Academic literature on the topic 'Vilsmeier Reagenz'

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Journal articles on the topic "Vilsmeier Reagenz"

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Brehme, R., E. Gründemann, and M. Schneider. "Reaktion von Acetophenonmonomethyl- und -dimethylhydrazonen mit dem Vilsmeier-Reagenz; Bildung von Pyrazol-4-carbiminiumsalzen: ein Beitrag zum Mechanismus." Journal für praktische Chemie 342, no. 7 (2000): 700–706. http://dx.doi.org/10.1002/1521-3897(200009)342:7<700::aid-prac700>3.0.co;2-u.

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Awad, Ibrahim M. A., and Khairy M. Hassan. "Studies in Vilsmeier-Haack reaction: Reaction of 3-methyl-1-phenyl-4-arylidene-5-pyrazolone." Collection of Czechoslovak Chemical Communications 54, no. 3 (1989): 706–12. http://dx.doi.org/10.1135/cccc19890706.

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The 3-methyl group in Ia, b has been found to undergo diformylation by Vilsmeier reagent to give the aminoacrolein derivatives (IIa, b). Treatment of IIa, b with different reagents affords the related 1-phenyl-4-arylidene-5-pyrazolone derivatives with different heterocyclic systems in the 3-position. The Vilsmeier reaction on pyrazolopyrazole (XIII) have been utilized to prove chemically that new heterocyclic systems are formed only at the 3-position and no addition on the carbon-carbon double bond in the conjugated system O=C-C=C-(B) takes place.
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Rhee, Hakjune, Yuri Jeong, Jaeyoung Ban, and Minkyung Lim. "A Novel Synthesis of N-Sulfonylformamidines from N-Sulfonyl­sulfonamides." Synthesis 50, no. 09 (2018): 1867–74. http://dx.doi.org/10.1055/s-0036-1591936.

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N-Sulfonylformamidines were synthesized from N-sulfonylsulfonamides by reacting with p-toluenesulfonyl chloride (TsCl) and N,N -disubstituted formamides. In this reaction, it was expected that mixing TsCl with the N,N-disubstituted formamide would generate an iminium salt (Vilsmeier reagent). The reaction avoids the use of metal catalysts and hazardous reagents, and the desired N-sulfonylformamidines were obtained in 60% to quantitative yields.
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Corbett, Michael, and Seb Caille. "A Bench-Stable Vilsmeier Reagent for in situ Alcohol Activation: Synthetic Application in the Synthesis of 2-Amino-2-Thiazolines." Synlett 28, no. 20 (2017): 2845–50. http://dx.doi.org/10.1055/s-0036-1589086.

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A robust, chemoselective direct condensation/cyclization of thioureas and amino alcohols is described. Employing a bench-stable Vilsmeier reagent, methoxymethylene-N,N-dimethyliminium methyl sulfate, the selective in situ activation of alcohols is achieved with high efficiency and broad functional-group tolerance. The reversible interaction of the Vilsmeier reagent with substrate was key to the success of this activation strategy.
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Lu, Shi-Han, Po-Lin Liu, and Fung Fuh Wong. "Vilsmeier reagent-mediated synthesis of 6-[(formyloxy)methyl]-pyrazolopyrimidines via a one-pot multiple tandem reaction." RSC Advances 5, no. 58 (2015): 47098–107. http://dx.doi.org/10.1039/c5ra07707a.

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Kumar, Ajay, Om Prakash, Mayank Kinger, and Shiv P. Singh. "Synthesis of some new 1-aryl-4-formyl-3-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)pyrazoles using the Vilsmeier–Haack reaction — Isolation of the key intermediate 1-aryl-3-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)pyrazoles." Canadian Journal of Chemistry 84, no. 3 (2006): 438–42. http://dx.doi.org/10.1139/v06-015.

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Arylhydrazones of dehydroacetic acid (DHA) underwent Vilsmeier–Haack reaction to generate the corresponding 1-aryl-4-formyl-3-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)pyrazoles (1) with the pyrone moiety of the DHA remaining intact. However, when the reaction was performed using 1 equiv. of the reagent, compounds of 1-aryl-3-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)pyrazoles (2a–2f) were obtained, which underwent smooth conversion to 1-aryl-4-formyl-3-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)pyrazoles (1) on further treatment with another equivalent of the Vilsmeier–Haack reagent. This unreported
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Roopa, Redamala*. "UNDER SOLVENT-FREE CONDITIONS, ACETYLATION and VILSMEIER-HAACK FORMYLATION REACTIONS WITH ACETANILIDES and ANILINES." Journal of Pharma Research 11, no. 06 (2022): 72–84. https://doi.org/10.5281/zenodo.7813300.

