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1

Cai, Yanqing, Xinggang Chen, Qian Xu, and Ying Xu. "Anodic behaviour of Cu, Zr and Cu–Zr alloy in molten LiCl–KCl eutectic." Royal Society Open Science 6, no. 1 (2019): 181278. http://dx.doi.org/10.1098/rsos.181278.

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The anodic dissolution behaviours of Cu, Zr and Cu–Zr alloy were analysed in LiCl–KCl at 500°C by anode polarization curve and potentiostatic polarization curve. The results show that the initial and fast-dissolving potentials of Cu are −0.50 and −0.29 V, and Zr are −1.0 and −0.88 V, respectively. But, in the Cu–Zr alloy, the initial and fast-dissolving potentials of Cu are −0.52 and −0.41 V, and Zr are −0.96 and −0.92 V, respectively. The potentials satisfy the selection dissolution principle that Zr in the alloy dissolves first, while Cu is left in the anode and is not oxidized. The passivat
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2

Pi, Zhao Hui, Guang Qiang Li, Yan Ping Xiao, Zhan Zhang, Zhuo Zhao, and Yong Xiang Yang. "An Experimental Investigation on the Solubility of Zr in Cu-Sn Alloys." Advanced Materials Research 887-888 (February 2014): 324–28. http://dx.doi.org/10.4028/www.scientific.net/amr.887-888.324.

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An experimental investigation on the solubility of Zr in Cu-Sn alloy was conducted in a resistance furnace. The solubility of Zr in Cu-Sn alloy was determined by investigating the influence of different conditions such as the ratio of Cu-Sn alloy and temperature. The solubility of Zr in Cu-Sn alloy changes with the proportion of Cu and Sn, and it increases with the increasing of Cu content. The experimental temperature has a significant effect on the solubility of Zr in Cu-Sn alloy. The maximum solubility of Zr in Cu-Sn alloy is 6.2 mass % at 900 °C with the mass ratio of Cu : Sn = 8:2.
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3

Liu, C. J., and J. S. Chen. "Influence of Zr additives on the microstructure and oxidation resistance of Cu(Zr) thin films." Journal of Materials Research 20, no. 2 (2005): 496–503. http://dx.doi.org/10.1557/jmr.2005.0068.

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In this work, the microstructure and oxidation resistance of pure Cu, Cu(0.2 at.% Zr) and Cu(2.5 at.% Zr) alloy films deposited on SiO2/Si by sputtering were explored. Upon annealing, the Zr additives diffused to the free surface and reacted with the residual oxygen in the vacuum system. An additional ZrO2 layer formed and covered the Cu(2.5 at.% Zr) film surface after annealing at 700 °C for 30 min. Simultaneously, of the three films, the Cu(2.5 at.% Zr) film exhibited the highest degree of Cu(111) preferred orientation and the lowest degree of void growth upon annealing. Additionally, the Cu
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4

Zhilli, Dong, Atsushi Sekiya, Wataru Fujitani, and Shigenori Hori. "Age Hardening of Cu-Zr and Cu-Zr-Si Alloys." Journal of the Japan Institute of Metals 53, no. 7 (1989): 672–77. http://dx.doi.org/10.2320/jinstmet1952.53.7_672.

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5

Dinda, G. P., H. Rösner, and G. Wilde. "Cold-rolling induced amorphization in Cu–Zr, Cu–Ti–Zr and Cu–Ti–Zr–Ni multilayers." Journal of Non-Crystalline Solids 353, no. 32-40 (2007): 3777–81. http://dx.doi.org/10.1016/j.jnoncrysol.2007.05.147.

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6

Kondoh, Katsuyoshi, Junji Fujita, Junko Umeda, and Tadashi Serikawa. "Estimation of Compositions of Zr-Cu Binary Sputtered Film and Its Characterization." Advances in Materials Science and Engineering 2008 (2008): 1–5. http://dx.doi.org/10.1155/2008/518354.

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Zr-Cu amorphous films were prepared by radio-frequency (RF) magnetron sputtering on glass substrate using two kinds of the elemental composite targets: Cu chips on Zr plate and Zr chips on Cu plate. It was easy to precisely control chemical compositions of sputtered films by selecting the chip metal and the number of chips. It is possible to accurately estimate the film compositions by using the sputtered area and the deposition rate of Cu and Zr. XRD analysis on every as-sputtered film showed the broadened pattern. Zr-rich composition film, however, revealed a small peak at the diffraction an
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7

Oh, Ki Hwan, Hob Yung Kim, and Sun Ig Hong. "Mechanical and Microstructural Analyses of Three Layered Cu-Ni-Zn/Cu-Zr/Cu-Ni-Zn Clad Material Processed by High Pressure Torsioning (HPT)." Advanced Materials Research 557-559 (July 2012): 1161–65. http://dx.doi.org/10.4028/www.scientific.net/amr.557-559.1161.

