Academic literature on the topic 'Vinyl chlorides'

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Journal articles on the topic "Vinyl chlorides"

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Herman, Jan A., Rodica Neagu-Plesu, and Leszek Wójcik. "Réactions ion/molécule de l'ion C2H3Cl+ dans le mélange gazeux: chlorure de vinyle – chlorure d'éthyle." Canadian Journal of Chemistry 67, no. 1 (1989): 97–103. http://dx.doi.org/10.1139/v89-017.

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Ion/molecule reactions of C2H3Cl+ have been studied in a mixture of vinyl and ethyl chlorides. The ionic processes have been followed using two mass spectrometers; one is based on the ionic cyclotronic resonance (ICR) while the other is based on photo-ionization at high pressure. The results obtained on these two instruments are complementary and they indicate that the ion C2H3Cl+ does not react directly with ethyl chloride. However, the ions C4H3Cl+ and C4H6Cl+, which are formed following the decomposition of the excited ion-dimer of vinyl chloride, do react with ethyl chloride in a series of
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Davis, Stephanie C. "Vinyl chlorides and phthalates." Environmental Quality Management 12, no. 1 (2002): 91–96. http://dx.doi.org/10.1002/tqem.10056.

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Lehr, Marvin H. "Miscibility in poly(vinyl chloride)/chlorinated poly(vinyl chloride) blends, and blends of different chlorinated poly(vinyl chlorides)." Polymer Engineering and Science 25, no. 17 (1985): 1056–68. http://dx.doi.org/10.1002/pen.760251703.

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Hadi, Angham G., Sadiq J. Baqir, Dina S. Ahmed, et al. "Substituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation." Polymers 13, no. 22 (2021): 3946. http://dx.doi.org/10.3390/polym13223946.

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Poly(vinyl chloride) suffers from degradation through oxidation and decomposition when exposed to radiation and high temperatures. Stabilizers are added to polymeric materials to inhibit their degradation and enable their use for a longer duration in harsh environments. The design of new additives to stabilize poly(vinyl chloride) is therefore desirable. The current study includes the synthesis of new tin complexes of 4-methoxybenzoic acid and investigates their potential as photostabilizers for poly(vinyl chloride). The reaction of 4-methoxybenzoic acid and substituted tin chlorides gave the
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Ghani, Hassan, Emad Yousif, Dina S. Ahmed, Benson M. Kariuki, and Gamal A. El-Hiti. "Tin Complexes of 4-(Benzylideneamino)benzenesulfonamide: Synthesis, Structure Elucidation and Their Efficiency as PVC Photostabilizers." Polymers 13, no. 15 (2021): 2434. http://dx.doi.org/10.3390/polym13152434.

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Poly(vinyl chloride) (PVC) suffers from photo-oxidation and photodegradation when exposed to harsh conditions. Application of PVC thus relies on the development of ever more efficient photostabilizers. The current research reports the synthesis of new complexes of tin and their assessment as poly(vinyl chloride) photostabilizers. The three new complexes were obtained in high yields from reaction of 4-(benzylideneamino)benzenesulfonamide and tin chlorides. Their structures were elucidated using different tools. The complexes were mixed with poly(vinyl chloride) at a very low concentration and t
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Bates, Gordon S., Michael D. Fryzuk, and Charles Stone. "Convenient synthesis and cycloaddition reactions of 2-phenylseleno-1,3-butadiene and 2-trialkylstannyl-1,3-butadienes." Canadian Journal of Chemistry 65, no. 11 (1987): 2612–17. http://dx.doi.org/10.1139/v87-431.

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The facile preparation of 2-trialkylstannyl-1,3-butadienes and 2-phenylseleno-1,3-butadiene by reaction of 2-(1,3-butadienyl)magnesium chloride with trialkylstannyl chlorides and phenylselenium chloride, respectively, is reported. The Diels–Alder reactivity of these dienes with a variety of activated dienophiles is also described. Finally, a novel transmetallation of tin, in vinyl stannanes, to selenium by use of phenylselenium chloride is outlined.
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Datta, Gopal K., and Mats Larhed. "High stereoselectivity in chelation-controlled intermolecular Heck reactions with aryl chlorides, vinyl chlorides and vinyl triflates." Organic & Biomolecular Chemistry 6, no. 4 (2008): 674. http://dx.doi.org/10.1039/b719131f.

