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Journal articles on the topic 'Zn-Cl'

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Published: 3 June 2025

Last updated: 31 July 2025

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1

Marjani, Katayoun, Mohsen Mousavi, Hamid Reza Khavasi, Maryam Ansari та Hamid Reza Qumi. "(2,2′-Bipyridine-κ2 N,N′)dichlorido(dimethyl sulfoxide-κO)zinc(II)". Acta Crystallographica Section E Structure Reports Online 63, № 11 (2007): m2645. http://dx.doi.org/10.1107/s1600536807047320.

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In the title compound, [ZnCl2(C10H8N2)(C2H6OS)], the Zn atom is five-coordinate, forming a distorted trigonal–bipyramidal geometry involving one Cl atom, one dimethyl sulfoxide O atom and one 2,2′-bipyridine N atom in equatorial positions, with distances Zn—Cl = 2.2863 (7) Å, Zn—O = 2.1024 (15) Å and Zn—N = 2.1546 (16) Å. The axial positions are occupied by the other 2,2′-bipyridine N atom and a Cl atom, with distances N—Zn = 2.1604 (16) Å and Zn—Cl = 2.3123 (7) Å.

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2

Maeda, M., T. Ito, M. Hori, and G. Johansson. "The Structure of Zinc Chloride Complexes in Aqueous Solution." Zeitschrift für Naturforschung A 51, no. 1-2 (1996): 63–70. http://dx.doi.org/10.1515/zna-1996-1-210.

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Abstract The structure of zinc chloride complexes with different ratios of chloride to zinc, formed in concentrated ZnCl2 aqueous solutions, were determined from large-angle X-ray scattering using concentrations of the chloride complexes estimated by complementary Raman spectroscopic measurements. The highest chloro complex, [ZnCl4]2-, is tetrahedral with a Zn-Cl bond length of 2.294(4) Å. The trichloro complex, [ZnCl3]-, which coordinates one water molecule, is pyramidal with the Cl-Zn-Cl angle 111°. The Zn-Cl and the Zn-H2O bonds are 2.282(4) and 1.9 Å, respectively. The two lower complexes,

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3

Lee, Rae Eun, Yeon Do Park та Jong Hwa Jeong. "{Bis[2-(3,5-dimethylpyrazol-1-yl)ethyl]amine-κ2 N,N′}dichloridozinc(II) methanol solvate". Acta Crystallographica Section E Structure Reports Online 63, № 11 (2007): m2679. http://dx.doi.org/10.1107/s1600536807048179.

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In the title compound, [ZnCl2(C14H23N5)]·CH3OH, the Zn atom is coordinated by two N atoms and two Cl atoms in an approximately tetrahedral arrangement. The dihedral angle between the N—Zn—N and Cl—Zn—Cl planes is 89.69 (5)°. The methanol solvent molecule takes part in the formation of the hydrogen-bond system.

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4

Wang, Ya-Rui, та Su-Zhen Luan. "Co-Doping Effects on the Electronic and Optical Properties of β-Ga2O3: A First-Principles Investigation". Materials 18, № 9 (2025): 2005. https://doi.org/10.3390/ma18092005.

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To meet the demands for functional layers in inverted flexible perovskite solar cells, high-performance formamidinium-based perovskite solar cells, and high-performance photodetectors in future applications, it is crucial to appropriately reduce the bandgap of third-generation wide-bandgap semiconductor materials. In this study, we first optimized doping sites through Ag-Cl and Ag-S configurations to establish stable substitution patterns, followed by density functional theory (DFT) calculations using the Generalized Gradient Approximation with the Perdew–Burke–Ernzerhof (GGA-PBE) functional,

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5

Sun, Hu Yuan, Bei Ni Zang, Shuan Liu, Li Juan Sun, and Hui Ji Fan. "Effects of Zn(OH)₂ on Corrosion Behavior of Hot Dipped Zn Coating in Freshwater." Advanced Materials Research 399-401 (November 2011): 152–55. http://dx.doi.org/10.4028/www.scientific.net/amr.399-401.152.

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The corrosion behavior of hot dipped Zn coating in freshwater with and without Zn(OH)2 was investigated through weight loss test, polarization curve and impedance spectroscopy. The morphology of the corroded hot dipped Zn coating was analyzed by SEM, meanwhile, the effect of Cl- on corrosion behavior of hot dipped Zn coating in saturated Zn(OH)2 solution was examined using polarization curve. It was found that corrosion product Zn(OH)2 accelerate the corrosion of coating, Cl- promoted dissolution of anodic coating and incrSubscript texteased the conductance of the solution, and the worst corro

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6

Flörke, Ulrich, Aziza Ahmida, Hans Egold та Gerald Henkel. "Crystal structure of dichloridobis(1,3-diisopropyl-4,5-dimethyl-2H-imidazole-2-thione-κS)zinc(II)". Acta Crystallographica Section E Structure Reports Online 70, № 11 (2014): m384. http://dx.doi.org/10.1107/s1600536814023642.

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The molecular structure of the title compound, [ZnCl2(C11H20N2S)2], shows tetrahedral Zn coordination from two Cl ligands and two thione groups. The Zn—Cl bond lengths differ sligthly at 2.2310 (10) and 2.2396 (11) Å while the Zn—S bond lengths are equal at 2.3663 (9) and 2.3701 (10) Å. The Cl—Zn—Cl angle is 116.04 (4) and S—Zn—S is 101.98 (3)°. All other angles at the central Zn atom range from 108.108 (3) to 110.21 (4)°. The C—S—Zn angles are 100.75 (10) and 103.68 (11)°, the difference most probably resulting from packing effects, as both the C—S and both the S—Zn bonds are equal in each ca

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7

Hoque, Kazi Mirajul, Vazhaikkurichi M. Rajendran, and Henry J. Binder. "Zinc inhibits cAMP-stimulated Cl secretion via basolateral K-channel blockade in rat ileum." American Journal of Physiology-Gastrointestinal and Liver Physiology 288, no. 5 (2005): G956—G963. http://dx.doi.org/10.1152/ajpgi.00441.2004.

