Дисертації з теми "Continental water"

Cold-water coral (CWC) habitats dwell on continental shelves, slopes, canyons, seamounts, and ridge systems around the world’s oceans, from 50 m to depths up to 4000 m. CWC species provide heterogeneous habitats supporting a myriad of associated fauna and form highly diverse CWC reefs and CWC gardens. Main threats, currently impacting CWC ecosystems come from anthropogenic stressors, such as fishing activities, oil and gas exploitation and the incipient mining activity. Likewise, climate change, causing changes in the water column, is also affecting these ecosystems. Life-history traits of CWC species (long lifespans, slow growth and limited recruitment) make them very vulnerable to current and potential threats. Given their limited recovery capacity, interest to preserve and restore CWC ecosystem is steadily growing. The creation of Marine Protected Areas and active ecological restoration actions are nowadays the best management tools to conserve native ecosystems and represents an opportunity to revert the anthropogenic damage that has already taken place. Through passive (natural regeneration after the cessation of stressors) and active (human interacts with biotic and/or abiotic ecosystem features) approaches, restoration activities seek to accelerate the recovery of ecosystem structure and functioning relative to a reference model. Contrarily to terrestrial and shallow-water marine ecosystems, ecological restoration in intermediate (50 – 200 m) and deep marine (> 200 m) environments has received lesser attention. To date, only few restoration actions at local scales have been carried out at those depths, mainly due to technical and economic limitations which questions its wide application. Scaling-up restoration actions and make them affordable are the main present challenges for CWC restoration. In this sense, in order to move forward towards the conservation of intermediate and deep-sea ecosystems, the general aim of the present thesis is to assess the impact of fishing activity on CWC gardens as well as to explore the feasibility of novel active ecological restoration techniques. All the work performed during this thesis has been carried out at the Cap de Creus marine area (North-Western Mediterranean Sea), specifically at the continental shelf (60 – 130 m), where gorgonians, sponges, and sea pen species form CWC gardens supporting a variety of mobile associated fauna. The target species is the yellow gorgonian Eunicella cavolini (Koch, 1887) which dominate in the area forming density patches. In the first chapter, the impact of artisanal fishing was quantified to evaluate the threat of this activity on CWC gardens and to provide essential information to mitigate such impact. The rest of chapters (2, 3 and 4) evaluated, for the first time, the viability to actively restore degraded E. cavolini populations. Specifically, in the second chapter, gorgonians obtained from bycatch (accidentally caught of non-target species) of local artisanal fishers, were transplanted to artificial structures deployed on the continental shelf (805 m). This pilot study demonstrated, for the first time, the high survival of E. cavolini transplants. Following, and going one step forward, in the third chapter, field experiments and modeling approaches were combined to develop and technically validate an innovative large-scale and cost- effective restoration method for CWC gardens. Successful results evidenced the feasibility of recovering bycatch E. cavolini and returning them to their natural habitat with this novel method so-called “badminton method”. Finally, in the fourth and last chapter, a large- scale restoration action of E. cavolini populations was carried out in collaboration with local artisanal fishers during two consecutive fishing seasons by applying the technique previously developed. A large number of gorgonians (460 colonies) were successfully reintroduced and survived at the end of the action (2 years) at 80-100 m depth. The results suggested an initial establishment of a new gorgonian population, which will potentially evolve toward a comparable natural population in terms of size and spatial structure, if natural recruitment also occurs. Moreover, an economic evaluation was performed, also confirming the cost efficiency of this method aimed at enhancing the recovery of impacted CWC gardens. The lack of knowledge of some key ecological processes of CWC ecosystems as well as the technical limitations hinder a complete evaluation of restoration efforts performed. However, this thesis represents a promising improvement for the conservation and recovery of CWCs that could be extended to other areas and regions.
Els coralls d’aigua freda habiten en les plataformes continentals, talussos, canyons, muntanyes submarines i dorsals oceàniques d’arreu del món, des de 50 a 4000 metres de profunditat. Les espècies de coralls d’aigua freda creen hàbitats heterogenis que donen suport a una infinitat de fauna associada i formen esculls i boscos de coralls altament diversos. Les principals amenaces que actualment impacten aquests ecosistemes de coralls d’aigua freda son d’origen antròpic, com ara l’activitat pesquera, l’explotació de petroli i gas i l’incipient explotació minera. Així mateix, el canvi climàtic, el qual provoca canvis en la columna d’aigua, també està afectant aquests ecosistemes. Les característiques vitals dels coralls d’aigua freda (longevitat, creixement lent i reclutament limitat) els fan molt vulnerables a les amaces tan actuals com futures. Atesa la seva limitada capacitat de recuperació, l’interès per preservar i restaurar els ecosistemes de coralls d’aigua freda està en constant creixement. La creació d’àrees marines protegides i les accions restauració ecològica activa són avui en dia les millors eines de gestió per conservar ecosistemes autòctons i representen una oportunitat per revertir els danys antròpics que ja han tingut lloc. A través d’enfocaments passius (regeneració natural després del cessament del impacte) i actius (l’ésser humà interacciona amb les característiques biòtiques i/o abiòtiques de l’ecosistema), les activitats de restauració busquen accelerar la recuperació de l’estructura i funcionament dels ecosistemes en funció a un model de referència. Contràriament als ecosistemes terrestres i d’aigües someres, la restauració ecològica enfocada a ambients marins intermedis (50–200 m) i profunds (> 200 m) ha rebut menor atenció. Fins ara, a aquestes profunditats només s’han dut a terme algunes poques accions de restauració a escala local, principalment a causa de limitacions tècniques i econòmiques que qüestionen la seva àmplia aplicació. Els principals reptes actuals per la restauració de coralls d’aigua freda són incrementar l’escala espacial de les accions de restauració i fer-les econòmicament més assequibles. En aquest sentit, per avançar en la conservació dels ecosistemes de fons intermedis i profunds, l’objectiu general de la present tesi és avaluar l’impacte de l’activitat pesquera sobre els boscos de coralls d’aigua freda i explorar la viabilitat de innovadores tècniques de restauració activa. Tot el treball realitzat en aquesta tesi s’ha dut a terme a la zona marina del Cap de Creus (Nord-Oest del mar Mediterrani), contretament a la plataforma continental (60 – 130 m) on espècies de gorgònies, esponges i plomalls formen boscos de coralls d’aigua freda donant suport a una gran varietat de fauna mòbil associada. L’espècie objectiu és la gorgònia groga Eunicella cavolini (Koch, 1887) la qual domina a la zona formant denses agregacions. En el primer capítol, es va quantificar el impacte de la pesca artesanal per avaluar l’amenaça d’aquesta activitat sobre els boscos de coralls d’aigua freda i proporcionar informació essencial per mitigar aquest impacte. La resta de capítols (2, 3 i 4) van avaluar, per primera vegada, viabilitat de restaurar activament les poblacions degradades de E.cavolini. Especificament, en el segon capítol és van trasplantar les gorgònies capturades accidentalment pels pescadors artesanals de la zona, a estructures artificials fondejades a la plataforma continental (85 m). Aquest estudi pilot va demostrar per primera vegada l’alta supervivència dels transplantaments d’E.cavolini. Seguidament, i anant un pas més enllà, al tercer capítol es van combinar experiments de camp i modelització per desenvolupar i validar tècnicament una nova tècnica de restauració per als boscos de coralls d’aigua freda, a gran escala i econòmicament assequible. Els exitosos resultats van evidenciar la viabilitat de recuperar les colònies de E.cavolini capturades accidentalment i retornar-les al seu hàbitat natural amb aquesta innovadora tècnica , anomenada “el mètode bàdminton”. Finalment, al quart i últim capítol, es va dur a terme una acció de restauració de les poblacions de E.cavolini a gran escala, amb la col·laboració de pescadors artesanals de la zona i al llarg de dues temporades de pesca consecutives aplicant la tècnica desenvolupada anteriorment. Un gran nombre de gorgònies (460 colònies) van ser re-introduïdes amb èxit i van sobreviure al final de l’acció (2 anys) a 80-100 m de profunditat. Els resultats van suggerir l'establiment inicial d'una nova població gorgònies, que potencialment evolucionarà cap a una població natural comparable en termes d’estructura de talles i estructura espacial, sempre i quan es produeix també un reclutament natural. D'altra banda, es va fer una avaluació econòmica, que va confirmar la rendibilitat d'aquest mètode dirigit a millorar la recuperació dels boscos de coralls d’aigua freda impactats. El desconeixement d'alguns processos ecològics claus en els ecosistemes de coralls d’aigua freda, així com les limitacions tècniques, dificulten una avaluació completa dels esforços de restauració realitzats. Tanmateix, aquesta tesi suposa una millora prometedora per a la conservació i recuperació dels coralls d’aigua feda, que es podria estendre a altres zones i regions.

Cette étude est basée sur la collection la plus complète d'éclogites cratoniques (> 180 nodules), provenant des cratons sibériens et sud-africains.Les éclogites non-métasomatisés de type IIA sont plus magnésiennes, enrichis en LREE, avec des valeurs de δ18O, de 3,7-7,5 ‰, des anomalies positives en Sr et correspondant à une couche à basse pression-température (PT). La composition de la roche totale est un protolithe basaltique. Les éclogites de type IIB sont plus sodiques et alumineux, appauvris en terres rares, avec des valeurs de δ18O de 2,3-3,6 ‰, correspondant à l'équilibre à haute PT. La composition de la roche totale correspond au protolithe pyroxénitique. Les éclogites à coésite, disthène ou corindon ont des clinopyroxènes riches en jadéite, avec des anomalies positives en Eu et Sr et des grenats riches en grossulaire, avec des anomalies positive en Eu et négatives en Sr. Les estimations de PT indiquent que les éclogites à co-ky-cor ont été équilibrées dans la partie la plus basse de la quille cratonique et la composition de la roche totale correspondant à un protolithe gabbroïque très appauvri, cohérente avec la subduction d'une séquence basaltique à websteritique d'une croûte océanique altérée, appauvrie en éléments incompatibles.L'estimation minimum d'eau dans l'omphacite d'Obnazhennaya est de ~930-1410 ppm d'H20 et pour la roche totale de ~310-890 ppm H2O, significativement supérieures aux péridotites environnantes. Ainsi, les éclogites du manteau peuvent être un important réservoir d'eau à la base de la racine cratonique, avec des conséquences majeures pour la longévité de la quille cratonique, la rhéologie du manteau et pour le cycle global de l'eau
This study is based on the most complete existing collection of cratonic eclogites (> 180 nodules), from the Siberian and South African cratons. Non-metasomatized Type IIA eclogites are typically more magnesian, LREE-enriched, with δ18O values of 3.7-7.5 ‰, positive Sr anomalies and corresponding to a low pressure-temperature (PT) layer. The whole-rock composition is consistent with a basaltic protolith. Type IIB eclogites are morsodic and aluminous, LREE-depleted, with δ18O values of 2.3-3.6‰, corresponding to equilibrium at high-PT. The whole-rock trace element composition is consistent with a pyroxenitic protolith. Coesite, kyanite and corundum-bearing eclogites ypically have jadeite-rich clinopyroxenes witlpositive Eu and Sr anomalies and grossular-rich gamets with corresponding positive Eu and negative Sr anomalies. PT-estimates indicate coe-kycor-bearing eclogites equilibrated in the lowermost part of the cratonic keel and reconstructed whole-rock trace element composition corresponds to a very depleted gabbroic protolith. This is consistent with the subduction of a hydrothermally altered, basaltic to websteritic sequence of an incompatible-element-depleted oceanic crust.Calculated water content of omphacite is a minmum estima te of ~930-1410 ppm by weight H2O and reconstructed estimates for whole-rock watercontent ~310-890 ppm HO) for the Obnazhennaya eclogites are significantly higher than those of the surrounding peridotites. Thus, mantle eclogite may be an important water reservoir at the base of the cratonic root, with major consequences for cratonic keel, longevity mantle rheology and global water cvcle

L'estimació dels recursos hídrics de les superfícies continentals a escala regional i global és fonamental per a una bona gestió dels recursos hídrics. Aquesta estimació cobreix una àmplia gamma de temes i camps, incloent-hi la caracterització dels sòls i dels recursos hídrics a l’escala de la conca, la modelització hidrològica i la predicció i la cartografia d'inundacions. En aquest context, la caracterització dels estats de la superfície continental, per a obtenir millors paràmetres d’entrada als models hidrològics, és essencial per millorar la precisió en la simulació de cabals, sequeres i inundacions. L’estimació del contingut d’aigua en el sistema, incloses les diferents masses d’aigua i l’aigua lliure en el sòl, és especialment necessària per a una descripció precisa dels processos hidrològics i, en general, del cicle de l’aigua a les superfícies continentals. Per caracteritzar millor els processos hidrològics, les intervencions antropogèniques no es poden negligir. L'home influeix en el cicle de l'aigua, principalment mitjançant el reg i la construcció de preses, fet que s’ha de quantificar correctament. L’objectiu de la tesi és la millora de l’estimació remota dels recursos hídrics, incloent-hi la quantificació dels factors antròpics, mitjançant l’ús de diversos sensors llançats recentment, aprofitant recents desenvolupaments en la tecnologia de teledetecció. Amb l'arribada de les constel·lacions Sentinel (Sentinel-1, 2, 3), disposem de millors eines per estimar els recursos hídrics, incloent-hi els impactes humans, amb una major precisió i cobertura. Aquest treball de tesi consta principalment de dues línies de recerca on s’estimen les intervencions humanes en el cicle hidrològic: la cartografia del reg (com a aplicació en humitat del sòl), i el forçament d’embassaments en simulacions hidrològiques (com a aplicació de l’altimetria). En la primera linia s’estima la humitat del sòl a partir de l’anàlisi estadística de les dades SAR de Sentinel-1. Es desenvolupen dues metodologies per obtenir la humitat del sòl amb una resolució espacial de 100 m basant-se en la interpretació de les dades de Sentinel-1 obtingudes amb la polarització VV (vertical-vertical), que es combina amb dades òptiques Sentinel-2 per a l'anàlisi dels efectes de la vegetació. Com aplicació de la humitat del sòl, es cartografia el reg en diverses condicions meteorològiques, i amb una alta resolució espacial i temporal. Es proposa una metodologia per a la cartografia del reg mitjançant dades SAR obtingudes en polaritzacions VV (vertical-vertical) i VH (vertical-horitzontal). A partir de la sèrie temporal Sentinel-1, s’analitzen diferents estadístiques i mètriques, incloent-hi el valor mitjà, la variància del senyal, la longitud de la correlació i la dimensió fractal, a partir dels quals es classifiquen els arbres irrigats, els cultius irrigats i els cultius no irrigats. En la segona línia, s’estima el nivell dels embassaments a partir de les dades d’altimetria de Sentinel-3, amb l’altímetre SAR (SRAL), basant-se en diferents algorismes per millorar la precisió. Aquest estudi presenta tres algorismes especialitzats o retrackers destinats a obtenir el nivell de la superfície dels cossos d’aigua estudiats, minimitzant la contaminació de les formes d’ona degut al sòl que els envolta. Es compara el rendiment del mètode proposat de selecció de la porció d’ona amb tres retrackers, és a dir, un retracker de llindar, el retracker del centre de gravetat (OCOG) i un retracker de base física de dos passos. S’obtenen sèries temporals del nivell de la làmina d’aigua d’embassaments situats a la conca del riu Ebre (Espanya). Com aplicació, les sèries de nivell dels embassaments obtingudes s’utilitzen per a forçar els embassaments en simulacions hidrològiques.
La estimación de los recursos hídricos de las superficies continentales a escala regional y global es fundamental para una buena gestión de los recursos hídricos. Esta estimación cubre una amplia gama de temas y campos, incluyendo la caracterización de los suelos y de los recursos hídricos a escala de cuenca, la modelización hidrológica y la predicción y la cartografía de inundaciones. En este contexto, la caracterización de los estados de la superficie continental, para obtener mejores parámetros de entrada para los modelos hidrológicos, es esencial para mejorar la precisión en la simulación de caudales, sequías e inundaciones. La estimación del contenido de agua en el sistema, incluidas las diferentes masas de agua y el agua libre en el suelo, es especialmente necesaria para una descripción precisa de los procesos hidrológicos y, en general, del ciclo del agua en las superficies continentales. Una caracterización precisa de los procesos hidrológicos requiere no descuidar las intervenciones humanas. El hombre influye en el ciclo del agua, principalmente mediante el riego y la construcción de embalses, lo que se debe cuantificar correctamente. El objetivo de la tesis es la mejora de la estimación remota de los recursos hídricos, incluyendo la cuantificación de los factores humanos, mediante el uso de varios sensores lanzados recientemente, aprovechando recientes desarrollos en la tecnología de teledetección. Con la llegada de las constelaciones Sentinel (Sentinel-1, 2, 3), disponemos de mejores herramientas para estimar los recursos hídricos, incluyendo los impactos humanos, con una mayor precisión y cobertura. Este trabajo de tesis consta principalmente en dos ejes de investigación donde se estiman las intervenciones humanas en el ciclo hidrológico: la cartografía del riego (como aplicación en humedad del suelo), y el forzamiento de embalses en simulaciones hidrológicas (como aplicación de la altimetría). En relación al primer eje, se estima la humedad del suelo a partir del análisis estadístico de los datos SAR de Sentinel-1. Se desarrollan dos metodologías para obtener la humedad del suelo con una resolución espacial de 100 m basándose en la interpretación de los datos de Sentinel-1 obtenidas con la polarización VV (vertical-vertical), que se combina con datos ópticas Sentinel-2 para el análisis de los efectos de la vegetación. Como aplicación de la humedad del suelo, se cartografía el riego en diversas condiciones meteorológicas, y con una alta resolución espacial y temporal. Se propone una metodología para la cartografía del riego mediante datos SAR obtenidos en polarizaciones VV (vertical-vertical) y VH (vertical-horizontal). A partir de la serie temporal Sentinel-1, se analizan diferentes estadísticas y métricas, incluyendo el valor medio, la varianza de la señal, la longitud de la correlación y la dimensión fractal, a partir de los cuales se clasifican los árboles irrigados, los cultivos irrigados y los cultivos no irrigados. En el segundo eje, se estima el nivel de los embalses a partir de los datos de altimetría de Sentinel-3, con el altímetro SAR (SRAL), basándose en diferentes algoritmos para mejorar la precisión. Este estudio presenta tres algoritmos especializados o retrackers destinados a obtener el nivel de la superficie de los cuerpos de agua estudiados, minimizando la contaminación de las formas de onda debido al suelo que los rodea. Se compara el rendimiento del método propuesto de selección de la porción de onda con tres retrackers, es decir, un retracker de umbral, el retracker del centro de gravedad (OCOG) y un retracker de base física de dos pasos. Se obtienen series temporales del nivel de la lámina de agua de embalses situados en la cuenca del río Ebro (España). Como aplicación, las series de nivel de los embalses obtenidas se utilizan para forzar los embalses en simulaciones hidrológicas.
The estimation of the water resources of the continental surfaces at a regional and global scale is fundamental for good water resources management. This estimation covers a wide range of topics and fields, including the characterisation of soils and water resources at the basin scale, hydrological modelling and flood prediction and mapping. In this context, the characterisation of the states of the continental surface, to obtain better input parameters for hydrological models, is essential to improve the precision in the simulation of flows, droughts, and floods. The estimation of the water content in the system, including the different water bodies and the free water in the soil, is especially necessary for a precise description of the hydrological processes and, in general, of the water cycle on the continental surfaces. To better characterise hydrological processes, human interventions cannot be neglected. Humans influence the water cycle, mainly through irrigation and the construction of reservoirs, which must be correctly quantified. The objective of the thesis is the improvement of the remote estimation of water resources, including the quantification of human factors, using several sensors recently launched, taking advantage of recent developments in remote sensing technology. With the arrival of the Sentinel constellations (Sentinel-1, 2, 3), we have better tools to estimate water resources, including human impacts, with greater precision and coverage. This thesis consists mainly of two parts where human interventions in the water cycle are considered: irrigation cartography (as an application of soil moisture), and the forcing of reservoirs in hydrological simulations (as an application of altimetry). Firstly, soil moisture is estimated from the statistical analysis of Sentinel-1 SAR data. Two methodologies are developed to obtain soil moisture with a spatial resolution of 100 m based on the interpretation of Sentinel-1 data collected with the VV polarization (vertical-vertical), which is combined with optical data of Sentinel-2 for the analysis of the effects of vegetation. Secondly, irrigation is mapped under various meteorological conditions, including high spatial and temporal resolution. A methodology for irrigation mapping is proposed using SAR data obtained in VV (vertical-vertical) and VH (vertical-horizontal) polarizations. With Sentinel-1 time series, different statistics and metrics are analysed, including the mean value, the variance of the signal, the correlation length and the fractal dimension, based on which the classification of irrigated trees, irrigated crops, and non-irrigated crops are derived. Finally, the level of the reservoirs is estimated from the Sentinel-3 altimetry data, with the SAR altimeter (SRAL), based on different algorithms to improve the accuracy. This study presents three specialised algorithms or retrackers designed to obtain the level of the surface of the studied inland bodies of water, minimising the contamination of the waveforms due to the surrounding soil. The performance of the selection method of the proposed wave portion is compared with three retrackers, that is, the centre of gravity retracker (OCOG) and the two-step physical-based retracker. Temporal series of the water level of reservoirs located in the basin of the Ebro River (Spain) are obtained. As an application, the level series of the reservoirs obtained are used to force the reservoirs in hydrological simulations.
L'estimation et le suivi des ressources en eau des surfaces continentales aux niveaux régional et global est essentielle pour la gestion du bilan hydrique, particulièrement dans le contexte des changements climatiques et anthropiques. Ils couvrent un large éventail de thèmes et de domaines, incluant la caractérisation des ressources en eau à l'échelle du bassin, la modélisation hydrologique ainsi que la prévision et la cartographie des inondations. Dans ce contexte, la caractérisation des états de surface, en tant que paramètres d’entrée dans les modèles hydrologiques, est essentielle pour obtenir une meilleure précision de la simulation, qui est liée à la précision prévisionnelle des débits des cours d’eau et le suivi des sécheresses et des inondations. L'estimation de la teneur en eau des surfaces continentales, incluant l’état hydrique du sol et les niveaux des surfaces couvertes d’eau, est particulièrement nécessaire pour une description précise des processus hydrologiques et plus généralement du cycle de l'eau sur les surfaces continentales. Afin de mieux comprendre les processus hydrologiques, l'influence humaine (l’effet anthropique) sur le cycle de l'eau nécessite une évaluation fine. Elle est particulièrement liée à la gestion de l’irrigation et la construction de barrages. L'objectif de la thèse était d'améliorer l'estimation des ressources en eau et une meilleure caractérisation des interventions anthropiques à travers l'utilisation de nouveaux capteurs satellitaires multi-configurations du programme européen Copernicus. Avec le développement de la technologie de télédétection spatiale, et plus particulièrement avec l’arrivée des constellations Sentinel (Sentinel-1, 2, 3) à haute résolution spatiale et temporelle, il existe un meilleur outil pour estimer les états des surfaces continentales. Ce travail de thèse comprend principalement deux priorités liées à des interventions humaines dans le cycle hydrologique:la cartographie de l'irrigation en tant que action humaine liée directement à l'humidité du sol et le forçage des barrages dans un modèle de simulation de rivière en tant qu'application liée à l’estimation du niveau de l'eau libre. Un premier axe de recherche a été basé sur une analyse statistique des données SAR Sentinel-1 pour caractériser l’état hydrique du sol. Deux méthodes ont été développées pour estimer ce paramètre avec une résolution spatiale de 100 m. Elles sont basées sur des approches de détection de changement à partir des données Sentinel-1 acquises en polarisation VV (verticale-verticale), combinées aux données optiques Sentinel-2 pour corriger les effets de la végétation. L’application consistait à cartographier l'irrigation, avec des résolutions spatiale et temporelle élevées. Une méthodologie de cartographie de l'irrigation utilisant des données SAR Sentinel-1 a été proposée. Elle estbasée sur les acquisitions en polarisations VV (vertical-vertical) et VH (vertical-horizontal). A partir de la série temporelle des mesures Sentinel-1, des paramètres statistiques tel que la valeur moyenne, la variance du signal, la longueur de corrélation temporelle et la dimension fractale, sont analysées, en fonction du type de culture; cultures annuelles irriguées, arbres irrigués et cultures pluviales. Des classifications supervisées utilisant les approches Random Forest et SVM sont testées. En deuxième axe, l'estimation de la hauteur de la surface de l'eau à partir des données altimétriques de Sentinel-3 avec l’altimètre SAR (SRAL) a été réalisée à l'aide de différents algorithmes afin d'améliorer la précision sur des petites surfaces. Cette étude présente trois algorithmes spécialisés (ou retrackers) dédiées à la minimisation de la contamination des sols par les formes d’ondes permettant de récupérer les niveaux d’eau à partir de données altimétriques SAR sur des masses d’eaux intérieures. Les performances de la méthode de sélection de portion de forme d'onde proposée avec trois retrackers, à savoir, le retracker à seuil, le retracker à centre de gravité décalé (OCOG) et le retracker à base physique à 2 étapes, sont comparées. Des séries chronologiques de niveaux d'eau sont extraites pour les masses d'eau du bassin de l'Èbre (Espagne). Une application des produits altimétriques est proposée. Le produit de niveau d’eau a été utilisé comme paramètre d’entrée pour analyser l’effet tampon des barrages dans les simulations de débits fluviaux.

