Academic literature on the topic 'Zn(II) Spectroscopic'

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Journal articles on the topic "Zn(II) Spectroscopic"

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Al-Rasbi, Nawal K., Bushra AlWihibi, and Nada AlNofali. "Synthesis and spectroscopic properties of a fluorosensor for Zn2+ ions." Sultan Qaboos University Journal for Science [SQUJS] 19, no. 1 (2014): 8. http://dx.doi.org/10.24200/squjs.vol19iss1pp8-14.

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The new Schiff base ligand L: (E)-N'-(pyridin-2-ylmethylene)acetohydrazide, was synthesized, and its reaction with Zn(II) ions form the complex: [ZnL2](ClO4)2, as confirmed by X-ray crystallography. This complex is stable in polar and non-polar solvents as proven by NMR. A significant enhancement in the fluorescence was observed from L upon coordination to Zn(II) ions over other transition metals such as Fe(II), Co(II), Ni(II), Cu(II), Cd(II) and Ag(I). These results suggest that L can be used as a selective flourosensor for the detection of Zn(II) ions.
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Spinu, Cezar, Angela Kriza, Aurelia Meghea, and Cristian Tigae. "STUDIES ON N-[2-THIENYLMETHYLIDENE)-2-AMINOPYRIDINE COMPLEXES OF Fe(II), Co(II), Ni(II), Cu(II), Zn(II) AND Cd(II)." SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 9, no. 10 (2001): 17–22. http://dx.doi.org/10.48141/sbjchem.v9.n10.2001.20_2001.pdf.

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Metal complexes ML2Cl2, where M is Fe(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) and L is Schiff base formed by condensation of 2-thiophenecarboxaldehyde and 2-aminopyridine, N-[2-thienylmethylidene]-2-arninopyridine (TNAPY), have been prepared and characterized by elemental analysis, magnetic and spectroscopic measurements. IR and NMR spectra show that the nitrogen of the azomethyne group and the sulphur of the thiophene ring take part in coordination. Magnetic, ESR and electronic spectral studies show a distorted octahedral structure for the Fe(II), Co(II), Ni(II) and Cu(II) complexes an
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Odunola, Olusegun A. "Spectroscopic and Magnetic Properties of Zn(II), Cd(II) and Hg(II) Carboxylates." Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 23, no. 8 (1993): 1241–49. http://dx.doi.org/10.1080/15533179308016683.

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Mansour, Ahmed M. "Terpyridine Zn(II) azide compounds: Spectroscopic and DFT calculations." Journal of Molecular Structure 1242 (October 2021): 130737. http://dx.doi.org/10.1016/j.molstruc.2021.130737.

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Konstantinovic, Sandra, Blaga Radovanovic, Zivojin Cakic, and Vesna Vasic. "Synthesis and characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes with 3-salicylidenehydrazono-2-indolinone." Journal of the Serbian Chemical Society 68, no. 8-9 (2003): 641–47. http://dx.doi.org/10.2298/jsc0309641k.

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Complexes of Co(II), Ni(II), Cu(II) and Zn(II) with 3-salicylidenehydrazono-2-indolinone were prepared. Their structure was established to be [MLCl].Cl by using elemental analysis and molar conductivity, as well as AA, FTIR, UV/VIS and 1H-NMR spectroscopic methods. The spectral studies indicated a square-planar geometry for the Ni(II) and Cu(II) complexes and a tetrahedral one for the Co(II) and Zn(II) complexes. The complexes were tested for antibacterial activity against Staphylococcus aureus, Enterococcus D, Proteus mirabilis, Escherichia coli, Bacillus anthracis, Pseudomonas aeruginosa and
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Guney Eskiler, Gamze, and Ibrahim Kani. "In vitro apoptotic effect of Zinc(II) complex with N-donor heterocyclic ligand on breast cancer cells." Turkish Journal of Biochemistry 44, no. 6 (2019): 761–68. http://dx.doi.org/10.1515/tjb-2019-0013.