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Zn, an essential micronutrient and second most abundant trace element in cell and tissues, reduces stool output when administered to children with acute diarrhea. The mechanism by which Zn improves diarrhea is not known but could result from stimulating Na absorption and/or inhibiting anion secretion. The aim of this study was to investigate the direct effect of Zn on intestinal epithelial ion absorption and secretion. Rat ileum was partially stripped of serosal and muscle layers, and the mucosa was mounted in lucite chambers. Potential difference and short-circuit current were measured by con

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8

Hartle, Matthew D., Mayra Delgado, John D. Gilbertson, and Michael D. Pluth. "Stabilization of a Zn(ii) hydrosulfido complex utilizing a hydrogen-bond accepting ligand." Chemical Communications 52, no. 49 (2016): 7680–82. http://dx.doi.org/10.1039/c6cc01373b.

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Inclusion of a hydrogen bond accepting motif in the secondary coordination sphere of a pyridinediimine ligand enables formation of a stable Zn–SH adduct. We report here reversible coordination of HS<sup>−</sup> to Zn(didpa)Cl<sub>2</sub> to form [Zn(didpa)Cl<sub>2</sub>SH]<sup>−</sup>, which is stabilized by an intramolecular hydrogen bond.

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9

Blake, Alexander J., Daniela Giunta, Jonathan Shannon, Maurizio Solinas, Francesca Walzer та Simon Woodward. "In Search of New Approaches to Asymmetric Conjugate Addition: Screening Studies on the Use of [Zn(bpy*)X(R)] Reagents and α,β-Unsaturated Amide Michael Acceptors". Collection of Czechoslovak Chemical Communications 72, № 8 (2007): 1107–21. http://dx.doi.org/10.1135/cccc20071107.

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Conjugate additions of [Zn(bpy*)Cl(Et)] (bpy* = 4,4'-di-tert-butyl-2,2'-bipyridine) to cyclohex-2-en-1-one are promoted by ZnMe2 in 88% ee but in moderate yield under CuI phosphoramidite catalysis. In the absence of ZnMe2 the [Zn(bpy*)Cl(Et)] is inactive indicating a Schlenk-type equilibrium. Other derivatives of [Zn(bpy*)Cl(R)] (R = Bu, 4-methylbenzyl), prepared in situ from [ZnCl(R)] and the bipyridine give low yields due to competing chloride abstraction. 13C NMR studies indicate facile organo-ligand exchange between [Zn(bpy*)(Et)2] and [Zn(bpy*)Cl2] complexes. In the presence of the bipyri

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10

Liu, Wenke, Lingyan Zha, and Yubin Zhang. "Growth and Nutrient Element Content of Hydroponic Lettuce are Modified by LED Continuous Lighting of Different Intensities and Spectral Qualities." Agronomy 10, no. 11 (2020): 1678. http://dx.doi.org/10.3390/agronomy10111678.

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LED red (R) and blue (B) continuous light (CL) is a potential efficient way to increase plant productivity of plant factory with artificial light (PFAL), but limited information was explored about their effects on plant mineral nutrition. In an environmentally controlled plant factory with artificial light (PFAL), the effects of CL of different intensities and spectral qualities, emitted by R and B LEDs on growth and nutrient element content and accumulation of lettuce (Lactuca sativa L.), were conducted in three hydroponic experiments. Two treatments, normal light (12 h/12 h) and CL (24 h/0 h

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11

Ciccone, Valerio, Arianna Filippelli, Chiara Bacchella, Enrico Monzani, and Lucia Morbidelli. "The Nitric Oxide Donor [Zn(PipNONO)Cl] Exhibits Antitumor Activity through Inhibition of Epithelial and Endothelial Mesenchymal Transitions." Cancers 14, no. 17 (2022): 4240. http://dx.doi.org/10.3390/cancers14174240.

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Exogenous nitric oxide appears a promising therapeutic approach to control cancer progression. Previously, a nickel-based nonoate, [Ni(SalPipNONO)], inhibited lung cancer cells, along with impairment of angiogenesis. The Zn(II) containing derivatives [Zn(PipNONO)Cl] exhibited a protective effect on vascular endothelium. Here, we have evaluated the antitumor properties of [Zn(PipNONO)Cl] in human lung cancer (A549) and melanoma (A375) cells. Metastasis initiates with the epithelial–mesenchymal transition (EMT) process, consisting of the acquisition of invasive and migratory properties by tumor

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12

Gossage, Robert A., Paras N. Yadav, Timothy D. MacInnis, J. Wilson Quail, and Andreas Decken. "Zinc halide oxazoline complexes — The quest for structural diversity." Canadian Journal of Chemistry 87, no. 1 (2009): 368–79. http://dx.doi.org/10.1139/v08-174.

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The synthesis and characterization of 14 ZnX2 (X = Cl or Br) complexes containing aryl-oxazoline (ox) ligands is reported. Eleven of these derivatives have been structurally elucidated in the solid state by single crystal X-ray diffraction methods. The ligands used are 2-(3-R-phenyl)-2-oxazoline (R = Cl or Me), 2-(4-R-phenyl)-2-oxazoline (R = Cl, F, Me or –OMe), and 2-(anisol-2-yl)-4,4-dimethyl-2-oxazoline (7a). All oxazolines, with the exception of 7a, lead to the formation of materials identified as ZnX2(ox)2 upon reaction with ZnX2. A distorted tetrahedral coordination motif around the Zn m

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13

Liu, Jia-Qin, Zhen-Jü Jiang, Zhi-Hong Xu та Yan Zhang. "Poly[chlorido[μ4-2,2′-(2-methyl-1H-benzimidazol-3-ium-1,3-diyl)diacetato]zinc]". Acta Crystallographica Section E Structure Reports Online 68, № 6 (2012): m751. http://dx.doi.org/10.1107/s1600536812020077.

