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Статті в журналах з теми "Spectroscopies exaltées de surface":
Boubekeur-Lecaque, Leïla, Nordin Felidj, and Marc Lamy de la Chapelle. "Comprendre. La diffusion Raman exaltée de surface." Photoniques, no. 90 (January 2018): 41–44. http://dx.doi.org/10.1051/photon/20189041.
Felidj, Nordin. "Introduction à la spectroscopie Raman classique et à la diffusion Raman exaltée de surface." Photoniques, no. 96 (May 2019): 39–42. http://dx.doi.org/10.1051/photon/20199639.
Felidj, Nordin. "Introduction à… La spectroscopie Raman et la diffusion exaltée de surface." Photoniques, no. 81 (April 2016): 46–49. http://dx.doi.org/10.1051/photon/20168146.
Richardson, Neville V., and David A. King. "Surface Spectroscopies." Physics Bulletin 36, no. 3 (March 1985): 114–17. http://dx.doi.org/10.1088/0031-9112/36/3/021.
Holze, Rudolf, and Sebastian Schlücker. "Surface-enhanced spectroscopies." Physical Chemistry Chemical Physics 17, no. 33 (2015): 21045. http://dx.doi.org/10.1039/c5cp90032h.
Madix, Robert J. "Surface reactivity and surface spectroscopies." Ultramicroscopy 31, no. 1 (September 1989): 58–66. http://dx.doi.org/10.1016/0304-3991(89)90034-x.
Kelley, Michael J. "Imaging with Surface Spectroscopies." MRS Bulletin 16, no. 3 (March 1991): 46–49. http://dx.doi.org/10.1557/s0883769400057407.
Belton, D. N., and S. J. Schmieg. "Surface spectroscopies for diamond." Carbon 28, no. 6 (1990): 760. http://dx.doi.org/10.1016/0008-6223(90)90275-4.
Salma, K., Z. J. Ding, H. M. Li, and Z. M. Zhang. "Surface excitation probabilities in surface electron spectroscopies." Surface Science 600, no. 7 (April 2006): 1526–39. http://dx.doi.org/10.1016/j.susc.2006.02.008.
Barkley, P. Glenn, Joseph P. Hornak, and Jack H. Freed. "Surface‐suppressed electron resonance spectroscopies." Journal of Chemical Physics 84, no. 3 (February 1986): 1886–900. http://dx.doi.org/10.1063/1.450437.
Дисертації з теми "Spectroscopies exaltées de surface":
Edely, Mathieu. "Etudes de surfaces métalliques nanolithographiées : application à la diffusion Raman exaltée de surface." Thesis, Le Mans, 2016. http://www.theses.fr/2016LEMA1020.
Since the first observation of Surface Enhanced Raman Scattering (SERS) in 1974 a variety of methods have been developed to physically control the arrangement of metallic nanostructures onto a surface in order to enhance Raman signals. The magnitude of the SERS enhancement factor is mainly driven by the enhanced local electromagnetic field in nanostructured metal surfaces. Gaps between adjacent nanoparticles give rise to strong enhancement effects, often referred as ‘hot spots’. One way to produce highly efficient SERS substrates is to develop a reproducible system of interacting metal nanostructures capable of high field enhancement.We patented a force-assisted Atomic Force Microscopy lithographic method allowing the fabrication of a metallic substrate. It will be shown that this method also provides a relatively simple approach to realize reproducible patterns with controlled geometry that can be used to study the influence of specific pattern geometry on SERS phenomenon.In order to investigate the relationship between optical properties and pattern geometries, localized surface plasmon resonance (LSPR) and local electric field enhancement are simulated.Whereas electric field enhancement regions (hot spot) have been observed on the top of the nanostructures with PhotoEmission Electron Microscopy (PEEM), SERS effect has been demonstrated by performing Raman measurements using several probe molecules. Correlations between PEEM measurements, Raman exaltation and local field calculations are presented in relation with the geometrical parameters of the nanostructured patterns
Lopes, Manuel. "Etude de nanoantennes optiques : application aux diffusions Raman exaltées de surface et par pointe." Phd thesis, Université de Technologie de Troyes, 2008. http://tel.archives-ouvertes.fr/tel-00357221.
