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Journal articles on the topic 'Zincate'

Author: Grafiati

Published: 8 June 2024

Last updated: 31 July 2025

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1

Semenov, V. V., N. V. Zolotareva, O. V. Novikova, et al. "Preparation of Water-Soluble Zinc(II) Complexes with Ethylenediaminetetraacetic Acid: Molecular Structure of Zinc Ethylenediaminetetraacetate Trihydrate." Координационная химия 49, no. 4 (2023): 205–16. http://dx.doi.org/10.31857/s0132344x22600436.

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Poorly soluble zinc ethylenediaminetetraacetate zincate Zn[ZnL] reacts with sodium Na4L, potassium K4L, ammonium (NH4)4L, 2-ammonioethanol (H3NCH2CH2OH)4L, and hexamethylene-1,6-diammonium {H3N(CH2)6NH3}2L salts of ethylenediaminetetraacetic acid H4L to give readily soluble sodium Na2[ZnL], potassium K2[ZnL], ammonium (NH4)2[ZnL], 2-ammonioethanol (H3NCH2CH2OH)2[ZnL], and hexamethylene-1,6-diammonium {H3N(CH2)6NH3}[ZnL] ethylenediaminetetraacetate zincates. The reaction of tetrakis(triethylammonium) salt {(C2H5)3NH}4L with Zn[ZnL] does not give the expected bis(triethylammonium) ethylenediamin

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2

Westerhausen, Matthias, Bernd Rademacher, Wolfgang Schwarz, and Sonja Henkel. "Lithium-zinkate mit heteroleptischem Triorganylzinkat-Anion / Lithium Zincates with Heteroleptic Triorganylzincate Anion." Zeitschrift für Naturforschung B 49, no. 2 (1994): 199–210. http://dx.doi.org/10.1515/znb-1994-0208.

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Abstract Bis[bis(trimethylsilyl)methyl]-as well as bis(2,2,4,4,6,6-hexa-methyl-2,4,6-trisila-cyclo-hexyl)zinc react with methyl lithium or phenyl lithium in the pres ence of the tridentate l,3,5-trimethyl-l,3,5-triazinane (TMTA) to yield zincates of the type LiZnR2R'·2TMTA. The compounds are colorless and insoluble in aliphatic or aromatic hydrocarbons. These zincates exist in solution as well as in the crystalline state as separated ions, as confirmed for lithium-methyl-bis(2,2,4,4,6,6-hexamethyl-2,4,6-trisila-cyc/o-hexyl)-zincate · 2TMTA by X-ray diffraction (P1̄; a -1139,5(3); b = 1482,4(4

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3

Chiba, Atsushi. "Crystal Orientation and Surface Morphology of Sono-Electroplated Zinc Film from Alkali Zincate Bath." Advanced Materials Research 79-82 (August 2009): 1743–46. http://dx.doi.org/10.4028/www.scientific.net/amr.79-82.1743.

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Zn plated on Cu plate from 0.65 mol/dm3 alkali zincate solution in 8 mol/dm3 KOH bath Electrolysis was carried out as current density of 10 - 100 mA/cm2. The sonication was prepared 40 kHz. The current efficiency was 76.1 % at 10 mA/cm2 in 0.10 mol/dm3 zincate and 100 % in 0.15 mol/dm3 zincate at 50 mA/cm2. The current efficiency and thickness of diffusion layer affected with the agitation of micro-jet. Surface of film was smooth and dense as particle crushed down with the shockwave pressure. (112) plane moved horizontally to <113> direction under the compressive stress or shearing stres

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4

Sun, Qi Lei, and Ze Rui Liu. "Electrochemical Behaviors of Q420 Hot Galvanized Plate in Simulated Concrete Pore Solution." Advanced Materials Research 941-944 (June 2014): 854–57. http://dx.doi.org/10.4028/www.scientific.net/amr.941-944.854.

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The electrochemical behaviors of Q420 hot galvanized plate in the simulated concrete pore solution are studied by means of polarization curves and AC impedance. The result shows that, when the Q420 galvanized plate is in the simulated concrete pore solution, the stable and protective calcium zincate grains can be produced on the coating surface of the galvanized steel, so that the coating can enter the passive state and prevent the further corrosion of zinc in the alkaline environment. When the carbonification occurring in the concrete reduces the pH of medium or changes the medium environment

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5

Bikulčius, Gedvidas, Sigitas Jankauskas, Aušra Selskienė, Laurynas Staišiūnas, Tadas Matijošius, and Svajus Joseph Asadauskas. "New Insight into Adherence of Ni-P Electroless Deposited Coatings on AA6061 Alloy through Al2O3 Ceramic." Coatings 12, no. 5 (2022): 594. http://dx.doi.org/10.3390/coatings12050594.

