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Journal articles on the topic 'Vinyl ester resins – Thermomechanical properties'

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1

Karami, Z., MJ Zohuriaan-Mehr, K. Kabiri, and N. Ghasemi Rad. "Bio-based thermoset alloys from epoxy acrylate, sesame oil- and castor oil-derived resins: Renewable alternatives to vinyl ester and unsaturated polyester resins." Polymers from Renewable Resources 10, no. 1-3 (February 2019): 27–44. http://dx.doi.org/10.1177/2041247919863633.

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This study deals with the synthesis of vegetable oil (VO)-derived formulated resins with high bio-based content (30–77%) as potential renewable alternatives to conventional fossil-based vinyl ester (VE) and unsaturated polyester (UP) resins. First, epoxy acrylate was synthesized from a commercial epoxy resin via acrylation with acrylic acid. Then, acrylated epoxidized sesame oil (AESSO) and maleated castor oil (MCO) were synthesized and spectrally characterized. Afterward, networks of VE, AESSO, and MCO or their binary blends were prepared. The curing trend of the resins was investigated by differential scanning calorimetry. According to thermal and thermomechanical analysis, all of the VO-based networks possessed slightly inferior properties compared to those of VE. However, the adhesion strength of the VO-based alloying systems was higher than that of their petroleum-based counterpart based on T-peel and lap shear tests. Overall, it was concluded that the bio-resourced alloys could be considered as good alternatives to VE and UP resins, and the novel bio-resin formulations may be designed for adhesives, the polymer–matrix composites, and surface coating applications.
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2

Zhang, Xi, Vahid Bitaraf, Suying Wei, Zhanhu Guo, Xi Zhang, Suying Wei, and Henry A. Colorado. "Vinyl ester resin: Rheological behaviors, curing kinetics, thermomechanical, and tensile properties." AIChE Journal 60, no. 1 (November 18, 2013): 266–74. http://dx.doi.org/10.1002/aic.14277.

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3

Salleh, Z., M. M. Islam, J. A. Epaarachchi, and M. T. I. Khan. "Thermo-mechanical properties of fused borosilicate syntactic foams." Journal of Mechanical Engineering and Sciences 13, no. 2 (June 28, 2019): 4898–910. http://dx.doi.org/10.15282/jmes.13.2.2019.10.0407.

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The coefficient thermal expansion, a (CTE) of glass microballoon/vinyl ester syntactic foam was determined using dimensional changes of a temperature gradient plot. The CTE was measured and found to be up to 53-63 % lower than the vinyl ester resin matrix when mixing with different weight percentages of the glass microballoon ranging from 2 wt.% to 10 wt.% using a thermomechanical analyzer (TMA). The results of CTE showed that it has a strong relationship with the syntactic foam density (r), radius ration (h) ,cavity porosity (fg) and matrix porosity (fm). Experimental results showed that the CTE decreases when glass microballoons are added into the composites measured at different temperatures ranging from 30 oC to 70 °C. The CTE from the experimental results were also compared with Turner’s modification model for composites for its suitability for thermal expansion of syntactic foams. The results indicate that Turner’s modification model exhibits a close correlation with the reduction up to 80 % of CTE based on experiment.
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4

Salleh, Zulzamri, Md Mainul Islam, and Jayantha Ananda Epaarachchi. "Thermal Expansion Properties of Fused Borosilicate Syntactic Foams." Nano Hybrids and Composites 23 (December 2018): 39–45. http://dx.doi.org/10.4028/www.scientific.net/nhc.23.39.

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The thermal properties such the coefficient thermal expansion, α (CTE) of fused borosilicate syntactic foam was determined using dimensional changes of a temperature gradient plot. The CTE was measured and found to be achieved the value lower than the vinyl ester resin matrix when mixing with different weight percentages of the glass microballoon ranging from 2 wt.% to 10 wt.% using a thermomechanical analyzer (TMA). These results showed that it has a strong relationship with the syntactic foam physical properties such density, radius ration,cavity porosity and matrix porosity. Experimental results showed that the CTE decreases when glass microballoons are added into the composites measured at different temperatures ranging from 30 °C to 70 °C. The CTE from the experimental results were also analysed using Turner’s modification model for composites for its suitability for thermal expansion of syntactic foams.
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5

Ramraji, K., K. Rajkumar, and P. Sabarinathan. "Tailoring of tensile and dynamic thermomechanical properties of interleaved chemical-treated fine almond shell particulate flax fiber stacked vinyl ester polymeric composites." Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications 233, no. 11 (May 9, 2019): 2311–22. http://dx.doi.org/10.1177/1464420719849616.

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Natural fiber and particulates are being exploited to attain eco-friendly products for construction and automotive sectors. These sectors are moving towards the use of high damping characteristic natural biofibers and particulate-reinforced polymer composite as part of the structural components. In this work, woven flax fiber (0° and 90°) and almond shell particulates were used. They were subsequently treated with alkaline and acetylene chemical solution separately. Polymer composite laminates were prepared using a vinyl ester resin as matrix and by stacking flax fibers and almond particulates interleaved in an alternative sequence using the hand layup technique. This was followed by hydraulic pressing. Composite laminates were fabricated by varying the almond shell particulate weight fraction of 0%, 5%, 10%, and 15%. Mechanical properties such as tensile and flexural strength were experimentally measured. Dynamic thermomechanical analysis was conducted on the alkaline-treated and untreated composites with different frequencies for the assessment of the damping characteristics. The alkaline-treated interleaved almond shell and flax fiber composite showed considerably higher damping characteristics. This could be due to the improved adhesion between the matrix and reinforcements. An addition of almond shell particulate positively increased the strength and stiffness of composites.
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6

Yin, Xiaoli, Yancong Liu, Yufei Miao, and Guijun Xian. "Water Absorption, Hydrothermal Expansion, and Thermomechanical Properties of a Vinylester Resin for Fiber-Reinforced Polymer Composites Subjected to Water or Alkaline Solution Immersion." Polymers 11, no. 3 (March 16, 2019): 505. http://dx.doi.org/10.3390/polym11030505.