Water balance models are important for the characterization of hydrologic systems, to help understand regional scale dynamics, and to identify hydro-climatic trends and systematic biases in data. Because existing models have, to-date, only been tested on data sets of limited spatial representativeness and extent, it has not yet been established that they are capable of reproducing the range of dynamics observed in nature. This dissertation develops systematic strategies to guide selection of water balance models, establish data requirements, estimate parameters, and evaluate performance. Through a series of three papers, these challenges are investigated in the context of monthly water balance modeling across the conterminous United States. The first paper reports on an initial diagnostic iteration to evaluate relevant components of model error, and to examine details of its spatial variability. We find that to conduct a robust model evaluation it is not sufficient to rely upon conventional NSE and/or r^2aggregate statistics of performance; to have reasonable confidence that the model can provide hydrologically consistent simulations, it is also necessary to examine measures of water balance and hydrologic variability. The second paper builds upon the results of the first, and evaluates the suitability of several candidate model structures, focusing specifically snow-free catchments. A diagnostic Maximum-Likelihood model evaluation procedure is developed to incorporate the notion of `Hydrological Consistency' and controls for structural complexity. The results confirm that the evaluation of hydrologic consistency, based on benchmark comparisons and on stringent analysis of residuals, provides a robust basis for guiding model selection. The results reveal strong spatial persistence of certain model structures that needs to be understood in future studies. The third paper focuses on understanding and improving the procedure for constraining model parameters to provide hydrologically consistent results. In particular, it develops a penalty-function based modification of the Mean Squared Error estimation to help ensure proper reproduction of system behaviors by minimizing interaction of error components and by facilitating inclusion of relevant information. The analysis and results provide insight into the identifiability of model parameters, and further our understanding of how performance criteria should be applied during model identification.

Thesis (PhD)--Stellenbosch University, 2013.
ENGLISH ABSTRACT: The sodic and leucocratic Tonalite, Trondhjemite and Granodiorite (TTG) granitoid series of rocks characterise Paleo- to Meso- Archaean felsic continental crust, yet are uncommon in the post-Archaean rock record. Consequently, petrogenetic studies on these rocks provide valuable insight into the creation and evolution of Earth’s early continental crust. The highpressure (HP)-type of Archaean TTG magmas are particularly important in this regard as their geochemistry requires that they are formed by high-pressure melting of a garnet-rich eclogitic source. This has been interpreted as evidence for the formation of these magmas by anatexis of the upper portions of slabs within Archaean subduction zones. In general, TTG magmas have been assumed to arise through fluid-absent partial melting of metamafic source rocks. Therefore, very little experimental data on fluid-present eclogite melting to produce Archaean TTG exist, despite the fact that water drives magmatism in modern arcs. Consequently, this study experimentally investigates the role of fluid-present partial melting of eclogite-facies metabasaltic rock in the production of Paleo- to Meso-Archaean HP-type TTG melts. Experiments are conducted between 1.6 GPa and 3.0 GPa and 700 ºC and 900 ºC using natural and synthetic eclogite, and gel starting materials of low-K2O basaltic composition. Partial melting of the natural and synthetic eclogite occurred between 850 ºC and 870 ºC at pressures above 1.8 GPa, and the melting reaction is characterised by the breakdown of sodic clinopyroxene, quartz and water: Qtz + Cpx1 + H2O ± Grt1 = Melt + Cpx2 ± Grt2. The experimental melts have the compositions of sodic peraluminous trondhjemites and have compositions that are similar to the major, trace and rare earth element composition of HPtype Archaean TTG. This study suggests that fluid-present eclogite melting is a viable petrogenetic model for this component of Paleo- to Meso-Archaean TTG crust. The nature of the wet low-K2O eclogite-facies metamafic rock solidus has been experimentally defined and inflects towards higher temperatures at the position of the plagioclase-out reaction. Therefore, the results indicate that a crystalline starting material is necessary to define this solidus to avoid metastable melting beyond temperatures of the Pl + H2O + Qtz solidus at pressures above plagioclase stability. Furthermore, this study uses numerical and metamorphic models to demonstrate that for reasonable Archaean mantle wedge temperatures within a potential Archaean subduction zone, the bulk of the water produced by metamorphic reactions within the slabs is captured by an anatectic zone near the slab surface. Therefore, this geodynamic model may account for HP-type Archaean TTG production and additionally provides constraints for likely Archaean subduction. The shape of the relevant fluid-present solidus is similar to the shape of the pressure-temperature paths followed by upper levels of the proposed Archaean subducting slab, which makes water-fluxed slab anatexis is very dependant on the temperature in the mantle wedge. I propose that cooling of the upper mantle by only a small amount during the late Archaean ended fluid-present melting of the slab. This allowed slab water to migrate into the wedge and produce intermediate composition magmatism which has since been associated with subduction zones.
AFRIKAANSE OPSOMMING: Die reeks natruimhoudende en leukokraties Tonaliet, Trondhjemiet en Granodioriet (TTG) felsiese stollingsgesteentes is kenmerkend in die Paleo- tot Meso-Argeïkum felsiese kontinentale kors, maar is ongewoon in die post-Argeïese rots rekord. Gevolglik, petrogenetiese studies op hierdie rotse verskaf waardevolle insig in die skepping en evolusie van die aarde se vroeë kontinentale kors. Die hoë-druk (HD)-tipe van die Argeïkum TTG magmas is veral belangrik in hierdie verband as hulle geochemie vereis dat hulle gevorm word deur hoë druk smelting van 'n granaat-ryk eklogitiese bron. Dit word interpreteer as bewys vir die vorming van hierdie magmas deur smelting van die boonste gedeeltes van die blaaie in Argeïese subduksie sones. TTG magmas in die algemeen, is veronderstel om op te staan deur middel van water-afwesig gedeeltelike smelting van metamafiese bron rotse. Daarom bestaan baie min eksperimentele data op water-teenwoordig eklogiet smelting om Argeïkum TTG te produseer, ten spyte van die feit dat water magmatisme dryf in moderne boë. Gevolglik is hierdie studie ‘n eksperimentele ondersoek in die rol van water-teenwoordig gedeeltelike smelting van eklogiet-fasies metamafiese rots in die produksie van Paleo- tot Meso-Argeïkum HD-tipe TTG smelte. Eksperimente word uitgevoer tussen 1.6 GPa en 3.0 GPa en 700 ºC en 900 ºC met behulp van natuurlike en sintetiese eklogiet, en gel begin materiaal van lae-K2O basaltiese samestelling. Gedeeltelike smelting van die natuurlike en sintetiese eklogiet het plaasgevind tussen 850 ºC en 870 ºC te druk bo 1.8 GPa, en die smeltings reaksie is gekenmerk deur die afbreek van natruimhoudende klinopirokseen, kwarts en water: Qtz + Cpx1 + H2O ± Grt1 = Smelt + Cpx2 ± Grt2. Die eksperimentele smelte het die komposisies van natruimhoudende trondhjemites en is soortgelyk aan die hoof-, spoor- en seldsame aard element samestelling van HD-tipe Argeïkum TTG. Hierdie studie dui daarop dat water-teenwoordig eklogiet smelting 'n lewensvatbare petrogenetiese model is vir hierdie komponent van Paleo- tot Meso-Argeïkum TTG kors. Die aard van die nat lae-K2O eklogietfasies metamafiese rock solidus is eksperimenteel gedefinieër en beweeg na hoër temperature by die posisie van die plagioklaas-out reaksie. Daarom dui die resultate daarop dat 'n kristallyne materiaal nodig is om hierdie solidus te definieër en metastabiele smelting buite temperature van die Pl + H2O + Qtz solidus druk bo plagioklaas stabiliteit te vermy. Verder maak hierdie studie gebruik van numeriese en metamorfiese modelle om aan te dui dat die grootste deel van die water geproduseer deur metamorfiese reaksies binne die blaaie bestaan vir redelike Argeïkum mantel wig temperature binne 'n potensiële Argeïkum subduksie sone, en word opgevang deur 'n smelting sone naby die blad oppervlak. Daarom kan hierdie geodinamies model rekenskap gee vir HD-tipe Argeïkum TTG produksie en dit bied ook die beperkinge vir waarskynlik Argeïese subduksie. Die vorm van die betrokke waterteenwoordig solidus is soortgelyk aan die vorm van die druk-temperatuur paaie gevolg deur die boonste vlakke van die voorgestelde Argeïkum subderende blad, wat water-vloeiing blad smeltingbaie afhanklik maak van die temperatuur in die mantel wig. Ons stel voor dat afkoeling van die boonste mantel met slegs 'n klein hoeveelheid gedurende die laat Argeïese, die water-vloeiing smelting van die blad beëindig. Dit het toegelaat dat die blad water in die wig migreer en intermediêre samestelling magmatisme produseer wat sedert geassosieer word met subduksie sones.

Recent research in seasonal climate prediction has focused on combining multiple atmospheric General Circulation Models (GCMs) to develop multimodel ensembles. A new approach to combine multiple GCMs is proposed by analyzing the skill of candidate models contingent on the relevant predictor(s) state. To demonstrate this approach, we combine historical simulations of winter (December-February, DJF) precipitation and temperature from seven GCMs by evaluating their skill â represented by Mean Square Error (MSE) â over similar predictor (DJF Nino3.4) conditions. The MSE estimates are converted into weights for each GCM for developing multimodel tercile probabilities. A total of six multimodel schemes are considered that includes combinations based on pooling of ensembles as well as based on the long-term skill of the models. To ensure the improved skill exhibited by the multimodel scheme is statistically significant, we perform rigorous hypothesis tests comparing the skill of multimodels with individual modelsâ skill. The multimodel combination contingent on Nino3.4 show improved skill particularly for regions whose winter precipitation and temperature exhibit significant correlation with Nino3.4. Analyses of weights also show that the proposed multimodel combination methodology assigns higher weights for GCMs and lesser weights for climatology during El Nino and La Nina conditions. On the other hand, due to the limited skill of GCMs during neutral conditions over the tropical Pacific, the methodology assigns higher weights for climatology resulting in improved skill from the multimodel combinations. Thus, analyzing GCMsâ skill contingent on the relevant predictor state provide an alternate approach for multimodel combination such that years with limited skill could be replaced with climatology.

The Gascoyne continental shelf is located along the north-central coastline of Western Australia between latitudes 21° and 28°S. This study presents CTD and ADCP data together with concurrent wind and satellite imagery, to provide a description of the summer surface circulation pattern along the continental margin, and the hydrography present in the upper 1km of ocean, between latitudes 21° and 35°S. It also discusses the outcome of a numerical modelling study that examined the physical factors contributing to a bifurcation event persistently observed in satellite imagery at Point Cloates. The region comprises a complex system of four surface water types and current systems. The Leeuwin Current dominated the surface flow, transporting lower salinity, warmer water poleward along the shelf-break, and causing downwelling. Its signature ‘aged’ from a warm (24.7°C), lower salinity (34.6) water in the north to a cooler (21.9°C), more saline (35.2) water in the south, as a result of 2-4Sv geostrophic inflow of offshore waters. The structure and strength of the current altered with changing bottom topographies. The Ningaloo Current flowed along the northernmost inner coast of the Gascoyne shelf, carrying upwelled water and re-circulated Leeuwin Current water from the south. Bifurcation of the Ningaloo Current was seen south of the coastal promontory at Point Cloates. Numerical modelling demonstrated a combination of southerly winds and coastal and bottom topography off Point Cloates to be responsible for the recirculation, and indicated that the strength of southerly winds affect recirculation. Hypersaline Shark Bay outflow influenced shelf waters at the Bay’s mouth and to the south of the Bay. The Capes Current, a wind-driven current from south of the study region was identified as a cooler, more saline water mass flowing northward. Results of the hydrography study show five different water masses present in the upper-ocean. Their orientations were affected by the geopotential gradient driven Leeuwin Current/Undercurrent system at the continental margin. The Leeuwin Undercurrent was found at the shelf-slope, carrying (>252 μM/L) Subantarctic Mode Water at a depth of 400m

Cluster analyses of seasonal (spring and fall) National Marine Fisheries Service Groundfish Survey bottom trawl catches on the Middle Atlantic Bight continental shelf revealed consistent species associations and faunal zones over a nine year period during. Boundaries between faunal zones tended to follow isotherms on the inner portions of the shelf and isobaths along the outer shelf. During the late winter/early spring, four faunal zones were identified: a northern inner and middle shelf zone extending from Cape Cod southward to about Delaware Bay, a northern middle and outer shelf zone offshore of the first zone, a southern middle and outer shelf zone, and a fourth zone on the shelf break and upper slope. The southern inner shelf was a transition zone between the first and third zones. Five species groups were identified: a small cryophilic group restricted to the first zone, a cold-water boreal group found in the first two zones, a ubiquitous boreal/resident group containing the major dominants, a warm-temperate group confined to the warmer southern and outer shelf waters, and a group of slope residents confined to the deepest zone. During the fall, five faunal zones were identified: a southern inner and middle shelf zone, a northern inner shelf zone, a northern mid-shelf zone, an outer shelf zone and a shelf break/upper slope zone. The five species associations recognized were largely analogous to those in the spring, with the following exceptions: the cryophilic group was absent, the ubiquitous group contained mixed boreal and warm-temperate elements, and a second outer shelf group was recognized. The most notable change in the distribution of groups from the spring was a general northward shift in the distributions of the boreal species and a sharply defined inshore movement of the warm temperate group. Analyses of a single summer cruise showed patterns of distribution intermediate to those seen during the spring and fall. Absolute abundances, both of individual species and the total fish community, were highly variable between areas, seasons and years. Species diversity and its components appear to be of little utility in describing the fish communities of the open continental shelves.

Thesis (Ph. D.)--Earth and Atmospheric Sciences, Georgia Institute of Technology, 2007.
Martial Taillefert, Committee Member ; Jay Brandes, Committee Member ; Markus Huettel, Committee Member ; Philip Froelich, Committee Member ; Ellery Ingall, Committee Member ; Richard A. Jahnke, Committee Chair.