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The adhesion quality of Ni-P coatings on aluminum is important for mechanical and anticorrosion properties. In this study, the adhesion of Ni-P coatings on nanoporous Al2O3 ceramic (NAC) was evaluated by impact testing. NAC was fabricated on AA6061 alloy by anodizing in sulfuric acid. The deposition of Ni-P coating was carried out on NAC with and without zincate pretreatment. It was found that zincate activation of Al2O3 accelerates the formation of Ni-P coating. A cross-sectional analysis using energy-dispersive X-ray spectroscopy showed that the mechanical properties and impact resistance of

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6

Li, Song, and Yuan Yuan Zhou. "Preparation of Tetragonal and Hexagonal Calcium Zincate." Applied Mechanics and Materials 130-134 (October 2011): 1454–57. http://dx.doi.org/10.4028/www.scientific.net/amm.130-134.1454.

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Tetragonal and hexagonal calcium zincate as an active material in Zn/Ni secondary battery has been successfully prepared with precipitation transformation method by isothermal in the reasonable concentration of KOH as base solution for the first time. The chemical composition of Ca [Zn (OH)3]2•2H2O was confirmed by X-ray powder diffraction pattern 、TG-DSC and infrared spectroscopy. These results all show that perfect crystal shape of either regular tetragonal or hexagonal calcium zincate (regardless of crystal size) should always have the same chemical expression of Ca [Zn (OH)3]2•2H2O as its

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7

Semenov, V. V., N. V. Zolotareva, N. M. Lazarev, B. I. Petrov, T. I. Lopatina, and E. N. Razov. "Crystals morphology of ethylenediaminetetraacetatozincate triethylenediaminium and tetramethylethylenediaminium." Kristallografiâ 69, no. 5 (2024): 795–801. http://dx.doi.org/10.31857/s0023476124050058.

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Trimethylenediamine ethylenediaminetetraacetate zincate trihydrate [HN(CH2CH2)3NH]ZnL · 3H2О and tetramethylethylenediamine ethylenediaminetetraacetate zincate dihydrate [H(CH3)2NCH2CH2N(CH3)2H]ZnL · 2H2О were synthesized by reacting zinc oxide with ethylenediaminetetraacetic acid (H4L) and then with its triethylenediamine or tetramethylethylenediamine salts. The resulting compounds precipitate from aqueous or organic solvents in the form of thread-like, cubic and pyramidal crystals, which are characterized by elemental analysis, scanning electron microscopy, IR spectroscopy, thermogravimetry

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8

KAWASHIMA, Satoshi. "Zincate Process of Aluminum." Journal of The Surface Finishing Society of Japan 64, no. 12 (2013): 645–49. http://dx.doi.org/10.4139/sfj.64.645.

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9

AZUMI, Kazuhisa, Takuma YUGIRI, Masahiro SEO, Katsuhiko TASHIRO, and Satoshi KAWASHIMA. "Double Zincate Pretreatment of Al Alloy in a LiOH-based Zincate Solution." Journal of the Surface Finishing Society of Japan 51, no. 3 (2000): 313–18. http://dx.doi.org/10.4139/sfj.51.313.

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10

Tong, Meng Liang, and Xuan Yan Liu. "Preparation and Electrochemical Performances of Calcium Zincate Synthesized by Microwave Method." Advanced Materials Research 236-238 (May 2011): 868–71. http://dx.doi.org/10.4028/www.scientific.net/amr.236-238.868.

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Calcium zincate as an active material in Zn/Ni secondary battery has been successfully synthesized by microwave method. The chemical composition of Ca(OH)2·2Zn(OH)2·2H2O was confirmed by X-ray powder diffraction pattern and weight loss in thermogravimetric analysis.The results of cyclic voltammetry and experimental Zn/Ni battery charge–discharge test showed that the material of calcium zincate had excellent electrochemical performances: a high discharging platform of 1.685 V and a good cycleability, discharge capacity would be 70.0% of initial capacity after circulated 120 times.