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Shpariy, M. V., P. Y. Shapoval, I. P. Poliuzhyn, S. V. Kolobych, and V. Ye Stadnik. "Composition of ash from combustion and solution of technological problems of chlororganic wastes utilization from direct ethylene chlorination to 1,2- dichlorethane." Chemistry, Technology and Application of Substances 3, no. 2 (2020): 17–22. http://dx.doi.org/10.23939/ctas2020.02.017.

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During organochlorine wastes thermal utilization formed at direct chlorination of ethylene to 1,2-dichloroethane in the production of vinyl chloride at Karpatnaftohim LLC, the ash is formed, which clogs gas pipelines and heat exchange elements of the steam generator, causes disruption of normal technological process and leads to emergency shutdowns.The composition of this ash was determined by chemical methods of quantitative analysis and flame photometry for such macrocomponents as Fe2O3 (28%) and FeCl3 (5%), as well as magnesium chlorides (30%) and sodium (4%), the rest (about 32% ) probably
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Mormann, Werner, and Thomas Wagner. "Acylation of (partially) silylated poly(vinyl alcohol)s with acyl chlorides. Vinyl chloride/vinyl ester copolymers by polymer analogous reaction." Macromolecular Chemistry and Physics 197, no. 10 (1996): 3463–71. http://dx.doi.org/10.1002/macp.1996.021971031.

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Arimitsu, Satoru, Kazuto Terukina та Tatsuro Ishikawa. "Stereoselective Synthesis of 4-Substituted 2,4-Dichloro-2-butenals by α- and γ-Regioselective Double Chlorination of Dienamine Catalysis". Synlett 29, № 14 (2018): 1887–91. http://dx.doi.org/10.1055/s-0037-1609559.

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The l-proline-catalyzed reaction of enolizable α,β-unsaturated aldehydes with N-chlorosuccinimide (NCS) gave the corresponding 4-substituted 2,4-dichloro-2-butenals with moderate yields and excellent diastereoselectivities (Z/E = >20/1) through consecutive double chlorination at the α- and γ-positions of the dienamine intermediate. The corresponding 2,4-dichloro-2-butenals contain a multireactive 1,3-dichloro allylic unit useful for the construction of Z-vinyl chlorides; the chloride on the allylic position was replaced with mild nucleophiles such as MeOH and EtOH via an SN2 substitution re
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Dissertations / Theses on the topic "Vinyl chlorides"

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Datta, Gopal K. "Heck Reactions with Aryl Chlorides : Studies of Regio- and Stereoselectivity." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-9202.

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Gaikwad, Parikshit S. "Chemically deposited optical fiber humidity sensor." Master's thesis, Mississippi State : Mississippi State University, 2003. http://library.msstate.edu/etd/show.asp?etd=etd-06092003-141607.

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Forrest, Martin J. "Characterisation of vinyl chloride oligomers." Thesis, Loughborough University, 1988. https://dspace.lboro.ac.uk/2134/27931.

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A low molecular weight fraction was obtained from a mass polymerised PVC resin by using diethyl ether Soxhlet extraction followed by either preparative gel filtration or solvent fractionation. A gas chromatography - mass spectroscopy (GC-MS) analysis of this fraction revealed that, in addition to vinyl chloride (VC) oligomers, it contained a large number of other compounds, in particular a large concentration of phthalates. By using adsorption liquid chromatography it was possible to remove the phthalates, along with other contaminants having a similar or greater polarity, from the low molecul
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Fairbrass, Sheila Ann. "Surface deterioration of poly(vinyl chloride)." Thesis, Imperial College London, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.322083.

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Ogilvy, Norman. "Vinyl chloride precipitation polymerisation : charge effects." Thesis, University of Edinburgh, 1985. http://hdl.handle.net/1842/11229.

