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1

Rao, P. R. H. P., A. A. Belhekar, S. G. Hegde, A. V. Ramaswamy, and P. Ratnasamy. "Studies on Crystalline Microporous Vanadium Silicates." Journal of Catalysis 141, no. 2 (1993): 595–603. http://dx.doi.org/10.1006/jcat.1993.1166.

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2

Reddy, K. R., A. V. Ramaswamy, and P. Ratnasamy. "Studies on Crystalline Microporous Vanadium Silicates." Journal of Catalysis 143, no. 1 (1993): 275–85. http://dx.doi.org/10.1006/jcat.1993.1272.

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3

Wang, Xiqu, Lumei Liu, and Allan J. Jacobson. "Open-Framework and Microporous Vanadium Silicates." Journal of the American Chemical Society 124, no. 26 (2002): 7812–20. http://dx.doi.org/10.1021/ja020354l.

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4

Lee, Dong-Jin, Sung-Gap Lee, Min-Ho Kim, and Kyeong-Min Kim. "Electrical Properties of Vanadium-doped Lanthanium Silicates for SOFCs." Journal of the Korean Institute of Electrical and Electronic Material Engineers 28, no. 5 (2015): 295–99. http://dx.doi.org/10.4313/jkem.2015.28.5.295.

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5

Kouznetsova, T. F., A. I. Ivanets, and V. S. Komarov. "Low-temperature synthesis of mesoporous M41S metal-silicates and their adsorption and capillary-condensation properties." Proceedings of the National Academy of Sciences of Belarus, Chemical Series 55, no. 3 (2019): 338–44. http://dx.doi.org/10.29235/1561-8331-2019-55-3-338-344.

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Low-temperature synthesis of the mesoporous silicates containing d-metals is carried out. The measured isotherms of low-temperature nitrogen adsorption-desorption by chrome, vanadium and zirconium silicate adsorbents belong to Type IV (b) of sorption isotherms on IUPAC classification. Such isothermal curves are inherent in mesoporous systems with the M41S type of ordering of the making elements. Increasing рН of sedimentation and metal content lead to amorphization of samples and distortion of a supramolecular lattice with uniform regular geometry and a long-range ordering.
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6

Li, Xing Bin, Chang Wei, Zhi Gan Deng, Min Ting Li, Cun Xiong Li, and Hong Sheng Xu. "Acid Leaching of Vanadium from a Vanadium Residue." Advanced Materials Research 402 (November 2011): 243–48. http://dx.doi.org/10.4028/www.scientific.net/amr.402.243.

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A process has been developed at the laboratory scale for leaching of vanadium from a vanadium residue using mixed hydrofluoric and sulfuric acid solutions, and NaClO as an oxidant. The extraction studies were carried out using various acid concentrations, liquid/solid ratios, addition of oxidant, reaction temperatures and leaching times. The optimum leaching conditions were then determined. Characterization of the leach residues was carried out by SEM and EDS analysis. Results indicate that the silicates can be effectively destroyed by HF, and the vanadium contained in the vanadium-iron spinel
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7

Wang, Xiqu, Lumei Liu, and Allan J. Jacobson. "ChemInform Abstract: Open-Framework and Microporous Vanadium Silicates." ChemInform 33, no. 38 (2010): no. http://dx.doi.org/10.1002/chin.200238020.

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8

Rao, P. R. Hari Prasad, and A. V. Ramaswamy. "Oxyfunctionalization of alkanes with H2O2 catalysed by vanadium silicates." Journal of the Chemical Society, Chemical Communications, no. 17 (1992): 1245. http://dx.doi.org/10.1039/c39920001245.

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9

Luca, Vittorio, Dugald J. MacLachlan, and Keith Morgan. "Synthesis and Characterization of Porous Vanadium Silicates in Organic Medium." Chemistry of Materials 9, no. 12 (1997): 2720–30. http://dx.doi.org/10.1021/cm960621k.

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10

Kornatowski, Jan, Blanka Wichterlová, Jaromir Jirkovský, Elke Löffler, and Walter Pilz. "Spectroscopic studies of vanadium-substituted zeolitic silicates of MFI topology." J. Chem. Soc., Faraday Trans. 92, no. 6 (1996): 1067–78. http://dx.doi.org/10.1039/ft9969201067.

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11

Corma, A., J. M. López Nieto, N. Paredes, and M. Pérez. "Oxidative dehydrogenation of propane on vanadium supported on magnesium silicates." Applied Catalysis A: General 97, no. 2 (1993): 159–75. http://dx.doi.org/10.1016/0926-860x(93)80082-2.

