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1

Liu, Lingna, Yi Hou, Xiuzhao Yin, Fang Zhang, and Zifei Peng. "Preparation and investigation of co-doped VO2 powders." Functional Materials Letters 12, no. 02 (2019): 1950015. http://dx.doi.org/10.1142/s1793604719500152.

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In this paper, tungsten-and molybdenum-doped vanadium dioxide (VO[Formula: see text] powders were prepared by hydrothermal reaction using vanadium pentoxide (V2O[Formula: see text], H2O2, white tungstic acid (WPTA) and sodium molybdate (Na2MoO[Formula: see text] as raw materials. The microstructure and composition of VO2 powders were characterized by means of XRD, XPS, DSC and FT-IR. We made a preliminary study on the thermal-induced phase transition properties of powders. The experimental results show that the co-doped samples are monoclinic rutile. Tungsten and molybdenum atoms exist in the
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2

Song, Qiang, Weitao Gong, Guiling Ning, et al. "A synergic effect of sodium on the phase transition of tungsten-doped vanadium dioxide." Phys. Chem. Chem. Phys. 16, no. 19 (2014): 8783–86. http://dx.doi.org/10.1039/c4cp00366g.

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3

Shin, Eunsung, KuanChang Pan, Weisong Wang, et al. "Tungsten-doped vanadium dioxide thin film based tunable antenna." Materials Research Bulletin 101 (May 2018): 287–90. http://dx.doi.org/10.1016/j.materresbull.2018.02.007.

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4

Peng, Zifei, Wei Jiang, and Heng Liu. "Structural Phase Transition of Tungsten-Doped Vanadium Dioxide Nanopowders Prepared by Thermolysis." Journal of Nanoscience and Nanotechnology 8, no. 3 (2008): 1417–21. http://dx.doi.org/10.1166/jnn.2008.18207.

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Tungsten-doped vanadium dioxide (VO2) nanopowders were prepared by thermolysis of (NH4)5[(VO)6(CO3)4(OH)9] · 10H2O at low temperature, with active white powdery tungstic acid used as a substitutional dopant. The composition and microstructure of the powders were examined by X-ray diffraction, transmission electron microscope, and differential scanning calorimetry. The change in electrical resistance due to the S–M transition was measured from 0 to 150 °C by the four-probe method. Hysteresis loops and differential scanning calorimetry analysis of the samples indicated that the phase-transition
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5

Liu, Chang, Mei Ping Jiang, Jin Hua Li, and Sa Ke Wang. "Stability of the Vanadium Oxide Films Forme by Reactive Sputtering and Ion Beam Enhanced Deposition Methods." Advanced Materials Research 399-401 (November 2011): 589–92. http://dx.doi.org/10.4028/www.scientific.net/amr.399-401.589.

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Vanadium oxide film is a common sensing film for infrared detector and uncooled infrared imaging devices, its stability directly affects the use of the thetse infrared devices.In this paper, high and low temperature cycles fatigue tests was used to check and compare the stability of the vanadium oxide films formed by different methods.The change of the temperature coefficient of resistance(TCR) and the room temperature resistance were measured and compared for the vanadium oxide film prepared by reactive sputtering and vanadium dioxide films by Ion Beam Enhanced Deposition(IBED) method. The re
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6

Qi, Ji, Bin Zhao, Naisen Yu, Chen Niu, and Guan Gran Sun. "Preparation of Tungsten-Doped VO2 (M) Nanoparticles through Sol-Gel Method and Hydrothermal Synthesis." Advanced Materials Research 881-883 (January 2014): 960–63. http://dx.doi.org/10.4028/www.scientific.net/amr.881-883.960.