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Dorobantu, Ioana-Miruna. "Vinyl chloride polymerization in microdroplet reactor." Thesis, Toulouse, INPT, 2012. http://www.theses.fr/2012INPT0037/document.

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La polymérisation du chlorure de vinyle est une réaction très fréquente dans l’industrie des polymères, conduisant à l’obtention d’un matériau plastique très commun, connu sous le nom de PVC (polychlorure de vinyle). Ses applications concernent principalement l’industrie des constructions néanmoins d’autres domaines sont également touchés. La complexité de ce procédé de polymérisation est due à la nature toxique du monomère, à la maitrise du transfert de chaleur ou au maintien de l’agitation. Le control de ces variables de procédé influence de manière directe les caractéristiques finales du pr
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He, Jianzhong. "Complete reductive dechlorination of chloroethenes to ethene and isolation of Dehalococcoides Sp. Strain BAV1." Diss., Available online, Georgia Institute of Technology, 2004:, 2003. http://etd.gatech.edu/theses/available/etd-04082004-180217/unrestricted/he%5Fjianzhong%5F200312%5Fphd.pdf.

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Sham, C. K. "Studies of poly (vinyl chloride)/polyacrylate blends." Thesis, Imperial College London, 1985. http://hdl.handle.net/10044/1/37850.

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Zaikov, Vadim Guennadievich. "A study of poly(vinyl chloride) microstructure." W&M ScholarWorks, 1997. https://scholarworks.wm.edu/etd/1539623916.

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High-field {dollar}\sp{lcub}13{rcub}{dollar}C and {dollar}\sp1{dollar}H NMR spectroscopies were used to investigate some unusual features of the molecular microstructure of poly(vinyl chloride) (PVC).;Several model monochloroalkenes were synthesized in order to determine {dollar}\sp{lcub}13{rcub}{dollar}C shift increments for the replacement of H by Cl at positions that are near an isolated internal double bond. These increments then were used to predict the {dollar}\sp{lcub}13{rcub}{dollar}C shifts of the internal allylic chloride structure in PVC. The predictions were not satisfactory, becau
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Chuang, Adina Shiang Mattes Timothy E. "Proteomic investigations of vinyl chloride-assimilating bacteria from pure cultures to the environment /." [Iowa City, Iowa] : University of Iowa, 2009. http://ir.uiowa.edu/etd/347.

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Books on the topic "Vinyl chlorides"

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Canada. Environmental Protection Programs Directorate. Technical Services Branch., ed. Vinyl chloride. Environmental Protection Service, 1985.

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J, Hathaway Gloria, Welch Laura S, Tamburro Carlo, United States. Agency for Toxic Substances and Disease Registry, and DeLima Associates, eds. Vinyl chloride toxicity. U.S. Dept. of Health & Human Services, Public Health Service, Agency for Toxic Substances and Disease Registry, 1990.

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United States. Agency for Toxic Substances and Disease Registry, ed. Toxicological profile for vinyl chloride. U.S. Department of Health and Human Services, Public Health Service, Agency for Toxic Substances and Disease Registry, 2006.

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Canada. Environmental Protection Directorate. Chemical Industries Division. and Canada Environment Canada, eds. Vinyl chloride industry environmental status report (1987-1990). Environment Canada, 1992.

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Canada. Environmental Protection Programs Directorate. Technical Services Branch., ed. Vinyl chloride: Environmental and technical information for problem spills. Environmental Canada, Environmental Protection Service, 1985.

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United States. Environmental Protection Agency, ed. Toxicological profile for vinyl chloride. [U.S. Department of Health & Human Services, Public Health Service, Centers for Disease Control], 1989.

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Grossman, Richard F. Handbook of vinyl formulating. 2nd ed. Wiley, 2008.

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Grossman, Richard F. Handbook of vinyl formulating. 2nd ed. Wiley, 2008.

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Morcos, Raouf. Environmental status report, 1985-1986: Vinyl chloride industry. Environment Canada, 1988.

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International Program on Chemical Safety., United Nations Environment Programme, International Labour Organisation, World Health Organization, and Inter-Organization Programme for the Sound Management of Chemicals.", eds. Vinyl chloride: Health and safety guide. World Health Organization, 1999.

