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Journal articles on the topic 'Tris-complex'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Chagas, Rafael S., та Sandro R. Marana. "Tris inhibits a GH1 β-glucosidase by a linear mixed inhibition mechanism". PLOS ONE 20, № 3 (2025): e0320120. https://doi.org/10.1371/journal.pone.0320120.

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Here we demonstrate that Tris (2-amino-2-(hydroxymethyl)-1,3-propanediol), largely used as a buffering agent, is a linear mixed inhibitor (Ki = 12 ± 2 mM and α = 3 ± 1) of the GH1 β-glucosidase from the insect Spodoptera frugiperda (Sfβgly). Such an inhibition mechanism implies the formation of a non-productive ESI complex involving Sfβgly, substrate, and Tris. In addition, Tris binding reduces by 3 fold the enzyme affinity for the substrate. Hence, at concentrations higher than the Ki, Tris can completely abolish Sfβgly activity, whereas even at lower concentrations the presence of Tris cause

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2

Wang, Yu-Long, Meng Feng, Xian Tao, Qing-Yun Tang та Ying-Zhong Shen. "Two lanthanum(III) complexes containing η2-pyrazolate and η2-1,2,4-triazolate ligands: intramolecular C—H...N/O interactions and coordination geometries". Acta Crystallographica Section C Crystal Structure Communications 69, № 1 (2012): 25–28. http://dx.doi.org/10.1107/s0108270112049281.

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The lanthanum(III) complexes tris(3,5-diphenylpyrazolato-κ2N,N′)tris(tetrahydrofuran-κO)lanthanum(III) tetrahydrofuran monosolvate, [La(C15H11N2)3(C4H8O)3]·C4H8O, (I), and tris(3,5-diphenyl-1,2,4-triazolato-κ2N1,N2)tris(tetrahydrofuran-κO)lanthanum(III), [La(C14H10N3)3(C4H8O)3], (II), both contain LaIIIatoms coordinated by three heterocyclic ligands and three tetrahydrofuran ligands, but their coordination geometries differ. Complex (I) has amer-distorted octahedral geometry, while complex (II) has afac-distorted configuration. The difference in the coordination geometries and the existence of

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3

Kersting, Berthold, and Gabriel Siedle. "Reactivity of Cobalt(III) Amine-Thiolate Complexes with Terminal and Bridging Thiolate Functions towards Hydrogen Peroxide." Zeitschrift für Naturforschung B 55, no. 12 (2000): 1179–87. http://dx.doi.org/10.1515/znb-2000-1211.

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The reactivity of CoIII amine-thiolate complexes with terminal and bridging thiolate functions towards oxidizing agents has been investigated. The mononuclear CoIII N3S3 complex [CoIII(L1)] (2) (H3L1 represents the hexadentate ligand N,N′,N″-Tris(2-thio-benzyl)-1,1,1 -tris- (aminomethyl)ethane) featuring three terminal thiolate ligands, and the binuclear N3CoIII- (μ-S)3CoIIIN3 complex [CoIII2(L2)]3+ (4) (H3L2 = N,N′,N″-Tris-[2-thio-3-aminomethyl-5-terrbutyl- benzyl]-1,1,1-tris(aminomethyl)ethane) featuring three bridging thiolates were selected. Hydrogen peroxide was the oxidizing agent. Where

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4

Jiao, Yunzhe, William W. Brennessel, and William D. Jones. "Nitrile coordination to rhodium does not lead to C—H activation." Acta Crystallographica Section C Structural Chemistry 72, no. 11 (2016): 850–52. http://dx.doi.org/10.1107/s2053229616006859.

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Tris(pyrazolyl)borate complexes of rhodium are well known to activate C—H bonds. The reactive [Tp′Rh(PMe3)] fragment [Tp′ is tris(3,5-dimethylpyrazol-1-yl)hydroborate] is found to react with valeronitrile to give the κ1N-bound complex (pentanenitrile-κN)(trimethylphosphane-κP)[tris(3,5-dimethylimidazol-1-yl)hydroborato-κ2N2,N2′]rhodium(I), [Rh(C15H22BN6)(C5H9N)(C3H9P)]. In contrast to the widespread evidence for the reaction of this fragment with C—H bondsviaoxidative addition, no evidence for such a complex is observed.

