Academic literature on the topic 'Catalysis of metal compounds'

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Journal articles on the topic "Catalysis of metal compounds"

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Mamedova, Shafa Agаеvna. "METAL COMPLEX CATALYSIS." Globus 7, no. 5(62) (2021): 31–33. http://dx.doi.org/10.52013/2658-5197-62-5-7.

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Complexes of transition metals with chiral ligands are considered as catalysts. Among metal-containing organic complexes with semiconducting properties, compounds of the porphin series occupy a special place in electrocatalytic studies. The properties of the porphyrin macrocycle, their role in catalysis, and the influence of the nature of the metal on the catalytic properties of the complex are considered.
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Baráth, Eszter. "Selective Reduction of Carbonyl Compounds via (Asymmetric) Transfer Hydrogenation on Heterogeneous Catalysts." Synthesis 52, no. 04 (2020): 504–20. http://dx.doi.org/10.1055/s-0039-1691542.

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Based on the ever-increasing demand for optically pure compounds, the development of efficient methods to produce such products is very important. Homogeneous asymmetric catalysis occupies a prominent position in the ranking of chemical transformations, with transition metals coordinated to chiral ligands being applied extensively for this purpose. However, heterogeneous catalysts have the ability to further extend the field of asymmetric transformations, because of their beneficial properties such as high stability, ease of separation and regeneration, and the possibility to apply them in con
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Lukey, CA, MA Long, and JL Garnett. "Aromatic Hydrogen Isotope Exchange Reactions Catalyzed by Iridium Complexes in Aqueous Solution." Australian Journal of Chemistry 48, no. 1 (1995): 79. http://dx.doi.org/10.1071/ch9950079.

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Sodium hexachloroiridate (III) and sodium hexachloroiridate (IV) have been used as homogeneous catalysts for hydrogen isotope exchange between benzenoid compounds and water. The ideal solvent consisted of 50 mole % acetic acid/water, and the optimum temperature was found to be 160°C. Under these conditions the rate of incorporation of deuterium into benzene was significant (typically 15% D in 6 h), and reduction to iridium metal was minimized. The active catalytic species was identified as a solvated iridium(III) species, which is also postulated to be the active catalyst in solutions containi
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Baird, Michael C. "Catalysis by organotransition metal compounds: Synergism between the pure and the applied1." Canadian Journal of Chemistry 81, no. 4 (2003): 330–37. http://dx.doi.org/10.1139/v03-065.

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The modern era of transition-metal-catalyzed polymerization of alkenes began with the Nobel Prize winning work of Ziegler and Natta in the 1950s, but the field has exploded since the mid-1980s and anticipated applications of organometallic catalysts are being spectacularly realized. Our research in metal-catalyzed alkene polymerization began about ten years ago with an investigation of the catalytic applications of half-sandwich complexes of the Group 4 metals, and this lecture will describe our efforts to find both better initiators to make known commercial polymers and new initiators to make
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Melián-Rodríguez, Saravanamurugan, Meier, Kegnæs, and Riisager. "Ru-Catalyzed Oxidative Cleavage of Guaiacyl Glycerol--Guaiacyl Ether-a Representative -O-4 Lignin Model Compound." Catalysts 9, no. 10 (2019): 832. http://dx.doi.org/10.3390/catal9100832.

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The introduction of efficient and selective catalytic methods for aerobic oxidation of lignin and lignin model compounds to aromatics can extend the role of lignin applications in biorefineries. The current study focussed on the catalytic oxidative transformation of guaiacyl glycerol--guaiacyl ether (GGGE)–a -O-4 lignin model compound to produce basic aromatic compounds (guaiacol, vanillin and vanillic acid) using metal-supported catalysts. Ru/Al2O3, prepared with ruthenium(IV) oxide hydrate, showed the highest yields of the desired products (60%) in acetonitrile in a batch reactor at 160 C an
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Yates, D. J. C., S. K. Behal, and B. H. Kear. "Studies of reactions between gaseous organo-silicon compounds and metal surfaces." Journal of Materials Research 3, no. 4 (1988): 714–22. http://dx.doi.org/10.1557/jmr.1988.0714.

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A procedure for modifying the surface composition of catalytically active metals with silicon-containing gaseous reactants has been developed. This new gas-solid reaction method is unique in that it can be used for the in situ synthesis of catalytically interesting materials, which cannot be done by conventional solid-solid reaction techniques. Using an oxygen-free silicon compound (e.g., hexamethyldisilazane, HMDS), the metals studied fall into two categories: those that involve reaction followed by diffusion, and those that exhibit surface reaction only. The first group, consisting of the me
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Xue, Zhong, Zhang та Xu. "Performance of Catalytic Fast Pyrolysis using a γ-Al2O3 Catalyst with Compound Modification of ZrO2 and CeO2". Catalysts 9, № 10 (2019): 849. http://dx.doi.org/10.3390/catal9100849.

