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Relevant bibliographies by topics / C₂-C₃ alkenes

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Academic literature on the topic 'C₂-C₃ alkenes'

Author: Grafiati

Published: 7 June 2025

Last updated: 2 August 2025

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Journal articles on the topic "C₂-C₃ alkenes"

1

Bower, John F., Timothy P. Aldhous, Raymond W. M. Chung, and Andrew G. Dalling. "Enantioselective Intermolecular Murai-Type Alkene Hydroarylation Reactions." Synthesis 53, no. 17 (2021): 2961–75. http://dx.doi.org/10.1055/s-0040-1720406.

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AbstractStrategies that enable the efficient assembly of complex building blocks from feedstock chemicals are of paramount importance to synthetic chemistry. Building upon the pioneering work of Murai and co-workers in 1993, C–H-activation-based enantioselective hydroarylations of alkenes offer a particularly promising framework for the step- and atom-economical installation of benzylic stereocenters. This short review presents recent intermolecular enantioselective Murai-type alkene hydroarylation methodologies and the mechanisms by which they proceed.1 Introduction2 Enantioselective Hydroary

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Grossi, Vincent, Cristiana Cravo-Laureau, Alain Méou, Danielle Raphel, Frédéric Garzino, and Agnès Hirschler-Réa. "Anaerobic 1-Alkene Metabolism by the Alkane- and Alkene-Degrading Sulfate Reducer Desulfatibacillum aliphaticivorans Strain CV2803T." Applied and Environmental Microbiology 73, no. 24 (2007): 7882–90. http://dx.doi.org/10.1128/aem.01097-07.

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ABSTRACT The alkane- and alkene-degrading, marine sulfate-reducing bacterium Desulfatibacillum aliphaticivorans strain CV2803T, known to oxidize n-alkanes anaerobically by fumarate addition at C-2, was investigated for its 1-alkene metabolism. The total cellular fatty acids of this strain were predominantly C-(even number) (C-even) when it was grown on C-even 1-alkenes and predominantly C-(odd number) (C-odd) when it was grown on C-odd 1-alkenes. Detailed analyses of those fatty acids by gas chromatography-mass spectrometry after 6- to 10-week incubations allowed the identification of saturate

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Maraswami, Manikantha, and Teck-Peng Loh. "Transition-Metal-Catalyzed Alkenyl sp2 C–H Activation: A Short Account." Synthesis 51, no. 05 (2019): 1049–62. http://dx.doi.org/10.1055/s-0037-1611649.

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Alkenes are ubiquitous in Nature and their functionalization continues to attract attention from the scientific community. On the other hand, activation of alkenyl sp2 C–H bonds is challenging due to their chemical properties. In this short account, we elucidate, discuss and describe the utilization of transition-metal catalysts in alkene activation and provide useful strategies to synthesize organic building blocks in an efficient and sustainable manner.1 Introduction2 Breakthrough3 Controlling E/Z, Z/E Selectivity3.1 Esters and Amides as Directing Groups3.2 The Chelation versus Non-Chelation

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Tomita, Ren, Yusuke Yasu, Takashi Koike, and Munetaka Akita. "Direct C–H trifluoromethylation of di- and trisubstituted alkenes by photoredox catalysis." Beilstein Journal of Organic Chemistry 10 (May 12, 2014): 1099–106. http://dx.doi.org/10.3762/bjoc.10.108.

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Background: Trifluoromethylated alkene scaffolds are known as useful structural motifs in pharmaceuticals and agrochemicals as well as functional organic materials. But reported synthetic methods usually require multiple synthetic steps and/or exhibit limitation with respect to access to tri- and tetrasubstituted CF3-alkenes. Thus development of new methodologies for facile construction of Calkenyl–CF3 bonds is highly demanded. Results: The photoredox reaction of alkenes with 5-(trifluoromethyl)dibenzo[b,d]thiophenium tetrafluoroborate, Umemoto’s reagent, as a CF3 source in the presence of [Ru

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Wrackmeyer, Bernd, Khadija Shahid, and Saqib Ali. "1,1-Ethylboration of Alkyn-1-yl- (dichloro)silanes: Alkenes Bearing Dichlorosilyl and Diethylboryl Groups." Zeitschrift für Naturforschung B 60, no. 5 (2005): 590–92. http://dx.doi.org/10.1515/znb-2005-0520.