Ensuite, j'ai monté une expérience de Raman en champ proche (ou TERS) et développé une technique reproductible de fabrication de pointes en or. Puis, j'ai effectué une étude quantitative des propriétés de dépolarisation des pointes métalliques utilisées en a-SNOM et en TERS. Nos résultats montrent des facteurs de dépolarisation entre 5 et 30% qui varient en fonction de la polarisation de la lumière incidente et de la forme de la pointe. Les conséquences importantes de ce phénomène de dépolarisation ont été mises en évidence dans des expériences TERS sur du Silicium cristallin; On montre que la dépolarisation doit être prise en compte pour une estimation correcte de l'exaltation induite par la pointe.
Rastogi, Rishabh. "Engineered Electromagnetic Hot-spots for Highly Sensitive (Bio)molecular Detection by Plasmonic Specytroscopies." Thesis, Troyes, 2020. http://www.theses.fr/2020TROY0018.
Nanoplasmonic sensing relies on enhanced electromagnetic fields at the vicinity of nanostructured metal surface to detect molecules at ultra-low concentrations. The EM enhancements are strongly pronounced at junctions between adjacent nanostructures resulting in gap hot-spots. EM enhancements at these hot-spots increase non-linearly as a function of gap distances down to sub-10 regime. Analyte present at these gaps can leverage these EM enhancements, resulting in ultra-high sensitivity in detection. However, such confining gaps affect the ability of large analytes such as biomolecules to enter and thereby leverage EM fields within the gaps. This presents spatial needs to enhance EM fields at odds with those for accommodating biomolecular interactions. This thesis demonstrates the rational design of array configurations that allows the EM hotspots to be better leveraged by the reporter of biomolecular binding event. The thesis uses molecular self-assembly based approach to fabricate reproducible plasmonic nanoarrays on full wafers. Multiple parameters are considered including the dimension, shape, and density of hotspots, surface functionalization, and the choice of substrates, to demonstrate quantitative detection of molecules down to picomolar concentrations
Haidar, Israa. "Nouvelles plateformes plasmoniques pour la spectroscopie Raman exaltée de surface." Thesis, Sorbonne Paris Cité, 2016. http://www.theses.fr/2016USPCC307.
The design of novel plasmonic platforms for Surface Enhanced Raman Spectroscopy (SERS) constitutes a very active field of research in nanosciences. Such platforms can be used for the detection and identification of various analytes at very low concentration, through a huge amplification of the Raman signal, resulting from the excitation of localized surface plasmon resonances. The main objective of my phd is to develop and to characterize new SERS substrates obtained by chemical assembly (surface functionalization) of nanoparticles with controlled hot spots. Design of such substrates contributes to a better understanding of the mechanisms of electromagnetic enhancement considered at the origin of the SERS effect
Delhaye, Caroline. "Spectroscopie Raman et microfluidique : application à la diffusion Raman exaltée de surface." Thesis, Bordeaux 1, 2009. http://www.theses.fr/2009BOR13927/document.
This thesis focuses on the development of a microfluidic platform coupled with confocal Raman microscopy, used in excitation conditions of Raman scattering (Surface enhanced Raman scattering, SERS) in order to gain in the detection sensitivity of molecular species flowing in channels of micrometer dimensions. This work aims to demonstrate the feasibility of coupling Raman microscopy / microfluidics for the in situ and local characterization of species and reactions taking place in the fluid flowing in microchannels. We used a T-shaped microchannel, made by soft lithography, in which gold or silver nanoparticles injected at constant speed, in one of the two branches of the channel and a solution of pyridine or pefloxacin in the other one. The laminar flow and the stationarity of the process allowed us to map the mixing zone and highlight the enhancement of the Raman signal of pyridine and pefloxacin, due to the metallic nanoparticles, in the interdiffusion zone. The recording of the both absorption band of the silver nanoparticles (plasmon band) and the Raman signal of pefloxacin, flowing in microchannel, allowed us to establish a link between the shape of the metallic nanostructure, and more precisely the silver nanoparticle aggregation state, and the enhancement of the Raman signal of pefloxacin observed. We then changed the channel geometry to introduce an electrolyte solution (NaCl and NaNO3) and locally modify the surface charge of the colloids. We have put in evidence that the change of the silver nanoparticle aggregation state, induced by the controlled addition of electrolyte solutions, could amplify the SERS signal of pefloxacin and thus optimizing the detection in microfluidics. At last, we established second a approach that consists in the metallic structuring of microchannel walls. This has shown that the surface chemical functionalization through organosilanes (APTES) allowed the pasting of the channel with silver nanoparticles, thus amplifying the Raman signal of the species flowing within the same microchannel
Makiabadi, Tahereh. "Etude de surfaces nanostructurées : applications à la spectroscopie Raman exaltée de surface et à la résonance de plasmons localisés." Phd thesis, Université de Nantes, 2010. http://tel.archives-ouvertes.fr/tel-00467582.
