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Journal articles on the topic 'Zinc metal battery'

Author: Grafiati
Published: 6 September 2023
Last updated: 31 July 2025

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1

Shao, Aiquan, Wenhao Zhang, Jiangyong Liu, et al. "Progress on the Application of Modified Anode Materials for Aqueous Zinc Ion Batteries." International Journal of Materials Science and Technology Studies 2, no. 3 (2024): 62–72. https://doi.org/10.62051/ijmsts.v2n3.09.

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In the current developed electrochemical energy storage device system, drainage zinc ion batteries have attracted wide attention due to their safe operation, environmental friendliness and high theoretical specific capacity. However, when applied to the anode of drainage zinc ion batteries, uneven zinc deposition leads to the formation and growth of zinc dendrite, piercing the diaphragm and causing a short circuit in the battery. Zinc dendrites have mechanical rigidity and structural inhomogeneity, which is easy to fall off from the zinc negative electrode to form "dead zinc", leading to the r
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2

Huang, Qian, Shuxian Zhuang, Xin You, et al. "Honeycomb-like carbon with doping of a transition-metal and nitrogen for highly efficient zinc–air battery and zinc-ion battery." Sustainable Energy & Fuels 6, no. 1 (2022): 188–96. http://dx.doi.org/10.1039/d1se01427g.

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The hierarchical honeycomb-like transition-metal/nitrogen co-doped carbon materials were fabricated, and they acted as highly efficient electrocatalysts for the cathode of a zinc–air battery and the anode of a zinc-ion battery.
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3

Sim, Wei Jian, Mai Than Nguyen, and Tetsu Yonezawa. "Noble-Metal Free Zinc-Air Battery Catalysts." Journal of the Japan Institute of Metals and Materials 88, no. 8 (2024): 137–43. http://dx.doi.org/10.2320/jinstmet.j2023039.

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4

Okobira, Tatsuya, Dang-Trang Nguyen, and Kozo Taguchi. "Effectiveness of doping zinc to the aluminum anode on aluminum-air battery performance." International Journal of Applied Electromagnetics and Mechanics 64, no. 1-4 (2020): 57–64. http://dx.doi.org/10.3233/jae-209307.

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Many efforts have been devoted to the improvement of metal-air batteries. Aluminum (Al) is the most abundant metal in the Earth’s crust and has high electrochemical potential. Therefore, the aluminum-air battery is one of the most attractive metal-air batteries. To overcome some disadvantages of the aluminum-air battery, some alloys of aluminum and several metals have been proposed. In this study, the performance improvement of the aluminum-air battery by doping zinc (Zn) to the aluminum anode was investigated. Zinc was doped to aluminum by a simple process. The difference in the characteristi
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5

Andrade, Tatiana S., Antero R. S. Neto, Francisco G. E. Nogueira, Luiz C. A. Oliveira, Márcio C. Pereira, and Panagiotis Lianos. "Photo-Charging a Zinc-Air Battery Using a Nb2O5-CdS Photoelectrode." Catalysts 12, no. 10 (2022): 1240. http://dx.doi.org/10.3390/catal12101240.

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Integrating a photoelectrode into a zinc-air battery is a promising approach to reducing the overpotential required for charging a metal-air battery by using solar energy. In this work, a photo-fuel cell employing a Nb2O5/CdS photoanode and a Zn foil as a counter-electrode worked as a photoelectrochemical battery that saves up to 1.4 V for battery charging. This is the first time a Nb2O5-based photoelectrode is reported as a photoanode in a metal-air battery, and the achieved gain is one of the top results reported so far. Furthermore, the cell consumed an organic fuel, supporting the idea of
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6

Zhang, Emma Qingnan, and Luping Tang. "Rechargeable Concrete Battery." Buildings 11, no. 3 (2021): 103. http://dx.doi.org/10.3390/buildings11030103.

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A rechargeable cement-based battery was developed, with an average energy density of 7 Wh/m2 (or 0.8 Wh/L) during six charge/discharge cycles. Iron (Fe) and zinc (Zn) were selected as anodes, and nickel-based (Ni) oxides as cathodes. The conductivity of cement-based electrolytes was modified by adding short carbon fibers (CF). The cement-based electrodes were produced by two methods: powder-mixing and metal-coating. Different combinations of cells were tested. The results showed that the best performance of the rechargeable battery was the Ni–Fe battery, produced by the metal-coating method.
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7

Phuc, Nguyen Huu Huy, Tran Anh Tu, Luu Cam Loc, et al. "A Review of Bifunctional Catalysts for Zinc-Air Batteries." Nanoenergy Advances 3, no. 1 (2023): 13–47. http://dx.doi.org/10.3390/nanoenergyadv3010003.

