Academic literature on the topic 'Tropospheric halogens'

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Journal articles on the topic "Tropospheric halogens"

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Caram, Cyril, Sophie Szopa, Anne Cozic, Slimane Bekki, Carlos A. Cuevas, and Alfonso Saiz-Lopez. "Sensitivity of tropospheric ozone to halogen chemistry in the chemistry–climate model LMDZ-INCA vNMHC." Geoscientific Model Development 16, no. 14 (2023): 4041–62. http://dx.doi.org/10.5194/gmd-16-4041-2023.

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Abstract. The atmospheric chemistry of halogenated species (Cl, Br, I) participates in the global chemical sink of tropospheric ozone and perturbs the oxidising capacity of the troposphere, notably by influencing the atmospheric lifetime of methane. Global chemistry–climate models are commonly used to assess the global budget of ozone and its sensitivity to emissions of its precursors, as well as to project its long-term evolution. Here, we report on the implementation of tropospheric sources and chemistry of halogens in the chemistry–climate model LMDZ-INCA (Laboratoire de Météorologie Dynami
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Sherwen, Tomás, Mat J. Evans, Lucy J. Carpenter, Johan A. Schmidt, and Loretta J. Mickley. "Halogen chemistry reduces tropospheric O<sub>3</sub> radiative forcing." Atmospheric Chemistry and Physics 17, no. 2 (2017): 1557–69. http://dx.doi.org/10.5194/acp-17-1557-2017.

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Abstract. Tropospheric ozone (O3) is a global warming gas, but the lack of a firm observational record since the preindustrial period means that estimates of its radiative forcing (RFTO3) rely on model calculations. Recent observational evidence shows that halogens are pervasive in the troposphere and need to be represented in chemistry-transport models for an accurate simulation of present-day O3. Using the GEOS-Chem model we show that tropospheric halogen chemistry is likely more active in the present day than in the preindustrial. This is due to increased oceanic iodine emissions driven by
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Wang, Siyuan, Johan A. Schmidt, Sunil Baidar, et al. "Active and widespread halogen chemistry in the tropical and subtropical free troposphere." Proceedings of the National Academy of Sciences 112, no. 30 (2015): 9281–86. http://dx.doi.org/10.1073/pnas.1505142112.

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Halogens in the troposphere are increasingly recognized as playing an important role for atmospheric chemistry, and possibly climate. Bromine and iodine react catalytically to destroy ozone (O3), oxidize mercury, and modify oxidative capacity that is relevant for the lifetime of greenhouse gases. Most of the tropospheric O3 and methane (CH4) loss occurs at tropical latitudes. Here we report simultaneous measurements of vertical profiles of bromine oxide (BrO) and iodine oxide (IO) in the tropical and subtropical free troposphere (10°N to 40°S), and show that these halogens are responsible for
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Long, M. S., W. C. Keene, R. C. Easter, et al. "Sensitivity of tropospheric chemical composition to halogen-radical chemistry using a fully coupled size-resolved multiphase chemistry/global climate system – Part 1: Halogen distributions, aerosol composition, and sensitivity of climate-relevant gases." Atmospheric Chemistry and Physics Discussions 13, no. 3 (2013): 6067–129. http://dx.doi.org/10.5194/acpd-13-6067-2013.

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Abstract. Observations and model studies suggest a significant but highly non-linear role for halogens, primarily Cl and Br, in multiphase atmospheric processes relevant to tropospheric chemistry and composition, aerosol evolution, radiative transfer, weather, and climate. The sensitivity of global atmospheric chemistry to the production of marine aerosol and the associated activation and cycling of inorganic Cl and Br was tested using a size-resolved multiphase coupled chemistry/global climate model (National Center for Atmospheric Research's Community Atmosphere Model (CAM); v3.6.33). Simula
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Lary, D. J. "Halogens and the chemistry of the free troposphere." Atmospheric Chemistry and Physics Discussions 4, no. 5 (2004): 5367–80. http://dx.doi.org/10.5194/acpd-4-5367-2004.