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In the present paper, a vinyl ester (VE) resin, potentially used as a resin matrix for fiber-reinforced polymer (FRP) composite sucker rods in oil drilling, FRP bridge cables, or FRP marine structures, was investigated on its resistance to water and alkaline solution immersion in terms of water uptake, hydrothermal expansion, and mechanical properties. A two-stage diffusion model was applied to simulate the water uptake processes. Alkaline solution immersion led to a slightly higher mass loss (approx. 0.4%) compared to water immersion (approx. 0.23%) due to the hydrolysis and leaching of uncured small molecules (e.g., styrene). Water immersion caused the expansion of VE plates monitored with Fiber Bragg Grating (FBG). With the same water uptake, the expansion increased with immersion temperatures, which is attributed to the increased relaxation extent of the resin molecular networks. Although an obvious decrease of the glass transition temperatures (Tg) of VE due to water immersion (5.4 to 6.1 °C/1% water uptake), Tg can be recovered almost completely after drying. Tensile test results indicate that a short-term immersion (less than 6 months) enhances both the strength and elongation at break, while the extension of the immersion time degrades both the strength and elongation. The modulus of VE shows insensitive to the immersion even at elevated temperatures.
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7

Tkachuk, A. I., I. V. Terekhov, Ya M. Gurevich, and K. N. Grigoreva. "RESEARCH OF THE INFLUENCE OF THE MODIFYING ADDITIVES NATURE ON THE RHEOLOGICAL AND THERMOMECHANICAL PROPERTIES OF A PHOTOPOLYMER COMPOSITION BASED ON EPOXY VINYL ESTER RESIN." «Aviation Materials and Technologies», no. 3 (2019): 31–40. http://dx.doi.org/10.18577/2071-9140-2019-0-3-31-40.

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8

Sun, Jia Ying, Yan Qing Li, Wei Tian, and Cheng Yan Zhu. "Study on the Resin Curing Time and the Mechanical Properties of the Composites." Advanced Materials Research 602-604 (December 2012): 33–36. http://dx.doi.org/10.4028/www.scientific.net/amr.602-604.33.

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In order to study the curing characteristics of common resins including bisphenol-A epoxy vinyl ester resin, phenolic epoxy vinyl ester resin and unsaturated polyester resin, the curing time of three resins was tested using cobalt naphthenate as accelerator and methyl ethyl ketone peroxide as curing agent. The results showed that the resin curing time reduces with the experimental temperature rising; in order to control the curing time at about 25 minutes when the experimental temperature is 23°C, the curing agent adding proportion of bisphenol-A epoxy vinyl ester resin, unsaturated polyester resin and phenolic epoxy vinyl ester resin are respective about 0.7%, 0.5% and 1.8%. The composites made by bisphenol-A epoxy vinyl ester resin have excellent tensile strength and composites made by phenolic epoxy vinyl ester resin have best bending strength.
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9

Siva, P., I. K. Varma, D. M. Patel, and T. J. M. Sinha. "Effect of structure on properties of vinyl ester resins." Bulletin of Materials Science 17, no. 6 (November 1994): 1095–101. http://dx.doi.org/10.1007/bf02757587.

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10

Cook, Wayne D., George P. Simon, Peter J. Burchill, Michelle Lau, and Travis J. Fitch. "Curing kinetics and thermal properties of vinyl ester resins." Journal of Applied Polymer Science 64, no. 4 (April 25, 1997): 769–81. http://dx.doi.org/10.1002/(sici)1097-4628(19970425)64:4<769::aid-app16>3.0.co;2-p.

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11

Goel, T. C., A. Tripathi, B. S. Rao, M. S. Choudhary, V. Choudhary, and I. K. Varma. "Vinyl ester resins. II. Effect of styrene on electrical properties." Journal of Applied Polymer Science 30, no. 4 (April 1985): 1491–97. http://dx.doi.org/10.1002/app.1985.070300414.

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12

Fakhari, Alireza, Abdul Razak Rahmat, Mat Uzir Wahit, Siti Noor Hidayah Mustapha, and Wan Nurhayati Wan Tajulruddin. "Mechanical Properties of Hybrid Thermosets from Vinyl Ester Resin and Acrylated Epoxidized Palm Oil (AEPO)." Applied Mechanics and Materials 695 (November 2014): 73–76. http://dx.doi.org/10.4028/www.scientific.net/amm.695.73.