Makiabadi, Tahereh. "Étude de surfaces nanostructurées : applications à la spectroscopie Raman exaltée de surface et à la résonance de plasmons localisés." Nantes, 2010. http://archive.bu.univ-nantes.fr/pollux/show.action?id=eb8aaf03-cd71-46c6-a427-2c4cf47a3a49.
The objectives of this work are the realization, characterization and optimization of nanostructured surfaces, e. G. Substrates for the surface-enhanced Raman spectroscopy and the surface plasmon resonance. Several main contributions were performed. The first one is based on the grafting of silver and gold nanoparticles on functionalized supports. Our bottomup approach enabled us to highlight the optimal conditions to obtain a mono-layer of nanoparticles, with homogeneous distribution and an important density. The curves of extinction and factors of exaltation were quantified and modeled. Also, the manufacturing time was optimized. The second contribution, which is based on a top-down approach, consists of making nanostructures by electro erosion of a thin film of silver or gold, carried out by physical deposit in vapor phase. This procedure, which relies on the optimization of oxidation-reduction cycle (ORC), was employed to realize rough films and metal nanostructures. The presence of nanostructures and the nano cavities on the substrates were confirmed by scanning electron microscopy (SEM) atomic force microscopy (AFM). The limit of detection by Raman spectrometry was evaluated at 1nM. The optimal conditions obtained from the curves of extinction and Raman scattering made it possible to converge towards a reliable and reproducible manufacturing protocol. The third contribution is the deposit of nanoparticles on optical fibers in order to evaluate the sensitivity of the localized surface plasmon resonance (LSPR)
Julien, Carine. "Fluorescence et Diffusion Raman exaltée de surface (SERS) de molécules individuelles." Phd thesis, Université Paris Sud - Paris XI, 2004. http://tel.archives-ouvertes.fr/tel-00011564.
Par microscopie grand champ de fluorescence, l'émission de molécules uniques de pérylène orange insérées dans un film solgel mince, par enregistrement de films d'une large zone de l'échantillon sur laquelle plus d'une centaine d'émetteurs individuels sont détectés, fournit des informations sur cette espèce et la matrice sondée. Pour exploiter les films, un outil logiciel a été développé. Les processus de photoblanchiment, la mobilité moléculaire, la nucléation des molécules excitées sont mis en évidence et discutés. On note une grande richesse des dynamiques temporelles d'émission, mais aussi des spectres qui reflètent notamment la reconformation proposée du pérylène orange excité. Il s'ensuit l'existence de nombreux nanoenvironnements différents dans la matrice poreuse.
Par microscopie confocale à balayage, le signal de diffusion Raman exaltée de surface de molécules uniques organique adsorbées sur des agrégats d'argent de morphologie complexe est exploité. Certains objets présentent une exaltation géante, estimée être de plus de 14 ordres de grandeur, ce qui permet l'enregistrement de spectres résolus en seulement une seconde. L'analyse chimique offerte permet de distinguer différentes espèces, et la présence nécessaire sur ces points chauds d'Ag+ est démontrée. Une caractérisation corrélée par microscopie électronique des agrégats actifs repérés met aussi en avant l'existence d'une morphologie privilégiée, avec de nombreuses protubérances de dimension nanométrique et interstices.