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A new process was developed for synthesizing tungsten-doped vanadium dioxide VO2(M) from ammonium metavanadate. The process includes obtaining V2O5by pyrolysing NH4VO3, doping tungsten in V2O5by sol-gel method, and reducing V2O5to VO2(M) with hydrazine by hydrothermal method. X-ray diffraction (XRD), scanning electron microscopy (SEM) and differential scanning calorimetry (DSC) were applied to characterizing the product. The experimental results indicated that tungsten doped VO2(M) nanoparticles were successfully synthesized. The product VO2(M) presents mainly rod-like and block-like morpholog
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7

Wang, Xue-Jin, Yu-Ying Liu, De-Hua Li, Bao-Hua Feng, Zhi-Wei He, and Zheng Qi. "Structural and optical properties of tungsten-doped vanadium dioxide films." Chinese Physics B 22, no. 6 (2013): 066803. http://dx.doi.org/10.1088/1674-1056/22/6/066803.

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8

Shi, Jianqiu, Shuxue Zhou, Bo You, and Limin Wu. "Preparation and thermochromic property of tungsten-doped vanadium dioxide particles." Solar Energy Materials and Solar Cells 91, no. 19 (2007): 1856–62. http://dx.doi.org/10.1016/j.solmat.2007.06.016.

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9

Lee, Yonghyun, Sang Won Jung, Sang Hwi Park, Jung Whan Yoo, and Juhyun Park. "Synthesis of Tungsten-Doped Vanadium Dioxide Using a Modified Polyol Method Involving 1-Dodecanol." Materials 13, no. 23 (2020): 5384. http://dx.doi.org/10.3390/ma13235384.

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The doping of tungsten into VO2 (M) via a polyol process that is based on oligomerization of ammonium metavanadate and ethylene glycol (EG) to synthesize a vanadyl ethylene glycolate (VEG) followed by postcalcination was carried out by simply adding 1-dodecanol and the tungsten source tungstenoxytetrachloride (WOCl4). Tungsten-doped VEGs (W-VEGs) and their calcinated compounds (WxVO2) were prepared with varying mixing ratios of EG to 1-dodecanol and WOCl4 concentrations. Characterizations of W-VEGs by powder X-ray diffraction, differential scanning calorimetry, scanning electron microscopy, an
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10

Zhu, Mao-Dong, Chong Shan, Cheng Li, et al. "Thermochromic and Femtosecond-Laser-Induced Damage Performance of Tungsten-Doped Vanadium Dioxide Films Prepared Using an Alloy Target." Materials 11, no. 9 (2018): 1724. http://dx.doi.org/10.3390/ma11091724.

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Thermochromic tungsten-doped VO2 thin films were successfully fabricated using a W-V alloy target. X-ray diffraction analyses showed that the W-doped VO2 film had a preferred orientation of (011), and that the doping did not degrade the film crystallinity compared with that of the pure film. X-ray photoelectron spectroscopy and energy-dispersive spectroscopy showed that the doped 0.81 atom% tungsten replaced vanadium in the lattice of the film. The metal–insulator transition temperature of the W-doped VO2 film was reduced to 35.5 °C, which is close to room temperature. Additionally, the infrar
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11

Andreev, V. N., and V. A. Klimov. "Metal–Insulator Phase Transition in Tungsten-Doped Vanadium Dioxide Thin Films." Physics of the Solid State 61, no. 8 (2019): 1471–74. http://dx.doi.org/10.1134/s1063783419080055.

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12

Peng, Zifei, Yuan Wang, Yanyun Du, Dan Lu, and Dazhi Sun. "Phase transition and IR properties of tungsten-doped vanadium dioxide nanopowders." Journal of Alloys and Compounds 480, no. 2 (2009): 537–40. http://dx.doi.org/10.1016/j.jallcom.2009.01.092.

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13

Qin Yuan, 覃源, 李毅 Li Yi, 方宝英 Fang Baoying, et al. "Fabrication and Optical Properties of Vanadium Dioxide Thin Films Doped by Tungsten-Vanadium Co-Sputtering." Acta Optica Sinica 33, no. 12 (2013): 1231002. http://dx.doi.org/10.3788/aos201333.1231002.