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Cu-Ni-Zn/Cu-Zr/Cu-Ni-Zn three layered clad plates were prepared by high pressure torsioning (HPT) at room temperature and theirmicrostructural and mechanical analyses wereperformed. No intermetallic compounds were observed at Cu-Zr/Cu-Ni-Zn interfaces in the as-HPTed and heat-treated Cu/Ni-Zn/Cu-Zr/Cu-Ni-Zn clad plates. The strength of as-HPTed clad plate reached up to 610 MPa with the ductility of 14%. After heat treatment at 500oC, Cu-Ni-Zn/Cu-Zr/Cu-Ni-Zn clad plate exhibited the strength up to 490 MPa and the ductility of 28 %. The clad plate fractured all together at the same time without
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8

Kim, Young-Min, and Byeong-Joo Lee. "A modified embedded-atom method interatomic potential for the Cu–Zr system." Journal of Materials Research 23, no. 4 (2008): 1095–104. http://dx.doi.org/10.1557/jmr.2008.0130.

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A modified embedded-atom method (MEAM) interatomic potential for the Cu–Zr system has been developed based on the previously developed MEAM potentials for pure Cu and Zr. The potential describes fundamental physical properties and alloy behavior of the Cu–Zr binary system reasonably well. The applicability of the potential to atomistic investigations of mechanical and deformation behavior for the Cu–Zr binary and Cu–Zr-based multicomponent amorphous alloys is also demonstrated by showing that fully relaxed and realistic amorphous structures can be generated by molecular dynamics simulations.
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9

Zhai, Yan Nan, Hun Zhang, Kun Yang, Zhao Xin Wang, and Li Li Zhang. "Improvement of Zr-N Diffusion Barrier Performance in Cu Metallization by Insertion of a Thin Zr Layer." Applied Mechanics and Materials 347-350 (August 2013): 1148–52. http://dx.doi.org/10.4028/www.scientific.net/amm.347-350.1148.

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In order to increase the failure temperature of Zr-N diffusion barrier for Cu, the effect of insertion of a thin Zr layer into Zr-N film on Zr-N diffusion barrier performance in Cu metallization was investigated by means of X-ray diffraction, scanning electron microscopy, Auger electron spectroscopy, and 4-point probe technique. XRD,SEM ,AES and FPP results show that the insertion of a thin Zr layer into Zr-N film improves barrier properties significantly when the ZrN / Zr/ZrN barrier layers are deposited by RF reactive magnetron sputtering and Zr-N(10nm)/Zr (5nm)/Zr-N(10nm) barrier tolerates
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10

Li, Hui Qiang, and Long Fei Liu. "Calculation of the Viscosity of Zr-Based Metallic Glass Alloys." Advanced Materials Research 239-242 (May 2011): 548–51. http://dx.doi.org/10.4028/www.scientific.net/amr.239-242.548.

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With the effects of electronic structure and atomic size being introduced, a revised model to calculate the viscosity of the bulk metallic glass alloys was proposed and the viscosity of ternary Zr-Al-Cu, Zr-Ni-Al and quaternary Zr-Al-Ni-Cu systems are calculated in this paper, and the computed results agree well with the empirical one. The sequence of viscosity of different systems is: VZr-Al-Cu <VZr-Al-Ni<.VZr-Al-Ni-Cu. To Zr-Al-Cu and Zr-Ni-Al, the highest viscosity locates in the composition range of XZr=0.37-0.86, XCu=0-0.40 and XZr = 0.45-0.79, XAl = 0.12-0.50, respectively. And to
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11

Zhang, J. Y., Y. Liu, J. Chen, et al. "Mechanical properties of crystalline Cu/Zr and crystal–amorphous Cu/Cu–Zr multilayers." Materials Science and Engineering: A 552 (August 2012): 392–98. http://dx.doi.org/10.1016/j.msea.2012.05.056.

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12

Sun, Haoliang, Xiaoxue Huang, Xinxin Lian, and Guangxin Wang. "Discrepancies in the Microstructures of Annealed Cu–Zr Bulk Alloy and Cu–Zr Alloy Films." Materials 12, no. 15 (2019): 2467. http://dx.doi.org/10.3390/ma12152467.

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Copper–zirconium bulk alloy and Cu–Zr alloy films are prepared by vacuum smelting and magnetron sputtering, respectively, and subsequently annealing is conducted. Results show that Cu–Zr bulk alloy and alloy films exhibit significantly different microstructure evolution behaviors after annealing due to different microstructures and residual stress states. CuxZr alloy compounds disperse at the grain boundary of Cu grains in as-cast and annealed Cu–Zr bulk alloys. However, unlike bulk alloys, a large number of polyhedral Cu particles are formed on the Cu–Zr thin films’ surface upon thermal annea
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13

Zhang, Ailong, Ding Chen, and Zhenhua Chen. "Effect of Cu/Zr content ratio on the thermal stability of Cu–Zr-rich Cu–Zr–Al BMGs." Philosophical Magazine Letters 93, no. 5 (2013): 283–91. http://dx.doi.org/10.1080/09500839.2013.769069.