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Abstract:&nbsp; <strong>The Vilsmeier-Haack reaction with anilines and acetanilides was carried out without the use of a solvent. At room temperature, the reactants are put in a mortar and ground with a pestle for 20 to 30 minutes. Formyl derivatives were generated in surprisingly good yields when dimethyl formamide (DMF) and POCl3 were used as the VH reagent. Nevertheless, acetyl derivatives were generated when DMF was substituted for DMA in the formulation of the VH reagent. The results of solvent free reactions are better to those of solution phase reactions, with high yields and much short
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Ruberte, Ana Carolina, Carlos Aydillo, Arun K. Sharma, Carmen Sanmartín, and Daniel Plano. "Vilsmeier reagent, NaHSe and diclofenac acid chloride: one-pot synthesis of a novel selenoindolinone with potent anticancer activity." RSC Advances 10, no. 63 (2020): 38404–8. http://dx.doi.org/10.1039/d0ra07332f.

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Nasuhipur, Forough, Zarrin Ghasemi, Morgane Poupon, and Michal Dušek. "POCl3 mediated one-pot deoxygenative aromatization and electrophilic chlorination of dihydroxy-2-methyl-4-oxo-indeno[1,2-b]pyrroles." RSC Advances 13, no. 26 (2023): 17812–16. http://dx.doi.org/10.1039/d3ra02515b.

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Guzmán, Angel, Moises Romero, and Joseph M. Muchowski. "Vilsmeier–Haack reaction with succinamidals. A convenient synthesis of 5-chloropyrrole-2-carboxaldehydes and 5-chloropyrrole-2,4-dicarboxaldehydes." Canadian Journal of Chemistry 68, no. 5 (1990): 791–94. http://dx.doi.org/10.1139/v90-125.

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It is shown that the reaction of N-alkylsuccinamidals (2) with the Vilsmeier–Haack reagent derived from DMF and phosphorus oxychloride can be controlled to preferentially produce either 5-chloropyrrole-2-carboxaldehydes (8) or 5-chloropyrrole-2,4-dicarboxaldehydes (9). The corresponding N-unsubstituted aldehydes are obtained when N-tert-butoxycarbonylsuccinamidal (11) is the substrate in the above reactions. Keywords: Vilsmeier–Haack reaction, succinamidals, 5-chloropyrrole-2-carboxaldehydes, 5-chloropyrrole-2,4-dicarboxaldehydes.
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Dissertations / Theses on the topic "Vilsmeier Reagenz"

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Goon, Simon. "Applications of the Vilsmeier reagent in synthesis." Thesis, University of Sunderland, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.245363.

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Willetts, S. E. "The reactions of modified Vilsmeier reagents." Thesis, Staffordshire University, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.370561.

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Cheng, Ying. "Part I: the 't-amino effect' in the Vilsmeier formylation of p-substituted tertiary anilines : part II: study of the chemistry of aminochlorocarbenes derived from Vilsmeier reagents by the action of bases." Thesis, University of Sunderland, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297371.

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Pester, Tom. "Synthese und Reaktionen von heteroatomgebundenen Aziden." 2021. https://monarch.qucosa.de/id/qucosa%3A75999.

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Hinweis: Zur optimalen Darstellung des Dokumentes bitte die Schriftart „ArnoPro“ installieren. Die vorliegende Arbeit beschäftigt sich mit der Synthese und den Reaktionen von heteroatomgebundenen Aziden. Im Speziellem werden vier verschiedene Gruppen untersucht, diese umfassen: Die Synthese von N-Azido-Aminen u. a. mittels nucleophiler Substitution und Diazotransfer-Reaktion, die Synthese von N-Azido-Iminen mittel
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Lu, Shih-Han, and 呂詩涵. "Vilsmeier Reagent Initialed One-pot Cascade Multiple Synthesis of N,O-Disubstituted Glycolamide Esters as Dipeptidyl peptidase 4 inhibitors." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/mx7tzm.

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Chang, Chun-Hsi, and 張濬璽. "The study of selective synthesis and biological activity of pyrazolo[3,4-d]pyrimidine, N-(1H-pyrazol-5-yl)formamide, or N-(1H-pyrazol-5-yl)formamidine derivatives from N-1-Substituted-5-aminopyrazoles with new Vilsmeier-type reagents." Thesis, 2013. http://ndltd.ncl.edu.tw/handle/95634777776867134802.

