Academic literature on the topic 'Ullman coupling reaction'

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Journal articles on the topic "Ullman coupling reaction"

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Baqi, Younis. "Recent Advances in Microwave-Assisted Copper-Catalyzed Cross-Coupling Reactions." Catalysts 11, no. 1 (2020): 46. http://dx.doi.org/10.3390/catal11010046.

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Cross-coupling reactions furnishing carbon–carbon (C–C) and carbon–heteroatom (C–X) bond is one of the most challenging tasks in organic syntheses. The early developed reaction protocols by Ullmann, Ullman–Goldberg, Cadiot–Chodkiewicz, Castro–Stephens, and Corey–House, utilizing elemental copper or its salts as catalyst have, for decades, attracted and inspired scientists. However, these reactions were suffering from the range of functional groups tolerated as well as severely restricted by the harsh reaction conditions often required high temperatures (150–200 °C) for extended reaction time.
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Mohammad, Mehdi Khodaei, Alizadeh Abdolhamid, and Haghipour Maryam. "Preparation and characterization of isatin complexed with Cu supported on 4-(aminomethyl) benzoic acid-functionalized Fe 3 O 4 nanoparticles as a novel magnetic catalyst for the Ullmann coupling reaction." Research on Chemical Intermediates 45 (February 6, 2019): 2727–47. https://doi.org/10.1007/s11164-019-03760-0.

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Isatin complexed with Cu supported on 4-(aminomethyl) benzoic acid-functionalized Fe3O4 nanoparticles (Cu-IS-AMBA-MNPs) as a new catalyst was designed, prepared and characterized by appropriate analyses. The heterogeneous reusable catalyst was successfully used for the efficient and widespread syntheses of diarylethers and diarylamines via the Ullmann coupling reaction. This green catalyst was easily removed, reused several times with no significant loss of its activity, and provided a clean synthesis with excellent yield and reduced time.
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Waters, Gabrielle D., and Jesse D. Carrick. "Convergent access to bis-1,2,4-triazinyl-2,2′-bipyridines (BTBPs) and 2,2′-bipyridines via a Pd-catalyzed Ullman-type reaction." RSC Advances 10, no. 18 (2020): 10807–15. http://dx.doi.org/10.1039/d0ra00673d.

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Chang, En-Chiuan, Chun-Yen Chen, Li-Ya Wang, Yu-Ying Huang, Mou-Yung Yeh, and Fung Fuh Wong. "Synthesis of 5-arylamino-1-arylpyrazoles from 5-aminopyrazoles with arylhalides via CuI catalyzed Ullman coupling reaction." Tetrahedron 69, no. 2 (2013): 570–76. http://dx.doi.org/10.1016/j.tet.2012.11.022.

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Chang, En-Chiuan, Chun-Yen Chen, Li-Ya Wang, Yu-Ying Huang, Mou-Yung Yeh, and Fung Fuh Wong. "ChemInform Abstract: Synthesis of 5-Arylamino-1-arylpyrazoles from 5-Aminopyrazoles with Arylhalides via CuI Catalyzed Ullman Coupling Reaction." ChemInform 44, no. 23 (2013): no. http://dx.doi.org/10.1002/chin.201323116.

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Shaabani, Ahmad, and Ronak Afshari. "Magnetic Ugi-functionalized graphene oxide complexed with copper nanoparticles: Efficient catalyst toward Ullman coupling reaction in deep eutectic solvents." Journal of Colloid and Interface Science 510 (January 2018): 384–94. http://dx.doi.org/10.1016/j.jcis.2017.09.089.

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Al-Shboul, Tareq M. A., Suha S. Al-Tarawneh, Taher S. Ababneh, and Taghreed M. A. Jazzazi. "Post-Functionalization of Bromo-Substituted Ether-Linked Polymers via Ullman Coupling Reaction: Synthesis, Characterization and Their Role toward Carbon Dioxide Capture." Separations 9, no. 3 (2022): 55. http://dx.doi.org/10.3390/separations9030055.

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A new open-chain ether-linked polymer has been prepared via nucleophilic aromatic substitution reaction on a C-F bond of 1,4-dibromo-2,5-difluorobenzene by using 2,2-bis(4-hydroxyphenyl) hexafluoropropane (bisphenol AF or BAF). The new polymer (PE-AF) has shown a good solubility in non-polar solvents, good thermal stability (up to 300 °C) and random surface morphology. Tailoring these properties has been achieved by utilizing the post-modification synthetic methodology on the bromo-sites of the polymer backbone via the application of an Ullmann coupling reaction with aniline to form the polyme
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O’Driscoll, Luke J., Sissel S. Andersen, Marta V. Solano, et al. "Advances in the synthesis of functionalised pyrrolotetrathiafulvalenes." Beilstein Journal of Organic Chemistry 11 (July 3, 2015): 1112–22. http://dx.doi.org/10.3762/bjoc.11.125.