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Abstract Background The synthesis of new ligand and transition metal complexes have drawn great attention in cancer treatment due to excellent DNA cleavage activities and high antitumor activity. Objective The purpose of this study was to synthesize a new Zn(II) complex with 2,2′-bipyridine (bpy) ligand, [Zn(bpy)2(H2O)]2(ClO4), and to investigate the potential therapeutic activity against breast cancer. Materials and methods Zn(II) complex was obtained and structurally characterized using crystallography and other spectroscopic methods. The cytotoxic and apoptotic effects of Zn(II) complex on
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Journal, Baghdad Science. "Preparation and Characterization of Cu (II), Mn(II) and Zn(II)complexes with new sulfamethoxazole Compounds." Baghdad Science Journal 14, no. 3 (2017): 575–81. http://dx.doi.org/10.21123/bsj.14.3.575-581.

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Acetophenone sulfamethoxazole and 3-Nitrobenzophenone sulfamethoxazole were prepared from the reaction of sulfamethoxazole with two ketones. The prepared ligands were identified by (C.H.N) analysis and UV-VIS, FT-IR spectroscopic techniques. Metal complexes of the two ligands were prepared in an aqueous alcohol with Zn (II), Mn (II) and Cu (II) ions with a molar ratio1:1. The proposed general formula for the resulting complexes was [ML.CL2.H2O]H2O .The complexes were characterized by (C.H.N) technique , spectroscopic methods ,conductivity, atomic absorption ,magnetic susceptibility measurement
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Turan, Nevin, Kenan Buldurun, Naki Çolak, and İsmail Özdemir. "Preparation and spectroscopic studies of Fe(II), Ru(II), Pd(II) and Zn(II) complexes of Schiff base containing terephthalaldehyde and their transfer hydrogenation and Suzuki-Miyaura coupling reaction." Open Chemistry 17, no. 1 (2019): 571–80. http://dx.doi.org/10.1515/chem-2019-0074.

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AbstractThis study describes synthesis, spectroscopic characterization and catalytic activities of Fe(II), Ru(II), Pd(II) and Zn(II) complexes with a novel Schiff base ligand (L) derived from methyl 2-amino-5,5,7,7-tetramethyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate and terephthalaldehyde. We used spectroscopic techniques including IR, UV-Vis, 1H-NMR, 13C-NMR, elemental analysis and also mass analysis and magnetic susceptibility measurements to identify the products. The Pd(II) complex was used as a potential catalyst for Suzuki-Miyaura coupling reaction of some aryl halides under op
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Yan, Yupeng, Biao Wan, Yanyi Zhang, Limei Zhang, Fan Liu, and Xionghan Feng. "In situ ATR-FTIR spectroscopic study of the co-adsorption of myo-inositol hexakisphosphate and Zn(II) on goethite." Soil Research 56, no. 5 (2018): 526. http://dx.doi.org/10.1071/sr17333.

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The coexistence of myo-inositol hexakisphosphate (IHP; phytate) and aqueous Zn(II) may affect the adsorbed amounts and speciation of each other on minerals, which can further influence the transport and fate of IHP and Zn(II) in soils and sediments. The objective of this study was to investigate the co-adsorption mechanism of IHP and Zn(II) on goethite (Gt). A combination of macroscopic experiments and in situ attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) was used to investigate the co-adsorption of IHP and Zn(II) at the Gt–water interface in the pH range of 3
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Salman, Mahmoud, Moamen S. Refat, Sabry A. El-Korashy, and Mostafa A. Hussien. "Synthesis and spectroscopic characterization of Zn(II), Cd(II), and Hg(II) ciprofloxacin complexes." Russian Journal of General Chemistry 84, no. 9 (2014): 1841–46. http://dx.doi.org/10.1134/s1070363214090345.

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Dissertations / Theses on the topic "Zn(II) Spectroscopic"

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Breece, Robert M. "Spectroscopic Characterization of Co(II)-Substituted VanX, a Zn(II)-Dependent Dipeptidase Required for High-Level Vancomycin Resistance." Miami University / OhioLINK, 2004. http://rave.ohiolink.edu/etdc/view?acc_num=miami1077576564.