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The 1,1-ethylboration of dichloro(hexyn-1-yl)silane, Cl2 Si(H)-C≡C-Bu, affords selectively an alkene which is the first example with dialkylboryl and dichlorosilyl groups in cis-positions at the C=C bond. The analogous reaction of dichloro( trimethylsilylethynyl)silane, Cl2(H)Si-C≡C-Si Me3, leads to a 4:1 mixture of alkenes, in one of which the boryl and dichlorosilyl groups are in trans-positions. The alkenes were characterized by a consistent set of NMR data.

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Gu, Zheng-Yang, Yang Wu, Xiaoguang Bao, Ji-Bao Xia, and Feng Jin. "Intermolecular C–H Amidation of Alkenes with Carbon Monoxide and Azides via Tandem Palladium Catalysis." Synthesis 53, no. 18 (2021): 3361–71. http://dx.doi.org/10.1055/a-1401-4486.

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AbstractAn atom- and step-economic intermolecular multi-component palladium-catalyzed C–H amidation of alkenes with carbon monoxide and organic azides has been developed for the synthesis of alkenyl amides. The reaction proceeds efficiently without an ortho-directing group on the alkene substrates. Nontoxic dinitrogen is generated as the sole by-product. Computational studies and control experiments have revealed that the reaction takes place via an unexpected mechanism by tandem palladium catalysis.

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Chae, Eunji, and Sung-Seen Choi. "Influence of Molecular Weight and Temperature on the Pyrolysis Behavior of Polyethylene." Polymers 17, no. 5 (2025): 576. https://doi.org/10.3390/polym17050576.

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The pyrolysis technique is a useful recycling method for waste polyethylene (PE). Various PEs with different molecular weights have been produced and are widely used. The major pyrolysis products of PE include alkadienes (CnH2n−2), alkenes (CnH2n), and alkanes (CnH2n+2). In this study, the differences in pyrolysis behavior of PE based on its molecular weight and the pyrolysis temperature (423–764 °C) were investigated using four types of PEs, with Mw = 2.0 ´ 103, 16.0 ´ 103, 28.3 ´ 103, and 56.8 ´ 103 g/mol. More specifically, the pyrolysis products were compared in terms of their type (alkane

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Sun, Kai, Fengji Ma, Lulu Liu, et al. "Iodine-mediated regioselective C–N and C–I bond formation of alkenes." RSC Advances 5, no. 100 (2015): 82492–95. http://dx.doi.org/10.1039/c5ra14407h.

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Iodine mediated intermolecular C–N and C–I bonds formation of alkenes was realized. A series of alkenes could be converted into the aminoiodination products, which are versatile building blocks in organic synthesis and medicinal chemistry.

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Martin, Alonso David, Jesse Bond, Ruiz Juan Carlos Serrano, and James Dumesic. "Production of liquid hydrocarbon transportation fuels by oligomerization of biomass-derived C9 alkenes." Green Chem 12 (April 26, 2010): 992–99. https://doi.org/10.1039/C001899F.

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A process is described to produce renewable liquid fuels, similar to existing petroleum-derived transportation fuels, through the oligomerization over solid acid catalysts of C<sub>9</sub>-alkenes derived from γ-valerolactone (GVL). Larger, non-terminal alkenes are shown to be less reactive than short chain α-alkenes for oligomerization over solid acid sites, and Amberlyst-70 has been identified to be an active and stable catalyst with sufficient acidity to couple C<sub>9</sub>-alkenes. The inhibiting effect of water on alkene&

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Zhang, Ping, Peng Huo, Xuan Zhang, Qin-Yu Zhu, and Jie Dai. "C–C to CC conversion within a supramolecular framework of tetrathiafulvalene: a confinement effect and an oxygen related dehydrogenation." Chemical Communications 54, no. 53 (2018): 7334–37. http://dx.doi.org/10.1039/c8cc03197e.

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A supramolecular framework with a TTF derivative can activate strong C–H bonds and transform alkanes to alkenes at room temperature under the confinement effect of the framework in the presence of oxygen.

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Dissertations / Theses on the topic "C₂-C₃ alkenes"

1

Wilkinson, Jon N. "Regioselective reactions at a diruthenium centre." Thesis, University of Bristol, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.266954.

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Cavanagh, Craig. "Iron-mediated C-H coupling of arylsulfides and simple terminal alkenes." Thesis, University of Manchester, 2016. https://www.research.manchester.ac.uk/portal/en/theses/ironmediated-ch-coupling-of-arylsulfides-and-simple-terminal-alkenes(c9b77782-2d78-468e-a6b2-cf5bb5b63243).html.