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14

Zhang Jiao, Li Yi, Liu Zhi-Min, et al. "Characteristics of electrically-induced phase transition in tungsten-doped vanadium dioxide film." Acta Physica Sinica 66, no. 23 (2017): 238101. http://dx.doi.org/10.7498/aps.66.238101.

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15

Lyu, Weizhong, Dezhen Huang, Zhongkuan Luo, and Bo Liu. "Hydrothermal synthesis and characterization of tungsten and fluorine co-doped vanadium dioxide." Journal of Shenzhen University Science and Engineering 32, no. 4 (2015): 385. http://dx.doi.org/10.3724/sp.j.1249.2015.04385.

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16

Li, Jinhua, Wei Liu, Xianlong Zhang, Paul K. Chu, Kenneth M. C. Cheung, and Kelvin W. K. Yeung. "Temperature-responsive tungsten doped vanadium dioxide thin film starves bacteria to death." Materials Today 22 (January 2019): 35–49. http://dx.doi.org/10.1016/j.mattod.2018.04.005.

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17

Peng, Zifei, Wei Jiang, and Heng Liu. "Structural Phase Transition of Tungsten-Doped Vanadium Dioxide Nanopowders Prepared by Thermolysis." Journal of Nanoscience and Nanotechnology 8, no. 3 (2008): 1417–21. http://dx.doi.org/10.1166/jnn.2008.355.

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18

Peng, Zifei, Wei Jiang, and Heng Liu. "Synthesis and Electrical Properties of Tungsten-Doped Vanadium Dioxide Nanopowders by Thermolysis." Journal of Physical Chemistry C 111, no. 3 (2006): 1119–22. http://dx.doi.org/10.1021/jp066342u.

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19

Ye, Zhi Guo, Xian Liang Zhou, Hui Min Meng, Xiao Zhen Hua, Ying Hu Dong, and Ai Hua Zou. "The Electrochemical Characterization of Electrochemically Synthesized MnO2-Based Mixed Oxides for Supercapacitor Applications." Advanced Materials Research 287-290 (July 2011): 1290–98. http://dx.doi.org/10.4028/www.scientific.net/amr.287-290.1290.

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Nanostructured elements, including: manganese-molybdenum (Mn-Mo) oxide, manganese-molybdenum-tungsten (Mn-Mo-W) oxide, manganese-molybdenum-iron (Mn-Mo-Fe) oxide, manganese-molybdenum-cobalt (Mn-Mo-Co) oxide, manganese-vanadium-tungsten (Mn-V-W) oxide, manganese-vanadium-iron (Mn-V-Fe) oxide and manganese-iron (Mn-Fe) oxide, have been anodically deposited onto titanium substrates by employing an iridium dioxide interlayer (Ti/IrO2anode). The electrochemical characteristics of the resultant oxide deposits have been investigated by cyclic voltammetry (CV) in an aqueous 0.1 M Na2SO4solution. The
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20

Song, Qiang, Hongchang Pang, Weitao Gong, et al. "Enhancing phase-transition sensitivity of tungsten-doped vanadium dioxide by high-temperature annealing." Materials Letters 161 (December 2015): 244–47. http://dx.doi.org/10.1016/j.matlet.2015.08.070.

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21

Manning, Troy D., Ivan P. Parkin, Martyn E. Pemble, David Sheel, and Dimitra Vernardou. "Intelligent Window Coatings: Atmospheric Pressure Chemical Vapor Deposition of Tungsten-Doped Vanadium Dioxide." Chemistry of Materials 16, no. 4 (2004): 744–49. http://dx.doi.org/10.1021/cm034905y.

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22

Pergament, A., G. Stefanovich, O. Berezina, and D. Kirienko. "Electrical conductivity of tungsten doped vanadium dioxide obtained by the sol–gel technique." Thin Solid Films 531 (March 2013): 572–76. http://dx.doi.org/10.1016/j.tsf.2013.01.011.

