Academic literature on the topic '2,4,-dinitrotoluene (DNT)'

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Journal articles on the topic "2,4,-dinitrotoluene (DNT)"

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Nishino, Shirley F., George C. Paoli, and Jim C. Spain. "Aerobic Degradation of Dinitrotoluenes and Pathway for Bacterial Degradation of 2,6-Dinitrotoluene." Applied and Environmental Microbiology 66, no. 5 (2000): 2139–47. http://dx.doi.org/10.1128/aem.66.5.2139-2147.2000.

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ABSTRACT An oxidative pathway for the mineralization of 2,4-dinitrotoluene (2,4-DNT) by Burkholderia sp. strain DNT has been reported previously. We report here the isolation of additional strains with the ability to mineralize 2,4-DNT by the same pathway and the isolation and characterization of bacterial strains that mineralize 2,6-dinitrotoluene (2,6-DNT) by a different pathway.Burkholderia cepacia strain JS850 andHydrogenophaga palleronii strain JS863 grew on 2,6-DNT as the sole source of carbon and nitrogen. The initial steps in the pathway for degradation of 2,6-DNT were determined by si
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Cheng, Jiayang, Makram T. Suidan, and Albert D. Venosa. "Kinetics of anaerobic cometabolism of 2,4-dinitrotoluene with ethanol as the primary substrate." Water Science and Technology 36, no. 6-7 (1997): 271–78. http://dx.doi.org/10.2166/wst.1997.0600.

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A kinetic model that describes the anaerobic cometabolism of 2,4-dinitrtoluene (DNT) with ethanol as the primary substrate has been developed based on experimental results. The kinetic parameters were estimated using the Levenberg-Marquardt algorithm. 2,4-DNT is anaerobically biotransformed to 2,4-diaminotoluene (DAT) via 4-amino-2-nitrotoluene (4-A-2-NT) and 2-amino-4-nitrotoluene (2-A-4-NT) by the bacteria whose growth is supported by utilizing ethanol. 2,4-DNT shows inhibition to its own biotransformation. It also exhibits a very strong competitive inhibition to further biotransformation of
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Huang, Zhong Hua, Xue Pu, Hui Zhang, Fang Yuan, and Zheng Li Liu. "Biodegradation of 2, 4-Dinitrotoluene by Pseudomonas fluorescens sp. Isolated from a Nitrobenzene Contaminated Soil." Advanced Materials Research 610-613 (December 2012): 1233–36. http://dx.doi.org/10.4028/www.scientific.net/amr.610-613.1233.

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A 2,4-Dinitrotoluene degrading bacterium was isolated from sludge contaminated by DNT and identified as a member of Pseudomonas fluorescens sp. based on 16S rDNA sequence. Under growth substrates limited conditions, the strain was enriched with 2,4-DNT as its sole source of carbon and energy in the groundwater environment. Results indicate the isolate grew optimally at 12(±4)°C and initial pH 7.5 in the mineral salts medium supplemented 2,4-DNT with 40mg/L, thus showing potential for the remediation of 2,4-DNT contaminated groundwater.
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Jiayang, Cheng, Makram T. Suidan, and Albert D. Venosa. "Abiotic reduction of 2,4-dinitrotoluene in the presence of sulfide minerals under anoxic conditions." Water Science and Technology 34, no. 10 (1996): 25–33. http://dx.doi.org/10.2166/wst.1996.0235.

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Abiotic reduction of 2,4-dinitrotoluene (DNT) in the presence of sulfide minerals has been investigated under anoxic conditions at 35°C. 2,4-DNT was abiotically reduced to 4-amino-2-nitrotoluene (4-A-2-NT) and 2-amino-4-nitrotoluene (2-A-4-NT) in the presence of high concentration of sulfide (0.84 mM). No abiotic reduction of 2,4-DNT was observed in the presence of low sulfide concentration (0.42 mM). The rate and the extent of the abiotic reduction of 2,4-DNT were increased with an increase in sulfide concentration. Sulfide served as an electron donor for the reduction of 2,4-DNT. The 2-nitro
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Wang, Jing, Guang Fei Liu, Hong Lu, Ji Ti Zhou, and Lihua Li. "Enhanced Biotransformation of Dinitrotoluene by Mediator-Functionalized Polypyrrole Composites." Advanced Materials Research 610-613 (December 2012): 129–32. http://dx.doi.org/10.4028/www.scientific.net/amr.610-613.129.