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A series of green hybrid thermosetting resins composed of acrylated epoxidized palm oil (AEPO) and vinyl ester (VE) were prepared via free radical polymerization. The AEPO/VE ratio was varied between 5/95 and 20/80 wt.%. The mechanical properties of resulting hybrid systems were investigated by tensile and flexural tests. The results revealed that these hybrids exhibit mechanical properties comparable to those of commercial vinyl ester resins.
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13

Ku, H., Mohan Trada, and V. C. Puttgunta. "Mechanical Properties of Vinyl Ester Composites Cured by Microwave Irradiation: Pilot Study." Key Engineering Materials 334-335 (March 2007): 537–40. http://dx.doi.org/10.4028/www.scientific.net/kem.334-335.537.

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Composite components made from vinyl ester resins by Centre of Excellence in Engineered Fiber Composites (CEEFC), University of Southern Queensland (USQ) suffer considerable shrinkage during hardening. Currently, CEEFC solves the shrinkage problem by breaking a large composite component into smaller composite parts because smaller parts tend to have less shrinkage. These smaller parts are then joined together to form the overall structure. The shrinkage of vinyl ester particulate composites has been reduced by curing the resins under microwave conditions. The reduction in the shrinkage of the resins by microwaves will enable the manufacture of large vinyl ester composite items possible. This project investigates the difference in impact strength, tensile strength and Young’s modulus of 33 percent by weight of fly-ash particulate reinforced vinyl ester composite, VE/FLY-ASH (33%) cured under microwave and ambient conditions. Drop weight impact tests were used to find out the impact strength of the composite, while tensile tests were used to find out the tensile strength and Young’s modulus of the composite. The power levels of microwaves used were 180 and 360 W; the duration of exposure of the composite samples to microwave irradiation varied from 20 to 50 seconds. The difference in impact strength and Young’s modulus between microwave cured vinyl ester particulate composites and those cured under ambient conditions had been found to be minimal. However, the tensile strength of the composite samples cured under microwave conditions can be higher than those cured under ambient conditions.
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14

Cui, Yu Qing, and Zhong Wei Yin. "Carbon-fibre-reinforced modified cyanate ester winding composites and their thermomechanical properties." High Performance Polymers 31, no. 2 (January 21, 2018): 154–67. http://dx.doi.org/10.1177/0954008317753526.

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Although the extensive research has expanded on the modification of cyanate ester (CE) resins and the mechanical properties of CE composites, very few studies have been conducted on carbon fibre (CF)/modified CE winding composites and the thermomechanical properties of the composites. In this research, epoxy (EP)-modified novolac cyanate ester (NCE) and bismaleimide (BMI)-modified NCE resins were prepared. The CF/modified CE winding composites were manufactured, and their thermomechanical properties were tested. The optimal winding process was determined, and a preheating technique was implemented. Then, the EP/CE resin (10:90) and the BMI–DBA/CE resin (10:90) were selected as the resin matrix of the winding composite based on the viscosity properties, mechanical properties and thermal analysis (using thermogravimetric analysis and differential scanning calorimetry) of the modified CE resin. The selected resin exhibited good manufacturability at 70°C, good thermal stability and high Tg (above 370°C). The thermomechanical property tests indicate that the modified CE resin composite exhibits an outstanding mechanical strength at room temperature and at high temperatures (130°C, 150°C and 180°C) compared with that of the pure CE resin composite. The reasons for this enhancement can be attributed to a toughening mechanism and the effect of sizing agents on the CFs.
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15

Bakar, Norliana, and Siew Choo Chin. "Performance of Bamboo Fiber Reinforced Composites: Mechanical Properties." Key Engineering Materials 879 (March 2021): 284–93. http://dx.doi.org/10.4028/www.scientific.net/kem.879.284.

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Fiber Reinforced Polymer (FRP) made from synthetic fiber had been widely used for strengthening of reinforced concrete (RC) structures in the past decades. Due to its high cost, detrimental to the environment and human health, natural fiber composites becoming the current alternatives towards a green and environmental friendly material. This paper presents an investigation on the mechanical properties of bamboo fiber reinforced composite (BFRC) with different types of resins. The BFRC specimens were prepared by hand lay-up method using epoxy and vinyl-ester resins. Bamboo fiber volume fractions, 30%, 35%, 40%, 45% and 50% was experimentally investigated by conducting tensile and flexural test, respectively. Results showed that the tensile and flexural strength of bamboo fiber reinforced epoxy composite (BFREC) was 63.2% greater than the bamboo fiber reinforced vinyl-ester composite (BFRVC). It was found that 45% of bamboo fiber volume fraction on BFREC exhibited the highest tensile strength compared to other BFRECs. Meanwhile, 40% bamboo fiber volume fraction of BFRVC showed the highest tensile strength between bamboo fiber volume fractions for BFRC using vinyl-ester resin. Studies showed that epoxy-based BFRC exhibited excellent results compared to the vinyl-ester-based composite. Further studies are required on using BFRC epoxy-based composite in various structural applications and strengthening purposes.
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16

Pajarito, Bryan B., Masatoshi Kubouchi, Hiroyuki Tomita, and Saiko Aoki. "Microstructural Dependency of Diffusion in Glass Flake-Reinforced Vinyl Ester Resins." ASEAN Journal of Chemical Engineering 12, no. 1 (August 6, 2012): 11. http://dx.doi.org/10.22146/ajche.49751.

