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Dissertations / Theses on the topic 'Zinc(II) complex'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Jönsson, Jörgen. "Phase transformation and surface chemistry of secondary iron minerals formed from acid mine drainage." Doctoral thesis, Umeå University, Chemistry, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-156.

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<p>The mining of sulphidic ore to extract metals such as zinc and copper produces huge quantities of waste material. The weathering and oxidation of the waste produces what is commonly known as Acid Mine Drainage (AMD), a dilute sulphuric acid rich in Fe(II) and heavy metals. This thesis serves to summarise five papers reporting how the precipitation of Fe(III) phases can attenuate the contamination of heavy metals by adsorption processes. </p><p>Schwertmannite (Fe8O8(OH)6SO4) is a common Fe(III) mineral precipitating in AMD environments at pH 3-4. The stability and surface chemistry of this m

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2

Mirjana, Radanović. "Kompleksi nekih prelaznih metala sa Šifovim bazama aminogvanidina." Phd thesis, Univerzitet u Novom Sadu, Prirodno-matematički fakultet u Novom Sadu, 2015. https://www.cris.uns.ac.rs/record.jsf?recordId=95548&source=NDLTD&language=en.

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   U ovoj doktorskoj disertaciji opisane su sinteze novih kompleksa prelaznih metala sa piridoksiliden-  (PLAG), odnosno saliciliden-aminogvanidinom (SALAG). Dobijenikompleksi su okarakterisani elementalnom analizom, IR spektrima, konduktometrijskim i magnetnim merenjima, a većina i rendgenskomstrukturnom analizom. Osim toga, dobijene su i nove forme ovih &Scaron;ifovih baza, i to u vidu monokristala, čime su omogućena ispitivanja njihovih  molekulskih i kristalnih struktura, kao i uporedna analiza sa koordinovanim ligandima.    Sa PLAG je sintetisano 7 novi 

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3

Pratt, Jo-Anne Margaret. "The development of zinc (II) selective fluorescent ligands /." Title page, contents and abstract only, 1995. http://web4.library.adelaide.edu.au/theses/09PH/09php915.pdf.

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4

Le, Mest Yves. "Etude des propriétés électrochimiques de biporphyrines de type "face-à-face" : réactivité des dérives du cobalt vis-à-vis de l'oxygène." Brest, 1988. http://www.theses.fr/1988BRES2013.

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5

Jamadar, Abeda. "Copper(II) and Zinc(II) complexes of aroyl hydrazones as potential antitubercular agents." Thesis, University of York, 2012. http://etheses.whiterose.ac.uk/3099/.

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There is a continuing need to make new antitubercular drugs due to development of resistance towards present drugs. To do this, series of pyruvate hydrazones (PVAHs) and their respective Cu(II) complexes and Zn(II) complexes were synthesized and fully characterised. Variable temperature NMR studies of PVAHs indicate the presence of E and Z isomers in the solution. Determination of the obtained single crystal X-ray structures reveals that Cu(II) ion binds to PVAH ligand in 1:1 ratio resulting in square pyramidal geometry in most of the Cu(II) complexes, whereas Zn(II) ion binds to two PVAH liga

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6

Alqahtani, Norah. "Synthesis and Characterization of Zinc(II) Dipyrrin Photosensitizers." Digital Commons @ East Tennessee State University, 2018. https://dc.etsu.edu/etd/3466.

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Photocatalytic carbon dioxide reduction transforms CO2 to useful chemicals and fuels, reducing CO2 emissions and making fossil fuels more renewable. Due to a lack of earthabundant sensitizers, we want to design new earth-abundant sensitizers to go with the many known carbon dioxide reduction catalysts. Zn(II) dipyrrin complexes strongly absorb visible light, but their excited state properties have not been widely studied. To investigate their photophysical properties, two Zn dipyrrin complexes, with and without heavy atoms, were synthesized and characterized by NMR and mass spectrometry. The p

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7

Steinborn, Martin. "Coordination chemistry of sugar-phosphate complexes with palladium(II), rhenium(V) and zinc(II)." Diss., Ludwig-Maximilians-Universität München, 2013. http://nbn-resolving.de/urn:nbn:de:bvb:19-161901.

