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1

Wang, Zhou, Zhiting Tang, Xueling Peng, Chuanhui Xia, and Feng Wang. "New viewpoint about the persistent luminescence mechanism of Mn2+/Eu3+ co-doped Zn2GeO4." International Journal of Modern Physics B 33, no. 32 (December 30, 2019): 1950389. http://dx.doi.org/10.1142/s0217979219503892.

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In this work, Mn[Formula: see text]Eu[Formula: see text] co-doped Zn2GeO4 (Zn2GeO4:Mn[Formula: see text] was prepared by high-temperature solid phase method. Compared with common fluorescent materials Zn2GeO4:Mn[Formula: see text], Zn2GeO4:Mn[Formula: see text] could not only emit strong green fluorescence of 535 nm, but also maintain excellent persistent luminescence performance. Through Density Functional Theory calculation, we obtained the fine band structure of Zn2GeO4:Mn[Formula: see text]. The results of the band structure were consistent with the experimental spectral data. On this basis, we proposed a new luminescence mechanism model of Zn2GeO4:Mn[Formula: see text] to explain the phenomena observed in experiment reasonably, though which was not completely consistent with previous works. When Zn2GeO4:Mn[Formula: see text] was excited, electron–hole separation occurred in the valence band (VB), and the electron transitioned to the conduction band (CB) directly. Through CB, the electron was trapped by trap levels (7F[Formula: see text]F5 of Eu[Formula: see text] and maintained metastable for a long time. Under the action of thermal stimulation, electron returned to CB from the trap level slowly. The electron was captured again by the 4T2(D) level of Mn[Formula: see text]. Then the electron transitioned down toward VB and recombined with the previous hole and emitted a photon with 535 nm (afterglow). The samples were being irradiated, trap levels accommodated the excited electrons to saturation. More electrons excited into the CB could not be captured by the trap levels any more. They were captured directly by the 4T2(D) and transitioned directly to VB, then emitted green fluorescence.
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2

TAKAHASHI, YOSHIHIRO, MASATAKA ANDO, RIE IHARA, TAKUMI FUJIWARA, and MINORU OSADA. "NANOCRYSTALLIZATION AND OPTICAL PROPERTY OF WILLEMITE-TYPE SEMICONDUCTIVE Zn2GeO4 IN GLASS." Functional Materials Letters 05, no. 02 (June 2012): 1260008. http://dx.doi.org/10.1142/s1793604712600089.

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A wide band-gap semiconductive oxide Zn2GeO4 has recently attracted considerable interest because it is a multifunctional material; excellent photoluminescent (PL) and photocatalytic property, high-capacity anode for lithium batteries, and so on. Recently, present authors' group have fabricated transparent Zn2GeO4 -nanocrystallized glass from a lithium zincogermanate glass. This article briefly describes a series of our studies on the nanocrystallized glass. Particularly, the phase-formation dynamics in supercooled-liquid phase and PL property of nanocrystallized glasses are presented.
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3

Li, Hong, Yinhai Wang, Lei Li, Haiju Huang, Hui Zhao, and Zhengfa Hu. "Enhanced photocatalytic activity and persistent luminescence in Zn2GeO4:Mn2+ by Eu3+ doping." Modern Physics Letters B 30, no. 27 (October 10, 2016): 1650305. http://dx.doi.org/10.1142/s021798491650305x.

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Zn2GeO4:Mn[Formula: see text],[Formula: see text]Eu[Formula: see text] and Zn2GeO4:Mn[Formula: see text] powders were synthesized by a high-temperature solid-state reaction. X-ray powder diffraction (XRD) and scanning electron microscopy (SEM) were used to characterize the structures and morphologies of the synthesized powders, respectively. The photocatalytic properties and long persistent luminescence performance were improved by Eu[Formula: see text] doping. Thermoluminescent (TL) curves showed that the trap concentration in the material was increased with Eu[Formula: see text] doping, which formed trap centers in Zn2GeO4:Mn[Formula: see text]. The trap centers can capture the electrons or holes and subsequently increase the separation of photogenerated electrons and holes by suppressing the recombination of captured electrons and holes; thus, resulting in an improved photocatalytic activity and a prolonged persistent luminescence. The present strategy may be used as a general method to improve the photocatalytic activity and persistent luminescence.
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4