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Vinyl ester resins are utilized for long-term corrosion protection of metal, alloy, and concrete substrates against concentrated acids, alkalis, and solvents at high temperature. Glass flakes are usually added as fillers to reduce chemical diffusion within the vinyl ester matrix. A common industry practice is to use glass flakes with large aspect ratio, high volume fraction, and in parallel alignment to surface in chemical contact for barrier applications. During processing and curing of glass flake-filled vinyl ester resins, irregular microstructures such as reduced flake aspect ratio and random orientation of flakes are commonly observed. Such microstructures can affect the overall chemical diffusion, resulting to barrier properties less predictable by simple diffusion models. Therefore, in this study, a simple 2D random walk simulation procedure is used in attempt to estimate the microstructural dependency of diffusion in glass flake-reinforced vinyl ester resins. While the random walk simulations are in good agreement with the tortuosity-based diffusion models in terms of microstructural effects, in most cases the simulation results are inconsistent with the experimental measurements of acid diffusion in glass flake-filled vinyl ester resins. A possible cause for this is the poor adherence of vinyl ester resin to glass flakes. Osmotic cracks are also formed during immersion which also influences overall diffusion through the material.
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17

Rodriguez, Exequiel, Maider Larrañaga, Iñaki Mondragón, and Analía Vázquez. "Relationship between the network morphology and properties of commercial vinyl ester resins." Journal of Applied Polymer Science 100, no. 5 (2006): 3895–903. http://dx.doi.org/10.1002/app.22732.

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18

Grishchuk, S., N. Castellà, and J. Karger-Kocsis. "Hybrid resins from polyisocyanate/vinyl ester/water glass systems: Structure and properties." European Polymer Journal 43, no. 4 (April 2007): 1245–57. http://dx.doi.org/10.1016/j.eurpolymj.2007.01.010.

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19

Afshar, Arash, Dorina Mihut, Stephen Hill, and Javad Baqersad. "Synergistic effects of environmental exposures on polymer matrix with or without metallic coating protection." Journal of Composite Materials 52, no. 27 (April 11, 2018): 3773–84. http://dx.doi.org/10.1177/0021998318770244.

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Epoxy and vinyl ester resins are widely being used in fiber-reinforced polymer matrix composites due to their superior physical and mechanical properties; however, they suffer significant degradation during prolonged environmental exposure that is affecting their extended use. The current study shows that the synergistic exposure to ultraviolet radiation, high temperature, and moisture has detrimental effects on the microstructure, strength, ductility, and toughness of both resins with more pronounced effects on the epoxy. The environmental damage in the microstructure of epoxy appeared primarily in the form of surface cavities and blisters while for the vinyl ester emerged mainly as microcracking events. Correlation between degradation of microstructure and loss in the flexural properties of epoxy and vinyl ester was also presented. Furthermore, the protective effect of copper metallic thin films on the epoxy substrate was characterized, revealing that the copper coating can be an effective barrier in preventing environmental degradation of epoxy based composites.
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20

OTA, Takao, Takashi MATSUOKA, and Kazuhiko SAKAGUCHI. "K-0902 Effect of Post-cure on Mechanical Properties of Vinyl-ester Resins." Proceedings of the JSME annual meeting I.01.1 (2001): 485–86. http://dx.doi.org/10.1299/jsmemecjo.i.01.1.0_485.

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21

Ziaee, S., and G. R. Palmese. "Effects of temperature on cure kinetics and mechanical properties of vinyl-ester resins." Journal of Polymer Science Part B: Polymer Physics 37, no. 7 (April 1, 1999): 725–44. http://dx.doi.org/10.1002/(sici)1099-0488(19990401)37:7<725::aid-polb23>3.0.co;2-e.

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22

Kandola, Baljinder K., John R. Ebdon, and Chen Zhou. "Development of vinyl ester resins with improved flame retardant properties for structural marine applications." Reactive and Functional Polymers 129 (August 2018): 111–22. http://dx.doi.org/10.1016/j.reactfunctpolym.2017.08.006.

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23

Karger-Kocsis, J., and O. Gryshchuk. "Morphology and fracture properties of modified bisphenol A and novolac type vinyl ester resins." Journal of Applied Polymer Science 100, no. 5 (2006): 4012–22. http://dx.doi.org/10.1002/app.23220.

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24

Li, Peng, Yunhua Yu, and Xiaoping Yang. "Effects of initiators on the cure kinetics and mechanical properties of vinyl ester resins." Journal of Applied Polymer Science 109, no. 4 (2008): 2539–45. http://dx.doi.org/10.1002/app.28234.

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25

Karger-Kocsis, J., N. Castellà, and S. Grishchuk. "Hybrid resins from polyisocyanate, vinyl ester, melamine formaldehyde and water glass: structure and properties." Plastics, Rubber and Composites 37, no. 5-6 (June 2008): 204–9. http://dx.doi.org/10.1179/174328908x309349.

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26

Scott, Timothy F., Wayne D. Cook, and John S. Forsythe. "Effect of the degree of cure on the viscoelastic properties of vinyl ester resins." European Polymer Journal 44, no. 10 (October 2008): 3200–3212. http://dx.doi.org/10.1016/j.eurpolymj.2008.07.009.

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27

Zattini, Giorgio, Laura Mazzocchetti, Tiziana Benelli, Emanuele Maccaferri, Gianluca Brancolini, and Loris Giorgini. "Mechanical Properties and Fracture Surface Analysis of Vinyl Ester Resins Reinforced with Recycled Carbon Fibres." Key Engineering Materials 827 (December 2019): 110–15. http://dx.doi.org/10.4028/www.scientific.net/kem.827.110.

