Academic literature on the topic 'Vinyl ether'

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Journal articles on the topic "Vinyl ether"

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Štěpánek, Petr, Ondřej Vích, Lukáš Werner, Ladislav Kniežo, Hana Dvořáková, and Pavel Vojtíšek. "Stereoselective Preparation of Precursors of α-C-(1→3)-Disaccharides." Collection of Czechoslovak Chemical Communications 70, no. 9 (2005): 1411–28. http://dx.doi.org/10.1135/cccc20051411.

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The stereoselectivity of cycloaddition of sugar-containing substituted 1-(thiazol-2-yl)but-2-en-1-ones 1 and vinyl ethers was studied using the achiral vinyl ether/chiral catalyst as well as the chiral vinyl ether/achiral catalyst combinations. It has been shown that Eu(fod)3-catalyzed cycloaddition of oxadienes 1a-1e with the chiral vinyl ethers 9 and 10 affords stereoselectively almost pure cycloadducts 11a-11e and 12a-12e, respectively. The obtained cycloadducts are suitable precursors for the synthesis of α-C-(1→3)-disaccharides, containing 2-deoxy-arabino-hexopyranose moiety of D- or L-configuration.
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Zhang, Jinghan, Yibo Wu, Kaixuan Chen, Min Zhang, Liangfa Gong, Dan Yang, Shuxin Li, and Wenli Guo. "Characteristics and Mechanism of Vinyl Ether Cationic Polymerization in Aqueous Media Initiated by Alcohol/B(C6F5)3/Et2O." Polymers 11, no. 3 (March 14, 2019): 500. http://dx.doi.org/10.3390/polym11030500.

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Aqueous cationic polymerizations of vinyl ethers (isobutyl vinyl ether (IBVE), 2-chloroethyl vinyl ether (CEVE), and n-butyl vinyl ether (n-BVE)) were performed for the first time by a CumOH/B(C6F5)3/Et2O initiating system in an air atmosphere. The polymerization proceeded in a reproducible manner through the careful design of experimental conditions (adding initiator, co-solvents, and surfactant or decreasing the reaction temperature), and the polymerization characteristics were systematically tested and compared in the suspension and emulsion. The significant difference with traditional cationic polymerization is that the polymerization rate in aqueous media using B(C6F5)3/Et2O as a co-initiator decreases when the temperature is lowered. The polymerization sites are located on the monomer/water surface. Density functional theory (DFT) was applied to investigate the competition between H2O and alcohol combined with B(C6F5)3 for providing a theoretical basis. The effectiveness of the proposed mechanism for the aqueous cationic polymerization of vinyl ethers using CumOH/B(C6F5)3/Et2O was confirmed.
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González-Belman, Oscar, Artur Brotons-Rufes, Michele Tomasini, Laura Falivene, Lucia Caporaso, Jose Jiménez-Halla, and Albert Poater. "Towards Dual-Metal Catalyzed Hydroalkoxylation of Alkynes." Catalysts 11, no. 6 (June 2, 2021): 704. http://dx.doi.org/10.3390/catal11060704.

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Poly (vinyl ethers) are compounds with great value in the coating industry due to exhibiting properties such as high viscosity, soft adhesiveness, resistance to saponification and solubility in water and organic solvents. However, the main challenge in this field is the synthesis of vinyl ether monomers that can be synthetized by methodologies such as vinyl transfer, reduction of vinyl phosphate ether, isomerization, hydrogenation of acetylenic ethers, elimination, addition of alcohols to alkyne species etc. Nevertheless, the most successful strategy to access to vinyl ether derivatives is the addition of alcohols to alkynes catalyzed by transition metals such as molybdenum, tungsten, ruthenium, palladium, platinum, gold, silver, iridium and rhodium, where gold-NHC catalysts have shown the best results in vinyl ether synthesis. Recently, the hydrophenoxylation reaction was found to proceed through a digold-assisted process where the species that determine the rate of the reaction are PhO-[Au(IPr)] and alkyne-[Au(IPr)]. Later, the improvement of the hydrophenoxylation reaction by using a mixed combination of Cu-NHC and Au-NHC catalysts was also reported. DFT studies confirmed a cost-effective method for the hydrophenoxylation reaction and located the rate-determining step, which turned out to be quite sensitive to the sterical hindrance due to the NHC ligands.
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Namikoshi, Takeshi, Tamotsu Hashimoto, Yuka Suzuki, Michio Urushisaki, and Toshikazu Sakaguchi. "Synthesis of poly(vinyl ether) optical plastics by cationic copolymerization of tricyclodecane vinyl ether with functionalized vinyl ethers." Journal of Applied Polymer Science 126, S2 (April 11, 2012): E307—E314. http://dx.doi.org/10.1002/app.36973.