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The use of directing groups in C-H functionalisation reactions provides a means to control the regioselectivity of such processes. Previous work in the Procter group reported the sulfoxide-directed metal-free C-H alkylation of arenes with organosilane nucleophiles. Attempts to expand this work by carrying out a similar process directly from the sulfide oxidation level, utilising an Fe(III) oxidant, a diarylsulfide and an alkene are discussed herein. During these investigations, it was discovered that the use of simple, unfunctionalised olefins selectively gave linear products of formal chloroa

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Okumura, Shogo. "Studies on Site-selective C-H Alkylation of Arenes with Alkenes." Kyoto University, 2019. http://hdl.handle.net/2433/242514.

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Reddy, S. R. "Enantioselective synthesis of bioactive molecules via hydrolytic kinetic resolution of alkoxy epoxides, dihydroxylation of alkenes and CuCN-mediated annulations in C-C, C-O bond formation." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2012. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/1910.

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Pawlikowski, Andrew V. "Developments in late metal-mediated C-N bond forming reactions /." Thesis, Connect to this title online; UW restricted, 2006. http://hdl.handle.net/1773/8489.

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McGoldrick, Trevor A. "C-S lyase-mediated toxicity in primary cultures of proximal tubular cells." Thesis, University of Aberdeen, 2000. http://digitool.abdn.ac.uk/R?func=search-advanced-go&find_code1=WSN&request1=AAIU602010.

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Halogenated alkenes are a group of commercially important chemicals. For example tetrafluoroethylene is the monomer used for the production of poly- tetrafluoroethylene, hexachloro-1:3-butadiene is a by-product from the manufacture of chlorinated solvents and perchloroethylene is widely used as a dry cleaning agent. Due to possible exposure to haloalkenes and the nephrotoxicity observed in animal studies, concern has been expressed for the potential of these compounds to cause toxicity to man. Animal studies have shown that these compounds undergo inter-organ metabolism and are bioactivated by

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Ma, Wenbo. "Transition Metal-Catalyzed C-H Functionalization for Sustainable Syntheses of Alkenes and Heterocycles." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2015. http://hdl.handle.net/11858/00-1735-0000-0022-5FDF-4.

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Fosu, Stacy C. "Functionalization of Arenes, Amines, Alkenes, and Alkynes Mediated by Radical Pathways." The Ohio State University, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=osu1555514456659022.

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Abed, Ali Abdine Racha. "Formation de liaisons C-C et C-hétéroatome par catalyse au cuivre ou en présence de complexes de ruthénium." Thesis, Montpellier, Ecole nationale supérieure de chimie, 2019. http://www.theses.fr/2019ENCM0014.

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Cette thèse se situe dans le cadre général de la recherche de nouvelles méthodes de synthèse peu couteuses et éco-compatibles permettant de valoriser certaines molécules en accédant à des composés intéressants dans plusieurs domaines comme la chimie des matériaux, pharmaceutique et organique. L’objectif consiste à créer des nouvelles liaisons C-C et C-hétéroatome sous un contrôle de sélectivité par catalyse avec des métaux de transition.Dans une première partie, une difonctionnalisation des alcènes a été réalisée par catalyse au cuivre pour aboutir à l’oxazolidinone qui comporte un squelette i

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Boer, Johannes Wietse de. "cis-Dihydroxylation and epoxidation of alkenes by manganese catalysts selectivity, reactivity and mechanism /." [S.l. : [Groningen : s.n.] ; University Library Groningen] [Host], 2008. http://irs.ub.rug.nl/ppn/.

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Books on the topic "C₂-C₃ alkenes"

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Pieter, Reimund. Chirale Homoenolat-Äquivalente - Untersuchungen zur asymmetrischen C-C-Verknüpfung mit metallierten N-, O- und S-(2-Alkenyl)-Derivaten [S-Alkenyl-Derivaten]. [s.n.], 1987.

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Science of synthesis: C-1 building blocks in organic synthesis. Georg Thieme Verlag KG, 2014.

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(Editor), Yavuz Imamogammalu, Birgül Zümreogammalu-Karan (Editor), and Allan J. Amass (Editor), eds. Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization (NATO Science Series C:). Springer, 1990.

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4

Taber, Douglass F. Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.001.0001.

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Organic synthesis is a vibrant and rapidly evolving field; we can now cyclize amines directly onto alkenes. Like its predecessors, this reference leads readers quickly to the field's more important recent developments. Two years of Douglass F. Taber's popular weekly online column, "Organic Chemistry Highlights", as featured on the organic-chemistry.org website, are consolidated here, with cumulative indices of all four volumes in this series. Important topics that are covered range from powerful new methods for C-C bond construction to asymmetric organocatalysis and direct C-H functionalizatio

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Taber, Douglass F., and Tristan Lambert. Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.001.0001.