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Book chapters on the topic "Vinyl chlorides"

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Gooch, Jan W. "Vinyl Chloride." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_12547.

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Ware, George W. "Vinyl Chloride." In Reviews of Environmental Contamination and Toxicology. Springer New York, 1988. http://dx.doi.org/10.1007/978-1-4684-7083-3_13.

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Patnaik, Pradyot. "Vinyl Chloride." In Handbook of Environmental Analysis. CRC Press, 2017. http://dx.doi.org/10.1201/9781315151946-138.

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Birley, A. W., R. J. Heath, and M. J. Scott. "Vinyl chloride plastics." In Plastics Materials. Springer US, 1988. http://dx.doi.org/10.1007/978-1-4615-3664-2_8.

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Birley, A. W., R. J. Heath, and M. J. Scott. "Vinyl chloride plastics." In Plastic Materials. Springer Netherlands, 1988. http://dx.doi.org/10.1007/978-94-011-7614-9_8.

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GOTTESMAN, ROY T., and DONALD GOODMAN. "Poly(vinyl chloride)." In ACS Symposium Series. American Chemical Society, 1985. http://dx.doi.org/10.1021/bk-1985-0285.ch018.

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Gooch, Jan W. "Vinyl Chloride Plastics." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_12549.

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Gooch, Jan W. "Poly(vinyl acetate co vinyl chloride)." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_9253.

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Gooch, Jan W. "Propylene-Vinyl Chloride Copolymer." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_9542.

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Takeoka, Yukikazu. "Poly(vinyl chloride) (PVC)." In Encyclopedia of Polymeric Nanomaterials. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-36199-9_247-1.

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Conference papers on the topic "Vinyl chlorides"

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Hendricks, Albert L., and Robert E. Moore. "Vinyl Ester Linings Protect FGD Systems." In CORROSION 1993. NACE International, 1993. https://doi.org/10.5006/c1993-93427.

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Abstract Liquid applied vinyl ester linings have been instrumental in providing corrosion protection to various components in flue gas desulfurization systems. These linings can be cost effectively applied with standard spray equipment. They exhibit excellent resistance to the reaction of chlorides, fluorides and sulfur under high temperature and abrasive conditions during the burning of fossil fuels. Lining systems have been successfully applied to provide protection to stack liners, ducting, scrubbers, thickener tanks and other vessels. This paper will provide a description of components req
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Hendricks, Albert L., Albert de Kreij, and Robert E. Moore. "Vinyl Ester Linings Protect FGD Systems." In CORROSION 1996. NACE International, 1996. https://doi.org/10.5006/c1996-96463.

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Abstract Liquid applied vinyl ester linings have been instrumental in providing corrosion protection to various components in flue gas desulfurization systems. These linings can be cost effectively applied with standard spray equipment. They exhibit excellent resistance to the reaction of chlorides, fluorides and sulfur under high temperature and abrasive conditions during the burning of fossil fuels. Lining systems have been successfully applied to provide protection to stack liners, ducting, scrubbers, thickener tanks and other vessels. This paper will provide a description of components req
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Caine, Marvin L. "Chlorinated Vinyl Acrylic Latices for Steel Protection." In CORROSION 1985. NACE International, 1985. https://doi.org/10.5006/c1985-85002.

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Abstract A novel emulsion polymer has been developed for use in protective coatings for steel. The latex polymer, which is described as a chlorinated vinyl acrylic, is made from the emulsion polymerization of vinylidene chloride, vinyl chloride and acrylates. The polymer film has low water vapor and oxygen permeability, is tough, flexible and nonflammable. Air-drying waterborne primers for steel have been successfully formulated with this chlorinated vinyl acrylic latex to overcome deficiencies associated with many other waterborne primers. For best results a nonionic surfactant is required in
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Manager, Jeffrey Stewart. "Vinyl Ester Linings for Flue Gas Desulfurization Systems." In Paint and Coatings Expo (PACE) 2007. SSPC, 2007. https://doi.org/10.5006/s2007-00090.