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14

Chen, Cunguang, Qianyue Cui, Chengwei Yu, Pei Li, Weihao Han, and Junjie Hao. "Effects of Zr-Cu Alloy Powder on Microstructure and Properties of Cu Matrix Composite with Highly-Aligned Flake Graphite." Materials 13, no. 24 (2020): 5709. http://dx.doi.org/10.3390/ma13245709.

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Highly-aligned flake graphite (FG) reinforced Cu matrix composites with high thermal conductivity and adaptive coefficient of thermal expansion were successfully prepared via the collaborative process of tape-casting and hot-pressing sintering. To overcome the problem of fragile interface, Zr-Cu alloy powder was introduced instead of pure Zr powder to enhance the interfacial strength, ascribed to the physical-chemical bonding at the Cu-FG interface. The results indicate that the synthetic ZrC as interfacial phase affects the properties of FG/Cu composites. The thermal conductivity reaches the
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15

Cai, An Hui, Wei Ke An, Xiao Song Li, Yun Luo, and Tie Lin Li. "Property of Cu-Zr-Ti Ternary Alloys." Advanced Materials Research 146-147 (October 2010): 1477–81. http://dx.doi.org/10.4028/www.scientific.net/amr.146-147.1477.

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The influence of Zr on the property of Cu(50+x)Zr(40-x)Ti10 (0≤x≤30 at.%) alloys were investigated. The results show that the maximum size for the glass formation in this Cu-Zr-Ti system is less than 8 mm. The hardness increases with decreasing of the Zr content, then decreases when the Zr content exceeds 10~15 at.% due to the obvious alteration of the type of the crystalline phases and the microstructure. With decreasing of the Zr content, the transformation sequence of the main Cu-Zr phase is Cu10Zr7→Cu5Zr→Cu51Zr14; the transformation sequence of Cu-Ti phase is Cu4Ti3→CuTi→CuTi3. In addition
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16

Janovszky, Dóra, and Kinga Tomolya. "Designing Amorphous/Crystalline Composites by Liquid-Liquid Phase Separation." Materials Science Forum 790-791 (May 2014): 473–78. http://dx.doi.org/10.4028/www.scientific.net/msf.790-791.473.

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The Cu-Zr-Ag system is characterized by a miscibility gap. The liquid separates into Ag-rich and Cu-Zr rich liquids. Yttrium was added to the Cu-Zr-Ag and Cu-Zr-Ag-Al systems and its influence on liquid immiscibility was studied. This alloying element has been chosen to check the effect of the heat of mixing between silver and the given element. In the case of Ag-Y system it is highly negative (-29 kJ/mol). The liquid becomes immiscible in the Cu-Zr-Ag-Y system. To the effect of Y addition the quaternary liquid decomposed into Ag-Y rich and Cu-Zr rich liquids. The Y addition increased the fiel
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17

Li, Hui Qiang, and Long Fei Liu. "Quantitative Evaluation of the Glass Forming Ability of (Cu-Zr) Based Glass Alloys with Thermodynamics Method." Advanced Materials Research 239-242 (May 2011): 1622–25. http://dx.doi.org/10.4028/www.scientific.net/amr.239-242.1622.

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Along nucleation → crystalline growth →crystalline fraction → critical cooling rate, the relationship between the nucleation, elements, cooling rate and the Glass Forming Ability of (Cu-Zr) based glass alloys is quantitatively studied with thermodynamics method, and a better method to evaluate the critical cooling rate of glass alloys is also proposed in this paper. The computed results show that: (1) with the increase of element number, the steady state nucleation rate drops gradually. From Cu-Zr, Cu-Zr-Al, Cu-Zr-Al-Ni, to Cu-Zr-Al-Ni-Ti, the peak value of nucleation rate decreases from 1021m
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18

Tian, Feng, Jing-wen Qu, Ming-hua Shi, Bo-shuai Li, and Jie Li. "Study on Effects of Cu content on Microstructure and corrosion resistance of Zr-Nb alloys." Journal of Physics: Conference Series 2539, no. 1 (2023): 012010. http://dx.doi.org/10.1088/1742-6596/2539/1/012010.

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Abstract With the further development of nuclear power, the fuel burn-up continues to increase and the refueling cycle is extended, which puts forward higher requirements for the performance of fuel cladding materials. In this paper, Zr-Nb-0.1Fe-x (0.05%, 0.1%, 0.2%) Cu alloy samples were prepared by using the process route and process parameters of industrial production of zirconium alloy plates. The effects of Cu content on the microstructure of Zr-Nb alloy and the corrosion resistance in 18.6 MPa / 360 °C Li+B aqueous solution were studied by means of high-temperature autoclave simulation t
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19

Simic, M., J. Ruzic, D. Bozic, et al. "The influence of boron addition on properties of copper-zirconium alloys." Science of Sintering, no. 00 (2023): 3. http://dx.doi.org/10.2298/sos220421003s.