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Nuyken, Oskar, and Stefan Ingrisch. "Block copolymers from isobutyl vinyl ether and 2-chloroethyl vinyl ether." Macromolecular Chemistry and Physics 199, no. 4 (April 1, 1998): 607–12. http://dx.doi.org/10.1002/(sici)1521-3935(19980401)199:4<607::aid-macp607>3.0.co;2-5.

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Bouchekif, H., A. I. Sulhami, R. D. Alghamdi, Y. Gnanou, and N. Hadjichristidis. "Triblock and pentablock terpolymers by sequential base-assisted living cationic copolymerization of functionalized vinyl ethers." Polymer Chemistry 6, no. 8 (2015): 1236–47. http://dx.doi.org/10.1039/c4py01728e.

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A series of novel, well-defined triblock and pentablock terpolymers of n-butyl vinyl ether (nBVE), 2-chloroethyl vinyl ether (CEVE) and tert-butyldimethylsilyl ethylene glycol vinyl ether (SiEGVE) were synthesized by sequential base-assisted living cationic polymerization.
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Ollevier, Thierry, and Topwe M. Mwene-Mbeja. "Diastereoselective bismuth triflate catalyzed Claisen rearrangement of 2-alkoxycarbonyl-substituted allyl vinyl ethers." Canadian Journal of Chemistry 86, no. 3 (March 1, 2008): 209–12. http://dx.doi.org/10.1139/v07-149.

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In the presence of a catalytic amount of bismuth triflate, 2-alkoxycarbonyl-substituted allyl vinyl ethers as a mixture of enol ether double bond isomers were smoothly converted into the β,γ-alkyl-substituted α-keto esters. The isomerization reaction proceeded rapidly to afford smoothly the α-keto esters in good to excellent yields using catalytic amounts of Bi(OTf)3·4H2O (1 mol%). (Z,Z)-2-iso-Propyloxycarbonyl-substituted allyl vinyl ethers 3Z,Z afforded the corresponding β,γ-alkyl-substituted α-keto esters 4 with very good syn diastereoselectivity.Key words: bismuth; bismuth(III) triflate; Claisen rearrangement; allyl vinyl ethers.
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YUMINOV, V. S. "ChemInform Abstract: Polyfluoroalkyl Vinyl Ethers. Part 2. Synthesis of Perfluorocyclohexylmethyl Vinyl Ether." ChemInform 27, no. 22 (August 5, 2010): no. http://dx.doi.org/10.1002/chin.199622098.

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Namikoshi, Takeshi, Tamotsu Hashimoto, and Michio Urushisaki. "Synthesis of poly(vinyl ether) plastics for optical use by cationic copolymerization of tricyclodecyl vinyl ether withn-butyl vinyl ether." Journal of Polymer Science Part A: Polymer Chemistry 45, no. 18 (2007): 4389–93. http://dx.doi.org/10.1002/pola.22205.

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Confortini, Ondine, and Filip E. Du Prez. "Functionalized Thermo-Responsive Poly(vinyl ether) by Living Cationic Random Copolymerization of Methyl Vinyl Ether and 2-Chloroethyl Vinyl Ether." Macromolecular Chemistry and Physics 208, no. 17 (September 5, 2007): 1871–82. http://dx.doi.org/10.1002/macp.200700205.

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Dissertations / Theses on the topic "Vinyl ether"

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Kim, Young-Min MacGregor John Frederick. "Photopolymerization of cycloaliphatic epoxide and vinyl ether /." *McMaster only, 2005.