Xia, Chuanhui, Mu Zhou, Miao He, Liu Yang, Miao Liu, Ping Zhou, Hang Chen, and Feng Wang. "Experimental and theoretical studies on luminescent mechanisms and different visual color of the mixed system composed of MgGeO3:Mn, Eu and Zn2GeO4:Mn." International Journal of Modern Physics B 34, no. 25 (September 8, 2020): 2050216. http://dx.doi.org/10.1142/s0217979220502161.

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In this work, the mixed system composed of Zn2GeO4: Mn and MgGeO3: Mn, Eu was synthesized by the high temperature solid phase method. Under the external excitation, visual color of samples was yellow. However, after the excitation was completed, visual color turned to be red. From luminescence spectrum, it was found that Zn2GeO4: Mn emitted green fluorescence of 534 nm under the excitation of 375 nm light. At the same time, MgGeO3: Mn, Eu emitted both fluorescence and persistent luminescence (PersL) of 668 nm. Moreover, the properties of PersL present samples were superior to other red PersL materials. Fine band structures from density functional theory (DFT) indicated that there were different luminescent mechanisms of Zn2GeO4: Mn and MgGeO3: Mn, Eu. When Zn2GeO4: Mn was excited, electron transitioned from VB to CB directly. Through CB, the electron was captured by the 4T2(D) of Mn ion, then the electron jumped from 4T2(D) to VB and recombined at once with the previous hole and emitted a 534 nm photon. When MgGeO3: Mn, Eu was excited, electron transitioned from 6A1(S) of Mn ion to CB and left a hole. Through CB, electron was captured by 7F6 levels of Eu[Formula: see text] and remained metastable for a long time, which slowed down the recombined rate between electron and hole. Under thermal stimulation, the captured electron returned to CB from 7F6 levels and was recaptured by the 4T2(D) of Mn. The electron transitioned down toward 6A1(S) and recombined with the hole immediately, then emitted a photon with 668 nm.
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5

Hou, Zhenfei, Xiaoli Zou, Xipeng Pu, Lei Wang, and Yanling Geng. "Facile synthesis and improved photocatalytic H2 production of ZnO/Zn2GeO4 and ZnO/Zn2GeO4-Cu composites." Journal of Solid State Chemistry 296 (April 2021): 121965. http://dx.doi.org/10.1016/j.jssc.2021.121965.

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6

Gu, Zhanjun, Feng Liu, Xufan Li, and Zheng Wei Pan. "Luminescent Zn2GeO4 nanorod arrays and nanowires." Physical Chemistry Chemical Physics 15, no. 20 (2013): 7488. http://dx.doi.org/10.1039/c3cp43977a.

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7

Cao, B., J. Chen, and W. Zhou. "Controlled Growth of Zn2GeO4/ZnO Heterojunction Nanowires." Microscopy and Microanalysis 17, S2 (July 2011): 1926–27. http://dx.doi.org/10.1017/s1431927611010506.

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8

Liu, Li, Weiliu Fan, Xian Zhao, Honggang Sun, Pan Li, and Liming Sun. "Surface Dependence of CO2 Adsorption on Zn2GeO4." Langmuir 28, no. 28 (June 29, 2012): 10415–24. http://dx.doi.org/10.1021/la301679h.

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9

Hidalgo, Pedro, Alejandro López, Bianchi Méndez, and Javier Piqueras. "Synthesis and optical properties of Zn2GeO4 microrods." Acta Materialia 104 (February 2016): 84–90. http://dx.doi.org/10.1016/j.actamat.2015.11.023.

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10

Gu, Zhanjun, Feng Liu, Xufan Li, and Zheng Wei Pan. "Luminescent GeO2–Zn2GeO4 hybrid one dimensional nanostructures." CrystEngComm 15, no. 15 (2013): 2904. http://dx.doi.org/10.1039/c3ce26809h.