Lakes are key indicators of environmental change and major repositories of biodiversity and ecosystem services. However, studies of lake response to drivers of change at a pan-European scale are exceptionally rare. The need for such studies has been given renewed impetus by concerns over climate change and because of international policyrelated schemes, such as the EU Water Framework Directive that has made it legal requirement to repeatedly assess and monitor the ecological status of European lakes toward their effective management and sustainable use. This has introduced the need for methods that can be widely applied across large spatial and temporal scales and produce comparable results. Remote sensing is a promising method for providing such information, but the spatial transferability and temporal repeatability of methods and relationships observed remains untested. In this project, an extensive dataset of field measurements was compiled covering temperature, chlorophyll a and Secchi disk depth in 23 European lakes spanning the last 30 years. The characteristics of these lake systems were explored and similarities in their ecological behavior identified, thus providing the basis for their grouping. Then the potential of remote sensing for estimating and monitoring lake water quality at wide spatial and temporal scales was assessed and thus the long remote sensing archive at the NEODAAS DSRS was fundamental for the purposes of this project. Using NOAA AVHRR, Terra/Aqua MODIS and field data from lakes that represented three main lake groups, the spatial and temporal reliability of 26 existing water quality estimation algorithms was assessed. Following this, the best performing algorithms were applied to all study sites and the effect of scale and spatial resolution upon reliable estimation of key water quality parameters was evaluated. It was demonstrated that the NOAA AVHRR and Terra/Aqua MODIS were both capable of producing highly accurate (R2 > 0.9) lake surface temperature estimates in lakes with variable characteristics and a variety of thermal spatial features, and longterm patterns within the study sites could be studied with NOAA AVHRR data despite the relatively coarse spatial resolution of the sensor. Restricting factors to the latter were the size and shape of lakes and the frequency of cloud cover. By contrast, the development of a universal Terra/Aqua MODIS algorithm for the estimation of chlorophyll a and Secchi disk depth in variable lakes was more challenging due to the optical complexity of Case II waters. Terra/Aqua MODIS data showed a potential, but the use of a different technique (e.g. multivariate regression or neural networks) and/or a different sensor (e.g. Envisat MERIS) could potentially improve the predictive accuracy of the algorithms.

Mestrado em Arquitectura Paisagista - Instituto Superior de Agronomia
The main goal of the present work is the study of the climate influence in the selection of plant species suitable to be used in landscape architecture in continental Portugal. The two climatic variables considered as conditioning the most the vegetation in the Portuguese continental territory were the average absolute minimum temperature (treated using USDA hardiness zones) and the annual potential water deficit. A map was produced for each one of these variables, for the study area. The maps were made using weather stations from the Portuguese Meteorology Institute (IM), and the interpolation method chosen was the multivariate regression with residual kriging. A cartographic application to the vegetation was made using four native plant species, for which a selection index was calculated for each crossed class of the two climatic maps and potential distribution maps made using the bioclimatic envelope method. It is intended that the two climatic maps produced here may be useful tools in the selection of vegetation in landscape architecture scope.

A presente tese tem como objectivo aumentar o conhecimento da flora diatomológica de água doce de Portugal e inclui as seguintes partes: 1) uma compilação dos táxones citados para o país (Arquipélagos dos Açores e Madeira incluídos), baseada numa análise bibliográfica; 2) um atlas ilustrado em microscopia óptica e electrónica dos táxones mais frequentes e abundantes em Portugal Continental, baseado na análise de amostras de cursos de água e albufeiras de todo o país; 3) um estudo detalhado de dois grupos taxonomicamente problemáticos, como o complexo Gomphonema tergestinum - G. rosenstockianum e a descrição do Achnanthidium caravelense, uma nova espécie frequente e abundante no Norte de Portugal, em águas com concentração baixa a moderada de nutrientes; 4) a aplicação de métodos baseados em diatomáceas epilíticas litorais e índices diatomológicos (Índice de Poluosensibilidade Específica) na avaliação do estado ecológico de albufeiras, de acordo com os requisitos da Directiva Quadro da Água; ABSTRACT: This thesis intends to increase the knowledge of the freshwater diatom flora from Portugal and comprises the following parts: 1) the compilation of the taxa already cited for the country (Azores and Madeira Archipelagos included) based on analysis of the literature; 2) the illustration under light and scanning electron microscopy of the most frequent and abundant taxa, based on samples collected in watercourses and reservoirs from the entire Continental Portugal; 3) a detailed study of two problematic species complexes, with taxonomic clarification of the Gomphonema tergestinum and G. rosenstockianum complex and description of Achnanthidium caravelense, a new taxon frequent and abundant in soft waters with low to moderate nutrient content in northern Portugal; 4) the application of methods based on epilithic littoral diatoms and diatom indices (Specific Polluosensitivity Index) for the assessment of the ecological status of reservoirs in accordance with the requirements of the Water Framework Directive.

Conselho Nacional de Desenvolvimento CientÃfico e TecnolÃgico
The contamination of surface water bodies due to antropic action has made water ever more scarce. Knowledge of the water quality is essential to determine instruments for it's management . Monitoring water quality in huge areas requires a high number of saimples for water quality control. This fact, allied to the high costs of water analysis, limits the evaluation that can be made of continental waters. Even though in later years geoprocessing and remote sensing techniques have been developed with important results in water quality studies, these techniques have yet to be applied in the study of aquatic systems in semiarid regions. Therefore, it was attempted to develop a methodology based on the spectral characteristics of water as a support method for the evaluation of water quality in semiarid regions. Water samples were collected in seven points from 2008 to 2010 (every two months) and in 20 points from 2011 and 2012 (every three months) . The campaigns for radiometric data acquisition occurred in 2011 and 2012, alongside the water sampling. The determinant factors and water similarity were identified by the multivariable analysis. Data from orbital and insitu remote sensing correlated with limnologic data were used. The determinant indicators for water quality in the Oros were defined mainly by the following factors: the geologic components of the soil; sediment transport by surface flow and organic pollution. The Cluster Analysis formed three distinct groups. The water similarity was defined by natural conditions and by the land use around the reservoir and along the basin. The models developed for limnologic variables, suspended inorganic solids, turbidity, transparency and electric conductivity, showed themselves to be trustworthy, indicating that these variables can be quantified remotely through remote sensing data. The models developed for the clorophile - a fitted well, indicating that this variable can be quantified accurately through in situand orbital remote sensing data. The general three banded model presented a better efficiency to that of the two band model. According to the developed model and the image use of the MERIS sensor, the Oros waters, as far as trophic state is concerned, presented 61.15% of it's water bater classified as eutrophic for the month of February, 2010. For the MERIS image of August 2011, 95.77% of it's waters were classified as eutrophic. Therefore, through remote sensing data it is possible to elaborate a water resources management at a lower cost, generating a usefull information for decision making by managers, vital for the implementation of public policies at county, regional, state and federal levels.
Com a contaminaÃÃo de corpos hÃdricos pela aÃÃo antrÃpica, a disponibilidade de Ãgua torna-se cada vez menor. O conhecimento da qualidade das Ãguas à essencial à proposiÃÃo de instrumentos de gestÃo das mesmas. O monitoramento em Ãreas extensas requer um elevado nÃmero de amostras para o controle da qualidade da Ãgua; este fato, aliado aos altos custos das anÃlises, limita a avaliaÃÃo do processo de degradaÃÃo das Ãguas interiores. Apesar do desenvolvimento, nos Ãltimos anos, das tÃcnicas de geoprocessamento e sensoriamento remoto, com a obtenÃÃo de informaÃÃes relevantes em estudo de qualidade de Ãguas, elas nÃo tÃm sido exploradas em estudos de sistemas aquÃticos de regiÃes semiÃridas. Com isso, objetivou-se desenvolver uma metodologia baseada nas propriedades espectrais da Ãgua como suporte a avaliaÃÃo de sua qualidade em ambientes semiÃridos. As amostras de Ãgua foram coletadas em sete pontos de 2008 a 2010 (bimestralmente) e em 20 pontos de 2011 a 2012 (trimestralmente). As campanhas para aquisiÃÃo de dados radiomÃtricos ocorreram em 2011 e 2012, concomitantes Ãs coletas das amostras de Ãgua. Os fatores determinantes e a similaridade das Ãguas foram identificados pelo emprego da anÃlise multivariada. Foram usados dados de sensoriamento remoto orbital e in situ, correlacionando com os dados limnolÃgicos. Os indicadores determinantes da qualidade das Ãguas do OrÃs sÃo definidos principalmente pelos seguintes fatores: processo natural de intemperismo dos componentes geolÃgicos do solo; carreamentos dos sÃlidos suspensos atravÃs do escoamento superficial das Ãguas e poluiÃÃo orgÃnica. A anÃlise de agrupamento formou trÃs grupos distintos. A similaridade das Ãguas foi definida pelas condiÃÃes naturais e pelas atividades antrÃpicas exercidas nas proximidades do reservatÃrio e ao longo da bacia. Os modelos desenvolvidos para as variÃveis limnolÃgicas, sÃlidos inorgÃnicos suspensos, turbidez, transparÃncia e condutividade elÃtrica, mostraram-se confiÃveis, indicando que essas variÃveis podem ser quantificadas remotamente a partir dos dados de sensoriamento remoto de campo. Os modelos desenvolvidos para a variÃvel clorofila-a sÃo confiÃveis, indicando que esta variÃvel pode ser quantificada remotamente a partir dos dados de sensoriamento remoto de campo e orbital com elevado grau de confiabilidade. O modelo geral de trÃs bandas apresentou desempenho superior ao modelo de duas bandas. De acordo com o modelo desenvolvido e com uso de imagens do sensor MERIS, as Ãguas do reservatÃrio OrÃs, quanto ao estado trÃfico, apresentaram 61,15% da sua bacia hidrÃulica classificadas como eutrÃfica, para o mÃs de fevereiro de 2010. Para a imagem MERIS de agosto de 2011, 95,77% das Ãguas foram classificadas como eutrÃficas. Portanto, com o uso do sensoriamento remoto à possÃvel elaborar um gerenciamento dos recursos hÃdricos de menor custo, gerando informaÃÃes Ãteis à tomada de decisÃes pelos gestores, vital para a implantaÃÃo de polÃticas pÃblicas em Ãmbito municipal, regional, estadual e federal.

The aim of this thesis is to assess the spatial and temporal recurrence of mass-transport deposits (MTDs) within salt withdrawal basins to unravel the complex interaction between mass-wasting processes and salt halokinesis. A high-quality 3D seismic dataset from the mid-continental slope of Espírito Santo Basin, SE Brazil, was used to assess the provenance of mass-transport deposits and their potentials as structural markers for seafloor perturbation and fault activity. A new proposition from this work includes scale-independent classification of mass- transport deposits into homogeneous and heterogeneous types. Heterogeneous MTDs are composed of seismic facies corresponding to slides, slumps and debrites. Homogeneous MTDs comprise consolidated debrites considered in this work as comprising barriers to fluid flow. In addition, MTD composed of rafted blocks displayed a disproportionate relationship between their shape, transporting distance and degree of remobilization. Drag zones denote sections of MTDs that are uplifted during salt diapir rise. These drag zones are extended and shortened along their long and short axis respectively. Ramps flanking salt diapirs are formed by either complete or partial erosion of paleo-seafloors and pre-existing fault scarps. In this thesis, it is shown that the risk of remobilized sediments is highest within drag zones. The erosive nature of mass-wasting processes is justified by the decoupling history of faults eroded by MTDs. An innovative method to assess fault decoupling history on continental margin is the use of cumulative throw character. MTD-decoupled faults are iv | P a g e characterised by shorter propagation rate and cumulative throw and are potentially sealing compared to their non-decoupled counterparts. The information from this study is crucial information for successful hydrocarbon exploration and risk assessment in deep-water environments. The methodologies and results from this thesis are applicable to continental margins worldwide.

A Plataforma Continental do Estado do Ceará (PCCE) foi dividida em: Plataforma Continental Externa (PCE), Plataforma Continental Média (PCM) e Plataforma Continental Interna (PCI). Os critérios físicos adotados levaram em consideração intrusões mais ou menos intensas de água tropical (AT) transportada pela Corrente Norte do Brasil (CNB) em direção à costa; a intensificação dos gradientes de salinidade superficial; e a mistura entre diferentes massas de água. Durante a estação de chuva, observamos que na região da PCE a massa de Água Tropical (AT) ficou aprisionada em níveis verticais maiores que 60 m, enquanto que na PCI observamos a formação de uma pluma estuarina que ocupou os dois primeiros metros da coluna de água e provocou o rebaixamento do topo da massa de água costeira (AC), chegando a 6 km da linha de costa. A variação espaço-temporal das correntes na frequência submaregráfica mostram que a tensão de cisalhamento do vento (TCV) foi o principal agente na transferência de momentum para as águas da PCCE, gerando uma corrente de deriva polarizada para NW, paralela à direção das isóbatas, em resposta ao empilhamento de água na costa. Este comportamento, associado a espessura da camada de Ekman muito maior que a profundidade local, mostra que a dinâmica do primeiro modo de oscilação (barotópico) é dominante, gerando correntes na direção do vento forçante, como resposta à sua ação. O modo barotópico também foi dominante nas correntes de maré, com as componentes semi-diurnas (M2 e S2) caracterizando-se como as mais energéticas. A orientação normal das elipses de maré associada ao sentido horário de rotação, foram responsáveis pelas maiores velocidades de corrente na frequência maregráfica. Os resultados obtidos com o modelo numérico mostram a res\\-posta barotrópica das águas da PC a um vento estacionário com correntes para NW. Os maiores valores das corrente e elevação do nível do mar ocorreram na região mais próxima à costa. As correntes de maré e a orientação das elipses de maré obtidas com a modelagem corroboram o o comportamento dos dados observacionais. Para o estuário do Rio Jaguaribe (CE), o período de grandes descargas fluviais resultou em fluxos unidirecionais transportando volumes de 97 x 106 m3, advectando os processos de mistura para a região da PCI. Entretanto, na estação seca, a minimização dos fluxos fluviais resultou na maior atuação da maré na região, controlando a posição espacial da zona de máxima turbidez. Nesta época do ano o estuário foi classificado de acordo com parâmetros de estratificação e circulação como do tipo 2a, parcialmente misturado.
The Continental Shelf of Ceará State was divided in: External (ECS), Middle (MCS) and Inner (ICS) Continental Shelf. The physical criteria of classification considered intrusions of Tropical Water (TW) transported onshore by the North Brazil Current (NBC); intensification of surface saline gradient; and mixing of different water masses. During the rainy season, the TW was retained the ECS at levels higher than 60 m, while an estuarine plume formation was observed in the PCI, occupying the two first meters of the water column, sinking top of the coastal water mass (CW) to 6 km off coast. The space-time variation of the currents in the subtidal frequency shows that wind stress was the main agent in the momentum transfer to continental shelf waters, generating a current to NW, parallel to the direction of the isobaths, in response to the stacking of water on the coast. This behavior associated to the thickness of the Ekman layer much larger than local depth, shows the dominance of the barotropic dynamic, generating currents in the wind direction, as response to its action. The barotropic mode was also dominant in the tidal currents, with semi-diurnals components (M2 e S2) characterized as the most energetic. The normal orientation of tidal ellipses, associated to clockwise rotation, were responsible for the highest current velocities in tidal frequency in MCS. Numerical model results show a barotropic response of waters to a stationary wind, with currents to NW, and highest values of currents and sea level ocurring closer the coast. Tidal currents and tidal ellipses orientation obtained by numerical model support the observations. In relation to Jaguaribe River estuary, the period of great river input led to unidirectional flows, which transport volumes of 97 x 106 m3, advecting the mixing process to the ICS region. However, during the dry season, river input decrease resulted in a larger tide influence in the region, controlling the spatial position of the mixing zone. For this time, the estuary was classified according to the parameters of estratification and circulation as a 2a type, partially mix

Accurate simulation of energy, water, and carbon fluxes exchanging between the land surface and the atmosphere is beneficial for improving terrestrial ecohydrological and climate predictions. We systematically assessed the Noah land surface model (LSM) with mutiparameterization options (Noah-MP) in simulating these fluxes and associated variations in terrestrial water storage (TWS) and snow cover fraction (SCF) against various reference products over 18 United States Geological Survey two-digital hydrological unit code regions of the continental United States (CONUS). In general, Noah-MP captures better the observed seasonal and interregional variability of net radiation, SCF, and runoff than other variables. With a dynamic vegetation model, it overestimates gross primary productivity by 40% and evapotranspiration (ET) by 22% over the whole CONUS domain; however, with a prescribed climatology of leaf area index, it greatly improves ET simulation with relative bias dropping to 4%. It accurately simulates regional TWS dynamics in most regions except those with large lakes or severely affected by irrigation and/or impoundments. Incorporating the lake water storage variations into the modeled TWS variations largely reduces the TWS simulation bias more obviously over the Great Lakes with model efficiency increasing from 0.18 to 0.76. Noah-MP simulates runoff well in most regions except an obvious overestimation (underestimation) in the Rio Grande and Lower Colorado (New England). Compared with North American Land Data Assimilation System Phase 2 (NLDAS-2) LSMs, Noah-MP shows a better ability to simulate runoff and a comparable skill in simulating R-n but a worse skill in simulating ET over most regions. This study suggests that future model developments should focus on improving the representations of vegetation dynamics, lake water storage dynamics, and human activities including irrigation and impoundments.