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12

Sen, Tapas, Maya Chatterjee, and S. Sivasanker. "Novel large-pore vanadium alumino- and boro-silicates with BEA structure." Journal of the Chemical Society, Chemical Communications, no. 2 (1995): 207. http://dx.doi.org/10.1039/c39950000207.

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13

Tuel, A., and Y. Ben Taârit. "Synthesis and characterization of vanadium silicates with the ZSM-48 structure." Zeolites 14, no. 1 (1994): 18–24. http://dx.doi.org/10.1016/0144-2449(94)90049-3.

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14

RAO, P. R. H. P., and A. V. RAMASWAMY. "ChemInform Abstract: Oxyfunctionalization of Alkanes with H2O2 Catalyzed by Vanadium Silicates." ChemInform 23, no. 49 (2010): no. http://dx.doi.org/10.1002/chin.199249098.

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15

Pârvulescu, V., C. Anastasescu, and B. L. Su. "Vanadium incorporated mesoporous silicates as catalysts for oxidation of alcohols and aromatics." Journal of Molecular Catalysis A: Chemical 198, no. 1-2 (2003): 249–61. http://dx.doi.org/10.1016/s1381-1169(02)00694-5.

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16

Brandão, Paula, Anabela Valente, Andreas Philippou, Artur Ferreira, Michael W. Anderson, and João Rocha. "Hydrothermal Synthesis and Characterisation of Two Novel Large-Pore Framework Vanadium Silicates." European Journal of Inorganic Chemistry 2003, no. 6 (2003): 1175–80. http://dx.doi.org/10.1002/ejic.200390151.

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17

CORMA, A., J. M. L. NIETO, N. PAREDES, and M. PEREZ. "ChemInform Abstract: Oxidative Dehydrogenation of Propane on Vanadium Supported on Magnesium Silicates." ChemInform 24, no. 31 (2010): no. http://dx.doi.org/10.1002/chin.199331098.

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18

Chen, Chih-Wei, and An-Nan Ko. "Synthesis of Aromatic Ketones from Aromatic Compounds Using Vanadium-Containing Mesoporous Silicates." Journal of the Chinese Chemical Society 59, no. 9 (2012): 1104–10. http://dx.doi.org/10.1002/jccs.201100684.

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19

HARIPRASADRAO, P. "Synthesis and catalytic properties of crystalline, microporous vanadium silicates with MEL structure." Journal of Catalysis 137, no. 1 (1992): 225–31. http://dx.doi.org/10.1016/0021-9517(92)90151-7.

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20

SEN, T., M. CHATTERJEE, and S. SIVASANKER. "ChemInform Abstract: Novel Large-Pore Vanadium Alumino- and Boro-Silicates with BEA Structure." ChemInform 26, no. 23 (2010): no. http://dx.doi.org/10.1002/chin.199523014.

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21

TUEL, A., and Y. BENTAARIT. "Synthesis, characterization and catalytic properties of vanadium silicates with a ZSM-48 structure." Applied Catalysis A: General 102, no. 2 (1993): 201–14. http://dx.doi.org/10.1016/0926-860x(93)80229-j.

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22

TUEL, A., and Y. B. TAARIT. "ChemInform Abstract: Synthesis, Characterization and Catalytic Properties of Vanadium Silicates with a ZSM-48 Structure." ChemInform 24, no. 48 (2010): no. http://dx.doi.org/10.1002/chin.199348028.

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23

Neuhold, Simone, André van Zomeren, Joris J. Dijkstra, et al. "Investigation of Possible Leaching Control Mechanisms for Chromium and Vanadium in Electric Arc Furnace (EAF) Slags Using Combined Experimental and Modeling Approaches." Minerals 9, no. 9 (2019): 525. http://dx.doi.org/10.3390/min9090525.

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In this study, possible leaching control mechanisms for Cr and V in electric arc furnace slags were investigated by using a multi-methodological approach. Aside from chemical and mineralogical bulk analyses, special emphasis was given to surface investigations of the slags prior to and after leaching. In addition, pH dependence leaching tests were performed and the obtained data were evaluated with hydrogeochemical models. Investigations revealed that Cr and V are mainly bound in spinel and wuestite as well as minor amounts of olivine. Spinel and wuestite do not dissolve during water leaching
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24

Chanquía, Corina M., Analía L. Cánepa, Karim Sapag, et al. "Mesoporous Silicates with Spherical Morphology Modified with Vanadium Highly Active in Oxidation of Cyclohexene with H2O2." Topics in Catalysis 54, no. 1-4 (2011): 160–69. http://dx.doi.org/10.1007/s11244-011-9635-8.