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Zhenxin, Hu. "KINETIC AND SPECTROSCOPIC STUDIES OF L1, THE METALLO-β-LACTAMASE FROM Stenotrophomonas maltophilia". Miami University / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=miami1218136291.

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Hu, Zhenxin. "Kinetic and spectroscopic studies of L1, the metallo-[beta]-lactamase from Stenotrophomonas maltophilia." Oxford, Ohio : Miami University, 2008. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=miami1218136291.

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MENDES, MARIA ROSANGELA DE VASCONCELOS. "SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC STUDY ON A NEW LIGAND DERIVED FROM BARBITURIC ACID AND ISONIAZID AND ITS COORDINATION COMPOUNDS WITH THE TRANSITION METAL IONS ZN(II) AND CU(II)." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2016. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=32444@1.

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PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO<br>COORDENAÇÃO DE APERFEIÇOAMENTO DO PESSOAL DE ENSINO SUPERIOR<br>PROGRAMA DE SUPORTE À PÓS-GRADUAÇÃO DE INSTS. DE ENSINO<br>O presente trabalho trata da síntese, caracterização e estudo espectroscópico de novo ligante derivado da reação do ácido barbitúrico e isoniazida e seus respectivos complexos de zinco e cobre que foram todos igualmente estudados. Foi proposto um roteiro de síntese em meio aquoso utilizando metodologia gráfica para delinear as melhores condições de obtenção dos produtos. Um estudo espectroscópico completo dos reagentes
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Germino, José Carlos 1990. "Propriedades luminescentes de compostos de coordenação de Zn(II)." [s.n.], 2014. http://repositorio.unicamp.br/jspui/handle/REPOSIP/249465.

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Orientador: Teresa Dib Zambon Atvars<br>Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Química<br>Made available in DSpace on 2018-08-27T20:25:11Z (GMT). No. of bitstreams: 1 Germino_JoseCarlos_M.pdf: 14479907 bytes, checksum: c9f86b7bc1995a755d797d3af0c41cfc (MD5) Previous issue date: 2014<br>Resumo: Nesta dissertação foram estudadas as propriedades fotoluminescentes de alguns compostos de coordenação de Zn(II) com N,N'-bis(salicilidenos) em soluções de THF e DMSO e em estado sólido: N,N'-bis(salicilideno)-1,2-fenilenodiamino - salofeno (KG-15) e seu composto de co
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Oliveira, Vanessa End de. "Síntese e caracterização espectroscópica de adutos obtidos com porfirinas, ácido esquárico e os metais de transição Co(II), Ni(II), Cu(II) e Zn(II)." Universidade Federal de Juiz de Fora (UFJF), 2011. https://repositorio.ufjf.br/jspui/handle/ufjf/4235.

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Submitted by Renata Lopes (renatasil82@gmail.com) on 2017-05-10T17:34:50Z No. of bitstreams: 1 vanessaenddeoliveira.pdf: 4675913 bytes, checksum: 04efabd176cdca177cc79c9c59b9b97b (MD5)<br>Approved for entry into archive by Adriana Oliveira (adriana.oliveira@ufjf.edu.br) on 2017-05-11T13:29:07Z (GMT) No. of bitstreams: 1 vanessaenddeoliveira.pdf: 4675913 bytes, checksum: 04efabd176cdca177cc79c9c59b9b97b (MD5)<br>Made available in DSpace on 2017-05-11T13:29:07Z (GMT). No. of bitstreams: 1 vanessaenddeoliveira.pdf: 4675913 bytes, checksum: 04efabd176cdca177cc79c9c59b9b97b (MD5) Previous is
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Dangleterre, Laëtitia. "Apport des spectroscopies moléculaires à l'étude des mécanismes de fixation des ions métalliques polluants par les substances humiques : complexation de Al(III), Pb(II) et Zn(II) par des systèmes modèles." Lille 1, 2007. http://www.theses.fr/2007LIL10068.

