flow synthesis of triptycene was achieved using triple cycloaddition of ynolate to benzyne. Employing the borate-type benzyne precursor, side reactions triggered by the addition of alkyllithium to benzyne were efficiently suppressed under microflow conditions, thus producing triptycene with a higher yield than that obtained under the corresponding batch conditions. Furthermore, ynolate prepared from α,α-dibromoester under microflow conditions was continuously added to the flow reaction with benzyne, which successfully synthesized triptycene in only one minute.

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13

TOMIOKA, H., and J. NAKAJIMA. "ChemInform Abstract: Thermolysis and Photolysis of 1-Substituted Triptycenes. Divergent Fragmentation Pathways of the Triptycyl Skeleton." ChemInform 27, no. 29 (2010): no. http://dx.doi.org/10.1002/chin.199629066.

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14

Qian, Rui, Hongjuan Tong, Cui Huang, et al. "A donor–acceptor triptycene–coumarin hybrid dye featuring a charge separated excited state and AIE properties." Organic & Biomolecular Chemistry 14, no. 22 (2016): 5007–11. http://dx.doi.org/10.1039/c6ob00822d.

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Triptycene–coumarin hybrid dye: the triptycene scaffold facilitates donor–acceptor interactions in DCT-1 through homoconjugation, resulting in a charge separated excited state and aggregation-induced emission (AIE) properties not seen in DC.

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15

Ishii, Akihiko, Yuichiro Mori, and Rei Uchiumi. "Synthesis and hydrolysis ofp-toluoyl and acetyl 9-triptycyl diselenides: A study on generation of triptycene-9-selenenoselenoic acid." Heteroatom Chemistry 16, no. 6 (2005): 525–28. http://dx.doi.org/10.1002/hc.20155.

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16

Van Der Ploeg, Frank. "Jan II van Coninxloo en zijn werkzaamheden voor het benedictinessenklooster van Groot-Bijgaarden bij Brussel." Oud Holland - Quarterly for Dutch Art History 112, no. 2-3 (1998): 104–26. http://dx.doi.org/10.1163/187501798x00293.

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AbstractThis article examines the relationship between the Brussels painter Jan 11 van Coninxloo (ca. 1489-1561 or later) and the Benedictine convent of Groot-Bijgaarden. In earlier publications by J. Maquet-Tombu the link between certain members of the Van Coninxloo family and the Vorst convent have already been pointed out. A new chapter can now be added. In the archive of Groot-Bijgaarden convent are two books in which payments made by the prioresses Françoise and Catherine van Straten for the dccoration of the convent and the church are recorded. The books list a separate item for painting

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17

Spyroudis, Spyros, and Nikoletta Xanthopoulou. "Triptycene quinones in synthesis: preparation of triptycene bis-cyclopentenedione." Arkivoc 2003, no. 6 (2003): 95–105. http://dx.doi.org/10.3998/ark.5550190.0004.612.

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18

Yamamoto, Gaku, Takashi Nemoto, and Yuji Ohashi. "Atropisomerism in Doublyperi-Substituted 9-(2-Methylbenzyl)triptycene Derivatives, 8-Chloro- and 8-Bromo-1,4-dimethyl-9-(2-methylbenzyl)triptycenes." Bulletin of the Chemical Society of Japan 65, no. 7 (1992): 1957–66. http://dx.doi.org/10.1246/bcsj.65.1957.

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19

Marks, Vered, Moshe Nahmany, Hugo E. Gottlieb, and Silvio E. Biali. "Polyethylated Triptycene Derivatives." Journal of Organic Chemistry 67, no. 22 (2002): 7898–901. http://dx.doi.org/10.1021/jo026206v.

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20

Shoji, Yoshiaki, Shion Yamamoto, and Takanori Fukushima. "Perchlorinated Triptycene Tribenzoquinone." Chemistry Letters 50, no. 6 (2021): 1240–43. http://dx.doi.org/10.1246/cl.210219.

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21

Perchellet, Elisabeth M., Molly J. Magill, Xiaodong Huang, Cyrille E. Brantis, Duy H. Hua, and Jean-Pierre Perchellet. "Triptycenes." Anti-Cancer Drugs 10, no. 8 (1999): 749–66. http://dx.doi.org/10.1097/00001813-199909000-00009.

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22

Shuku, Yoshiaki, Asato Mizuno, Ryo Ushiroguchi та ін. "An exotic band structure of a supramolecular honeycomb lattice formed by a pancake π–π interaction between triradical trianions of triptycene tribenzoquinone". Chemical Communications 54, № 31 (2018): 3815–18. http://dx.doi.org/10.1039/c8cc00753e.