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Copper-zirconium alloys with high conductivity were produced using powder metallurgy. Two-steps manufacturing process, containing mechanical alloying followed by hot pressing, was applied in achieving improved mechanical and physical properties of Cu-Zr alloy. In this paper, the influence of boron on Cu-Zr alloys properties was studied on Cu-1Zr (wt.%) and Cu-1.1Zr-0.3B (wt.%) systems. Scanning electron microscopy, laser nanoparticle sizer, computed tomography and X-ray diffraction were employed for observation of changes in the microstructure during production steps. More specifically - varia
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20

Wang, C. C., and C. H. Wong. "Interpenetrating networks in Zr–Cu–Al and Zr–Cu metallic glasses." Intermetallics 22 (March 2012): 13–16. http://dx.doi.org/10.1016/j.intermet.2011.10.022.

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21

BASKOUTAS, S., V. KAPAKLIS, and C. POLITIS. "BULK AMORPHOUS Zr57Cu20Al10Ni8Ti5 AND Zr55Cu19Al8Ni8Ti5Si5 ALLOYS PREPARED BY ARC MELTING." International Journal of Modern Physics B 16, no. 24 (2002): 3707–14. http://dx.doi.org/10.1142/s0217979202013018.

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We have produced bulk amorphous materials by quenching arc melted melts in water cooled copper die. Alloys of the composition Zr 57 Cu 20 Al 10 Ni 8 Ti 5 and Zr 55 Cu 19 Al 8 Ni 8 Ti 5 Si 5 were produced in the form of small cylinders with a diameter of 3 mm and a length of 25 mm. The alloys were investigated by X-ray diffraction and thermal analysis to determine the structure and thermal properties. Complete amorphous X-ray patterns were observed for both alloys. The glass transition temperature is 362°C for the Zr 57 Cu 20 Al 10 Ni 8 Ti 5 alloy and 363°C for the Zr 55 Cu 19 Al 8 Ni 8 Ti 5 Si
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22

Turchanin, M. A., P. G. Agraval, and A. R. Abdulov. "Thermodynamic assessment of the Cu-Ti-Zr system. II. Cu-Zr and Ti-Zr systems." Powder Metallurgy and Metal Ceramics 47, no. 7-8 (2008): 428–46. http://dx.doi.org/10.1007/s11106-008-9039-x.

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23

Thaiyanurak, Tittaya, Olivia Gordon, Muyang Ye, Zhengming Wang, and Donghua Xu. "Compositional Effects on the Tensile Behavior of Atomic Bonds in Multicomponent Cu93−xZrxAl7 (at.%) Metallic Glasses." Molecules 30, no. 12 (2025): 2602. https://doi.org/10.3390/molecules30122602.

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The mechanical properties of materials are fundamentally determined by the behavior of atomic bonds under stress. Probing bond behavior during deformation, however, is highly challenging, particularly for materials with complex chemical compositions and/or atomic structures, such as metallic glasses (MGs). As a result, a significant gap exists in the current understanding of the mechanical properties of MGs in relation to the atomic bond behavior and how this relationship is influenced by metallurgical factors (e.g., alloy composition, processing conditions). Here, we present our study of the
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24

Song, Tae-Ung, Ja-Uk Koo, Seung-Byeong Jeon, and Chang-Yeol Jeong. "Investigation of Phase Transformation and Mechanical Properties of A356 Alloy with Cu and Zr Addition during Heat Treatment." Korean Journal of Metals and Materials 61, no. 5 (2023): 311–23. http://dx.doi.org/10.3365/kjmm.2023.61.5.311.

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Cast A356(Al-Si-Mg) alloys are widely used in automotive and general applications because of their mechanical properties and castability. Al-Si-Mg-(Cu) alloys typically lose their strength above 170 o C due to coarsening of precipitates, which limits their application to components. To maintain their strength at elevated temperature, Al-Si-Mg-(Cu) alloys are modified by adding transitional metals. Several studies have been carried out to evaluate the effect of Zr addition on the high temperature mechanical properties of cast Al-Si alloys because Zr can form thermally stable phases such as Al&l
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25

Zhai, Yannan, Zhaoxin Wang, Hui Zhang, Ling Gao, and Changhong Ding. "Improvement of thermal stability of Ta-N film in Cu metallization by a Zr-Si interlayer." E3S Web of Conferences 271 (2021): 04015. http://dx.doi.org/10.1051/e3sconf/202127104015.