Yazidi, Senda. "Structure et propriétés optiques de nanoparticules couplées : application à la spectroscopie Raman exaltée de surface." Thesis, Poitiers, 2018. http://www.theses.fr/2018POIT2279/document.
The aim of this work is to use nanostructured alumina surfaces to guide the growth and to optimize the organization of metallic particles (Ag, Au and AgxAu1-x), and to test those systems as reusable SERS-active substrates. We used spectrophotometry to characterize the resulting optical properties, spectroscopic ellipsometry for the determination of the optical index and transmission electron microscopy for the structural characterizations. Surfaced-enhanced Raman spectroscopy (SERS) was used for the detection of adsorbed bipyridine molecules on the sample surface, in collaboration with the Institut des Matériaux Jean Rouxel at Nantes. We first study systems consisting of monometallic and bimetallic nanoparticles in order to understand the growth modes of such particle assemblies. A particular attention is paid to the influence of the sequential deposition of Au and Ag on the structural and optical properties. We show that different arrangements of bimetallic nanoparticles are obtained according to the deposition sequence used and that an alloy is obtained after ex situ annealing under vacuum. The near-field and far-field optical properties of AgxAu1-x nanoparticle alloys embedded in an alumina matrix are compared numerically by the finite difference time domain method, with those of pure metal nanoparticles. Our results indicate that pure metal nanoparticles exhibit a greater field enhancement than alloy nanoparticles. Finally, SERS experiments conducted with a dichroic system made of coupled Ag nanoparticles show that an intense SERS signal can be obtained with coated nanoparticles
Grand, Johan. "Plasmons de surface de nanoparticules : spectroscopie d'extinction en champs proche et lointain, diffusion Raman exaltée." Troyes, 2004. http://www.theses.fr/2004TROY0014.
The intrinsic weakness of the Raman process makes its application in a near field optical experiment rather difficult. Thus, as a first step towards near field Raman spectroscopy, we studied Surface-Enhanced Raman Scattering (SERS), a technique that enables the detection of very low concentration of molecules adsorbed on rough metallic surfaces. For the purpose of the near field experiments, these SERS-active samples have to be reproducible and yield good enhancement factors. By designing metallic nanoparticle grating through electron beam lithography, we manage to vary the shape, size and arrangement of the particles, hence enabling a fine tuning of the Localized Surface Plasmon Resonance (LSPR) over the whole visible spectrum. We then investigate the relationship between the spectral position of the LSPR and the SERS intensity. The enhancement factor turned out to depend not only on the spectral position of the LSPR, but also on the shape of the metallic nanoparticles on which the surface plasmon is localized. In the same time, we build up an Apertureless Scanning Near Field Optical Microscope (ASNPM) set-up. The microscope is based on an atomic force microscope and a confocal detection coupled to a spectrometer. The near field/far field discrimination is achieved through the use of a lock-in detection of a photon counting device. Using this set-up along with a white light continuum, generated by coupling a Photonic Crystal Fiber to a Ti:Sa laser, made it possible to investigate the near field optical response of metallic nanoparticle gratings at different excitation wavelengths. A photon counting scheme was then used to directly record near field “extinction” spectra
Книги з теми "Spectroscopies exaltées de surface":
Czanderna, A. W. Ion Spectroscopies for Surface Analysis. Boston, MA: Springer US, 1991.
Czanderna, A. W., and David M. Hercules, eds. Ion Spectroscopies for Surface Analysis. Boston, MA: Springer US, 1991. http://dx.doi.org/10.1007/978-1-4615-3708-3.
Onsgaard, Jens. Some metal-and semiconductor surfaces studied by surface sensitive spectroscopies. Denmark: Fysisk Institut, Odense Universitet, 1988.
Hercules, David M., and Alvin W. Czanderna. Ion Spectroscopies for Surface Analysis. Springer, 2011.
1930-, Czanderna Alvin Warren, and Hercules David M, eds. Ion spectroscopies for surface analysis. New York: Plenum Press, 1991.
Corallo, Gregory Richard. Chemical- and electronic-state characterization of the surface region of metals following chemisorption of simple gases using electron beam spectroscopies. 1987.