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The continuous dosing and discharge of water soluble redox mediators such as biologically recalcitrant compounds will result in the secondary contamination. The immobilized redox mediator prepared by incorporation of anthraquinonedisulphon-ate (AQDS) during the electropolymerization of pyrrole monomer on active carbon felt (ACF), AQDS/PPy/ACF, was used for catalyzing bioreduction of 2,4-dinitrotoluene(2,4-DNT) in this study. The results showed that the morphology of the PPy films deposits on ACF are characterized by some globular structure; AQDS/PPy/ACF exhibited good catalytic activity and st
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Martin, J. L., S. D. Comfort, P. J. Shea, R. A. Drijber, and T. A. Kokjohn. "Denitration of 2,4,6-trinitrotoluene byPseudomonas savastanoi." Canadian Journal of Microbiology 43, no. 5 (1997): 447–55. http://dx.doi.org/10.1139/m97-063.

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Past disposal of wastewaters containing 2,4,6-trinitrotoluene (TNT) at the former Nebraska Ordnance Plant has resulted in numerous acres of TNT-contaminated soil. Examining the microbial population of these soils revealed several TNT-tolerant Pseudomonas spp. We selected one species, P. savastanoi, to determine its ability to transform TNT. Pure culture experiments were performed in pseudomonas minimal medium containing 0.31 mM TNT (70 mg TNT∙L−1) under varied nutrient and cell density regimes. Experiments with TNT as a sole C or N source showed that P. savastanoi has the ability to denitrate
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Mohammed, Mohammed S., Igor S. Kovalev, Natalya V. Slovesnova та ін. "(1-(4-(5-Phenyl-1,3,4-oxadiazol-2-yl)phenyl)-1H-1,2,3-triazol-4-yl)-methylenyls α,ω-Bisfunctionalized 3- and 4-PEG: Synthesis and Photophysical Studies". Molecules 28, № 13 (2023): 5256. http://dx.doi.org/10.3390/molecules28135256.

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Two new azaheterocycle-based bolas, such as (1-(4-(5-phenyl-1,3,4-oxadiazol-2-yl)phenyl)-1H-1,2,3-triazol-4-yl)-methylenyls α,ω-bisfunctionalized PEGs, were prepared via Cu-catalyzed click reaction between 2-(4-azidophenyl)-5-(aryl)-oxadiazole-1,3,4 and terminal ethynyls derived from PEG-3 and PEG-4. Due to the presence of two heteroaromatic cores and a PEG linker, these bola molecules are considered as promising fluorescent chemosensors for electron-deficient species. As a result of a well-pronounced “turn-off” fluorescence response towards common nitro-explosive components, such as 2,4-dinit
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Strehse, Jennifer Susanne, Tobias Hartwig Bünning, Jan Koschorreck, Anita Künitzer, and Edmund Maser. "Long-Term Trends for Blue Mussels from the German Environmental Specimen Bank Show First Evidence of Munition Contaminants Uptake." Toxics 11, no. 4 (2023): 347. http://dx.doi.org/10.3390/toxics11040347.

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Submerged munitions are present in marine waters across the globe. They contain energetic compounds (ECs), such as TNT and metabolites thereof, which are considered carcinogenic, exhibit toxic effects in marine organisms, and may affect human health. The aim of this study was to investigate the occurrence of ECs and their trends in blue mussels from the annual collections of the German Environmental Specimen Bank sampled over the last 30 years at three different locations along the coastline of the Baltic and North Sea. Samples were analyzed by GC-MS/MS for 1,3-dinitrobenzene (1,3-DNB), 2,4-di
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Schick, Luca Aroha, Jennifer Susanne Strehse, Tobias Hartwig Bünning, Edmund Maser, and Ursula Siebert. "Energetic Compounds in the Trophic Chain—A Pilot Study Examining the Exposure Risk of Common Eiders (Somateria mollissima) to TNT, Its Metabolites, and By-Products." Toxics 10, no. 11 (2022): 685. http://dx.doi.org/10.3390/toxics10110685.

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The Baltic and North Seas still contain large amounts of dumped munitions from both World Wars. The exposure of the munition shells to the seawater causes corrosion, which leads to the disintegration of shells and a leakage of energetic compounds, including the highly toxic 2,4,6-trinitrotoluene (TNT), and consequently threatening the marine environment. To evaluate the risk of accumulation of energetic compounds from conventional munitions in the marine food chain, we analyzed the presence of TNT and its metabolites 2-amino-4,6-dinitrotoluene (2-ADNT) and 4-amino-2,6-dinitrotoluene (4-ADNT) a
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Xiufang, Qi, Li Yuan, and Song Chunyao. "A facile preparation of g-C3N4/a-Fe2O3/TiO2 composite and its photocatalysis performance on the degradation of DNT/TNT under simulated sunlight." Journal of Physics: Conference Series 2639, no. 1 (2023): 012006. http://dx.doi.org/10.1088/1742-6596/2639/1/012006.