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Ta-N (10 nm)/Zr (20 nm) film was grown on n-type (100) silicon wafer at various substrate temperatures in a rf magnetron sputtering system, followed by in situ deposition of Cu. The Cu/Ta-N/Zr/Si samples were subjected to thermal annealing up to 800 ℃ under the protection of pure nitrogen gas. In order to investigate the effect of insertion of a thin Zr layer under Ta-N film on Ta-N diffusion barrier performance in Cu metallization, Cu/Ta-N/Zr/Si contact system was characterized by X-ray diffraction (XRD), four-point probe (FPP) measurement, scanning electron microscopy (SEM), and Auger electr
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26

Liang, Zhoubing, Huan Li, Jianrong Xie, Songshou Ye, Jinbao Zheng, and Nuowei Zhang. "Cu/ZrO2 Catalyst Modified with Y2O3 for Effective and Stable Dehydration of Glycerol to Acetol." Molecules 29, no. 2 (2024): 356. http://dx.doi.org/10.3390/molecules29020356.

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Glycerol is a main by-product of biodiesel production, and its further processing is essential for the biorefinery. In this paper, a highly active and stable catalyst for the catalytic dehydration of glycerol to acetol is obtained by modifying a Cu-Zr (ZrO2 supported Cu) catalyst with Y2O3 using a co-precipitation method. It is found that the addition of Y2O3 effectively enhances the catalytic performance of Cu-Zr. Cu-Zr reaches the highest selectivity (82.4%) to acetol at 24 h. However, the selectivity decreases to 70.1% at 36 h. The conversion also decreases from 99.2 to 91.1%. Cu-Zr-Y exhib
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27

Lityńska, Lidia, Jan Dutkiewicz, and Krzysztof Parliński. "Experimental and theoretical characterization of Al3Sc precipitates in Al–Mg–Si–Cu–Sc–Zr alloys." International Journal of Materials Research 97, no. 3 (2006): 321–24. http://dx.doi.org/10.1515/ijmr-2006-0051.

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Abstract The structure of Al3Sc precipitates in Al –Mg– Si–Cu – Sc –Zr alloys annealed at 450 °C was investigated using transmission electron microscopy and energy-dispersive X-ray spectroscopy. The Al3Sc particles contain mainly Sc and small amounts of Zr, Si, and Cu. The addition of Zr limits the size of the Al3Sc precipitates to about 10– 30 nm, and these precipitates are coherent with the matrix. Density functional energy calculations showed that exceptionally small energies are required to dissolve Zr and Cu in Sc and Al sublattices, respectively. On the contrary, Cu, Mg, and Si are diffi
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28

Inoue, Akihisa, Bao Long Shen, and Akira Takeuchi. "Syntheses and Applications of Fe-, Co-, Ni- and Cu-Based Bulk Glassy Alloys." Materials Science Forum 539-543 (March 2007): 92–99. http://dx.doi.org/10.4028/www.scientific.net/msf.539-543.92.

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This paper reviews our recent results of the formation, fundamental properties, workability and applications of late transition metal (LTM) base bulk glassy alloys (BGAs) developed since 1995. The BGAs were obtained in Fe-(Al,Ga)-(P,C,B,Si), Fe-(Cr,Mo)-(C,B), Fe-(Zr,Hf,Nb,Ta)-B, Fe-Ln-B(Ln=lanthanide metal), Fe-B-Si-Nb and Fe-Nd-Al for Fe-based alloys, Co-(Ta,Mo)-B and Co-B-Si-Nb for Co-based alloys, Ni-Nb-(Ti,Zr)-(Co,Ni) for Ni-based alloys, and Cu-Ti-(Zr,Hf), Cu-Al-(Zr,Hf), Cu-Ti-(Zr,Hf)-(Ni,Co) and Cu-Al-(Zr,Hf)-(Ag,Pd) for Cu-based alloys. These BGAs exhibit useful properties of high mecha
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29

Guo, Pan-Pan, Zhen-Hong He, Shao-Yan Yang, et al. "Electrocatalytic CO2 reduction to ethylene over ZrO2/Cu-Cu2O catalysts in aqueous electrolytes." Green Chemistry 24, no. 4 (2022): 1527–33. http://dx.doi.org/10.1039/d1gc04284j.

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30

Martínez, C., F. Briones, P. Rojas, S. Ordoñez, C. Aguilar, and D. Guzmán. "Microstructure and Mechanical Properties of Copper, Nickel and Ternary Alloys Cu-Ni-Zr Obtained by Mechanical Alloying and Hot Pressing." MRS Advances 2, no. 50 (2017): 2831–36. http://dx.doi.org/10.1557/adv.2017.519.