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11

Tsehaye, Misgina Tilahun, Getachew Teklay Gebreslassie, Nak Heon Choi, et al. "Pristine and Modified Porous Membranes for Zinc Slurry–Air Flow Battery." Molecules 26, no. 13 (2021): 4062. http://dx.doi.org/10.3390/molecules26134062.

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The membrane is a crucial component of Zn slurry–air flow battery since it provides ionic conductivity between the electrodes while avoiding the mixing of the two compartments. Herein, six commercial membranes (Cellophane™ 350PØØ, Zirfon®, Fumatech® PBI, Celgard® 3501, 3401 and 5550) were first characterized in terms of electrolyte uptake, ion conductivity and zincate ion crossover, and tested in Zn slurry–air flow battery. The peak power density of the battery employing the membranes was found to depend on the in-situ cell resistance. Among them, the cell using Celgard® 3501 membrane, with in

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12

Abbasi, Ali, Soraya Hosseini, Anongnat Somwangthanaroj, Ahmad Azmin Mohamad, and Soorathep Kheawhom. "Poly(2,6-Dimethyl-1,4-Phenylene Oxide)-Based Hydroxide Exchange Separator Membranes for Zinc–Air Battery." International Journal of Molecular Sciences 20, no. 15 (2019): 3678. http://dx.doi.org/10.3390/ijms20153678.

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Rechargeable zinc–air batteries are deemed as the most feasible alternative to replace lithium–ion batteries in various applications. Among battery components, separators play a crucial role in the commercial realization of rechargeable zinc–air batteries, especially from the viewpoint of preventing zincate (Zn(OH)42−) ion crossover from the zinc anode to the air cathode. In this study, a new hydroxide exchange membrane for zinc–air batteries was synthesized using poly (2,6-dimethyl-1,4-phenylene oxide) (PPO) as the base polymer. PPO was quaternized using three tertiary amines, including trime

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13

Sharma, Ram A. "Kinetics of Calcium Zincate Formation." Journal of The Electrochemical Society 135, no. 8 (1988): 1875–82. http://dx.doi.org/10.1149/1.2096172.

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14

HUANG, Xiao-mei, Ning LI, De-yu LI, and Li-min JIANG. "Zincate mechanism on cast Al-Si alloy in non-cyanide multi-metal zincate solutions." Transactions of Nonferrous Metals Society of China 16, no. 2 (2006): 414–20. http://dx.doi.org/10.1016/s1003-6326(06)60071-x.

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15

Pokorný, P., R. Pernicová, M. Vokáč, I. Sedlářová, and M. Kouřil. "The impact of produced hydrogen gas and calcium zincate on changes of porous structure of cement paste in the vicinity of hot-dip galvanized steel." Koroze a ochrana materialu 61, no. 2 (2017): 67–79. http://dx.doi.org/10.1515/kom-2017-0012.

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Abstract The paper summarizes the impact of produced hydrogen and calcium hydroxyzincate (Ca[Zn(OH)3]2·2H2O) on the formation of the porous structure of cement paste in the vicinity of hot-dip galvanized steel. These substances result from cathodic (hydrogen) and anodic (zincates-formed by reaction with hydroxides) corrosion reactions of hot-dip galvanized steel (or pure zinc) in the cement paste. The cement binder pore structure was studied by means of mercury porosimetry and analysis of scanning electron microscopy and confocal microscopy images. The porosity of the cement paste at the galva

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16

Shin, JaeWook, Jung-Min You, Jungwoo Z. Lee, et al. "Deposition of ZnO on bismuth species towards a rechargeable Zn-based aqueous battery." Physical Chemistry Chemical Physics 18, no. 38 (2016): 26376–82. http://dx.doi.org/10.1039/c6cp04566a.

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17

Wang, Tanyanyu, Masahiro Kunimoto, and Takayuki Homma. "Synergetic Effect of Silicate Addition on Modifying Zincate Solvation and Regulating ZnO Formation Revealed by in-Situ Raman Measurements during Zn Discharging Process." ECS Meeting Abstracts MA2025-01, no. 6 (2025): 712. https://doi.org/10.1149/ma2025-016712mtgabs.

