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Journal articles on the topic 'VO(salen)'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Nishida, Yuzo, Tadashi Tokii, and Izumi Watanabe. "Reaction between Superoxide Anion and Several Oxovanadium(IV) Compounds." Zeitschrift für Naturforschung B 47, no. 7 (1992): 905–10. http://dx.doi.org/10.1515/znb-1992-0701.

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We have observed that the superoxide anion reacts with VO(salen), but not with VO(saldpt), where H2(salen) and H2(saldpt) are Schiff base ligands derived from salicylaldehyde and ethylenediamine or dipropylenetriamine, respectively. Based on the electrochemical, ESR, and UV spectroscopic studies of the reaction mixture, it was concluded that the superoxide anion reacts with VO(salen) to oxidize V(IV) to V(V) through the formation of a vanadium(V)-peroxide adduct with side-on configuration. The SOD-like function of VO(salen) was elucidated in terms of the above assumption.

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2

North, Michael, and Marta Omedes-Pujol. "Kinetics and mechanism of vanadium catalysed asymmetric cyanohydrin synthesis in propylene carbonate." Beilstein Journal of Organic Chemistry 6 (November 3, 2010): 1043–55. http://dx.doi.org/10.3762/bjoc.6.119.

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Propylene carbonate can be used as a green solvent for the asymmetric synthesis of cyanohydrin trimethylsilyl ethers from aldehydes and trimethylsilyl cyanide catalysed by VO(salen)NCS, though reactions are slower in this solvent than the corresponding reactions carried out in dichloromethane. A mechanistic study has been undertaken, comparing the catalytic activity of VO(salen)NCS in propylene carbonate and dichloromethane. Reactions in both solvents obey overall second-order kinetics, the rate of reaction being dependent on the concentration of both the aldehyde and trimethylsilyl cyanide. T

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3

Shokrollahi, Ardeshir, Mehrorang Ghaedi, Ali Hossain Kianfar, Morteza Montazerozohori, and Marziyeh Najibzadeh. "Construction of New Iodide Ion-Selective Electrodes Based on New Ionophores: Comparison of the Effect of Structures and Additives on Electrode Response." Journal of AOAC INTERNATIONAL 92, no. 4 (2009): 1208–18. http://dx.doi.org/10.1093/jaoac/92.4.1208.

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Abstract New iodide ion-selective electrodes based on bis(2-methyl-3-phenyl-propenylidene)1,2-propanediamine) mercury(II) bromide [Hg(BMPPMB)Br2], bis (5-bromo salicylaldehyde) ethylenediimine vanadyl(IV) [VO(5-Br Salen)], and bis(5-bromo salicylaldehyde) ethylenediimine uranyl(VI) [UO2(5-Br Salen)] carriers are described. The electrodes exhibited Nernstian slopes of 58.3 1.0, 58.5 1.4, and 59.0 1.2 mV/decade for Hg(BMPPMB)Br2, VO(5-Br Salen), and UO2(5-Br Salen) iodide ion concentration in the range of 1.0 1060.1 M, with detection limits of about 0.6, 0.5, and 0.3 M, respectively. The potenti

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4

Sristicheta, Misra, Bihari Pandeya Krishna, Kumar Tiwari Ashok, Zebra Ali Amtul та Saradamani T. "α-Glucosidase inhibition and DPPH free radical scavenging by oxovanadium(IV) complexes of some tetradentate Schiff bases". Journal of Indian Chemical Society Vol. 88, Aug 2011 (2011): 1195–201. https://doi.org/10.5281/zenodo.5786081.