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Kirschbaum, Stefan [Verfasser]. "Vinyl ether functional polyurethanes as novel photopolymers / Stefan Kirschbaum." Mainz : Universitätsbibliothek Mainz, 2017. http://d-nb.info/1125907592/34.

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Pietri, Valerie. "Electron beam irradiation of polystyrene/poly(vinyl methyl ether) blends." Thesis, This resource online, 1993. http://scholar.lib.vt.edu/theses/available/etd-07292009-090349/.

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Gestoso, Souto Patricia. "Orientation study of poly(vinyl phenol)/poly(vinyl methyl ether) blends by infrared dichroism and molecular dynamics." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp05/NQ65420.pdf.

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Lang, Weihong. "Synthesis of oligo (vinyl ether)s in ab initio cationic polymerisation." Thesis, University of Sheffield, 2002. http://etheses.whiterose.ac.uk/10205/.

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Terminally functionalised oligo(vinyl ether)s were produced in ab initio cationic polymerisations. Various polymerisations and chain end functionalisation systems were investigated. MALDI-TOF mass spectrometry was applied to analyse the obtained oligomers and thus the polymerisation and chain end functionalisation process. Oligo(isobutyl vinyl ether), also oligo(ethyl vinyl ether) and oligo(methyl vinyl ether) were synthesised in cationic polymerisation. Silyl enol ethers were added to the polymerisation as end-capping agents before initiations and they compete with monomer to cap the carbocationic chain end. The methodology relies on a comparable end capping rate to chain propagation rate so that oligomers can still be produced in the presence of reactive end-capping agents whilst other side reactions are suppressed. Polymerisation temperatures investigated range from -78°C to the room temperature (21 °C), 4 out of 6 silyl enol ethers were applied and are proved to be reactive in the end-capping. Initiation systems investigated include iBVEHCl/Yb(OTf)3 and iBVE-HCl/SnC14 and both produced oligomers with high chain end functionalities. Generally silyl enol ether functionalised oligo(vinyl ether)s have lower molecular weights and broader molecular weight distributions than their identical control polymerisations without end-capping. The iBVE-HCl/SnCI4 initiation system produced functionalised oligomers with narrower molecular weight distribution than iBVE-HCl/Yb(OTf)3 initiation system. Different silyl enol ether reactivities in end-capping were observed. It was also observed that ab initio chain end functionalisation by reactive silyl enol ethers largely suppressed the majority of side reactions during polymerisation. This suppression was attributed to the higher rates of end-capping than side reaction rates. When (1-tert-butyl-vinyloxy)trimethyl-silane was applied as end-capping agent, the polymerisation system produced oligomers with narrower molecular weight distributions than the control polymerisations without end-capping while the chain end functionalities were also obtained. This indicates the possibility of setting up a controlled ab initio chain end functionalisation cationic polymerisation system in which the oligomer's molecular weight, polydispersity and chain end functionality can be regulated at the same time. MALDI-TOF MS, NMR and SEC are mainly applied in the oligomer characterisation. Side reactions in this polymerisation system were examined from these analyses. Under less critical polymerisation conditions 7 different chain ends from side reactions are observed in MALDI-TOF mass spectra. Based on the MS and NMR observation the various chain end structures are identified. Side reactions are also postulated which mainly include ß-proton elimination, water capping of the carbocationic chain end and combinations of these. Sample preparation for MALDI-TOF MS analysis of oligo(vinyl ether)s is investigated. Direct laser desorption of oligo(isobutyl vinyl ether) was observed for the samples of molecular weight of up to 2k Daltons. Complementary information of oligo(isobutyl vinyl ether)s obtained from ESI MS indicates a serious mass discrimination in MALDI-TOF MS technique and thus it is regarded that MALDITOF MS can not provide reliable molecular weight distributions for polymers with broad molecular weight distributions. Combination of SEC and MALDI-TOF MS to calibrate SEC columns and quantitative application of MALDI-TOF MS to analyse the oligomers' chain end functionalities were also explored.
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Kalita, Deep Jyoti. "Polymers and Coatings Derived From Novel Bio-Based Vinyl Ether Monomers." Diss., North Dakota State University, 2018. https://hdl.handle.net/10365/27852.