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25

SHYLESH, S., and A. SINGH. "Vanadium-containing ordered mesoporous silicates: Does the silica source really affect the catalytic activity, structural stability, and nature of vanadium sites in V-MCM-41?" Journal of Catalysis 233, no. 2 (2005): 359–71. http://dx.doi.org/10.1016/j.jcat.2005.05.001.

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26

Ramaswamy, A. V., S. Sivasanker, and P. Ratnasamy. "Selective oxidation reactions over metallosilicate molecular sieves: A comparison of titanium and vanadium silicates with MEL structure." Microporous Materials 2, no. 5 (1994): 451–58. http://dx.doi.org/10.1016/0927-6513(94)00018-2.

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27

Rao, P. R. H. P., A. V. Ramaswamy, and P. Ratnasamy. "Studies on Crystalline Microporous Vanadium Silicates III. Selective Oxidation of n-Alkanes and Cyclohexane over VS-2." Journal of Catalysis 141, no. 2 (1993): 604–11. http://dx.doi.org/10.1006/jcat.1993.1167.

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28

WANTY, R., and M. GOLDHABER. "A method for the determination of vanadium and iron oxidation states in naturally occurring oxides and silicates." Talanta 32, no. 5 (1985): 395–98. http://dx.doi.org/10.1016/0039-9140(85)80105-3.

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29

Rassomakhin, M. A., E. V. Belogub, K. A. Novoselov, and P. V. Khvorov. "Tourmaline from Late Quartz Veins of the Murtykty Gold Deposit, Republic of Bashkortostan." МИНЕРАЛОГИЯ (MINERALOGY) 6, no. 1 (2020): 69–83. http://dx.doi.org/10.35597/2313-545x-2020-6-1-7.

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Tourmaline, an intermediate member of the oxyschorl–oxydravite–oxymagnesio-foitite-bosiite series with a predominance of the oxy-dravite-bosiite end-member, was studied from late calcite-quartz veins in the eastern zone of the Murtykty gold deposit (Republic of Bashkortostan). Sulfide mineralization in veins includes rare chalcopyrite, pyrite, sphalerite and galena. Accessory minerals are xenotime-(Y), vanadium-containing rutile and fine high-fineness gold. Supergene mineralization resulted from decomposition of carbonates, sulfides and rock-forming silicates includes kaolinite, hydroxides of
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30

Wang, Xiqu, Lumei Liu, and Allan J. Jacobson. "The Novel Open-Framework Vanadium Silicates K2(VO)(Si4O10)⋅H2O (VSH-1) and Cs2(VO)(Si6O14)⋅3 H2O (VSH-2)." Angewandte Chemie International Edition 40, no. 11 (2001): 2174–76. http://dx.doi.org/10.1002/1521-3773(20010601)40:11<2174::aid-anie2174>3.0.co;2-m.

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31

Wang, Xiqu, Lumei Liu, and Allan J. Jacobson. "The Novel Open-Framework Vanadium Silicates K2(VO)(Si4O10)⋅H2O (VSH-1) and Cs2(VO)(Si6O14)⋅3 H2O (VSH-2)." Angewandte Chemie 113, no. 11 (2001): 2232–34. http://dx.doi.org/10.1002/1521-3757(20010601)113:11<2232::aid-ange2232>3.0.co;2-b.

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32

Sutton, S. R., C. A. Goodrich, and S. Wirick. "Titanium, vanadium and chromium valences in silicates of ungrouped achondrite NWA 7325 and ureilite Y-791538 record highly-reduced origins." Geochimica et Cosmochimica Acta 204 (May 2017): 313–30. http://dx.doi.org/10.1016/j.gca.2017.01.036.

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33

Wang, Xiqu, Lumei Liu, and Allan J. Jacobson. "ChemInform Abstract: The Novel Open-Framework Vanadium Silicates K2(VO)(Si4O10)×H2O (VSH-1) and Cs2(VO)(Si6O14)×3H2O (VSH-2)." ChemInform 32, no. 36 (2010): no. http://dx.doi.org/10.1002/chin.200136025.

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34

ÅSTRÖM, M., and K. RÖNNBACK. "Concentration levels and spatial distribution of sulphur and metals in fine-grained sediments in western Finland." Agricultural and Food Science 14, no. 1 (2008): 14. http://dx.doi.org/10.2137/1459606054224093.

