Relevant bibliographies by topics / C-H Activation/Functionalization

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters

Academic literature on the topic 'C-H Activation/Functionalization'

Author: Grafiati
Published: 4 June 2021
Last updated: 1 February 2022

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Journal articles on the topic "C-H Activation/Functionalization"

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Muñoz-Molina, José María, Tomás R. Belderrain, and Pedro J. Pérez. "Recent Advances in Copper-Catalyzed Radical C–H Bond Activation Using N–F Reagents." Synthesis 53, no. 01 (2020): 51–64. http://dx.doi.org/10.1055/s-0040-1707234.

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This Short Review is aimed at giving an update in the area of copper-catalyzed C–H functionalization involving nitrogen-centered radicals generated from substrates containing N–F bonds. These processes include intermolecular Csp3–H bond functionalization, remote Csp3–H bond functionalization via intramolecular hydrogen atom transfer (HAT), and Csp2–H bond functionalization, which might be of potential use in industrial applications in the future.1 Introduction2 Intermolecular Csp3–H Functionalization3 Remote Csp3–H Functionalization4 Csp2–H Functionalization5 Conclusion
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Senge, Mathias O., and Nitika Grover. "Synthetic Advances in the C–H Activation of Rigid Scaffold Molecules." Synthesis 52, no. 22 (2020): 3295–325. http://dx.doi.org/10.1055/s-0040-1707884.

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The remarkable structural and electronic properties of rigid non-conjugated hydrocarbons afford attractive opportunities to design molecular building blocks for both medicinal and material applications. The bridgehead positions provide the possibility to append diverse functional groups at specific angles and in specific orientations. The current review summarizes the synthetic development in CH functionalization of three rigid scaffolds namely: (a) cubane, (b) bicyclo[1.1.1]pentane (BCP), (c) adamantane.1 Introduction2 Cubane2.1 Cubane Synthesis2.2 Cubane Functionalization3 Bicyclo[1.1.1]pent
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Sarpong, Richmond. "C–H Functionalization/activation in organic synthesis." Beilstein Journal of Organic Chemistry 12 (November 3, 2016): 2315–16. http://dx.doi.org/10.3762/bjoc.12.224.

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Qiu, Guanyinsheng, and Jie Wu. "Transition metal-catalyzed direct remote C–H functionalization of alkyl groups via C(sp3)–H bond activation." Organic Chemistry Frontiers 2, no. 2 (2015): 169–78. http://dx.doi.org/10.1039/c4qo00207e.

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This review is focused on the recent advances in the transition metal-catalyzed direct remote C–H-functionalization of alkyl groups via C(sp<sup>3</sup>)–H bond activation. In general, carboxamide/ester-chelated β-functionalization reactions are summarized.
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Wang, Weixiang, Tianqi Liu, Chang-Hua Ding, and Bin Xu. "C(sp3)–H functionalization with isocyanides." Organic Chemistry Frontiers 8, no. 13 (2021): 3525–42. http://dx.doi.org/10.1039/d1qo00153a.

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This review highlights the state-of-the-art advances in C(sp<sup>3</sup>)–H functionalization involving isocyanides through the synergistic combination of isocyanide insertion and C(sp<sup>3</sup>)–H bond activation.
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Shi, Z., S. Yang, B. Li, and X. Wan. "C-H Functionalization via C-H Activation and C-C Bond Formation with Arylsilanes." Synfacts 2007, no. 7 (2007): 0751. http://dx.doi.org/10.1055/s-2007-968643.

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Liu, Yichang, Hong Yi, and Aiwen Lei. "Oxidation-Induced C-H Functionalization: A Formal Way for C-H Activation." Chinese Journal of Chemistry 36, no. 8 (2018): 692–97. http://dx.doi.org/10.1002/cjoc.201800106.

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ZHAO, Mengdi, and Wenjun LU. "Alkanes Functionalization via C―H Activation." Acta Physico-Chimica Sinica 35, no. 9 (2019): 977–88. http://dx.doi.org/10.3866/pku.whxb201811045.

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Roudesly, Fares, Julie Oble, and Giovanni Poli. "Metal-catalyzed C H activation/functionalization: The fundamentals." Journal of Molecular Catalysis A: Chemical 426 (January 2017): 275–96. http://dx.doi.org/10.1016/j.molcata.2016.06.020.

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Sinha, Soumya Kumar, Trisha Bhattacharya, and Debabrata Maiti. "Role of hexafluoroisopropanol in C–H activation." Reaction Chemistry & Engineering 4, no. 2 (2019): 244–53. http://dx.doi.org/10.1039/c8re00225h.

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HFIP has developed immense importance in the C–H functionalization methodology. Both the reactivity and selectivity have been vastly improved using HFIP whose H-bonding to the substrate facilitates and accelerates C–H activation. This review summarizes the chronological development of the evolution of HFIP in C–H activation along with important mechanistic details.
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Dissertations / Theses on the topic "C-H Activation/Functionalization"

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Devaraj, Karthik. "Ruthenium-catalyzed C-H Functionalization of (Hetero)arenes." Doctoral thesis, Uppsala universitet, Organisk kemi, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-310998.