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11

Liao, Chi-Hung, Chun-Wei Huang, Jui-Yuan Chen, Chung-Hua Chiu, TzungChuen Tsai, Kuo-Chang Lu, Ming-Yen Lu, and Wen-Wei Wu. "Optoelectronic Properties of Single-Crystalline Zn2GeO4 Nanowires." Journal of Physical Chemistry C 118, no. 15 (April 3, 2014): 8194–99. http://dx.doi.org/10.1021/jp500830x.

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12

Sun, Xiao-Yu, Zheng He, and Xuan Gu. "Persistent luminescence of Zn2GeO4:Mn2+/Pr3+ phosphors." Journal of Materials Science: Materials in Electronics 29, no. 20 (August 4, 2018): 17217–21. http://dx.doi.org/10.1007/s10854-018-9814-5.

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13

Yamaguchi, O., J. Hidaka, and K. Hirota. "Formation and characterization of alkoxy-derived Zn2GeO4." Journal of Materials Science Letters 10, no. 24 (1991): 1471–74. http://dx.doi.org/10.1007/bf00724409.

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14

Bender, J. P., J. F. Wager, J. Kissick, B. L. Clark, and D. A. Keszler. "Zn2GeO4:Mn alternating-current thin-film electroluminescent devices." Journal of Luminescence 99, no. 4 (November 2002): 311–24. http://dx.doi.org/10.1016/s0022-2313(02)00349-6.

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15

Wan, Lijuan. "Synthesis and photo-degradation activity of Zn2GeO4 photocatalyst." IOP Conference Series: Earth and Environmental Science 300 (August 9, 2019): 032026. http://dx.doi.org/10.1088/1755-1315/300/3/032026.

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16

Cong, Yan, Yangyang He, Bin Dong, Yu Xiao, and Limei Wang. "Long afterglow properties of Zn2GeO4:Mn2+, Cr3+ phosphor." Optical Materials 42 (April 2015): 506–10. http://dx.doi.org/10.1016/j.optmat.2015.01.045.

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17

Takahashi, Yoshihiro, Masataka Ando, Kenichiro Iwasaki, Hirokazu Masai, and Takumi Fujiwara. "Defect activation in willemite-type Zn2GeO4 by nanocrystallization." Applied Physics Letters 97, no. 7 (August 16, 2010): 071906. http://dx.doi.org/10.1063/1.3481081.

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18

Wan, Minhua, Yinhai Wang, Xiansheng Wang, Hui Zhao, Hailing Li, and Cheng Wang. "Long afterglow properties of Eu2+/Mn2+ doped Zn2GeO4." Journal of Luminescence 145 (January 2014): 914–18. http://dx.doi.org/10.1016/j.jlumin.2013.09.011.

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19

Rubaiya, Fariha, Swati Mohan, Bhupendra B. Srivastava, Horacio Vasquez, and Karen Lozano. "Piezoelectric Properties of PVDF-Zn2GeO4 Fine Fiber Mats." Energies 14, no. 18 (September 18, 2021): 5936. http://dx.doi.org/10.3390/en14185936.

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The current paper presents the development and characterization of polyvinylidene fluoride (PVDF)-Zn2GeO4 (ZGO) fine fiber mats. ZGO nanorods (NRs) were synthesized using a hydrothermal method and incorporated in a PVDF solution to produce fine fiber mats. The fiber mats were prepared by varying the concentration of ZGO NRs (1.25–10 wt %) using the Forcespinning® method. The developed mats showed long, continuous, and homogeneous fibers, with average fiber diameters varying from 0.7 to 1 µm, depending on the ZGO concentration. X-ray diffraction spectra depicted a positive correlation among concentration of ZGO NRs and strengthening of the beta phase within the PVDF fibers. The composite system containing 1.25 wt % of ZGO displayed the highest piezoelectric response of 172 V. This fine fiber composite system has promising potential applications for energy harvesting and the powering of wearable and portable electronics.
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20

Zhang, Shaoan, Yihua Hu, Ren Chen, Xiaojuan Wang, and Zhonghua Wang. "Photoluminescence and persistent luminescence in Bi3+-doped Zn2GeO4 phosphors." Optical Materials 36, no. 11 (September 2014): 1830–35. http://dx.doi.org/10.1016/j.optmat.2014.05.037.

