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Journal articles on the topic 'Two-dimensional titanium carbide'

Author: Grafiati

Published: 28 May 2022

Last updated: 31 July 2025

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1

Hu, Tao, Minmin Hu, Zhaojin Li, et al. "Interlayer coupling in two-dimensional titanium carbide MXenes." Physical Chemistry Chemical Physics 18, no. 30 (2016): 20256–60. http://dx.doi.org/10.1039/c6cp01699e.

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The interlayer coupling in Ti<sub>n+1</sub>C<sub>n</sub>T<sub>2</sub>(n= 1 and 2, T = OH, O and F) is significantly stronger than van der Waals bonding, as evidenced by the fact that binding energies are 2–6 times those of graphite and MoS<sub>2</sub>from first-principles calculations.

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2

Kamysbayev, Vladislav, Alexander S. Filatov, Huicheng Hu, et al. "Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes." Science 369, no. 6506 (2020): 979–83. http://dx.doi.org/10.1126/science.aba8311.

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Versatile chemical transformations of surface functional groups in two-dimensional transition-metal carbides (MXenes) open up a previously unexplored design space for this broad class of functional materials. We introduce a general strategy to install and remove surface groups by performing substitution and elimination reactions in molten inorganic salts. Successful synthesis of MXenes with oxygen, imido, sulfur, chlorine, selenium, bromine, and tellurium surface terminations, as well as bare MXenes (no surface termination), was demonstrated. These MXenes show distinctive structural and electr

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3

Lyles, Saniya L., Sadhana Vattikuti, Gabriel Kinney, Andrew Smith, Bhoj R. Gautam, and Chandra M. Adhikari. "Structural Stability and Electronic Structure of (Ti,Ta)2C MXenes." Journal of Nepal Physical Society 10, no. 1 (2024): 8–14. https://doi.org/10.3126/jnphyssoc.v10i1.72828.

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Graphene-like two-dimensional early transition metal carbides, nitrides, or carbonitrides with a metal-to-nonmetal atomic ratio of (n+1)/n called MXenes have many excellent electronic, optical, and electrochemical properties, such as metallicity, high electrical conductivity, larger charge density, high capacitance, efficient lithium, sodium, and potassium ions intercalability, etc. First-principles Density Functional Theory (DFT) calculations are performed to study the structural relationship of (Ti, Ta)2C MXenes to their electronic structure, magnetism, and optical properties. Calculations s

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4

Halim, Joseph, Maria R. Lukatskaya, Kevin M. Cook, et al. "Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films." Chemistry of Materials 26, no. 7 (2014): 2374–81. http://dx.doi.org/10.1021/cm500641a.

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5

Wozniak, Jaroslaw, Mateusz Petrus, Tomasz Cygan, et al. "Silicon carbide matrix composites reinforced with two-dimensional titanium carbide – Manufacturing and properties." Ceramics International 45, no. 6 (2019): 6624–31. http://dx.doi.org/10.1016/j.ceramint.2018.12.149.

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6

Collini, Pieralberto, Sankalp Kota, Andrew D. Dillon, Michel W. Barsoum, and Aaron T. Fafarman. "Electrophoretic Deposition of Two-Dimensional Titanium Carbide (MXene) Thick Films." Journal of The Electrochemical Society 164, no. 9 (2017): D573—D580. http://dx.doi.org/10.1149/2.0211709jes.

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7

Ghidiu, Michael, Maria R. Lukatskaya, Meng-Qiang Zhao, Yury Gogotsi, and Michel W. Barsoum. "Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance." Nature 516, no. 7529 (2014): 78–81. http://dx.doi.org/10.1038/nature13970.

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8

Zhao, Chongjun, Qian Wang, Huang Zhang, Stefano Passerini, and Xiuzhen Qian. "Two-Dimensional Titanium Carbide/RGO Composite for High-Performance Supercapacitors." ACS Applied Materials & Interfaces 8, no. 24 (2016): 15661–67. http://dx.doi.org/10.1021/acsami.6b04767.

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9

Maleski, Kathleen, Vadym N. Mochalin, and Yury Gogotsi. "Dispersions of Two-Dimensional Titanium Carbide MXene in Organic Solvents." Chemistry of Materials 29, no. 4 (2017): 1632–40. http://dx.doi.org/10.1021/acs.chemmater.6b04830.

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10

Lee, Eunji, Armin VahidMohammadi, Barton C. Prorok, Young Soo Yoon, Majid Beidaghi, and Dong-Joo Kim. "Room Temperature Gas Sensing of Two-Dimensional Titanium Carbide (MXene)." ACS Applied Materials & Interfaces 9, no. 42 (2017): 37184–90. http://dx.doi.org/10.1021/acsami.7b11055.