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This work is focused on the mechanical characterization and fracture surfaces analysis of thermosetting polymers reinforced with short, randomly oriented, recycled carbon fibres (rCFs). This work aims at evaluating fibre/matrix adhesion between recycled CFs - reclaimed via pyrolysis followed by controlled oxidation of the pyrolytic char - and different polymer matrices, namely epoxy and vinyl ester resins. The latter is the main focus in this work, being amongst the most widely used thermosetting resins in SMC processes, which are the typical target for short rCFs. The evaluation of the properties of this new recycled carbon fibre reinforced polymer (rCFRP) has been via thermogravimetric analysis, dynamic mechanical analysis, stress/strain tests in tensile mode, and a subsequent analysis of the fracture surfaces by means of images analysis obtained by macrophotography, Optical Microscopy and Scanning Electron Microscopy. The comparison amongst the results allowed to evaluate the influence of the polymer nature and of the adhesion quality between fibres and polymeric matrix, mainly on the mechanical properties of the rCFRPs.
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28

Park, Sang-won, Jin-Mook Jung, and Jae-Hak Choi. "Mechanical Properties of Room Temperature-cured Vinyl Ester Resins Post-cured by Electron Beam Irradiation." Polymer Korea 41, no. 2 (March 31, 2017): 276. http://dx.doi.org/10.7317/pk.2017.41.2.276.

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29

Li, Peng, Xiaoping Yang, Yunhua Yu, and Dingsheng Yu. "Cure kinetics, microheterogeneity, and mechanical properties of the high-temperature cure of vinyl ester resins." Journal of Applied Polymer Science 92, no. 2 (2004): 1124–33. http://dx.doi.org/10.1002/app.13686.

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30

Goswami, Sudipta, and Jagesh Kumar Ranjan. "Study of Mechanical and Thermomechanical Properties of Vinyl Ester/Polyurethane Interpenetrating Polymer Network Based Hybrid Composites." Fibers and Polymers 21, no. 5 (May 2020): 1096–114. http://dx.doi.org/10.1007/s12221-020-9338-5.

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31

Agarwal, Nimisha, Abhishek Singh, Indra K. Varma, and Veena Choudhary. "Effect of structure on mechanical properties of vinyl ester resins and their glass fiber-reinforced composites." Journal of Applied Polymer Science 108, no. 3 (2008): 1942–48. http://dx.doi.org/10.1002/app.27779.

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32

Shahedifar, Vahideh, Amir Masoud Rezadoust, and Iraj Amiri Amraei. "Comparison of Physical, Thermal, and Thermomechanical Properties of Cotton/Epoxy Composite and Cotton/Vinyl Ester Composite Inhibitors." Propellants, Explosives, Pyrotechnics 41, no. 2 (March 8, 2016): 321–26. http://dx.doi.org/10.1002/prep.201500005.

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33

Ayers, S. R., and G. M. Van Erp. "Characterization of new structural core materials based on vinyl ester and hollow ceramic microspheres." Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications 217, no. 3 (July 1, 2003): 221–28. http://dx.doi.org/10.1177/146442070321700304.

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A new class of structural core material has been developed at the University of Southern Queensland for applications of composite materials in civil and structural engineering. These materials combine polymer resins with hollow ceramic microspheres to produce core materials with high structural capacity at low cost. A number of prototype structural elements using these materials have displayed significant potential for application in civil engineering structures. An ongoing research programme has been initiated to improve fundamental understanding of these materials and to provide the knowledge required for broad utilization. This current study has investigated the behaviour of core material formulations based on vinyl ester resins and hollow ceramic cenospheres. Investigations have focused on identifying key relationships between the constituent materials and resulting mechanical properties of the core material. A variety of matrix and filler characteristics have been examined. This work has shown that, at the type of filler levels considered feasible for structural engineering applications (vf > 30 per cent), the behaviour of the material is largely determined by the filler particles, with only minimal influence from the matrix material. Further investigations are continuing to quantify these effects and to develop predictive models for key relationships.
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34

Atta, Ayman M., Sayed I. Elnagdy, Manar E. Abdel-Raouf, Shimaa M. Elsaeed, and Abdel-Azim A. Abdel-Azim. "Compressive Properties and Curing Behaviour of Unsaturated Polyester Resins in the Presence of Vinyl Ester Resins Derived from Recycled Poly(ethylene terephthalate)." Journal of Polymer Research 12, no. 5 (October 2005): 373–83. http://dx.doi.org/10.1007/s10965-005-1638-3.

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35

Huang, Ming, and Cameron Abrams. "Effects of Reactivity Ratios on Network Topology and Thermomechanical Properties in Vinyl Ester/Styrene Thermosets: Molecular Dynamics Simulations." Macromolecular Theory and Simulations 28, no. 6 (August 20, 2019): 1900030. http://dx.doi.org/10.1002/mats.201900030.

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36

Huang, Ming, and Cameron Abrams. "Effects of Reactivity Ratios on Network Topology and Thermomechanical Properties in Vinyl Ester/Styrene Thermosets: Molecular Dynamics Simulations." Macromolecular Theory and Simulations 28, no. 6 (November 2019): 1970011. http://dx.doi.org/10.1002/mats.201970011.

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37

Malik, Mona, Veena Choudhary, and I. K. Varma. "Effect of Non-halogen Flame Retardant Additives on the Properties of Vinyl Ester Resins and their Composites." Journal of Fire Sciences 20, no. 4 (July 2002): 329–42. http://dx.doi.org/10.1177/073490402762574767.