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To investigate the catalytic pyrolysis performance of complex metal oxide catalysts for biomass, γ-Al2O3 was prepared through the precipitation method, and then ZrO2 and γ-Al2O3 were blended in the proportion of 2:8 using the co-precipitation method. Next, CeO2 was loaded on the surface of the catalyst for further modification. The three catalysts, A, ZA and CZA, were obtained. The specific surface and acidity of the catalysts were characterized by nitrogen adsorption–desorption and NH3-Temperature Programmed Desorption (NH3-TPD) respectively. The catalytic pyrolysis performance of catalysts f
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Saeid, Soudabeh, Matilda Kråkström, Pasi Tolvanen, et al. "Synthesis and Characterization of Metal Modified Catalysts for Decomposition of Ibuprofen from Aqueous Solutions." Catalysts 10, no. 7 (2020): 786. http://dx.doi.org/10.3390/catal10070786.

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The presence of pharmaceuticals in surface water, drinking water, and wastewater has attracted significant concern because of the non-biodegradability, resistance, and toxicity of pharmaceutical compounds. The catalytic ozonation of an anti-inflammatory pharmaceutical, ibuprofen was investigated in this work. The reaction mixture was analyzed and measured by high-performance liquid chromatography (HPLC). Liquid chromatography-mass spectrometry (LC-MS) was used for the quantification of by-products during the catalytic ozonation process. Ibuprofen was degraded by ozonation under optimized condi
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Qiu, Jikuan, Yue Zhao, Yuling Zhao, et al. "Cu(I)/Ionic Liquids Promote the Conversion of Carbon Dioxide into Oxazolidinones at Room Temperature." Molecules 24, no. 7 (2019): 1241. http://dx.doi.org/10.3390/molecules24071241.

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Recently, the efficient chemical fixation of carbon dioxide (CO2) into high value chemicals without using noble metal catalysts has become extremely appealing from the viewpoint of sustainable chemistry. In this work, a one-pot three component reaction of propargylic alcohols, anines and CO2 that can proceed in an atom economy and environmentally benign manner by combination of CuI and tetrabutylphosphonium imidazol ([P4444][Im]) as a catalyst was described. Catalysis studies indicate that this catalytic system is an effective catalyst for the conversion of CO2 into oxazolidinones at room temp
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Shul’pin, Georgiy B., and Lidia S. Shul’pina. "Oxidation of Organic Compounds with Peroxides Catalyzed by Polynuclear Metal Compounds." Catalysts 11, no. 2 (2021): 186. http://dx.doi.org/10.3390/catal11020186.

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The review describes articles that provide data on the synthesis and study of the properties of catalysts for the oxidation of alkanes, olefins, and alcohols. These catalysts are polynuclear complexes of iron, copper, osmium, nickel, manganese, cobalt, vanadium. Such complexes for example are: [Fe2(HPTB)(m-OH)(NO3)2](NO3)2·CH3OH·2H2O, where HPTB-¼N,N,N0,N0-tetrakis(2-benzimidazolylmethyl)-2-hydroxo-1,3-diaminopropane; complex [(PhSiO1,5)6]2[CuO]4[NaO0.5]4[dppmO2]2, where dppm-1,1-bis(diphenylphosphino)methane; (2,3-η-1,4-diphenylbut-2-en-1,4-dione)undecacarbonyl triangulotriosmium; phenylsilse
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Dissertations / Theses on the topic "Catalysis of metal compounds"

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Illesinghe, Jayamini P. M. "Synthesis and use of nitrogen heterocycles in metal mediated reactions." Monash University, School of Chemistry, 2004. http://arrow.monash.edu.au/hdl/1959.1/9637.

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Van, Der Waals Dominic. "Atom economical and environmentally benign metal catalysed synthesis." Thesis, University of Bath, 2014. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.636541.

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The use of inexpensive metal catalysts for a range of acylation reactions including the activation of anhydrides and the aminolysis of esters. Discussion on the use of a heterogeneous copper catalyst for teh reduction of a range of organic functional groups and its use in amination of nitriles.
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Julius, Gerrit Richard. "New transition metal carbene complexes for application in homogeneous catalysis /." Link to the online version, 2005. http://hdl.handle.net/10019/1063.

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Lo, Kar-yan. "Gold catalysis stereoselective synthesis of propargylamines and axially chiral allenes, and application on natural product modifications /." Click to view the E-thesis via HKUTO, 2009. http://sunzi.lib.hku.hk/hkuto/record/B41758122.