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Zinc–air batteries are promising candidates as stationary power sources because of their high specific energy density, high volumetric energy density, environmental friendliness, and low cost. The oxygen-related reactions at the air electrode are kinetically slow; thus, the air electrode integrated with an oxygen electrocatalyst is the most critical component, and inevitably determines the performance of a Zn–air battery. The aim of this paper was to document progress in researching bifunctional catalysts for Zn–air batteries. The catalysts are divided into several categories: noble metal, met
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8

Zhang, Ruizhi. "Comprehensive Evaluation and Analysis of New Batteries." MATEC Web of Conferences 386 (2023): 03007. http://dx.doi.org/10.1051/matecconf/202338603007.

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New batteries are the mainstream of battery development, and many industries cannot live without new batteries. Most of the new batteries do not pollute the environment and exceed traditional batteries in terms of energy efficiency and charge and discharge times. This paper mainly introduces solid battery, metal battery, sodium ion battery, lithium sulfur battery, fuel cell and nickel-metal hydride battery. In addition, the new battery is compared with the traditional batteries represented by lead-acid batteries, zinc-manganese batteries, zinc-air batteries, zinc-silver batteries, zinc-mercury
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9

Mathialagan, Kowsalya, Saranya T, Ammu Surendran, Ditty Dixon, Nishanthi S.T., and Aiswarya Bhaskar. "(Digital Presentation) Development of Bifunctional Oxygen Electrocatalysts for Electrically Rechargeable Zinc-Air Batteries." ECS Meeting Abstracts MA2022-02, no. 4 (2022): 403. http://dx.doi.org/10.1149/ma2022-024403mtgabs.

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Zinc-air battery is a promising battery system as it possesses high theoretical energy density and is cost-effective3. The theoretical energy density of a Zinc-air battery is 1086 Wh kg-1, which is five times greater than that of lithium-ion batteries2. Moreover, zinc metal is one of the most abundant metals in the earth’s crust and is inexpensive. Rechargeable metal-air batteries operate based on two fundamental electrochemical reactions as Oxygen Reduction Reaction (ORR) during discharge and Oxygen Evolution Reaction (OER) during recharge processes, respectively3. Electrocatalytic activity o
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10

Kheawhom, Soorathep, and Sira Suren. "Printed air cathode for flexible and high energy density zinc-air battery." MRS Advances 1, no. 53 (2016): 3585–91. http://dx.doi.org/10.1557/adv.2016.443.

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ABSTRACTFlexible zinc-air batteries were fabricated using an inexpensive screen-printing technique. The anode and cathode current collectors were printed using commercial nano-silver conductive ink on a polyethylene terephthalate (PET) substrate and a polypropylene (PP) membrane, respectively. Air cathodes made of blended carbon black with inexpensive metal oxides including manganese oxide (MnO2) and cerium oxide (CeO2), were studied. The presence of the metal oxides in the air cathodes enhanced the oxygen reduction reaction which is the most important cathodic reaction in zinc-air batteries.
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11

Kim, Sun, Hee Jae Kim, Kwang Heo, Jae-Hong Lim, Hitoshi Yashiro, and Seung-Taek Myung. "Nature of Zinc-Derived Dendrite and Its Suppression in Mildly Acidic Aqueous Zinc-Ion Battery." ECS Meeting Abstracts MA2023-01, no. 5 (2023): 906. http://dx.doi.org/10.1149/ma2023-015906mtgabs.

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Aqueous zinc-ion batteries (ZIBs) are attractive in energy storage due to the use of aqueous electrolytes that ensures safety and ease of handling all parts in air. However, catastrophic zinc dendritic growth on zinc metal anode impedes their practical application. Herein, we introduce Zn3(PO4)3·4H2O (ZP)-coated zinc metal anode, to effectively suppress the dendrite growth and first elucidate the chemical state of dendrite that is composed of metallic Zn0, ZnO, and Zn(OH)2. Significant improvement is observed for the ZP-coated zinc metal symmetric cell. Operando synchrotron tomography demonstr
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12

Satchidhanandam, Kalaiarasi, Edward P. L. Roberts, and Mayank Sabharwal. "Developing a Suspended Zinc Electrolyte System for Zinc-Based Flow Batteries." ECS Meeting Abstracts MA2025-01, no. 45 (2025): 2375. https://doi.org/10.1149/ma2025-01452375mtgabs.