The Antarctic plays an important role in the global climate system. On the one hand, the Antarctic Ice Sheet is the largest freshwater reservoir on Earth. On the other hand, a major proportion of the global bottom-water formation takes place in Antarctic shelf regions, forcing the global thermohaline circulation. The main goal of this dissertation is to provide new insights into the dynamics and stability of the EAIS during the Quaternary. Additionally, variations in the activity of bottom-water formation and their causes are investigated. The dissertation is a German contribution to the International Polar Year 2007/ 2008 and was funded by the ‘Deutsche Forschungsgesellschaft’ (DFG) within the scope of priority program 1158 ‘Antarctic research with comparative studies in Arctic ice regions’. During RV Polarstern expedition ANT-XXIII/9, glaciomarine sediments were recovered from the Prydz Bay-Kerguelen region. Prydz Bay is a key region for the study of East EAIS dynamics, as 16% of the EAIS are drained through the Lambert Glacier into the bay. Thereby, the glacier transports sediment into Prydz Bay which is then further distributed by calving icebergs or by current transport. The scientific approach of this dissertation is the reconstruction of past glaciomarine environments to infer on the response of the Lambert Glacier-Amery Ice Shelf system to climate shifts during the Quaternary. To characterize the depositional setting, sedimentological methods are used and statistical analyses are applied. Mineralogical and (bio)geochemical methods provide a means to reconstruct sediment provenances and to provide evidence on changes in the primary production in the surface water column. Age-depth models were constructed based on palaeomagnetic and palaeointensity measurements, diatom stratigraphy and radiocarbon dating. Sea-bed surface sediments in the investigation area show distinct variations in terms of their clay minerals and heavy-mineral assemblages. Considerable differences in the mineralogical composition of surface sediments are determined on the continental shelf. Clay minerals as well as heavy minerals provide useful parameters to differentiate between sediments which originated from erosion of crystalline rocks and sediments originating from Permo-Triassic deposits. Consequently, mineralogical parameters can be used to reconstruct the provenance of current-transported and ice-rafted material. The investigated sediment cores cover the time intervals of the last 1.4 Ma (continental slope) and the last 12.8 cal. ka BP (MacRobertson shelf). The sediment deposits were mainly influenced by glacial and oceanographic processes and further by biological activity (continental shelf), meltwater input and possibly gravitational transport. Sediments from the continental slope document two major deglacial events: the first deglaciation is associated with the mid-Pleistocene warming recognized around the Antarctic. In Prydz Bay, the Lambert Glacier-Amery Ice Shelf retreated far to the south and high biogenic productivity commenced or biogenic remains were better preserved due to increased sedimentation rates. Thereafter, stable glacial conditions continued until 400 - 500 ka BP. Calving of icebergs was restricted to the western part of the Lambert Glacier. The deeper bathymetry in this area allows for floating ice shelf even during times of decreased sea-level. Between 400 - 500 ka BP and the last interglacial (marine isotope stage 5) the glacier was more dynamic. During or shortly after the last interglacial the LAIS retreated again due to sea-level rise of 6 - 9 m. Both deglacial events correlate with a reduction in the thickness of ice masses in the Prince Charles Mountains. It indicates that a disintegration of the Amery Ice Shelf possibly led to increased drainage of ice masses from the Prydz Bay hinterland. A new end-member modelling algorithm was successfully applied on sediments from the MacRobertson shelf used to unmix the sand grain size fractions sorted by current activity and ice transport, respectively. Ice retreat on MacRobertson Shelf commenced 12.8 cal. ka BP and ended around 5.5 cal. ka BP. During the Holocene, strong fluctuations of the bottomwater activity were observed, probably related to variations of sea-ice formation in the Cape Darnley polynya. Increased activity of bottom-water flow was reconstructed at transitions from warm to cool conditions, whereas bottom-water activity receded during the mid- Holocene climate optimum. It can be concluded that the Lambert Glacier-Amery Ice Shelf system was relatively stable in terms of climate variations during the Quaternary. In contrast, bottom-water formation due to polynya activity was very sensitive to changes in atmospheric forcing and should gain more attention in future research.
Die Antarktis spielt im globalen Umweltsystem eine tragende Rolle. Mit ihrem mächtigen Eispanzer ist sie nicht nur der größte Süsswasserspeicher auf der Erde, in ihren Schelfregionen wird auch ein Großteil der globalen Bodenwassermassen gebildet, welche die globale thermohaline Zirkulation antreiben. Hauptziel dieser Arbeit, welche einen deutschen Beitrag zum Internationalen Polarjahr 2007/ 2008 liefert, war es, neue Erkenntnisse hinsichtlich der Stabilität des Ostantarktischen Eisschildes während des Quartärs zu liefern. Weiterhin sollten Aussagen über Variationen in der Bildung von Antarktischem Bodenwasser und deren Ursachen getroffen werden. Dazu wurde im Rahmen der ‚Polarstern‘ Expedition ANT-XXIII/9 eine Beprobung glaziomariner Sedimente zwischen Prydz Bucht und Kerguelen Plateau durchgeführt. Diese Region eignet sich zur Untersuchung der Ostantarktischen Eisdynamik besonders gut, da hier der Lambert Gletscher, etwa 16% des Ostantarktischen Eispanzers drainiert. Er transportiert dabei Sediment nach Norden, das schließlich die Prydz Bucht erreicht und durch direkten Transport über kalbende Eisberge oder durch Umlagerung und Verteilung mithilfe von Meeresströmungen weiter verfrachtet wird. Der wissenschaftliche Ansatz dieser Arbeit besteht darin, über die Verteilung dieser Sedimente in Raum und Zeit, d.h. über Variationen des glaziomarinen Paläoregimes, die Reaktion des Lambert Gletschers und des vorgelagerten Amery Schelfeises auf Klimaschwankungen während des Quartärs zu rekonstruieren. Dabei werden sowohl sedimentologische Methoden unter Einbeziehung neuer statistischer Möglichkeiten angewandt, um Sedimentationsprozesse zu charakterisieren, als auch mineralogische und (bio)geochemische Parameter verwendet, um Aussagen über die Herkunft der Sedimente und Änderungen in der Produktivität im Oberflächenwasser treffen zu können. Die Altersbestimmung der Sedimentkerne erfolgte mittels Paläomagnetik, Paläointensitäten, Biostratigraphie und Radiokarbondatierungen. Die Oberflächensedimente im Untersuchungsgebiet zeigen deutliche Unterschiede sowohl hinsichtlich ihrer Tonmineral- als auch Schwermineralzusammensetzung. Beide mineralogischen Parameter zeigen die größten Differerenzen auf dem Schelf. Dort lassen sich deutlich Sedimente der Prydz Bucht von Sedimenten des MacRobertson Shelfes differenzieren. Sie stellen daher ein gutes Hilfsmittel dar, um sowohl die Herkunft von eis- als auch strömungstransportiertem Material zu rekonstruieren. Die untersuchten Sedimentkerne decken den Zeitraum der letzten 1,4 Millionen Jahre (Kontinentalhang) bzw. der letzten 12,8 tausend kal. Jahre v. H. ab (MacRobertson Schelf). Die abgelagerten Sedimente wurden i. W. durch glaziale und ozeanographische Einflüsse geprägt, aber auch durch Bioproduktion (Schelf) bzw. durch Schmelzwassereinträge und möglicherweise gravitative Prozesse (Kontinentalhang). In den Sedimenten des Kontinentalhangs sind zwei starke Enteisungsereignisse überliefert: Das erste Ereignis steht mit dem mittelpleistozänen Klimaoptimum in Verbindung, das auch in anderen antarktischen Regionen nachgewiesen wurde. Es führte in der Prydz Bucht zu einem weitreichenden Rückzug des Lambert Gletscher-Amery Schelfeises (LAIS) und gleichzeitig zu einer hohen Primärproduktion. Danach herrschten bis etwa 400 - 500 tausend Jahre v. H. stabile glaziale Bedingungen. Kalbung von Eisbergen war wahrscheinlich auf den westlichen Teil des Lambert Gletschers begrenzt, wo eine tiefere Bathymetrie auch bei niedrigerem globalen Meeresspiegel noch Aufschwimmen des Gletschereises erlaubt. Zwischen 400 - 500 tausend Jahren v. H. und vermutlich dem letzten Interglazial wurde der Gletscher schließlich wieder dynamischer, um mit oder kurz nach dem letzten Interglazial (Meeresspiegel etwa 6 - 9 m höher) eine weitere Phase deutlichen Rückzuges zu durchlaufen. Beide Ereignisse lassen sich mit Phasen der Eisreduktion in den Prinz Charles Bergen korrelieren, d.h. der Rückzug des Lambert Gletschers hatte möglicherweise ein erhöhtes Nachfließen von Eismassen aus dem Hinterland zur Folge. An den Sedimenten des Schelfkernes wurde ein neu entwickeltes Verfahren der Endmember-Modellierung erfolgreich getestet. Der Eisrückzug auf dem MacRobertson Schelf begann etwa 12,8 tausend kal. Jahre v. H. und war gegen 5,5 tausend kal. Jahre v. H. abgeschlossen. Während des Holozäns kam es zu starken Schwankungen in der Bodenwasseraktivität, die höchst wahrscheinlich mit der Neubildungsrate von Meereis in der Kap Darnley Polynia in Zusammenhang stehen. Besonders auffallend war eine erhöhte Bodenwasseraktivität am Übergang von Warm- zu Kaltphasen bzw. ihr extremer Rückgang während des Mittel-Holozänen Klimaoptimums. Insgesamt zeigen die Ergebnisse der Arbeit, dass sich das LAIS während des Quartärs relativ stabil gegenüber Klimaveränderungen verhalten hat. Die Bodenwasserproduktion in Polynien dagegen reagierte sehr empfindlich auf relative geringe atmosphärische Veränderungen und bedarf in Zukunft verstärkter Aufmerksamkeit.

Dissertação(mestrado) - Universidade Federal do Rio Grande, Programa de Pós-Graduação em Oceanografia Física, Química e Geológica, Instituto de Oceanografia, 2007.
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A costa sul do Brasil, constituída pelas áreas costeiras e oceânicas do Rio Grande do Sul e Santa Catarina, é conhecida como uma das regiões de maior potencial pesqueiro de todo o litoral brasileiro. Isto se deve, sobretudo, a presença de várias massas de água que interagem formando um sistema complexo, dinâmico e altamente produtivo. Além dos intensos processos de mistura, essas regiões apresentam frentes termohalinas e ação de ventos. O presente trabalho apresenta um diagnóstico comparativo, de enfoque químico, entre a plataforma das regiões de Santa Marta (SC) e Albardão (RS). Para tanto, são utilizados parâmetros hidroquímicos, amostrados em 33 estações oceanográficas importantes para a avaliação da produção biológica, e também a interpretação dos processos oceanográficos. Ao efetuar a comparação entre as referidas regiões de plataforma, durante o inverno de 2005, observou-se claramente maiores concentrações de nutrientes dissolvidos na região do Albardão, devido a menor influência da Água Tropical, apresentando-se submetida a processos oceanográficos mais intensos resultantes da proximidade à Convergência Subtropical, da intrusão da Água Subtropical de Plataforma (através do paleocanal), da formação da Frente Subtropical de Plataforma, frentes frias e do volume de descarga continental substancial proveniente do Rio do Prata, Lagoa dos Patos e do transporte subterrâneo que potencializam a dinâmica entre as massas de água, elevando a produtividade da região.
The southern Brazilian Coast comprises of the coastal and oceanic areas of Rio Grande do Sul and Santa Catarina and is a region with the highest fishing potential along the Brazilian coast. This is due to the presence of several water masses that interact form a complex, dynamic and highly productive system. Mixing is also provided by thermohaline fronts, upwelling and wind. The present work presents a diagnosis, using hydrochemical data, between Santa Marta Shelf (SC) and Albardão (RS) (33 oceanographic stations) to determine biological production and other oceanographical processes. During the 2005 winter there were higher nutrients concentrations in Albardão zone, due to less influence of Tropical Water. There is high productivity in the region due to mixing of water masses by proximity to Subtropical Convergence, intrusion of the Subtropical Water on to the Shelf (through the paleochannel), formation of Subtropical Shelf Front, groundwater transport, cold fronts discharge from Prata River, Patos Lagoon.

Numerical classification analyses (clustering) of spring, summer and fall National Marine Fisheries Service bottom trawl catches on the inshore continental shelf between Cape Ann, Ma. and Cape Fear, N.C., showed consistent species associations and faunal zones over a three year period. Analysis of a data set created by combining all nine survey cruises also produced consistent species associations, however sites clustered by seasons as well as by geographic area. The three faunal provinces of the U.S. east coast (Gulf of Maine, Middle Atlantic Bight and South Atlantic Bight) were represented in the study area, as were the seasonal faunal barriers at Nantucket Shoals and Cape Hatteras. Generally, the faunal zones correlated well with the thermal regimes of each province and respected the faunal barriers when strong thermal gradients were present. Only south of Cape Hatteras did depth appear to define a boundary between faunal zones. During the spring, when bottom water temperatures were lowest, four species associations and three faunal zones were identified. The species associations consisted of a cold water boreal group (affiliated only with the faunal zone between Cape Ann and Cape May, N.J.), a less cryophilic boreal group, a eurythermal warm temperate group and a warm temperate group which was restricted to waters south of Cape Hatteras. With vernal warming, a northerly and onshore migration of warm temperate species increased to five the number of species associations in summer. Beside the four groups found in spring, a more thermophilic association was identified. Separations between the northern three summer faunal zones occurred at Nantucket Shoals and northern New Jersey. The other two summer zones were restricted to south of Cape Hatteras and were separated longitudinally (inshore and offshore). In fall, when bottom temperatures were highest, a sixth species group of primarily southern species was identified. This group appeared restricted to the inshore faunal zone south of Cape Hatteras. The five faunal zones recognized in summer were also identified in fall.

Pour la première fois, une étude par spectroscopie infrarouge à transformée de Fourrier et par microsonde ionique des minéraux majeurs de la croûte inférieure et des péridotites mantelliques a été entreprise afin de mieux caractériser les mécanismes d’incorporation et les teneurs en eau de ces minéraux nominalement anhydres, et de déterminer leurs compostions isotopiques en H, O, et Li pour retracer les échanges latéraux et horizontaux de l’eau dans la lithosphère continentale profonde. Les résultats montrent que: (1) Les minéraux nominalement anhydres, comme les pyroxènes et plagioclase, dans les granulites de la croûte inférieure contiennent de l’eau en trace essentiellement sous forme hydroxyles et accessoirement sous forme moléculaire, avec des concentrations (exprimées en poids H2O) allant de 200 à 2330 ppm pour les clinopyroxènes, de 60 à 1875 ppm pour les orthopyroxènes, de 65 à 900 ppm pour les plagioclases. Les teneurs calculées pour chaque roche totale d’après sa composition minéralogique et la teneur en eau des minéraux varient de 155 à 1100 ppm. (2) Les teneurs en H2O des minéraux majeurs et en roche totale de la croûte continentale inférieure sont manifestement plus élevées que celles du manteau lithosphérique sous-jacent, suggérant des variations verticales de la quantité d’H2O dans la lithosphère continentale profonde. Un tel contraste peut affecter de façon notable le comportement rhéologique de la lithosphère continentale. (3) Les rapports isotopiques de l’oxygène des pyroxènes étudiés, et probablement les roches totales, exprimés en [delta]18OSMOW , vont de ~ 4,5 à 12,5‰. Ceci indique la contribution de matériaux recyclés de la croûte continentale durant la pétrogenèse des échantillons ayant un TM18O élevé. (4) Les minéraux de la granulites sont caractérisés par des valeurs de élevées TMD, avec des valeurs de -80~-10‰ exprimées en [delta]DSMOW; les minéraux sont le plus souvent en équilibre les uns avec les autres lorsque l’on considère leurs compositions isotopiques moyennes. (5) Les compositions isotopiques du Lithium mesurée dans les minéraux de nos échantillons de granulites, exprimées en [delta]7Li par rapport à Lsvec, varient de -13 à +4.7 ‰. Ces valeurs sont donc pour la plus part inférieures à celles mesurées sur les MORB (2 – 6‰). La dispersion des valeurs reflètent l’hétérogénéité de la source des granulites, et les valeurs bassent resultent probablement de la perte par diffusion de Li pendant la mise en place des liquides silicatées provenant du manteau dans la croûte inférieure. (6) La grande hétérogénéité des teneurs en eau et en Lithium, et des compositions isotopiques de H-O-Li indique l’absence de circulation de fluide pervasive au travers de la croûte inférieure, qui aurait pour effet de supprimer les hétérogénéités à petite échelle et de les diminuer fortement à grande échelle
For the first time, systematic investigations of water content and H-O-Li isotopic compositions of minerals in lower crustal granulites, as well as water content of minerals in mantle peridotites, from eastern China have been carried out by Fourier transform infrared spectrometer and ion microprobe. The results show that: (1) Nominally anhydrous minerals, such as pyroxenes and plagioclase, in the lower crust generally contain trace amounts of structural water, with their content (H2O by wt.) varying from 200 to 2330 ppm for clinopyroxene, 60 to 1875 ppm for orthopyroxene, 65 to 900 ppm for plagioclase and 155 to 1100 ppm for the estimated bulk compositions. (2) Water contents of minerals in lower crustal granulites from eastern China, and their bulk values, are significantly higher than those in the underlying upper mantle, implying vertical heterogeneities of water distribution in the deep continental lithosphere; the contrast in water content even affect the rheological strength of the lithosphere. (3) The O-isotopic compositions of pyroxenes in the lower crustal granulites from eastern China are highly variable between different localities (~ 4.5 to 12.5‰, expressed in [delta]18OSMOW values), indicating variable influences from recycled crustal materials on their protoliths. (4) The H-isotopic compositions of granulite minerals from eastern China, are mostly in the range of -80 to -10‰ expressed in [delta]DSMOW values, and these minerals are usually in equilibrium with their [delta]D values. The relatively high [delta]D of granulite minerals may be related with degassing loss of H during the genesis of granulites. (5) The Li-isotopic compositions of granulite minerals from eastern China are usually in the range of -13 to 4.7‰, mostly lower than those of MORB (2-6‰). They reflect the source heterogeneity and are probably results of high-T Li diffusion during the intrusion of their original melts into the preexisting lower crust. (6) The large dispersion of Li and water contents and of H-O-Li isotopic results indicate the absence of any pervasive fluids in the lower crust

L’application de la Directive Cadre sur l’Eau et l’obligation de surveillance de la qualité de l'eau pour la consommation humaine et les activités industrielles entraînent une forte demande pour des systèmes d’évaluation et de suivi de la qualité de l’eau. Le projet de recherche MIGR'HYCAR (http://www.migrhycar.com) a donc été mis en place pour répondre à un besoin opérationnel et à un défaut d'outils d'aide à la décision adaptés face aux déversements d'hydrocarbures en eaux continentales (rivières, lacs et estuaires) qui représentent plus de 50% des déversements accidentels en France. Ce travail de thèse s'inscrit dans le cadre de ce projet et a pour but l’étude du comportement des nappes d'hydrocarbures en milieu contrôlé pour les eaux continentales. A cet effet, il propose une approche expérimentale à l’échelle laboratoire pour étudier les phénomènes agissant sur une nappe d'hydrocarbures déversée : dissolution, étalement, évaporation et volatilisation. Les données expérimentales réunis ont permis de constituer une base de données de référence, qui servira de support aux outils de modélisation mathématique de dérive de nappe d'hydrocarbures développés dans le cadre de ce projet.

The climatic conditions of the northern Sierra of Peru are marked by the interaction of different macro- to mesoscale climatic features such as the El Niño Southern Oscillation (ENSO) or Mesoscale Convective Complexes (MCCs) and the seasonally shifting Intertropical Convergence Zone (ITCZ), but also by local scale climatic features such as inhomogeneous topography and local wind fields. The region under investigation, located in the vicinity of the South America Continental Water Divide (CWD), provides the opportunity to study interactions of western and eastern disturbances in a high mountain environment and their effects on rainfall variability. In general, rainfall variability is related to diurnal convection patterns, enhanced by valley breeze systems and modulated by local scale wind anomalies. Spillover of low-level air masses of Pacific origin passing over the Andean ridges is frequent. Although direct effects of ENSO on high Andean rainfall variability are in debate, our findings show that the majority of rain gauges used in this study follow an El Niño/dry and a La Niña/wet signal. However, high elevation areas on the western escarpment of the Andes benefit from abundant nocturnal rainfall that partly offsets the rainfall deficits during El Niño. Our data suggest that the spatial extent of this easterly wet pulse is limited to areas located above 3000 m asl. ENSO cycles contribute to rainfall variability near the CWD in the northern Sierra of Peru by modulating the seasonal rainfall regime and causing a positive temperature anomaly.
Las condiciones climáticas de la sierra norte del Perú están marcadas por la interacción de diferentes rasgos climáticos a escalas macro y meso, tal como el fenómeno ENSO o los Complejos Convectivos a Meso-escala (MCC) y la estacionalmente móvil Zona de Interconvergencia Intertropical (ITCZ), pero también por rasgos climáticos a escala local tales como la heterogeneidad topográfica y los campos de vientos locales. La zona de estudio se ubica en las cercanías de la divisoria de aguas continentales de Sudamérica (CWD), provee la oportunidad de estudiar las interacciones de las disturbancias occidental y oriental en un ambiente de alta montaña y sus efectos en la variabilidad de las precipitaciones. En general la variabilidad de las precipitaciones se relaciona con patrones de convección diurna, reforzada por los sistemas de brisas de valle y modulada por anomalías de vientos a escala local. El desplazamiento de masas de aire a baja altura provenientes del Pacífico que remontan los Andes es frecuente. Aunque los efectos directos del ENSO en la variabilidad de las precipitaciones andinas está todavía en debate, nuestras investigaciones muestran que la mayoría de las mediciones hechas para este estudio siguen una señal El Niño/seco y La Niña/húmedo. Sin embargo, las zonas altas de lasescarpas occidentales de los Andes se benefician de abundante lluvia nocturna que parcialmente completa los déficits de precipitaciones durante El Niño. Nuestros datos sugieren que la cobertura espacial de este pulso húmedo del Este se limita a áreas que se ubican encima de los 3000 msnm. Los ciclos ENSO contribuyen a la variabilidad de las precipitaciones cerca del CWD en la sierra norte del Perú mediante la modulación del régimen estacional de lluvias que causa una anomalía de temperatura positiva.