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21

Dolado, Jaime, Kate L. Renforth, James E. Nunn, Steve A. Hindsmarsh, Pedro Hidalgo, Ana M. Sánchez, and Bianchi Méndez. "Zn2GeO4/SnO2 Nanowire Heterostructures Driven by Plateau–Rayleigh Instability." Crystal Growth & Design 20, no. 1 (November 15, 2019): 506–13. http://dx.doi.org/10.1021/acs.cgd.9b01494.

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22

Liang, Jun, Jie Xu, Quan Gu, Yangen Zhou, Changcang Huang, Huaxiang Lin, and Xuxu Wang. "A novel Zn2GeO4 superstructure for effective photocatalytic hydrogen generation." Journal of Materials Chemistry A 1, no. 26 (2013): 7798. http://dx.doi.org/10.1039/c3ta11374d.

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23

Srivastava, Bhupendra B., Santosh K. Gupta, Yang Li, and Yuanbing Mao. "Bright persistent green emitting water-dispersible Zn2GeO4:Mn nanorods." Dalton Transactions 49, no. 22 (2020): 7328–40. http://dx.doi.org/10.1039/d0dt00361a.

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This work reports on a green and facile approach for designing bright and persistent green luminescent Zn2GeO4:Mn2+ nano crystals with high quantum yield (∼52%) and water dispersibility designated for LEDs, security, and bio imaging.
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24

Wu, Songping, and Qing Ma. "Synthesis, characterization and microwave dielectric properties of Zn2GeO4 ceramics." Journal of Alloys and Compounds 567 (August 2013): 40–46. http://dx.doi.org/10.1016/j.jallcom.2013.03.052.

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25

Li, Hong, Yinhai Wang, Shihao Chen, Jun Li, Haiju Huang, Zhengfa Hu, and Hui Zhao. "Enhanced persistent luminescence of Zn2GeO4 host by Ti4+ doping." Journal of Materials Science: Materials in Electronics 28, no. 19 (June 14, 2017): 14827–32. http://dx.doi.org/10.1007/s10854-017-7353-0.

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26

Tsai, Meng-Yen, Sheng-Hsin Huang, and Tsong-Pyng Perng. "Low temperature synthesis of Zn2GeO4 nanorods and their photoluminescence." Journal of Luminescence 136 (April 2013): 322–27. http://dx.doi.org/10.1016/j.jlumin.2012.12.018.

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27

Wang, Jiangxin, Chaoyi Yan, Shlomo Magdassi, and Pooi See Lee. "Zn2GeO4 Nanowires As Efficient Electron Injection Material for Electroluminescent Devices." ACS Applied Materials & Interfaces 5, no. 15 (July 15, 2013): 6793–96. http://dx.doi.org/10.1021/am401234a.

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28

Guo, Silin, Shuai Kang, Shuanglong Feng, and Wenqiang Lu. "MXene-Enhanced Deep Ultraviolet Photovoltaic Performances of Crossed Zn2GeO4 Nanowires." Journal of Physical Chemistry C 124, no. 8 (February 6, 2020): 4764–71. http://dx.doi.org/10.1021/acs.jpcc.0c01032.

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29

LI Ting, 李婷, 方芳 FANG Fang, 周政 ZHOU Zheng, 赵海峰 ZHAO Hai-feng, 方铉 FANG xuan, 李金华 LI Jin-hua, 楚学影 CHU Xue-ying, 魏志鹏 WEI Zhi-peng, 房丹 FANG Dan, and 王晓华 WANG Xiao-hua. "Preparation and Luminescent Properties of Upright Zn2GeO4/ZnO Nanorod Arrays." Chinese Journal of Luminescence 35, no. 10 (2014): 1188–93. http://dx.doi.org/10.3788/fgxb20143510.1188.

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30

Gao, Guojun, and Lothar Wondraczek. "Near-infrared down-conversion in Mn2+–Yb3+ co-doped Zn2GeO4." Journal of Materials Chemistry C 1, no. 10 (2013): 1952. http://dx.doi.org/10.1039/c3tc00803g.