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Zinc-based flow batteries such as the zinc-iodide flow battery represent a promising solution for large-scale stationary energy storage, offering high energy density (160–200 Wh/L), cost-effectiveness, scalability, and safety compared to traditional vanadium redox flow batteries (30–50 Wh/kg) and lithium-ion batteries (250–300 Wh/kg) [1] . However, challenges such as zinc dendrite formation, low operating current density, and limited areal capacity hinder the efficiency and long-term performance of zinc-based flow batteries [2] . Current strategies for mitigating dendrites involve electrode mo
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13

Yu, Jingya, and Zheng-Long Xu. "Heterointerfaces Chemistry of Transition Metal-Shielded Zinc Anode for High-Performance Aqueous Zinc Batteries." ECS Meeting Abstracts MA2024-01, no. 5 (2024): 756. http://dx.doi.org/10.1149/ma2024-015756mtgabs.

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Aqueous zinc metal batteries confront impediments such as severe side reactions and dendrite formation on the zinc metal anode, impeding its commercialization. Although various metals and zinc-metal alloys aim to optimize the zinc anode, the preferential order and reaction mechanisms at the metal/electrolyte interface remain unclear. Here, we utilized magnetron sputtering to create nanolayered metal coatings (Cu, Ti, Ag, Au, Al) on the zinc surface. Notably, the Cu@Zn anode exhibited moderate binding energy with Zn atoms and lower nucleation overpotential than bare Zn, resulting in excellent c
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14

Liu, Jinglin, Lina Han, Shicai Xiao, et al. "Metal–Organic-Framework-Derived Nitrogen-Doped Carbon-Matrix-Encapsulating Co0.5Ni0.5 Alloy as a Bifunctional Oxygen Electrocatalyst for Zinc–Air Batteries." Materials 17, no. 11 (2024): 2629. http://dx.doi.org/10.3390/ma17112629.

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The development of low-cost, high-performance oxygen electrocatalysts is of great significance for energy conversion and storage. As a potential substitute for precious metal electrocatalysts, the construction of efficient and cost-effective oxygen electrocatalysts is conducive to promoting the widespread application of zinc–air batteries. Herein, CoxNiyMOF nanoparticles encapsulated within a carbon matrix were synthesized and employed as cathode catalysts in zinc–air batteries. Co0.5Ni0.5MOF exhibits superior oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) performance and
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15

Madan, Chetna, and Aditi Halder. "Nonprecious Multi-Principal Metal Systems As the Air Electrode for a Solid-State Rechargeable Zinc-Air Battery." ECS Meeting Abstracts MA2022-02, no. 64 (2022): 2327. http://dx.doi.org/10.1149/ma2022-02642327mtgabs.

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Zinc-air battery technology is gaining recognition as a promising energy storage device to be used in portable electronics and electric vehicles. Despite possessing high theoretical energy density, environmental and operational safety, and easy accessibility of zinc reservoirs, the successful commercialization of zinc-air batteries suffers due to the poor oxygen electrocatalysis kinetics at the air cathode. The kinetically inept oxygen reduction and oxygen evolution reactions at the cathode lead to a large overpotential barrier and poor charge-discharge cyclic performance of the rechargeable z
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16

Xu, Xiaoyun, Songmei Li, Huibo Yan, Juan Du, Shubin Yang, and Bin Li. "Manipulating underpotential deposition nucleation of zinc deposition towards high-stable zinc metal battery." Journal of Energy Storage 72 (November 2023): 108625. http://dx.doi.org/10.1016/j.est.2023.108625.

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17

Ma, Nengyan, Peijun Wu, Yixue Wu, Donghao Jiang, and Gangtie Lei. "Progress and perspective of aqueous zinc-ion battery." Functional Materials Letters 12, no. 05 (2019): 1930003. http://dx.doi.org/10.1142/s1793604719300032.

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Aqueous zinc-ion batteries (ZIBs) as a new battery technology have received great attention due to the high energy and power density, low cost, high safety and environmental friendliness. However, their practical deployment has been restricted by some serious issues such as corrosion of zinc metal anode in aqueous electrolyte, undesired growth of zinc dendrites, and hydrogen evolution from the water splitting. Therefore, tremendous efforts have been devoted to mitigate these issues and significant progresses have been achieved. In this paper, we review some key recent progresses of aqueous ZIB
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18

Matthews, Kyle. "2023 H. H. Uhlig Fellowship Research Fellowship – Summary Report: Zinc Plating on Ti3C2T x MXene Characterized through in-situ Optical Microscopy and UV-Vis Spectroscopy." Electrochemical Society Interface 32, no. 4 (2023): 39–40. http://dx.doi.org/10.1149/2.f06234if.