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ABSTRACTElemental powders of Cu and Ni, binary alloys (Cu-Ni and Cu-Zr) and ternary alloy (Cu-Ni-Zr) obtained by mechanical alloying and uniaxial compaction hot microstructure and mechanical properties were investigated. The alloys studied were: pure Cu, pure Ni, binary alloys (Cu-Ni; Cu-Zr) and ternary alloys (Cu-Ni-Zr) under the same mechanical milling and hot pressing conditions. The samples were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM); the mechanical properties were studied by compression tests and hardness in Vickers scale (HV0.5) on polished surfaces at ro
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31

Jia, Zhengfeng, Yuchang Su, Yanqiu Xia, Xin Shao, Yanxin Song, and Junjie Ni. "Friction and wear behavior of Cu–Cr–Zr alloy lubricated with acid rain." Industrial Lubrication and Tribology 66, no. 3 (2014): 473–80. http://dx.doi.org/10.1108/ilt-02-2012-0015.

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Purpose – The purpose of this paper is to investigate the tribological properties of a Cu–Cr–Zr alloy lubricated with acid rain. Design/methodology/approach – The Cu 2.5 weight per cent–Cr-0.08 weight per cent–Zr alloy was produced in a vacuum induction furnace. The H2SO4 + H2O, HNO3 + H2O and H2SO4 + HNO3 + H2O mixtures with pH of 5 were used as acid rain. Pure water was used as rain. The friction and wear properties of Cu–Cr–Zr alloy/American Iron and Steel Institute (AISI) 52100 steel couples lubricated with acid rain were investigated using a reciprocating ball-on-disc friction and wear te
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32

Zhang, Jiale, Huihui Song, Jinyu Fang, et al. "Study on Coated Zr-V-Cr Getter with Pore Gradient Structure for Hydrogen Masers." Materials 15, no. 17 (2022): 6147. http://dx.doi.org/10.3390/ma15176147.

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As the core component of satellite navigation, the hydrogen maser needs a high vacuum environment to maintain the stability of the frequency signal. The getter pump, composed of various non-evaporable getters, plays an important role in maintaining the high vacuum. In this paper, the Zr100-xCux (x = 0, 2, 4, 6)/Zr56.97V35.85Cr7.18 getter was studied and the contradiction between sorption performance and mechanical properties was solved. The Zr-V-Cr getter, a better candidate for getter pump, exists for problems which will destroy the high vacuum and affect the service life of the hydrogen mase
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33

Cho, Hoon. "Development of High Strength and High Conductivity Cu-Ag-Zr Alloy." Materials Science Forum 654-656 (June 2010): 1323–26. http://dx.doi.org/10.4028/www.scientific.net/msf.654-656.1323.

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The development trend for diagnostics is reducing the diameter of coaxial signal cables that comprise the probe cable. The thinner super-fine coaxial cable which is offering superior electronic and mechanical properties, such as 75% IACS (International Annealed Copper Standard, electrical conductivity) and 700 ~ 800 MPa in tensile strength has to be developed. Three binary systems, Cu-Ag, Cu-Zr and Ag-Zr were thermodynamically optimized in the present study. Integration of optimized binary phase diagram can give useful information to predict the possible phases for the ternary Cu-Ag-Zr during
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34

Morozova, A., R. Mishnev, A. Belyakov, and R. Kaibyshev. "Microstructure and Properties of Fine Grained Cu-Cr-Zr Alloys after Termo-Mechanical Treatments." REVIEWS ON ADVANCED MATERIALS SCIENCE 54, no. 1 (2018): 56–92. http://dx.doi.org/10.1515/rams-2018-0020.

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Abstract Cu-Cr-Zr alloys provide an excellent combination of strength and electric conductivity and are frequently used as engineering materials in various electric/electronic devises. The present review deals with the microstructural design of Cu-Cr-Zr alloys, their alloying concept, thermo-mechanical processing based on technique of severe plastic deformation, physical mechanisms responsible for high strength and electric conductivity. The influences of microstructure and a dispersion of secondary phases on the mechanical properties and electric conductivity are discussed in detail. First, p
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35

Sun, Ju-Hyun, Dong-Myoung Lee, Chi-Hwan Lee, Joo-Wha Hong, and Seung-Yong Shin. "A novel Zr-Ti-Ni-Cu eutectic system with low melting temperature for the brazing of titanium alloys near 800 °C." Journal of Materials Research 25, no. 2 (2010): 296–302. http://dx.doi.org/10.1557/jmr.2010.0047.

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This article reports on low (below 800 °C) melting temperature characteristics of a Zr-Ti-Ni-Cu alloy system, designed by adding a small amount of Cu to a Zr-Ti-Ni eutectic alloy system in the Zr-rich corner of the Zr-Ti-Ni system. A series of Zr-Ti-Ni-Cu-based alloy buttons of varying Cu content was fabricated by an arc melting machine. The melting temperature ranges of the quaternary alloys were systematically examined by differential thermal analysis (DTA). As a result, a quaternary eutectic alloy of composition Zr54Ti22Ni16Cu8 with a low melting temperature range from 774 °C to 783 °C was
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36

Okamoto, H. "Cu-Zr (Copper-Zirconium)." Journal of Phase Equilibria and Diffusion 29, no. 2 (2008): 204. http://dx.doi.org/10.1007/s11669-008-9267-2.

