Academic literature on the topic 'Victorian Brown Coals (VBC)'

Horizontal bores are essential infrastructures for maintaining the stability of open-pit mine batters. The infiltration of water from large surface catchments during rain events and induced deformation caused by mining activities can cause the build-up of pore water pressures in mine batters, potentially leading to catastrophic slope failures. A field investigation unit containing a camera has been developed to survey long (>300m) horizontal bores. Features observed using the camera along the profile of horizontal bores are discussed. Water flow was quantified by flow meters. X-Ray Diffraction (XRD) was undertaken to investigate the water precipitates within the selected bores. Water flow temperature was recorded to test the hypothesis of a possibility to indicate whether a borehole was draining from the saturated zone or from the surface water through its temperature. The investigations have been conducted to determine the cause of change in the efficiency of horizontal boreholes and find a reliable measure to assess longevity and performance of horizontal drains. Bore efficiency has been defined as the bore functioning as a preferential path for water within the batter to be drained out to reduce the saturated zone and associated pore water pressures within the batter. The results suggest blockages and fractures inside the bores can be considered the leading cause of the change in the efficiency of a bore. Blockages occur because of sediment accumulation and because of coal chunks from internal wall collapses. Internal fractures affect efficiency when they become the water preferred path; thus, retaining water flowing within the batter. The bore’s longevity is considered the period of the bore is considered effective. Water flow measurement is suggested as a reliable measure to assess bores’ longevity.
Masters by Research

The solvent-induced swelling behaviour of Victorian brown coals was examined in detail to probe the bonding mechanisms in very low rank coals (in this case Victorian brown coal). Correlation of solvent properties with differences in observed swelling behaviour were interpreted in terms of the coal structure, and means of predicting the observed behaviour were considered. Modification of the coal structure via physical compression (briquetting), chemical digestion, thermal modification, and functional group alkylation was used to further elucidate those structural features which govern the swelling behaviour of Victorian brown coals. Briquette weathering (i.e. swelling and disintegration of briquettes when exposed to variations in humidity and temperature) was examined by making alterations to briquette feed material and observing the effects on swelling in water. The application of solubility parameter alone to prediction of coal swelling was rejected due to the many exceptions to any proposed trend. Brown coal swelling showed a minimum when the solvent electron-donor number (DN) minus its electron-acceptor number (AN) was closest to zero, i.e. when DN and AN were of similar magnitude. The degree of swelling increased either side of this point, as predicted by theory. In contrast to the solubility parameter approach (which suffers from the uncertainty caused by specific interaction between coal and solvent), the electron donor/acceptor approach is about specific interactions. It was concluded that a combination of total and three-dimensional solubility parameters and solvent electron donor/acceptor numbers may be used to predict solvent swelling of unextracted brown coals with some success. Solvent access to chemically densified coal was found to be insensitive to a reduction in pore volume, and chemical effects were dominant. Thermal modification of the digested coal resulted in reduced swelling for all solvents, indicating that the structure had adopted a minimum energy configuration due to decarboxylation and replacement of hydrogen bonds with additional covalent bonds. Swelling of oxygen-alkylated coals demonstrated that the more polar solvents are able to break relatively weak hydrogen bonded crosslinks. The large difference between the rate and extent of swelling in water (and hence weathering) of Yallourn and Morwell briquettes was shown to be almost entirely attributable to exchanged magnesium. Magnesium exchange significantly increases the rate and extent of swelling of Yallourn coal. It was also shown that the swelling of briquettes due to uptake of water by magnesium-exchanged coals is reduced significantly with controlled ageing of the briquettes. The solvent swelling behaviour of Victorian brown coals is consistent with the notion that coal is a both covalently and non-covalently crosslinked and entangled macromolecular network comprising extractable species, which are held within the network by a wide range of non-covalent, polar, electron donor/acceptor interactions. Solvents capable of significant extraction of whole brown coals are also capable of significant swelling, but not dissolution, of the macromolecular coal network, which supports the view that the network is comprised of both covalent and ionic bonding. Victorian brown coals have also been shown to exhibit polyelectrolytic behaviour due to a high concentration of ionisable surface functionalities.