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Department of Chemistry, University of Allahabad, Allahabad-211 002, Uttar Pradesh, India <em>E-mail</em> : kbpandeya@yahoo.com Division of Pharmacology, Indian Institute of Chemical Technology, Hyderabad-500 007, India <em>Manuscript received 04 July 2011, accepted 05 July 2011</em> <em>α</em>-Glucosidase inhibition and DPPH free radical scavenging by four oxovanadium(IV) complexes of tetradentate Schiff bases, derived from salicylaldehyde/5-bromosalicylaldehyde and ethylenediamine/phenylenediamine (VO-salen, VO-brsalen, VO-salphn and VO-brsalphn), have been screened. Among the four com

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5

Vergopoulos, Vassilios, Sven Jantzen, Nathalie Julien, Eric Rose, and Dieter Rehder. "Oxo- und Non-oxovanadium(IY)-Komplexe mit Oxy-Carboxylaten als Liganden, und die Struktur von VCl2(salen) / Oxo and Non-oxovanadium(IV) Complexes with Oxy-Carboxylate Ligands, and the Structure of VCl2(salen)." Zeitschrift für Naturforschung B 49, no. 8 (1994): 1127–36. http://dx.doi.org/10.1515/znb-1994-0818.

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V02+ forms complexes of composition VO(L1)EtOH), VO(HL1)2 and VO(HL2)(H2O) with the ithium or sodium salts of 6-droxymethyl-pyridine-2-arboxylic acid (H2L1) and 4,8-hydroxyquinoline-2-carboxylic acid (H3L2). VCl2(salen/salphen) and VCl2(napgly/ nappa) (napgly and nappa are the Schiff bases derived from o-ydroxynaphthaldehyde and glycine or phenylalanine, respectively), prepared from the oxo precursor and SOCl2, react with Li2L1 and the lithium salts of benzilic acid (H2L3) and ortho-ydroxybenzoic acid (H2L4) to yield the non-oxo (“bare”) complexes V(salen)L1 , V(salen)L3, V(salphen)L3, V(salen

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6

Galloni, Pierluca, Alessia Coletti, Barbara Floris, and Valeria Conte. "Electrochemical properties of VO salen complexes." Inorganica Chimica Acta 420 (August 2014): 144–48. http://dx.doi.org/10.1016/j.ica.2013.12.019.

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7

Aida, Fuyuki, Yohei Takatori, Daichi Kiyokawa, Kentaro Nagamatsu, Kenichi Oyaizu, and Hiroyuki Nishide. "Enhanced catalytic activity of oxovanadium complexes in oxidative polymerization of diphenyl disulfide." Polymer Chemistry 7, no. 11 (2016): 2087–91. http://dx.doi.org/10.1039/c5py01980j.

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8

Horn, Adolfo, Carlos A. L. Filgueiras, James L. Wardell, et al. "A fresh look into VO(salen) chemistry: synthesis, spectroscopy, electrochemistry and crystal structure of [VO(salen)(H2O)]Br·0.5 CH3CN." Inorganica Chimica Acta 357, no. 14 (2004): 4240–46. http://dx.doi.org/10.1016/j.ica.2004.06.023.

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9

Stick, R. V., K. A. Stubbs, D. M. G. Tilbrook, and A. G. Watts. "A New Catalyst for the Reductive Elimination of Acylated Glycosyl Bromides to Form Glycals." Australian Journal of Chemistry 55, no. 2 (2002): 83. http://dx.doi.org/10.1071/ch02011.

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Ethylene-N,N-bis(salicylideneiminato)oxovanadium(IV) {VO(salen)} has been developed as a useful catalyst for the reductive elimination of acylated glycosyl bromides to form glycals, both in the pyranose and furanose series, using zinc/ammonium chloride/methanol or zinc/acetic acid/acetonitrile.

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10

Stick, R. V., K. A. Stubbs, D. M. G. Tilbrook, and A. G. Watts. "Corrigendum to: A New Catalyst for the Reductive Elimination of Acylated Glycosyl Bromides to Form Glycals." Australian Journal of Chemistry 55, no. 4 (2002): iv. http://dx.doi.org/10.1071/ch02011_co.

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Ethylene-N,N-bis(salicylideneiminato)oxovanadium(IV) {VO(salen)} has been developed as a useful catalyst for the reductive elimination of acylated glycosyl bromides to form glycals, both in the pyranose and furanose series, using zinc/ammonium chloride/methanol or zinc/acetic acid/acetonitrile.