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11

Rasid, Z. A. M., M. F. Omar, M. F. M. Nazeri, M. A. A. A’ziz, and M. Szota. "Low Cost Synthesis Method of Two-Dimensional Titanium Carbide MXene." IOP Conference Series: Materials Science and Engineering 209 (June 2017): 012001. http://dx.doi.org/10.1088/1757-899x/209/1/012001.

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12

Yoon, Yeoheung, Anand P. Tiwari, Minhe Lee, et al. "Enhanced electrocatalytic activity by chemical nitridation of two-dimensional titanium carbide MXene for hydrogen evolution." Journal of Materials Chemistry A 6, no. 42 (2018): 20869–77. http://dx.doi.org/10.1039/c8ta08197b.

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13

Michael, Johnson, Zhang Qifeng, and Wang Danling. "Titanium carbide MXene: Synthesis, electrical and optical properties and their applications in sensors and energy storage devices." Nanomaterials and Nanotechnology 9 (January 1, 2019): 184798041882447. http://dx.doi.org/10.1177/1847980418824470.

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MXenes have been under a lot of scientific investigation due to the novel characteristics that are inherent to two-dimensional nanostructures. There are a multitude of MXenes being studied and one of the most popular among these would be the titanium carbides. The general formula for titanium carbide is Ti n+ 1C n for the nanosheets produced that have undergone much study in the past few years. These studies include how the etching process affects the final MXene sheet and how the post-processing via heat or combining with polymers and/or inorganic compounds influences the mechanical and elect

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14

Shi, Huanhuan, Panpan Zhang, Zaichun Liu, et al. "Ambient‐Stable Two‐Dimensional Titanium Carbide (MXene) Enabled by Iodine Etching." Angewandte Chemie International Edition 60, no. 16 (2021): 8689–93. http://dx.doi.org/10.1002/anie.202015627.

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15

Shi, Huanhuan, Panpan Zhang, Zaichun Liu, et al. "Ambient‐Stable Two‐Dimensional Titanium Carbide (MXene) Enabled by Iodine Etching." Angewandte Chemie 133, no. 16 (2021): 8771–75. http://dx.doi.org/10.1002/ange.202015627.

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16

Wang, Fen, Minjuan Cao, Yi Qin, Jianfeng Zhu, Lei Wang, and Yi Tang. "ZnO nanoparticle-decorated two-dimensional titanium carbide with enhanced supercapacitive performance." RSC Advances 6, no. 92 (2016): 88934–42. http://dx.doi.org/10.1039/c6ra15384d.

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17

Lukatskaya, M. R., O. Mashtalir, C. E. Ren, et al. "Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide." Science 341, no. 6153 (2013): 1502–5. http://dx.doi.org/10.1126/science.1241488.

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18

Lin, Shuang-Yan, and Xitian Zhang. "Two-dimensional titanium carbide electrode with large mass loading for supercapacitor." Journal of Power Sources 294 (October 2015): 354–59. http://dx.doi.org/10.1016/j.jpowsour.2015.06.082.

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19

Sarycheva, Asia, Taron Makaryan, Kathleen Maleski, et al. "Two-Dimensional Titanium Carbide (MXene) as Surface-Enhanced Raman Scattering Substrate." Journal of Physical Chemistry C 121, no. 36 (2017): 19983–88. http://dx.doi.org/10.1021/acs.jpcc.7b08180.

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20

Rajavel, Krishnamoorthy, Tao Ke, Kun Yang, and Daohui Lin. "Condition optimization for exfoliation of two dimensional titanium carbide (Ti3C2T x )." Nanotechnology 29, no. 9 (2018): 095605. http://dx.doi.org/10.1088/1361-6528/aaa687.

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21

Shen, Bao-Shou, Hao Wang, Li-Jun Wu, Rui-Sheng Guo, Qing Huang, and Xing-Bin Yan. "All-solid-state flexible microsupercapacitor based on two-dimensional titanium carbide." Chinese Chemical Letters 27, no. 10 (2016): 1586–91. http://dx.doi.org/10.1016/j.cclet.2016.04.012.

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22

Li Jianlin, 李健淋, 闫理贺 Yan Lihe, 司金海 Si Jinhai, and 侯. 洵. Hou Xun. "Study on optical limiting properties of new two-dimensional titanium carbide nanosheets." Infrared and Laser Engineering 48, no. 11 (2019): 1103002. http://dx.doi.org/10.3788/irla201948.1103002.