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Rechargeable Zn alkaline batteries (RZABs) batteries, with the advantages of low cost, high theoretical energy density and intrinsic safety, are considered favorable for next-generation grid-scale energy storage. [ 1 ] Nonetheless, the cyclability of RZABs is not comparable to state-of-the-art lithium-ion batteries, which greatly holds back their practical application. [ 2 ] One critical concern is the quick passivation of Zn anodes, which leads to a drastic capacity drop and accordingly terminates the battery work. [ 3 ] As the name implies, the origin of Zn passivation is known to be accumul

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18

Sharma, Ram A. "Physico‐Chemical Properties of Calcium Zincate." Journal of The Electrochemical Society 133, no. 11 (1986): 2215–19. http://dx.doi.org/10.1149/1.2108376.

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19

Debiemme‐Chouvy, Catherine, Jacques Vedel, Marie‐Claire Bellissent‐Funel, and Robert Cortes. "Supersaturated Zincate Solutions: A Structural Study." Journal of The Electrochemical Society 142, no. 5 (1995): 1359–64. http://dx.doi.org/10.1149/1.2048582.

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20

Cheng, Ya-Qian, Lu-Ping Lv, Jian-Wu Xie, Hai-Bin Wang, and Zhi-Min Jin. "Ammonium trichloro(hexamethylenetetramine)zincate(II) sesquihydrate." Acta Crystallographica Section E Structure Reports Online 62, no. 12 (2006): m3591—m3593. http://dx.doi.org/10.1107/s1600536806050550.

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21

Simicic, Milos, and Konstantin Popov. "Zinc electrodeposition from alkaline zincate solution by pulsating overpotentials." Journal of the Serbian Chemical Society 65, no. 9 (2000): 661–70. http://dx.doi.org/10.2298/jsc0009661s.

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It is well known that smooth zinc deposits cannot be obtained from alkaline zincate using constant overpotential and current rate. During prolonged metal deposition, spongy and dendritic deposits are formed. It has been shown that the deposits are less agglomerated in the case of square-wave pulsating overpotentials regime than the ones obtained in case of constant overpotential regime. This is explained in a semiquantitative way by two phenomena: selective anodic dissolution during overpotentials ?off? period and decreasing diffusion control. These effects is more pronounced at higher pause-t

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22

Heydorn, Raymond Leopold, Jana Niebusch, David Lammers, et al. "Production and Characterization of Bacterial Cellulose Separators for Nickel-Zinc Batteries." Energies 15, no. 15 (2022): 5727. http://dx.doi.org/10.3390/en15155727.

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The need for energy-storing technologies with lower environmental impact than Li-ion batteries but similar power metrics has revived research in Zn-based battery chemistries. The application of bio-based materials as a replacement for current components can additionally contribute to an improved sustainability of Zn battery systems. For that reason, bacterial cellulose (BC) was investigated as separator material in Ni-Zn batteries. Following the biotechnological production of BC, the biopolymer was purified, and differently shaped separators were generated while surveying the alterations of it

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23

Bochatay, Valentin, Zeina Neouchy, Fabrice Chemla, Franck Ferreira, Olivier Jackowski, and Alejandro Pérez-Luna. "4-Amino-1-allenylsilanes from 4-Aminopropargylic Acetates through a Silylzincation/Elimination Sequence." Synthesis 48, no. 19 (2016): 3287–300. http://dx.doi.org/10.1055/s-0035-1562429.

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4-Aminopropargylic acetates afford 4-amino-1-allenylsilanes upon reaction with the lithium (triorganosilyl)zincate (PhMe2Si)3ZnLi. The reaction is both stereoselective and stereospecific and proceeds through syn-silylzincation of the carbon–carbon triple bond followed by subsequent anti-β-elimination of the acetate group.

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24

Mohammed, Abdul Jalil, and Michael Moats. "Effects of Carrier, Leveller, and Booster Concentrations on Zinc Plating from Alkaline Zincate Baths." Metals 12, no. 4 (2022): 621. http://dx.doi.org/10.3390/met12040621.

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Organic additives are required for alkaline zincate plating baths to obtain an acceptable coating on steel for corrosion protection. The effects and possible interactions of three commercial additives (Eldiem Carrier, Eldiem Booster, and Bright Enhancer 2× on zinc electrodeposition from a high-concentration alkaline zincate bath were investigated. Visually acceptable deposits were produced within the current density range of 130 to 430 A m−2 for most additive conditions examined. Over concentration ranges examined, decreasing the booster concentration led to brighter zinc deposits, and an inte

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25

Linton, David J., Robert P. Davies, Paul Schooler, and Andrew E. H. Wheatley. "Selective Oxygen Capture in Lithium Zincate Chemistry." Phosphorus, Sulfur, and Silicon and the Related Elements 169, no. 1 (2001): 309–12. http://dx.doi.org/10.1080/10426500108546650.