A utilização de técnicas integradas de análise de proveniência sedimentar, incluindo a petrografia quantitativa utilizando o método Gazzi-Dickinson, a análise convencional de minerais pesados, a análise da composição química de granadas (análise varietal) e a geocronologia U-Pb (LAM-ICPMS-MC) em zircão, permitiram a identificação das áreas-fonte e o padrão de suprimento sedimentar dos arenitos de água profunda maastrichtianos que constituem os reservatórios do Campo de Jubarte, Bacia de Campos. Os arenitos são pobremente selecionados, com grãos sub-angulares a angulares, denotando rápido transporte. Apresentam composição original rica em feldspatos (arcósios sensu Folk, 1968) e pobre em fragmentos líticos de textura fina, proveniente de terrenos soerguidos de embasamento (sensu Dickinson, 1985). As assembléias de minerais pesados indicam proveniência a partir de rochas metamórficas de alto e médio grau, derivadas de metapelitos aluminosos metamorfisados em altas temperaturas e pressões baixas a médias, de granitos e subordinadamente de rochas máficas (metabasitos), pertencentes ao Domínio Tectônico Cabo Frio e ao terreno Oriental (domínio Costeiro) do orógeno Ribeira.A direção principal de suprimento sedimentar foi de sudoeste para nordeste, interpretada com base na identificação dos terrenos-fonte com abundante cianita no Domínio Tectônico Cabo Frio. Foi descartado o suprimento de sedimentos provenientes de noroeste, coincidente com a direção estrutural da faixa cataclasada de Colatina. As seqüências de quarta e quinta ordem analisadas não mostram variação na composição essencial, embora apresentem uma variação discreta na razão apatita:turmalina, que por isto apresenta potencial para ser utilizada como correlação entre os corpos de arenito dentro do campo. O índice ZTR baixo, combinado com a ausência de fragmentos metassedimentares e minerais pesados de baixo grau sugerem que ao final do Cretáceo os processos erosivos já haviam removido completamente as rochas supracrustais de baixo grau, expondo os terrenos plutônicos infracrustais. A composição quartzo-feldspática resultante favoreceu a qualidade dos reservatórios. A análise integrada dos dados sugere uma área-fonte tectonicamente ativa, relativamente próxima da bacia, submetida a um soerguimento rápido que permitiu a erosão de grandes volumes de sedimentos sob um regime de intemperismolimitado. Assim que erodidos das rochas-fonte os sedimentos foram transportados desde curtos rios de montanha e/ou leques aluviais rapidamente para águas profundas. A variação de alta freqüência da razão apatita:turmalina indica derivação direta dos arenitos do Campo de Jubarte a partir de um sistema aluvial relativamente próximo.
The application of integrated techniques of provenance analysis, including quantitative petrography using the Gazzi-Dickinson point-counting method, conventional heavy mineral analysis, garnet mineral chemistry and U-Pb zircon geochronology, allowed the identification of source-rocks and the sedimentary supply pattern for the Maastrichtian deep-water reservoir sandstones of the Jubarte Field, Campos Basin. The sandstones are poorly-sorted with angular to sub-angular grains denoting fast transportation. They present a detrital composition rich in feldspars (arkoses sensu Folk, 1968) and poor in finely-crystalline lithic fragments, with provenance from continental blocks of uplifted basement (sensu Dickinson, 1985). The heavy mineral assemblages indicate provenance from high-grade metamorphic rocks, derived from aluminous metapelites metamorphosed at high temperatures and low to medium pressures, from granites and from subordinate mafic rocks (metabasites), belonging to the Cabo Frio Tectonic Domain and the Oriental (Costeiro) terrain of the Ribeira orogen. The main sedimentary supply route during late Cretaceous was from southwest to northeast, indicated mainly by the presence of kyanite in the Cabo Frio Domain source-rocks. A possible dispersal pattern from northwest to southeast, coinciding with the Colatina shear zone, can be discarded. The fourth and fifth-order depositional sequences analyzed show no variation in major composition through time, although displaying a discrete variation of the apatite:tourmaline ratio, which thus present potential to be used as a parameter for sandstone correlation within the field. A low ZTR index coupled to the absence of low-grade heavy minerals and meta-sedimentary rock fragments suggest that at late Cretaceous the erosive processes had already removed the supracrustal, low-grade meta-sedimentary rocks, exposing the infracrustal plutonic terrains. The resulting quartz-feldspathic composition favored the quality of the reservoirs. The integrated analysis of compositional data suggests a tectonically-active source-area located close to the basin, where rapid tectonic uplift produced a large amount of sediments under a weathering-limited regime of erosion. Soon after being eroded from the bedrocks, these sediments were transported from short mountain rivers and/or by alluvial fans, directly to deep-water. The high-frequency variation inapatite:tourmaline ratio support direct derivation of Jubarte sandstones from a relatively proximal alluvial system.

Les teneurs en éléments majeurs et trace, les isotopes Sr-Nd-Pb, les teneurs en H2O et l’isotope de l’O des phénocristaux de cpx des basaltes cénozoïques de 11 sites du Sud Est Chinois situés dans des contextes géodynamiques variables ont été mesurés pour identifier les différents composants faisant partie de leur source. Les basaltes Cénozoïques de Zhejiang se sont mi en place durant deux périodes, 20-27Ma et après 11Ma. Leurs teneurs en H2O varient de 1.3-2.6%. Les basaltes Cénozoïques du Fujian ont fait éruption il y a moins de 10 Ma. Le teneurs en H2O initial des basaltes de Shiheng s’étend de 1.3-2.4%; les diabases de Bailin ont des teneurs s en eau estimés de 1.9-2.1%, et ceux de Mingxi des teneurs es initiaux de 0.3-0.5%. Les teneurs en H2O des basaltes de sont de 1.3-2.6%. Les basaltes de Xilong (Zhejiang), Mingxi (Fujian) et Leihuling (Hainan) ont des sources mantelliques contaminées par de la croûte océanique recyclée, ceux de Gaoping et Shuangcai (Zhejiang), Shiheng, Bailin et Niutuoshan (Fujian) et Maanling, Dayang et Fujitian (Hainan) voient leurs sources mantelliques contaminées par à la fois des sédiments et la croûte océanique recyclés. Les matériaux recyclés diffèrent suivant l’âge et la localisation. En résumé, les basaltes cénozoïques SE chinois ont des signatures élémentaires et isotopiques marquées par la présence de matériaux océaniques recyclés dans leurs sources mantelliques. Les matériaux recyclés varient entre les différentes localités, tant dans leurs proportions que leur degré d’évolution. Nos résultats montrent que la plaque subductée Ouest Pacifique affecte probablement la composition du manteau sous continentale du Sud Est Chinois
The major and trace element contents, Sr-Nd-Pb isotope, H2O contents and the cpx phenocryst O isotope of Cenozoic basalts from 11 places with distinct geological backgrounds in SE China have been measured to decipher the relationship between the possible recycled components and mantle geochemical heterogeneities. Zhejiang basalts erupted in two stages, 20-27Ma and after 11Ma. Their H2O contents range from 1.3-2.6%. The estimated H2O contents of initial basaltic melts for the Shiheng basalts range from 1.3-2.4%; the Bailin diabases have “fake” basaltic melt water contents from 1.9-2.1%; and the Mingxi basalts have initial H2O contents of 0.3-0.5%, in Fujian. H2O content the basalts from Leihuling (LH), Dayang (DY) and Fujitian (FJT) areas in Hainan are 2.7 wt. %, 1.3 wt. %, and 2.6 wt. %. The Xilong basalts from Zhejiang, Mingxi basalts from Fujian and Leihuling basalts from Hainan involved recycled oceanic crust components in the mantle source, while the Gaoping and Shuangcai basalts from Zhejiang, Shiheng, Bailin, and Niutoushan basalts from Fujian as well as the Maanling, Dayang and Fujitian basalts from Hainan involved recycled oceanic sediments and crust components in their mantle source. Overall, the SE China Cenozoic basalts have involved the recycled oceanic materials in their mantle source. The recycled oceanic materials have different existential state and locations, when the geological history of SE China are considered. The subducted Pacific slab most likely effect the composition of mantle in SE China

O perifíton é formado por uma complexa comunidade de organismos aderidos a um substrato orgânico ou inorgânico, dos quais as diatomáceas (Bacillariophyta) constituem importante parcela. Mais recentemente inventários florísticos que contemplam as diatomáceas bentônicas em sistemas lóticos vêm incrementando o conhecimento da flora na região Neotropical e Neosubtropical, porém grande parte desses sistemas permanece inexplorado, especialmente em águas oligotróficas, de altitude e de baixo pH. Tais ecossistemas em geral possuem uma flora bastante peculiar, e são importantes referências em termos qualidade de água. Desta forma, o presente estudo teve por objetivos contribuir para o conhecimento da flora de diatomáceas perifíticas do Parque Estadual do Ibitipoca, localizado na serra da Mantiqueira em Minas Gerais. Como resultado, foram identificados 15 gêneros, 18 espécies e duas variedades taxonômicas. Duas novas espécies do gênero Eunotia são propostas e três espécies do gênero Nupela não puderam ser identificadas de acordo com a literatura, sendo provavelmente novas para a ciência. São feitos 16 registros pioneiros para o estado de Minas Gerais, sendo quatro delas primeiras ocorrências em território brasileiro. A composição taxonômica das diatomáceas perifíticas do Parque Estadual do Ibitipoca apresenta semelhanças com a flora de outros ambientes oligo-distróficos já inventariados nos Neotrópicos. Palavras-chave: ambientes continentais, águas oligotróficas, Eunotia, Nupela, taxonomia de criptógamos.
The periphyton is composed by a complex community of organisms adhered to an organic or inorganic substrate, and diatoms (Bacillariophyta) constitute an important part of it. More recent floristic inventories in lotic systems that include benthic diatoms increased the knowledge of the Neosubtropical Neotropical flora for the region, but most environments remains unexplored, especially those with oligotrophic and low pH waters in altitude sites. Such ecosystems in general have a very peculiar flora and are important indicators of water quality. Thus, the present study aimed to contribute to the knowledge of periphytic diatom flora of Ibitipoca State Park, located in the Mantiqueira ridge, in Minas Gerais. As a result, we identified 15 genera, 18 species and two taxonomic varieties. Two new species of Eunotia are proposed and three species of the genus Nupela could not be identified according to the literature, and are probably new to science. Sixteen new records were made for the state of Minas Gerais, including four first occurrences for Brazil. The taxonomic composition of the periphytic diatoms of Ibitipoca State Park share similarities with other oligo-dystrophic environments already surveyed in the Neotropics.

On etudie les sediments recents de l'interface dans la baie des anges, la baie de villefranche-sur-mer et dans la reserve sous-marine du larvotto au large de monaco, afin de mettre en evidence les relations existant entre les processus diagenetiques et lithologiques d'une part et les proprietes physico-chimiques des sediments d'autre part. On observe en particulier la qualite de la matiere organique presente dans l'eau et les sediments ainsi que les relations entre m. O. Ou ses produits de desintegration et les metaux-traces. On analyse les variations spatio-temporelles des teneurs en sels nutritifs et en metaux-traces, leur differenciation en fonction des conditions d'oxydo-reduction. On determine les facteurs dominants controlant les processus geochimiques

The intrusion pathways and physical mechanisms associated with intrusions of cold, nutrient-rich South Atlantic Central Water (SACW) onto the continental shelf of the Espírito Santo Basin (ESB), off southeast Brazil (18°S-22°S), are investigated. The approach consists of analyses of a set of simplified, process-oriented, primitive-equation numerical models supported by the analyses of an independent, more realistic numerical model and available observations. The cross-isobath circulation is found to be strongly dominated by wind-driving, consistent with previous findings. In the model experiments, SACW enters the ESB shelf through two preferential pathways along the Tubarão Bight area (TB, 19.5°S-22°S). These pathways are found to be locations where an equatorward along-isobath pressure gradient force (PGFy∗) of ∼2 x 10-6 m s-2 develops in response to steady wind forcing. This equatorward PGFy∗ is essentially in geostrophic balance, and therefore induces onshore flow across the shelf edge and most of the shelf proper. The Brazil Current (BC) imparts an additional equatorward PGFy∗ on the shelf. The momentum budget reveals that the ageostrophic residue of the PGFy∗ is compensated mostly by momentum advection and bottom friction. Buoyancy arrest might be important under more intense SACW intrusion events, as suggested by the maximum observed values of the slope Burger number (0.32-0.92). Among the deep ocean forcing mechanisms considered, the intrinsic pycnocline uplifting effect of the BC seems to be responsible for ∼1.4°C colder upwelled water under steady, upwelling-favorable wind forcing, relative to a flat stratification scenario. The BC also seems to induce local intrusions by inertially overshooting the shelf edge, consistent with Rossby numbers of ∼0.3-0.5, as estimated for the area along the TB shelf edge. Finally, the planetary β-effect is also related to a background equatorward PGFy∗. In addition, the steady response of the continental shelf to a periodic (in the along-shelf direction) pressure forcing at the shelf edge is compared with the BC-forced primitive-equation numerical solutions. A simple Arrested Topographic Wave (ATW) analytical model is found to be successful in representing the general features of the numerical solutions. The cross-shelf e-folding scales of the cross-shelf velocity estimated from the numerical solutions agree in order of magnitude with the cross-shelf penetration scale q-1 = [-2r/(lfs)]½ = 10 km predicted by the ATW, where r is a linear bottom resistance parameter, l is the along-shelf wavenumber of the forcing at the shelf edge, f is the Coriolis parameter and s is the bottom slope. Furthermore, the use of quadratic bottom stress accounts for some of the relative increase in the numerical onshore penetration scales, which are predicted to be qquadratic-1 = [-2CD/(lfs)]½ [Ubot]½, where CD is a quadratic bottom friction parameter and Ubot is the near-bottom velocity magnitude. The kind of steady response to periodic deep ocean forcing examined here may provide insight into other continental shelves under the influence of western boundary currents.
Os caminhos e os mecanismos físicos associados ao fenômeno de intrusão da Água Central do Atlântico Sul (ACAS) na plataforma continental da Bacia do Espírito Santo (BES) ao largo da costa sudeste (18°S-22°S) são investigados nesta dissertação. A abordagem consiste da análise de experimentos numéricos de equações primitivas simplificados, combinados com a análise de um modelo numérico mais completo, e com análise de observações disponíveis. Conclui-se que a circulação na direção perpendicular às isóbatas é fortemente dominada pelo vento, de acordo com resultados pretéritos. Nos experimentos numéricos, a ACAS ingressa na plataforma da BES através de dois caminhos preferenciais de intrusão no Embaiamento de Tubarão (ET, 19,5°S-22°S). Estes caminhos de intrusão coincidem com áreas em que uma Força do Gradiente de Pressão na direção paralela às isóbatas (PGFy∗), com magnitude de ∼2 x 10-6 m s-2, se forma em resposta ao vento. A PGFy∗ se encontra essencialmente em balanço geostrófico, e impulsiona um escoamento na direção da costa. A Corrente do Brasil (CB) induz uma PGFy∗ adicional favorável à intrusão. O balanço de momentum revela que o resíduo ageostrófico da PGFy∗ é balanceado principalmente pela advecção de momentum e pelo atrito de fundo. O mecanismo de desligamento da camada de Ekman de fundo por empuxo (tradução livre de buoyancy arrest) pode ser importante em eventos mais intensos de intrusão de ACAS, em razão das estimativas do número de Burger de inclinação (tradução livre de slope Burger number) observado (0,32-0,92). O efeito de soerguimento da termoclina ligado à CB aparenta diminuir em ∼1,4 °C a temperatura da água que aflora em eventos de ressurgência costeira. A CB também parece produzir intrusões locais na borda da plataforma por efeitos inerciais, de acordo com as estimativas de ∼0,3-0,5 para o número de Rossby ao longo da borda da plataforma. Por fim, o efeito β planetário também é associado a uma PGFy∗ básica na direção do equador. Adicionalmente, a resposta estacionária da plataforma continental a um campo de pressão periódico ao longo da borda da plataforma é comparada com as soluções numéricas. Um simples modelo analítico do tipo Onda Topográfica Aprisionada (OTA, tradução livre de Arrested Topographic Wave) representa as características gerais das soluções numéricas. As escalas de decaimento Neperiano (e) na direção perpendicular à plataforma estimadas a partir das soluções numéricas são comparáveis à escala de penetração q-1 = [-2r/(lfs)]½ = 10 km prevista pela OTA, onde r é um coeficiente linear de atrito de fundo, l é o número de onda da forçante, f é o parâmetro de Coriolis e s é a inclinação do fundo. O uso de uma parametrização quadrática para o atrito de fundo prevê parte da diminuição da e. A escala de penetração quadrática é qquadratic-1 = [-2CD/(lfs)]½[Ubot]½, onde CD é um coeficiente quadrático de atrito de fundo e Ubot é a magnitude da velocidade próxima ao fundo. Este tipo de resposta estacionária da plataforma a uma forçante periódica ligada ao oceano profundo pode ajudar a elucidar processos físicos em outras plataformas continentais que se encontram sob a influência de correntes de limite oeste.

Fundação Carlos Chagas Filho de Amparo a Pesquisa do Estado do Rio de Janeiro
A pesquisa aqui apresentada amostrou a plataforma continental e talude superior entre Ubatuba (SP) e o cabo Búzios (RJ), em dois projetos de escala local e de meso-escala. A campanha entre Ubatuba e o cabo Frio foi realizada no âmbito do projeto Oceano-Rio: levantamentos oceanográficos integrados ao largo do Estado do Rio de Janeiro, realizado em colaboração com o Ministério de Ciência e Tecnologia (MCT) e com a cooperação da Marinha do Brasil (MB), a bordo do Navio Hidro-oceanográfico Cruzeiro do Sul. Dos dados coletados nesta campanha oceanográfica, foram analisados os dados de CTD, concentração de oxigênio dissolvido, fluorescência, transmissividade, atenuação, retro-espalhamento além de amostras de água para a determinação direta da concentração de material particulado em suspensão (MPS). No experimento de menor escala, entre o cabo Frio e o cabo Búzios, além destes dados, foi realizado um fundeio entre 02 e 30 de julho de 2011, que amostrou a intensidade do eco, as correntes e as ondas. As análises realizadas permitiram observar uma grande abrangência da massa dágua característica da Ressurgência sobre a plataforma continental entre Ubatuba (SP) e cabo Búzios (RJ), inclusive em regiões muito rasas. A ressurgência nem sempre ocorreu associada aos ventos NE, sugerindo que a ocorrência de vórtices tem grande influência sobre o Sistema de Ressurgência de Cabo Frio. O padrão de distribuição de MPS na região é muito influenciado pela ressuspensão dos sedimentos de fundo (aumentada durante as tempestades, quando a coluna dágua passa a apresentar maiores concentrações de MPS), produção fitoplanctônica e aporte das baías costeiras. Outros processos que parecem influenciar este padrão são os vórtices e as ondas internas no talude. A complexidade da interação destas diferentes fontes de MPS e processos associados à sua distribuição ficou evidenciada no processo de conversão dos sinais óticos do transmissômetro e nefelômetro em concentração de MPS. Apesar desta dificuldade associada à grande variabilidade das características do MPS, as análises dos testes de conversão do sinal ótico em concentração de MPS permitem concluir que as melhores conversões podem ser obtidas após a inspeção visual das concentrações de MPS medidos (filtração) e remoção das amostras que não seguem a tendência geral esperada de dispersão sinal ótico versus concentração de MPS.
The research presented here sampled the continental shelf and upper slope from Ubatuba (SP) to Búzios cape (RJ) on two projects at local and meso-scale. The cruise between Cape Frio and Ubatuba was performed under the project Oceano-Rio: levantamentos oceanográficos integrados ao largo do Estado do Rio de Janeiro, conducted in collaboration with the Ministry of Science and Technology (MCT) and the Brazilian Navy aboard the Cruzeiro do Sul Hydro-Oceanographic vessel. Of oceanographic data collected in this campaign, we analyzed data from CTD, dissolved oxygen, fluorescence, transmissivity, attenuation, back-scattering as well as water samples for the direct determination of the concentration of suspended particulate matter (SPM). In the experiment between Cabo Frio and Búzios capes, in addition to these data, an Acoustic Doppler Current Profiler (ADCP) was positioned near the bottom and collected data from the echo intensity, currents and waves, between 02 and 30 July 2011. The analysis allowed to observe a wide range of water mass characteristic of upwelling on the continental shelf from Ubatuba (SP) to Búzios cape (RJ), even in very shallow regions. The resurgence was not always associated with the NE winds, suggesting that the occurrence of vortices has a great influence on the Upwelling System of Cabo Frio. The distribution pattern of SPM in the region is strongly influenced by resuspension of bottom sediments (enhanced during storms, when the water column begins to show higher concentrations of SPM), phytoplankton production and supply of coastal bays. Other processes that seem to influence this pattern are the vortices and internal waves on the slope. The complexity of the interaction of these different sources of MPS and processes associated with its distribution was evident in the process of converting the optical signals (transmissivity, attenuation and back-scattering) at a concentration of SPM. Despite this difficulty associated with the high variability of the characteristics of the SPM, the analysis of several tests that were carried out to convert optical signals into concentrations of SPM revealed that significantly improved results may be achieved after visual inspection of the directly determined values (through filtration of water samples) and removal of samples that do not follow the expected trend in regressions of the optical signals against concentrations.