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5

Mejuto, Carmen, Beatriz Royo, Gregorio Guisado-Barrios, and Eduardo Peris. "Rhodium, iridium and nickel complexes with a 1,3,5-triphenylbenzene tris-MIC ligand. Study of the electronic properties and catalytic activities." Beilstein Journal of Organic Chemistry 11 (December 14, 2015): 2584–90. http://dx.doi.org/10.3762/bjoc.11.278.

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The coordination versatility of a 1,3,5-triphenylbenzene-tris-mesoionic carbene ligand is illustrated by the preparation of complexes with three different metals: rhodium, iridium and nickel. The rhodium and iridium complexes contained the [MCl(COD)] fragments, while the nickel compound contained [NiCpCl]. The preparation of the tris-MIC (MIC = mesoionic carbene) complex with three [IrCl(CO)2] fragments, allowed the estimation of the Tolman electronic parameter (TEP) for the ligand, which was compared with the TEP value for a related 1,3,5-triphenylbenzene-tris-NHC ligand. The electronic prope

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6

Phonsri, Wasinee, Barnaby A. I. Lewis, Guy N. L. Jameson, and Keith S. Murray. "Double spin crossovers: a new double salt strategy to improve magnetic and memory properties." Chemical Communications 55, no. 93 (2019): 14031–34. http://dx.doi.org/10.1039/c9cc07416c.

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The first example of a “double spin crossover” material, [Fe<sup>II</sup>(3,5-Me<sub>2</sub> tris(pyrazolyl)methane)(tris(pyrazolyl)methane)][Fe<sup>III</sup> azodiphenolate]ClO<sub>4</sub>·2MeCN was synthesised by reacting a spin crossover Fe<sup>II</sup> complex cation with a spin crossover Fe<sup>III</sup> complex anion.

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7

Boese, O., S. I. Troyanov, and E. Kemnitz. "Crystal Structure of a New Dimethyl Carbonate/2,4,6-Tris(trifluoromethyl)- 1,3,5-triazine 1:1 Adduct." Zeitschrift für Naturforschung B 58, no. 4 (2003): 356–58. http://dx.doi.org/10.1515/znb-2003-0417.

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The crystal structure of a new 1:1 complex of dimethyl carbonate and 2,4,6-tris(trifluoromethyl)-1,3,5-triazine is reported. A high tendency of sublimation was observed by differential thermal analysis (DTA) and thermogravimetry (TG). Donor-acceptor interactions between dimethyl carbonate and 2,4,6-tris(trifluoro-methyl)-1,3,5-triazine are assumed to be responsible for the complex formation.

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8

Boreen, Michael A., Bernard F. Parker, Trevor D. Lohrey, and John Arnold. "A Homoleptic Uranium(III) Tris(aryl) Complex." Journal of the American Chemical Society 138, no. 49 (2016): 15865–68. http://dx.doi.org/10.1021/jacs.6b11182.

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9

Beloglazkina, Elena K., Elena S. Barskaya, Alexander G. Majouga, and Nikolai V. Zyk. "The first tris(imidazolylbenzothiazole) copper(II) complex." Mendeleev Communications 25, no. 2 (2015): 148–49. http://dx.doi.org/10.1016/j.mencom.2015.03.025.

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10

Chayanika, Debnath, Debnath Diptanu, and Kumar Misra Tarun. "Inorganic base assisted synthesis of sodium [tris-(acetylacetonato)nickelate(II)] complex and kinetics of its acid-dissociation." Journal of Indian Chemical Society Vol. 92, Sep 2015 (2015): 1337–47. https://doi.org/10.5281/zenodo.5701707.

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Department of Chemistry, National Institute of Technology, Agartala-799 046, Tripura, India <em>E-mail </em>: t_k_misra@yahoo.com <em>Manuscript received online 26 October 2014, revised 11 December 2014, accepted 15 January 2015</em> Nickel(II) complexes of acetylacetone are potential materials in all disciplines notably catalysis and biology. Most of them are not easy to prepare. A synthetic method of preparation and isolation of sodium salt of <em>tris</em>- (acetylacetonato)nickelate(II), Na[Ni(acac)<sub>3</sub> ] and study of its stability in aqueous and acidic media have been reported. Th

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11

Carmalt, Claire J., Alan H. Cowley, Robert D. Culp, and Richard A. Jones. "Synthesis and crystal structure of the tris(pyridine) complex of gallium tris(azide)." Chemical Communications, no. 12 (1996): 1453. http://dx.doi.org/10.1039/cc9960001453.