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The electron-donor and unique redox properties of the tetrathiafulvalene (TTF, 1) moiety have led to diverse applications in many areas of chemistry. Monopyrrolotetrathiafulvalenes (MPTTFs, 4) and bispyrrolotetrathiafulvalenes (BPTTFs, 5) are useful structural motifs and have found widespread use in fields such as supramolecular chemistry and molecular electronics. Protocols enabling the synthesis of functionalised MPTTFs and BPTTFs are therefore of broad interest. Herein, we present the synthesis of a range of functionalised MPTTF and BPTTF species. Firstly, the large-scale preparation of the
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Fui, Choong Jian, Mohd Sani Sarjadi, Shaheen M. Sarkar, and Md Lutfor Rahman. "Recent Advancement of Ullmann Condensation Coupling Reaction in the Formation of Aryl-Oxygen (C-O) Bonding by Copper-Mediated Catalyst." Catalysts 10, no. 10 (2020): 1103. http://dx.doi.org/10.3390/catal10101103.

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Transition metal-catalyzed chemical transformation of organic electrophiles and organometallic reagents belong to the most important cross coupling reaction in organic synthesis. The biaryl ether division is not only popular in natural products and synthetic pharmaceuticals but also widely found in many pesticides, polymers, and ligands. Copper catalyst has received great attention owing to the low toxicity and low cost. However, traditional Ullmann-type couplings suffer from limited substrate scopes and harsh reaction conditions. The introduction of homogeneous copper catalyst with presence o
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Li, Yuqiang, and Guoyin Yin. "Bathocuproine-Enabled Nickel-Catalyzed Selective Ullmann Cross-Coupling of Two sp2-Hybridized Organohalides." Synlett 32, no. 16 (2021): 1657–61. http://dx.doi.org/10.1055/a-1608-5693.

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AbstractCross-coupling reactions are essential for the synthesis of complex organic molecules. Here, we report a nickel-catalyzed Ullmann cross-coupling of two sp2-hybridized organohalides, featuring high cross-selectivity when the two coupling partners are used in a 1:1 ratio. The high chemoselectivity is governed by the bathocuproine ligand. Moreover, the mild reductive reaction conditions allow that a wide range of functional groups are compatible in this Ullmann cross-coupling.
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Dissertations / Theses on the topic "Ullman coupling reaction"

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Rovira, Coll Mireia. "Reaction mechanisms involved in cross coupling processes catalysed by copper and nickel." Doctoral thesis, Universitat de Girona, 2017. http://hdl.handle.net/10803/403434.

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Organometallic aryl-CuIII species have been proposed as key intermediates in Ullmann-type reactions. However, such species have long remained elusive and mechanistic investigations of a plausible catalytic cycle remained ambiguous and speculative. The first part of this thesis deals with the reactivity of well-defined aryl-CuIII macrocyclic complex in presence of activated methylenes (Hurtley-type coupling) and terminal acetylenes (Stephens-Castro-type coupling). The subsequent part deals with the synthesis and fully characterization of well-defined aryl-NiII complex, which is analogous to ary
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Khan, Faiyaz. "Palladium-Catalyzed Ullmann Cross-Coupling Reactions for the Synthesis of Heterocyclic Compounds." Phd thesis, 2019. http://hdl.handle.net/1885/187201.

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Publication 1 is an invited review article that details the development of the palladium-catalyzed Ullmann cross-coupling reaction within the Banwell Group. Specifically, it describes the extensive effort directed towards modernizing the Ullmann reaction so as to circumvent the harsh conditions associated with the classic protocol. The reductive cyclisation of ensuing cross-coupling products is also Publication 2 describes work directed towards engaging beta-iodinated alpha,beta- unsaturated carbonyl compounds in the palladium-catalyzed Ullmann cross-coupling with o-halonitroarenes as well
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Lin, Zhe-Yi, and 林哲毅. "The study in cascade reactions of Csp2-Csp cross-coupling(Sonogashira-type reaction)、cyclization and Csp2-S cross-coupling(Ullmann-type reaction) for one-pot three-step synthesis of benzo[b]thiophene derivatives using a simple copper-chloride system." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/31214405631202089597.