Частини книг з теми "Spectroscopies exaltées de surface":
Komeda, Tadahiro, and Norio Okabayashi. "Spatially Resolved Surface Vibrational Spectroscopies." In Springer Handbook of Surface Science, 815–52. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-46906-1_25.
Czanderna, A. W. "Overview of Ion Spectroscopies for Surface Compositional Analysis." In Ion Spectroscopies for Surface Analysis, 1–44. Boston, MA: Springer US, 1991. http://dx.doi.org/10.1007/978-1-4615-3708-3_1.
Winograd, Nicholas, and Barbara J. Garrison. "Surface Structure and Reaction Studies by Ion-Solid Collisions." In Ion Spectroscopies for Surface Analysis, 45–141. Boston, MA: Springer US, 1991. http://dx.doi.org/10.1007/978-1-4615-3708-3_2.
Busch, Kenneth L. "Particle-Induced Desorption Ionization Techniques for Organic Mass Spectrometry." In Ion Spectroscopies for Surface Analysis, 143–271. Boston, MA: Springer US, 1991. http://dx.doi.org/10.1007/978-1-4615-3708-3_3.
Becker, Christopher H. "Laser Resonant and Nonresonant Photoionization of Sputtered Neutrals." In Ion Spectroscopies for Surface Analysis, 273–310. Boston, MA: Springer US, 1991. http://dx.doi.org/10.1007/978-1-4615-3708-3_4.
Feldman, L. C. "Rutherford Backscattering and Nuclear Reaction Analysis." In Ion Spectroscopies for Surface Analysis, 311–61. Boston, MA: Springer US, 1991. http://dx.doi.org/10.1007/978-1-4615-3708-3_5.
Taglauer, E. "Ion Scattering Spectroscopy." In Ion Spectroscopies for Surface Analysis, 363–416. Boston, MA: Springer US, 1991. http://dx.doi.org/10.1007/978-1-4615-3708-3_6.
Powell, C. J., D. M. Hercules, and A. W. Czanderna. "Comparisons of SIMS, SNMS, ISS, RBS, AES, and XPS Methods for Surface Compositional Analysis." In Ion Spectroscopies for Surface Analysis, 417–37. Boston, MA: Springer US, 1991. http://dx.doi.org/10.1007/978-1-4615-3708-3_7.
Lucas, A. A. "Charged Particle-Surface Interactions and Spectroscopies." In Interaction of Charged Particles with Solids and Surfaces, 193–96. Boston, MA: Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-8026-9_5.
Doyen, G., D. Drakova, and F. von Trentini. "Theoretical Aspects of Electronic Spectroscopies at (Adsorbate Covered) Surfaces." In Lectures on Surface Science, 154–68. Berlin, Heidelberg: Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-71723-9_28.
Тези доповідей конференцій з теми "Spectroscopies exaltées de surface":
ADAM, P. M. "NANOPLASMONICS AND SURFACE ENHANCED SPECTROSCOPIES." In Proceedings of International Conference Nanomeeting – 2013. WORLD SCIENTIFIC, 2013. http://dx.doi.org/10.1142/9789814460187_0001.
Le, F., F. Hao, and P. Nordlander. "Plasmonic substrates for surface-enhanced spectroscopies." In SPIE Optics + Photonics, edited by Satoshi Kawata, Vladimir M. Shalaev, and Din Ping Tsai. SPIE, 2006. http://dx.doi.org/10.1117/12.682195.
Tay, Li-Lin, John Hulse, Shawn Poirier, Ali Ghaemi, and Sarah Milliken. "Multilayered Au nanorod arrays for surface enhanced Raman and infrared absorption spectroscopies." In Enhanced Spectroscopies and Nanoimaging 2020, edited by Prabhat Verma and Yung Doug Suh. SPIE, 2020. http://dx.doi.org/10.1117/12.2575028.
Wang, Xiang, Shengchao Huang, Yifan Bao, Tengxiang Huang, and Bin Ren. "Nanoscale characterization of the surface plasmon catalysis with electrochemical tip-enhanced Raman spectroscopy." In Enhanced Spectroscopies and Nanoimaging 2021, edited by Prabhat Verma and Yung Doug Suh. SPIE, 2021. http://dx.doi.org/10.1117/12.2595112.