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26

Tomita, Yuichi, Yoshiyuki Ichikawa, Yoshimitsu Itoh, Kosuke Kawada та Koichi Mikami. "Zincate-type enolate for radical α-trifluoromethylation". Tetrahedron Letters 48, № 50 (2007): 8922–25. http://dx.doi.org/10.1016/j.tetlet.2007.10.041.

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27

Assmann, B., S. Sievertsen, and H. Homborg. "Bis(triphenylphosphine)iminium Nitrito(phthalocyaninato)zincate Hydrate." Acta Crystallographica Section C Crystal Structure Communications 52, no. 4 (1996): 876–79. http://dx.doi.org/10.1107/s0108270195014351.

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28

Kamp, Mathias, Jonas Bartsch, Gisela Cimiotti, et al. "Zincate processes for silicon solar cell metallization." Solar Energy Materials and Solar Cells 120 (January 2014): 332–38. http://dx.doi.org/10.1016/j.solmat.2013.05.035.

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29

TRINSCHEK, D., and M. JANSEN. "ChemInform Abstract: Na2ZnO2, a New Sodium Zincate." ChemInform 27, no. 35 (2010): no. http://dx.doi.org/10.1002/chin.199635012.

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30

SCHEIKOWSKI, M., and HK MUELLER-BUSCHBAUM. "ChemInform Abstract: Potassium-Barium-Oxogallate/-zincate KBa6Ga7Zn4O21." ChemInform 25, no. 16 (2010): no. http://dx.doi.org/10.1002/chin.199416016.

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31

Hu, Hang, Anqiang He, Douglas Ivey, Drew Aasen, Sheida Arfania, and Shantanu Shukla. "Failure Analysis of Nickel-Coated Anodes in Zinc-Air Hybrid Flow Batteries." ECS Meeting Abstracts MA2022-01, no. 1 (2022): 26. http://dx.doi.org/10.1149/ma2022-01126mtgabs.

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A zinc-air flow battery system pumps "fuel” (a zinc particle/KOH slurry) from a fuel tank to a fuel cell stack, where the zinc particles are combined with oxygen from the air to form zincate ions and produce electricity. The zincate-rich electrolyte is then returned to the fuel tank. During the charging cycle, the electrolyte is passed to the zinc regenerator, where electricity (from renewable sources such as solar or wind) is utilized to convert the zincate ions to zinc particles. The regenerated fuel is pumped back into the fuel tank for the discharge process. Nickel is considered for use as

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32

Graham, David V., Eva Hevia, Alan R. Kennedy, and Robert E. Mulvey. "Lithium Dimethyl(amido)zinc Complexes: Contrasting Zincate (Amido = TMP) and Inverse Zincate (Amido = HMDS) Structures on Addition of TMEDA." Organometallics 25, no. 14 (2006): 3297–300. http://dx.doi.org/10.1021/om060334i.

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33

Tahseen Anwer, Iqra Shahzadi, Syed Anwaar Hussain Shah, et al. "Solar Photocatalytic Removal of Natural Organic Matter using Fluorinated Calcium Zincate Grafted on Gravel." Indus Journal of Bioscience Research 2, no. 2 (2024): 1533–49. https://doi.org/10.70749/ijbr.v2i02.429.

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Natural organic matter issue (NOM) is a delegated class of harmful poisons in water that must be evacuated by utilizing efficient and eco-accommodating treatment procedures to chop down water contamination. In this, a composite of the evacuation of NOM utilizing fluorinated and non-fluorinated calcium zincate composite joined over rock by splash pyrolysis technique was accounted for. The created material was portrayed by checking electron microscopy, vitality dispersive X-beam, Fourier change infrared spectroscopy and X-beam diffraction spectroscopy. Response parameters like starting centraliz

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34

Ajibola, Olawale Olarewaju, Daniel T. Oloruntoba, and Benjamin O. Adewuyi. "Effects of Hard Surface Grinding and Activation on Electroless-Nickel Plating on Cast Aluminium Alloy Substrates." Journal of Coatings 2014 (September 21, 2014): 1–10. http://dx.doi.org/10.1155/2014/841619.