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37

Okamoto, H. "Cu-Zr (Copper-Zirconium)." Journal of Phase Equilibria and Diffusion 33, no. 5 (2012): 417–18. http://dx.doi.org/10.1007/s11669-012-0077-1.

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38

Arias, D., and J. P. Abriata. "Cu-Zr (Copper-Zirconium)." Journal of Phase Equilibria 11, no. 5 (1990): 452–59. http://dx.doi.org/10.1007/bf02898260.

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39

Савиных, Д. О., С. А. Хайнаков, А. И. Орлова, С. Гарсия-Гранда та Л. С. Алексеева. "Синтез и тепловое расширение фосфатов Na-Zr-Cu и Ca-Zr-Cu". Неорганические материалы 56, № 4 (2020): 408–14. http://dx.doi.org/10.31857/s0002337x20040144.

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40

Lekka, Ch E. "Cu–Zr and Cu–Zr–Al clusters: Bonding characteristics and mechanical properties." Journal of Alloys and Compounds 504 (August 2010): S190—S193. http://dx.doi.org/10.1016/j.jallcom.2010.02.067.

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41

Sun, Xiao Jun, Jie He, and Jiu Zhou Zhao. "Microstructure Formation and Nanoindentation Behavior of Rapidly Solidified Cu-Fe-Zr Immiscible Alloys." Materials Science Forum 993 (May 2020): 39–44. http://dx.doi.org/10.4028/www.scientific.net/msf.993.39.

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The binary Cu-Fe system is characterized by a metastable liquid miscibility gap. WhenZr is added into the Cu-Fe alloy, the miscibility gap can be extended into Cu-Fe-Zr ternary system. In the present study Cu-Fe-Zr alloys were prepared by single-roller melting-spinning method, and the samples were characterized by the SEM, EDS, HRTEM and nanoidentation. The results show that liquid-liquid phase separation into CuZr-rich and FeZr-rich liquids takes place during rapid cooling the Cu-Fe-Zr alloy, and the mechanism depends on the atomic ratio of Cu to Fe. With increasing Zr content, the size of se
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42

Feng, Lu, Quanming Liu, Weimin Long, Guoxiang Jia, Haiying Yang, and Yangyang Tang. "Microstructures and Mechanical Properties of V-Modified Ti-Zr-Cu-Ni Filler Metals." Materials 16, no. 1 (2022): 199. http://dx.doi.org/10.3390/ma16010199.

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TA2 titanium alloy was brazed with Ti-Zr-Cu-Ni-V filler metals developed in a laboratory. The melting properties, the microstructures, phase compositions of filler metals and wettability, erosion properties, tensile properties of the brazed joint were studied in detail. The results show that with the increase of V content, the solidus–liquidus temperature of Ti-Zr-Cu-Ni-V filler metals increased, but the temperature difference basically remained unchanged, trace V element had a limited influence on the melting temperature range of Ti-Zr-Cu-Ni filler metals. The microstructure of Ti-Zr-Cu-Ni-1.
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43

Xia, Peng, Shuncheng Wang, Huilan Huang, Nan Zhou, Dongfu Song, and Yiwang Jia. "Effect of Sc and Zr Additions on Recrystallization Behavior and Intergranular Corrosion Resistance of Al-Zn-Mg-Cu Alloys." Materials 14, no. 19 (2021): 5516. http://dx.doi.org/10.3390/ma14195516.

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The recrystallization and intergranular corrosion behaviors impacted by the additions of Sc and Zr in Al-Zn-Mg-Cu alloys are investigated. The stronger effect of coherent Al3(Sc1−xZrx) phases on pinning dislocation resulted in a lower degree of recrystallization in Al-Zn-Mg-Cu-Sc-Zr alloy, while the subgrain boundaries can escape from the pinning of Al3Zr phases and merge with each other, bringing about a higher degree of recrystallization in Al-Zn-Mg-Cu-Zr alloy. A low degree of recrystallization promotes the precipitation of grain boundary precipitates (GBPs) with a discontinuous distributio
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44

Kang, Dae Hoon, and In-Ho Jung. "Critical thermodynamic evaluation and optimization of the Ag–Zr, Cu–Zr and Ag–Cu–Zr systems and its applications to amorphous Cu–Zr–Ag alloys." Intermetallics 18, no. 5 (2010): 815–33. http://dx.doi.org/10.1016/j.intermet.2009.12.013.

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45

Bhatt, J., and B. S. Murty. "Identification of Bulk Metallic Forming Compositions through Thermodynamic and Topological Models." Materials Science Forum 649 (May 2010): 67–73. http://dx.doi.org/10.4028/www.scientific.net/msf.649.67.

