Academic literature on the topic 'Zintl, Composés de'

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Journal articles on the topic "Zintl, Composés de"

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Zhou, Jian, Santanab Giri, and Purusottam Jena. "18-Electron rule inspired Zintl-like ions composed of all transition metals." Phys. Chem. Chem. Phys. 16, no. 37 (2014): 20241–47. http://dx.doi.org/10.1039/c4cp03141e.

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Göbgen, Kai C., Kai S. Fries, Fabian C. Gladisch, Richard Dronskowski, and Simon Steinberg. "Revealing the Nature of Chemical Bonding in an ALn2Ag3Te5-Type Alkaline-Metal (A) Lanthanide (Ln) Silver Telluride." Inorganics 7, no. 6 (2019): 70. http://dx.doi.org/10.3390/inorganics7060070.

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Although the electronic structures of several tellurides have been recognized by applying the Zintl-Klemm concept, there are also tellurides whose electronic structures cannot be understood by applications of the aforementioned idea. To probe the appropriateness of the valence-electron transfers as implied by Zintl-Klemm treatments of ALn2Ag3Te5-type tellurides (A = alkaline-metal; Ln = lanthanide), the electronic structure and, furthermore, the bonding situation was prototypically explored for RbPr2Ag3Te5. The crystal structure of that type of telluride is discussed for the examples of RbLn2A
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Song, Junseong, Hyun Yong Song, Zhen Wang, et al. "Creation of two-dimensional layered Zintl phase by dimensional manipulation of crystal structure." Science Advances 5, no. 6 (2019): eaax0390. http://dx.doi.org/10.1126/sciadv.aax0390.

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The discovery of new families, beyond graphene, of two-dimensional (2D) layered materials has always attracted great attention. However, it has been challenging to artificially develop layered materials with honeycomb atomic lattice structure composed of multicomponents such as hexagonal boron nitride. Here, through the dimensional manipulation of a crystal structure from sp3-hybridized 3D-ZnSb, we create an unprecedented layered structure of Zintl phase, which is constructed by the staking of sp2-hybridized honeycomb ZnSb layers. Using structural analysis combined with theoretical calculation
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Zhu, Min, Xu-Tang Tao, and Sheng-Qing Xia. "Electron-deficient copper pnictides: A2Mg3Cu9Pn7 (A = Sr, Eu; Pn = P, As) and Eu5Mg2.39Cu16.61As12." Inorganic Chemistry Frontiers 3, no. 10 (2016): 1264–71. http://dx.doi.org/10.1039/c6qi00221h.

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Five pnictide Zintl compounds, A<sub>2</sub>Mg<sub>3</sub>Cu<sub>9</sub>Pn<sub>7</sub> (A = Sr, Eu; Pn = P, As) and Eu<sub>5</sub>Mg<sub>2.39</sub>Cu<sub>16.61</sub>As<sub>12</sub>, were synthesized from the Pb-flux reactions. The anion structures of these compounds can be described as being composed of edge- or corner-sharing CuPn<sub>4</sub> tetrahedra, which construct complex 3D frameworks with cations filled into the cavities.
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Emmerling, Franziska, Nina Längin, Frank Pickhard, Marco Wendorff, and Caroline Röhr. "Verbindungen mit Pentelid-Hanteln M2: AIII M6 und AII11M10 (A = Rb, Cs, Ba; M = Sb, Bi) / Compounds with Pentelide Dumbbells M2: AI11M6 and AII11M10 (A = Rb, Cs, Ba; M = Sb, Bi)." Zeitschrift für Naturforschung B 59, no. 1 (2004): 7–16. http://dx.doi.org/10.1515/znb-2004-0102.

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Abstract The new ternary alkali pentelides A11M6 (A = Rb, Cs; M = Sb/Bi) all contain non electron-precise isolated dumbbells statistically composed of Sb/Bi. Their phase ranges as determined from single crystal data were found to be on the Sb-rich side of the overall composition A11Sb6−xBix in the case of the Rb compound (i. e. Rb11Sb5.4Bi0.6: orthorhombic Immm, a = 766.7(3), b = 1052.2(3), c = 1732.7(6) pm, Z = 4, R1 = 0.0554), and on the Bi-rich side of the overall composition A11Sb6−xBix in the case of A = Cs (i.e. Cs11Sb1.6Bi4.4). In the series of known alkaline earth compounds A11M10, con
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Asamiya, Yuki, Takahiro Yamada, and Hisanori Yamane. "Synthesis and Characterization of NaCd0.92Sn1.08, Na(Cd0.28Sn0.72)2 and Na2CdSn5 with Three-Dimensional Cd-Sn Frameworks." Inorganics 9, no. 3 (2021): 19. http://dx.doi.org/10.3390/inorganics9030019.