Na presente dissertação eu estudei a distribuição potencial dos corais de águas profundas ao longo da margem continental brasileira e o efeito da resolução das variáveis ambientais em modelos de adequabilidade de habitat (MAH). Primeiramente foi determinada a distribuição potencial de corais de águas profundas a partir de modelos de adequabilidade de habitat de máxima entropia (MaxEnt). Os modelos foram alimentados com diversas camadas de dados SIG de variáveis ambientais e dados de ocorrência de espécies extraídos de bancos de dados e de novos registros. Foram estudados os grupos Scleractinia e Octocorallia, assim como quatro espécies de corais formadores de recifes (Solenosmilia variabilis, Lophelia pertusa, Madrepora oculata e Enallopsammia rostrata) e duas espécies de escleractínios não formadores de recifes (Cladocora debilis e Deltocyathus spp.). O nicho ambiental ocupado pelos táxons foi representado a partir de uma análise multivariada, sendo determinada a sobreposição entre os nichos. A partir disso foi avaliada a similaridade e equivalência de nicho ambiental entre as espécies. Os modelos resultantes indicaram que Scleractinia apresenta distribuição potencial na margem continental leste e sudeste do Brasil (porção Central e Sul), enquanto que Octocorallia apresenta uma distribuição potencial mais ampla abarcando toda a margem continental brasileira, com maior adequabilidade nas margens norte e nordeste. Assim, as áreas de distribuição potencial compartilhada entre octocorais e escleractínios foram aquelas ao largo da porção leste e sudeste do Brasil, sendo estas prioritárias para futuras pesquisas. Os nichos ambientais específicos indicaram menos tolerância de Scleractinia a altas temperaturas em comparação com Octocorallia. Os octocorais ocuparam uma maior amplitude do gradiente ambiental, principalmente relacionado às condições de carbono orgânico particulado, oxigênio dissolvido e temperatura. Isto possivelmente permite aos octocorais habitar a porção norte da margem continental brasileira, onde os modelos de escleractínios indicaram baixa adequabilidade de habitat. A margem continental sudeste do Brasil teve a maior adequabilidade para as espécies de escleractínios formadores de recifes profundos. Isto é de grande valor para planos de conservação nesta área que atualmente apresenta atividades de extração de óleo e gás e que, futuramente, pode ser explotada para a extração de minério. Além disso, as espécies formadoras de recifes ocuparam nichos ambientais similares e, portanto, mudanças nas condições ambientais, como por exemplo as associadas às mudanças climáticas, podem afetar todas elas. Contudo, seus nichos não são equivalentes e, portanto, cada uma delas faz um uso diferente do espaço ambiental da margem continental brasileira. Por último, foram desenvolvidos modelos MaxEnt para Solenosmilia variabilis, Lophelia pertusa, Madrepora oculata e Enallopsammia rostrata em duas resoluções de análise, uma de baixa (i.e., com um tamanho de pixel de aproximadamente 1000 m2) e uma de alta resolução (i.e., pixel de aproximadamente 100 m2) para determinar o efeito da resolução das variáveis ambientais utilizadas na performance e na extensão de área predita de modelos de adequabilidade de habitat. A diferença na extensão da área adequada predita por ambas resoluções foi medida de acordo a três limiares de corte diferentes. Os resultados indicaram diferenças na performance dependendo da resolução, com maior performance nos modelos de alta resolução. Além disso, a extensão de área adequada predita foi geralmente maior nos modelos de baixa resolução, com algumas exceções dependendo da espécie e do limiar de corte. Estes resultados ressaltam a importância da resolução das variáveis ambientais e suas implicações no uso de MAH no planejamento e manejo de Áreas Marinhas Protegidas (MPAs).
In this thesis I studied the deep-sea coral distribution along the Southwestern Atlantic Ocean and the effect of the environmental variables resolution on habitat suitability models (HSM). In the second chapter, I developed HSM based on the Maximum Entropy (MaxEnt) algorithm to identify the potential distribution of deep-water corals. To perform the models, I have used species presence data from existing datasets together with new species records and global environmental variables. I used the main environmental variables to identify suitable areas by modeling niches of different coral taxa. The studied taxa were Scleractinia and Octocorallia, as well as four reef-forming scleractinian species (Solenosmilia variabilis, Lophelia pertusa, Madrepora oculata and Enallopsammia rostrata), and two non-reef-building scleractinians (Cladocora debilis and Deltocyathus spp.). Furthermore, I used multivariate approach to compare their environmental occupied niche in order to assess the spatial niche overlap and test niche similarity and equivalence. The resulting cold-water coral models showed that the most suitable areas occur along the west and southwestern continental margin of Brazil, which permitted to determine areas of priority for future exploration/research to determine conservation areas. Specific environmental niches suggested lower tolerance to high temperatures for Scleractinia than for Octocorallia. Besides, octocorals occupied a wider range of the environmental gradient, which was mainly related to particulate organic carbon, oxygen and temperature. This probably enables them to inhabit the northern part of Brazil where scleratinian models classified as poor habitats for this group. In addition, the Southwestern Brazilian continental margin encloses the most suitable habitats for deep reef-building species. This has important implications for conservation plans in that area already facing gas and oil exploitation and probably future mineral extraction. On the other hand, results suggest that different scleractinian cold-water coral species occupy similar environmental niches and, for this reason, I concluded that changes in environmental conditions, such as those associated to climate change, may affect them all. However, their niches are not equivalent and this suggests that each environmental factor could affect each species in different ways. In the third chapter, I performed HSM based on Maximum Entropy for Solenosmilia variabilis, Lophelia pertusa, Madrepora oculata and Enallopsammia rostrata with two different environmental variables resolution, a low (i.e., a coarse resolution data with pixel size of ca. 1000 m2) and a high resolution (pixel of ca. 100 m2) to determine the effect of the environmental variables resolution on habitat suitability model performances and spatial extent of predicted suitable areas. From the final suitability maps, the changes in area extent depending of both resolution models were measured based in different thresholds. The results showed different performances of the models depending on data resolution, with higher performance at higher resolution. Furthermore, the predicted area varied between resolutions and threshold chosen. These results highlight the importance of environmental variables resolution and their implications for the use of HSM in planning and managing Marine Protected Areas (MPAs).

Dans ce travail de thèse, certaines étendues d’eaux continentales regroupant plusieurs types de système de dépôt comme les lacs, mers intérieures et lagunes ont été regroupées au sein d'un nouveau groupe de système sédimentaire mentionnés sous l'appellation de Wind-driven Water Body (WWB).Afin de caractériser l'évolution et l'enregistrement sédimentaire d'un exemple de WWB, une étude sédimentologique intégrée du bassin quaternaire du Lac Saint-Jean (Québec, Canada) a été menée à partir d'une approche intégrant géologie de terrain et imagerie géophysique très haute résolution (CHIRP 2D). A l'échelle du cortège sédimentaire, le régime glaciaire à paraglaciaire de la sédimentation et le rebond glacio-isostatique ont contrôlé au premier ordre, à la fois la succession lithologique et les architectures grandes échelles du bassin pour générer un Cortège de Régression Forcée (CRF) atypique. Au sein de ce cortège de régression forcée fini-glaciaire, une dynamique de système WWB s'est progressivement affirmée à partir de 8,5 cal. ka BP. Elle s'est exprimée par la mise en place d'une dynamique littorale importante occasionnellement associée à une circulation interne générant des courants de fonds lors d'épisodes de vents forts.Finalement, l'analyse sédimentologique du bassin du Lac Saint-Jean a permis de dégager plusieurs interprétations ayant attrait (1) à l'évolution des systèmes WWB et (2) aux séquences de déglaciation en domaine précédemment englacé. De plus, ce travail représente une contribution à l'échelle régionale pour les modalités de la dernière déglaciation du Sud-Est du Québec
In this study, a certain number of continental enclosed basins including several depositional systems such as lakes, inland seas or lagoons have been grouped in a new sort of sedimentary system referred to as Wind driven Water Body. To characterize the sedimentary evolution and record of a WWB basin, an integrated sedimentological study has been carried out on the quaternary Saint-Jean basin (Québec, Canada) based on field onshore geology and offshore geophysics (CHIRP 2D).At the system-tract scale, the glacial to paraglacial sedimentation and the glacio-isostatic rebound controlled at first-order the lithofacies succession and large-scale architectures to generate an original Falling Stage System Tract (FSST). Within this FSST, since 8.5 cal. ka BP a WWB related sedimentary evolution overprinted the glacial to paraglacial evolution. This expressed in the form of the emplacement of an important coastal dynamics, occasionally accompanied by a lake-scale hydrodynamics at the origins of bottom currents during strong wind to storm events.Finally, the sedimentological analysis of the Saint-Jean basin brought numerous interpretations related to (1) the sedimentary evolution of WWB systems and (2) deglaciation sequences in previously glaciated domains. In addition, this work supplements the regional quaternary framework concerning the latest deglaciation evolution in southeast Quebec

Dans le jargon de l’océanographie physique, un «overflow » est une masse d’eau dense, formée sur un plateau continental ou dans une mer marginale, qui rejoint l’océan ouvert en s’écoulant par-delà de fortes contraintes topographiques telles que d’étroits détroits, des seuils ou des talus continentaux particulièrement pentus. Ces processus d'overflow jouent un rôle important en distribuant les flux de chaleur et de sel dans l'océan, car ils alimentent les courants profonds et la plus grande partie des eaux profondes de l'océan global. Une représentation irréaliste de ces processus dans les modèles peut avoir un impact sur leur aptitude à simuler d'autres aspects majeurs de la circulation océanique globale.Représenter de manière réaliste les overflows est encore un défi en modélisation numérique de l’océan. Cette thèse étudie ce problème en utilisant le modèle de la circulation générale océanique NEMO avec une configuration régionale de l’overflow du détroit du Danemark (Denmark Strait Overflow, DSO) avec des résolutions dites eddy-permitting/resolving (permettant la génération de turbulence de mésoéchelle). Dans ce travail je propose d’abord une définition du DSO pour pouvoir caractériser les masses d'eaux qui lui sont associées et pour mettre en évidence et quantifier les principaux défauts de représentation du DSO rencontrés dans une simulation de référence réalisée avec les paramètres standards couramment utilisés dans les configurations globales de NEMO (configurations Drakkar).Grâce à cette définition, j’ai pu quantifier l'impact d'un grand nombre de paramètres du modèle sur la représentation du DSO avec des résolutions allant de l'eddy-permitting (1/12°) à l'eddy-resolving (1/60°). Cette étude, qui a nécessité un grand nombre de simulations de sensibilité, a été faite avec le système de coordonnée verticale classique utilisé dans NEMO, qui est la coordonnée géopotentielle z.Les améliorations les plus importants ont été trouvées en augmentant la résolution verticale et horizontale de façon cohérente. Mes résultats ont cependant montrés que la plupart des paramètres du modèle ont un impact très faible sur la représentation finale du DSO. En particulier, nous avons trouvé qu'augmenter la résolution verticale sans utiliser une résolution horizontale cohérente détériore la solution. La principale raison est que la paramétrisation EVD, représentant la convection libre forcée par une instabilité statique de la colonne d’eau, propage la veine de fluide en direction de la pente de la grille, et non de la pente de la topographie, ce qui induit une trop forte dilution des propriétés de l’overflow. Une très haute résolution horizontale et verticale (1/60° et 300 niveaux) permet de résoudre la couche d'Ekman de fond et de maintenir l'EVD localisé au fond, limitant ainsi la dilution de la veine d’eau dense.J’ai ensuite étudié la représentation du DSO dans un système de coordonnée hybride combinant une coordonnée suivant-le-terrain (s) avec la coordonnée géopotentielle (z). Les améliorations obtenues dans la représentation du DSO sont remarquables et pour une faible augmentation du coût de calcul. Finalement, nous proposons un système de coordonnée verticale mixte s-z qui consiste en une implémentation locale de la coordonnée s à l’intérieur de la grille du modèle en coordonnée z, limité à la région où le DSO se produit. Cette implémentation locale minimise les effets des erreurs du gradient de pression liés à ce type de coordonnée, fait une connexion lisse avec la coordonnée z, et n'introduit pas de coûts de calcul démesurés. L'amélioration de la représentation du DSO est encore très importante.Ce travail souligne l'importance d’adapter le système de coordonnée verticale aux processus physiques les plus pertinents. Un défi de la modélisation serait d'avoir un système de coordonnée verticale qui est localement adapté aux processus océaniques dominants
Overflows play an important role distributing the heat and salt fluxes in the ocean, feeding deep boundary currents and most of the world ocean deep waters. Therefore, an unrealistic representation of overflows in global models may have impacts over many aspects of the simulated state of the ocean.To achieve a realistic representation of overflows is still a challenge for ocean modelling. This work addresses this problem using the community ocean general circulation model NEMO with a regional configuration of the Denmark Strait Overflow (DSO) at eddying resolutions. This work first proposes a definition of the DSO in order to characterize its associated water masses and to find the main caveats in a control simulation that uses the most standard parameters of the commonly used global configurations of NEMO (e.g. Drakkar configurations).Thanks to this definition we then study the impacts on the DSO of a large number of model parameters through a range of eddy-permitting to eddy-resolving resolutions (e.g. 1/12° and 1/60°) in the classic z-coordinate system used in NEMO. Main findings were found increasing the horizontal and vertical resolution, but most model parameters have no significant impacts. In particular it was found that increasing vertical resolution without using a coherent horizontal resolution degrades the solution. The main reason is the EVD parameterisation that propagates the dense vein of fluid along a grid-slope, instead the topographic slope. Coherent and very high resolution both in the horizontal and in the vertical is needed in order to resolve Ekman bottom boundary layer dynamics and keep the EVD localized to the very bottom.We also study the representation of the DSO with a hybrid terrain-following (s) and geopotential (z) coordinate system and obtained considerable improvements for a relatively small increase in computational cost. Finally, we propose a mixed s-z vertical coordinate that relies on a local implementation of s-coordinates within the z-coordinate model, limited to the area where DSO waters are produced. This local implementation is such that it minimizes the effects of pressure gradient errors linked to this type of coordinate, smoothly connects to the global z-coordinate, and does not add any significant computational cost. The improvement of the DSO is found to be drastic.This work emphasizes the utility of adapting the vertical coordinate system to the main physical problem. A modeling challenge would be to have a vertical coordinate system that is locally adapted to the most critical ocean process

Des xénolites de péridotite provenant de deux localités du sud du Massif Central Français (Allègre et Mont Coupet), émis avec des modes éruptifs différents, ont été étudiés pour définir l’évolution du manteau sous continental et pour étudier le comportement de Li et H lors des réactions fluides roches lors de leur remonté vers la surface. Un ensemble de 6 xénolites représentatifs a été sélectionné pour chaque localité. La description pétrologique et minéralogique de chaque échantillon a été associée à la mesure des compositions chimiques en éléments majeur (par microsonde électronique) et trace (par LA-ICP-MS) des principales phases minéralogiques (Olivine, Pyroxène, Amphibole). La teneur et la composition isotopique du Li ont été mesurées par microsonde ionique (SIMS), et les teneurs en eau par spectroscopie infrarouge à transformée de Fourrier (FTIR) et SIMS dans les pyroxènes et les olivines. Pour les xénolites d’Allègre, les anomalies négatives en HFSE et les rapports LREE/HREE élevés reflètent un métasomatisme lié à des liquides carbonatitiques, succédant à un processus de fusion partielle du manteau lithosphérique. Pour les échantillons du Mont Coupet, Les anomalies négatives en Ti et Nb des Cpx de tous les échantillons et les anomalies négatives de Zr et Hf pour deux échantillons plus fortement métasomatisés (MC38 et MC34) soulignent également un métasomatisme carbonatitique. Les amphiboles des échantillons MC36 et MC53, dont l'origine doit être associée à des fluides de subduction, sont à l’équilibre avec les Cpx coexistant, ce qui indique que le fluide qui a permis leur formation n’a pas enrichi les Cpx en LREE ou LILE. La composition isotopique de des xénolites d’Allègre montre qu’ils ont été affectés par un métasomatisme en au moins deux étapes par des fluides différents. Les teneurs très élevées en Li des Cpx (jusqu'à 50 ppm) et l’enrichissement même modéré des bordures des olivines sont attribués à un apport de Li par diffusion depuis le magma hôte. Par contre, les compositions isotopiques pauvres en 7Li préservées au coeur des Ol (δ7Li jusqu’à -25‰) suggèrent l’existence d’un autre évènement métasomatique ayant affecté les péridotites avant leur remonté vers la surface. En revanche, les minéraux des xénolites de Mont Coupet ont des concentrations en Li similaires à celles du manteau, avec une répartition à l’équilibre entre les minéraux. Cependant les valeurs de δ7Li négatives observées pour les Cpx et Opx de certains échantillons suggèrent une interaction avec un fluide en quantité limitée et une composition isotopique négative. La préservation du fractionnement isotopique du Li entre les pyroxènes et olivines indique que cette interaction a du avoir lieu peu de temps avant l'entrainement des xénolites vers la surface. Les fluides métasomatiques à l’origine des valeurs de δ7Li négatives observées à Allègre et à Mont Coupet sont liés à un environnement de subduction, probablement lié à l'orogenèse varisque dans le cadre régional du FMC. Les teneurs en eau mesurées dans les xénolites d’Allègre vont de 10,6 à 12,4 ppm, des valeurs beaucoup plus faible que celle du manteau source des MORB. Ceci s’explique par une perte d’eau associée au dégazage du magma lors du refroidissement du lac de lave. L’absence de variation cœur-bord montre une distribution de l’eau à l’équilibre entre les xénolites et la lave hôte. A l’inverse, les xénolites du Mont Coupet ont pu conservé leur teneur en eau acquise en profondeur, contrôlée par les processus de fusion partielle qui ont affecté les péridotites. Cependant, l'échantillon MC34, affecté par le métasomatisme carbonatitique, a la plus haute teneur en eau parmi ces xénolites. Inversement, les échantillons MC36 et MC53 qui contiennent des amphiboles, n’ont pas des teneurs en eau élevées, suggérant que l'agent métasomatique responsable de la formation des amphiboles n'a pas enrichi en eau les autres phases de la péridotite
Peridotite xenoliths sampled from two volcanoes erupting in different modes in two localities, Allègre and Mont Coupet, in the southern domain of the French Massif Central (FMC), have been investigated to constrain the evolution of the sub-continental lithospheric mantle beneath the FMC and the behaviors of Li and H during melt-rock reactions. To answer these questions, a set of 6 representative xenoliths was selected for each locality, and described for their mineralogy and petrography. In-situ measurements were then performed for major and trace elements in Ol, Cpx and Amp when existing, via EPMA and LA-ICP-MS respectively, for Li concentrations and isotopic compositions in pyroxenes and Ol (via SIMS), and water concentrations in minerals (via FTIR and SIMS). Negative HFSE anomalies and markedly high LREE/HREE ratios reflect a carbonatite-related metasomatism following an earlier partial melting process in the lithospheric mantle under Allègre. The Ti and Nb negative anomalies in Cpx from all the Mont Coupet samples and Zr-Hf negative anomalies in Cpx from two most strongly metasomatized samples MC38 and MC34 also point to a carbonatite-related mantle metasomatism. Amp in samples MC36 and MC53, whose origin should be associated with fluids from the subducting slab, have equilibrated most of the trace element composition with coexisting Cpx and the modal metasomatism responsible for the Amp genesis haven’t refertilized Cpx in LREE and LILE. Lithium isotope systematics indicates that Allègre xenoliths were overprinted by (at least) a two-stage metasomatism by melts of different origins. Exceptionally high Li concentrations in Cpx (up to 50 ppm by weight) and slightly increased Li contents at Ol rims are ascribed to a diffusive Li uptake from infiltrating melts derived from the host magma. On the other hand, extremely light Li isotopic compositions preserved in Ol cores (with δ7Li as low as -25‰) suggest another metasomatic event prior to xenolith entrainment by the host magma. In contrast, xenoliths from Mont Coupet have Li concentrations in constituent minerals similar to the normal mantle, and display nearly equilibrated inter-mineral Li partitioning and homogeneous intragranular Li distribution in every phase. The negative δ7Li values of Cpx and Opx in some samples were brought by the exchange with a small-volume melt with Li concentration similar to the normal mantle and light Li isotopic compositions. The preservation of inter-mineral large Li isotopic fractionation currently observed in these samples indicates that the percolation of the melt should occur shortly prior to the entrainment of Mont Coupet peridotite xenoliths by the host magmas. The metasomatic agents, accounting for negative δ7Li values in Ol cores in Allègre xenoliths and in Cpx and Opx in some Mont Coupet xenoliths, are related to a subduction environment. In the regional framework of the FMC, the subduction event most likely occurred during the Variscan orogeny. Water content in Allègre xenoliths ranges from 10.6 to 12.4 ppm in weight, much lower than the water content in the MORB source mantle. It implies that water were lost during the degassing of the host magma during slow cooling of the lava lake. No core-rim variations from profile analysis suggest that xenoliths have achieved water diffusive equilibrium with the host magmas. Peridotite xenoliths from Mont Coupet have retained their original water content from the mantle depths. Partial melting has controlled the water content in most samples from Mont Coupet. However, the subsequent carbonatite-related metasomatism has affected the sample MC34, which had the highest water content among the Mont Coupet xenoliths. And the aqueous agent responsible for presence of Amp in samples MC36 and MC53 has not lead to the considerable increase of water content