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Gasperini, Danila. "Design and study of novel gold complexes for efficient catalytic process towards the activation of alkynes." Thesis, University of St Andrews, 2018. http://hdl.handle.net/10023/14247.

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Gold has emerged as valuable tool for chemists. The physico-chemical properties of the metal centre make it exceptionally prone to activate multiple bonds, such as alkynes and alkenes. Thus, its utility in catalysis has been exploited together with the synthesis of suitable catalysts to allow new, efficient transformations, and the understanding of their intrinsic mechanisms. Reported in this thesis are efforts to this goal, such as the design and study of new Au(I) and Au(III) complexes towards functionalisation of alkynes. The development of new catalytic systems is tackled in Chapter 2. An
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Ying, Fang. "Au/CeO₂ based catalysts for catalytic oxidation of volatile organic compounds and carbon monoxide." HKBU Institutional Repository, 2010. http://repository.hkbu.edu.hk/etd_ra/1185.

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Lo, Kar-yan, and 盧嘉茵. "Gold catalysis: stereoselective synthesis of propargylamines and axially chiral allenes, and application on naturalproduct modifications." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2009. http://hub.hku.hk/bib/B41758122.

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Lorusso, Patrizia. "Metal catalysed alkylation of carbonyl compounds with formaldehyde." Thesis, University of St Andrews, 2015. http://hdl.handle.net/10023/7823.

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Formaldehyde is a chemical used widely in the manufacture of building materials. A remarkable example is represented by the Lucite two-step Alpha technology for the large scale production of methyl methacrylate (MMA), the essential building block of all acrylic-based products. Esters and ketones are important intermediates in the manufacture of acrylate esters therefore α-hydroxymethylenation of carbonyl compounds using formaldehyde as a one carbon alkylating agent and subsequent dehydration to the corresponding methylenated derivatives has been explored in the current work. We report a novel
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Julius, Gerrit R. "New transition metal carbene complexes for application in homogeneous catalysis." Thesis, Stellenbosch : University of Stellenbosch, 2005. http://hdl.handle.net/10019.1/1391.

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Thesis (PhD (Chemistry and Polymer Science))--University of Stellenbosch,2005.<br>This study comprises the preparation and full characterisation of new carbene complexes of group 10 metals (Ni, Pd or Pt), the group 9 metal, rhodium, as well as group 6 metals (Cr and/or W). N-heterocyclic carbene (NHC) complexes of nickel and palladium were prepared via oxidative addition of the corresponding carbene precursors imidazolium-, imidazolinium-, pyridinium- and quinolinium chloride salts, to M(PPh3)4 (M = Ni or Pd). Three types of carbene complexes, namely the standard five-membered two-N carbe
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Histed, M. J. "A matrix isolation study of the reactions of some zero valent metal atoms of catalytic interest." Thesis, Liverpool John Moores University, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.380260.

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Books on the topic "Catalysis of metal compounds"

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Organotransition metal chemistry: From bonding to catalysis. University Science Books, 2010.

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Brunner, Henri. Handbook of enantioselective catalysis: With transition metal compounds. VCH, 1993.

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Pomogaĭlo, A. D. Catalysis by polymer-immobilized metal complexes. Gordon and Breach Science Publishers, 1998.

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Ikariya, Takao. Bifunctional Molecular Catalysis. Springer-Verlag Berlin Heidelberg, 2011.

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Cazin, Catherine Suzanne Julienne. N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis. Springer Science+Business Media B.V., 2011.

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Petrus Adrianus Johannes Marinus Angevaare. Surface chemistry of oxygen containing organic compounds on oxides. Pasmans Offsetdrukkerij BV, 1991.

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Kazmaier, Uli. Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis. Springer-Verlag Berlin Heidelberg, 2012.

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Behr, Arno. Carbon dioxide activation by metal complexes. VCH, 1988.

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D, Ittel Steven, ed. Homogeneous catalysis: The applications and chemistry of catalysis by soluble transition metal complexes. 2nd ed. Wiley, 1992.

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Diederich, François. Metal-catalyzed cross-coupling reactions. Wiley-VCH, 1998.

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Book chapters on the topic "Catalysis of metal compounds"

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Simándi, László I. "Oxidation of Sulfur Compounds." In Catalysis by Metal Complexes. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2850-6_12.

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Cenini, S., and C. Crotti. "Catalytic Carbonylations of Nitrogen Containing Organic Compounds." In Catalysis by Metal Complexes. Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3408-8_15.

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Simándi, László I. "Catalytic Oxidation of Nitrogen Compounds with O2." In Catalysis by Metal Complexes. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2850-6_10.

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Curci, Ruggero, and John O. Edwards. "Activation of Hydrogen Peroxide by Organic Compounds." In Catalysis by Metal Complexes. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-017-0984-2_3.