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23

Borodkin, G. I., I. R. Elanov, R. V. Andreev, and V. G. Shubin. "Nitrosonium complexes of triptycene." Russian Journal of Organic Chemistry 45, no. 9 (2009): 1344–48. http://dx.doi.org/10.1134/s1070428009090061.

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24

Lucchesini, Francesco, Michael Grasse, Beate Neumann, Hans-Georg Stammler, Jörg Tellenbröker, and Dietmar Kuck. "Merging Tribenzotriquinacene and Triptycene." European Journal of Organic Chemistry 2016, no. 16 (2016): 2828–41. http://dx.doi.org/10.1002/ejoc.201600176.

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25

Norvez, Sophie. "Liquid crystalline triptycene derivatives." Journal of Organic Chemistry 58, no. 9 (1993): 2414–18. http://dx.doi.org/10.1021/jo00061a012.

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26

Luo, Shuangjiang, Junyi Liu, Haiqing Lin, et al. "Preparation and gas transport properties of triptycene-containing polybenzoxazole (PBO)-based polymers derived from thermal rearrangement (TR) and thermal cyclodehydration (TC) processes." Journal of Materials Chemistry A 4, no. 43 (2016): 17050–62. http://dx.doi.org/10.1039/c6ta03951k.

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27

Genduso, Giuseppe, Bader Ghanem, Yingge Wang, and Ingo Pinnau. "Synthesis and Gas-Permeation Characterization of a Novel High-Surface Area Polyamide Derived from 1,3,6,8-Tetramethyl-2,7-diaminotriptycene: Towards Polyamides of Intrinsic Microporosity (PIM-PAs)." Polymers 11, no. 2 (2019): 361. http://dx.doi.org/10.3390/polym11020361.

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A triptycene-based diamine, 1,3,6,8-tetramethyl-2,7-diamino-triptycene (TMDAT), was used for the synthesis of a novel solution-processable polyamide obtained via polycondensation reaction with 4,4′-(hexafluoroisopropylidene)bis(benzoic acid) (6FBBA). Molecular simulations confirmed that the tetrasubstitution with ortho-methyl groups in the triptycene building block reduced rotations around the C–N bond of the amide group leading to enhanced fractional free volume. Based on N2 sorption at 77 K, 6FBBA-TMDAT revealed microporosity with a Brunauer–Emmett–Teller (BET) surface area of 396 m2 g−1; to

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28

Liang, Qian, Guiyuan Jiang, Zhen Zhao, Zhongyu Li, and Mark J. MacLachlan. "CdS-decorated triptycene-based polymer: durable photocatalysts for hydrogen production under visible-light irradiation." Catalysis Science & Technology 5, no. 6 (2015): 3368–74. http://dx.doi.org/10.1039/c5cy00470e.

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29

Wiegand, Jennifer R., Zachary P. Smith, Qiang Liu, Christopher T. Patterson, Benny D. Freeman, and Ruilan Guo. "Synthesis and characterization of triptycene-based polyimides with tunable high fractional free volume for gas separation membranes." J. Mater. Chem. A 2, no. 33 (2014): 13309–20. http://dx.doi.org/10.1039/c4ta02303j.

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30

Magno, Rosa Maria. "Triptych." Feminist Studies 26, no. 1 (2000): 209. http://dx.doi.org/10.2307/3178601.

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31

Samina Najmi. "Triptych." World Literature Today 91, no. 2 (2017): 9. http://dx.doi.org/10.7588/worllitetoda.91.2.0009.

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32

Bennett, Martin. "Triptych." Wasafiri 15, no. 30 (1999): 19–20. http://dx.doi.org/10.1080/02690059908589651.

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33

Pendyal, Akshay. "Triptych." JAMA 322, no. 2 (2019): 175. http://dx.doi.org/10.1001/jama.2019.4325.

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34

Larsen, Deena, Stace Johnson, and Robert Lavett Smith. "Triptych." Cream City Review 40, no. 1 (2016): 95. http://dx.doi.org/10.1353/ccr.2016.0025.

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35

Fagan, Kathy. "Triptych." Missouri Review 17, no. 1 (1994): 164–66. http://dx.doi.org/10.1353/mis.1994.0060.

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36

Khwaja, Waqas. "Triptych." South Asian Review 27, no. 3 (2006): 111–13. http://dx.doi.org/10.1080/02759527.2006.11932475.

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37

Zhai, Tian-Long, Qing Du, Sheng Xu, Yan Wang, and Chun Zhang. "Electrospun nanofibrous membrane of porous fluorine-containing triptycene-based polyimides for oil/water separation." RSC Advances 7, no. 36 (2017): 22548–52. http://dx.doi.org/10.1039/c7ra01614j.