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12

Lazic, Dragica, Branko Skundric, Jelena Penavin-Skundric, et al. "Stability of tris-1,10 - phenanthroline iron (II) complex in different composites." Chemical Industry and Chemical Engineering Quarterly 16, no. 2 (2010): 193–98. http://dx.doi.org/10.2298/ciceq100204028l.

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The composition of composites has a huge impact on the stability of tris-1, 10 - phenanthroline iron (II) complex during the determination of total iron. The subject of this work is determination the stability of tris-1, 10 - phenanthroline iron (II) complex in different composites. Composites with different concentration in which total iron was determined were alumina and zeolite. Stability of this complex was monitored in a time period of 0-60 min. The aim of this work is to determine the concentration of different composite samples and the time interval in which the stability of the complex

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13

Ibáñez, S., M. Poyatos, and E. Peris. "A D3h-symmetry hexaazatriphenylene-tris-N-heterocyclic carbene ligand and its coordination to iridium and gold: preliminary catalytic studies." Chemical Communications 53, no. 26 (2017): 3733–36. http://dx.doi.org/10.1039/c7cc00525c.

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A planar star-shaped tris-NHC ligand with a hexaazatriphenylene core was coordinated to gold and iridium. The tris–Au(i) complex shows enhanced catalytic activities due to the electron-deficient character of the HAT core.

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14

Wang, Jie, Hongyu Guan, Chunhua Ge, Ping Fan, Xijuan Xing, and Yunshan Shang. "Azocalix[4]arene with three distal ethyl ester residues as a highly selective chromogenic sensor for Ca2+ ions." Heterocyclic Communications 24, no. 3 (2018): 147–50. http://dx.doi.org/10.1515/hc-2017-0239.

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AbstractThree azocalix[4]arenes with distal ethyl ester residues, 5-phenylazo-25,26,27-tris[(ethoxycarbonyl)methoxy]-28-hydroxycalix[4]arene (2), 5-(o-methylphenyl)azo-25,26,27-tris[(ethoxycarbonyl)methoxy]-28-hydroxycalix[4]arene (3), 5-(p-Methylphenyl)azo-25,26,27-tris[(ethoxycarbonyl)methoxy]-28-hydroxycalix[4]arene (4), were synthesized and their binding properties with metal ions were investigated by ultraviolet (UV)/visible spectroscopy. The chromogenic behavior of these compounds upon metal ion complexation indicates a specific selectivity toward Ca2+ ion in the presence of other cation

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15

Szilágyi, István, László Horváth, Imre Labádi, Klara Hernadi, István Pálinkó, and Tamás Kiss. "Mimicking catalase and catecholase enzymes by copper(II)-containing complexes." Open Chemistry 4, no. 1 (2006): 118–34. http://dx.doi.org/10.1007/s11532-005-0009-6.

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AbstractAn imidazolate-bridged copper(II)-zinc(II) complex (Cu(II)-diethylenetriamino-μ-imidazolato-Zn(II)-tris(2-aminoethyl)amine perchlorate (denoted as “Cu,Zn complex”) and a simple copper(II) complex (Cu(II)-tris(2-aminoethyl) amine chloride (“Cu-tren”) were prepared and immobilised on silica gel (by hydrogen or covalent bonds) and montmorillonite (by ion exchange). The immobilised substances were characterised by FT-IR spectroscopy and their thermal characteristics were also studied. The obtained materials were tested in two probe reactions: catalytic oxidation of 3,5-di-tert-butyl catech

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16

Nakai, Hidetaka, Juncheol Seo, Kazuhiro Kitagawa, Takahiro Goto, Takahiro Matsumoto, and Seiji Ogo. "An oxygen-sensitive luminescent Dy(iii) complex." Dalton Transactions 45, no. 23 (2016): 9492–96. http://dx.doi.org/10.1039/c6dt01057a.