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To fulfill the demand for household, industrial, light weight transportation, health, and cosmetic products etc., production of polymeric materials has been increasing every year. However, limited resource of fossil fuel is threatening the sustainability of the raw materials used to produce these products. These products have very low to no biodegradability, thereby staying in the ecosystem for long time causing serious threats. Increasing environmental concerns and strict regulations has made renewable based materials suitable for the development of environmental friendly polymers with sustainability. Novel plant oil based vinyl ether (POVE) monomers were derived from plant oil such as soybean, linseed and camelina oil. Polymers varying in molecular weight (MW) were derived from these monomers and studied for air-drying coatings. Study of the coating and free film properties showed that at a given MW, Tensile (Young’s modulus, and tensile strength), viscoelastic (Tg, XLD), physical (hardness, solvent resistance, and impact resistance) properties increased with increasing unsaturation in the parent PO. Polymers derived from distilled POVE monomers resulted essentially colorless poly(POVEs) which were evaluated as a binder for artist paint in comparison to linseed oil. Colorless poly(POVE)s showed significantly faster dry/cure along with dramatically lower yellowness than linseed oil. Novel, vinyl ether monomers, were also synthesized from cardanol (CEVE) and eugenol (EEVE) and coatings produced from their homopolymers and copolymers with cyclohexyl vinyl ether were studied in comparison to commercial alkyds. Glass transition temperatures of these homopolymers were increased with CHVE incorporation. However, incorporation of 25% CHVE resulted in cured coatings and free films with better mechanical, viscoelastic and physical properties than commercial alkyds. Incorporation of CHVE > 50wt.% in the copolymer resulted in low crosslinked networks with reduced properties such as percent elongation, chemical resistance and impact resistance. Epoxidized poly(EEVE) resins varying in percent epoxide (30%, 50% and 70%) were synthesized and studied for two component amine cured coatings in comparison to BPA based epoxy resin. Results obtained from high throughput experimentation showed the ability of Epoly(EEVE) resins with 50% or higher epoxide to form harder, higher crosslinked coatings with tunability based on type of curative than BPA based resin.
National Science Foundation EPSCoR Program (grant IIA-1355466)
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Kleissler, Charles Richard. "Comparison of poly(vinyl alcohol) backbone-grafted ethers and chain-growth crown ether polymers in selective cation adsorption." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/10115.

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Ohgi, Hiroyuki. "Studies on Synthesis and Physical Properties of Highly Isotactic Poly(vinyl alcohol) Derived from Poly(tert-butyl vinyl ether)." 京都大学 (Kyoto University), 2007. http://hdl.handle.net/2433/57290.

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Chang, Teng. "Studies of Genistein Modified Poly(Ether Sulfone)/Poly(Vinyl Pyrrolidone) and Poly(Vinyl Chloride)/Epoxidized Soybean Oil Blends with Enhanced Blood-Compatibility for Biomedical Application." University of Akron / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=akron1427712989.

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Lea, Santa Cinzia Chemical Sciences &amp Engineering Faculty of Engineering UNSW. "An investigation into the synthesis of poly(co-maleic anhydride/iso-butyl vinyl ether)with RAFT polymerisation." Awarded by:University of New South Wales. Chemical Sciences and Engineering, 2006. http://handle.unsw.edu.au/1959.4/31435.