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The title compound, [Zn(C12H11N2O4)Cl] n , contains a centrosymmetric dimetal tetracarboxylate paddle-wheel moiety in which the ZnII atom is square-pyramidally coordinated by four carboxylate O atoms at the basal positions and one Cl− anion at the apical position. Each paddle-wheel unit is joined to four such neighbours through bridging dicarboxylate ligands, producing a two-dimensional undulating layer parallel to (-101). Adjacent sheets are stacked in a parallel fashion to form a three-dimensional supramolecular structure which is stabilized by interlayer π–π interactions between benzene rin

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14

Yao, X., K. Ohtsu, S. Tajima, H. Zama, F. Wang, and Y. Shiohara. "Zn doping in YBCO single crystal by the solute-rich liquid-crystal pulling method." Journal of Materials Research 11, no. 5 (1996): 1120–26. http://dx.doi.org/10.1557/jmr.1996.0143.

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Zn-doped YBa2Cu3O6+δ (YBCO) single crystals were fabricated by the solute-rich liquid-crystal pulling (SRL-CP) method. The Zn content of x ranged from 0.0035–0.029 and almost uniformly distributed in YBa2(Cu1−xZnx)3O6+δ. There is a nearly linear relationship between the added Zn content in the liquid and the analyzed Zn content in the liquid/in the crystal. When the added Zn content Cl was 1.086 at. %, decreasing of growth temperature led to increasing growth rate. However, growth temperature had no obvious effect on the doped Zn content in the crystal Cs, the Zn content in the flux Cl, and th

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15

Royer, Jane E., Keng Hong Tan, and David G. Mayer. "Comparative Trap Catches of Male Bactrocera, Dacus, and Zeugodacus Fruit Flies (Diptera: Tephritidae) With Four Floral Phenylbutanoid Lures (Anisyl Acetone, Cue-Lure, Raspberry Ketone, and Zingerone) in Queensland, Australia." Environmental Entomology 49, no. 4 (2020): 815–22. http://dx.doi.org/10.1093/ee/nvaa056.

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Abstract The male fruit fly attractants, cue-lure (CL) and raspberry ketone (RK), are important in pest management. These volatile phenylbutanoids occur in daciniphilous Bulbophyllum Thouar (Orchidaceae: Asparagales) orchids, along with zingerone (ZN) and anisyl acetone (AA). While these four compounds attract a similar range of species, their relative attractiveness to multiple species is unknown. We field tested these compounds in two fruit fly speciose locations in north Queensland, Australia (Lockhart and Cairns) for 8 wk. Of 16 species trapped in significant numbers, 14 were trapped with

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16

Hu, J. X., S. Karamshuk, J. Gorbaciova, et al. "Enhancing the sensitization efficiency of erbium doped organic complexes by heavy halogen substitution." Journal of Materials Chemistry C 6, no. 26 (2018): 7012–17. http://dx.doi.org/10.1039/c8tc00971f.

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17

Govindaraj, J., S. Thirumurugan, D. Snehalatha Reddy, K. Anbalagan та A. SubbiahPandi. "Crystal structure of dichloridobis(4-ethylaniline-κN)zinc". Acta Crystallographica Section E Crystallographic Communications 71, № 2 (2015): m21—m22. http://dx.doi.org/10.1107/s2056989014027832.

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The title compound, [ZnCl2(C8H11N)2], was synthesized by the reaction of zinc dichloride and 4-ethylaniline. The Zn2+cation is coordinated by two Cl−anions and the N atoms of two 4-ethylaniline ligands, forming a distorted Zn(N2Cl2) tetrahedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N—H...Cl hydrogen bonds link the molecules into sheets perpendicular to theaaxis. C—H...Cl interactions also occur.

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18

Altowyan, Mezna Saleh, Eman M. Fathalla, Dalia Hawas, et al. "Synthesis, X-ray, Hirshfeld, and AIM Studies on Zn(II) and Cd(II) Complexes with Pyridine Ligands." Crystals 12, no. 5 (2022): 590. http://dx.doi.org/10.3390/cryst12050590.

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The synthesis and crystal structures of three heteroleptic complexes of Zn(II) and Cd(II) with pyridine ligands (ethyl nicotinate (EtNic), N,N-diethylnicotinamide (DiEtNA), and 2-amino-5-picoline (2Ampic) are presented. The complex [Zn(EtNic)2Cl2] (1) showed a distorted tetrahedral coordination geometry with two EtNic ligand units and two chloride ions as monodentate ligands. Complexes [Zn(DiEtNA)(H2O)4(SO4)]·H2O (2) and [Cd(OAc)2(2Ampic)2] (3) had hexa-coordinated Zn(II) and Cd(II) centers. In the former, the Zn(II) was coordinated with three different monodentate ligands, which were DiEtNA,

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19

Carballo, Rosa, Alfonso Castiñeiras, and Teresa Pérez. "Group 12 Metal Complexes of 2-Formylpyrrole-(4PL1) and 2-Acetylpyrrole-N(4)-phenylthiosemicarbazone (4Pl2), as Examples form Different Donor Modes. Crystal and Molecular Structures of [Hg(4PL1- H)Br]2 and [Zn(4PL2)2Br2] · 2 EtOH." Zeitschrift für Naturforschung B 56, no. 9 (2001): 881–88. http://dx.doi.org/10.1515/znb-2001-0904.