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Zinc metal batteries are promising candidates for multiple energy storage applications. Zinc dendrite formation is one of the major factors inhibiting their implementation, and multiple directions have been explored to mitigate this. MXenes are 2D transition metal carbides with the structure Mn+1XnTx. MXenes have high conductivity with hydrophilic, redox-active terminations, which makes them prime candidates in energy storage applications. MXenes (mainly Ti3C2Tx) have established use in Zn battery dendrite suppression as a coating on the Zn metal or an electrolyte additive. There is considerab
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19

Jeong, Minji, Jaehong Lim, and Si Hyoung Oh. "Safe Solvent-in-Salt Electrolytes for Dendrite-Free Zinc Metal Batteries." ECS Meeting Abstracts MA2023-02, no. 4 (2023): 614. http://dx.doi.org/10.1149/ma2023-024614mtgabs.

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As global markets for electric vehicles (EV) and energy storage systems (ESS) expand rapidly, there are growing needs to develop alternative battery systems to replace current lithium-ion battery (LIBs) technology, which suffers from high material cost, and insufficient safety. Rechargeable zinc batteries have emerged as one of the most viable and sustainable candidates to replace LIB owing to various beneficial features of zinc such as natural abundance, easy recyclability (by electrowinning), high safety and high volumetric capacity (5,854 Ah/L) compared with lithium (2,062 Ah/L). However, p
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20

Vacandio, Florence, Philippe Knauth, Papa-kwakye Kwarteng, Luca Pasquini, and Suanto Syahputra. "Zinc Anodes with Electrodeposited Ionomer Protection Layer for Rechargeable Zinc-Air Batteries." ECS Meeting Abstracts MA2023-01, no. 5 (2023): 905. http://dx.doi.org/10.1149/ma2023-015905mtgabs.

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Metal air batteries are assembled from a metal anode and a porous cathode in a suitable electrolyte. They combine the design of fuel cells and conventional batteries and have been demonstrated to have large theoretical energy densities higher compared to devices based on Li-ion chemistry, due to the ability to use air at the cathode and to exchange two electrons per zinc atom. ZAB represent a safe, environmentally benign, affordable and simple way to store and deliver electrical energy for a wide variety of devices. However, research efforts are necessary to increase the efficiency of recharge
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21

Wang, Shurui. "Research Status and Optimization Methods of Zinc Ion Battery." MATEC Web of Conferences 382 (2023): 01015. http://dx.doi.org/10.1051/matecconf/202338201015.

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Up against the energy shortage and aggravating environmental pollution, it is extremely urgent to develop renewable clean energy. With efficient energy storage and energy conversion, electrochemical energy storage is the key direction for the development of energy storage technology in the future. Besides, aqueous zinc ion battery has attracted researchers because of its low cost and high theoretical specific capacity. Cathode materials for aqueous zinc ion batteries are roughly divided into manganese-based compounds, vanadium-based compounds, Prussian blue analogues, etc, which usually use zi
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22

Kumar, Yedluri Anil, Shanmugam Vignesh, Tholkappiyan Ramachandran, et al. "Solidifying the future: Metal-organic frameworks in zinc battery development." Journal of Energy Storage 97 (September 2024): 112826. http://dx.doi.org/10.1016/j.est.2024.112826.

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23

Xu, Lei, Mi Yan, Xinying Wang, Wei Li, and Jinhui Peng. "The influences of silver and zinc addition on the electrochemical performances of the Pb–Ca–Sn Grids for lead acid batteries." Metallurgical Research & Technology 115, no. 6 (2018): 609. http://dx.doi.org/10.1051/metal/2018002.

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The silver and zinc addition on the electrochemical performances of the Pb–Ca–Sn Grids were investigated. The corrosion film structure, phase composition and electrochemical performances of Pb − 0.08 wt.% Ca − 1.2 wt.% Sn alloy, Pb − 0.08 wt.% Ca − 1.2 wt.% Sn − 0.03 wt.% Ag alloy and Pb − 0.08wt.% Ca − 1.2 wt.% Sn − 0.06 wt.% Zn alloy in a 1.28 g/mL of H2SO4 solution were studied by SEM observation, metallographic study, XRD, CV test and Constant DC discharge. It was found that the corrosion film of the alloy Pb – 0.08 wt.% Ca – 1.2 wt.% Sn appears as flaky crystal structure, while with the a
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Lin, Ming-Hsien, Chen-Jui Huang, Pai-Hsiang Cheng, Ju-Hsiang Cheng, and Chun-Chieh Wang. "Revealing the effect of polyethylenimine on zinc metal anodes in alkaline electrolyte solution for zinc–air batteries: mechanism studies of dendrite suppression and corrosion inhibition." Journal of Materials Chemistry A 8, no. 39 (2020): 20637–49. http://dx.doi.org/10.1039/d0ta06929a.