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On the coastal plains of Finland, widespread Holocene marine and lacustrine sediments have developed into acid sulphate soil as a result of extensive artificial drainage for agricultural purposes. This has caused a variety of environmental problems. The aim of this study was to determine the concentration levels and spatial distribution of sulphur, carbon and metals [titanium, vanadium, chromium, manganese (Mn), iron, cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn)] in these sediments, in order to increase the geochemical understanding of the parent materials from which acid sulphate soil dev
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35

Abeysinghe, Dileka, Mark D. Smith, Gregory Morrison, Jeongho Yeon, and Hans-Conrad zur Loye. "Facile in-situ reduction: Crystal growth and magnetic studies of reduced vanadium (III/IV) silicates CaxLn1−xVSiO5 (Ln = Ce–Nd, Sm–Lu, Y)." Journal of Solid State Chemistry 260 (April 2018): 80–86. http://dx.doi.org/10.1016/j.jssc.2018.01.004.

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36

REDDY, K. R., A. V. RAMASWAMY, and P. RATNASAMY. "ChemInform Abstract: Studies on Crystalline Microporous Vanadium Silicates. Part 4. Synthesis, Characterization, and Catalytic Properties of V-NCL-1, a Large-Pore Molecular Sieve." ChemInform 24, no. 51 (2010): no. http://dx.doi.org/10.1002/chin.199351018.

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37

Wu, Liu Shun, Yun Zhou, and Yuan Chi Dong. "Precipitation Behavior of V-Enrichment Mineral in Steelmaking Slag Bearing Vanadium Modified by SiO2." Applied Mechanics and Materials 295-298 (February 2013): 1729–34. http://dx.doi.org/10.4028/www.scientific.net/amm.295-298.1729.

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In order to concentrate vanadium in converter slag bearing vanadium, the effect of SiO2 on behavior of vanadium in the process of enriching was studied. Experimental results show that, during cooling, dicalcium silicate containing vanadium and phosphorus precipitate first from original slag. For original with 7% SiO2, most of vanadium dissolves in calcium silicate phase. However, the proportion of dicalcium silicate is big. For slag modified by 12% SiO2, during cooling, two vanadium-rich minerals precipitate firstly, i.e. Ca3(V,P)2O8(30-33%V2O5) and Ca3(V,P)2O8•nCa2SiO4 (14-31%V2O5), then 3CaO
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38

Xu, Runsheng, Wei Wang, Weilin Chen, Bin Jia, and Zhihui Xu. "3D Microstructure and Micromechanical Properties of Minerals in Vanadium-Titanium Sinter." High Temperature Materials and Processes 38, no. 2019 (2019): 101–12. http://dx.doi.org/10.1515/htmp-2017-0181.

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AbstractTo investigate the structural characteristics and mechanical properties of minerals in vanadium-titanium sinter, the 3D microstructures of the sinter were reconstructed by serial sectioning in conjunction with computer-aided 3D reconstruction techniques The results show that hematite and magnetite in vanadium-titanium sinter will grow along the longitudinal axis direction and act as a scaffold. The size of magnetite crystals in vanadium-titanium sinter is much smaller than that in traditional sinter. The calcium ferrite in vanadium-titanium sinter is columnar-like, while that in tradit
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39

Gao, Minglei, Xiangxin Xue, Lanjie Li, He Yang, and Donghui Chen. "Leaching behavior and kinetics of vanadium extraction from vanadium-bearing steel slag." Metallurgical Research & Technology 116, no. 4 (2019): 407. http://dx.doi.org/10.1051/metal/2018129.

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The vanadium-bearing steel slag as solid waste is also one of valuable vanadium-containing resource. Recovering vanadium from the refractory steel slag is a great challenge in the world. A leaching process study using high concentration sodium hydroxide solution was proposed in this laboratory work. The effects of sodium hydroxide concentration, particle size, leaching temperature and the ratio of alkali to slag on the rate of vanadium leaching were determined and the leaching kinetics was presented. It indicates that the leaching rate is highly sensitive to the sodium hydroxide concentration
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40

Kornatowski, Jan, Mikhail Sychev, Werner H. Baur, and Gerd Finger. "Studies of the Synthesis of Large VAPO-5 Crystals and Incorporation of Vanadium Ions." Collection of Czechoslovak Chemical Communications 57, no. 4 (1992): 767–73. http://dx.doi.org/10.1135/cccc19920767.

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The molecular sieve VAPO-5 has been synthesized hydrothermally in form of large crystals up to 660 μm in length. They have been used as a model substance for the study of vanadium incorporation into the framework. Our results show that vanadium was incorporated into the framework though in relatively small amounts. The results are in agreement with earlier findings for powder preparations of VAPO-5, except for the oxidation state of the vanadium ions and its stability. These conclusions agree with those arrived at previously for vanadium silicate KVS-5.
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41

Jian, Xingwen, Jing Huang, Zhenlei Cai, Yimin Zhang, Tao Liu, and Hong Liu. "Effect of alkaline fusion on muscovite decomposition and the vanadium release mechanism from vanadium shale." Royal Society Open Science 5, no. 10 (2018): 180700. http://dx.doi.org/10.1098/rsos.180700.