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38

Dey, Tania. "Properties of vinyl ester resins containing methacrylated fatty acid comonomer: the effect of fatty acid chain length." Polymer International 56, no. 7 (2007): 853–59. http://dx.doi.org/10.1002/pi.2215.

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39

Danilov, Vladimir A., Oleg A. Kolyamshin, Nadezhda E. Temnikova, Oleg V. Stoyanov, and Marina V. Kolpakova. "MODIFICATION OF OLIGOESTER MALEINATE BY ALKYL ESTER OF N-MALEINIMIDOBENZOIC ACID." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 62, no. 12 (December 8, 2019): 78–84. http://dx.doi.org/10.6060/ivkkt.20196212.6109.

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When using products from unsaturated polyester resins (NPS), often increased requirements for thermal and chemical resistance are raised. Increasing the thermal stability of the PS is possible due to the modification of resins by polymerization compounds, which can copolymerize with both oligoether maleinate and styrene. One of such effective additives is N-phenylmaleinimides. The paper presents the results of modification of unsaturated polyester grade PN-1 UT with alkyl ethers n-maleinimidobenzoic acid. The properties of terpolymers are investigated. The effect of substituents of the aromatic group with N-phenylmaleinimides on the properties of terpolymers was investigated. It is also of interest to study the effect of substituents of the aromatic group in N-phenylmaleinimide on the properties of modified polymers. It is shown that terpolymers due to their maleinimides are superior in strength and thermomechanical properties of the copolymers of oligoestermaleinate and styrene. The increase in the size of the hydrocarbon radical substituents of the aromatic group of maleinimides contributes to the increase of the thermo-and physico-mechanical properties of terpolymers. It is also shown that the glass transition temperature of polymers depends on the content of maleinimides, as well as on the structure of the aromatic group. With an increase in the content of maleinimides (up to 5 wt. %) there is an increase in the glass transition temperature and the beginning of the destructive flow. The greatest increase in glass transition temperature (30 °C) is observed at a content of 3 wt. % butyl ether of n-maleimidobenzoic acid. The increase in the length of the hydrocarbon radical (С5Н11 and С8Н17) of the ester group of n-maleimidobenzoic acid leads to the appearance of a plasticizing effect. Synthesized terpolymers can be recommended as binders in the production of heat-resistant composite materials, in particular, fiberglass.
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40

Chen, Hong Yan, Zhen Xing Kong, and Ji Hui Wang. "Influence of Carbon Nanotubes on Mechanical and Thermal Properties of Glass Fiber Reinforced Vinyl Ester Resin Composites." Materials Science Forum 675-677 (February 2011): 419–22. http://dx.doi.org/10.4028/www.scientific.net/msf.675-677.419.

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Carbon nanotubes (CNTs) were incorporated into glass fiber/ vinyl ester resins composites to improve their mechanical and thermal properties, especially the interlaminar shear and longitudinal compressive strengths which are belong to the matrix-dominanted properties and much weaker than the fiber-dominated properties. In this study, a higher temperature initiator was added to improve the polymerization degree and raise the transition temperature (Tg). Mechanical testing indicated that by adding 0.4 wt% CNTs, the nano-filled composites attributed to 21%, 16%, 10%, and 8% improvement in interlaminar shear strength, compressive strength, tensile strength and flexural strength with respect to their counterparts without CNTs, respectively. Moreover, Thermogravimetric analysis (TGA) also exhibits approximately 14°C higher decomposition temperature than those of conventional composites.
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41

Akishin, Pavel, Evgeny Barkanov, Nora Miazza, and Santiago Galvez. "Curing Kinetic Models of Resins for Microwave Assisted Pultrusion." Key Engineering Materials 721 (December 2016): 92–96. http://dx.doi.org/10.4028/www.scientific.net/kem.721.92.

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Traditional description of the rate of the thermoset resin reaction by the Arrhenius relationship multiplied by a reaction function has been used in this study. The Kissinger method and ASTM E 698 procedure have been used for a determination of parameters of the Arrhenius relationship. N-th order, Prout-Tompkins and Kamal-Sourour models have been used and evaluated as the reaction functions to formulate the curing kinetic models of an epoxy resin.An engineering tool based on Microsoft Excel code has been developed by using the developed methodology. This tool has been successfully applied for a building of the curing kinetic model of vinyl ester resin with high microwave absorption properties to be used in the microwave assisted pultrusion processes.
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42

Gryshchuk, O., and J. Karger-Kocsis. "Influence of the type of epoxy hardener on the structure and properties of interpenetrated vinyl ester/epoxy resins." Journal of Polymer Science Part A: Polymer Chemistry 42, no. 21 (2004): 5471–81. http://dx.doi.org/10.1002/pola.20371.

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43

Grishchuk, Sergiy, Núria Castellà, Anton A. Apostolov, and Jozsef Karger-Kocsis. "Structure and properties of vinyl ester resins modified with organophilic synthetic layered silicates bearing non- and co-reactive intercalants." Journal of Composite Materials 46, no. 8 (August 15, 2011): 941–47. http://dx.doi.org/10.1177/0021998311413311.

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44

Patel, H. S., K. K. Panchal, S. R. Patel, and S. N. Desai. "Interacting Blends of Novel Unsaturated Polyester Amide Resin with Vinyl Acetate." E-Journal of Chemistry 1, no. 5 (2004): 237–42. http://dx.doi.org/10.1155/2004/924136.