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We detailly reveal the effects of PEI on zinc nuclei growth and corrosion protection of zinc anode in the alkaline electrolyte solution and confirm the benefit of PEI for improving cycling stability in the practical zinc–air battery.
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25

Fayette, Matthew, Xiaolin Li, and David M. Reed. "High Performance Zinc-Based Anodes for Aqueous Zinc Batteries." ECS Meeting Abstracts MA2024-02, no. 9 (2024): 1438. https://doi.org/10.1149/ma2024-0291438mtgabs.

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In the past thirty years, there has been significant development in the search for alternative energy sources such as secondary battery systems. Zinc (fourth-most mined material) has attracted much attention due to its abundance, low-cost, and recyclability. Moreover, as zinc-based batteries can be manufactured with aqueous-based electrolytes that benefits from many advantages of Zn anode, such as low redox potential (-0.76V vs SHE), high theoretical capacity (820mAh/g), and enhanced safety. These features allow for high applicability in large-scale stationary energy storage system. Zinc-based
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Fayette, Matthew, Xiaolin Li, and David Reed. "High Performance Zinc-Based Anodes for Aqueous Zinc Batteries." ECS Meeting Abstracts MA2023-01, no. 5 (2023): 928. http://dx.doi.org/10.1149/ma2023-015928mtgabs.

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In the past thirty years, there has been significant development in the search for alternative energy sources such as secondary battery systems. Zinc (fourth-most mined material) has attracted much attention due to its abundance, low-cost, and recyclability. Moreover, as zinc-based batteries can be manufactured with aqueous-based electrolytes that benefits from many advantages of Zn anode, such as low redox protentional (-0.76V vs SHE), high theoretical capacity (820mAh/g), and enhanced safety. These features allow for high applicability in large-scale stationary energy storage system. Zinc-ba
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27

You, Seungmin, Chaeeun Kang, Jooeun Park, and Jae-Kwang Kim. "Ceramic Composite Gel Polymer Electrolyte for Aqueous Zinc-Ion Battery." ECS Meeting Abstracts MA2023-02, no. 4 (2023): 750. http://dx.doi.org/10.1149/ma2023-024750mtgabs.

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As the most extreme application of electrical energy storage devices, lithium-ion batteries (LIBs) not only have the high energy density, but also show long charge/discharge life cycles. Nevertheless, some inherent issues hinder its widespread application, such as the safety problems, lithium metal extrusion, dendrite growth, and the high cost, together with the limited resources of lithium metal. As one of the next-generation batteries, zinc-ion battery (ZIB) is a promising candidate to solve the above problems, due to their high theoretical capacity, low cost, high abundance, low potential,
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Wang, Runkang. "Controlled Construction and Properties Study of PDMS Coatings for Stabilizing Zinc Metal Anode." Highlights in Science, Engineering and Technology 21 (December 4, 2022): 286–97. http://dx.doi.org/10.54097/hset.v21i.3174.

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Polydimethylsilane (PDMS) is a promising coating material. The subject proposes a SiO2-doped PDMS coating material (defined as SO-PDMS), which is hydrophobic and can help desolvate ions in solution, regulate the electric field distribution on the electrode surface, inhibit the formation of dendrites, and reduce the side reactions such as the evolution of oxygen and hydrogen. SiO2 is rich in silanol groups, which can coordinate with zinc ions to promote the rapid transport of zinc ions and facilitate the uniform deposition of zinc ions on the anode surface. The SO-PDMS@Zn symmetric battery has
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Zhang, Duhan. "Regulating Zinc Electrodeposition on the Anode By Controlling Crystal Growth." ECS Meeting Abstracts MA2024-02, no. 22 (2024): 1902. https://doi.org/10.1149/ma2024-02221902mtgabs.

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Ensuring the reversible electrodeposition of metals at liquid-solid interfaces is crucial for the long cycle life of rechargeable batteries that employ metals as anodes. While extensive research has focused on the electrochemical transformations influencing reversibility, the fundamental hurdles related to maintaining morphological control when an intrinsically crystalline solid metal phase emerges from an electrolyte solution have received less attention. However, these challenges present significant opportunities for advancement. Here, we propose a method to stabilize crystal growth and resh
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Sohn, Jeong Soo. "Integrated management of spent zinc-carbon batteries and lithium ion batteries using innovative recycling technology." Korean Journal of Life Cycle Assessment 12, no. 1 (2011): 95–104. http://dx.doi.org/10.62765/kjlca.2011.12.1.95.