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17

Hocek, Michal, Irena G. Stará, Ivo Starý, and Hana Dvořáková. "Covalent Analogues of DNA Base-Pairs and Triplets IV. Synthesis of Trisubstituted Benzenes Bearing Purine and/or Pyrimidine Rings by Cyclotrimerization of 6-Ethynylpurines and/or 5-Ethynyl-1,3-dimethyluracil." Collection of Czechoslovak Chemical Communications 67, no. 8 (2002): 1223–35. http://dx.doi.org/10.1135/cccc20021223.

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Ni-Catalyzed cyclotrimerizations of 6-ethynylpurines 3 or 5-ethynyl-1,3-dimethyluracil (4) afforded the 1,2,4-tris(purin-6-yl)benzenes 7 or 1,2,4-tris(1,3-dimetyhyluracil-5-yl)benzene (9), respectively. The symmetrical 1,3,5-tris(purin-6-yl)benzenes 8 were also formed as minor products in very low yields. Co-cyclotrimerization of 9-benzyl-6-ethynylpurine (3a) with 4 afforded the tris(purinyl)benzene 7a as a major product along with 1,2-bis(9-benzylpurin-6-yl)-4-(1,3-dimethyluracil-5-yl)benzene (10) and a complex mixture of other derivatives and isomers. Compounds 7-10 are analogues of Hoogstee

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18

Hodzic, I. M., and S. R. Niketic. "Synthesis and characterization of a novel (glycinato-N,O) yttrium(III) complex." Journal of the Serbian Chemical Society 66, no. 5 (2001): 331–34. http://dx.doi.org/10.2298/jsc0105331h.

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A novel yttrium(III) complex with glycine has been synthesized starting from tris(ethanedioato-O,O)yttrium(III) by the substitution of the acetylacetonato chelate ligands with glycine. The reaction product was purified by ion-exchange chromatography and characterized on the basis of infrared spectroscopy. The structure of the productwas tentatively established as tris(glycinato-N,O)yttrium(III) dihydrate.

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19

Kellö, Eleonóra, Jan Lokaj, and Viktor Vrábel. "Structure of the Tris(diallyldithiocarbamate)cobalt(III) Complex." Collection of Czechoslovak Chemical Communications 57, no. 2 (1992): 332–38. http://dx.doi.org/10.1135/cccc19920332.

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The structure of [Co{S2CN(CH2-CH=CH2)2}3] was determined by the heavy atom method, all nonhydrogen atoms being refined by anisotropic diagonal approximation using the least squares method to the value of R= 0.067 for 1 024 reflections with I ≥ 1.96σ(I). The substance is isostructural with [Fe{S2CN(CH2-CH=CH2)2}3], crystallizes in the monoclinic system, space group C2/c, lattice parameters a = 1.8763(9), b = 1.0209(5), c = 1.5402(7) nm, β = 106.18(4)°, Z = 4. Cobalt is coordinated by 3 dithiocarbamate ligands in the bidentate way, the average Co-S lenght is 0.2267(2) nm. The metal atom and two

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20

Bedford, R. B., P. A. Chaloner, and P. B. Hitchcock. "An iridium complex of tris(4-methoxyphenyl)phosphine." Acta Crystallographica Section C Crystal Structure Communications 50, no. 3 (1994): 354–56. http://dx.doi.org/10.1107/s0108270193008819.

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21

Bedford, R. B., P. A. Chaloner, P. B. Hitchcock, and S. S. Al-Juaid. "An iridium complex of tris(2,4,6-trimethoxyphenyl)phosphine." Acta Crystallographica Section C Crystal Structure Communications 50, no. 3 (1994): 356–58. http://dx.doi.org/10.1107/s0108270193009424.

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22

Hou, Zhaomin, Akira Fujita, Hiroshi Yamazaki, and Yasuo Wakatsuki. "First Isolation of a Tris(ketyl) Metal Complex." Journal of the American Chemical Society 118, no. 33 (1996): 7843–44. http://dx.doi.org/10.1021/ja9616185.