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This paper attempts to optimize the bulk metallic glass forming compositions using enthalpy of chemical mixing (DHchem) as thermodynamic, mismatch entropy (DSs/kB) as topological and configurational entropy (DSconfig/R) as statistical parameters. The product of DHchem and DSs/kB which is termed as PHS in the DSconfig/R range of 0.9 to 1.0 can be correlated strongly to glass forming ability. PHS being an important parameter has been used to design the quaternary and quinary Bulk Metallic Glass compositions from ternary compositions. This has been demonstrated for two Zr rich quaternary systems
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46

Tillmann, W., J. Pfeiffer, L. Wojarski, and J. E. Indacochea. "Reaktives Diffusionslöten von Keramik an Stahl mittels Zr-Cu-Zr- und Zr-Ni-Cu-Zr-Schichten für Anwendungen im Hochtemperaturbereich." Materialwissenschaft und Werkstofftechnik 45, no. 6 (2014): 512–21. http://dx.doi.org/10.1002/mawe.201400267.

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47

Xu, Xiangping, Yi Wang, Jiasheng Zou, and Chunzhi Xia. "Interfacial Microstructure and Properties of Si3N4 Ceramics/Cu/304 Stainless Steel Brazed by Ti40Zr25B0.2Cu Amorphous Solder." Materials 11, no. 11 (2018): 2226. http://dx.doi.org/10.3390/ma11112226.

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Si3N4 ceramics and 304 stainless steel were brazed by Ti40Zr25B0.2Cu amorphous solder, and the interfacial microstructure of brazed joint Si3N4 ceramics/Ti40Zr25B0.2Cu/Cu/Ti40Zr25B0.2Cu/304 stainless steel was analyzed. The mechanical properties of the brazed joint were overtly affected by the brazing temperature and Cu foil thickness. The results revealed that the interface structure of the brazed joint might be 304 stainless steel/FeTi/Cu-Zr+Cu-Ti+Fe-Ti/Cu(s,s)/Cu-Zr+Cu-Ti+Fe-Ti/Ti-Si+Zr-Si/TiN/Si3N4 ceramics. The four-point bending strength of the brazed joint decreased sharply as the brazi
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48

Huang, Fu Xiang. "Microsture and Properties of a Cu-Cr-Zr-Fe-Ti Alloy." Applied Mechanics and Materials 723 (January 2015): 556–60. http://dx.doi.org/10.4028/www.scientific.net/amm.723.556.

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The effect of 0.45 wt. % Fe and 0.2 wt. % Ti additions on the age hardening behavior of Cu-Cr-Zr-Zn alloys has been investigated with respect to hardness, electrical conductivity and microstructure. It was showed that the addition of Fe /Ti to Cu-Cr-Zr-Zn alloys enhance strength and hardness, but decrease the electrical conductivity, and increase the aging temperature and time for attaining peak hardness. The scanning electron microscope (SEM) and transmission electron microscopy (TEM) results showed that there are four types of phases in the alloy, Cu-matrix, Cr-rich, (Cu,Zr)-rich and (Fe,Ti)
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49

Li, Zhuo Ran, Guang Dong Wu, Zheng Zheng Wang, and Ji Cai Feng. "Microstructure and Mechanical Property of the ZrB2-Based Ultra-High-Temperature Ceramic Composites Brazed Joint." Advanced Materials Research 314-316 (August 2011): 1184–88. http://dx.doi.org/10.4028/www.scientific.net/amr.314-316.1184.

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ZrB2-SiC ceramic composites was brazed by using Ti-Zr-Ni-Cu active filler in a vacuum furnace. The microstructure and interfacial phenomena of the joints were analyzed by means of SEM, EDS and XRD. The joining effect was evaluated by shear strength. The results showed that the reaction products of the ZrB2-SiC ceramic composites joint brazed with Ti-Zr-Ni-Cu active filler were TiC, ZrC, Ti5Si3, Zr2Si, Zr(s,s) and (Ti, Zr)2 (Ni, Cu). The maximum shear strength of the ZrB2-based ultra-high-temperature ceramic composites brazed joints is 143.5 Subscript textMPa at brazing temperature T=920°C and
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50

Pan, X. F., H. F. Zhang, A. M. Wang, B. Z. Ding, and Z. Q. Hu. "Preparation of superfine Fe-base alloy by liquidus casting." Journal of Materials Research 16, no. 12 (2001): 3459–63. http://dx.doi.org/10.1557/jmr.2001.0475.

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The superfine Fe–B–Si–Mo and Fe–B–Zr–Nb alloys were prepared by liquidus casting in which the levitation melting combining with the rapid solidification was used. The melt was poured into a copper mold at various temperatures, and a superfine granular microstructure was obtained at liquidus temperature. The behavior of Cu and Ag addition to Fe–B–Si–Mo and Fe–B–Zr–Nb alloys was studied. Both adding Cu and Ag to Fe–B–Si–Mo and Fe–B–Zr–Nb alloys had influence on refining the alloys. The refinement effect of adding Cu is stronger than that of adding Ag in Fe–B–Zr–Nb alloy.
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