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8

Peralta, Rosely Aparecida. "Novos complexos binucleares de cobre(II) e de ferro(III) zinco(II)." Florianópolis, SC, 2005. http://repositorio.ufsc.br/handle/123456789/101680.

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Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas. Programa de Pós-graduação em Química<br>Made available in DSpace on 2013-07-15T22:57:09Z (GMT). No. of bitstreams: 0<br>Neste trabalho foram sintetizados e caracterizados 6 novos complexos de Cu(II) empregando-se os ligantes: H2Ldtb, H2BPBPMP-CH3, H2BPBPMP-NO2 e H2BPBPMP. Os complexos de Cu(II) foram testados na reação de oxidação do substrato 3,5-DTBC e podem ser considerados modelos funcionais para as catecol oxidases. Também foram sintetizados e caracterizados 4 novos complexos de Fe(III)Zn(

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9

Dancs, Ágnes. "New peptide-type tripodal ligands and their metal complexes : synthesis, thermodynamic and structural study, application in catalytic function." Thesis, Université de Lorraine, 2017. http://www.theses.fr/2017LORR0292/document.

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De nos jours, un des objectifs importants de la recherche bioinorganique moderne est le développement d'enzymes artificielles. L'étude séquentielle des acides aminés présents dans le centre actif des métalloenzymes peut présenter une voie possible de la stratégie de modélisation enzymatique. Cependant, les peptides linéaires ont leurs limites lors de la reconstitution des centres actifs des métalloenzymes : ils ne possèdent pas la structure tridimensionnelle bien définie, par conséquent leur structure est vulnérable vis-à-vis de la coordination ou de l’hydrolyse des azotes amidiques. La capaci

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10

Ngan, Tung-wan. "Design, synthesis and studies of novel photochromic zinc(II) thiolate complexes." Click to view the E-thesis via HKUTO, 2004. http://sunzi.lib.hku.hk/hkuto/record/B31367380.

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11

Ngan, Tung-wan, and 顏冬芸. "Design, synthesis and studies of novel photochromic zinc(II) thiolate complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B31367380.

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12

REIS, ALINE CRUZ DE MORAES. "SYTHESIS AND CHARACTERIZATION OF COPPER (II) AND ZINC (II) COMPLEXES WITH DIPEPTIDES OF BIOLOGICAL INTEREST." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2010. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=16186@1.

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CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO<br>FUNDAÇÃO DE APOIO À PESQUISA DO ESTADO DO RIO DE JANEIRO<br>Este trabalho descreve a síntese e caracterização de quatro complexos de cobre (II) e quatro complexos de zinco (II), com dipeptídeos, no estado sólido. Os dipeptídeos envolvidos foram: glicil-glicina, glicil-valina, metionil-metionina, metionil-glicina e cisteinil-glicina, cujos aminoácidos fazem parte de algumas proteínas envolvidas em processos de neurodegeneração, mais especificamente na doença de Alzheimer. Embora os mecanismos que desencadeiam esta patologia não es

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13

SZYFMAN, NATALIE WAISSMANN. "STUDY OF COPPER(II) AND ZINC(II) COMPLEXES WITH SOME POLYAMINES AND PHOSPHOCREATINE OR ATP." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2011. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=18244@1.

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CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO<br>Foram estudados alguns sistemas binários de Cu(II) e Zn(II) formados com as poliaminas (PA= En, Tn, Put, Spd e Spm) e os complexos ternários (MLPA), onde L foi a PCr ou o ATP e PA uma das cinco poliaminas. O estudo foi realizado em solução aquosa por potenciometria, espectroscopia de ultravioleta-visível, Raman, RMN e RPE e cálculos de menor energia de estabilização e modelagem molecular. As constantes de estabilidade foram determinadas pela potenciometria. Os valores das constantes dos complexos com as poliaminas apresentam um c

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14

OLIVEIRA, MARIA STELLA NUNES DE. "SYNTHESIS AND CHARACTERIZATION OF COMPLEXES INVOLVING POLYAMINES AND THE METAL IONS ZINC (II), NICKEL (II) AND PALLADIUM (II)." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2010. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=16447@1.