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Abstract The reactions of 4N-phenyl-2-[ 1 -(pyrrol-2-yl)methylidene]-hydrazine carbothioamide (4PL1) and 4N-phenyl-2-[l-(pyrrol-2-yl)ethylidene]-hydrazine carbothioamide (4PL2) with Group 12 metal halides afford complexes of types [M(L)2X2] [M = Zn, L = 4PL1 or 4PL2, X = Cl, Br or I; M = Cd, L = 4PL1, and X = Cl, or L = 4PL2 and X = Cl, Br or I] and [M(L)X2] [M = Cd, L = 4PL1, X = Br or I; M = Hg, L = 4PL1 or 4PL2, X = Cl, Br or I]. The new compounds were characterized by elemental analysis, FAB mass spectrometry, IR spectroscopy, and, in the case of sufficiently soluble compounds, 1H, 13C and

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20

Batista, Luana C., Fernanda S. de Souza, Vagner M. de Assis, et al. "Antiproliferative activity and conversion of tachyzoite to bradyzoite of Toxoplasma gondii promoted by new zinc complexes containing sulfadiazine." RSC Advances 5, no. 122 (2015): 100606–17. http://dx.doi.org/10.1039/c5ra17690e.

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Here we describe the synthesis and biological effect against Toxoplasma gondii of two new zinc complexes containing sulfadiazine: [(SDZ)Zn(μ-BPA)<sub>2</sub>Zn(SDZ)] 1 and [Zn(SDZ)(HSDZ)(Cl)(OH<sub>2</sub>)] 2, where SDZ is the anion sulfadiazine.

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21

MA, XIYING, and JINWEI SONG. "AN INVESTIGATION OF THE DOPING PROPERTIES OF ZnSe NANOCRYSTALS." International Journal of Modern Physics B 25, no. 27 (2011): 3655–62. http://dx.doi.org/10.1142/s0217979211101752.

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This paper investigates the properties of ZnSe nanocrystals doped with single N , P or As atoms (for p-type doping) or single F , Cl or Br atoms (for n-type doping). The crystals are simulated using the local density functional method. Structures doped with an N or Cl atom remained symmetrical, but some distortion appeared with the other dopants. We found that N is the most efficient acceptor impurity for p-type doping, while Cl is the most suitable impurity for n-type doping. In the case of heavy p-type doping, complex defects such as N Se – Zn – V Se and N Se – Zn int easily form in the stru

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22

Zelenák, V., K. Györyová, and D. Mlynarcík. "Antibacterial and Antifungal Activity of Zinc(II) Carboxylates With/Without N-Donor Organic Ligands." Metal-Based Drugs 8, no. 5 (2002): 269–74. http://dx.doi.org/10.1155/mbd.2002.269.

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The antibacterial and antifungal activity of zinc(II) carboxylates with composition Zn(RCOO)2•nH2O(R =H-, CH3− , CH3CH2CH2- , (CH3)2CH- , XCH2- , X=Cl, Br, I, n=0 or 2), [ZnX2(Nia+CH2COO-)2] (Nia=nicotinamide, X=Cl, Br, I) and [Zn(XCH2COO)2(Caf)2]•2H2O (Car=caffeine, X=Cl, Br) is studied against bacterial strains Staphylococcus aureus, Escherichia coli and yeast Candida albicans. The structural types are assigned to the prepared compounds and the influence of (i) carboxylate chain length, (ii) substitution of hydrogen atom of carboxylate by halogen and (iii) presence of N-donor organic ligands

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23

Zhi, Chunyi. "(Invited) Zn Batteries: Stable Anode and High Energy Cathodes." ECS Meeting Abstracts MA2023-02, no. 4 (2023): 623. http://dx.doi.org/10.1149/ma2023-024623mtgabs.

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Our research focuses on a stable aqueous Zn-based battery with long cycling stability, decent energy density, and ultimate safety performance for large-scale energy storage. To achieve this purpose, we did systematic studies on the Zn metal anode, electrolytes, and new cathode development. For the anode side, we developed a few strategies, including pH value manipulation, ion redistribution coating, gradient coating, etc to induce stable stripping and plating of Zn. Moreover, we also found that a Zn initially plated can be much more stable than the one initially stripped during the subsequent

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24

Chen, Xiao-Ming, Xiao-Chun Huang, Ming-Liang Tong, Ye-Xiang Tong, and Seik Weng Ng. "Synthesis and Crystal Structures of Two Monomeric Zinc(II) Complexes Containing Carboxylate and Aqua Ligands." Australian Journal of Chemistry 50, no. 8 (1997): 865. http://dx.doi.org/10.1071/c97019.

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Two monomeric zinc(II) complexes of betaine (Me3N+CH2CO2¯ = bet), [Zn(bet)2(H2O)Cl] (ClO4) (1) and [Zn(bet)3(H2O)] (ClO4)2 (2), have been prepared and characterized by single-crystal structural analysis. The zinc atom in both complexes is coordinated in a distorted tetrahedral geometry: the zinc atom in complex (1) is surrounded by one aqua ligand (Zn–O 1·979(3) Å), one chloro ligand (Zn–Cl 2·218(1) Å ) and two monodentate carboxylate groups (Zn–O 1·946(2) Å); the zinc atom in complex (2) is ligated by one aqua ligand (Zn–O 1·997(6) Å) and three monodentate carboxylategroups (Zn–O 1·943(5)–2·1

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25

Kalhor, Payam, Yaqian Wang, and Zhiwu Yu. "The Structures of ZnCl2-Ethanol Mixtures, a Spectroscopic and Quantum Chemical Calculation Study." Molecules 26, no. 9 (2021): 2498. http://dx.doi.org/10.3390/molecules26092498.