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Les substances humiques (SH) sont issues de la dégradation de résidus organiques et représentent la partie la plus importante de la matière organique des systèmes naturels. Les SH sont capables de piéger de nombreux polluants comme les métaux lourds et jouent donc un rôle majeur dans la rétention des ions métalliques. Leurs propriétés complexantes sont dues principalement à certaines fonctions récurrentes : les groupements carboxyliques et phénoliques. Dans une 1ère partie, l'étude de la complexation de molécules modèles possédant des sites similaires à ceux rencontrés dans les biopolymères na
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Dangleterre, Laëtitia. "Apport des spectroscopies moléculaires à l'étude des mécanismes de fixation d'ions métalliques polluants par les substances humiques.Complexation de Al(III), Pb(II) et Zn(II) par des systèmes modèles." Phd thesis, Université des Sciences et Technologie de Lille - Lille I, 2007. http://tel.archives-ouvertes.fr/tel-00366217.

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Les substances humiques (SH) sont issues de la dégradation de résidus organiques et représentent la partie la plus importante de la matière organique des systèmes naturels. Les SH sont capables de piéger de nombreux polluants comme les métaux lourds et jouent donc un rôle majeur dans la rétention des ions métalliques. Leurs propriétés complexantes sont dues principalement à certaines fonctions récurrentes : les groupements carboxyliques et phénoliques.<br />Dans une 1ère partie, l'étude de la complexation de molécules modèles possédant des sites similaires à ceux rencontrés dans les biopolymèr
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Chang, Tsungyi, and 張宗義. "Design, Synthesis, Spectroscopy and Luminescence of Metal-Organic Frameworks of Di- and Tri-pyridylamide Ligands with Cu(I), Cu(II), Zn(II) and Cd(II) Ions." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/12701879212763805305.

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博士<br>國立中正大學<br>化學暨生物化學研究所<br>100<br>The interesting phase transformation, mechanochromic luminescence, and catalytic properties of metal-organic frameworks are presented and discussed in this thesis. In Chapter 1, A 1-D double-zigzag framework, {[Zn(paps)2(H2O)2]•2ClO4}n (1; paps= N,N’-bis(pyridylcarbonyl)-4,4’- diaminodiphenyl thioether), was synthesized by the reaction of Zn(ClO4)2 with paps. However, a similar reaction, except that dry solvents were used, led to the formation of a novel 2-D polyrotaxane framework, [Zn(paps)2(ClO4)2]n (2). This difference relies on the fact that water coor
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Book chapters on the topic "Zn(II) Spectroscopic"

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Stillman, Martin J. "Spectroscopic Properties of Ag(I), Cd(II), Cu(I), Hg(II), and Zn(II) Metallothioneins." In Cytotoxic, Mutagenic and Carcinogenic Potential of Heavy Metals Related to Human Environment. Springer Netherlands, 1997. http://dx.doi.org/10.1007/978-94-011-5780-3_9.

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Daumann, Lena Josefine. "Structural and Mechanistic Studies of Zn(II) Complexes as Phosphoesterase Models." In Spectroscopic and Mechanistic Studies of Dinuclear Metallohydrolases and Their Biomimetic Complexes. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-06629-5_4.

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Daumann, Lena Josefine. "Asymmetric Zn(II) Complexes as Structural and Functional Models for GpdQ." In Spectroscopic and Mechanistic Studies of Dinuclear Metallohydrolases and Their Biomimetic Complexes. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-06629-5_7.

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Yoon, Min-Chul, Sung Cho, and Dongho Kim. "Femtosecond coherent spectroscopic study of Zn(II) porphyrin by chirping-controlled ultrashort pulses." In Springer Series in Chemical Physics. Springer Berlin Heidelberg, 2005. http://dx.doi.org/10.1007/3-540-27213-5_158.

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Kovala-Demertzi, D., E. Theodorou, D. Mentzafos, and A. Terzis. "Metal-Drugs Interactions Spectroscopic Studies of Complexes of Cu(II), Zn(II) and Cd(II) with Diclofenac. A very unusual Structure of Cadmium Diclofenac." In Fifth International Conference on the Spectroscopy of Biological Molecules. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1934-4_93.