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Abstract Vinyl Esters are highly chemical resistant polymers that provide an excellent foundation for the building blocks with which to line the interior of a Flue Gas Desulfurizatoin System. Understanding that vinyl ester systems cure through polymerization in order to provide the proper environment and achieve maximum results is necessary. The general characteristics of vinyl esters: acid resistance, chloride resistance, and physical toughness provide the qualities required to withstand the internal environments found in FGD Systems. The addition of additives or fillers, make them versatile
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Lake, R. D., R. B. Henrich, W. H. Julius, and T. S. McQuarrie. "Evaluation of Corrosion Resistant Resins for Hot/Wet Chlorine Service." In CORROSION 1986. NACE International, 1986. https://doi.org/10.5006/c1986-86281.

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Abstract A study was undertaken to compare the resistance of several kinds of commercially produced polyester and vinyl ester resins to hot, wet chlorine gas. The study includes corrosion grade polyester resins of the bisphenol A type, modified-bisphenol A, brominated-bisphenol A, modified, brominated bisphenol A and chlorendic type. Vinyl esters under investigation comprise modified, brominated, and modified, brominated bisphenol A epoxy derived resins as well as an epoxy-novolac type. Final, twelve month exposure data is presented for several resins in conventional "C" glass veil/"E" glass m
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Scott, P. J. B., A. Al-Hashem, and J. Carew. "Experiments on MIC of Steel and FRP Downhole Tubulars in West Kuwait Brines." In CORROSION 2007. NACE International, 2007. https://doi.org/10.5006/c2007-07113.

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Abstract The candidate waters available for secondary recovery of oil in West Kuwait oil fields are all high in salt. Total dissolved solids (TDS) of an aquifer water is 239,000 ppm (chloride, 146,000 ppm). Effluent water varies, but TDS can reach 241,000 ppm (chloride, 151,000 ppm). Candidate materials for tubulars for secondary injection were tested for MIC attack at high salt concentrations. N-80 and L-80 steels, and three FRPs - phenolic, vinyl ester and epoxy resin were tested in the two water types. A mixed bacterial consortium (including SRB) from a natural Mediterranean marine environm
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Drake, Stephen. "Corrosion Resistant Pipe with Extremely High Impact Resistance." In CORROSION 1999. NACE International, 1999. https://doi.org/10.5006/c1999-99394.

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Abstract The next generation of fiberglass pipe, which combines outstanding corrosion resistance to an extremely wide range of industrial chemicals with impact resistance more than 100 times better than existing fiberglass pipe, is introduced. This pipe is initially rated for operating pressures of 150 psi (10 Bar) at up to 225F (107C), and has corrosion resistance that generally is as good or better than traditional vinyl ester or epoxy resins. Its resistance to halogens such as chlorine and bromine is especially outstanding. These properties are achieved with the use of a new type of DUCTILE
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Moreno, Eric I., Rómel G. Solís-Carcaño, Daniel Serrano-Ixtepan, and César A. Arias-Palma. "Performance of Concrete Coatings against Carbonation-Induced Corrosion." In CORROSION 2007. NACE International, 2007. https://doi.org/10.5006/c2007-07297.

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Abstract Concrete carbonation, as long as chloride ion, is the main cause of corrosion in reinforced concrete structures. Away from marine environments, carbonation-induced corrosion would be the corrosion mechanism in reinforced concrete. After carbonation occurred, plain reinforcing steel bars are known to corrode actively. The objective of this investigation was to study the performance of concrete coatings as an alternative to avoid carbonation of concrete elements, and therefore, corrosion of the reinforcement. Two different coatings (vynil-acrylic and acrylic) were employed in concrete s
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Kelley, Don, and Rafic Moubarac. "Fiberglass-Reinforced Plastic (FRP) Chemical Resistance in 100°C (212°F) Wet Chlorine Gas and Anolyte." In CORROSION 2003. NACE International, 2003. https://doi.org/10.5006/c2003-03615.