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We report in this article the structural properties, spectral behavior and heterogeneity of ZnCl2-ethanol (EtOH) mixtures in a wide-composition range (1:3 to 1:14 in molar ratios), using ATR-FTIR spectroscopy and quantum chemical calculations. To improve the resolution of the initial IR spectra, excess spectroscopy and two-dimensional correlation spectroscopy were employed. The transformation process was suggested to be from EtOH trimer and EtOH tetramer to EtOH monomer, EtOH dimer and ZnCl2-3EtOH complex upon mixing. The theoretical findings showed that increasing the content of EtOH was acco

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Hennings, Erik, Horst Schmidt, and Wolfgang Voigt. "Crystal structures of ZnCl2·2.5H2O, ZnCl2·3H2O and ZnCl2·4.5H2O." Acta Crystallographica Section E Structure Reports Online 70, no. 12 (2014): 515–18. http://dx.doi.org/10.1107/s1600536814024738.

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The formation of different complexes in aqueous solutions is an important step in understanding the behavior of zinc chloride in water. The structure of concentrated ZnCl2solutions is governed by coordination competition of Cl−and H2O around Zn2+. According to the solid–liquid phase diagram, the title compounds were crystallized below room temperature. The structure of ZnCl2·2.5H2O contains Zn2+both in a tetrahedral coordination with Cl−and in an octahedral environment defined by five water molecules and one Cl−shared with the [ZnCl4]2−unit. Thus, these two different types of Zn2+cations form

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27

Dasna, I. Wayan, Dewi Mariyam, Husni Wahyu Wijaya, Ubed Sonai Fahruddin Arrozi, and Sugiarto Sugiarto. "Synthesis, Structural Determination and Antibacterial Properties of Zinc(II) Complexes Containing 4-Aminopyridine Ligands." Indonesian Journal of Chemistry 23, no. 4 (2023): 1108. http://dx.doi.org/10.22146/ijc.82801.

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Three zinc(II) complexes containing 4-aminopyridine (4-NH2py) [Zn(4-NH2py)2(NCS)2] (1), [Zn(4-NH2py)2Cl2] (2), and [Zn(4-NH2py)2(NCS)Cl] (3) were synthesized and characterized by FTIR and single crystal X-ray diffraction. All complexes adopt a slightly distorted tetrahedral geometry with different crystal packing. Complex 1 crystallizes in the orthorhombic Pmmn space group, complex 2 in the monoclinic C2/c space group, and complex 3 in the orthorhombic Pbca space group. Non-covalent interactions such as NC-S···H, -Cl···H, and µ-µ stacking interaction between 4-NH2py and other ligands (NCS− and

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28

Bowmaker, Graham A., Yang Kim, Brian W. Skelton, Alexandre N. Sobolev, and Allan H. White. "Structures of 1:1 Mononuclear Adducts of Zinc(II) Halides, ZnX2 (X=Cl, Br, I) and of New Hydrates of 1:1 Adducts of Zinc(II) Nitrate and Sulfate with Aromatic N,N′′-Bidentate Base Derivatives of Pyridine (bpy, phen)." Australian Journal of Chemistry 73, no. 6 (2020): 511. http://dx.doi.org/10.1071/ch19365.

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Single crystal X-ray structure determinations have been executed for several title compounds of the mononuclear form [LMX2], namely [(bpy)ZnX2], X=Cl, Br; [(phen)ZnX2], X=Cl, Br, I (bpy=2,2′-bipyridine; phen=1,10-phenanthroline). Also reported are the crystal structures of ZnSO4/bpy/H2O (1:1:5) (≡ [(bpy)Zn(OH2)4](SO4)·H2O) and Zn(NO3)2/bpy/H2O (1:1:3) (≡ [(bpy)Zn(OH2)3(ONO2)](NO3)). The sulfate complex completes the array [LM(OH2)4]2+, L=bpy, phen, M=Zn, Cd, while the nitrate is the first nitrate example for [LM(OH2)3(OX)](+) (OX=ONO2, OSO3). In all examples of the sulfate and nitrate forms he

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Crespo, Cecilia, Pablo Barbieri, Matías Cuervo, and María Pía Rodriguez. "Fertilización con zinc, cobre y cloro en el cultivo de trigo en el sudeste bonaerense." Revista de la Facultad de Agronomía 120, no. 2 (2021): 076. http://dx.doi.org/10.24215/16699513e076.

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La fertilización con nitrógeno (N), fósforo (P) y azufre (S) es una práctica frecuente en la producción de trigo (Triticum aestivum L.), sin embargo, micronutrientes como zinc (Zn), cobre (Cu) y cloro (Cl) pueden ser deficientes en el suelo y limitar las funciones metabólicas de las plantas en sistemas productivos extensivos. El objetivo de este trabajo fue explorar la respuesta a la fertilización con Zn, Cu y Cl sobre la acumulación de materia seca (MS) y N, el rendimiento en grano y el contenido de proteína en el cultivo de trigo. La experiencia se llevó a cabo en la Estación Experimental Ag

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30

Dong, Xinxin, Bo Wei, Dominik Legut, Haijun Zhang, and Ruifeng Zhang. "Electrochemical Pourbaix diagrams of Mg–Zn alloys from first-principles calculations and experimental thermodynamic data." Physical Chemistry Chemical Physics 23, no. 35 (2021): 19602–10. http://dx.doi.org/10.1039/d1cp02754a.

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The first-principles informed Pourbaix diagrams of Mg–Zn alloys in pure water and in Cl-containing solutions were constructed and the corrosion behaviours of the alloys were discussed, and the effects of the second phases and Cl− were explored.

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31

Zakiyya, Hanna, and Tamás Kékesi. "Anion exchange separations to produce a suitable electrolyte for the electrodeposition of pure zinc." Multidiszciplináris tudományok 12, no. 3 (2022): 127–38. http://dx.doi.org/10.35925/j.multi.2022.3.12.