Maier, Stefan A. "Dielectric platforms for surface-enhanced spectroscopies (Conference Presentation)." In Colloidal Nanoparticles for Biomedical Applications XI, edited by Xing-Jie Liang, Wolfgang J. Parak, and Marek Osinski. SPIE, 2016. http://dx.doi.org/10.1117/12.2208492.
Lozeman, Jasper, Ketki Srivastava, Hai Le-The, Albert van den Berg, and Mathieu Odijk. "Large-area fabrication of Au nanoantennas for surface enhanced infrared spectroscopy without an adhesion layer." In Enhanced Spectroscopies and Nanoimaging 2020, edited by Prabhat Verma and Yung Doug Suh. SPIE, 2020. http://dx.doi.org/10.1117/12.2566757.
Gonçalves, Paulo André, and F. Javier García de Abajo. "Quantum surface-response in nanoplasmonics probed by electron spectroscopies." In Photonic and Phononic Properties of Engineered Nanostructures XII, edited by Ali Adibi, Shawn-Yu Lin, and Axel Scherer. SPIE, 2022. http://dx.doi.org/10.1117/12.2609060.
Kantarovich, Keren, Inbal Tsarfati, Levi A. Gheber, Karsten Haupt, Ilana Bar, P. M. Champion, and L. D. Ziegler. "Detection Of Biochips By Raman And Surface Enhanced Raman Spectroscopies." In XXII INTERNATIONAL CONFERENCE ON RAMAN SPECTROSCOPY. AIP, 2010. http://dx.doi.org/10.1063/1.3482265.
Kwon, J., and M. C. Downer. "Second-harmonic generation and reflectance-difference: a meeting of two surface spectroscopies." In Quantum Electronics and Laser Science (QELS). Postconference Digest. IEEE, 2003. http://dx.doi.org/10.1109/qels.2003.238322.
Grinblat, Gustavo, Yi Li, Javier Cambiasso, Toshishiko Shibanuma, Michael P. Nielsen, Emiliano Cortés, Pablo Albella Echave, Aliaksandra Rakovich, Rupert F. Oulton, and Stefan A. Maier. "Low-loss dielectric nanoantennas for surface-enhanced spectroscopies and nonlinear photonics (Conference Presentation)." In Optical Sensing, Imaging, and Photon Counting: Nanostructured Devices and Applications 2017, edited by Oleg Mitrofanov, Chee Hing Tan, Manijeh Razeghi, and José Luis Pau Vizcaíno. SPIE, 2017. http://dx.doi.org/10.1117/12.2273790.
Звіти організацій з теми "Spectroscopies exaltées de surface":
Tamura, E. Fully relativistic surface green function and its application to surface spectroscopies. Office of Scientific and Technical Information (OSTI), June 1993. http://dx.doi.org/10.2172/105849.
Corrigan, Dennis S., John K. Foley, Ping Gao, Stanley Pons, and Michael J. Weaver. Comparison Between Surface-Enhanced Raman and Surface Infrared Spectroscopies For Strongly Perturbed Adsorbates: Thiocyanate at Gold Electrodes. Fort Belvoir, VA: Defense Technical Information Center, August 1985. http://dx.doi.org/10.21236/ada159954.
Walters, G., and F. Dunning. Studies of ultrathin magnetic films and particle-surface interactions with spin-sensitive electron spectroscopies. Office of Scientific and Technical Information (OSTI), July 1990. http://dx.doi.org/10.2172/6746099.
El-Batanouny, Maged. Investigations of surface structural, dynamical, and magnetic properties of systems exhibiting multiferroicity, and topological phases by helium scattering spectroscopies. Office of Scientific and Technical Information (OSTI), August 2015. http://dx.doi.org/10.2172/1206408.
Garofalini, Stephen. Solid Electrolyte/Electrode Interfaces: Atomistic Behavior Analyzed Via UHV-AFM, Surface Spectroscopies, and Computer Simulations Computational and Experimental Studies of the Cathode/Electrolyte Interface in Oxide Thin Film Batteries. Office of Scientific and Technical Information (OSTI), March 2012. http://dx.doi.org/10.2172/1036745.