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Poly (co iso-butyl vinyl ether-alt-maleic anhydride), an alternating copolymer, was synthesised. For this class of copolymers the formation of an electron-donor complex is invoked to explain their microstructure in which the two comonomers strictly alternate. Due to its polarity, this copolymer constitutes a potential additive for imparting hydrophilic properties to a hydrophobic matrix. In order to obtain narrow molecular weight polymers and study the relation between the molecular weight of this additive and its ability to migrate to the host polymer surface, chain transfer agents were introduced in the system and also the Reversible Addition-Fragmentation chain Transfer (RAFT) process was employed. Free radical polymerisation was first carried out to allow for a comparison with the RAFT process and kinetics of copolymerisation was studied by NIR-FTIR and 1H NMR spectroscopy in order to analyse the rate of reaction of each comonomer. Dibenzyl trithiobenzoate, 3-benzyl sulfanyl thiocarbonyl sulfanyl-propionic acid and dibenzyl trithiobenzoate were used as RAFT agents. Results demonstrate that only benzyl dithiobenzoate is able to control the molecular weight of this copolymer and decrease its polydispersity index; possible reasons laying behind this result are discussed. It was also found that, in particular in the presence of benzyl dithiobenzoate, poly(iso-butyl vinyl ether) forms. This is an unusual phenomenon considering that the free radical polymerisation affords alternating copolymers and that iso-butyl vinyl ether is a monomer that polymerises through the cationic process. Experiments were carried out in various solvents in an attempt to counteract this side reaction, but no appreciable correlation between the properties of the solvents and the formation of homopolymer were found. Various hypothesis are considered, however it is likely that, in the conditions adopted, the presence of the RAFT agents alters the equilibrium constant of complex formation favouring the synthesis of the homopolymer. In addition to this side???reaction also inhibition of the copolymerisation reaction was at times encountered and an investigation into this phenomenon was also conducted.
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Books on the topic "Vinyl ether"

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Leibovitch, Mordechai. Vinyl ether hydrolysis in aqueous solution. Ottawa: National Library of Canada = Bibliothèque nationale du Canada, 1992.

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Ubysz, Dorota. Vinyl ether hydrolisis in aqueous solution. Ottawa: National Library of Canada, 1993.

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Marococcia, John Frank. Investigation of the potential energy surface for the protonated and unprotonated conformers: vinyl alcohol, methyl vinyl ether, 1,3-butadien-1-OL. 1986.

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Swanson, Karen L. Neoplastic and Vascular Diseases. Oxford University Press, 2012. http://dx.doi.org/10.1093/med/9780199755691.003.0618.

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Neoplastic and vascular disorders are reviewed. Lung cancer is the most common malignancy and cause of cancer death in both men and women worldwide. The incidence of new lung cancers has continued to decrease in men and increase in women. The risk factors include cigarette smoking, other carcinogens, cocarcinogens, radon exposure, arsenic, asbestos, coal dust, chromium, vinyl chloride, chloromethyl ether, and chronic lung injury. Genetic and nutritional factors have been implicated. Among vascular disorders, pulmonary embolism is most common. Pulmonary embolism (PE) is the cause of death in 5% to 15% of hospitalized patients who die in the United States. In a multicenter study of PE, the mortality rate at 3 months was 15% and important prognostic factors included age older than 70 years, cancer, congestive heart failure, COPD, systolic arterial hypotension, tachypnea, and right ventricular hypokinesis.
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Darsot, Mariam S. Anion chemistry of cyclic vinyl and allyl ethers: Structure and reactions. 1985.

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Bolshakov, G. Rotational Isomerism of Vinyl Ethers and Sulfides. Routledge, 1987.

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Aogain, Conor Fiacra Mac. The polymerization of alkyl vinyl ethers with ferricenium salts. 1987.

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A, Kopti͡u︡g V., Novosibirskiĭ institut organicheskoĭ khimii, and Nauchno-tekhnicheskiĭ t͡s︡entr khimicheskoĭ informatiki (Akademii͡a︡ nauk SSSR), eds. IK spektry novykh funkt͡s︡ionalʹnykh vinilovykh ėfirov. Novosibirsk: Novosibirskiĭ in-t organicheskoĭ khimii SO AN SSSR, 1988.

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IK i UF spektry gidrazidov ftorkarbonovykh i pentaftorbenzoĭnoĭ kislot i ikh neftorirovannykh analogov. Novosibirsk: Akademii͡a︡ nauk SSSR, Sibirskoe otd-nie, Novosibirskiĭ in-t organicheskoĭ khimii, 1989.

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Book chapters on the topic "Vinyl ether"

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Gooch, Jan W. "Vinyl Ether." In Encyclopedic Dictionary of Polymers, 794. New York, NY: Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_12553.

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Mueller, Helmut W. J. "Vinyl Ether Polymers." In Handbook of Pressure Sensitive Adhesive Technology, 494–507. Boston, MA: Springer US, 1989. http://dx.doi.org/10.1007/978-1-4757-0866-0_17.