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11

Abdolmaleki, Arash, and Saber Zahri. "Comparison of toxicity and teratogenic effects of salen and vo-salen on chicken embryo." Drug and Chemical Toxicology 39, no. 3 (2015): 344–49. http://dx.doi.org/10.3109/01480545.2015.1121492.

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12

Oyaizu, Kenichi, та Eishun Tsuchida. "The First Oxovanadium Ring in [{OV(salen)}2(μ-F)][VO(salen)][BF4]·(CH2Cl2)xCrystals". Journal of the American Chemical Society 125, № 19 (2003): 5630–31. http://dx.doi.org/10.1021/ja021374q.

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13

Belokon, Y., M. North, V. Maleev, and D. Usanov. "Role of the X Anion in the VO(salen) (X)-Mediated Cyanohydrin Synthesis." Synfacts 2007, no. 1 (2007): 0060. http://dx.doi.org/10.1055/s-2006-955734.

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14

Yang, Hengquan, Lei Zhang, Peng Wang, Qihua Yang, and Can Li. "The enantioselective cyanosilylation of aldehydes on a chiral VO(Salen) complex encapsulated in SBA-16." Green Chem. 11, no. 2 (2009): 257–64. http://dx.doi.org/10.1039/b815997a.

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15

Cheng, S. H., S. R. Sheen, C. P. Cheng, and C. T. Chang. "The electronic structure of VO(5-X-salen), X = H, OMe, OH, Cl, Br and NO2." Inorganica Chimica Acta 171, no. 1 (1990): 21–24. http://dx.doi.org/10.1016/s0020-1693(00)84657-5.

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16

Shekaari, Hemayat, Amir Kazempour, and Ayyob Soltanpour. "Molecular interactions of VO(salen) Schiff base complex with an ionic liquid in dimethyl sulfoxide solutions." Ionics 21, no. 9 (2015): 2557–65. http://dx.doi.org/10.1007/s11581-015-1449-4.

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17

Belokon, Yuri N., William Clegg, Ross W. Harrington, et al. "Mechanism-Guided Development of VO(salen)X Complexes as Catalysts for the Asymmetric Synthesis of Cyanohydrin Trimethylsilyl Ethers." Chemistry - A European Journal 15, no. 9 (2009): 2148–65. http://dx.doi.org/10.1002/chem.200801679.

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18

Sasajima, Yasuhide, Motoharu Shimizu, Norie Kuroyanagi, et al. "Redox reactions of [VO(salen)]+/0 couple in acetonitrile: Volume analyses in relation to large chiral recognitions observed for electron self-exchange reactions of [VO(Schiff-Base)]+/0." Inorganica Chimica Acta 359, no. 1 (2006): 346–54. http://dx.doi.org/10.1016/j.ica.2005.10.028.

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19

Belokon, Yuri N., Victor I. Maleev, Michael North, and Dmitry L. Usanov. "VO(salen)(X) catalysed asymmetric cyanohydrin synthesis: an unexpected influence of the nature of anion X on the catalytic activity." Chemical Communications, no. 44 (2006): 4614. http://dx.doi.org/10.1039/b609591g.

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20

Mohammadi, Mohsen, and Razieh Yazdanparast. "Methoxy VO-salen complex: In vitro antioxidant activity, cytotoxicity evaluation and protective effect on CCl4-induced oxidative stress in rats." Food and Chemical Toxicology 47, no. 4 (2009): 716–21. http://dx.doi.org/10.1016/j.fct.2008.12.029.

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21

Roy, Souvik, Anil Kumar Mondru, Sudheer Kumar Dontamalla, Ram Prasad Vaddepalli, Santanu Sannigrahi та Prabhakar Reddy Veerareddy. "Methoxy VO–salen Stimulates Pancreatic β Cell Survival by Upregulation of eNOS and Downregulation of Apoptosis in STZ-induced Diabetic Rats". Biological Trace Element Research 144, № 1-3 (2011): 1095–111. http://dx.doi.org/10.1007/s12011-011-9139-1.