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Abstract As manufacturers increase the operating temperature of chlorine production to improve yields, the service life of traditional fiberglass-reinforced plastic (FRP) gas ductwork has decreased by as much as 50%. The purpose of this paper is to report the results of a pilot plant investigation of FRP laminates exposed to chlorine gas and anolyte produced by membrane cells operating at 100°C (212°F). Materials demonstrating potential for longer service life in ongoing case studies were chosen for the pilot plant study. This investigation was conducted to compare laminates made with the vari
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Marshall, Mark, Joseph Messinger, and Helen Leung. "CHLORINE NUCLEAR QUADRUPOLE HYPERFINE STRUCTURE IN THE VINYL CHLORIDE-HYDROGEN CHLORIDE COMPLEX." In 70th International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2015. http://dx.doi.org/10.15278/isms.2015.wj06.

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Reports on the topic "Vinyl chlorides"

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Huggett, Clayton, and Barbara C. Levin. Toxicity of the pyrolysis and combustion of poly(vinyl chlorides) :. National Bureau of Standards, 1986. http://dx.doi.org/10.6028/nbs.ir.85-3286.

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Chirachanchai, Suwabun. A New approach for the synthesis of advanced polymers by stereochemically controlled structure using inclusion polymerization technique. Chulalongkorn University, 1999. https://doi.org/10.58837/chula.res.1999.73.

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Inclusion compound of deoxycholic acid (DCA) host molecule and vinyl chloride monomer (VCM) guest molecule is prepared from solvent free DCA crystal via guest insertion technique. Solvent free DCA inclusion compound is achieved from a series of DCA-solvent guest, i.e., ethylacetate, dioxane, o- and p-xylene. X-ray diffraction, FT-IR and thermal analysis results indicate that vinyl chloride monomer is entrapped and stabilized in DCA crystal in solvent free DCA. Guest releasing peak of DCA-VCM is confirmed at ca. 40-60 degree Celsius. Inclusion polymerization is accomplished from the [gamma]-rad
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Spormann, Alfred M. Factors Affecting Cis-Dichloroethene and Vinyl Chloride Biological Transformation Under Anaerobic Conditions. Defense Technical Information Center, 2006. http://dx.doi.org/10.21236/ada635026.

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McCarty, P. L., and A. M. Spormann. Mechanisms, Chemistry, and Kinetics of Anaerobic Biodegradation of cis-Dichloroethene and Vinyl Chloride. Office of Scientific and Technical Information (OSTI), 2000. http://dx.doi.org/10.2172/775373.

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Cox, Evan. Elucidation of the Mechanisms and Environmental Relevance of cis-Dichloroethene and Vinyl Chloride Biodegradation. Defense Technical Information Center, 2012. http://dx.doi.org/10.21236/ada581957.

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Cox, Evan. Elucidation of the Mechanisms and Environmental Relevance of cis-Dichloroethene and Vinyl Chloride Biodegradation. Defense Technical Information Center, 2012. http://dx.doi.org/10.21236/ada582232.

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Blank, D. A., A. G. Suits, and Y. T. Lee. Photoinitiated decomposition of substituted ethylenes: The photodissociation of vinyl chloride and acrylonitrile at 193 nm. Office of Scientific and Technical Information (OSTI), 1997. http://dx.doi.org/10.2172/603616.

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Tiedje, James M., Frank E. Loeffler, Babu Z. Fathepure, and Erik A. Petrovskis. Aerobic and Anaerobic Transformation of cis-Dichloroethene (cis-DCE) and Vinyl Chloride (VC): Steps for Reliable Remediation. Defense Technical Information Center, 2003. http://dx.doi.org/10.21236/ada483508.

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McCarty, P. L., and A. M. Spormann. Mechanisms, chemistry, and kinetics of anaerobic biodegradation of cis-dichloroethylene and vinyl chloride. 1998 annual progress report. Office of Scientific and Technical Information (OSTI), 1998. http://dx.doi.org/10.2172/13692.

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Freedman, David, Jessica High, Anthony Reid, et al. Characterization of Microbes Capable of Using Vinyl Chloride and Ethene as Sole Carbon and Energy Sources by Anaerobic Oxidation. Defense Technical Information Center, 2013. http://dx.doi.org/10.21236/ada606832.

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