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Gooch, Jan W. "Poly(vinyl isobutyl ether)." In Encyclopedic Dictionary of Polymers, 577. New York, NY: Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_9273.

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Steiner, G., and C. Zimmerer. "Poly(vinyl methyl ether) (PVME)." In Polymer Solids and Polymer Melts – Definitions and Physical Properties I, 1073–79. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-32072-9_123.

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Severance, Daniel L., and William L. Jorgensen. "Claisen Rearrangement of Allyl Vinyl Ether." In Structure and Reactivity in Aqueous Solution, 243–59. Washington, DC: American Chemical Society, 1994. http://dx.doi.org/10.1021/bk-1994-0568.ch017.

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Wohlfarth, Christian. "Refractive index of propyl vinyl ether." In Optical Constants, 197. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49236-9_184.

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Wohlfarth, Ch. "Solubility parameter of poly(vinyl methyl ether)." In Polymer Solutions, 1677. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_1028.

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Satoh, Kotaro, Yuuma Fujiki, Mineto Uchiyama, and Masami Kamigaito. "Vinyl Ether/Vinyl Ester Copolymerization by Cationic and Radical Interconvertible Simultaneous Polymerization." In ACS Symposium Series, 323–34. Washington, DC: American Chemical Society, 2018. http://dx.doi.org/10.1021/bk-2018-1284.ch015.

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Wohlfarth, Ch. "Partial specific volume of poly(hexadecyl vinyl ether)." In Polymer Solutions, 469. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_247.

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Wohlfarth, Ch. "Second virial coefficient of poly(vinyl butyl ether)." In Polymer Solutions, 1213–14. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_731.

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Conference papers on the topic "Vinyl ether"

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Furukawa, Taiichi, Frances A. Houle, Deborah L. Casher, and Dolores C. Miller. "Characterization of vinyl ether UV-cure nanoimprint resist." In SPIE Advanced Lithography, edited by Frank M. Schellenberg and Bruno M. La Fontaine. SPIE, 2009. http://dx.doi.org/10.1117/12.813065.

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Ito, Hiroshi, Frances A. Houle, Mark W. Hart, and Rick A. DiPietro. "Vinyl ether resist system for UV-cured nanoimprint lithography." In SPIE 31st International Symposium on Advanced Lithography, edited by Qinghuang Lin. SPIE, 2006. http://dx.doi.org/10.1117/12.656518.

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McCann, J. L., P. Bour, and H. Wieser. "Vibrational and VCD spectra of poly(menthyl vinyl ether)." In The eleventh international conference on fourier transform spectroscopy. AIP, 1998. http://dx.doi.org/10.1063/1.55719.

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Kolesniková, Lucie, José Alonso, and Adam Daly. "Cis-METHYL VINYL ETHER: THE ROTATIONAL SPECTRUM UP TO 600 GHz." In 69th International Symposium on Molecular Spectroscopy. Urbana, Illinois: University of Illinois at Urbana-Champaign, 2014. http://dx.doi.org/10.15278/isms.2014.ta12.

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Lee, JongSoo, Hideo Suzuki, Keisuke Odoi, Nobukazu Miyagawa, Shigeru Takahara, and Tsuguo Yamaoka. "Performance of vinyl ether cross-linkers on resist for 193-nm lithography." In SPIE's 27th Annual International Symposium on Microlithography, edited by Theodore H. Fedynyshyn. SPIE, 2002. http://dx.doi.org/10.1117/12.474254.

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Christianson, Matthew D., Matthew M. Meyer, Owendi Ongayi, David Valeri, and Michael Wagner. "High absorbing resists based on trifluoromethacrylate-vinyl ether copolymers for EUV lithography." In SPIE Advanced Lithography, edited by Mark H. Somervell. SPIE, 2013. http://dx.doi.org/10.1117/12.2014385.

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Ran Zhang and Haixiong Ge. "A novel vinyl ether resin of poly(4-vinylphenol) derivative for lithographic resist." In 2008 2nd IEEE International Nanoelectronics Conference. IEEE, 2008. http://dx.doi.org/10.1109/inec.2008.4585519.