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31

Wang, Teng, Qian Liu, Gao Li, Kaibing Xu, Rujia Zou, and Junqing Hu. "Hydrothermal control growth of Zn2GeO4–diethylenetriamine 3D dumbbell-like nanobundles." CrystEngComm 16, no. 15 (2014): 3222. http://dx.doi.org/10.1039/c3ce41604f.

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32

Zhang, Lei, Xiao-Feng Cao, Ying-Li Ma, Xue-Tai Chen, and Zi-Ling Xue. "Microwave-assisted preparation and photocatalytic properties of Zn2GeO4 nanorod bundles." CrystEngComm 12, no. 10 (2010): 3201. http://dx.doi.org/10.1039/b927170h.

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33

Zhang, Lei, Jun-Sen Dai, Lin Lian, and Yin Liu. "Hydrothermal synthesis, characterisation and influencing factors of Zn2GeO4 hexagonal prism." Micro & Nano Letters 7, no. 11 (November 1, 2012): 1143–46. http://dx.doi.org/10.1049/mnl.2012.0761.

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34

Wagstaff, Brandon, and Adrian Kitai. "Electroluminescence of Zn2GeO4:Mn through SiC whisker electric field enhancement." Journal of Luminescence 167 (November 2015): 310–15. http://dx.doi.org/10.1016/j.jlumin.2015.06.016.

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35

Lin, Keying, Baojun Ma, Weiguang Su, and Wanyi Liu. "Improved photocatalytic hydrogen generation on Zn2GeO4 nanorods with high crystallinity." Applied Surface Science 286 (December 2013): 61–65. http://dx.doi.org/10.1016/j.apsusc.2013.09.014.

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36

Fan, Dong Hua, Kai Zhen Huang, and Yu Bao Huang. "Effect of Annealing Temperature on the Optical and Structural Properties of Ge Doped ZnO Films." Advanced Materials Research 304 (July 2011): 79–83. http://dx.doi.org/10.4028/www.scientific.net/amr.304.79.

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Ge doped ZnO films were synthesized on silicon substrate via RF magnetron co-sputtering methods. The effects of annealing temperature on the optical and structural properties of the Ge doped ZnO films were investigated by means of photoluminescence spectra, X-ray diffraction, and X-ray Photoelectron Spectroscopy. The ultra-violet emission should be related with the free-exciton recombination, and blue and yellow emissions should be attributed to the defect state caused by Ge. The varieties of annealing temperature affect greatly the optical properties. The high annealing temperature leads to the oxidation of Ge and the formation of Zn2GeO4, which could lead to the change of PL spectra.
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37

ZHAO Shu-ting, 赵淑婷, 李文琪 LI Wen-qi, 牟博石 MU Bo-shi, 李志超 LI Zhi-chao, and 李成仁 LI Cheng-ren. "Preparation of Zn2GeO4∶Mn2+Green Phosphors and Investigation of Afterglow Characteristics." Chinese Journal of Luminescence 40, no. 2 (2019): 189–95. http://dx.doi.org/10.3788/fgxb20194002.0189.

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38

Zhao, Yuxin, Shuwen Yang, Jun Zhu, Guangfu Ji, and Fang Peng. "The study of oxygen ion motion in Zn2GeO4 by Raman spectroscopy." Solid State Ionics 274 (June 2015): 12–16. http://dx.doi.org/10.1016/j.ssi.2015.02.015.

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39

Bai, Qiongyu, Panlai Li, Zhijun Wang, Shuchao Xu, Ting Li, Zhiping Yang, and Zheng Xu. "Inducing tunable host luminescence in Zn2GeO4 tetrahedral materials via doping Cr3+." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 199 (June 2018): 179–88. http://dx.doi.org/10.1016/j.saa.2018.03.065.

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40

Takeshita, Satoru, Joji Honda, Tetsuhiko Isobe, Tomohiro Sawayama, and Seiji Niikura. "Solvothermal synthesis of Zn2GeO4:Mn2+ nanophosphor in water/diethylene glycol system." Journal of Solid State Chemistry 189 (May 2012): 112–16. http://dx.doi.org/10.1016/j.jssc.2011.12.001.