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22

Hoshina, Gakuse, Masanobu Tsuchimoto, and Shigeru Ohba. "Thermal Dehydrogenation Reacton of [N,N′-Bis(3-ethoxysalicylidene)-1,2-diphenyl-1,2-ethanediaminato]nickel(II) with [VO(salen)]NO3in the Solid State." Bulletin of the Chemical Society of Japan 73, no. 2 (2000): 369–74. http://dx.doi.org/10.1246/bcsj.73.369.

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23

Vithalani, Ravi S., Dikin Patel, Chetan K. Modi, Prafulla K. Jha, Himanshu Srivastava, and Sanjeev R. Kane. "Synthesis of less acidic VO-salen complex grafted onto graphene oxide via functionalization of surface carboxyl groups for the selective oxidation of norbornene." Graphene Technology 5, no. 3-4 (2020): 83–101. http://dx.doi.org/10.1007/s41127-020-00037-x.

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24

Baleizão, Carlos, Bárbara Gigante, Hermenegildo Garcia, and Avelino Corma. "Ionic liquids as green solvents for the asymmetric synthesis of cyanohydrins catalysed by VO(salen) complexesDedicated to Prof. W. Adam on the occasion of his 65th Birthday." Green Chemistry 4, no. 3 (2002): 272–74. http://dx.doi.org/10.1039/b201497c.

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25

Anjali, Deshmukh, and Bansa Lekhika. "SAPINDUS EMARGINATUS VAHL AS A NATURAL SCOURUNG AGENT IN DYEING OF COTTON WITH CARISSA CARANDAS LEAF EXTRACT." Biolife 2, no. 2 (2022): 599–604. https://doi.org/10.5281/zenodo.7214322.

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  <strong>ABSTRACT</strong>   Comparative study of <em>Sapindus</em> <em>emarginatus</em> vahl as natural soap and synthetic soap for scouring of cotton was carried out. Scoured samples were tested for physical properties expressed as cotton scoured with <em>Sapindus emarginatus</em> vahl. showed high tearing strength.  Scoured cotton samples were mordanted with <em>Terminalia</em> <em>chebula</em> Linn, <em>Punica</em> <em>granatum</em> Linn as natural mordants and stannous chloride, potash alum as metal mordants.  Physical and fastnesss properties of mordanted and dyed co

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26

Blake, Antony B., John R. Chipperfield, Wasif Hussain, Reinhard Paschke, and Ekkehard Sinn. "Effects of Ligand Substituents (F for H; OR for R) on Mesogenic Properties of M(Salen) Derivatives (M = Cu, Ni, VO). New Fluoro-Substituted Complexes and Crystal Structure of the Mesogen Ni(5-hexylSalen)." Inorganic Chemistry 34, no. 5 (1995): 1125–29. http://dx.doi.org/10.1021/ic00109a020.

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27

Jankiram, B. Devhade, B. Pethe Gaurav, R. Yaul Amit, and S. Aswar Anand. "Polychelates of salen-type Schiff base : Synthesis, characterization, thermal, electrical conductivity and biological study." Journal of Indian Chemical Society Vol. 92, Sep 2015 (2015): 1359–69. https://doi.org/10.5281/zenodo.5701732.

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Department of Chemistry, Sant Gadge Baba Amravati University, Amravati-444 602, Maharashtra, India <em>E-mail</em> : aswaranand@gmail.com <em>Manuscript received online 03 December 2014, revised 19 January 2015, accepted 27 January 2015</em> Metal polychelates of the type [ML.(2H<sub>2</sub>O)X]Y where M = Cr<sup>III</sup>, Mn<sup>III</sup>, Fe<sup>III</sup>, Ti<sup>III</sup>, Zr<sup>IV</sup>, VO<sup>IV</sup>, MoO<sub>2</sub> <sup>VI</sup> , UO2 <sup>VI</sup>; X = H<sub>2</sub>O, Y = Cl with 4,4´-bis[(I-propanesalicylaldimine-5)azo]biphenyl (L) have been synthesized. Their structures hav

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28

Winpenny, Richard, Tom S. Bennett, Selena J. Lockyer, et al. "Two‐ and Three‐Spin Hybrid Inorganic‐Organic [2]Rotaxanes Containing Metallated Salen Groups." Chemistry – An Asian Journal, June 19, 2024. http://dx.doi.org/10.1002/asia.202400641.