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PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO<br>O presente trabalho descreve a síntese e a caracterização de treze complexos envolvendo as poliamina etilenodiamina, diaminopropano, diaminobutano, espermidina e espermina e os íons metálicos Zn (II), Ni (II) e Pd (II). Todas as sínteses foram realizadas em água, um solvente de importância biológica, e em condições próximas às fisiológicas, com o objetivo de mimetizar as ligações e compreender como ocorre a interação das poliaminas com ânions no ciclo biológico, haja vista que em pH fisiológico essas moléculas se encontram primordialmente n

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15

Steinborn, Martin [Verfasser]. "Coordination Chemistry of Sugar-Phosphate Complexes with Palladium(II), Rhenium(V) and Zinc(II) / Martin Steinborn." München : Verlag Dr. Hut, 2013. http://d-nb.info/1042878439/34.

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16

Vieira, Lígia Maria Mendonça. "“Síntese e caracterização de complexos de paládio(II), platina(II), zinco(II) e cobre(II) com ligantes do grupo das fluorquinolonas”." Universidade Federal de Juiz de Fora (UFJF), 2007. https://repositorio.ufjf.br/jspui/handle/ufjf/3290.

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Submitted by isabela.moljf@hotmail.com (isabela.moljf@hotmail.com) on 2017-02-10T14:08:37Z No. of bitstreams: 1 ligiamariamendonçavieira.pdf: 853219 bytes, checksum: 8557fdfc34277e259c221b21a42e75a6 (MD5)<br>Approved for entry into archive by Adriana Oliveira (adriana.oliveira@ufjf.edu.br) on 2017-02-13T16:43:00Z (GMT) No. of bitstreams: 1 ligiamariamendonçavieira.pdf: 853219 bytes, checksum: 8557fdfc34277e259c221b21a42e75a6 (MD5)<br>Made available in DSpace on 2017-02-13T16:43:00Z (GMT). No. of bitstreams: 1 ligiamariamendonçavieira.pdf: 853219 bytes, checksum: 8557fdfc34277e259c221b21a42e75a

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Fonseca, David Edson Pedrosa. "Estudo computacional de complexos mononucleares de cobre (II) e zinco (II) com ligantes triazólicos." reponame:Repositório Institucional da UFSC, 2013. https://repositorio.ufsc.br/handle/123456789/106954.

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Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-Graduação em Química, Florianópolis, 2013.<br>Made available in DSpace on 2013-12-05T22:50:13Z (GMT). No. of bitstreams: 1 318433.pdf: 7855620 bytes, checksum: 24eaf8e2a28649c3bb88fdfcfd002fec (MD5) Previous issue date: 2013<br>Neste trabalho foram estudados complexos mononucleares de cobre(II) ou zinco(II) coordenados a ligantes triazólicos contendo anéis do tipo 1,2,3- e 1,2,4-triazol. O presente trabalho é baseado em métodos teóricos de estrutura eletrônica enraizados

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18

de, Rosales R. T. M. "Zinc(II) complexes with internal hydrogen bonding interactions : towards more efficient synthetic nucleases." Thesis, University of Edinburgh, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.649255.

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A series of zinc(II) complexes of tripodal ligands resembling the catalytic zinc sites of nucleases have been synthesised and fully characterised. Some of these complexes were used to explore strategies to induce the hydrogen bond interactions that influence the catalytic performance of nucleases, and to investigate the factors that affect their strength. X-ray diffraction, NMR and IR studies revealed the formation of hydrogen bonding interactions between amide/amine groups and other zinc-bound ligands both in solution and in the solid state. We have been able to estimate the energies of these

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Salvagni, Emiliano. "Mononuclear zinc(II) complexes with intramolecular hydrogen bonding interactions as models of peptidases." Thesis, University of Edinburgh, 2005. http://hdl.handle.net/1842/11359.