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Annually above 1 billion unit cells (15,000 tons) of spent batteries have been generated as wastes in Korea. Spent Ni-Cd batteries have been recycled but the other spent batteries did not be treated yet. So recycling processes of spent lithium-ion battery and zinc carbon battery should be developed for environmental aspect as well as the effective utility of resources. In case of spent zinc-carbon and alkaline battery, magnetic material and zinc sheet from the battery were regained by physical treatment process. A series of mechanical processing is conducted in the following sequence to yield
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Molina, Anna Shekinah, Aaron Carlo Bejarin, Yelena Evale, Angelica May Fontanilla, Carsten Althensor Requiroso, and Charisse Angelique Escobal. "Comparative Analysis of Pure and Scrap Metal Electrodes of Aluminum (Al), Zinc (Zn) and Copper (Cu) for the Development of Saline Batteries as an Alternative Power Source during Calamities." E3S Web of Conferences 624 (2025): 04002. https://doi.org/10.1051/e3sconf/202562404002.

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This study was conducted to explore the development of a cost-effective and accessible battery system that can be assembled by residents during disaster situations. Specifically, the research compared pure and scrap metals, namely Aluminum (Al), Zinc (Zn), and Copper (Cu) to evaluate the feasibility of using scrap metals as substitutes for pure metals in battery electrodes. The results indicate that the metal electrode combination (MEC) of Galvanized Copper scrap (Gal-Cuscrap) produced voltage and current outputs comparable to those generated by pure Zinc-Copper electrodes. This conclusion is
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Zhang, Pengfei, Keliang Wang, Yayu Zuo, et al. "3D Spiral Zinc Electrode for Rechargeable Aqueous Zinc-Air Battery." Journal of The Electrochemical Society, June 2, 2023. http://dx.doi.org/10.1149/1945-7111/acdafa.

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Abstract Zinc metal has emerged as seeded anode material in the field of high-efficiency aqueous metal-air battery system due to the advantages of abundant reserves, strong reversibility, and high capacity. Unfortunately, the conventional zinc electrodes commonly adopt a flat structure, and the dendrite accumulation and corrosion during the cycle process lead to sub-optimal efficiency and performance. Herein, the zinc electrode is designed as a three-dimensional (3D) spiral structure to improve the utilization efficiency of zinc and the quality of the battery. Compared with the zinc plate, the
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Bai, Youcun, Heng Zhang, Wenhao Liang, Chong Zhu, Lijin Yan, and Changming Li. "Advances of Zn Metal‐Free “Rocking‐Chair”‐Type Zinc Ion Batteries: Recent Developments and Future Perspectives." Small, October 11, 2023. http://dx.doi.org/10.1002/smll.202306111.

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AbstractAqueous zinc ion battery (AZIBs) has attracted the attention of many researchers because of its safety, economy, environmental protection, and high ionic conductivity of electrolytes. However, the battery greatly suffers from zinc dendrite produced by zinc metal anode leading to poor cycle life and even unsafe problems, which limit its further development for various important applications. It is known that the success of the commercialization of lithium‐ion batteries (LIBs) is mainly due to replacement of lithium metal anode with graphite, which avoids the formation of Li dendrite. Th
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Zhang, Wenwei, Wenhui Zhong, Junjun Wang, Qinyou An, and Liqiang Mai. "Current Challenges and Advanced Design Strategy of Vanadium Dioxide Cathode for Low‐Cost Aqueous Zinc Metal Battery." Advanced Energy and Sustainability Research, October 11, 2023. http://dx.doi.org/10.1002/aesr.202300139.

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Rechargeable aqueous zinc metal battery has been one of the next‐generation energy storage systems with a promising future due to the advantages of aqueous electrolyte and metallic zinc anode. Among many cathode materials, vanadium‐based materials with considerable specific capacity, adjustable crystal structure, and multiple valence states are very promising cathodes, but the electrochemical performance of vanadium‐based zinc metal batteries faces severe challenges such as the limited and declining capacity and sluggish ion/e− transport kinetics process. Herein, taking VO2 as an example, the
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Guo, Dongfang, Fengyu Li, and Bin Zhang. "The ZnO‐SiO2 Composite Phase with Dual Regulation Function Enables Uniform Zn2+ Flux and Fast Zinc Deposition Kinetics Toward Zinc Metal Batteries." Advanced Science, December 4, 2024. https://doi.org/10.1002/advs.202411995.

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AbstractAs an important candidate for rechargeable energy storage devices, the large‐scale development of aqueous zinc ion batteries has been hindered by hydrogen evolution and uncontrollable dendrites of metal anodes. A novel ZnO‐SiO2 composite interface phase (Zn@ZSCP) with a double protective effect based on in situ synthesis by hydrothermal method is used to improve these difficulties. The hydrophilic SiO2 layer is beneficial to the dissolution of hydrated zinc ions and reduces the nucleation barrier during zinc deposition, while the stable ZnO layer helps to adjust the electric field dist
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Sim, Wei Jian, Mai Thanh Nguyen, and Tetsu Yonezawa. "Noble-Metal Free Zinc-Air Battery Catalysts." MATERIALS TRANSACTIONS, 2023. http://dx.doi.org/10.2320/matertrans.mt-mh2022008.