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23

Omar, Mohd Firdaus, Zarrul Azwan Mohd Rasid, M. A. Abdul A’ziz, Muhammad Firdaus Mohd Nazeri, and S. A. Saidi. "Study of Mxene: Characterization and Radiation Properties of Two-Dimensional Titanium Carbide." Solid State Phenomena 280 (August 2018): 31–35. http://dx.doi.org/10.4028/www.scientific.net/ssp.280.31.

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In this study, radon concentration of 2D Titanium Carbide MXene Ti3C2 was studied by using an established radon monitor. A layered MAX phase of Ti3AlC2 was synthesized through pressureless sintering (PLS) the initial powder of TiH2/Al/C without preliminary dehydrogenation under argon atmosphere at 1350 °C. An elegant exfoliation approach was used to eliminates Al from its precursor to form a layered-structure of Ti3C2. Morphological and structural properties of this 2D material also studied. SEM images shows two types of morphology which is a layer of Ti3C2 and the agglomerates Al2O3 with grap

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24

Mu, Wanjun, Shenzhen Du, Qianhong Yu, Xingliang Li, Hongyuan Wei, and Yuchuan Yang. "Improving barium ion adsorption on two-dimensional titanium carbide by surface modification." Dalton Transactions 47, no. 25 (2018): 8375–81. http://dx.doi.org/10.1039/c8dt00917a.

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To capture radioactive barium from wastewater, the Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> material was modified by activation treatment and it exhibited high adsorption ability for removal of Ba<sup>2+</sup> from aqueous solution.

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25

Alhabeb, Mohamed, Kathleen Maleski, Babak Anasori, et al. "Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti3C2Tx MXene)." Chemistry of Materials 29, no. 18 (2017): 7633–44. http://dx.doi.org/10.1021/acs.chemmater.7b02847.

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26

Handoko, Albertus D., Hetian Chen, Yanwei Lum, Qianfan Zhang, Babak Anasori, and Zhi Wei Seh. "Two-Dimensional Titanium and Molybdenum Carbide MXenes as Electrocatalysts for CO2 Reduction." iScience 23, no. 6 (2020): 101181. http://dx.doi.org/10.1016/j.isci.2020.101181.

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27

Mashtalir, O., K. M. Cook, V. N. Mochalin, M. Crowe, M. W. Barsoum, and Y. Gogotsi. "Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media." J. Mater. Chem. A 2, no. 35 (2014): 14334–38. http://dx.doi.org/10.1039/c4ta02638a.

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Herein we report on the adsorption and photocatalytic decomposition of organic molecules in aqueous environments containing two-dimensional Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>, a representative of the MXene family.

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28

Chen, Xiaoyue, Yichen Guo, Ruiming Bian, et al. "Titanium carbide MXenes coupled with cadmium sulfide nanosheets as two-dimensional/two-dimensional heterostructures for photocatalytic hydrogen production." Journal of Colloid and Interface Science 613 (May 2022): 644–51. http://dx.doi.org/10.1016/j.jcis.2022.01.079.

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29

Yu, Tian, and Carmel B. Breslin. "Review—Two-Dimensional Titanium Carbide MXenes and Their Emerging Applications as Electrochemical Sensors." Journal of The Electrochemical Society 167, no. 3 (2020): 037514. http://dx.doi.org/10.1149/2.0142003jes.

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30

Peng, Qiuming, Jianxin Guo, Qingrui Zhang, et al. "Unique Lead Adsorption Behavior of Activated Hydroxyl Group in Two-Dimensional Titanium Carbide." Journal of the American Chemical Society 136, no. 11 (2014): 4113–16. http://dx.doi.org/10.1021/ja500506k.

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31

Overbury, Steven H., Alexander I. Kolesnikov, Gilbert M. Brown, et al. "Complexity of Intercalation in MXenes: Destabilization of Urea by Two-Dimensional Titanium Carbide." Journal of the American Chemical Society 140, no. 32 (2018): 10305–14. http://dx.doi.org/10.1021/jacs.8b05913.

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32

Fan, Dong, Shaohua Lu, Yundong Guo, and Xiaojun Hu. "Two-Dimensional Tetragonal Titanium Carbide: a High-Capacity and High-Rate Battery Material." Journal of Physical Chemistry C 122, no. 27 (2018): 15118–24. http://dx.doi.org/10.1021/acs.jpcc.8b03425.