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As an approach to explore the amide cleavage reaction, we designed, synthesised, fully characterised and investigated different model systems resembling the catalytic zinc sites of peptidases. The models are mononuclear zinc(II) complexes containing the unit (6-NHR-2-pyridylmethyl)amine (R = CO<sup>t</sup>But, H) as a common feature. This unit supplies an N2 coordination motif and an intramolecular amide oxygen capable of binding the metal ion (Zn<sup>…</sup>O=C(amide)); such event has been proposed to be crucial for the cleavage of peptide bonds in peptidases. Besides, these models offer diff

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20

Ydi, Simone Jaconetti. "Determinação espectrofotométrica de cobalto na presença de zinco, manganês e níquel." Universidade de São Paulo, 1994. http://www.teses.usp.br/teses/disponiveis/46/46133/tde-06112009-141955/.

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O ion Co2+, quando coordenado com ligante bipiridina (bipy), pode ser reduzido por ataque químico de redutores fortes, como NaBH4 (boroidreto de sódio), formando [Co(I) (bipy)3]+, azul. Este complexo pode ser determinado espectrofotometricamente por conferir um espectro na região do visível com λmax = 600 nm (ε = 5,8x103 L.mol-1 .cm-1). Somente cobalto estabiliza-se na forma de [M(i)(bipy)3]+, enquanto que outros metais como Mn, Ni e Zn reduzem-se ao estado metálico. A estabilização do NaBH4 foi conseguida em DMF (N,N´-dimetilformamida). Foi utilizado o método da adição de padrão, c

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21

Lin, Yongyue, and 林勇躍. "Luminescent platinum(II), copper(I), silver(I) and zinc(II) complexes with functional pyridyl and arylacetylide ligands: structures, spectroscopic properties and applications." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2001. http://hub.hku.hk/bib/B31243381.

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22

Lin, Yongyue. "Luminescent platinum(II), copper(I), silver(I) and zinc(II) complexes with functional pyridyl and arylacetylide ligands : structures, spectroscopic properties and applications /." Hong Kong : University of Hong Kong, 2001. http://sunzi.lib.hku.hk/hkuto/record.jsp?B25155325.

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23

FERRARO, VALENTINA. "Synthesis, characterization and photophysical properties of first-row transition metal complexes." Doctoral thesis, Università degli Studi di Trieste, 2023. https://hdl.handle.net/11368/3041032.

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Abstract According to Horizon 2020, Europe's photonics industry is strong (e.g. in laser-based manufacturing, medical photonics, sensing, lighting) and has the possibility to exploit new emerging market opportunities. Advanced lighting technology includes the use of Solid State Lighting (SSL) based on organic light-emitting diodes (OLEDs). The advantages involve higher quality lighting in terms of energy efficiency, quality (robustness, longer lifetime, colour tunability), and therefore cost reduction and energy saving. Lighting represents around 19% of electricity consumption worldwide and th

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24

Rodopoulos, Theo. "An equilibrium and kinetic study of cryptand, lariat ether and fluorescent zinc (II) complexes /." Title page, contents and abstract only, 1993. http://web4.library.adelaide.edu.au/theses/09PH/09phr695.pdf.

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Torres, Martin de Rosales Rafael. "Mononuclear zinc(II) complexes with intramolecular hydrogen bonding interactions : towards more efficient synthetic nucleases." Thesis, University of Edinburgh, 2005. http://hdl.handle.net/1842/14558.

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26

Brooks, Anthony. "The Photon Driven Reduction of Zn(II) to Zinc Metal by Transition Metal Complexes." Research Showcase @ CMU, 2014. http://repository.cmu.edu/dissertations/1048.