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23

Alexiou, Anamaria, Denny Silva, Paulete Romoff та Marcelo Ferreira. "Tris(3,7-dihydroxyflavonolate-κO3,O4)chromium(III) Complex". Molbank 2016, № 1 (2016): M886. http://dx.doi.org/10.3390/m886.

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24

Kuhn, Norbert, Stefan Fuchs, and Manfred Steimann. "(C7H13N2)3Al − The First Tris(diketiminato)metal Complex." European Journal of Inorganic Chemistry 2001, no. 2 (2001): 359–61. http://dx.doi.org/10.1002/1099-0682(200102)2001:2<359::aid-ejic359>3.0.co;2-r.

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25

Benn, Michael H., Arvi Rauk та Thomas W. Swaddle. "Measurement of the interaction of aqueous copper(II) with a model amyloid-β protein fragment — Interference from buffers". Canadian Journal of Chemistry 89, № 12 (2011): 1429–44. http://dx.doi.org/10.1139/v11-101.

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For the formation of a complex of Cu2+ with the amyloid-β (Aβ) proxy N-α-dihydrourocanylhistamine (L) in unbuffered aqueous solution (pH ∼ 5.7, 25.0 °C), UV spectrophotometric measurements give a stability constant of 3.8 × 105 L mol–1. This stability constant is within the lower limit of the range of stability constants reported in the literature for complexes of Aβ with Cu2+ — as expected, in view of the smaller number of coordination sites in L. Computer modeling indicates that the Cu2+–L complex is CuL(H2O)22+, with terdentate L bound to Cu2+ via two Nπ atoms and the O atom of the peptide

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26

Zagidullin, Almaz A., Farida F. Akhmatkhanova, Mikhail N. Khrizanforov, et al. "Synthesis and electrochemical properties of 3,4,5-tris(chlorophenyl)-1,2-diphosphaferrocenes." Beilstein Journal of Organic Chemistry 18 (September 27, 2022): 1338–45. http://dx.doi.org/10.3762/bjoc.18.139.

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A novel representative of sodium 3,4,5-triaryl-1,2-diphosphacyclopentadienide containing a chloro substituent in the meta-position of the aryl groups was obtained with a high yield based on the reaction of tributyl(1,2,3-triarylcyclopropenyl)phosphonium bromide and sodium polyphosphides. Further reaction of sodium 3,4,5-tris(3-chlorophenyl)-1,2-diphosphacyclopentadienide with [FeCp(η6-C6H5CH3)][PF6] complex gives a new 3,4,5-tris(3-chlorophenyl)-1,2-diphosphaferrocene. The electrochemical properties of 3,4,5-tris(3-chlorophenyl)-1,2-diphosphaferrocene were studied and compared to 3,4,5-tris(4-

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27

Sirianni, Eric R., Glenn P. A. Yap, Eser S. Akturk, and Klaus H. Theopold. "Improved syntheses, and structural and electronic characterization of carboxamide-substituted TpCONHPh,Meand TpCONHt-Bu,Meligands." Acta Crystallographica Section C Crystal Structure Communications 69, no. 9 (2013): 947–53. http://dx.doi.org/10.1107/s0108270113015898.

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Improvements in the syntheses of the carboxamide-substituted tris(pyrazolyl)borate ligands TpCONHPh,Me[tris(3-anilinocarbonyl-5-methylpyrazol-1-yl)borate] and TpCONHt-Bu,Me[tris(3-tert-butylaminocarbonyl-5-methylpyrazol-1-yl)borate] are reported. Their TlIsalts, namely [tris(3-anilinocarbonyl-5-methylpyrazol-1-yl-κN2)borato]thallium(I), [Tl(C33H31BN9O3)], (II), and [tris(3-tert-butylaminocarbonyl-5-methylpyrazol-1-yl-κN2)borato]thallium(I), [Tl(C27H43BN9O3)], (III), as well as the CuIcarbonyl complexes (TpCONHPh,Me)Cu(CO), namely carbonyl[tris(3-anilinocarbonyl-5-methylpyrazol-1-yl-κN2)borato]

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28

Oh, Jinyoung, Dahyun Kang, Sugyeong Hong, Sun H. Kim, Jun-Ho Choi, and Jiwon Seo. "Formation of a tris(catecholato) iron(iii) complex with a nature-inspired cyclic peptoid ligand." Dalton Transactions 50, no. 10 (2021): 3459–63. http://dx.doi.org/10.1039/d1dt00091h.