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23

Huang, Zhangli, Changhong Chen, Chaohong Lv, and Sihai Chen. "Tungsten-doped vanadium dioxide thin films on borosilicate glass for smart window application." Journal of Alloys and Compounds 564 (July 2013): 158–61. http://dx.doi.org/10.1016/j.jallcom.2013.02.108.

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24

Kim, Hee Jung, Dong Kyu Roh, Jung Whan Yoo, and Dae-Sung Kim. "Designable Phase Transition Temperature of VO2 Co-Doped with Nb and W Elements for Smart Window Application." Journal of Nanoscience and Nanotechnology 19, no. 11 (2019): 7185–91. http://dx.doi.org/10.1166/jnn.2019.16618.

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Monoclinic vanadium dioxide (VO2 (M)) particles co-doped with niobium and tungsten, with potential application in smart windows, were synthesized by hydrolysis and subsequent thermal decomposition of vanadyl sulfate. All the doped VO2 particles exhibited a monoclinic crystalline phase and the critical phase transition temperature (Tc) of VO2 (M) was adjusted by Nb and W co-doping. The Tc of Nb-doped VO2 (M) decreased at a rate of approximately 10 °C/at% Nb dopant, and the transition temperature could also be accurately controlled to room temperature (about 27 °C) by co-doping with Nb and W. A
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25

Chae, Ji-Yeon, Donguk Lee, Da Won Lee, Ho-Young Woo, Jong Bae Kim, and Taejong Paik. "Direct transfer of thermochromic tungsten-doped vanadium dioxide thin-films onto flexible polymeric substrates." Applied Surface Science 545 (April 2021): 148937. http://dx.doi.org/10.1016/j.apsusc.2021.148937.

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26

Binions, Russell, Clara Piccirillo, and Ivan P. Parkin. "Tungsten doped vanadium dioxide thin films prepared by atmospheric pressure chemical vapour deposition from vanadyl acetylacetonate and tungsten hexachloride." Surface and Coatings Technology 201, no. 22-23 (2007): 9369–72. http://dx.doi.org/10.1016/j.surfcoat.2007.03.026.

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27

Louloudakis, Dimitrios. "Atmospheric Pressure Chemical Vapor Deposition Of Amorphous Tungsten Doped Vanadium Dioxide For Smart Window Applications." Advanced Materials Letters 7, no. 3 (2016): 192–96. http://dx.doi.org/10.5185/amlett.2016.6024.

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28

MAO, Mao, Wan-Xia HUANG, Ya-Xin ZHANG, et al. "Study on Phase Transition Property of Tungsten-doped Vanadium Dioxide Thin Film at Terahertz Range." Journal of Inorganic Materials 27, no. 8 (2012): 891–96. http://dx.doi.org/10.3724/sp.j.1077.2012.12131.

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29

Lu, Yinfeng, Shuxue Zhou, Guangxin Gu, and Limin Wu. "Preparation of transparent, hard thermochromic polysiloxane/tungsten-doped vanadium dioxide nanocomposite coatings at ambient temperature." Thin Solid Films 534 (May 2013): 231–37. http://dx.doi.org/10.1016/j.tsf.2013.02.130.

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30

Dou, Shuliang, Weiyan Zhang, Yuemin Wang, et al. "The influence of temperature on preparing tungsten doped vanadium dioxide films by sol-gel method." Materials Research Express 6, no. 1 (2018): 016408. http://dx.doi.org/10.1088/2053-1591/aae3c9.

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31

Ye, Junwei, Li Zhou, Fengjuan Liu, et al. "Preparation, characterization and properties of thermochromic tungsten-doped vanadium dioxide by thermal reduction and annealing." Journal of Alloys and Compounds 504, no. 2 (2010): 503–7. http://dx.doi.org/10.1016/j.jallcom.2010.05.152.

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32

Liang, Zihui, Li Zhao, Wanfan Meng, et al. "Tungsten-doped vanadium dioxide thin films as smart windows with self-cleaning and energy-saving functions." Journal of Alloys and Compounds 694 (February 2017): 124–31. http://dx.doi.org/10.1016/j.jallcom.2016.09.315.