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碩士<br>中國醫藥大學<br>藥物化學研究所碩士班<br>102<br>Various halomethyleniminium salts as novel Vilsmeier reagents were synthesized from the reaction of formamide or N-methylformamide with phosphoryl chloride. Treatment of N-1-substituted-aminopyrazoles including, N-1-(2-pyridinyl)-5-aminopyrazoles and N-1-(2-quinolinyl)-5-aminopyrazoles with these Vilsmeier reagents to obtain the corresponding pyrazolo[3,4-d]pyrimidine, N-(1H-pyrazol-5-yl)formamide, or N-(1H-pyrazol-5-yl)formamidine products. The experimentant results were different with our previous data which the formylated amidylpyazole and formamidine pr
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Books on the topic "Vilsmeier Reagenz"

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R, Giles Paul, ed. Synthesis using Vilsmeier reagents. CRC Press, 1994.

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Marson, C. M. Synthesis Using Vilsmeier Reagents. Taylor & Francis Group, 2018.

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Marson, Charles M., and Paul R. Giles. Synthesis Using Vilsmeier Reagents. CRC Press, 2018. http://dx.doi.org/10.1201/9781351077071.

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Marson, C. M. Synthesis Using Vilsmeier Reagents. Taylor & Francis Group, 2018.

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Marson, C. M. Synthesis Using Vilsmeier Reagents. Taylor & Francis Group, 2018.

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Marson, C. M. Synthesis Using Vilsmeier Reagents. Taylor & Francis Group, 2018.

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Synthesis Using Vilsmeier Reagents. Taylor & Francis Group, 2017.

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Book chapters on the topic "Vilsmeier Reagenz"

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Marson, Charles M., and Paul R. Giles. "Formation, Structure, and General Reactions of Vilsmeier Reagents." In Synthesis Using Vilsmeier Reagents. CRC Press, 2018. http://dx.doi.org/10.1201/9781351077071-1.

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Marson, Charles M., and Paul R. Giles. "Synthesis of Functional Groups using Vilsmeier Reagents." In Synthesis Using Vilsmeier Reagents. CRC Press, 2018. http://dx.doi.org/10.1201/9781351077071-2.

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Marson, Charles M., and Paul R. Giles. "Ring Formation by Aromatization and Heteroaromatization." In Synthesis Using Vilsmeier Reagents. CRC Press, 2018. http://dx.doi.org/10.1201/9781351077071-3.

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Marson, Charles M., and Paul R. Giles. "Ring-forming Reactions using either Vilsmeier Reagents or β-Chlorovinylaldehydes." In Synthesis Using Vilsmeier Reagents. CRC Press, 2018. http://dx.doi.org/10.1201/9781351077071-4.

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Marson, Charles M., and Paul R. Giles. "Transformations to give New Ring Systems." In Synthesis Using Vilsmeier Reagents. CRC Press, 2018. http://dx.doi.org/10.1201/9781351077071-5.

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Ito, S., and N. Morita. "Reaction with a Vilsmeier Reagent." In Monocyclic Arenes, Quasiarenes, and Annulenes. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-045-00393.

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"Formylation and the Vilsmeier Reagent." In C-1 Building Blocks in Organic Synthesis 2, edited by van Leeuwen. Georg Thieme Verlag, 2014. http://dx.doi.org/10.1055/sos-sd-213-00191.

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Seela, F., N. Ramzaeva, and H. Rosemeyer. "Chlorination with the Vilsmeier Reagent." In Six-Membered Hetarenes with Two Identical Heteroatoms. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-016-01275.

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Keller, P. A. "The Use of Vilsmeier Reagents." In Six-Membered Hetarenes with One Nitrogen or Phosphorus Atom. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-015-00561.

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Keller, P. A. "Dual-Purpose Substrate and Vilsmeier Reagent." In Six-Membered Hetarenes with One Nitrogen or Phosphorus Atom. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-015-00562.

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Conference papers on the topic "Vilsmeier Reagenz"

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Vinogradov, Andrey, and Vyacheslav Platonov. "Reactions of polyfluoroarylzinc compounds with Vilsmeier-Haack reagent; new synthesis of polyfluorinated aromatic aldehydes and acetales." In The 15th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2011. http://dx.doi.org/10.3390/ecsoc-15-00607.

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