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Abstract. The role of halogens in both the marine boundary layer and the stratosphere has long been recognized, while their role in the free troposphere is often not considered in global chemical models. However, a careful examination of free-tropospheric chemistry constrained by observations using a full chemical data assimilation system shows that halogens do play a significant role in the free troposphere. In particular, the chlorine initiation of methane oxidation in the free troposphere can contribute more than 10%, and in some regions up to 50%, of the total rate of initiation. The initi
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Lary, D. J. "Halogens and the chemistry of the free troposphere." Atmospheric Chemistry and Physics 5, no. 1 (2005): 227–37. http://dx.doi.org/10.5194/acp-5-227-2005.

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Abstract. The role of halogens in both the marine boundary layer and the stratosphere has long been recognized, while their role in the free troposphere is often not considered in global chemical models. However, a careful examination of free-tropospheric chemistry constrained by observations using a full chemical data assimilation system shows that halogens do play a significant role in the free troposphere. In particular, the chlorine initiation of methane oxidation in the free troposphere can contribute more than 10%, and in some regions up to 50%, of the total rate of initiation. The initi
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Cadoux, Anita, Susann Tegtmeier, and Alessandro Aiuppa. "Natural Halogen Emissions to the Atmosphere: Sources, Flux, and Environmental Impact." Elements 18, no. 1 (2022): 27–33. http://dx.doi.org/10.2138/gselements.18.1.27.

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Understanding the atmospheric geochemical cycle of both natural and anthropogenic halogens is important because of the detrimental effect halogens have on the environment, notably on tropospheric and stratospheric ozone. Oceans are the primary natural source for atmospheric Cl, F, Br, and I, but anthropogenic emissions are still important, especially for Cl. While emissions of human-made halocarbons (e.g., chlorofluorocarbons or CFCs) are expected to continue to decrease allowing progressive stratospheric ozone recovery, volcanic activity (e.g., clusters of mid-scale explosive eruptions or lar
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Sherwen, Tomás, Johan A. Schmidt, Mat J. Evans, et al. "Global impacts of tropospheric halogens (Cl, Br, I) on oxidants and composition in GEOS-Chem." Atmospheric Chemistry and Physics 16, no. 18 (2016): 12239–71. http://dx.doi.org/10.5194/acp-16-12239-2016.

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Abstract. We present a simulation of the global present-day composition of the troposphere which includes the chemistry of halogens (Cl, Br, I). Building on previous work within the GEOS-Chem model we include emissions of inorganic iodine from the oceans, anthropogenic and biogenic sources of halogenated gases, gas phase chemistry, and a parameterised approach to heterogeneous halogen chemistry. Consistent with Schmidt et al. (2016) we do not include sea-salt debromination. Observations of halogen radicals (BrO, IO) are sparse but the model has some skill in reproducing these. Modelled IO show
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Lehrer, E., G. Hönninger, and U. Platt. "The mechanism of halogen liberation in the polar troposphere." Atmospheric Chemistry and Physics Discussions 4, no. 3 (2004): 3607–52. http://dx.doi.org/10.5194/acpd-4-3607-2004.

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Abstract. Sudden depletions of tropospheric ozone during spring were reported from the Arctic and also from Antarctic coastal sites. Field studies showed that those depletion events are caused by reactive halogen species, especially bromine compounds. However the source and seasonal variation of reactive halogen species is still not completely understood. There are several indications that the halogen mobilisation from the sea ice surface of the polar oceans may be the most important source for the necessary halogens. Here we present a 1-D model study aimed at determining the primary source of
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Lehrer, E., G. Hönninger, and U. Platt. "A one dimensional model study of the mechanism of halogen liberation and vertical transport in the polar troposphere." Atmospheric Chemistry and Physics 4, no. 11/12 (2004): 2427–40. http://dx.doi.org/10.5194/acp-4-2427-2004.