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Siderophore-mimicking catechol-containing macrocyclic peptoids were synthesized, and their Fe(iii) complexes were characterized. The 3-Fe(iii) complex exhibited stable tris-complex with a 1 : 1 stoichiometry.

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29

Mandal, Poulami, Jerome Kretzschmar, and Björn Drobot. "Not just a background: pH buffers do interact with lanthanide ions—a Europium(III) case study." JBIC Journal of Biological Inorganic Chemistry 27, no. 2 (2022): 249–60. http://dx.doi.org/10.1007/s00775-022-01930-x.

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AbstractThe interaction between Eu(III) ion and different pH buffers, popular in biology and biochemistry, viz. HEPES, PIPES, MES, MOPS, and TRIS, has been studied by solution nuclear magnetic resonance spectroscopy (NMR) and time-resolved laser-induced fluorescence spectroscopy (TRLFS) techniques. The Good’s buffers reveal non-negligible interaction with Eu(III) as determined from their complex stability constants, where the sites of interaction are the morpholine and piperazine nitrogen atoms, respectively. In contrast, TRIS buffer shows practically no affinity towards Eu(III). Therefore, wh

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Zhan, Yan-Cen, Jia-Jen Tsai, and Yu-Chie Chen. "Zinc Ion-Based Switch-on Fluorescence-Sensing Probes for the Detection of Tetracycline." Molecules 27, no. 23 (2022): 8403. http://dx.doi.org/10.3390/molecules27238403.

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Tetracycline (TC) is an antibiotic that has been widely used in the animal husbandry. Thus, TC residues may be found in animal products. Developing simple and sensitive methods for rapid screening of TC in complex samples is of great importance. Herein, we demonstrate a fluorescence-sensing method using Zn2+ as sensing probes for the detection of TC. Although TC can emit fluorescence under the excitation of ultraviolet light, its fluorescence is weak because of dynamic intramolecular rotations, leading to the dissipation of excitation energy. With the addition of Zn2+ prepared in tris(hydroxym

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31

Zhang, Zaihui, T. L. Thomas Hui, and Chris Orvig. "One-pot synthesis of N-substituted-3-hydroxy-4-pyridinone chelate complexes of aluminum, gallium, and indium." Canadian Journal of Chemistry 67, no. 11 (1989): 1708–10. http://dx.doi.org/10.1139/v89-263.

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A series of tris(3-hydroxy-2-methyl-4-pyridinonato)metal(III) and tris(3-hydroxy-6-hydroxymethyl-4-pyridinonato)metal(III) complexes have been prepared in water by one-pot synthesis directly from maltol and kojic acid, respectively, and the metal ion (M = Al, Ga, In) with an appropriate amine. The pyridinones have substituents at the ring nitrogen atom (CH3, C2H5). The tris(3-hydroxy-4-pyronato)metal(III) complexes are formed insitu and these undergo nucleophilic attack by the primary amine; the appropriate tris(3-hydroxy-4-pyridinonato)metal(III) complexes are obtained. This method bypasses t

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32

Kay, Neil, Traci Sassoon, Charla Secreto, Asish K. Ghosh, and Jack L. Arbiser. "TRIS (DIBENZYLIDENEACETONE) Dipalladium a Small-Molecule Palladium Complex Is Effective in the Induction of Apoptosis for B-Chronic Lymphocytic Leukemia B-Cells." Blood 118, no. 21 (2011): 2851. http://dx.doi.org/10.1182/blood.v118.21.2851.2851.

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Abstract Abstract 2851 Background: In an attempt to better treat B-Chronic Lymphocytic Leukemia (CLL) patients, we have examined a unique organometallic complex called Tris (dibenzylideneacetone) dipalladium (Tris DBA). This novel agent is a small-molecule palladium complex shown to have antiproliferative activity against melanoma cells and possible antitumor activity. Tris DBA is known to inhibit activation of signaling molecules such as PI3K and STAT-3, critical factors in CLL B-cell survival and resistance to therapeutic agents. Because B-CLL remains incurable and treatment strategies chall

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33

Sagatys, Dalius S., Graham Smith, Raymond C. Bott, and Peter C. Healy. "The Preparation and Crystal Structure of Ammonium Bismuth(III) Thiosalicylate Dihydrate." Australian Journal of Chemistry 56, no. 9 (2003): 941. http://dx.doi.org/10.1071/ch03067.