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The crystal structures of three new ternary compounds, NaCd0.92Sn1.08 (I), Na(Cd0.28Sn0.72)2 (II), and Na2CdSn5 (III) synthesized in a sodium-cadmium-tin system were determined by single-crystal X-ray analysis to be the following: (I) LiGeZn-type structure (hexagonal, a = 4.9326(1) Å, c = 10.8508(3) Å, space group P-6m2); (II) CaIn2-type structure (hexagonal, a = 4.8458(2) Å, c = 7.7569(3) Å, P63/mmc); and (III) isotype with tI-Na2ZnSn5 (tetragonal, a = 6.4248(1) Å, c = 22.7993(5) Å, I-42d). Each compound has a three-dimensional framework structure mainly composed of four-fold coordinated Cd a
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Lu, Erdong, Jonathan S. Van Buskirk, Jingxiang Cheng, and Daniel C. Fredrickson. "Tutorial on Chemical Pressure Analysis: How Atomic Packing Drives Laves/Zintl Intergrowth in K3Au5Tl." Crystals 11, no. 8 (2021): 906. http://dx.doi.org/10.3390/cryst11080906.

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The tight atomic packing generally exhibited by alloys and intermetallics can create the impression of their being composed of hard spheres arranged to maximize their density. As such, the atomic size factor has historically been central to explanations of the structural chemistry of these systems. However, the role atomic size plays structurally has traditionally been inferred from empirical considerations. The recently developed DFT-Chemical Pressure (CP) analysis has opened a path to investigating these effects with theory. In this article, we provide a step-by-step tutorial on the DFT-CP m
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Dissertations / Theses on the topic "Zintl, Composés de"

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Flot, David. "Nouvelles phases de Zintl ternaires et quaternaires contenant des architectures à clusters des éléments du groupe 13 : élaboration, étude cristallographique et structure électronique." Montpellier 2, 1997. http://www.theses.fr/1997MON20114.

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Dans les phases intermetalliques avec les metaux alcalins (phases de zintl), les elements du groupe 13 (ga, in, tl) forment des architectures macroanioniques contenant des clusters. Les elements electronegatifs reduits par les metaux alcalins adaptent leur mode de liaison et leur coordination au nombre global d'electrons de valence dans la structure. Dans le cadre de ce travail, une phase ternaire et cinq phases quaternaires ont ete caracterisees et etudiees. L'icosaedre, unite de base des reseaux anioniques, y est associe a d'autres clusters: cluster tubulaire cd#1#2in#6 dans na#8k#2#3cd#1#2i
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Pelosi, Mathilde. "Nanostructures de silicium et de germanium à partir de précurseurs de Zintl : élaboration, caractérisation et comportement électrochimique." Montpellier 2, 2009. http://www.theses.fr/2009MON20191.

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Ce travail s'inscrit dans le cadre général de l'exploration de nouvelles voies de synthèse originales de nanostructures de silicium ou de germanium. Ces méthodes d'oxydation mettent à profil les fortes propriétés réductrices des phases de Zintl, utilisées comme précurseurs. Aussi bien pour les nanomatériaux de silicium que de germanium, plusieurs voies de synthèse ont été mises au point et ensuite transposées à la synthèse de nanoparticules mixtes germanium/silicium. L'influence des paramètres réactionnels sur l'homogénéité, la forme et la cristallinité des nanostructures a été étudiée. Les ma
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Candolfi, Christophe. "Synthèse, caractérisation physico-chimique et propriétés de transport de composés de type Mo3Sb7." Thesis, Vandoeuvre-les-Nancy, INPL, 2008. http://www.theses.fr/2008INPL041N/document.

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Les préoccupations environnementales actuelles ont conduit à un regain d’intérêt pour la conversion d'énergie par effets thermoélectriques au cours de ces 20 dernières années. Le challenge lié à cette technologie consiste à découvrir des matériaux qui possèdent à la fois une faible conductivité thermique, une forte conductivité électrique et un fort pouvoir thermoélectrique. Les travaux présentés dans ce mémoire se sont orientés vers l'étude de phases cristallines complexes à base de Mo3Sb7. Contrôler finement les propriétés électriques et thermiques de ces matériaux par le biais de substituti
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Oliveira, Elio Thizay Magnavita. "Crescimento e caracterização do composto Zintl Yb11AlSb9." reponame:Repositório Institucional da UFABC, 2015.

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Orientadora: Profa. Dra. Raquel de Almeida Ribeiro<br>Tese (doutorado) - Universidade Federal do ABC, Programa de Pós-Graduação em Física, 2015.<br>O crescente interesse em novos materiais com propriedades eletrônicas promissoras, tais como termoeletricidade e supercondutividade entre outras, tem levado a comunidade científica a estudar intensivamente por muitos anos uma classe de materiais conhecida como compostos Zintl. Nesse sentido que propomos nesta Tese o estudo de novos materiais termoelétricos, caracterizando e avaliando suas propriedades, buscando um melhor entendimento das propriedad
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Candolfi, Christophe Lenoir Bertrand Dauscher Anne. "Synthèse, caractérisation physico-chimique et propriétés de transport de composés de type Mo3Sb7." S. l. : S. n, 2008. http://www.scd.inpl-nancy.fr/theses/2008_CANDOLFI_C.pdf.

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