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Abstract. Sudden depletions of tropospheric ozone during spring were reported from the Arctic and also from Antarctic coastal sites. Field studies showed that those depletion events are caused by reactive halogen species, especially bromine compounds. However the source and seasonal variation of reactive halogen species is still not completely understood. There are several indications that the halogen mobilisation from the sea ice surface of the polar oceans may be the most important source for the necessary halogens. Here we present a one dimensional model study aimed at determining the prima
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Dissertations / Theses on the topic "Tropospheric halogens"

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Choi, Sungyeon. "Investigation of tropospheric bro using space-based total column bro measurements." Diss., Georgia Institute of Technology, 2012. http://hdl.handle.net/1853/43682.

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We derive tropospheric column BrO during the ARCTAS and ARCPAC field campaigns in spring 2008 using retrievals of total column BrO from the satellite UV nadir sensors OMI and GOME-2 using a radiative transfer model and stratospheric column BrO from a photochemical simulation. We conduct a comprehensive comparison of satellite-derived tropospheric BrO column to aircraft in-situ observations of BrO and related species. The aircraft profiles reveal that tropospheric BrO, when present during April 2008, was distributed over a broad range of altitudes rather than being confined to the planetary bou
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Galeazzo, Tommaso. "Tracking volcanic sulphate : modelling tropospheric volcanic sulphate formation and its oxygen isotopic signatures." Electronic Thesis or Diss., Sorbonne université, 2018. http://www.theses.fr/2018SORUS300.

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Les émissions volcaniques sont une source importante de soufre. Le soufre volcanique est oxydé et forme des aérosols sulfatés qui influencent le climat en absorbant et en dispersant le rayonnement solaire incident. Les émissions de soufre dans la troposphère influencent le climat local et régional, mais de grandes incertitudes subsistent en ce qui concerne l’oxydation et sa conversion en aérosols de sulfate volcanique. L’oxydation du soufre dans une vaste gamme de panaches volcaniques et l’influence des halogènes volcaniques sur la chimie du panache sont étudiées à l’aide d’un modèle de boîte
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Caram, Cyril. "Rôle et fonctionnement des atmosphères naturelles ou faiblement polluées dans la régulation de la capacité oxydante de l’atmosphère terrestre." Electronic Thesis or Diss., université Paris-Saclay, 2021. http://www.theses.fr/2021UPASJ008.

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La chimie des espèces halogénées (Cl, Br, I) dans l’atmosphère joue un rôle, à l’échelle mondiale, dans le puits chimique d'ozone troposphérique, gaz à effet de serre et source principale du radical hydroxyle (OH). Par conséquent, la chimie des composés halogénés peut affecter le radical OH dont la concentration est assimilée au pouvoir oxydant de la troposphère, et ainsi modifier le temps de vie de gaz à effet de serre comme le méthane. Néanmoins, cette chimie est rarement représentée pour la troposphère dans les modèles de chimie climat. Le modèle numérique tridimensionnel de chimie-climat L
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Impey, Gary A. "Photolyzable halogens in the Arctic troposphere." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0027/NQ39274.pdf.

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Enami, Shinichi. "Halogen cycles in the stratosphere and troposphere." 京都大学 (Kyoto University), 2006. http://hdl.handle.net/2433/136139.

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Allan, Beverley. "A spectroscopic study of radical chemistry in the troposphere." Thesis, University of East Anglia, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.266729.

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Sihler, Holger [Verfasser], and Ulrich [Akademischer Betreuer] Platt. "Halogen Activation in the Polar Troposphere / Holger Sihler ; Betreuer: Ulrich Platt." Heidelberg : Universitätsbibliothek Heidelberg, 2012. http://d-nb.info/1179786041/34.

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Viswanathan, Balakrishnan. "Theoretical investigation of mercury reactions with halogen species in the Arctic troposphere." Thesis, McGill University, 2001. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=33038.