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Organic synthesis is a vibrant and rapidly evolving field; chemists can now cyclize alkenes directly onto enones. Like the first five books in this series, Organic Synthesis: State of the Art 2013-2015 will lead readers quickly to the most important recent developments in a research area. This series offers chemists a way to stay abreast of what's new and exciting in organic synthesis. The cumulative reaction/transformation index of 2013-2015 outlines all significant new organic transformations over the past twelve years. Future volumes will continue to come out every two years. The 2013-2015

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Taber, Douglass. Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.001.0001.

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Organic synthesis is a vibrant and rapidly evolving field; we can now cyclize amines directly onto alkenes. Like the first two books in this series, Organic Synthesis: State of the Art 2003-2005 and Organic Synthesis: State of the Art 2005-2007, this reference leads readers quickly to the most important recent developments. Two years of Taber's popular weekly online column, "Organic Chemistry Highlights", as featured on the organic-chemistry.org website, are consolidated here, with cumulative indices of all three volumes in this series. Important topics that are covered range from powerful new

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Book chapters on the topic "C₂-C₃ alkenes"

1

Hintermann, Lukas. "Recent Developments in Metal-Catalyzed Additions of Oxygen Nucleophiles to Alkenes and Alkynes." In C-X Bond Formation. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-12073-2_6.

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Jean-Gérard, Ludivine, Rodolphe Jazzar, and Olivier Baudoin. "CH Bond Alkylation (Including Hydroarylation of Alkenes)." In Metal-Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527655588.ch19.

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Dérien, Sylvie. "C–C Bond Formation on Activation of Alkynes and Alkenes with (C5R5)Ru Catalysts." In Ruthenium in Catalysis. Springer International Publishing, 2014. http://dx.doi.org/10.1007/3418_2014_82.

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Bruneau, Christian, and Pierre H. Dixneuf. "Ruthenium(II)-Catalysed Functionalisation of C–H Bonds with Alkenes: Alkenylation versus Alkylation." In C-H Bond Activation and Catalytic Functionalization I. Springer International Publishing, 2015. http://dx.doi.org/10.1007/3418_2015_134.

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Bruneau, Christian, and Pierre H. Dixneuf. "Erratum to: Ruthenium(II)-Catalysed Functionalisation of C–H Bonds with Alkenes: Alkenylation versus Alkylation." In C-H Bond Activation and Catalytic Functionalization I. Springer International Publishing, 2015. http://dx.doi.org/10.1007/3418_2015_150.

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Ishiyama, Tatsuo, and Norio Miyaura. "Metal-Catalyzed Borylation of CH and CHalogen Bonds of Alkanes, Alkenes, and Arenes for the Synthesis of Boronic Esters." In Boronic Acids. Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527639328.ch2.

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Westwell, Andrew D., and Jonathan M. J. Williams. "Summary of alkene syntheses." In Preparation of Alkenes. Oxford University PressOxford, 1996. http://dx.doi.org/10.1093/oso/9780198557951.003.0009.

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Abstract Each previous chapter in this book has been devoted to particular methods for the synthesis of alkenes, and has included experimental protocols which provide details for the preparation of alkenes. These chapters have broadly been arranged into the types of starting material which are required. There have been alkene syntheses from two components, from single C-C bonds, from triple C-C bonds, and from other alkenes.

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Ho, C. Y., and D. Raja. "47.1.9 Alkene Hydrovinylation, Hydroalkenylation, and Cycloisomerization." In Knowledge Updates 2023/2. Georg Thieme Verlag KG, 2024. http://dx.doi.org/10.1055/sos-sd-147-00289.

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AbstractThis review on homogeneous C-C bond-forming reactions to form alkenes focuses on hydrovinylation, hydroalkenylation, and cycloisomerization, and covers the literature published from ca. 1990 to early 2020. The account is arranged by reaction type, and then further categorized according to the alkene donors and alkene acceptors employed. This chapter highlights the potential of using well-controlled insertion catalysts in the green and catalytic synthesis of higher substituted alkenes. The methods described avoid the stoichiometric use of alkenyl halides and metallic reagents and serve

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Kakiuchi, F., and T. Kochi. "7 Alkene/Alkene Cross-Dehydrogenative Coupling for C(sp2)—C(sp2) Bond Formation." In Cross-Dehydrogenative Coupling. Georg Thieme Verlag KG, 2023. http://dx.doi.org/10.1055/sos-sd-240-00034.