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The photon driven reduction of Zn(II) to zinc metal is a novel field of study with many potential applications including the use of zinc metal as a solar fuel. Although it has not been widely considered for such a role in the past, zinc is an appealing means to store solar energy as a stable fuel without the safety risks of hydrogen gas. As a solar fuel, zinc metal would be used in efficient zinc air batteries and then regenerated by the photocatalytic reduction of Zn(II) and a concurrent oxidation reaction. In this vein, this work reports the photocatalytic reduction of Zn(II) to zinc metal u

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27

Steinborn, Martin Verfasser], and Peter [Akademischer Betreuer] [Klüfers. "Coordination chemistry of sugar-phosphate complexes with palladium(II), rhenium(V) and zinc(II) / Martin Steinborn. Betreuer: Peter Klüfers." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2013. http://d-nb.info/1043906479/34.

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28

Malatji, Peter. "Studies towards degradable polymers new zinc (II) and palladium (II) complexes as catalysts for lactide polymerization and carbon monoxide." Doctoral thesis, University of Cape Town, 2012. http://hdl.handle.net/11427/11137.

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Includes abstract.<br>Includes bibliographical references.<br>In this study a range of new zinc and palladium complexes were synthesized, characterized and used in the production of degradable polymers. Zinc complexes were used for the production of polylactides (PLAs) functionalized with a drug candidate on a polymer tail. These functionalized polymers displayed slow drug release properties under physiological conditions. Palladium complexes were utilized for the production of a photodegradable CO/styrene copolymer (CP) which was subsequently reacted with lactide to form a new poly(lactide-co

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29

Gajda, Tamas Pal. "Équilibres et structure des complexes de métaux de transition avec des peptidoamines contenant l'histamine." Nancy 1, 1993. http://www.theses.fr/1993NAN10141.

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Nous avons synthétisé de nouvelles molécules pseudo-peptidiques a base d'histamine: -alanyl-histamine, glycyl-histamine, sarcosyl-histamine etglycyl-glycyl-histamine. Les études cristallographique, RMN solide et liquide de ces molécules sous forme de chlorhydrates ont été réalisées. L'utilisation des différentes techniques (ph-métrie, rmn #1h, #1#3c et #1#4n) nous a offert la possibilité d'étudier la protonation, micro-protonation et le tautomerisme des produits synthétisés. La complexation des ligands avec les ions cobalt(II), nickel(II), cuivre(ii) et zinc(II) a été examinée. La richesse des

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Anselmo, Daniele. "Lewis acidic zn(ii) schiff base complexes in homogeneous catalysis." Doctoral thesis, Universitat Rovira i Virgili, 2013. http://hdl.handle.net/10803/127634.

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El trabajo descrito en esta tesis muestra estudios hacia nuevas aplicaciones de complejos derivados de bases de Schiff en catálisis homogénea. En concreto, se han investigadoligandos “salen” (incluyendo sistemas quelantes N2S2) ytambiénse han examinado otros aspectos que generalmente se consideran importantes en el contexto del aumento de la sostenibilidad de los procesos químicos. Estudios sobre el uso de estos compuestos acidos de Lewis en la catálisis de la fijación de dióxido de carbono, de reacciones de múltiples componentespara obtener indoles sustituidos y de reciclado de agregados supr

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Marques, Elizabete. "Proprietes complexantes de nouveaux recepteurs moleculaires : catenands et calixarenes fonctionnalises." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13105.

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Proprietes complexantes des coordinats : cat-30, de son motif constitutif m-30, de dimethyl-2,9 phenanthroline-1. 10 et de di(p-anasyl-)2,9 phenantroline-1. 10, vis a vis de cu**(+), ag, li, zu, cd. On etudie egalement les derives de calixarenes comportant des groupes ester ou cetone sur les o phenoliques-meres

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Bispo, Júnior Walfrido. "Estudo da atividade antinoceptiva e anti-inflamatoria protótipos de fármacos." Universidade Federal de Alagoas, 2013. http://www.repositorio.ufal.br/handle/riufal/3551.