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Mercury is one of the most toxic elements present in the geosphere, present in many chemical and physical forms. Nearly uniform mixing ratios are observed within a hemisphere, the concentration being higher in the northern than in the Southern Hemisphere. Lack of kinetic data regarding mercury reactions prevents an explanation of the behaviour and deposition pathways of mercury from the atmosphere. Theoretical calculations have been carried out using DFT theory to investigate the thermodynamics and kinetics of the reactions of Hg0 with Cl, Br, ClO, and BrO radicals and with Cl 2 and Br2. The r
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Cao, Le [Verfasser], and Eva [Akademischer Betreuer] Gutheil. "Numerical Investigation of Tropospheric Halogen Release and Ozone Depletion in the Polar Spring / Le Cao ; Betreuer: Eva Gutheil." Heidelberg : Universitätsbibliothek Heidelberg, 2014. http://d-nb.info/1179924622/34.

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Leather, Kimberley. "Tropospheric ozone and photochemical processing of hydrocarbons : laboratory based kinetic and product studies." Thesis, University of Manchester, 2012. https://www.research.manchester.ac.uk/portal/en/theses/tropospheric-ozone-and-photochemical-processing-of-hydrocarbons-laboratory-based-kinetic-and-product-studies(39b76a99-2358-4db2-be58-baa75d18efea).html.

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Laboratory based temperature-dependent kinetics and product yields for alkene ozonolysis and the reaction of CH3O2 with ClO and BrO have been measured via chamber studies and a turbulent flow tube coupled to CIMS (Chemical Ionisation Mass Spectrometry). In order to gain a better understanding of the fate of the products formed during hydrocarbon oxidation and their subsequent impact on the ozone budget (and so the oxidising capacity of the atmosphere) it is imperative to know the rate at which these reactions proceed and to identify their product yields. As tropospheric temperature varies, Arr
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Books on the topic "Tropospheric halogens"

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"HALOE algorithm improvements for upper tropospheric sounding": Yearly progress report, NRA-97-MTPE-04. National Aeronautics and Space Administration, 1999.

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Book chapters on the topic "Tropospheric halogens"

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Molina, Mario J. "Chemical Interactions of Tropospheric Halogens on Snow/Ice." In The Tropospheric Chemistry of Ozone in the Polar Regions. Springer Berlin Heidelberg, 1993. http://dx.doi.org/10.1007/978-3-642-78211-4_19.

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Lavigne, J. Allen, and Cooper H. Langford. "Liquid Phase Photochemistry in Relation to Tropospheric Chemistry of Halogens." In The Tropospheric Chemistry of Ozone in the Polar Regions. Springer Berlin Heidelberg, 1993. http://dx.doi.org/10.1007/978-3-642-78211-4_22.

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Hanson, David R., and A. R. Ravishankara. "Reactions of Halogen Species on Ice Surfaces." In The Tropospheric Chemistry of Ozone in the Polar Regions. Springer Berlin Heidelberg, 1993. http://dx.doi.org/10.1007/978-3-642-78211-4_20.

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Wine, P. H., J. M. Nicovich, R. E. Stickel, et al. "Halogen and Sulfur Reactions Relevant to Polar Chemistry." In The Tropospheric Chemistry of Ozone in the Polar Regions. Springer Berlin Heidelberg, 1993. http://dx.doi.org/10.1007/978-3-642-78211-4_28.

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Sander, Stanley P., Scott L. Nickolaisen, and Randall R. Friedl. "ClO + ClO → Products: A Case Study in Halogen Monoxide Disproportionation and Recombination Reactions." In The Tropospheric Chemistry of Ozone in the Polar Regions. Springer Berlin Heidelberg, 1993. http://dx.doi.org/10.1007/978-3-642-78211-4_24.

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Platt, U. "Reactive Halogen Species in the Mid-Latitude Troposphere — Recent Discoveries." In Environmental Challenges. Springer Netherlands, 2000. http://dx.doi.org/10.1007/978-94-011-4369-1_20.

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Platt, Ulrich. "The Impact of Halogen Chemistry on the Oxidation Capacity of the Troposphere." In Global Atmospheric Change and its Impact on Regional Air Quality. Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0082-6_11.