O presente trabalho tem como objetivo geral o estudo da composição e estrutura da macrofauna bêntica em escala espacial e sazonal, da região de Cabo Frio (RJ). O aspecto temporal nessa área é especialmente importante devido a ocorrência do fenômeno sazonal da ressurgência costeira. Esse ocorre devido alguns fatores físicos característicos da área, tais como mudanças na topografia e na direção da costa, e principalmente, em decorrência das condições meteorológicas atuantes no local. A interação desses fatores favorece, principalmente no verão, o ressurgimento próximo à costa da Água Central do Atlântico Sul (ACAS), uma massa de água fria e rica em nutrientes. Essa massa de água disponibiliza grande quantidade de nutrientes para o fitoplâncton das camadas superficiais, ocasionando uma elevada produção primária nova. Parte dessa produção é exportada para o fundo incrementando a biomassa bêntica. Assim, a comunidade bêntica assume um papel vital no ecossistema, sendo tanto receptora como fornecedora de energia. Os descritores de comunidade (densidade, biomassa, riqueza, diversidade e equitatividade) e a identificação dos grupos tróficos de Polychaeta foram analisados entre 40 e 1000m de profundidade e em três épocas do ano, inverno de 2001 e verão e primavera de 2002. A integração dos dados biológicos com os ambientais mostrou que as variações espaciais na estrutura e composição dos organismos foi relacionada à profundidade e ao tipo de sedimento verificado nas estações. A estrutura da comunidade também apresentou variações temporais, especialmente nas estações situadas na plataforma continental, respondendo à entrada de matéria orgânica decorrente do evento de ressurgência.
The main objective of the present study was to evaluate the composition and spatial and seasonal structure of the macrobenthic fauna off Cabo Frio (RJ). The temporal scale was investigated in the light of the seasonal coastal upwelling. This phenomenon occurs due to changes in bottom topography and in the coastline direction, and specially, because of the prevailing seasonal NE winds in the area. The interaction of these factors enables the South Atlantic Central Water (SACW) to rise up and reaches the surface, intensively during the summer months. Large amounts of nutrients are then brought to the euphotic zone, enhancing primary productivity. This high productivity increases food supply for benthic communities by sinking of particulate organic carbon. In this way, the benthic communities are an important link in the ecosystem. The density of organisms, biomass, species richness and evenness and also the trophic group of Polychaeta were analyzed in a depth gradient from 40 to 1000m during the 2001 winter and 2002 summer and spring. Faunal distributional patterns and species composition correlated with environmental variables, especially depth and sediment types. The faunal structure also showed temporal changes along the sample period, especially in the stations located in the continental shelf due to the input of organic matter to the sea floor.

A presente pesquisa está centrada na interpretação das análises de palinofácies e de geoquímica orgânica realizadas em três perfis sedimentares (T1, T2 e T3) de zonas úmidas continentais influenciadas por diferentes regimes hidrológicos na faixa climática subtropical durante o Quaternário no sul do Brasil (Estado do Rio Grande do Sul) com o principal objetivo de demonstrar a utilidade dessas análises para a obtenção de dados paleoclimáticos e paleoambientais. A análise de palinofácies realizada nos testemunhos T1-Mina do Museu (7.963 anos antes do presente - AP) e T2-Mina Modelo (9.542 anos AP), provenientes de Ametista do Sul, e no testemunho T3-Iraí (10.586 anos BP), proveniente de Iraí, revelou um amplo domínio do Grupo Fitoclasto. Os Palinomorfos são o segundo grupo dominante e o Grupo Produto Amorfo é o menos abundante. Esse tipo de análise foi particularmente eficaz para as interpretações dos eventos de precipitação e de sucessão vegetacional em Ametista do Sul, porque o isolamento hidrológico desses alagados efêmeros de altitude torna-os muito sensíveis aos efeitos climáticos. As flutuações na profundidade da água foram inferidas a partir das concentrações dos elementos autóctones (especialmente Botryoccocus e outras algas), que predominam nos intervalos basais e tendem a diminuir progressivamente em direção ao topo. Pseudoschizaea, por sua vez, parece atuar como um marcador biológico de intervalos de transição. O aumento da frequência e da variedade dos esporomorfos terrestres nas camadas mais superficiais indica um aumento da diversidade vegetal e está relacionado ao processo de evolução sucessional da área. Para Ametista do Sul, os resultados permitiram determinar que as oscilações nos padrões de umidade resultaram em um padrão intermitente do nível de água dos alagados, o qual pode representar um reflexo de mudanças climáticas regionais ou, talvez, de mudanças em escala global relacionadas com os “eventos Bond”. Em Iraí, a fração orgânica melhor representada é constituída por elementos derivados de plantas terrestres, uma característica típica da matéria orgânica preservada em turfeiras Esse tipo de ambiente úmido nunca chegou a secar completamente, uma vez que os teores de umidade eram subsidiados por diferentes fatores, tais como o nível do lençol freático, as inundações do Rio Uruguai e a água da chuva. A ocorrência muito baixa de algas, contudo, indica que a profundidade da água não era suficientemente espessa para o desenvolvimento da biomassa algálica, embora o ambiente anóxico e redutor também possa ter limitado a expansão deste grupo. Os parâmetros organogeoquímicos foram particularmente úteis para interpretações de eventos de anoxia e de mudanças nos regimes hidrológicos dos sedimentos turfosos. Os teores de carbono orgânico total (COT) e enxofre total (ST) são mais altos na porção basal do perfil, diminuindo em direção ao topo, e podem estar relacionados ao regime hidrológico ou à interferência antrópica na dinâmica da paisagem. O teor anômalo de enxofre observado em uma das amostras de Iraí pode ser devido a uma fonte externa e talvez relacionado com a presença de fontes termais na região. A presente pesquisa tem potencial como uma referência moderna capaz de ser aplicada na reconstrução de paleoambientes continentais análogos associados a regiões alagadas em cinturões subtropicais.
The present research focuses on the interpretation of the palynofacies and organic geochemistry analyses performed on three sedimentary cores (T1, T2 and T3) from continental wetlands influenced by different hydrological regimes in the sub-tropical climatic belt during the Quaternary in southern Brazil (Rio Grande do Sul State), with the main goal of demonstrating the usefulness of these analyses for obtaining paleoclimatic and palaeoenvironmental data. Palynofacies analysis was performed for the cores T1-Mina do Museu (7963 years before present - BP) and T2-Mina Modelo (9542 years BP) from Ametista do Sul, and for the T3-Iraí core (10586 years BP) from Iraí and revealed a high dominance of the Phytoclast Group. The Palynomorph is the second most dominant group and the Amorphous Product is the least abundant group. This kind of analysis was particularly effective in the interpretations of rainfall events and vegetation succession in Ametista do Sul, because the hydrological isolation renders the ephemeral ponds at high altitude highly sensitive to climatic effects. The fluctuations in the water depth are inferred from the concentration of the autochthonous elements (especially Botryoccocus and other algae), which predominate in the basal intervals and tend to decrease progressively towards the top. Pseudoschizaea, in its turn, appears to act as a biological marker for transitional intervals. The increasing frequency and variety of the terrestrial sporomorphs in the topmost interval indicate an increased vegetal diversity and is most likely related to the process of successional evolution of the area. For Ametista do Sul, the results allowed to determine that the oscillations in the moisture pattern resulted in the intermittent feature of pond water level and this may reflect the regional climate changes or perhaps the global scale changes related to the Bond events. In Iraí, the better represented organic fraction consists of elements derived from terrestrial plants, a characteristic typical of organic matter preserved in peat bogs. This kind of wetland never dried completely, since the moisture content was subsidized by different factors, such as the groundwater, the flood events of the Uruguay River and the rainfall water. The very low occurrence of algae, however, indicates that the water was not deep enough for the development of algalic biomass, although the anoxic, reducing environment may also have limited the expansion of this group. The organic geochemistry parameters were particularly useful for interpretation of anoxia events and changes of hydrological regimes in the peaty sediment. The total organic carbon (TOC) and the total sulfur (TS) contents are higher in the basal portion of the profile, decreasing towards the top and could be linked to hydrologic regimes or to anthropogenic interference in the landscape dynamics. The anomalous TS content observed in one of the samples from Iraí might be due to an external source and perhaps related to the presence of thermal springs in the region. The present research has potential as a modern reference that can be applied in the reconstruction of past analogous continental paleoenvironments associated to wetland areas in subtropical belts.

Mestrado em Biologia Aplicada - Biologia Marinha
Floating marine debris are present throughout the oceans and may have negative impacts on marine fauna, such as entanglement, ingestion and transport of exotic species. The present work aims at obtaining estimates of abundance and density of floating marine debris and vessels, as well as their spatial distributions along the entire study area. It also aims at identifying areas of spatial overlap between marine debris, cetaceans and vessels. The sighting surveys were performed during the summer of 2011, aboard the sailing vessel Santa Maria Manuela. This campaign was part of the project LIFE+ MARPRO - Conservation of marine protected species in Mainland Portugal, and the study area ranged between the 50 and the 220 nautical miles west of Portugal mainland, covering an area of about 252833 Km2. The survey was conducted along line transects, following a methodology that allowed to using conventional distance sampling methods to estimate the abundance and density of floating marine debris and vessels. Mean density (objects per km2) of debris in the study area overall was 2.96 objects per km2 and the total abundance was 747720 floating pieces. Floating plastic was the most common type of debris. In respect of vessels, mean density was 0.0013434 vessels per km2 and the estimated total abundance was 340 vessels.
Os detritos flutuantes estão presentes em todos os oceanos do mundo, podendo ter impactos negativos na fauna marinha, tais como o enredamento, ingestão e o transporte de espécies exóticas. O presente trabalho tem como objectivos obter estimativas de abundância e densidade de detritos flutuantes e navios, assim como as suas distribuições espaciais ao longo da área de estudo e tentar identificar áreas de sobreposição espacial entre os detritos, a cetáceos e os navios. A pesquisa foi realizada durante o verão de 2011, a bordo do veleiro Santa Maria Manuela. Esta campanha faz parte do projecto LIFE+ MARPRO – Conservação de espécies marinhas protegidas em Portugal continental, e a região abrangida desde as 50 às 220 milhas náuticas totalizou uma área de 252833 Km2. A pesquisa foi realizada ao longo de transectos lineares, seguindo uma metodologia que permitiu usar métodos convencionais de distance sampling para estimar a abundância e densidade dos detritos flutuantes e navios. A densidade média dos detritos em toda a área de estudo foi 2.96 objectos por km2 e a abundância total foi 747720 objectos flutuantes. O plástico flutuante foi o tipo de detrito mais comum. No que diz respeito aos navios, a densidade média obtida foi 0.0013434 embarcações por km2 e a abundância total foi 340 embarcações.

Doutoramento em Biologia
Diatoms are generally the most frequent and abundant algae in streams and are known by their responsiveness to changes in the environmental conditions of streams. Diatoms are frequently the only biological quality element representative of the aquatic flora in small streams. As a result, diatoms are nowadays a mandatory biological element in the evaluation of the ecological quality of European rivers, according to the Water Framework Directive. Nevertheless, there is still a relative lack of knowledge of key effects of global changes and spatial scale on diatoms. To bridge this gap, this work aims to study the effect of relevant global changes as well as spatial scale on diatom communities of temperate rivers and to deal with its implications in bioassessment. The relevant global changes were assessed in streams from the central Portuguese littoral region which is highly populated and suffers from high anthropogenic impacts. The effect of spatial scale on diatom communities was investigated by a laboratorial experiment (mesocosm experiment) and by using diatom data from temperate regions of the United States of America and Australia. In order to achieve the main aim, three global questions were raised: (1) How to deal with the historical anthropogenic influences in the bioassessment?; (2) Are extreme events due to climatic changes reflected in diatom communities? A comparison with macroinvertebrate communities; (3) How are diatom communities influenced at the spatial scale (small-scale: habitats; large-scale: inter-continental). A strong anthropogenic influence on the streams and rivers of the Portuguese littoral region was confirmed as well as the lack of true reference sites. Sites in the Least Disturbed Condition (LDC) had considerable high nutrient concentrations. As the strong anthropogenic pressures (e.g., alteration of the riparian vegetation, morphological condition and sediment load) prevented an adequate definition of reference conditions for streams in this area an alternative procedure to define suitable reference conditions was investigated, consisting of a combination of modelling and filter approach. This procedure is suitable to deal with the implications of global changes on diatom and on macroinvertebrate communities. The communities observed in the different streams were less homogeneous than those predicted for the same streams under reference conditions (i.e., through the filter approach), as would be expected in sites having variable levels of anthropogenic change. Along with the development of this new approach a new multimetric diatom index was developed. This index produced strong correlations with the selected pressures, providing a more comprehensive assessment of biological quality than the Indice de Polluosensibilité Spécifique (IPS) officially adopted for Portugal. To answer the second global question a smaller set of streams were used within the Portuguese littoral region that were affected by an unusual drought event that lead to the complete drying of the stream channels. Diatoms, as well as macroinvertebrates, were affected by the drought event considering trait proportions, community’s composition and bioassessment classifications. However, the diatom communities had a faster recovery response than macroinvertebrates. The type of substrate – hard and soft –representing the small spatial scale affected diatom communities by changing its composition and trait proportions but not water quality classification in a mesocosm experiment. However, the differences found in the epipsammic and epilithic diatom communities in the streams that were used to answer the first global question were more evident than those found in the mesocosm experiment. In fact, with the mesocosm results, and under the same physical and chemical conditions the IPS differences between substrates disappeared contrasting with the differences that were found in the streams. Additionally, the diatom communities were different between continents with the same type of climate, suggesting that diatom communities are also influenced at the large-scale (even at the order level). Therefore, constraints other than climate are likely to have contributed to the inter-continental differences in diatom community composition found at all taxonomical levels (e.g., geology, historical biogeographic processes and hydrology). On the whole, the results obtained during this study bring new information and new approaches to deal with the bioassessment. However, some more work must be done in order to investigate e.g., based in the global warming predictions, the effects of the temperature increase, on the water quality assessment based on diatom communities.
As diatomáceas são as algas que se encontram mais frequentemente e em maior abundância em cursos de água doce. São conhecidas pela capacidade dos diferentes taxa responderem a variações das condições ambientais dos rios e por serem frequentemente o único elemento de qualidade biológica representativo da flora aquática em pequenos rios e ribeiras. Em consequência destas características, e de acordo com a Directiva Quadro da Água, as diatomáceas são presentemente um dos elementos biológicos obrigatórios na avaliação da qualidade ecológica dos rios europeus. No entanto, ainda existe algum desconhecimento acerca dos efeitos das alterações globais e da escala espacial nas diatomáceas. Para colmatar esta lacuna, o presente trabalho tem como objetivo estudar o efeito de alterações globais relevantes e da escala espacial nas comunidades de diatomáceas de rios temperados assim como estudar a melhor forma de lidar com as suas implicações na biomonitorização. O efeito das alterações globais foi estudado em rios e ribeiras da região centro litoral de Portugal continental dado tratar-se de uma região densamente povoada e sujeita a impactos antropogénicos significativos. O efeito da escala espacial nas comunidades de diatomáceas foi investigado através de uma experiência laboratorial (mesocosmos) e também com recurso a informação estatística de comunidades de diatomáceas de várias regiões temperadas, incluindo as costas ocidentais dos Estados Unidos da América e da Austrália. De modo atingir o objetivo principal deste trabalho, três questões globais foram colocadas: (1) Como lidar com as influências antrópicas históricas na biomonitorização?; (2) Será que as comunidades de diatomáceas reflectem os eventos extremos causados pelas alterações climáticas? Uma comparação com as comunidades de macroinvertebrados; (3) Como são as comunidades de diatomáceas influenciadas pela escala espacial (pequena escala: habitats; grande escala: inter-continental). Verificou-se uma influência antropogénica considerável nos rios e ribeiras da região centro litoral de Portugal continental assim como a inexistência de verdadeiros locais de referência. Mesmo os locais considerados como estando em condições de menor perturbação apresentaram concentrações de nutrientes consideravelmente elevadas na água. Uma vez que as fortes pressões antropogénica (p.e., alteração da vegetação ripária, condição morfológica e carga de sedimentos) não permitiram o estabelecimento de condições de referência adequadas para os rios desta região, foi proposto um procedimento alternativo baseado numa combinação de dois métodos – modelação e filtros ambientais. A aplicação deste procedimento na definição de condições de referência revelou-se útil para lidar com os efeitos das alterações globais na biomonitorização com recurso a comunidades de diatomáceas e macroinvertebrados. De facto, como seria de esperar, as comunidades observadas em rios sujeitos a alterações antropogénicas revelaram-se menos homogéneas do que as previstas em condições de referência para esses mesmos rios, i.e., através da aplicação dos referidos filtros ambientais. Em conjunto com o desenvolvimento deste novo procedimento, foi também proposto um novo índice multimétrico de diatomáceas. Este novo índice revelou-se fortemente correlacionado com as pressões selecionadas, fornecendo uma avaliação da qualidade biológica mais abrangente do que o índice oficial adotado por Portugal, o Indice de Polluosensibilité spécifique (IPS). Para responder à segunda questão global apenas um subconjunto de ribeiras da região litoral de Portugal foi selecionado, o qual engloba as ribeiras cujos leitos secaram durante uma vaga de calor invulgar que ocorreu em Portugal em 2011/2012. Verificou-se que, de facto, quer as comunidades de diatomáceas quer de macroinvertebrados foram afetadas pelo evento de seca extrema tendo-se observado alterações ao nível das proporções de traits, composição e a classificação da qualidade biológica. No entanto, as diatomáceas apresentaram uma recuperação significativamente mais rápida que os macroinvertebrados. Os tipos de substratos usados na experiência de mesocosmos realizada neste trabalho (duro vs. macio; pequena escala espacial) também mostraram afetar as comunidades de diatomáceas, uma vez que houve diferenças quer na sua composição quer nas proporções de traits. Esta resposta ao tipo de substrato foi mais evidente em condições físico-químicas controladas do que aquela sugerida pelas diferenças entre as comunidades epipsâmicas e epilíticas dos rios monitorizados neste trabalho. Não obstante, durante a experiência de mesocosmos verificou-se que ao nível de IPS as diferenças entre substratos não eram relevantes quando comparadas com as que se haviam verificado nos rios. As diferenças observadas entre as comunidades de diatomáceas dos vários continentes (Europa, América e Austrália) sugerem que variações ao nível da grande escala também ocasionam diferenças nas comunidades, apesar de influenciados pelo mesmo tipo de clima. Isto sugere que outros factores para além do clima (p.e., geologia, processos biogeográficos históricos e hidrologia) podem ter contribuído para as diferenças inter-continentais verificadas ao nível da composição das comunidades de diatomáceas, a todos os níveis taxonómicos estudados. De um modo geral, os resultados obtidos durante este estudo trazem novas informações e novas abordagens para lidar com a biomonitorização. No entanto, mais trabalho será necessário a fim de investigar, por exemplo, os efeitos do aumento da temperatura previstos devido ao aquecimento global na avaliação da qualidade da água com base em comunidades de diatomáceas.