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This work examined effects of hard surface polishing grits and activation on electroless-nickel (EN) plating on cast aluminium alloy substrates in sodium hypophosphite baths. As-received aluminium alloy sample sourced from automobile hydraulic brake master cylinder piston was melted in electric furnace and sand cast into rod. The cast samples were polished using different grits (60 μm–1200 μm) before plating. The effects on adhesion, appearance, and quantity of EN deposits on substrates were studied. Observation shows that the quantity of EN deposit is partly dependent on the alloy type and ro

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35

Geier, Michael J., Xiaotian Wang, Luke D. Humphreys, Selcuk Calimsiz, and Mark E. Scott. "Warming Up to Oxazole: Noncryogenic Oxazole Metalation and Negishi Coupling Development." Synlett 30, no. 15 (2019): 1776–81. http://dx.doi.org/10.1055/s-0037-1611909.

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This report details the development of several suitable noncryogenic metalation conditions for the synthesis of oxazole zincate. Subsequent rounds of high-throughput catalyst screening ultimately led to the identification of several suitable Pd sources that can be used for the Negishi coupling of unsubstituted oxazole. The scope and generality for one of the reported conditions is also presented.

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36

Siu, S., and J. W. Evans. "Density and Viscosity Measurements of Zincate/KOH Solutions." Journal of The Electrochemical Society 144, no. 4 (1997): 1278–80. http://dx.doi.org/10.1149/1.1837583.

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37

Lin, Dong-Dong, Li Zhang та Duan-Jun Xu. "Poly[disodium bis(μ-malonato)zincate(II) dihydrate]". Acta Crystallographica Section E Structure Reports Online 59, № 11 (2003): m1010—m1012. http://dx.doi.org/10.1107/s1600536803022153.

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38

Miminoshvili, Elguja B., Alexandre N. Sobolev, Ketevan E. Miminoshvili, and Tamara N. Sakvarelidze. "Bis(piperidinium)trans-dichlorobis(3,5-dinitrobenzoato)zincate(II)." Acta Crystallographica Section E Structure Reports Online 60, no. 3 (2004): m319—m321. http://dx.doi.org/10.1107/s160053680400337x.

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39

Jin, Shouwen, Yanfei Huang, Shuaishuai Wei, Yong Zhou та Yingping Zhou. "Poly[diammonium [(μ4-butane-1,2,3,4-tetracarboxylato)zincate] tetrahydrate]". Acta Crystallographica Section E Structure Reports Online 68, № 10 (2012): m1268—m1269. http://dx.doi.org/10.1107/s1600536812038883.

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40

Kiros, Yohannes. "Separation and permeability of zincate ions through membranes." Journal of Power Sources 62, no. 1 (1996): 117–19. http://dx.doi.org/10.1016/s0378-7753(96)02420-2.

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41

Liu, PengFei, and YiFei Zhang. "Nucleation and Structure of Supersaturated Sodium Zincate Solution." Industrial & Engineering Chemistry Research 58, no. 47 (2019): 21187–93. http://dx.doi.org/10.1021/acs.iecr.9b03070.

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42

Ravindran, Visalakshi, and V. S. Muralidharan. "Cathodic processes on zinc in alkaline zincate solutions." Journal of Power Sources 55, no. 2 (1995): 237–41. http://dx.doi.org/10.1016/0378-7753(95)02184-i.

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43

Peng, Wen-jie, and Yun-yan Wang. "Mechanism of zinc electroplating in alkaline zincate solution." Journal of Central South University of Technology 14, no. 1 (2007): 37–41. http://dx.doi.org/10.1007/s11771-007-0008-1.

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44

Azumi, Kazuhisa, Takuma Yugiri, Masahiro Seo, and Shinji Fujimoto. "Double Zincate Pretreatment of Sputter-Deposited Al Films." Journal of The Electrochemical Society 148, no. 6 (2001): C433. http://dx.doi.org/10.1149/1.1370966.

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45

Caldeira, Vincent, Laurent Jouffret, Julien Thiel, et al. "Ultrafast Hydro-Micromechanical Synthesis of Calcium Zincate: Structural and Morphological Characterizations." Journal of Nanomaterials 2017 (2017): 1–8. http://dx.doi.org/10.1155/2017/7369397.