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Novel unsaturated poly (ester- amide) resins (UPEAs) were prepared by the reaction between an epoxy resin, namely diglycidyl ether of bisphenol–A (DGEBA) and unsaturated aliphatic bisamic acids using a base catalyst. These UPEAs were then blended with a vinyl monomer namely, Vinyl acetate (VA) to produce a homogeneous resin syrup. The curing of these UPEAs-VA resin blends was carried out by using benzoyl peroxide (BPO) as an initiator for the radical polymerization and was monitored by using a differential scanning calorimeter (DSC). The glass fibre reinforced composites (i.e. laminates) of these UPEA-VA resin blends were fabricated using the DSC data. The chemical, mechanical and electrical properties of the glass fibre composites have also been evaluated. The unreinforced cured samples of the UPEA-VA resin blends were also analyzed by thermogravimetry (TGA).
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45

Lara-González, Luis Ángel, Wilmar Guillermo-Rodríguez, Yaneth Pineda-Triana, Gabriel Peña-Rodríguez, and Hugo Felipe Salazar. "Optimization of the Tensile Properties of Polymeric Matrix Composites Reinforced with Magnetite Particles by Experimental Design." TecnoLógicas 23, no. 48 (May 15, 2020): 83–98. http://dx.doi.org/10.22430/22565337.1499.

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A full-factorial 33 experiment was used in this study to determine the optimal values of the tensile properties of three composite materials manufactured based on three polymeric resins: Derakane Momentum epoxy vinyl ester based on bisphenol-A (DM-411), polyester based on terephthalic acid (P115-A), and isophthalic polyester (P2000). Such materials were reinforced with magnetite powders at concentrations of 10, 20, and 30 wt %, and the particle sizes were classified with three sieves: #200 (46–75 μm), #325 (26–45 μm), and #500 (0–25 μm). The compounds were manufactured using the hand lay-up method at room temperature in accordance with ASTM D638-14 for M1-type specimens. A tensile test was conducted on a universal Microtest EM2/300/FR machine at a test speed of 5 ± 25 % mm/min using an Epsilon extensometer calibrated in accordance with the ASTM E83 standard at 20 ± 2 °C. The magnetite powders and compound morphology were studied by Scanning Electron Microscopy. The mechanical properties of the compounds and the optimal response found by Analysis of Variance (ANOVA) and Response Surface Methodology (RSM) are also reported. The best response to the mechanical stimuli occurs with the composite material prepared with the epoxy vinyl ester resin DM-411, a concentration of 29.4 % of magnetite (Fe3O4), a particle size of 58.5 microns, and a 200 sieve.
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46

Mao, Wei, Shouhai Li, Mei Li, Kun Huang, and Jianling Xia. "Design, preparation and properties of novel flame retardant thermosetting vinyl ester copolymers based on castor oil and industrial dipentene." Polish Journal of Chemical Technology 19, no. 3 (September 1, 2017): 1–8. http://dx.doi.org/10.1515/pjct-2017-0040.

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Abstract A novel bio-based flame-retardant thermosetting vinyl ester resin monomer was synthesized from castor oil. The chemical structures of the monomer was characterized by FTIR and 1H-NMR. In order to improve its rigidity and expand its application in the field of bio-based materials, it was mixed with certain proportions of another reactive bio-based VER monomer, which had rigid and strong polar groups, and then a series of copolymers were prepared with thermal curing method. Then their tensile property, hardness, morphology of fractured surface, flame retardant property, DMA and thermostability were all investigated. The results indicated that the copolymers had relatively high tensile strength of 11.2 MPa, and the limiting oxygen index is above 23% in all prepared copolymers. DMA demonstrates that the glass transition temperature of the cured resins is up to 56.1°C. Thermogravimetric analysis shows that the copolymers have excellent thermal stability.
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47

Clay, Anthony M., Joshua R. Mitchell, Zachary R. Boelter, and John J. La Scala. "Superior Properties through Feedstock Development for Vat Photopolymerization Additive Manufacturing of High-Performance Biobased Feedstocks." Materials 14, no. 17 (August 26, 2021): 4843. http://dx.doi.org/10.3390/ma14174843.

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Vat photopolymerization additive manufacturing (Vat AM) technologies have found niche industrial use being able to produce personalized parts in moderate quantity. However, Vat AM lacks in its ability to produce parts of satisfactory thermal and mechanical properties for structural applications. The purpose of this investigation was to develop high-performance resins with glass transition temperatures (Tg) above 200 °C for Vat AM, evaluate the properties of the produced thermosets and establish a structure–property relationship of the thermosets produced. Herein, we have developed SLA-type resins that feature bio-derived monomer hesperetin trimethacrylate (HTM) synthesized from the flavonone hesperetin. Diluents 4-acryloyl morpholine, styrene, 4-methyl styrene and 4-tert butylstyrene (tbutylsty) were photocured with HTM as the monomer and all produced thermosets with Tg values above 200 °C. Investigations of suitable crosslinkers urethane dimethacrylate, the vinyl ester CN 151 and Ebecryl 4859 (Eb4859) showed that each crosslinker displayed different benefits when formulated with HTM as the monomer and tbutylSty as the diluent (HTM:crosslinker:tbutylSty with mass ratio 2:1:2). The crosslinker CN 151 produced the thermoset of greatest onset of thermal decomposition temperature (T0) of 352 °C. Eb4859 produced the thermoset of highest tensile strength, 19 ± 7 MPa, amongst the set of varied crosslinkers. The formulation featuring UDM (HTM:UDM:tbutysty) offered ease of processing and was seemingly the easiest to print. Investigations of reactive diluent showed that styrene produced the thermoset of the highest extent of cure and the overall highest tensile strength, 25 ± 5 MPa, while tbutylSty produced the thermoset with the greatest Tan-δ Tg, 231 °C. HTM was synthesized, formulated with diluents, crosslinkers and initiators. The HTM resins were then 3D printed to produce thermosets of Tg values greater than 200 °C. The polymer properties were evaluated and a structure–reactivity relationship was discussed.
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48