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The bismuth(III) complex of thiosalicylic acid (2-mercaptobenzoic acid; H2L), ammonium tris(2-mercaptobenzoato-O,S) bismuth(III) dihydrate, {(NH4)3[Bi(L)3]·2 H2O}, has been prepared and its crystal structure determined. The distorted octahedral tris-bidentate complex unit has pseudo-C3 symmetry with the facially related thiolate sulfur donors providing a regular facial cap to the octahedron (Bi–S 2.595, 2.596, 2.596(5) Å) with the Bi–O(carboxylate) distances less regular (2.715, 2.741, 2.785(15) Å). The network polymeric structure is stabilized by hydrogen-bonding associations through both the

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34

Wu, Ruixia, Weiqiang Liu, Liang Zhou, Xiaokang Li, Kai Chen, and Hongjie Zhang. "Highly efficient green single-emitting layer phosphorescent organic light-emitting diodes with an iridium(iii) complex as a hole-type sensitizer." Journal of Materials Chemistry C 7, no. 9 (2019): 2744–50. http://dx.doi.org/10.1039/c8tc06509h.

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The electroluminescent (EL) performances of a green iridium complex tris(2-(4-tolyl)phenylpyridine)iridium Ir(mppy)<sub>3</sub> were significantly improved by employing another hole-type iridium complex as a sensitizer.

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35

Settineri, Nicholas S., Angela A. Shiau, and John Arnold. "Two-electron oxidation of a homoleptic U(iii) guanidinate complex by diphenyldiazomethane." Chemical Communications 54, no. 77 (2018): 10913–16. http://dx.doi.org/10.1039/c8cc06514d.

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36

Rousset, E., D. Chartrand, I. Ciofini, V. Marvaud, and G. S. Hanan. "Red-light-driven photocatalytic hydrogen evolution using a ruthenium quaterpyridine complex." Chemical Communications 51, no. 45 (2015): 9261–64. http://dx.doi.org/10.1039/c5cc02124c.

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37

Matsumoto, Wako, Muneyuki Naito, and Hiroshi Danjo. "Preparation of spiroborate supramolecular and peapod polymers containing a photoluminescent ruthenium(ii) complex." RSC Advances 13, no. 36 (2023): 25002–6. http://dx.doi.org/10.1039/d3ra03940d.

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38

Beh, Daniel W., Warren E. Piers, Benjamin S. Gelfand, and Jian-Bin Lin. "Tandem deoxygenative hydrosilation of carbon dioxide with a cationic scandium hydridoborate and B(C6F5)3." Dalton Transactions 49, no. 1 (2020): 95–101. http://dx.doi.org/10.1039/c9dt04323c.

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A scandium hydridoborate complex supported by the dianionic pentadentate ligand B<sub>2</sub>Pz<sub>4</sub>Py is prepared via hydride abstraction from the previously reported scandium hydride complex with tris-pentafluorophenyl borane.

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39

Hoffmann, A., U. Flörke, and S. Herres-Pawlis. "Tris-phenyl substituted tris(pyrazolyl)methane: Victim of a novel rearrangement in a cobalt(II) complex." Inorganic Chemistry Communications 22 (August 2012): 154–57. http://dx.doi.org/10.1016/j.inoche.2012.05.049.

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40

Endo, Akira, Masamitsu Kimura, Takeshi Hashimoto, and Takashi Hayashita. "A novel electrochemical sugar recognition system using a ruthenium complex and phenylboronic acid assembled on gold nanoparticles." Anal. Methods 6, no. 22 (2014): 8874–77. http://dx.doi.org/10.1039/c4ay01716a.