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Anion exchange separations have been devised to purify model solutions of the usual pickling liquor (SPL) obtained from hot dip galvanization to produce a suitable ZnCl2 electrolyte for electrodepositing pure Zn. The method was based on the established anion-exchange distribution functions in chloride media. Both the simple batch and the more accurate chromatographic methods of separation were examined. The loaded solutions contained Zn, Fe, Mn, Ni and Pb of different concentrations with 1.8 - 2 M NaCl or HCl as the background. The resin bed primarily retained Zn while divalent Fe, Mn and Ni w

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32

Gauzzi, Teodoro, Leonardo Martins Graça, Leonardo Lagoeiro, Isolda de Castro Mendes, and Gláucia Nascimento Queiroga. "The fingerprint of imperial topaz from Ouro Preto region (Minas Gerais state, Brazil) based on cathodoluminescence properties and composition." Mineralogical Magazine 82, no. 4 (2018): 943–60. http://dx.doi.org/10.1180/minmag.2017.081.078.

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ABSTRACTA study of the cathodoluminescence (CL) properties of imperial topaz from Ouro Preto region (Minas Gerais state, Brazil) and its relation with trace-element composition was conducted, using scanning electron microscope cathodoluminescence (SEM-CL), optical microscope cathodoluminescence (OM-CL), cathodoluminescence-spectrometry (CL-spectrometry), electron microprobe analysis (EMPA), laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) and Raman spectrometry. Each analytical technique allowed characterization of the imperial topaz fingerprint. SEM-CL panchromatic imag

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33

Meng, Lifen, and Haizhi Wu. "Preparation of carbon quantum dots and their application in the detection of vitamin B2." RSC Advances 14, no. 22 (2024): 15499–506. http://dx.doi.org/10.1039/d4ra01388c.

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34

Morais, M. G., L. C. Gonçalves, H. O. S. Lopes, M. F. V. Costa, and A. B. Nunes. "Variação sazonal de eletrólitos no sangue de vacas aneloradas sob pastejo contínuo de Brachiaria decumbens." Arquivo Brasileiro de Medicina Veterinária e Zootecnia 52, no. 2 (2000): 105–11. http://dx.doi.org/10.1590/s0102-09352000000200004.

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Durante 13 meses foram acompanhadas as mudanças sazonais dos eletrólitos cálcio (Ca), fosfatos (PO4), potássio (K), cloretos (Cl), cobre (Cu) e zinco (Zn) no sangue de 20 de vacas "aneloradas" mantidas sob pastejo contínuo de Brachiaria decumbens com alta taxa de lotação. As vacas apresentaram-se hipocalcêmicas e hipofosfatêmicas durante praticamente todo o ano. Na primavera, com a brotação dos pastos (novembro e dezembro), vacas mantidas em pastos de solo argiloso foram mais propensas à alcalose metabólica, caracterizada por hipocalemia e hipocloremia, do que vacas mantidas em pastos de solo

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35

Kim, Young-Inn, You-Soon Lee, Hoe-Joo Seo, Jin-Young Lee, and Sung Kwon Kang. "[Bis(2-pyridylmethyl)amine]dichloridozinc(II) chloroform solvate." Acta Crystallographica Section E Structure Reports Online 63, no. 11 (2007): m2810—m2811. http://dx.doi.org/10.1107/s1600536807051422.

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The Zn atom in the title complex, [ZnCl2(C12H13N3)]·CHCl3, adopts a distorted square-pyramidal geometry, being coordinated by three N atoms of the tridentate dipicolylamine ligand and two Cl atoms. Intermolecular N—H...Cl hydrogen-bonding interactions link the molecules into centrosymmetric dimers.

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36

Colibaba, G. V., D. Rusnac, V. Fedorov, et al. "ZnO thin films co-doped with III-valence metals and halogens: theory and experiment." Physica Scripta 99, no. 10 (2024): 105967. http://dx.doi.org/10.1088/1402-4896/ad74ab.

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Abstract The efficiency of metal-halogen co-doping of ZnO thin films deposited by DC magnetron sputtering of ceramic targets has been studied theoretically and experimentally. The influence of deposition temperature (300 − 900 K range), ZnX2 pressure (10−10−1 atm), Me2O3 dopant concentration (10−3 − 10 mol %), and Zn pressure (10−14 − 10−6 atm) on the composition of ZnO − Me2O3 − ZnX2 − Zn (Me = Al, Ga, In; X = F, Cl, Br, I) systems has been analyzed theoretically. The surface migration velocity of oxides and halides is also estimated for a wide temperature range. According to the calculation

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37

Ibrahim, R., M. S. Dauda, N. C. Igwemmar, and F. Adebisi. "Study on physicochemical and levels of selected metals in the soils of Abuja Metropolis, Nigeria." Science World Journal 19, no. 2 (2024): 432–39. http://dx.doi.org/10.4314/swj.v19i2.20.

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A study of Abuja soils was carried out to determine physicochemical parameters and levels of selected metals. Flame atomic absorption spectrometer was used to determine total metal concentration. Aqua-regia (HCl-HNO3-H2O in the ratio 1:1:1) for the determination of the concentrations of Zn, Mn, Cu and As in the soils was employed also. Range of urban soil parameters were: electrical conductivity(16.20±0.20-374±0.50), pH(6.30±0.30-7.20±0.20), SO4(7.40±0.40-127.35±0.07)and Cl (25.02±0.02-65.05±0.01). Range of parameters in sub urban soil samples were: EC(12.10±0.10–269.05±0.05), pH(2.20±0.20-7.2

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Yang, Jie, Lei Shen, Cheng Ji, Xiao-Feng Shen та Gao-Weng Yang. "Tetraaquabis(N,N-dimethylformamide-κO)zinc(II) bis[(2-{3-[2-(carboxylatomethoxy-κ2 O,O′)phenyl]pyrazol-1-yl-κN 2}acetato-κO)chloridozincate(II)]". Acta Crystallographica Section E Structure Reports Online 68, № 6 (2012): m817. http://dx.doi.org/10.1107/s1600536812023045.