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33

Zhang, Yue Fei, Chun Yao Hsu, and Chih Chung Hu. "Deposition of Tungsten-Doped V2O5 Thin Films on Non-Alkali Glass Substrate by RF Magnetron Sputtering for Thermal Insulation." Key Engineering Materials 732 (March 2017): 16–23. http://dx.doi.org/10.4028/www.scientific.net/kem.732.16.

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The thermal insulation function of tungsten-doped vanadium dioxide (V2O5) thin films deposited on non-alkali glass substrate using RF magnetron sputtering was analyzed in this study. Grinded hot-dry V2O5 and tungsten powders, mixed in weight ratio of 98.1:1.9 or 97:3, were pressed at 800 psi for 10 min. These compounds were sintered at 550 or 600 °C for 8 hours, in oxygen gas environments (10 sccm and 0 sccm), to several W-doped V2O5 targets. The surface morphologies of these targets were analyzed by a SEM, and the crystal structure was characterized by a XRD. The experimental studies with ref
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34

Yang, Haneul, Seoyun Lee, and Changhyun Ko. "Tungsten-doped vanadium dioxide thin film synthesis by alternate layer-by-layer growth and post-deposition annealing." Materials Letters 262 (March 2020): 127081. http://dx.doi.org/10.1016/j.matlet.2019.127081.

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35

Xiao, Yang, Zhao-Hui Zhai, Qi-Wu Shi, et al. "Ultrafast terahertz modulation characteristic of tungsten doped vanadium dioxide nanogranular film revealed by time-resolved terahertz spectroscopy." Applied Physics Letters 107, no. 3 (2015): 031906. http://dx.doi.org/10.1063/1.4927383.

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36

Kong, Mengqin, Kingsley Egbo, Chao Ping Liu, et al. "Rapid thermal annealing assisted facile solution method for tungsten-doped vanadium dioxide thin films on glass substrate." Journal of Alloys and Compounds 833 (August 2020): 155053. http://dx.doi.org/10.1016/j.jallcom.2020.155053.

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37

Jung, Sang Won, Sang Hwi Park, Jung Whan Yoo, and Juhyun Park. "Thermochromic Hybrid Nanoparticles Comprising a Tungsten-Doped Vanadium Dioxide Core and a Poly(N-isopropylacrylamide) Shell Structure." Polymer Korea 45, no. 2 (2021): 286–93. http://dx.doi.org/10.7317/pk.2021.45.2.286.

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38

Barra, Hamdi Muhyuddin, Soo Kien Chen, Nizam Tamchek, Zainal Abidin Talib, Oon Jew Lee, and Kar Ban Tan. "Phase, Microstructure, Thermochromic, and Thermophysical Analyses of Hydrothermally Synthesized W-Doped VO2 Nanopowder." Advances in Materials Science and Engineering 2021 (September 11, 2021): 1–8. http://dx.doi.org/10.1155/2021/8582274.

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Vanadium dioxide (VO2) has great potential as an intelligent architectural glazing system as it can control the amount of light, heat, and solar energy relative to the temperature in the environment. However, the applicability of VO2 for commercial use is yet to be realized because its phase transition temperature (τc) of ∼68°C is too high for use in buildings. A proven strategy to lower its τc is by elemental doping. Hence, in this study, hydrothermal synthesis of nanostructured VO2 was carried out with the introduction of tungsten (W) as a dopant. Furthermore, the effects of W doping on the
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39

Blackman, Christopher S., C. Piccirillo, R. Binions, and Ivan P. Parkin. "Atmospheric pressure chemical vapour deposition of thermochromic tungsten doped vanadium dioxide thin films for use in architectural glazing." Thin Solid Films 517, no. 16 (2009): 4565–70. http://dx.doi.org/10.1016/j.tsf.2008.12.050.

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40

Zhang, Yifu, and Yuting Huang. "A facile hydrothermal synthesis of tungsten doped monoclinic vanadium dioxide with B phase for supercapacitor electrode with pseudocapacitance." Materials Letters 182 (November 2016): 285–88. http://dx.doi.org/10.1016/j.matlet.2016.07.007.