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This work was conducted to evaluate the activity anti-inflammatory and antinocieptive two series of derivatives of N-acilidrazonas (NAH) rationally designed and synthesized by LASSBio® UFRJ. The first series consists of four compounds, being two metal complexes generated from the coordination of prototypes LASSBio-1064 and LASSBio-466 and second prototype LASSBio-1064 and LASSBio-466. The second series comprised eight derivatives, designed as structural analogues of piroxicam. Were performed nociception models of functional chemical (writhing induced by acetic acid 0.1 N, formalin test), therm

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Yuen, Lao-Duien. "Part I. Studies involving the formation of pyridoxamine-5'-phosphate Schiff bases and their zinc(II) complexes ; Part II. Activity of partly metallated polymer in the decarboxylation of oxalacetic acid /." The Ohio State University, 1985. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487262825075348.

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Pankhurst, James Richard. "Complexes of Schiff-base macrocycles and donor-expanded dipyrrins for catalysis and uranyl reduction." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/28887.

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The modern world faces a number of challenges related to energy and the environment. Atmospheric levels of carbon dioxide have now surpassed the 400 ppm mark due to the burning of fossil fuels, yet despite its abundance and potential use as a C1 feedstock for value-added products, there are both thermodynamic and kinetic barriers associated with the strong carbon-oxygen bonds that preclude its widespread deployment in industry. Nuclear energy is an alternative power source that reduces carbon emissions by billions of tonnes each year, but there are widespread concerns regarding the treatment o

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Thomson, Peter. "Studies of the different effects of zinc(II) ions and complexes on the activity of inositol lipid phosphatases." Thesis, Imperial College London, 2016. http://hdl.handle.net/10044/1/45284.

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The 5’-phosphatases are a family of metalloenzymes involved in the regulation of phosphoinositide signalling in cells and also implicated in diseases such as cancer, diabetes and neurodegenerative disorders. Even so,only a handful of modulators have been reported to target these enzymes. In this thesis,efforts towards the design of zinc(II)complexes for 5’-phosphatase inhibition are described with further analysis of the interaction between these enzymes and zinc(II). The validation of previous reports that zinc(II) can inhibit the 5’-phosphatases is described and, alongside published evidence

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Klitzke, Joice Sandra. "Complexos de zinco(II) contendo ligantes hidrotris(pirazolil)borato altamente impedidos : síntese, reatividade e estrutura no estado sólido." reponame:Biblioteca Digital de Teses e Dissertações da UFRGS, 2009. http://hdl.handle.net/10183/172772.

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A química de coordenação e reatividade dos complexos de zinco(II) contendo ligantes mono aniônicos hidrotris(pirazolil)borato substituídos por grupos 3,3,3 - mesitil (TpMs) e 3,3,5 - mesitil (TpMs*) foram investigadas. A metátese dos sais Tl[TpMs] ou Tl[TpMs*] com ZnCl2, ZnEt2, e Zn(OAc)2 permitiu a formação dos compostos correspondentes puros TpMsZnCl, TpMsZnEt, TpMs*ZnEt e TpMsZnOAc. O composto TpMs*ZnEt, lentamente, desproporcionou-se em solução de benzeno para produzir o complexo bis(ligante) (k²-TpMs*)2Zn. Alternativamente, o complexo TpMsZnOAc, como também TpMsZnOCOPh e [TpMs*ZnOAc]2 for

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Bhuyan, Mouchumi [Verfasser], and Burkhard [Akademischer Betreuer] König. "Synthesis and exploration of functionalized Zinc(II) and Terbium(III) complexes as molecular probes / Mouchumi Bhuyan. Betreuer: Burkhard König." Regensburg : Universitätsbibliothek Regensburg, 2012. http://d-nb.info/1035808374/34.