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37

Devi, Meghali, Brindha Moorthy, and Ranjith Thangavel. "Recent Developments in Zinc Metal Anodes, Cathodes, and Electrolytes for Zinc-ion Hybrid Capacitors." Sustainable Energy & Fuels, 2023. http://dx.doi.org/10.1039/d3se00565h.

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The recent developments in Li-ion battery, Na-ion battery, and supercapacitors are redefining their applications in several portable and large-scale energy storage applications. However, the demand for energy storage devices with...
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Ding, Yunfang, Tongtong Zheng, Haoyu Wu, et al. "Sn Protective Layer via Electroless Manufacturing for Stable Zinc Metal Batteries." ChemistrySelect 10, no. 10 (2025). https://doi.org/10.1002/slct.202405068.

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AbstractAqueous zinc metal battery is facing the challenges of zinc dendrite growth, zinc anode corrosion, and hydrogen evolution reaction (HER). Here, we prepared an artificial interface layer by the electroless precipitation method, in which Ni, Sn, and Ag layers were uniformly grown on Cu foil for dendritic‐free aqueous zinc batteries. Dendrite growth and side reactions were inhibited by inducing uniform Zn deposition, among which Sn‐modified Cu electrode (Sn@Cu) showed the best electrochemical performance because of its highest Zn2+ diffusion and corrosion inhibition ability. The Sn@Cu sym
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39

Zhu, Jing, Xumeng Ge, Zhi Peng, et al. "Interfacial regulation for zinc metal anode of aqueous zinc-ion battery." Green Energy & Environment, November 2024. http://dx.doi.org/10.1016/j.gee.2024.11.001.

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40

Yao, Rui, Yunxiang Zhao, Lumeng Wang, et al. "A Corrosion-Free Zinc Metal Battery with Ultra-Thin Zinc Anode and High Depth of Discharge." Energy & Environmental Science, 2024. http://dx.doi.org/10.1039/d3ee04320g.

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Zinc metal battery featuring high capacity, low cost, and environmental benignity has been receiving more attention than ever. Regrettably, due to the intrinsic thermodynamic instability of metallic zinc in conventional...
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41

Huh, Sung-Ho, Yoon Jeong Choi, So Hee Kim, Jong Seong Bae, Si-Hwan Lee, and Seung-Ho Yu. "Enabling the uniform zinc deposition by zwitterion additive in aqueous zinc metal anode." Journal of Materials Chemistry A, 2023. http://dx.doi.org/10.1039/d3ta01943h.

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The rechargeable aqueous zinc metal battery is considered one of the most promising next-generation batteries for energy storage systems, owing to its low negative standard reduction potential (–0.76 vs. Zn2+/Zn),...
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42

Liu, Wen, Qiwen Zhao, Siru He, et al. "Sustainable Release of Zincophilic Metal Ions from Separator Proactively Drives Interfacial Stabilization for Durable Zinc Anode." Advanced Functional Materials, March 7, 2025. https://doi.org/10.1002/adfm.202425680.

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AbstractOne of the important challenges in advancing aqueous zinc‐ion batteries is the separator, which is crucial for promoting stable electrode‐electrolyte interface and energy density of the battery. Herein, this study introduces a metal ion‐activated air‐laid paper (ALP Act) as an alternative for traditional glass fiber separators with big thickness and weight. Notably, the sustainable release of metal ions facilitates in situ interface engineering, thus creating a surface layer with high zinc affinity to promote the uniform migration and deposition of zinc ions. By continuously adjusting
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43

Han, Xiaomin, Ran Zhao, Jingjing Yang, et al. "High-Entropy Materials for Aqueous Zinc Metal Batteries." Energy & Environmental Science, 2024. http://dx.doi.org/10.1039/d4ee04442h.

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44

Zuo, Yinze, Zheng Wang, Mingquan Liu та ін. "Boosting Interfacial Zn2+ Desolvation Kinetics by a π-Electron-Rich Janus Catalyst for Robust Zn Metal Batteries". Energy & Environmental Science, 2025. https://doi.org/10.1039/d5ee01472g.

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The application of zinc metal-based battery is hindered by the low thermodynamic stability of zinc anodes and sluggish desolvation kinetics of the interfacial [Zn(H2O)6]2+ complex, which can induce serious side...
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45

Yang, Huijun, Yang Yang, Wuhai Yang, Gang Wu, and Ruijie Zhu. "Correlating the hydrogen evolution and zinc deposition/ dissolution kinetics to cyclability of metallic zinc electrodes." Energy & Environmental Science, 2024. http://dx.doi.org/10.1039/d3ee04515c.