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41

Binions, Russell, Geoffrey Hyett, Clara Piccirillo, and Ivan Paul Parkin. "Doped and un-doped vanadium dioxide thin films prepared by atmospheric pressure chemical vapour deposition from vanadyl acetylacetonate and tungsten hexachloride: the effects of thickness and crystallographic orientation on thermochromic properties." Journal of Materials Chemistry 17, no. 44 (2007): 4652. http://dx.doi.org/10.1039/b708856f.

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42

Han, Yong Hee, Seung Hoon Lee, Kun Tae Kim, In Hoon Choi, and Sung Moon. "Properties of Electrical Conductivity of Amorphous Tungsten-Doped Vanadium Oxide for Uncooled Microbolometers." Solid State Phenomena 124-126 (June 2007): 343–46. http://dx.doi.org/10.4028/www.scientific.net/ssp.124-126.343.

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In recent years, we have reported uncooled microbolometer with amorphous vanadium-tungsten oxide as a thermometric material. The reported tungsten-doped vanadium oxide showed very high TCR over -3.0%/K compared with common vanadium oxide, which generally has the TCR values near -2.0%/K. In this work, we characterized properties of electrical conductivity of amorphous tungsten-doped vanadium oxide by investigating electronic structure between vanadium oxide and tungsten-doped vanadium oxide. Finally, it is concluded that tungsten addition into vanadium give rise to changes of electronic structu
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43

Berezina, O. Ya, A. A. Velichko, L. A. Lugovskaya, et al. "Properties of tungsten-doped vanadium oxide films." Technical Physics Letters 33, no. 7 (2007): 552–55. http://dx.doi.org/10.1134/s1063785007070048.

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44

DeLima, J. J., A. J. Snell, K. V. Krishna, A. E. Owen, A. Hawryliw, and R. Thompson. "Device applications of vanadium‐doped silicon‐dioxide." Journal of Applied Physics 65, no. 10 (1989): 4082–84. http://dx.doi.org/10.1063/1.343340.

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45

Das, S., S. Chakraborty, O. Parkash, et al. "Vanadium doped tin dioxide as a novel sulfur dioxide sensor." Talanta 75, no. 2 (2008): 385–89. http://dx.doi.org/10.1016/j.talanta.2007.11.010.

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46

Zhou, Cailong, Yufeng Li, Yiwen Chen, and Jing Lin. "Hydrothermal synthesis of tungsten doped tin dioxide nanocrystals." Materials Research Express 5, no. 1 (2018): 015911. http://dx.doi.org/10.1088/2053-1591/aaa7a4.

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47

Cai, W., K. Zhang, Y. Miao, et al. "Synthesis and Characterization of Nano-Structure Tungsten-Doped Vanadium Oxide." ECS Transactions 60, no. 1 (2014): 477–82. http://dx.doi.org/10.1149/06001.0477ecst.

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48

Vernardou, D., M. E. Pemble, and D. W. Sheel. "Tungsten-Doped Vanadium Oxides Prepared by Direct Liquid Injection MOCVD." Chemical Vapor Deposition 13, no. 4 (2007): 158–62. http://dx.doi.org/10.1002/cvde.200606527.

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49

Simol, Hasina Akhter, Rumana A. Jahan, Tapas Debnath, Claus H. Rüscher, and Altaf Hussain. "Synthesis and characterization of vanadium-doped alkali metal tungsten bronzoid." Acta Crystallographica Section A Foundations and Advances 73, a2 (2017): C950. http://dx.doi.org/10.1107/s2053273317086247.

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50

Semenyuk, N. A., and et al. "Analysis of vanadium dioxide doped with iron by XPS." Izvestiya vysshikh uchebnykh zavedenii. Fizika, no. 12 (December 1, 2019): 114–18. http://dx.doi.org/10.17223/00213411/62/12/114.

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