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Yunus, Sami. "Spectroscopie de fluorescence du 9-(1', 4', 7', 10', 13'-pentaazacyclopentadécyl)méth ylanthracène et de ses complexes du cadmium (II) et du zinc (II) :apport des outils d'analyse multivariée." Doctoral thesis, Universite Libre de Bruxelles, 2002. http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/211463.

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Oliveri, Ivan Pietro. "Zinc(II) Schiff Base Complexes and their Aggregation/Deaggregation Properties: Versatile and Multifunctional Materials as Chemosensors and Building Blocks for New Supramolecular Architectures." Doctoral thesis, Università di Catania, 2013. http://hdl.handle.net/10761/1292.

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In this PhD thesis the synthesis, characterization, and study of the aggregation/deaggregation properties of a series of amphiphilic bis(salicylaldiminato)ZnII Schiff base complexes, involving different bridging diamino groups, and their applications as molecular probes, nonlinear optical (NLO) and vapochromic materials, as well as synthons for the formation of new fibrillar and branched supramolecular nanostructures, are reported. Through detailed 1H NMR, DOSY NMR and optical spectroscopic studies, it is found that these species always form aggregates in solution of non-coordinating solvents

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NOGUEIRA, VANESSA DE SOUZA. "SYNTHESIS AND CHARACTERIZATION OF PARA-SUBSTITUTED DI-HYDRAZONES AND SOME OF THEIR DINUCLEAR ZINC(II) COMPLEXES AS POTENTIAL ENTRY INHIBITORS FOR THE TREATMENT OF HIV/AIDS." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2016. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=27522@1.

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PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO<br>COORDENAÇÃO DE APERFEIÇOAMENTO DO PESSOAL DE ENSINO SUPERIOR<br>PROGRAMA DE SUPORTE À PÓS-GRADUAÇÃO DE INSTS. DE ENSINO<br>A Síndrome da Imunodeficiência Adquirida (SIDA/AIDS) é causada pelo HIV. De uma forma geral, o HIV é um retrovírus que ataca o sistema imunológico, principalmente os linfócitos T auxiliares (também chamados de linfócitos T4 ou T CD4+), que normalmente se encontram na corrente sanguínea e são responsáveis por toda a coordenação da defesa imunológica do organismo. Muitas estratégias de tratamento estão sendo desenvolvidas

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Diantouba, Bertin Aimé. "Effets structuraux des acyl-4-pyrazolones-5 dans l'extraction liquide-liquide des cations metalliques divalents." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13093.

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Etude de l'effet de l'acidite de la lipophilie et effets structuraux des acyl-4 pyrazolones-5 dans l'extraction de cu, co, zu et pb divalents. Extraction de 3 types de complexes metalliques : mononucleaires de type m(l-n-lh)::(2) ou m(l-n-l) et polynucleaires (m(l-n-l))::(j). Meilleures possibilites des bis-acyl-4 pyrazolones-5

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Baltas, Michel. "Sulfinamides fonctionnalises inhibiteurs de la coniferylalcool deshydrogenase : synthese, etude de complexation par l'ion zn**(2+), mecanisme d'hydrolyse basique et aminolyse des sulfinamoyl acetates : schema d'inactivation enzymatique via un intermediaire sulfine." Toulouse 3, 1987. http://www.theses.fr/1987TOU30145.

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Coleman, Hilary Ceywood. "An investigation of transition metal complex chemistry: enzyme mimicry and Zn(II) detection." Thesis, 2015. http://hdl.handle.net/2440/98730.

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This thesis presents research in the field of transition metal complex chemistry. The major project, reported in Part I, is focussed on the mimicking of enzymes in order to produce simple catalyst molecules that enhance the rate of ester hydrolysis. This work involved a systematic characterisation of a suite of potential enzyme mimics which were based on the simple template molecules tris(2-aminoethyl)amine (tren) and 1,4,7-triazacyclononane (tacn). The effects of substituting tren and tacn with methyl groups and β-cyclodextrin and then complexing these with Zn²⁺, Cu²⁺, Cd²⁺ and Ni²⁺ were exam

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"Oligo(phenylene-vinylene) terpyridine ligands and their ruthenium(II), platinum(II) and zinc(II) complex systems: Synthesis, photophysical and photochemical properties." Tulane University, 2004.