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von Glasow, R., and P. J. Crutzen. "Tropospheric Halogen Chemistry." In Treatise on Geochemistry. Elsevier, 2003. http://dx.doi.org/10.1016/b0-08-043751-6/04141-4.

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von Glasow, R., and P. J. Crutzen. "Tropospheric Halogen Chemistry." In Treatise on Geochemistry. Elsevier, 2014. http://dx.doi.org/10.1016/b978-0-08-095975-7.00402-2.

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Calvert, Jack G., John J. Orlando, William R. Stockwell, and Timothy J. Wallington. "The Impact of Inorganic Trace Gases on Ozone in the Atmosphere." In The Mechanisms of Reactions Influencing Atmospheric Ozone. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190233020.003.0010.

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A major focus of the previous six chapters has been on the chemistry and interactions of the HOx, NOx, and volatile organic compound (VOC) families. Details of the reactions of O3 NO3, and HO that act to initiate VOC oxidation have been presented, as has the ensuing chemistry involving organic peroxy and alkoxy radicals and their interactions with NOx. In this chapter, we complete our discussion of thermal chemical reactions that impact tropospheric ozone. The chapter begins with a discussion of the budgets of two simple (inorganic) carbon-containing species not yet discussed, carbon dioxide (
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Conference papers on the topic "Tropospheric halogens"

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Cao, Le, and Eva Gutheil. "Modeling and Simulation of Tropospheric Ozone Depletion in the Polar Spring." In ASME 2014 4th Joint US-European Fluids Engineering Division Summer Meeting collocated with the ASME 2014 12th International Conference on Nanochannels, Microchannels, and Minichannels. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/fedsm2014-22045.

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In polar spring, tropospheric ozone depletion is related to the presence of halogen oxide concentrations in the atmospheric boundary layer. Halogen oxides such as BrO participate in an autocatalytic chemical reaction cycle, leading to the release of Br2 and BrCl from the fresh sea ice. The paper presents the identification of a detailed chemical reaction mechanism for the ozone depletion event, where bromine plays the major role. The heterogeneous reactions in the chemical reaction mechanism are studied in detail, and a sensitivity analysis is performed to identify the importance of each react
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Gunson, M. R., M. C. Abrams, C. B. Farmer, L. L. Lowes, C. P. Rinsland, and R. Zander. "Results from the flight of the Atmospheric Trace Molecule Spectroscopy on the ATLAS-1 Space Shuttle Mission." In Optical Remote Sensing of the Atmosphere. Optica Publishing Group, 1993. http://dx.doi.org/10.1364/orsa.1993.ma.4.

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During the ATLAS-1 space shuttle mission, the ATMOS experiment, a Fourier transform infrared spectrometer operating in solar occultation mode from on-orbit (Farmer, 1987), collected data through more than 90 orbital sunrises and sunsets at latitudes between 30°N and 55°S. The resulting high-resolution infrared solar absorption spectra from these observations have so far been analyzed for the vertical profiles of several species (O3, HNO3, ClNO3, HCl, HF, N2O, CH4 and H2O) of immediate importance as correlative measurements for other satellite instruments, such as those carried on the Upper Atm
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Russell, J. M., L. L. Gordley, J. H. Park, and S. R. Drayson. "HALOE Observations of Ozone, Halogen, Nitrogen, and Hydrogen Compounds Made from the UARS Platform." In Optical Remote Sensing of the Atmosphere. Optica Publishing Group, 1993. http://dx.doi.org/10.1364/orsa.1993.thd.3.

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The Halogen Occultation Experiment (HALOE) was launched September 12, 1991, by the Space Shuttle Discovery into a 57°, 585-km, near-circular orbit onboard the Upper Atmosphere Research Satellite (UARS). The experiment was allowed to outgass for about 1 month before science observations began on October 11, 1991. The experiment approach is solar occultation. The instrument technique uses the principle of gas-filter radiometry in four channels to measure vertical profiles of HCℓ, HF, CH4, and NO, and broadband radiometry in four other channels to measure NO2, H2O, O3, and CO2. The latter channel
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