Nous etudions a l'aide de la theorie de l'eau peu profonde une onde interne plane dans le contexte d'un fluide tournant stratifie en bicouche. Differents cas ont ete traites pour lesquels les hypotheses de faible ecart de densite entre les couches et de faibles epaisseurs de couches sont considerees independamment ou en meme temps. Nous apportons la demonstration qu'une equation d'ostrovsky gouverne les ondes internes non-lineaires d'interface dans le cas faiblement tournant. Nous demontrons que reduire l'ecart de densite conduit a augmenter les effets de la rotation. Enfin nous etablissons les equations qui gouvernent les ondes internes dans quelques cas particuliers et nous donnons la forme de celle-ci. Des experiences ont ete menees dans la grande cuve tournante du laboratoire coriolis pour etudier l'influence de la rotation sur des ondes internes axisymetriques. Nous avons mis en evidence quelques phenomenes interessant et les conclusions experimentales confirment nos resultats analytiques en ce qui concerne les influences respectives de l'ecart de densite et de la rotation. La rotation modifie considerablement les lois d'evolution de l'amplitude en fonction de la distance au centre de la cuve. Une autre partie de l'etude a ete consacree a la recherche experimentale de la generation des ondes internes non-lineaires par la maree en presence du talus continental ainsi que leur propagation. L'originalite de ce travail reside dans la generation d'ondes internes tridimensionnelles ainsi que dans la prise en compte des effets de la rotation sur le mecanisme de generation et la propagation des ondes. Nous avons montre que seul le jusant engendre la maree interne sur le plateau et le talus. La rotation n'agit pas sur le mecanisme de generation mais sur la propagation des ondes, de plus elle en diminue l'amplitude et en augmente la vitesse de propagation.

Au cours de cette etude, de nombreuses experiences ont ete menees sur le devenir de la composition isotopique de l'eau dans le continuum sol-plante-atmosphere. Les processus qui gouvernent l'evolution des teneurs en isotopes stables de l'eau des feuilles ont pu etre identifiees et discutes. L'evolution tempiorelle des abondances relatives en oxygene-18 et en deuterium dans l'eau foliaire ont ete egalement modelisee. Ce modele prend en compte des parametres de nature differente, tels que des parametres climatiques (humidite relative, temperature de l'air), de l'envirronement (vitesse du vent), isotopiques (teneurs en isotopes lourds de l'eau d'alimentation, de la vapeur d'eau atmospherique qui participe aux echanges avec le reservoir d'eau foliaire, facteurs de fractionnement isotopique) et intrinseques a la plante

Mestrado em Engenharia Agronómica - Instituto Superior de Agronomia
The Palmer Drought Severity Index (PDSI) was tested along with two indices resulting from modifying its original formulation, one concerning the replacement of the Thornthwaite equation to compute potential evapotranspiration (ETP) by the FAO Penman-Monteith method, and the other consisting in replacing the soil water balance model and the ETP computation that passes to correspond to the ETP of an olive orchard, generating a new index: the MedPDSI. A factor for the normalization of the index, the climate characteristic (K), was reviewed and the index was calibrated for each analyzed location. The Standardized Precipitation Index (SPI) for the 9 and 12 month time-scales was also tested and compared with the three variants of the PDSI. The results revealed that the modification of K improved the standardization of the PDSI and that the calibration produced statistically improved results. It was found that the MedPDSI anticipates the initiation of droughts over the original PDSI, either with ETP Thornthwaite or with ETP FAO Penman-Monteith, and tends to classify droughts more severely than the first. The use of 9 month time-scale in the SPI is the one that best relates to the PDSI, since it clearly anticipates the onset of droughts relative to the 12 month scale.

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Ocean Engineering, 2002.
Includes bibliographical references (p. 347-354).
The long range imaging of submerged objects, seafloor and sub-seafloor geomorphology in continental shelf waters using an active sonar system is explored experimentally and theoretically. A unified model for 3-D object scattering and reverberation that takes into account the coupling between propagation and scattering in a stratified medium is developed from wave theory. The conditions necessary for scattering in a waveguide to become diffuse is derived directly from Green's Theorem. Simulations with the unified model indicate that the detection of submerged target echoes above diffuse seafloor reverberation is highly dependent upon waveguide properties, bandwidth, array aperture, measurement geometry, and the scattering properties of the target. Analysis with the unified model shows that it is theoretically plausible for coherent returns from the scattering of evanescent waves by extended but discrete sub-bottom geologic features to stand significantly above diffuse or incoherent returns arising from small-scale roughness of the waveguide boundaries. A long-range bistatic sonar system was deployed in a field experiment and used to image extensive networks of buried river channels and inclined sub-seafloor strata over tens of kilometers in nearreal time. Such a capability is of great advantage in geophysical applications. Since buried river channels are expected to be ubiquitous in continental shelf environments, sub-seafloor geomorphology will play a major role in producing "false alarms" or cluster in long-range sonar systems that search for submerged objects such as underwater vehicles.
(cont.) A generalized extinction theorem for object scattering in a stratified medium is derived that can be applied to detect and classify objects from the total field in the forward scatter direction in a waveguide. Analytic expressions are derived for the attenuation and dispersion in the forward propagated field due to scattering from random surface and volume inhomogeneities in a waveguide. The unified model is applied to show that the active sonar equation is not in general valid for scattering in a waveguide. It is shown that the sonar equation may be made approximately valid in a waveguide by lowering the active frequency of operation sufficiently for the given measurement scenario to simplify analysis for target classification and localization.
by Purnima Ratilal.
Ph.D.

La gestion et la conservation des lacs de haute montagne Pyrénéens dans le contexte actuel du changement climatique et de l’augmentation de la pression anthropique nécessitent une connaissance approfondie de leur fonctionnement biogéochimique. Dans cette thèse, cinq campagnes d’échantillonnage ont été réalisées (2017-2019) dans plus de 20 lacs alpins. L’analyse d’échantillons d’eau nous a permis d’étudier les teneurs, les profils en profondeurs, la répartition géographique, et les variations saisonnières de nombreuses caractéristiques physico-chimiques et biogéochimiques. Le cycle du dioxyde de carbone (CO2) et le devenir des Eléments Traces Potentiellement Dangereux (PHTEs) ont été étudiés. Le mercure (Hg) a été particulièrement étudié au travers du développement d’une procédure analytique pour la détermination de concentrations en traces dans les eaux naturelles et de recherches biogéochimiques sur la distribution et le devenir des espèces du Hg dans la colonne d’eau, et dans des archives de sédiments.La procédure développée pour analyser l’alcalinité totale (TA) et le carbone inorganique dissous (DIC) nous a permis de déterminer les autres paramètres du système du CO2, le pH et la fugacité du CO2 (fCO2). Les spécificités du substrat rocheux apparaissent essentielles pour l’état d’acidification des lacs étudiés. De plus, les valeurs de fCO2 obtenues montrent que les lacs sont des sources de CO2 pour l’atmosphère.La mesure de divers paramètres physico-chimiques nous a permis de classer les lacs en fonction de leur géochimie de l’eau mettant en évidence l’importance de l’état trophique des lacs, des caractéristiques géologiques et des apports atmosphériques. La présence, les sources et le comportement des PHTEs ont été étudiés, démontrant un contraste entre les apports géologiques et atmosphériques. Le suivi intensif a démontré que certains PHTEs sont très sensibles aux changements environnementaux comme la température et les conditions redox.La mesure des concentrations de Hg total dans les systèmes aquatiques reste complexe et il est nécessaire de développer des méthodes analytiques moins coûteuses et faciles d’utilisation. La méthode développée et optimisée dans ce travail a été appliquée avec succès et a montré une bonne limite de détection et une excellente répétabilité. La spéciation du Hg dans la colonne d’eau a démontré l’état intact et la dynamique des lacs Pyrénéens. L’homogénéité dans les concentrations de Hg total non-gazeux a confirmé l’absence de sources locales et l’utilisation potentielle de ces écosystèmes en tant que sentinelles de la contamination régionale et globale du Hg. Alors que lemercure inorganique (iHg) n’a pas montré de variations saisonnières, le monométhylmercure (MMHg) a été significativement plus élevé en automne 2018 et le mercure gazeux dissous (DGM) a fortement varié parmi les lacs. Les expérimentation in-situ ont confirmé les conditions qui favorisent la méthylation (eaux anoxiques stratifiées), la déméthylation et la photoréduction (intense lumière UV) du Hg.L’analyse des archives de sédiments a mis en lumière les tendances temporelles des taux d’accumulation du Hg (HgARs), avec une augmentation progressive depuis le 16ème siècle et l’industrialisation, reflétant la production de Hg dans les mines d’Almadén. Les isotopes stables du Hg permettent de tracer certaines sources anthropiques ainsi que les variations climatiques passées.Globalement, les changements environnementaux dans les écosystèmes des lacs, provoqués à la fois par les conditions climatiques (température, intensité lumineuse) et la pression anthropique (apports atmosphériques, eutrophisation, CO2 atmosphérique) sont susceptibles d’entrainer des répercussions importantes parmi le CO2, certains PHTEs et le cycle biogéochimique du Hg dans les écosystèmes montagnards
The management and conservation of Pyrenean high mountain lakes within the current context of climate change and increasing anthropogenic pressure require detailed knowledge of their biogeochemical functioning. In this doctoral thesis, five sampling campaigns were carried out (2017-2019) in more than 20 alpine lakes. The analysis of water samples allowed us to study the occurrence, the depth profiles, the geographical distribution and the seasonal trends of a large array of physico-chemical and biogeochemical parameters. Specifically, the cycle of carbon dioxide (CO2) and the fate of Potentially Harmful Trace Elements (PHTEs) were investigated. The mercury (Hg) was specially studied through the development of an analytical procedure for the measurement of trace concentrations in natural waters and through biogeochemical investigations on the distribution and the fate of Hg species in the water column, as well as in sediment archives.The new and robust procedure developed in this work to measure the total alkalinity (TA) and the dissolved inorganic carbon (DIC) allowed us to determine the other two parameters of the CO2 system, the pH and the fugacity of CO2 (fCO2). The bedrock characteristics of the watershed appear to be the most important parameters influencing the acid status of the studied lakes. Moreover, obtained fCO2 values indicate that lakes are sources of CO2 for the atmosphere.The measurement of various physico-chemical parameters allowed us to discriminate and classify the studied lakes according to their water geochemistry, highlighting the importance of the trophic status of the lakes, the geological background and the atmospheric inputs. The occurrence, sources and behaviour of the PHTEs were investigated with evidence of a contrast between geological and atmospheric inputs. Intensive monitoring revealed some PHTEs to be highly sensitive to environmental changes such as temperature and redox conditions.Monitoring natural concentrations of total Hg in aquatic systems remains a difficult challenge and there is a need for the development of low cost and easy handling analytical methods. The method for analysis of trace Hg concentrations developed and optimized in this work was successfully operational and exhibits a suitable limit of detection and an excellent reproducibility. Hg speciation results in the water column demonstrated the pristine state and the dynamic of the Pyrenean lakes. The homogeneity in the non-gaseous total Hg concentrations in the studied lakes confirmed the absence of local sources and the potential use of these ecosystems as sentinels of regional to global Hg contamination. While inorganic mercury (iHg) did not show seasonal variations, monomethylmercury(MMHg) was significantly higher in autumn 2018 and dissolved gaseous mercury (DGM) varied strongly within and among lakes. In-situ experiments confirmed the conditions that promote Hg methylation (stratified anoxic waters), demethylation and photoreduction (intense UV light).The historical Hg record in sediment archives highlighted temporal trends in Hg accumulation rates (HgARs) with a progressive increase since the 16th Century and the industrialization, mirroring the Hg production in Almadén mines (Southern Spain). Besides, Hg stable isotopes allow the identification of distinct anthropogenic sources as well as past climate variability.Overall, environmental changes in lake ecosystems, induced by either climatic conditions (temperature, light intensity) or anthropogenic pressure (atmospheric inputs, eutrophication, atmospheric CO2) are likely to produce significant impacts among CO2, specific PHTEs and Hg biogeochemical cycles in mountainous ecosystems

Cette thèse a pour but de préparer un travail d’extrapolation de l’impact des overshoots stratosphériques (SOC) sur le bilan de vapeur d’eau (VE) dans la couche de la tropopause tropicale (TTL) et dans la basse stratosphère à l’échelle continentale.Pour ce faire, nous profitons des mesures de la campagne de terrain TRO-Pico tenue à Bauru, au Brésil, pendant deux saisons convectives/humides en 2012 et 2013, et de plusieurs simulations numériques de la TTL sur un domaine englobant une grande partie de l’Amérique du Sud avec le modèle méso-échelle BRAMS.Premièrement, nous effectuer une simulation d’une une saison humide complète sans tenir compte des SOC. Cette simulation est ensuite évaluée pour d’autres caractéristiques clés typiques (température de la TTL, VE, sommets de nuages et ondes de gravité) dans la TTL. En l’absence de SOC et avant d’extrapoler son leur impact, nous démontrons que le modèle reproduit correctement les caractéristiques principales de la TTL. L’importance de l’ascension lente à grande échelle par rapport aux processus convectifs profonds à échelle finie est ensuite discutée.Deuxièmement, à partir de simulations BRAMS à fine à échelle de cas de SOC observés pendant TRO-Pico, nous déduisons des quantités physiques (flux de glace, bilan de masse de glace, tailles des SOCs), qui serviront à définir un forçage de l’impact des overshoots dans des simulations à grande échelle. Nous montrons un impact maximum d’environ 2 kt en VE et 6 kt de glace par SOC. Ces chiffres sont 30% nférieurs pour un autre réglage microphysique du modèle. Nous montrons que seul trois types d’hydrométéores du modèle contribuent à cette hydratation
This dissertation aims at laying a foundation on upscaling work of the impact of stratospheric overshooting convection (SOC) on the water vapor budget in the tropical tropopause layer (TTL) and lower stratosphere at a continental scale.To do so, we take advantage of the TRO-Pico field campaign measurements held at Bauru, Brazil, during two wet/convective seasons in 2012 and 2013, and perform accordingly several numerical simulations of the TTL which encompass through a large part of south America using the BRAMS mesoscale model.Firstly, we adopt a strategy of simulating a full wet season without considering SOC. This simulation is then evaluated for other typical key features (e.g., TTL temperature, convective clouds, gravity wave) of the TTL. In the absence of SOC and before upscaling its impact, we demonstrate that the model has a fair enough ability to reproduce a typical TTL. The importance of large-scale upwelling in comparison to the finite-scale deep convective processes is then discussed.Secondly, from fine scale BRAMS simulations of an observational case of SOC during TRO-Pico, we deduce physical parameters (mass flux, ice mass budget, SOC size) that will be used to set a nudging of the SOC impact in large-scale simulations. A typical maximum impact of about 2kt of water vapor, and 6kt of ice per SOC cell is computed. This estimation is 30% lower for another microphysical setup of the model. We also show that the stratospheric hydration by SOC is mainly due to two types of hydrometeors in the model

L'augmentation continue des concentrations atmosphériques de CO2 due aux activités anthropogéniques est un des principaux facteurs responsable du changement climatique. De par leur forte propension à stocker ce CO2 anthropogénique, les océans jouent un rôle essentiel dans le cycle global du carbone. La quantification des échanges air-mer de CO2 et de leur variabilité à diverses échelles spatio-temporelles représentent encore aujourd'hui un défi majeur dans l'étude du cycle global du carbone. Alors que les flux air-mer de CO2 sont relativement bien quantifiés en milieu océanique, les études réalisées en milieu marin côtier demeurent insuffisantes au regard de l'importante variabilité spatio-temporelle de ces échanges et de la diversité de ces écosystèmes. L'objectif de cette thèse est de mener une étude approfondie de la dynamique du système des carbonates et des échanges air-mer de CO2 à de multiples échelles spatio-temporelles au sein des écosystèmes contrastés du plateau continental nord-ouest européen. Ces systèmes particulièrement dynamiques d'un point de vue biogéochimique présentent l'avantage d'être représentatifs des principales structures hydrographiques des marges continentales tempérés. A ce jour, les études portant sur la dynamique du CO2 dans les eaux de la partie occidentale du plateau continental nord-ouest européen restent peu nombreuses. Du cycle diurne à une échelle multi-annuelle, d'une station fixe au large de Roscoff au plateau continental nord-ouest européen, et d'échantillons d'eau de mer à des données satellitaires, cette thèse offre un aperçu exhaustif de la complexité de la dynamique du système des carbonates et des flux air-mer de CO2 en milieu côtier
The raise of atmospheric CO2 due to anthropogenic activities is a major driver of the climate change. The ocean plays a key role in the uptake of this anthropogenic CO2. The constraint of air–sea CO2 fluxes and their variability at various time and spatial levels remain a central task in global carbon cycle and climate studies. The contribution of open ocean to this uptake is presently rather well quantified, whereas the role of the coastal ocean to this process remains ambiguous due to the diversity and the high spatio-temporal variability of the CO2 system and air-sea CO2 fluxes in these ecosystems. This PhD thesis investigated the spatial and temporal variability of the CO2 system and air-sea CO2 fluxes in contrasted ecosystems of the north-west European continental shelf. These highly dynamic biogeochemical ecosystems host numerous key hydrographical structures (permanently well-mixed, seasonally stratified, frontal structures, estuarine) of temperate zones, in which the dynamic of the CO2 system were poorly documented. From tidal to multi-annual variability, from a fixed station off Roscoff to the north-west European continental shelf and from seawater samples to satellite data, this PhD thesis provides an integrative overview of the complexity of the CO2 system dynamics in coastal seas and the ongoing challenges to achieve