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Polypyridine d6 and d8 transition metal complexes have received a great deal of attention because of their wide applications in various areas such as photo-induced energy- and electron-transfer process, artificial photosynthetic centers, electroluminescent displays, dye-sensitized solar cell, and molecular-level machines, etc Compared to 2, 2'-bipyridine-type complexes, 2, 2':6', 2″-terpyridine(tpy)-type complexes have been much less thoroughly examined, because the weak ligand field of tpy-type ligands results in the weak emissive and short-lived excited states of their complexes. Howev

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Yang, Meng-Yin. "Mechanistic studies for transesterification of RNA analogues catalyzed by a dinuclear zinc(II) complex." 2007. http://proquest.umi.com/pqdweb?did=1240709881&sid=10&Fmt=2&clientId=39334&RQT=309&VName=PQD.

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Thesis (Ph.D.)--State University of New York at Buffalo, 2007.<br>Title from PDF title page (viewed on July 12, 2007) Available through UMI ProQuest Digital Dissertations. Thesis adviser: Morrow, Janet R. Includes bibliographical references.

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葉國良. "I. Ruthenium and Zinc Complex Catalyzed Reactions from Propargyl Derivatives II. Disc Molecules in Polarizer ― Synthesis and Physical Properties." Thesis, 2005. http://ndltd.ncl.edu.tw/handle/30146174210943065190.

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博士<br>國立清華大學<br>化學系<br>93<br>Abstract Organometallics plays an essential role on organic synthesis in these decades. It was applied in coupling reactions, cyclization reactions or ring opening reactions. Organometallics catalyzed reactions not only have good regioselectivities but have good stereoselectivities. In natural products synthesis, it is very important to control stereo or regio direction in specific positions. We emphasize on ruthenium and zinc metal complex which apply in ethynyl alcohol catalyzed transfer reactions. First, ruthenium complex was applied on transformation of propar

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吳姿萱. "Synthesis and characterization of Iron (III) complex with aromaticity-functionlized N2S3 ligand and Synthesis and characterization of Mercury (II) and Zinc (II) complexes with 1,3,5-triethyl-2,4-bis(2-mercaptoanilinyl[1]methyl)benzene." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/79421157144339124300.

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Almaraz, Elky. "The Interactions of Zinc Thiolate Complexes and Exogenous Metal Species: Investigations of Thiolate Bridging and Metal Exchange." 2009. http://hdl.handle.net/1969.1/ETD-TAMU-2009-05-536.

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Small molecule Zn(II) complexes containing N- and S- donor environments may serve as appropriate models for mimicking Zn protein sites, and thus, their reactions with heavy metal ions such as Pt(II) and W(0) may provide insight into possible adduct formation and zinc displacement. To study such possible interactions between zinc finger proteins and platinum-bound DNA, the ZnN2S2 dimeric complex, N,N?-bis(2- mercaptoethyl)-1,4-diazacycloheptane zinc (II), [Zn-1?]2, has been examined for Znbound thiolate reactivity in the presence of Pt(II) nitrogen ? rich compounds. The reactions yielded Zn/Pt

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劉公典. "Solvent extraction studies on PAN complexes of Zinc (II) and Cadmium (II) with flow injection analysis." Thesis, 1987. http://ndltd.ncl.edu.tw/handle/78322574092645494568.

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You, Jyun-Siang, and 游竣翔. "Synthesis of Ruthenium(II) Complexes Containing Dialkyl Diselenophosphate Ligands and Luminescent Zinc(II) complexes Incorporating Selenium/Sulfur and Nitrogen Donor Ligands." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/55619626707819579364.

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