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Diao, Cuimei, and Yingquan Zou. "Photoinitiated polymerization of new hybrid monomer containing vinyl ether and (methyl) acryloyl groups." In SPIE Advanced Lithography, edited by Robert D. Allen and Mark H. Somervell. SPIE, 2011. http://dx.doi.org/10.1117/12.879382.

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Li, Wei, and Ying Quan Zou. "Synthesize and polymerization of novel photocurable vinyl ether monomers containing perfluorinated aromatic units." In SPIE Advanced Lithography, edited by Mark H. Somervell and Thomas I. Wallow. SPIE, 2012. http://dx.doi.org/10.1117/12.916674.

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Gipson, Kyle G., Philip J. Brown, Kathryn A. Stevens, and Christopher L. Cox. "Properties, Characterization and Fiber Extrusion Simulation of Novel Amorphous Polymers for Optical Application." In ASME 2009 International Mechanical Engineering Congress and Exposition. ASMEDC, 2009. http://dx.doi.org/10.1115/imece2009-11544.

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Polymeric optical fibers are generally manufactured in the same manner as traditional glass (silica) fibers. As technology advances, more efficient, cost effective materials and processes are being developed to serve the duties of optical materials within networks. Traditional polymer optical fibers are comprised of hydrocarbon amorphous polymers and include polymethyl methacrylate (PMMA) and polystyrene (PS). These types of polymers have inherent issues in optical applications such as their signal absorption loss. This is largely due to the vibration of the carbon-hydrogen (C-H) bond contained in the polymer backbone. Therefore, to broaden the scope of polymer optical fibers, novel exotic amorphous polymers are being developed. One such polymer family, reported to have excellent optical properties, is perfluorocyclobutyl aryl ethers (PFCB), which do not exhibit the strong C-H vibrations associated with absorption loss. At this time, little is known of the intrinsic properties of PFCBs as well as the behavior of the polymer melt during extrusion. This work will review the thermal and rheological properties of two PFCB polymers: biphenylvinyl ether (BPVE) and hexafluoroisopropylidene vinyl ether (6F). The information gathered from the analysis of these two intrinsic properties will be used as the input data for a fiber extrusion simulation model, FiSim. The application of the FiSim software was done in order to produce a viable limited range of process conditions for which fibers could be melt spun.
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Reports on the topic "Vinyl ether"

1

Bhatia, Q. S., D. H. Pan, and J. T. Koberstein. Preferential Surface Adsorption in Miscible Blends of Polystyrene and Poly(vinyl methyl ether). Fort Belvoir, VA: Defense Technical Information Center, February 1988. http://dx.doi.org/10.21236/ada191451.

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2

Percec, Virgil, Myongsoo Lee, and C. Ackerman. Molecular Engineering of Liquid Crystalline Polymers by Living Polymerization. 9. Living Cationic Polymerization of 5-((4-Cyano-4'-Biphenyl) oxy)pentyl Vinyl Ethers and 7-((4-Cyano-4'-Biphenyl)oxy)heptyl Vinyl Ether, and the Mesomorphic Behavior of the Resulting Polymers. Fort Belvoir, VA: Defense Technical Information Center, October 1990. http://dx.doi.org/10.21236/ada229769.

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3

Perce, Virgil, Myongsoo Lee, and Dimitris Tomazos. Molecular Engineering of Liquid Crystalline Polymers by Living Cationic Polymerization. 21. Synthesis and Characterization of Poly(3-((4-Cyano-4'- Biphenyl)oxy)propyl Vinyl Ether) Macromonomers. Fort Belvoir, VA: Defense Technical Information Center, March 1992. http://dx.doi.org/10.21236/ada248305.

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4

Percec, V., Q. Zheng, and M. Lee. Molecular Engineering of Liquid Crystal Polymers by Living Polymerization. 13. Synthesis and Living Cationic Polymerization of 4-((S(-)-2- Methyl-1-Butyl)Oxycarbonyl)-4'-(omega-Oxyalkyl-1-Vinyl Ether)Biphenyl with Undecanyl and Hexyl Alkyl Groups. Fort Belvoir, VA: Defense Technical Information Center, April 1991. http://dx.doi.org/10.21236/ada235791.

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