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41

Wang, Jiaqi, Peng Xu, Huanli Yuan, Qilong Gao, Qiang Sun, and Erjun Liang. "Negative thermal expansion driven by acoustic phonon modes in rhombohedral Zn2GeO4." Results in Physics 19 (December 2020): 103531. http://dx.doi.org/10.1016/j.rinp.2020.103531.

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42

Xue, Jie, Jiawei Chen, Jizhong Song, Leimeng Xu, and Haibo Zeng. "Wearable and visual pressure sensors based on Zn2GeO4@polypyrrole nanowire aerogels." Journal of Materials Chemistry C 5, no. 42 (2017): 11018–24. http://dx.doi.org/10.1039/c7tc04147k.

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A high-performance and tailorable pressure sensor based on the Zn2GeO4@PPy nanowire aerogel for applications in visual and wearable fields has been developed and show high sensitivity of the pressure sensor (0.38 kPa−1at pressure regions less than 1.5 kPa). We also combined the aerogels with Light Emitting Diode which make a visible sensor come true.
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43

Moreira, Roberto L., and Anderson Dias. "Intra-grain polarized infrared spectroscopy realized in domain-engineered Zn2GeO4 ceramics." Materials Research Bulletin 118 (October 2019): 110513. http://dx.doi.org/10.1016/j.materresbull.2019.110513.

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44

Granerød, Cecilie S., Bjørn L. Aarseth, Phuong Dan Nguyen, Calliope Bazioti, Alexander Azarov, Bengt G. Svensson, Lasse Vines, and Øystein Prytz. "Structural and optical properties of individual Zn2GeO4 particles embedded in ZnO." Nanotechnology 30, no. 22 (March 19, 2019): 225702. http://dx.doi.org/10.1088/1361-6528/ab061c.

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45

Luo, Chen, Jiefang Li, Xin Yang, Xing Wu, Siyu Zhong, Chaolun Wang, and Litao Sun. "In Situ Interfacial Sublimation of Zn2GeO4 Nanowire for Atomic-Scale Manufacturing." ACS Applied Nano Materials 3, no. 5 (April 28, 2020): 4747–54. http://dx.doi.org/10.1021/acsanm.0c00740.

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46

Tang, Haiping, Xingda Zhu, and Haiping He. "Vapor phase growth and photoluminescence of oriented-attachment Zn2GeO4 nanorods array." Journal of Crystal Growth 451 (October 2016): 170–73. http://dx.doi.org/10.1016/j.jcrysgro.2016.07.011.

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47

Zhang, Qiuhong, and Jing Wang. "Synthesis and characterization of Zn2GeO4:Mn2+ phosphor for field emission displays." Applied Physics A 108, no. 4 (May 31, 2012): 943–48. http://dx.doi.org/10.1007/s00339-012-7003-6.

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48

Xie, Zhang-Yi, Hong-Liang Lu, Yuan Zhang, Qing-Qing Sun, Peng Zhou, Shi-Jin Ding, and David Wei Zhang. "The electronic structures and optical properties of Zn2GeO4 with native defects." Journal of Alloys and Compounds 619 (January 2015): 368–71. http://dx.doi.org/10.1016/j.jallcom.2014.09.003.

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49

Cao, Baobao, Jiajun Chen, Rong Huang, Yumi H. Ikuhara, Tsukasa Hirayama, and Weilie Zhou. "Axial growth of Zn2GeO4/ZnO nanowire heterojunction using chemical vapor deposition." Journal of Crystal Growth 316, no. 1 (February 2011): 46–50. http://dx.doi.org/10.1016/j.jcrysgro.2010.12.060.

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50

Sun, Yangang, Li Yu, and Pinhua Rao. "Rational growth of ternary Zn2GeO4 nanorods and self-assembled hierarchical nanostructures." Journal of Crystal Growth 347, no. 1 (May 2012): 73–76. http://dx.doi.org/10.1016/j.jcrysgro.2012.03.020.

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