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Ishioka, T., Y. Shibata, M. Takahashi, and I. Kanesaka. "Vibrational Spectra and Structure of Zn Soaps II. Normal Mode Analysis of Zinc Acetate Anhydride." In Spectroscopy of Biological Molecules: Modern Trends. Springer Netherlands, 1997. http://dx.doi.org/10.1007/978-94-011-5622-6_275.

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Chirvony, V. S., V. A. Galievsky, S. N. Terekhov, B. M. Dzhagarov, V. V. Ermolenkov, and P. Y. Turpin. "Binding of the cationic 5-coordinate Zn(II)-5, 10, 15, 20-tetrakis(4-N-methylpyridyl) porphyrin (ZnTMpyP4+) to DNA and model polynucleotides: ionic-strength dependent intercalation in [Poly(dG-dC)]2." In Spectroscopy of Biological Molecules: New Directions. Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4479-7_127.

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Jordan, Robert B. "Bioinorganic Systems." In Reaction Mechanisms of Inorganic and Organometallic Systems. Oxford University Press, 2007. http://dx.doi.org/10.1093/oso/9780195301007.003.0010.

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The field of bioinorganic chemistry has grown tremendously in the past 25 years. Much of the work is concerned with establishing the coordination site, ligand geometry and metal oxidation state in biologically active systems. The field also extends to the preparation and characterization of simpler model complexes that mimic the spectroscopic properties and perhaps some of the reactivity of the biological system. Much of this characterization work must precede meaningful mechanistic studies. Williams has provided an interesting overview of metal ions in biology from an inorganic perspective. There are several early review series and specialized journals devoted to the subject, and a recent issue of Chemical Reviews is devoted to the area. There also are several books covering general aspects of the subject. The field is so large and the systems are so individualistic that it is necessary, for the purposes of a text such as this, to choose a few sample systems as illustrative of the mechanistic achievements and problems. Studies of bioinorganic systems inevitably use some terminology from biochemistry which may be unfamiliar to an inorganic chemist. The examples in this Chapter are all metalloenzymes which catalyze some process. Clearly they contain a metal, but there are other components of an enzyme, and terms used to describe these are summarized as follows: An apoenzyme is a polypeptide whose composition, peptide sequence and structure depend on the biological source of the metalloenzyme. Typically, the molar mass of the polypeptide is in the range of 1.5-5xl05 daltons. The polypeptide is folded into coils and sheets whose shape is determined by electrostatics and hydrogen bonding. These terms designate the same type of component, but one or the other is used more commonly for a particular system. This is a nonprotein component which binds to the apoenzyme to produce the active catalyst. It is not covalently bonded to the apoenzyme and can be removed by relatively mild denaturation of the polypeptide. Common bioinorganic examples are coenzyme B12, discussed in Section 8.3, and Zn(II) in carbonic anhydrase, discussed in Section 8.4. A prosthetic group is analogous to a coenzyme except that a prosthetic group is believed to be covalently bonded to the apoenzyme.
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Conference papers on the topic "Zn(II) Spectroscopic"

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Durantini, Edgardo, and Carlos Suchetti. "Synthesis, Spectroscopic Properties and Photodynamic Activity of Zn(II) tetraalkyltetrapyridinoporphyrazinium Derivatives." In The 9th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01482.

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Durantini, Edgardo, and M. Cormick. "Synthesis, spectroscopic properties and photodynamic activity of a novel Zn(II) phthalocyanine substituted by fluconazole." In The 10th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2006. http://dx.doi.org/10.3390/ecsoc-10-01392.

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Bardakci, Tayyibe, Ahmet Altun, and Mustafa Kumru. "QUANTUM CHEMICAL STUDIES ON THE PREDICTION OF STRUCTURES, CHARGE DISTRIBUTIONS AND VIBRATIONAL SPECTRA OF SOME Ni(II), Zn(II), AND Cd(II) IODIDE COMPLEXES." In 71st International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2016. http://dx.doi.org/10.15278/isms.2016.mi15.

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