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Mono‐ and bis‐salen functionalised [2]rotaxanes have been synthesised from the esterification of [2]rotaxanes containing phenol‐terminated threads (salen = N,N′‐bis(salicylidene)ethylenediamine). The [2]rotaxanes have general formula [RH][Cr7NiF8(O2CtBu)16], where [RH]+ is a thread with a central secondary ammonium site that templates a [Cr7NiF8(O2CtBu)16]− ring. The threads are terminated at one or both ends by carboxylic acid functionalised salen groups. The {M(salen)} groups can be free‐base [M = (H+)2] or metallated [M = Cu2+, Ni2+, (VO)2+]. The [2]rotaxanes have been characterised by sing

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29

"Chiral VO(salen) Metal–Organic Framework for Asymmetric Cyanosilylation of Aldehydes." Synfacts 13, no. 03 (2017): 0334. http://dx.doi.org/10.1055/s-0036-1589989.

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30

Golamirad, Farah, Saber Zahri, Arash Abdolmaleki, Abolfazl Bezaatpour, and Seyed Mehdi Razavi. "Vanadium oxide 3- methoxy salen, a synthetic biologically active complex against HeLa and McCoy cell lines." Basic & Clinical Cancer Research, December 10, 2023. http://dx.doi.org/10.18502/bccr.v14i1.14389.

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Background: Vanadium is an essential dietary microelement that plays a key role in metabolic pathways and has anti-neoplastic effects. In this regard, vanadium oxide 3-methoxy salen complex was produced and its anticancer effects were evaluated against HeLa and McCoy cell lines. Methods: Schiff bases produced from equivalents of Vanadyl acetylacetonate [VO(acac)2] in methanol were used to make a vanadium oxide 3-methoxy salen complex. Then, The antioxidant property of compound, cell viability and cytotoxicity assay, DNA fragmentation analysis and determination of the apoptosis pathway ge

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31

Belokon, Yuri N., Victor I. Maleev, Michael North, and Dmitry L. Usanov. "VO(salen)(X) Catalyzed Asymmetric Cyanohydrin Synthesis: An Unexpected Influence of the Nature of Anion X on the Catalytic Activity." ChemInform 38, no. 11 (2007). http://dx.doi.org/10.1002/chin.200711045.

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32

Al‐Farraj, Eida S., Sultan K. Alharbi, Mehran Feizi‐Dehnayebi, et al. "Molecular, Stochiometric, Stability and Biological Investigations of Novel Multifunctional Salen Metal Chelates: From Synthesis to Therapeutic Potential Supported by Theoretical Approaches." Applied Organometallic Chemistry 39, no. 8 (2025). https://doi.org/10.1002/aoc.70273.

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ABSTRACTThree novel complexes comprising a 2,6‐bis((E)‐1‐(2‐(4‐bromophenyl)hydrazono)ethyl)pyridine (BPHE) ligand with PdII, ZnII, and VOII metal centers have been synthesized and thoroughly characterized using FT‐IR, mass spectrometry, UV–vis spectroscopy, thermogravimetric analysis, and conductivity measurement data. The thermodynamic and kinetic aspects of their thermal degradation phases have been evaluated. Conductivity measurements confirmed that all the chelates exhibited electrolytic behavior where BPHEPd (60.50 Ω−1 cm2 mol−1), BPHEZn (58.40 Ω−1 cm2 mol−1), and BPHEV (94.21 Ω−1 cm2 mol

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