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The asymmetric unit of the title compound, [Zn(C3H7NO)2(H2O)4][Zn(C13H10N2O5)Cl]2, is composed of a single anion and half a cation. The ZnII atom in the monoanion has a distorted triganol–pyramidal geometry, being coordinated by three O atoms and one N atom from one 2-{3-[2-(carboxylatomethoxy)phenyl]pyrazol-1-yl}acetate ligand and one Cl atom. In the dication, the ZnII atom is located on an inversion center and is coordinated by six O atoms in a slightly distorted octahedral geometry. In the crystal, the ions are linked by O—H...O hydrogen bonds, forming a two-dimensional network lying parall

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Moon, Dohyun, Md Abdus Subhan та Jong-Ha Choi. "Bis[trans-dichloridobis(propane-1,3-diamine-κ2 N,N′)chromium(III)] tetrachloridozincate determined using synchrotron radiation". Acta Crystallographica Section E Structure Reports Online 68, № 6 (2012): m832. http://dx.doi.org/10.1107/s1600536812023355.

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In the title compound, [CrCl2(C3H10N2)2]2[ZnCl4], the CrIII atom is coordinated by four N atoms of propane-1,3-diamine (tn) and two Cl atoms in a trans arrangement, displaying a distorted octahedral geometry with crystallographic inversion symmetry; the Zn atom in the [ZnCl4]2− anion lies on a -4 axis. The orientations of the two six-membered chelate rings in the complex cation are in an anti chair–chair conformation with respect to each other. The Cr—N bond lengths are 2.087 (6) and 2.097 (6) Å. The Cr—Cl and Zn—Cl bond lengths are 2.3151 (16) and 2.3255 (13) Å, respectively. Weak intermolecu

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40

Ai, Tian, Xiaojun Jiang, Qingyu Liu, Linlin Lv, and Shujuan Dai. "Single-component and competitive adsorption of tetracycline and Zn(ii) on an NH4Cl-induced magnetic ultra-fine buckwheat peel powder biochar from water: studies on the kinetics, isotherms, and mechanism." RSC Advances 10, no. 35 (2020): 20427–37. http://dx.doi.org/10.1039/d0ra02346a.

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Single-component and competitive adsorption of tetracycline (TC) and Zn(ii) on an NH<sub>4</sub>Cl-induced magnetic ultra-fine buckwheat peel powder biochar (NH<sub>4</sub>Cl-BHP-char/Fe<sub>3</sub>O<sub>4</sub>) was investigated in batch experiments.

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41

Parajón-Costa, Beatriz S., Gustavo A. Echeverría, Oscar E. Piro, and Enrique J. Baran. "Synthesis and Characterization of a Zinc(II) Complex of Bispicen." Zeitschrift für Naturforschung B 68, no. 12 (2013): 1327–32. http://dx.doi.org/10.5560/znb.2013-3193.

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The synthesis of a Zn(II) complex of bispicen, the tetradentate ligand N,N′-bis(2-pyridylmethyl)- ethylenediamine, of composition [Zn(bispicen)Cl(H2O)]2[ZnCl4] is reported. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2=c with Z =4 molecules per unit cell. The Zn(II) cation in the [Zn(bispicen)Cl(H2O)]+ complex is in a distorted octahedral environment, coordinated to a neutral bispicen molecule acting as a tetradentate ligand through its two amine nitrogen atoms, at cis positions, and its two pyri

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42

Pickardt, Joachim, and Benedikt Staub. "Supram olekulare chloridverbrückte Metall(II)chlorid-Diazin-Komplexe: Kristallstrukturen von [Cd(pyrazin)Cl2], [Zn(pyrazin)Cl2] und [Zn(pyrimidin)C l2] / Supram olecular Chloride Bridged Metal(II) Dichloride Diazine Complexes: Crystal Structures of [Cd(pyrazine)Cl2], [Zn(pyrazine)Cl2], and [Zn(pyrimidine)Cl2]." Zeitschrift für Naturforschung B 51, no. 7 (1996): 947–51. http://dx.doi.org/10.1515/znb-1996-0707.

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Single crystals of [Cd(pyrazine)Cl2],[Zn(pyrazine)Cl2] and [Zn(pyrimidine)Cl2] were obtained by a diffusion technique from aqueous solutions of the metal dichlorides and solutions of the respective diazine.The structures consist of “supramolecular” networks of-M-Cl-M - and -M-diazine-M-chains.

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Terranova, Zachary L., and Francesco Paesani. "The effects of framework dynamics on the behavior of water adsorbed in the [Zn(l-L)(Cl)] and Co-MOF-74 metal–organic frameworks." Physical Chemistry Chemical Physics 18, no. 11 (2016): 8196–204. http://dx.doi.org/10.1039/c5cp07681a.

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44

DING, Zhi-ying, Qi-yuan CHEN, Zhou-lan YIN, and Kui LIU. "Predominance diagrams for Zn(II)–NH3–Cl−−H2O system." Transactions of Nonferrous Metals Society of China 23, no. 3 (2013): 832–40. http://dx.doi.org/10.1016/s1003-6326(13)62536-4.

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45

Alonso, Ruben, Elena Bermejo, Rosa Carballo, Alfonso astiñeiras, and Teresa Pérez. "Synthesis and Structural Characterization of Metal Complexes of 2-Formylpyrrole 4N-Methylthiosemicarbazone (4ML1) and 2-Acetyl- pyrrole 4N-Methylthiosemicarbazone (4ML2). The X-Ray Crystal Structures of [Ni(4ML1-H)2], [Pd(4ML1-H)2] and [Cd(4ML2)2I2]." Zeitschrift für Naturforschung B 56, no. 3 (2001): 219–28. http://dx.doi.org/10.1515/znb-2001-0301.