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This thesis concerned about the Ru-catalyzed C-H functionalizations on the synthesis of 2-arylindole unit, silylation of heteroarenes and preparation of aryne precursor. In the first project, we developed the Ru-catalyzed C2-H arylation of N-(2-pyrimidyl) indoles and pyrroles with nucleophilic arylboronic acids under oxidative conditions. Wide variety of arylboronic acids afforded the desired product in excellent yield regardless of the substituents or functional group electronic nature. Electron-rich heteroarenes are well suited for this method than electron-poor heteroarenes. Halides such as
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Pahls, Dale R. "Pathways for C—H Activation and Functionalization by Group 9 Metals." Thesis, University of North Texas, 2015. https://digital.library.unt.edu/ark:/67531/metadc801909/.

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As fossil fuel resources become more and more scarce, attention has been turned to alternative sources of fuels and energy. One promising prospect is the conversion of methane (natural gas) to methanol, which requires an initial activation of a C-H bond and subsequent formation of a C-O bond. The most well studied methodologies for both C-H activation and C-O bond formation involve oxidation of the metal center. Metal complexes with facile access to oxidation states separated by four charge units, required for two subsequent oxidations, are rare. Non-oxidative methods to perform C-H bond activ
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Li, Bin. "Ruthenium(II) catalyzed C-H bond functionalization and hydrosilylation reactions." Thesis, Rennes 1, 2013. http://www.theses.fr/2013REN1S114.

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Dans ce travail de recherche, la synthèse de complexes de ruthénium cyclometallés a été effectuée à partir d'imines, 2-phénylpyridine, 2-phényloxazoline, phénylpyrazole, et benzo[h]quinoline par réaction avec [RuCl2(p-cymène)]2 et KOAc via une activation de liaison sp2 C-H. Le système [RuCl2(p-cymène)]2/KOAc/PPh3 est un catalyseur efficace pour réaliser la diarylation d'imines et de 2-phénylpyridine dans l'eau, solvant qui donne de meilleures activités que les solvants organiques. Des amines encombrées ont été préparées par une séquence catalytique activation C-H/arylation/ hydrosilylation d'i
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Mei, Ruhuai. "Ruthenium- and Cobalt-Catalyzed Chelation-Assisted C–H Functionalization." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2017. http://hdl.handle.net/11858/00-1735-0000-0023-3EFB-C.

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Fallon, Brendan. "Cobalt-catalyzed bond activation : C-H functionalization, hydrosilylation and coupling reactions." Thesis, Paris 6, 2016. http://www.theses.fr/2016PA066411/document.

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Dans cette thèse, nous nous concentrerons principalement sur l’utilisation de complexes basse-valence de cobalt bien définis de la famille des RCo(PMe3)4 pour l’activation de divers types de liaisons (C–H, Si–H, C–X). Notre but était de développer un système compétitif par rapport au système bimétallique de Yoshikai, mais aussi par rapport aux systèmes onéreux à base de rhodium. Nous avons démontré avec succès que les complexes isolés Co(PMe3)4 et HCo(PMe3)4 étaient des catalyseurs efficaces pour l’hydroarylation de différents alcynes et alcènes via une activation de liaisons C–H. De plus, nou
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Sun, Zhicheng. "Computational Study of C−H/C−C Activation and Functionalization with Nitrene, Carbene and Related Complexes." Thesis, University of North Texas, 2020. https://digital.library.unt.edu/ark:/67531/metadc1752352/.

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This dissertation involves inorganic/organometallic catalysis models, in particular the functionalization of carbon-hydrogen and carbon-carbon bonds. Computational methods have been utilized to better understand the factors affecting the kinetics and thermodynamics of C−H and C−C bond activation/functionalization in this dissertation. Chapter 2 investigates methane C−H activation with a diiminopyridine nitride/nitridyl complex of 3d transition metals and main group elements via three competing pathways: 1,2-addition/[2 + 2] addition, insertion and H-atom abstraction/proton coupled electron t
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Kaplaneris, Nikolaos [Verfasser]. "Resource-Economical C–H Activation for Late-Stage Functionalization / Nikolaos Kaplaneris." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2021. http://d-nb.info/1237128854/34.

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Zhang, Zhuan. "Late Stage Modifications of Phosphines using Transition-Metal-Catalyzed C–H Bond Functionalization." Thesis, Rennes, Ecole nationale supérieure de chimie, 2020. http://www.theses.fr/2020ENCR0067.

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L'objectif principal de cette thèse de doctorat porte sur la préparation de phosphines polyfonctionnelles par diversification tardive de ligands commerciaux. Nous avons développé l'alkylation la liaison C–H en position ortho' des biarylphosphines catalysée par le rhodium(I). Cette nouvelle méthodologie permet d'accéder facilement à une vaste bibliothèque de phosphines multifonctionnelles. Certains de ces ligands modifiés ont surpassé les phosphines disponibles dans le commerce dans la carboxylation des bromures d'aryle catalysée par le palladium avec du dioxyde de carbone en présence d'un cata
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Planas, Fàbrega Oriol. "Cobalt-catalyzed C-H functionalization: from mechanistic studies to synthetic methodologies." Doctoral thesis, Universitat de Girona, 2018. http://hdl.handle.net/10803/482111.