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碩士<br>國立中興大學<br>化學系所<br>98<br>It has been known that 2,3-disubstituted benzo[b]thiophenes have been prepared in excellent yields via coupling of terminal alkynes with commercially available o-iodothioanisole in the presence of a palladium catalyst and subsequent electrophilic cyclization of the resulting o-(1-alkynyl)thioanisole derivatives. We have developed a new synthetic method that by using copper choride-mediated cascade reactions of Csp2-Csp coupling, intramolecular cyclization, and Csp2-S coupling without using palladium catalyst and any ligand for one-pot three-step syntheses of 2,3
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Jones, Matthew Thomas. "The chemoenzymatic synthesis of the lycorine framework and the synthesis of C-3-mono-alkylated oxindoles via the palladium-catalysed Ullmann cross-coupling reaction." Phd thesis, 2013. http://hdl.handle.net/1885/150048.

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Chapter One of this Thesis briefly describes the history and production of cis-1,2-dihydrocatechol chiral starting materials and summarises their synthetic attributes as well as providing several examples of their use in natural product synthesis. Chapter Two begins with a succinct review of the structural characteristics and biological properties of the Amaryllidaceae alkaloid ({uF02D})-lycorine and describes several established synthetic approaches to compounds of this type. Thereafter, experimentally-based research leading to the development of a rapid and enantioselective synthesis of the
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Grudzień, Krzysztof. "Nowe kompleksy rutenu, palladu, miedzi i niklu z N-heterocyklicznymi karbenami. Synteza, struktura, reaktywność i zastosowania." Doctoral thesis, 2018. https://depotuw.ceon.pl/handle/item/2875.

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Celem działań podjętych w ramach realizacji pracy doktorskiej jest zbadanie chemii kompleksów N-heterocyklicznych karbenów (NHC) z metalami przejściowymi, z naciskiem na ich zastosowanie w katalizie. Specjalna uwaga poświęcona jest na wyjaśnienie obserwowanych ostrych różnic w reaktywności pomiędzy klasycznymi, symetrycznie podstawionymi NHC i nowo zaprojektowanymi i zsyntetyzowanymi niesymetrycznymi. 4 części prezentowanej pracy doktorskiej dotyczą studiów literaturowych i oryginalnych wyników badań w różnych obszarach chemii organicznej i metaloorganicznej. 1) Kompleksy NHC rutenu(II) jako
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Book chapters on the topic "Ullman coupling reaction"

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Li, Jie Jack. "Ullmann coupling." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_277.

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Li, Jie Jack. "Ullmann coupling." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_258.

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Li, Jie Jack. "Ullmann Coupling." In Name Reactions. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-50865-4_153.

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Jouvin, Kévin, and Gwilherm Evano. "Beyond Ullmann-Goldberg Chemistry: Vinylation, Alkynylation, and Allenylation of Heteronucleophiles." In Copper-Mediated Cross-Coupling Reactions. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118690659.ch5.

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Casitas, Alicia, and Xavi Ribas. "Insights into the Mechanism of Modern Ullmann-Goldberg Coupling Reactions." In Copper-Mediated Cross-Coupling Reactions. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118690659.ch7.

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Jiang, Yongwen, and Dawei Ma. "Modern Ullmann-Goldberg Chemistry: Arylation of N-Nucleophiles with Aryl Halides." In Copper-Mediated Cross-Coupling Reactions. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118690659.ch1.

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Tlili, Anis, and Marc Taillefer. "Ullmann Condensation Today: Arylation of Alcohols and Thiols with Aryl Halides." In Copper-Mediated Cross-Coupling Reactions. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118690659.ch2.

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Jiang, Yongwen, and Dawei Ma. "Copper-Catalyzed Ligand Promoted Ullmann-Type Coupling Reactions." In Catalysis without Precious Metals. Wiley-VCH Verlag GmbH & Co. KGaA, 2010. http://dx.doi.org/10.1002/9783527631582.ch9.

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Yamamoto, Yoshihiko. "Copper-Mediated Aryl-Aryl Bond Formation Leading to Biaryls: A Century after the Ullmann Breakthrough." In Copper-Mediated Cross-Coupling Reactions. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118690659.ch10.

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Dong, L., S. Wang, W. Wang, et al. "Transition Metals Trigger On-Surface Ullmann Coupling Reaction: Intermediate, Catalyst and Template." In Advances in Atom and Single Molecule Machines. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-26600-8_2.

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