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AbstractConjugated dienes are not only synthetically versatile but are also often found in natural products and bioactive compounds, and various methods have been developed for the stereo- and regioselective synthesis of 1,3-diene structures. Recently, much attention has been paid to transition-metal-catalyzed cross-dehydrogenative coupling (CDC) reactions between alkenes, because they enable the synthesis of 1,3-dienes in few steps from readily available molecules, thus providing atom-economical, environmentally benign synthetic methods. This chapter briefly describes representative examples

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Wang, P. S., M. Sayed, and L. Z. Gong. "47.1.2.5 Allylic C—H Functionalization." In Knowledge Updates 2023/1. Georg Thieme Verlag KG, 2023. http://dx.doi.org/10.1055/sos-sd-147-00159.

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AbstractThe direct functionalization of allylic C(sp3)—H bonds allows alkenes to serve as versatile allylating agents capable of undergoing diverse bond-forming reactions, thereby enabling rapid access to alkene-bearing structural complexity from readily accessible feedstocks. In this review, representative reports on allylic C—H functionalization reactions published since 2013 are summarized by describing six types of allylic C—H activation modes: C—H insertion, hydrogen-atom transfer, concerted metalation/deprotonation (CMD), concerted proton and two-electron transfer (CPTET), base-mediated

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Conference papers on the topic "C₂-C₃ alkenes"

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Tagmatarchis, Nikos. "Photosensitized oxygenation of alkenes in the presence of bisazafullerene (C[sub 59]N)[sub 2] and hydroazafullerene C[sub 59]HN." In NANONETWORK MATERIALS: Fullerenes, Nanotubes, and Related Systems. AIP, 2001. http://dx.doi.org/10.1063/1.1420140.

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Thiemann, Thies, and Nuha al Soom. "NaBH4, CH3CO2H, Pd/C as a Reagent System to Hydrogenate Activated Alkenes Without O-or N-Debenzylation." In The 19th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2015. http://dx.doi.org/10.3390/ecsoc-19-a036.

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Reihani, Amin, Brent Patterson, John Hoard, et al. "Rapidly Pulsed Reductants for Diesel NOx Reduction With Lean NOx Traps: Comparison of Alkanes and Alkenes as the Reducing Agent." In ASME 2016 Internal Combustion Engine Division Fall Technical Conference. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/icef2016-9475.

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Lean NOx Traps (LNTs) are often used to reduce NOx on smaller diesel passenger cars where urea-based Selective Catalytic Reduction (SCR) systems may be difficult to package. However, the performance of LNTs at temperatures above 400°C needs to be improved. The use of Rapidly Pulsed Reductants (RPR) is a process in which hydrocarbons are injected in rapid pulses ahead of the LNT in order to improve its performance at higher temperatures and space velocities. This approach was developed by Toyota and was originally called Di-Air (Diesel NOx aftertreatment by Adsorbed Intermediate Reductants) [1]

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Al Shoaibi, Ahmed, and Anthony M. Dean. "Kinetic Analysis of C4 Alkane and Alkene Pyrolysis: Implications for SOFC Operation." In ASME 2008 6th International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2008. http://dx.doi.org/10.1115/fuelcell2008-65033.

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Pyrolysis experiments of isobutane, isobutylene, and 1-butene were performed over a temperature range of 550–750 °C and a pressure of ∼ 0.8 atm. The residence time was ∼ 5 s. The fuel conversion and product selectivity were analyzed at these temperatures. The pyrolysis experiments were performed to simulate the gas phase chemistry that occurs in the anode channel of a solid-oxide fuel cell. The experimental results confirm that molecular structure has a substantial impact on pyrolysis kinetics. The experimental data show considerable amounts of C5 and higher species (∼2.8 mole % with isobutane

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Shihui Wu, Lianhe Shu, and Kangnian Fan. "ENE reaction of fullerene C/sub 60/ and 4-allylanisole introduction of alkene to buckminsterfullerene." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835567.

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Patil, Vikram, and Chad B. O'Neal. "Adhesive Strength Characterization of CYTOP™: Low Temperature Wafer-Level Packaging." In ASME 2006 International Mechanical Engineering Congress and Exposition. ASMEDC, 2006. http://dx.doi.org/10.1115/imece2006-14791.

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This study describes a wafer bonding technique using CYTOP™ inking method for the high volume packaging of micro-electro mechanical system (MEMS) devices. CYTOP™ is a class of perfluoro (alkenyl vinyl ether) polymer which is obtained by cyclopolymerization of perfluoro. The CYTOP™ adhesive bonding requires much lower temperature (150 to 200° C) compared to other bonding techniques such as soldering (&gt; 250° C) or anodic (~350° C) bonding. The lower temperatures involved in the process reduce the risk of thermal damage to temperature sensitive devices during packaging. The described bondi

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