Patel, Hasmukh S., and Kumar K. Panchal. "Interacting Blends of Novel Unsaturated Polyester Amide Resin with Styrene." E-Journal of Chemistry 1, no. 1 (2004): 32–37. http://dx.doi.org/10.1155/2004/521631.

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Novel unsaturated poly (ester-amide) resins (UPEAs) were prepared by the reaction between an epoxy resin, namely diglycidyl ether of bisphenol–A (DGEBA) and unsaturated aliphatic bisamic acids using a base catalyst. These UPEAs were then blended with a vinyl monomer namely, Styrene (STY.) to produce a homogeneous resin syrup. The curing of these UPEAs-STY. resin blends was carried out by using benzoyl peroxide (BPO) as a catalyst and was monitored by using a differential scanning calorimeter (DSC). The glass fibre reinforced composites (i.e. laminates) of these UPEA-STY. resin blends were fabricated using the DSC data. The chemical, mechanical and electrical properties of the glass fibre composites have also been evaluated. The unreinforced cured samples of the UPEA-STY. resin blends were also analyzed by thermogravimetry (TGA).
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49

Ali, Ahmed H., Brahim Benmokrane, Hamdy M. Mohamed, Allan Manalo, and Adel El-Safty. "Statistical analysis and theoretical predictions of the tensile-strength retention of glass fiber-reinforced polymer bars based on resin type." Journal of Composite Materials 52, no. 21 (February 9, 2018): 2929–48. http://dx.doi.org/10.1177/0021998318755866.

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This paper presents experimental investigation, statistical analysis, and theoretical predictions of tensile-strength retention of glass fiber-reinforced polymer bars, made with vinyl-ester, polyester, or epoxy resins. The durability of glass fiber-reinforced polymer bars was evaluated as a function of time of immersion in alkaline solution. The aging of the three glass fiber-reinforced polymer bar types consisted of immersion glass fiber-reinforced polymer bar samples in an alkaline solution (up to 5000 h) at different elevated exposure temperatures. Subsequently, the physical and tensile properties of the unconditioned bars were compared with that of the conditioned bars to assess the durability performance of the glass fiber-reinforced polymer bars. Microstructure of all of the glass fiber-reinforced polymer bar types was investigated with scanning electron microscopy, energy dispersive spectroscopy, and Fourier transform infrared spectroscopy for both the conditioned and unconditioned cases, to qualitatively explain the experimental results and to assess changes and/or degradation in the glass fiber-reinforced polymer bars. In addition, the long-term performance of glass fiber-reinforced polymer bars was assessed considering the effect of service years, environmental humidity, and seasonal temperature fluctuations. The test results showed that the tensile strength of the glass fiber-reinforced polymer bars was affected by increased immersion time at higher temperatures and the reduction in tensile strength was statistically significantly dependent on the type of resin system. The prediction approach of the glass fiber-reinforced polymer bars based on the environmental reduction factor ( CE) after 200 years indicated that the CE values for vinyl-ester, epoxy, and polyester glass fiber-reinforced polymer bars can be conservatively recommended to 0.81, 0.75, and 0.71, respectively, for a moisture-saturated environment (relative humidity = 100%) and at 30℃. The polyester glass fiber-reinforced polymer bars experienced greater debonding at the fiber–resin interface than the vinyl-ester and epoxy glass fiber-reinforced polymer bars.
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50

Sarath Chandra, D., Dr K.Vijaya Kumar Reddy, and Dr Omprakash Hebbal. "Fabrication and Mechanical Characterization of Glass and Carbon Fibre Reinforced Composite’s Used for Marine Applications." International Journal of Engineering & Technology 7, no. 4.5 (September 22, 2018): 228. http://dx.doi.org/10.14419/ijet.v7i4.5.20052.

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The composite materials are replacing the traditional materials, because of its superior properties such as high tensile strength, low thermal expansion, high strength to weight ratio. The developments of new materials are on the anvil and are growing day by day. Fiber composites such as Glass-Fiber Reinforced Polymers (GFRP) composites and Carbon-Fiber Reinforced Composites (CFRP) became more attractive due to their better properties for marine applications. In this paper, GFRP, CFRP and Hybrid composites are developed and their mechanical properties such as Hardness, tensile strength, compression strength, impact strength, toughness are evaluated. The study used to compare the effect volumetric fraction of fibers in order to improve strength and toughness, this done by using two types of fibers E-glass and carbon & two types of resins epoxy ( AralditeLY556 and Aradur HY951 ) and vinyl ester. In this experimental study, we found that high tensile strength, high specific strength, hardness and low density are obtained with carbon fibre reinforced composites, but high impact strength and toughness are obtained with glass fibre reinforced composites. Finally incorporate the result and try to find alternatives composites using for marine applications and obtain the best mechanical properties
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