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Calcium zincate is a compound with a large panel of application: mainly known as an advantageous replacement of zinc oxide in negative electrodes for air-zinc or nickel-zinc batteries, it is also used as precursor catalyst in biodiesel synthesis and as antifungal compound for the protection of limestone monuments. However, its synthesis is not optimized yet. In this study, it was elaborated using an ultrafast synthesis protocol: Hydro-Micromechanical Synthesis. Two other synthesis methods, Hydrochemical Synthesis and Hydrothermal Synthesis, were used for comparison. In all cases, the as-synthe

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46

Häggman, Leif, Cecilia Lindblad, Anders Cassel, and Ingmar Persson. "Complex Formation Between Zinc(II) and Alkyl-N-iminodiacetic Acids in Aqueous Solution and Solid State." Journal of Solution Chemistry 49, no. 9-10 (2020): 1279–89. http://dx.doi.org/10.1007/s10953-020-01031-w.

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Abstract Removal of metal compounds from wastewater using processes where metals can be removed and valuable chemicals recycled is of significant industrial importance. Chelating surfactants are an interesting group of chemicals to be used in such applications. Carboxylated polyamines are a promising group to be used in such processes. To apply carboxylated polyamines as chelating surfactants, detailed knowledge of the solution chemistry, including complex formation, kinetics and structures of pure fundamental systems, is required. In this study zinc(II) alkyl-N-iminodiacetate systems with var

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47

Guschlbauer, Jannick, Tobias Vollgraff, and Jörg Sundermeyer. "Homoleptic trimethylsilylchalcogenolato zincates [Zn(ESiMe3)3]− and stannanides [Sn(ESiMe3)3]− (E = S, Se): precursors in solution-based low-temperature binary metal chalcogenide and Cu2ZnSnS4 (CZTS) synthesis." Dalton Transactions 49, no. 8 (2020): 2517–26. http://dx.doi.org/10.1039/c9dt04144c.

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Organic cation salts with homoleptic zincate and stannanide anions, Ph<sub>4</sub>P [Zn(ESiMe<sub>3</sub>)<sub>3</sub>] (E = S (1a), Se (1b)) and Cat [Sn(ESiMe<sub>3</sub>)<sub>3</sub>] (Cat = Ph<sub>4</sub>P<sup>+</sup> (E = S (2a-Ph4P); Cat = PPN<sup>+</sup> (E = S 2a-Ph4P, Se (2a)) are presented and structurally characterized.

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48

de Oliveira, Iara, Leandro Cunha, Leila Visconte, Marcelo Oliveira, and Mayura Rubinger. "The Evaluation of bis(4-Methylphenylsulfonyldithiocarbimato)zincate (II) (ZNIBU) Activity in the Vulcanization of NBR Compounds and its Effect on their Mechanical Properties." Chemistry & Chemical Technology 4, no. 3 (2010): 237–40. http://dx.doi.org/10.23939/chcht04.03.237.

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The effect of accelerator type on the vulcanization process and mechanical properties of nitrile rubber (NBR) compounds was investigated. Three commercial accelerators were selected, N-N-t-butyl-2-benzothiazole sulfenamide (TBBS), tetramethylthiuram disulfide (TMTD) and bis(dimethyldithiocarbamato)zinc (II) (ZDMC) and compared with the compound bis(4 methylphenylsulfonyldithiocarbimato)zincate (II) (ZNIBU). Surprisingly, it was found that the optimum vulcanization time for ZNIBU showed better results than for TBBS.

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Trinschek, D., and M. Jansen. "Na2ZnO2, ein neues Natriumzinkat / Na2ZnO2, a New Sodium Zincate." Zeitschrift für Naturforschung B 51, no. 5 (1996): 711–14. http://dx.doi.org/10.1515/znb-1996-0515.

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By reacting Na2O, which was produced in situ from NaN3 and NaNO2, with reactive ZnO in the solid state, the synthesis of Na2ZnO2 has been achieved. Na2ZnO2 is metastable up to about 750°C. The novel sodium zincate crystallizes in the spaceogroup P21/c (No. 14) with the lattice parameters a = 7.7352(2), b = 5.9782(2), c = 5.7248(2) Å, β = 94.934(3)°, Z = 4. According to a single crystal structure determination it is an representative of the anti type of the Ln2S2O (Ln = Er, Tm, Yb, Dy) structure.

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Rohan, James F., Patricia A. Murphy, and John Barrett. "Zincate-Free, Electroless Nickel Deposition on Aluminum Bond Pads." Journal of The Electrochemical Society 152, no. 1 (2005): C32. http://dx.doi.org/10.1149/1.1836131.

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