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Metal plating/stripping reversibility critically constrains the cyclability of battery performances. Prior reports have unexpectedly noted that zinc (Zn) plating/stripping gains higher reversibility when subjected to elevate current densities, yet the...
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Chang, Linhui, Jiamin Li, Qiangchao Sun, Xijun Liu, Xionggang Lu, and Hongwei Cheng. "Innovative Zinc Anodes: Advancing Metallurgy Methods to Battery Applications." Small, October 20, 2024. http://dx.doi.org/10.1002/smll.202408124.

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AbstractAqueous zinc metal batteries (AZMBs) are emerging as a powerful contender in the realm of large‐scale intermittent energy storage systems, presenting a compelling alternative to existing ion battery technologies. They harness the benefits of metal zinc's high safety, natural abundance, and favorable electrochemical potential (−0.762 V vs Standard hydrogen electrode, SHE), alongside an impressive theoretical capacity (820 mAh g−1 and 5655 mAh cm−3). However, the electrochemical performance of ZMBs is impeded by several challenges, including poor compatibility with high‐loading cathodes
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47

Cao, Jin, Junxiu Wu, Haiyang Wu, et al. "Dendrite‐Free Zinc Anode via Oriented Plating with Alkaline Earth Metal Ion Additives." Advanced Functional Materials, April 3, 2024. http://dx.doi.org/10.1002/adfm.202401537.

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AbstractThe cost‐effectiveness and environmentally friendly nature of aqueous zinc‐ion batteries (ZIBs) have garnered significant attention. Nevertheless, obstacles such as dendrite growth and side reactions have hindered their practical application. Here, an alkaline earth metal ion, strontium ions (Sr2+), is chosen as a dual‐functional electrolyte additive to improve the reversibility of ZIBs. Importantly, Sr2+ ions adsorb on the anode surface, creating a dynamic electrostatic shield layer, thus regulating the Zn2+ deposition behavior and suppressing side reactions. Meanwhile, Sr2+ ions pref
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48

Wang, Yu, Tairan Wang, Shuyu Bu, et al. "Sulfolane-containing aqueous electrolyte solutions for producing efficient ampere-hour-level zinc metal battery pouch cells." Nature Communications 14, no. 1 (2023). http://dx.doi.org/10.1038/s41467-023-37524-7.

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AbstractAqueous zinc metal batteries are appealing candidates for grid energy storage. However, the inadequate electrochemical reversibility of the zinc metal negative electrode inhibits the battery performance at the large-scale cell level. Here, we develop practical ampere-hour-scale aqueous Zn metal battery pouch cells by engineering the electrolyte solution. After identifying the proton reduction as the primary source of H2 evolution during Zn metal electrodeposition, we design an electrolyte solution containing reverse micelle structures where sulfolane molecules constrain water in nanodo
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Deckenbach, Daniel, and Jörg J. Schneider. "Toward a Metal Anode‐Free Zinc‐Air Battery for Next‐Generation Energy Storage." Small, February 6, 2024. http://dx.doi.org/10.1002/smll.202311065.

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AbstractRechargeable aqueous zinc‐air batteries (ZABs) promise high energy density and safety. However, the use of conventional zinc anodes affects the energy output from the battery, so that the theoretical energy density is not achievable under operation conditions. A large portion of the zinc is shielded by anode passivation during the discharge process and remains electrochemically unused, making the operation of rechargeable ZABs inefficient up to date. In a metal anode‐free ZAB, there is no unnecessary excess zinc if the zinc reservoir can be precisely adjusted by electrodeposition of zi
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50

Liu, Chaozheng, Wangwang Xu, Lei Zhang, et al. "Electrochemical Hydrophobic Tri‐layer Interface Rendered Mechanically Graded Solid Electrolyte Interface for Stable Zinc Metal Anode." Angewandte Chemie International Edition, January 8, 2024. http://dx.doi.org/10.1002/anie.202318063.

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The aqueous zinc‐ion battery is promising as grid scale energy storage device, but hindered by the instable electrode/electrolyte interface. Herein, we report the lean‐water ionic liquid electrolyte for aqueous zinc metal batteries. The lean‐water ionic liquid electrolyte creates the hydrophobic tri‐layer interface assembled by first two layers of hydrophobic OTF‐ and EMIM+ and third layer of loosely attached water, beyond the classical Gouy–Chapman–Stern theory based electrochemical double layer. By taking advantage of the hydrophobic tri‐layer interface, the lean‐water ionic liquid electroly
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