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Abstract It has been difficult to solve the environmental problems caused by trinitrotoluene(TNT)/dinitrotoluene(DNT) containing explosive wastewater for decades. The advanced oxidation method based on photocatalysis and hydrogen peroxide has gained considerable popularity in the field of pollutant degradation. In order to find a coping strategy, using a simple method involving obtaining g-C3N4/Fe2O3(CNFe) by two-step calcination and then mixing butyl titanate and CNFe through a sol-gel pathway, a type of low-cost g-C3N4/Fe2O3/TiO2(CNFeTi) ternary composite was prepared and then characterized
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Dissertations / Theses on the topic "2,4,-dinitrotoluene (DNT)"

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Gust, Kurt A., Bindu Nanduri, Arun Rawat, et al. "Systems toxicology identifies mechanistic impacts of 2-amino-4, 6-dinitrotoluene (2A-DNT) exposure in Northern Bobwhite." BioMed Central Ltd, 2015. http://hdl.handle.net/10150/610284.

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BACKGROUND: A systems toxicology investigation comparing and integrating transcriptomic and proteomic results was conducted to develop holistic effects characterizations for the wildlife bird model, Northern bobwhite (Colinus virginianus) dosed with the explosives degradation product 2-amino-4,6-dinitrotoluene (2A-DNT). A subchronic 60d toxicology bioassay was leveraged where both sexes were dosed via daily gavage with 0, 3, 14, or 30 mg/kg-d 2A-DNT. Effects on global transcript expression were investigated in liver and kidney tissue using custom microarrays for C. virginianus in both sexes at
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Christopher, Heidi Jandell. "Biodegradation of 2,4-Dinitrotoluene in the Waste Streams of a Munitions Plant." Thesis, Virginia Tech, 1998. http://hdl.handle.net/10919/31106.

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Wastewater from the manufacture of propellants typically contains 2,4-dinitrotoluene (DNT), a suspected animal carcinogen. Previous studies have indicated that DNT is aerobically biodegradable. However, inconsistent removal of DNT during aerobic treatment has been observed at a munitions wastewater treatment plant, necessitating the use of activated carbon pre-treatment. The objective of this study was to evaluate the effect of nutrient and cosubstrate amendments on the rate and extent of DNT removal. Addition of ethanol (100-500 mg/l) and phosphate (0.8-3.3 mg/l) significantly accelerated
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Sheikh, Kharisha S. "Kinetics of 2, 4, 6-Trinitrotoluene Reduction by Pseudomonas Putida." Ohio University / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1156790187.

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Book chapters on the topic "2,4,-dinitrotoluene (DNT)"

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Williams, Marc A., and Stephen W. Rice. "Wildlife Toxicity Assessment for 2-Amino-4,6-Dinitrotoluene and 4-Amino-2,6-Dinitrotoluene." In Wildlife Toxicity Assessments for Chemicals of Military Concern. Elsevier, 2015. http://dx.doi.org/10.1016/b978-0-12-800020-5.00016-8.

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CHEN, YUNQING, HAIBO LIU, and X. C. ZHANG. "EXPERIMENTAL AND DENSITY FUNCTIONAL THEORY STUDY ON THz SPECTRA OF 4-NT AND 2, 6-DNT." In Selected Topics in Electronics and Systems. WORLD SCIENTIFIC, 2007. http://dx.doi.org/10.1142/9789812771803_0008.

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Conference papers on the topic "2,4,-dinitrotoluene (DNT)"

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Chen, Yunqing, Haibo Liu, and X. C. Zhang. "THz spectra of 4-NT and 2, 6-DNT." In Defense and Security Symposium, edited by Dwight L. Woolard, R. Jennifer Hwu, Mark J. Rosker, and James O. Jensen. SPIE, 2006. http://dx.doi.org/10.1117/12.666158.

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Chandu, B., M. S. S. Bharati, and S. Venugopal Rao. "AG Nanoparticles Coupled with AG Nanostructures as Efficient SERS Platform for Detection of 2, 4-Dinitrotoluene." In 2017 IEEE Workshop on Recent Advances in Photonics (WRAP). IEEE, 2017. http://dx.doi.org/10.1109/wrap.2017.8468553.

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LeMonte, Joshua, Cynthia L. Price, Thomas A. Douglas, Jennifer M. Seiter, Mark A. Chappell, and Karl J. Indest. "Energetic Compounds (RDX and 2, 4-DNT) are most Vulnerable to Movement Through Discontinuous Permafrost Soils during Initial Freeze-Thaw Events." In Goldschmidt2020. Geochemical Society, 2020. http://dx.doi.org/10.46427/gold2020.1457.

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Reports on the topic "2,4,-dinitrotoluene (DNT)"

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NIOSH skin notation (SK) profile: dinitrotoluene [CAS No. 25321-14-6]; 2,4-dinitrotoluene (2,4-DNT) [CAS No. 121-14-2]; 2,6-dinitrotoluene (2,6-DNT) [CAS No. 606-20-2]. U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, 2011. http://dx.doi.org/10.26616/nioshpub2011138.

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