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In order to figure out the decomposition of muscovite and the release mechanism of vanadium from vanadium shale in the alkaline fusion process, the process of vanadium release and roasting kinetics by alkaline fusion was studied. It was found that the addition of sodium hydroxide made the muscovite convert into the sodium silicate and gehlenite. This process promoted the dissolution of silicon and the destruction of muscovite, which could facilitate the release of vanadium. The kinetic analysis indicated that the controlling step of vanadium transformation reaction is changed from chemical rea
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42

Desautels, Ryan D., Michael P. Rowe, John W. Freeland, Michael Jones, and Johan van Lierop. "Influence of vanadium-doping on the magnetism of FeCo/SiO2 nanoparticle." Dalton Transactions 45, no. 25 (2016): 10127–30. http://dx.doi.org/10.1039/c6dt00991c.

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43

Reddy, Kondam Madhusudan, Igor Moudrakovski, and Abdelhamid Sayari. "Synthesis of mesoporous vanadium silicate molecular sieves." Journal of the Chemical Society, Chemical Communications, no. 9 (1994): 1059. http://dx.doi.org/10.1039/c39940001059.

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44

Wu, Hao, Yali Feng, Heng Zhang, and Haoran Li. "The process of vanadium migration and silicon extraction by alkaline leaching from high silicon stone coal under reduction conditions." Metallurgical Research & Technology 116, no. 3 (2019): 313. http://dx.doi.org/10.1051/metal/2018101.

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It is difficult to utilize stone coal with a vanadium grade of below 0.7%. With the aim of effectively utilizing the silicon and vanadium in stone coal, the vanadium concentration and silicon extraction processes by alkaline leaching under reducing conditions were investigated. The effect of NaOH mass fraction, temperature and the amount of hydrazine hydrate on the leaching process was researched. Moreover, the laws of phase transformation and the migration process of vanadium were revealed. The results show that the dissolution of quartz resulted in the exposure of muscovite and goldmanite, b
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45

Zheng, Haiyan, Weiling Zhang, Yongchun Guo, Qiangjian Gao, and Fengman Shen. "Transformation of Vanadium-Bearing Titanomagnetite Concentrate in Additive-Free Roasting and Alkaline-Pressure Leaching for Extracting Vanadium (V)." Minerals 9, no. 3 (2019): 197. http://dx.doi.org/10.3390/min9030197.

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With a view to satisfying the requirements of environmental protest and efficient usage of resources, a novel process for efficiently extracting vanadium (V), titanium (Ti), and iron (Fe) from vanadium-bearing titanomagnetite concentrate was developed. In the new process, vanadium is pre-extracted by additive-free roasting under the air atmosphere and alkaline leaching technologies. In this paper, transformation of vanadium-bearing titanomagnetite concentrate in the roasting is investigated based on thermodynamic analyses and experimental discussion. Thermodynamic analyses show that oxidation
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46

Shiller, Alan M., and Lunjin Mao. "Dissolved vanadium in rivers: effects of silicate weathering." Chemical Geology 165, no. 1-2 (2000): 13–22. http://dx.doi.org/10.1016/s0009-2541(99)00160-6.

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47

NEUMANN, R., and M. LEVINELAD. "Vanadium silicate xerogels in hydrogen peroxide catalyzed oxidations." Applied Catalysis A: General 122, no. 2 (1995): 85–97. http://dx.doi.org/10.1016/0926-860x(94)00206-1.

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48

Gontier, S., and A. Tuel. "Characterization of vanadium-containing mesoporous silicas." Microporous Materials 5, no. 3 (1995): 161–71. http://dx.doi.org/10.1016/0927-6513(95)00057-g.

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49

Prakash, A. M., and Larry Kevan. "Structure and Adsorbate Interactions of Vanadium in a Vanadium Silicate (VS-1) Molecular Sieve." Journal of Physical Chemistry B 104, no. 29 (2000): 6860–68. http://dx.doi.org/10.1021/jp000987r.

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50

Mekki, A., G. D. Khattak, D. Holland, M. Chinkhota, and L. E. Wenger. "Structure and magnetic properties of vanadium–sodium silicate glasses." Journal of Non-Crystalline Solids 318, no. 1-2 (2003): 193–201. http://dx.doi.org/10.1016/s0022-3093(02)01883-5.

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