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33

Liu, Xiaoxu, Ting Nie, Yanpeng Li, et al. "Nanocomposites induced by two-dimensional titanium carbide nanosheets for highly efficient energy storage." Polymer Testing 89 (September 2020): 106712. http://dx.doi.org/10.1016/j.polymertesting.2020.106712.

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34

Xin, ZHANG, ZHANG Jian-Feng, YANG Shui-Xian, CAO Hui-Yang, HUANG Hua-Jie, and JIANG Wan. "Electrocatalytic Performance of Palladium Nanoparticle Supported by Two-dimensional Titanium Carbide-CNT Composites." Journal of Inorganic Materials 33, no. 2 (2018): 206. http://dx.doi.org/10.15541/jim20170365.

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35

RASID, Zarrul Azwan MOHD, Mohammad Arshad ABDUL A’ZIZ, Mohd Firdaus OMAR, Muhammad Firdaus MOHD NAZERI, and Syahrul Affandi SAIDI. "Morphological, Structural and Radon Concentration Properties of Two-Dimensional Titanium Carbide MXene, Ti3C2." International Journal of Current Research in Science, Engineering & Technology 1, Spl-1 (2018): 535. http://dx.doi.org/10.30967/ijcrset.1.s1.2018.535-539.

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36

Zong, Luyan, Huixia Wu, Han Lin, and Yu Chen. "A polyoxometalate-functionalized two-dimensional titanium carbide composite MXene for effective cancer theranostics." Nano Research 11, no. 8 (2018): 4149–68. http://dx.doi.org/10.1007/s12274-018-2002-3.

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37

Borysiuk, Vadym N., Vadym N. Mochalin, and Yury Gogotsi. "Bending rigidity of two-dimensional titanium carbide (MXene) nanoribbons: A molecular dynamics study." Computational Materials Science 143 (February 2018): 418–24. http://dx.doi.org/10.1016/j.commatsci.2017.11.028.

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38

Zhu, Xiaohua, Xiao Pang, Youyu Zhang, and Shouzhuo Yao. "Titanium carbide MXenes combined with red-emitting carbon dots as a unique turn-on fluorescent nanosensor for label-free determination of glucose." Journal of Materials Chemistry B 7, no. 48 (2019): 7729–35. http://dx.doi.org/10.1039/c9tb02060h.

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Titanium carbides (Ti<sub>3</sub>C<sub>2</sub>), a new family of two-dimensional (2D) nanomaterials, have attracted extensive attention due to their unique structure and desirable physiochemical properties.

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39

Sarycheva, Asia, Alessia Polemi, Yuqiao Liu, Kapil Dandekar, Babak Anasori, and Yury Gogotsi. "2D titanium carbide (MXene) for wireless communication." Science Advances 4, no. 9 (2018): eaau0920. http://dx.doi.org/10.1126/sciadv.aau0920.

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With the development of the Internet of Things (IoT), the demand for thin and wearable electronic devices is growing quickly. The essential part of the IoT is communication between devices, which requires radio-frequency (RF) antennas. Metals are widely used for antennas; however, their bulkiness limits the fabrication of thin, lightweight, and flexible antennas. Recently, nanomaterials such as graphene, carbon nanotubes, and conductive polymers came into play. However, poor conductivity limits their use. We show RF devices for wireless communication based on metallic two-dimensional (2D) tita

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40

Meichandiran, Balasubramaniam, and Tadhg Kennedy. "Fluoride-Free Sonochemical Exfoliation of Titanium Aluminium Carbide to Few-Layered Titanium Carbide Nanosheets." ECS Meeting Abstracts MA2024-02, no. 9 (2024): 1375. https://doi.org/10.1149/ma2024-0291375mtgabs.

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Two-dimensional (2D) transition metal carbides and carbonitrides, also known as MXenes, possess a unique blend of hydrophilic surfaces and excellent electrical conductivity,[1] characteristics seldom found in other 2D nanostructures like graphene and transition metal dichalcogenides. Particularly, titanium carbide (Ti3C2Tx) and its composites have garnered increasing attention across diversified fields such as catalysis,[2] energy conversion and storage,[3] membrane separation,[4] photothermal conversion,[5] and field-effect transistors.[6] Thus far, chemical etching of aluminium (Al) layers f

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41

Ren, Yingying, Jianfeng Zhu, Lei Wang, et al. "Synthesis of polyaniline nanoparticles deposited on two-dimensional titanium carbide for high-performance supercapacitors." Materials Letters 214 (March 2018): 84–87. http://dx.doi.org/10.1016/j.matlet.2017.11.060.