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This Ph.D. dissertation describes the synthesis and characterization of bench-top stable aryl-Co(III) organometallic species using commercially available cobalt(II) salts and a macrocyclic model substrate. Special attention will be paid to the C-H activation step to elucidate the operating mechanism in the high-valent cobalt-mediated cleavage of C-H bonds. Mechanistic experiments, as well as spectroscopic characterization of intermediates will be useful to give light to a basic underdeveloped step in cobalt C-H activation methodologies. In addition, reactivity of the isolated aryl-Co(III) inte
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Gustafson, Samantha Jane. "Computational Studies of Alkane C-H Functionalization by Main-Group Metals." BYU ScholarsArchive, 2016. https://scholarsarchive.byu.edu/etd/5992.

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The most efficient homogeneous catalysts for hydroxylation of light alkanes utilize transition metals in superacid solvent and operate by tandem electrophilic C-H activation/metal-alkyl (M-R) functionalization. An emerging alternative strategy to transition metals is the use of high-oxidation state main-group metals (e.g. TlIII, PbIV, IIII) that hydroxylate light alkanes. This dissertation reports density-functional theory calculations that reveal the mechanisms, reactivity, and selectivity of TlIII promoted alkane C-H functionalization in trifluoroacetic acid and TlIII-dialkyl functionalizati
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Books on the topic "C-H Activation/Functionalization"

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Goldberg, Karen I., and Alan S. Goldman, eds. Activation and Functionalization of C—H Bonds. American Chemical Society, 2004. http://dx.doi.org/10.1021/bk-2004-0885.

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Dixneuf, Pierre H., and Henri Doucet, eds. C-H Bond Activation and Catalytic Functionalization I. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-24630-7.

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Dixneuf, Pierre H., and Henri Doucet, eds. C-H Bond Activation and Catalytic Functionalization II. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-29319-6.

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Activation and functionalization of C-H bonds. American Chemical Society, 2004.

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Dixneuf, Pierre H., and Henri Doucet. C-H Bond Activation and Catalytic Functionalization II. Springer, 2018.

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Dixneuf, Pierre H., and Henri Doucet. C-H Bond Activation and Catalytic Functionalization I. Springer, 2018.

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(Editor), Karen I. Goldberg, and Alan S. Goldman (Editor), eds. Activation and Functionalization of C-H Bonds (Acs Symposium Series, 885). An American Chemical Society Publication, 2004.

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Book chapters on the topic "C-H Activation/Functionalization"

1

Liu, Guosheng, and Yichen Wu. "Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins." In C-H Activation. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/128_2009_16.

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Davies, Huw M. L., and Allison R. Dick. "Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion." In C-H Activation. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/128_2009_11.

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Martins, Andrew, Brian Mariampillai, and Mark Lautens. "Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization." In C-H Activation. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/128_2009_13.

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Beck, Elizabeth M., and Matthew J. Gaunt. "Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus." In C-H Activation. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/128_2009_15.

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Goldsmith, Christian R. "Regioselectivity of Non-heme Iron Catalysts for CH Activation." In Alkane Functionalization. John Wiley & Sons, Ltd, 2018. http://dx.doi.org/10.1002/9781119379256.ch11.

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Li, Jie, Suman De Sarkar, and Lutz Ackermann. "meta- and para-Selective C–H Functionalization by C–H Activation." In C-H Bond Activation and Catalytic Functionalization I. Springer International Publishing, 2015. http://dx.doi.org/10.1007/3418_2015_130.

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Bruneau, Christian, and Mathieu Achard. "Alkane-Related CH Bond Activation and Functionalization of Aliphatic Amines." In Alkane Functionalization. John Wiley & Sons, Ltd, 2018. http://dx.doi.org/10.1002/9781119379256.ch27.

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Li, Bi-Jie, and Zhang-Jie Shi. "Homogeneous Transition-Metal-Catalyzed C-H Bond Functionalization." In Homogeneous Catalysis for Unreactive Bond Activation. John Wiley & Sons, Inc., 2014. http://dx.doi.org/10.1002/9781118788981.ch6.

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Dana, Suman, M. Ramu Yadav, and Akhila K. Sahoo. "Ruthenium-Catalyzed C−N and C−O Bond-Forming Processes from C−H Bond Functionalization." In C-H Bond Activation and Catalytic Functionalization I. Springer International Publishing, 2015. http://dx.doi.org/10.1007/3418_2015_126.

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Wencel-Delord, Joanna, Frederic W. Patureau, and Frank Glorius. "Rh(III)- and Ir(III)-Catalyzed C–C Bond Cross Couplings from C–H Bonds." In C-H Bond Activation and Catalytic Functionalization I. Springer International Publishing, 2015. http://dx.doi.org/10.1007/3418_2015_140.

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