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38

Zhang, Chun, and Chuan-Feng Chen. "Synthesis and analysis of hydroxyl substituted triptycene adducts: the competitive recognition between the hydroxyl substituted triptycenes with 4, 4′-bipyridine and solvent molecules." CrystEngComm 12, no. 10 (2010): 3255. http://dx.doi.org/10.1039/c002943b.

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39

YAMAMOTO, G., T. NEMOTO, and Y. OHASHI. "ChemInform Abstract: Atropisomerism in Doubly peri-Substituted 9-(2-Methylbenzyl)triptycene Derivatives, 8-Chloro- and 8-Bromo-1,4-dimethyl-9-(2-methylbenzyl) triptycenes." ChemInform 23, no. 45 (2010): no. http://dx.doi.org/10.1002/chin.199245065.

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40

Abdulhamid, Mahmoud A., Sang-Hee Park, Hakkim Vovusha, et al. "Molecular engineering of high-performance nanofiltration membranes from intrinsically microporous poly(ether-ether-ketone)." Journal of Materials Chemistry A 8, no. 46 (2020): 24445–54. http://dx.doi.org/10.1039/d0ta08194a.

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41

Zhang, Yindong, Yunlong Zhu, Jun Guo, et al. "The role of the internal molecular free volume in defining organic porous copolymer properties: tunable porosity and highly selective CO2 adsorption." Physical Chemistry Chemical Physics 18, no. 16 (2016): 11323–29. http://dx.doi.org/10.1039/c6cp00981f.

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42

Chandrasekhar, Pujari, Arindam Mukhopadhyay, Govardhan Savitha, and Jarugu Narasimha Moorthy. "Orthogonal self-assembly of a trigonal triptycene triacid: signaling of exfoliation of porous 2D metal–organic layers by fluorescence and selective CO2 capture by the hydrogen-bonded MOF." Journal of Materials Chemistry A 5, no. 11 (2017): 5402–12. http://dx.doi.org/10.1039/c6ta11110f.

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43

Liang, Qian, Sainan Cui, Song Xu, Chao Yao, Mark J. MacLachlan, and Zhongyu Li. "A porous triptycene-based covalent polymer stabilized binary metal sulfide for enhanced hydrogen evolution under visible light." Chemical Communications 54, no. 27 (2018): 3391–94. http://dx.doi.org/10.1039/c8cc00665b.

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44

Wang, Han-Xiao, Zheng Meng, Jun-Feng Xiang, et al. "Guest-dependent directional complexation based on triptycene derived oxacalixarene: formation of oriented rotaxanes." Chemical Science 7, no. 1 (2016): 469–74. http://dx.doi.org/10.1039/c5sc03511b.

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45

Amro, Kassem, Anil K. Thakur, Marc Rolland, et al. "Linking triptycene to silole: a fruitful association." Materials Chemistry Frontiers 4, no. 7 (2020): 2006–17. http://dx.doi.org/10.1039/d0qm00087f.

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46

Zhang, Li-Peng, Wenchao Zhao, Xiaoyu Liu, et al. "A triptycene-cored perylenediimide derivative and its application in organic solar cells as a non-fullerene acceptor." New Journal of Chemistry 41, no. 18 (2017): 10237–44. http://dx.doi.org/10.1039/c7nj01971h.

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47

Alam, Akhtar, Atikur Hassan, Ranajit Bera, and Neeladri Das. "Silsesquioxane-based and triptycene-linked nanoporous polymers (STNPs) with a high surface area for CO2 uptake and efficient dye removal applications." Materials Advances 1, no. 9 (2020): 3406–16. http://dx.doi.org/10.1039/d0ma00672f.

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48

Li, Hui, Qi Chen, and Bao-Hang Han. "Sugar-functionalized triptycenes used for dispersion of single-walled carbon nanotubes in aqueous solution by supramolecular interaction." New Journal of Chemistry 40, no. 4 (2016): 3300–3307. http://dx.doi.org/10.1039/c5nj03075g.

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49

Hamacek, Josef, Alexandra Vuillamy, Lisa Peterhans, et al. "Ln(iii) complexes with triptycene based tripodal ligands: speciation and equilibria." New Journal of Chemistry 42, no. 10 (2018): 7803–9. http://dx.doi.org/10.1039/c8nj00252e.

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50

Zeng, Fei, Zheng Meng, Ying Han, and Chuan-Feng Chen. "Formation of a “pseudosuitane”-type complex between a triptycene-derived bis(crown ether) host and 1,1′-(anthracene-9,10-diyl)bis(N-benzylmethanaminium): a new method for the synthesis of linear polyrotaxanes." Chem. Commun. 50, no. 57 (2014): 7611–13. http://dx.doi.org/10.1039/c4cc02904f.

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