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Abstract Reaction of 4N-methyl-2-[1-(pyrrol-2-yl)methylidene]hydrazinecarbothioamide (4ML1 and 4N-methyl-2-[1-(pyrrol-2-yl)-ethylidene]hydrazine carbothioamide (4ML1) with zinc(II), cadmium(II) and mercury(II) halides afforded complexes with formulas [M(L)X2] [(L; M; X) =(4ML1; Cd; Cl) (4), (4ML1; Hg; Cl, Br, I) (7 - 9), (4ML2; Cd; Cl) (17), (4ML2; Hg; Cl, Br, I) (20 - 22)] or [M(L)2X2] [(L; M; X) = (4ML1; Zn; Cl, Br, I) (1 - 3), (4ML1; Cd; Br, I) (5, 6), (4ML2; Zn; Cl, Br, I) (14 - 16), (4ML2; Cd; Br, I) (18, 19)]. Reaction of 4ML1 with salts of copper(II), nickel(II), palladium(II) and plati

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Mahjoubi, F. Z., A. Khalidi, O. Cherkaoui, R. Elmoubarki, M. Abdennouri, and N. Barka. "Treatment of textile effluents by chloride-intercalated Zn-, Mg- and Ni-Al layered double hydroxides." Journal of Water Reuse and Desalination 7, no. 3 (2016): 307–18. http://dx.doi.org/10.2166/wrd.2016.041.

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This work involved the preparation, characterization and dyes removal ability of Zn-Al, Mg-Al and Ni-Al layered double hydroxide (LDH) minerals intercalated by chloride ions. The materials were synthetized by the co-precipitation method. X-ray diffraction, Fourier transform infrared, thermogravimetric-differential thermal analysis and transmission electron microscopy characterization exhibited a typical hydrotalcite structure for all the samples. Adsorption experiments for methyl orange were performed in terms of solution pH, contact time and initial dye concentration. Experimental results ind

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47

Tian, Zhimei, Chongfu Song, and Hai Wu. "Density Functional Study to Investigate the Ability of (ZnS)n (n = 1–12) Clusters Removing Hg0, HgCl, and HgCl2 via Electron Localization Function and Non−Covalent Interactions Analyses." Molecules 28, no. 3 (2023): 1214. http://dx.doi.org/10.3390/molecules28031214.

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In this study, the density functional theory is used to study the ability of (ZnS)n clusters to remove Hg0, HgCl, and HgCl2 and reveals that they can be absorbed on (ZnS)n clusters. According to electron localization function (ELF) and non−covalent interactions (NCI) analyses, the adsorption of Hg0 on (ZnS)n is physical adsorption and the adsorption ability of (ZnS)n for removing Hg0 is weak. When (ZnS)n adsorbs HgCl and HgCl2, two new Hg−S and Zn−Cl bonds form in the resultant clusters. An ELF analysis identifies the formation of Hg−S and Zn−Cl bonds in (ZnS)nHgCl and (ZnS)nHgCl2. A partial d

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48

Zaichick, Vladimir. "Differences of Relationships between Iodine and Some Chemical Elements in Normal Thyroid and Thyroid Benign Nodules Revealed by Neutron Activation and Inductively Coupled Plasma Atomic Emission Spectrometry." Women's Health Science Journal 7, no. 1 (2023): 1–18. http://dx.doi.org/10.23880/whsj-16000173.

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Thyroid benign nodules (TBN) are the most common lesions of this endocrine gland. The etiology of TBN is not clear. The aim of this exploratory study was to examine differences in the content of such chemical elements (ChEs) as Al, B, Ba, Br, Ca, Cl, Cu, Fe, I, K, Li, Mg, Mn, Na, P, S, Si, Sr, V and Zn, as well as differences in I/ChEs content ratios in tissues of normal thyroid and TBN. Thyroid tissue levels of ChEs were prospectively evaluated in 105 apparently healthy persons and in 79 patients with TBN. Measurements were performed using neutron activation analysis combined with inductively

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49

Omokaro, Godspower Oke, Constance Odinakachukwu Ojie, Emmanuel Stephen Otas, and Precious Aghogho Onakpoma. "Macro and Micronutrient Status under Different Land Use Types in the University of Benin." International Journal of Precision Farming 1, no. 1 (2023): 42–49. http://dx.doi.org/10.54536/ijpf.v1i1.2242.

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This experiment was conducted to ascertain the macro and micronutrient status of soils under different land uses: Arable, Fallow, Residential, and Silvicultural land. Three different sites were carefully selected for each land use (replicates). Auger points were taken at 0-15 cm and 15-30 cm depths for each location, and samples were collected for laboratory analysis. Parameters measured included pH, TOC, TN, Av. P, K, Ca, Mg, Na, S-SO4, B, Cl, Cu, Fe, Mn, Mo, Zn, and soil particle contents. Results showed that pH in the top 15 cm ranged from very slightly acidic in silviculture and arable lan

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50

Vershinin, Mikhail A., Marianna I. Rakhmanova, Alexander S. Novikov, Maxim N. Sokolov, and Sergey A. Adonin. "Zn(II) Heteroleptic Halide Complexes with 2-Halopyridines: Features of Halogen Bonding in Solid State." Molecules 26, no. 11 (2021): 3393. http://dx.doi.org/10.3390/molecules26113393.

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Reactions between Zn(II) dihalides and 2-halogen-substituted pyridines 2-XPy result in a series of heteroleptic molecular complexes [(2-XPy)2ZnY2] (Y = Cl, X = Cl (1), Br (2), I (3); Y = Br, X = Cl (4), Br (5), I (6), Y = I, X = Cl (7), Br (8), and I (9)). Moreover, 1–7 are isostructural (triclinic), while 8 and 9 are monoclinic. In all cases, halogen bonding plays an important role in formation of crystal packing. Moreover, 1–9 demonstrate luminescence in asolid state; for the best emitting complexes, quantum yield (QY) exceeds 21%.

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