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41

Miarzlou, Dzmitry A., Florian Leisinger, Daniel Joss, Daniel Häussinger, and Florian P. Seebeck. "Structure of formylglycine-generating enzyme in complex with copper and a substrate reveals an acidic pocket for binding and activation of molecular oxygen." Chemical Science 10, no. 29 (2019): 7049–58. http://dx.doi.org/10.1039/c9sc01723b.

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42

Matin, Mohammad A., Mazharul M. Islam, and Mohammed A. Aziz. "Characterization of Chromium-tris(catecholate) Complex: A Theoretical Study." Dhaka University Journal of Science 65, no. 2 (2017): 113–17. http://dx.doi.org/10.3329/dujs.v65i2.54518.

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Phenolic compounds generally have special smell and are easily soluble in water, organic solvents (alcohols, esters, chloroform, ethyl acetate) and in alkali. Phenols produce coloured complexes with heavy metal ions, such as with chromium ion. The molecular details underlying the cross-linking mediated by transition metal ions are largely unknown. Using HF/DFT hybrid approach B3LYP, this study examines the structure, binding energy, spectroscopic and electronic properties of complex formed by the attachment of Cr3+ with a catechol ligand. Our study shows that the binding of Cr3+ with the catec

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43

Shin, Yong Woon, Hyun Sook Baek, Jae-Kyung Yang, Jineun Kim, and Moo Lyong Seo. "Stability of Tris(2-cyclohexylaminoethyl)amine-Zn(II) Complex." Journal of the Korean Chemical Society 47, no. 2 (2003): 121–26. http://dx.doi.org/10.5012/jkcs.2003.47.2.121.

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44

Sharma, Sonika, and Neeraj Sharma. "Synthesis and Characterization of Tris(nicotinohydroxamato) Vanadium(III) Complex." Advanced Science, Engineering and Medicine 12, no. 5 (2020): 695–701. http://dx.doi.org/10.1166/asem.2020.2639.

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The tris(nicotinohydroxamato) vanadium(III) complex of composition [V(C5H4NCONHO)3] have been synthesized by the reaction of VCl3 with three equivalents of potassium salts of nicotinohydroxamate in methanol medium under nitrogen atmosphere. The characterization of complex has been accomplished by elemental analyses, molar conductivity, magnetic moment measurements, IR, electronic and mass spectral studies. An octahedral geometry around vanadium, inferred from physicochemical and spectral studies has been proposed for complex. The antimicrobial activities of the newly synthesized complex, ligan

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45

Thummel, Randolph P., Francois Lefoulon, and Sara Chirayil. "A ruthenium tris(diimine) complex with three different ligands." Inorganic Chemistry 26, no. 18 (1987): 3072–74. http://dx.doi.org/10.1021/ic00265a031.

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Saravana Bharathi, D., M. A. Sridhar, J. Shashidhara Prasad, and Ashoka G. Samuelson. "The first copper(I) complex of tris(hydroxymethyl)phosphine." Inorganic Chemistry Communications 4, no. 9 (2001): 490–92. http://dx.doi.org/10.1016/s1387-7003(01)00253-2.

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Khokhlov, Mikhail L., Aleksandr E. Miroslavov, Evgenii K. Legin, et al. "Tris(methyltrihydroborato)(tetrahydrofuran)ytterbium(III) complex: structure and volatility." Mendeleev Communications 29, no. 6 (2019): 696–97. http://dx.doi.org/10.1016/j.mencom.2019.11.032.

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Zilian, Arne, and Hans U. Güdel. "Zeeman spectra of a rhodium(III) tris chelate complex." Journal of Luminescence 51, no. 5 (1992): 237–47. http://dx.doi.org/10.1016/0022-2313(92)90075-k.

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Khadikar, Padmakar V. "Novel thermal decarboxylation of tris(mandelato)-thallium(III) complex." Thermochimica Acta 116 (June 1987): 171–82. http://dx.doi.org/10.1016/0040-6031(87)88177-7.

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Halbach, Robert L., David Gygi, Eric D. Bloch, Bryce L. Anderson, and Daniel G. Nocera. "Structurally characterized terminal manganese(iv) oxo tris(alkoxide) complex." Chemical Science 9, no. 19 (2018): 4524–28. http://dx.doi.org/10.1039/c8sc01164h.

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