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42

Chang, Ting-Hsiang, Tianran Zhang, Haitao Yang, et al. "Controlled Crumpling of Two-Dimensional Titanium Carbide (MXene) for Highly Stretchable, Bendable, Efficient Supercapacitors." ACS Nano 12, no. 8 (2018): 8048–59. http://dx.doi.org/10.1021/acsnano.8b02908.

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43

Deng, Junjie, Zong Lu, Li Ding, et al. "Fast electrophoretic preparation of large-area two-dimensional titanium carbide membranes for ion sieving." Chemical Engineering Journal 408 (March 2021): 127806. http://dx.doi.org/10.1016/j.cej.2020.127806.

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44

Yang, Chenhui, Wenxiu Que, Xingtian Yin, Yapeng Tian, Yawei Yang, and Meidan Que. "Improved capacitance of nitrogen-doped delaminated two-dimensional titanium carbide by urea-assisted synthesis." Electrochimica Acta 225 (January 2017): 416–24. http://dx.doi.org/10.1016/j.electacta.2016.12.173.

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45

Yang, Sheng, Panpan Zhang, Faxing Wang, et al. "Fluoride‐Free Synthesis of Two‐Dimensional Titanium Carbide (MXene) Using A Binary Aqueous System." Angewandte Chemie 130, no. 47 (2018): 15717–21. http://dx.doi.org/10.1002/ange.201809662.

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46

Yang, Sheng, Panpan Zhang, Faxing Wang, et al. "Fluoride‐Free Synthesis of Two‐Dimensional Titanium Carbide (MXene) Using A Binary Aqueous System." Angewandte Chemie International Edition 57, no. 47 (2018): 15491–95. http://dx.doi.org/10.1002/anie.201809662.

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47

Yan, Bingdong, Zike Cheng, Caiyan Lai, et al. "Boosting the Photocatalytic Ability of TiO2 Nanosheet Arrays for MicroRNA-155 Photoelectrochemical Biosensing by Titanium Carbide MXene Quantum Dots." Nanomaterials 12, no. 20 (2022): 3557. http://dx.doi.org/10.3390/nano12203557.

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The electrodes of two-dimensional (2D) titanium dioxide (TiO2) nanosheet arrays were successfully fabricated for microRNA-155 detection. The (001) highly active crystal face was exposed to catalyze signaling molecules ascorbic acid (AA). Zero-dimensional (0D) titanium carbide quantum dots (Ti3C2Tx QDs) were modified to the electrode as co-catalysts and reduced the recombination rate of the charge carriers. Spectroscopic methods were used to determine the band structure of TiO2 and Ti3C2Tx QDs, showing that a type Ⅱ heterojunction was built between TiO2 and Ti3C2Tx QDs. Benefiting the advantage

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48

Kaipoldayev, Olzhas, Ye Mukhametkarimov, Renata Nemkaeva, et al. "Studying of 2D Titanium Carbide Structure by Raman Spectroscopy after Heat Treatment in Argon and Hydrogen Atmospheres." Eurasian Chemico-Technological Journal 19, no. 2 (2017): 181. http://dx.doi.org/10.18321/ectj194.

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Herein we show the effect of heat treatment of two dimensional layered titanium carbide structure (Ti3C2Tx), so called MXene. As prepared MXene has functional groups -OH, -F, -Cl. In order to remove the functional groups we heat treated the MXene in Ar (with 0.01% O2) and H2 (with 0.01% H2O) atmospheres. We discovered the significant decrease in the amount of functional groups (-F and -Cl) and increase in the -O content, which refers to the oxidation of the material. Also we determined the optimal regime for Raman spectroscopy in order to avoid any changes in the structure of the material. We

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49

Bai, Lei, Wenhui Yi, Taiyang Sun, et al. "Surface modification engineering of two-dimensional titanium carbide for efficient synergistic multitherapy of breast cancer." Journal of Materials Chemistry B 8, no. 30 (2020): 6402–17. http://dx.doi.org/10.1039/d0tb01084g.

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A nanocomposite drug delivery system (Ti<sub>3</sub>C<sub>2</sub>@Met@CP) can be used for the synergistic treatment of tumors through photothermal/photodynamic/chemotherapy and can also inhibit tumor recurrence and metastasis by activating the immune system.

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50

Byeon, Ayeong, Meng-Qiang Zhao, Chang E. Ren, et al. "Two-Dimensional Titanium Carbide MXene As a Cathode Material for Hybrid Magnesium/Lithium-Ion Batteries." ACS Applied Materials & Interfaces 9, no. 5 (2016): 4296–300. http://dx.doi.org/10.1021/acsami.6b04198.

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