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Hasselberg, J., Arno Behr, and Andreas J. Vorholt. "Continuously Operated Cooligomerisation of Fatty Compounds with Ethylene." In Catalysis by Metal Complexes. Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-54161-7_9.

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Brunner, Henri. "Enantioselective Catalysis with Transition Metal Compounds." In Advances in Chemistry. American Chemical Society, 1992. http://dx.doi.org/10.1021/ba-1992-0230.ch009.

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Carpentier, Jean-François, and Yann Sarazin. "Alkaline-Earth Metal Complexes in Homogeneous Polymerization Catalysis." In Alkaline-Earth Metal Compounds. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-36270-5_5.

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Crimmin, Mark R., and Michael S. Hill. "Homogeneous Catalysis with Organometallic Complexes of Group 2." In Alkaline-Earth Metal Compounds. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-36270-5_6.

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Rösch, Notker, Cristiana Di Valentin, and Ilya V. Yudanov. "Mechanism of Olefin Epoxidation by Transition Metal Peroxo Compounds." In Catalysis by Metal Complexes. Springer US, 2002. http://dx.doi.org/10.1007/0-306-47718-1_12.

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Vogler, A., and H. Kunkely. "Charge Transfer Excitation of Coordination Compounds. Generation of Reactive Intermediates." In Catalysis by Metal Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-017-2626-9_4.

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Conference papers on the topic "Catalysis of metal compounds"

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Sudiyarmanto, Anis Kristiani, Luthfiana N. H., Andreas, and Haznan Abimanyu. "Catalytic conversion of ethanol to aromatic compounds using metal/zeolite catalysts." In PROCEEDINGS OF THE 12TH INTERNATIONAL CONFERENCE ON SYNCHROTRON RADIATION INSTRUMENTATION – SRI2015. Author(s), 2016. http://dx.doi.org/10.1063/1.4958515.

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Parks, James E. "Mitigation of Sulfur Effects on a Lean NOx Trap Catalyst by Sorbate Reapplication." In ASME 2007 Internal Combustion Engine Division Fall Technical Conference. ASMEDC, 2007. http://dx.doi.org/10.1115/icef2007-1628.

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Lean NOx trap catalysis has demonstrated the ability to reduce NOx emissions from lean natural gas reciprocating engines by &gt;90%. The technology operates in a cyclic fashion where NOx is trapped on the catalyst during lean operation and released and reduced to N2 under rich exhaust conditions; the rich cleansing operation of the cycle is referred to as “regeneration” since the catalyst is reactivated for more NOx trapping. Natural gas combusted over partial oxidation catalysts in the exhaust can be used to obtain the rich exhaust conditions necessary for catalyst regeneration. Thus, the lea
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Suzuki, Kenichirou, Anil K. Sinha, and Kazuhiro Fukumoto. "Novel Promising 3-D Mesoporous Metal Oxides Sorbent/Catalyst with Volatile Organic Compounds Elimination Ability." In SAE World Congress & Exhibition. SAE International, 2007. http://dx.doi.org/10.4271/2007-01-1011.

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Sulman, Esther. "THE ROLE OF ALKALI METAL COMPOUNDS IN SYNTHESIS OF EFFECTIVE POLYMER-BASED PALLADIUM CATALYSTS OF SELECTIVE HYDROGENATION." In 18th International Multidisciplinary Scientific GeoConference SGEM2018. Stef92 Technology, 2018. http://dx.doi.org/10.5593/sgem2018/4.1/s17.094.

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Zuben, Theodora Von, Airton Salles Junior, and Gabriela de Souza. "A metal-catalyst-free oxidative coupling of anilines to aromatic azo compounds in water using bleach." In Congresso de Iniciação Científica UNICAMP. Universidade Estadual de Campinas, 2019. http://dx.doi.org/10.20396/revpibic2720192327.

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Kwong, C. W., C. Y. H. Chao, and K. S. Hui. "Recycling Biomass Co-Combustion Fly-Ash Products for an Integrated Solar-Assisted Ventilation System." In ASME 2009 3rd International Conference on Energy Sustainability collocated with the Heat Transfer and InterPACK09 Conferences. ASMEDC, 2009. http://dx.doi.org/10.1115/es2009-90128.

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The potential use of biomass co-combustion derived fly-ash products and zeolite 13X for the elimination of volatile organic compounds (VOCs) using ozone was investigated for an integrated solar-assisted air purification and desiccant cooling system. Fly-ash products from rice husk-coal co-combustion at different biomass blending ratios were used as the adsorbent/catalyst materials. The material characteristics of the adsorbent/catalyst materials such as metal content and surface area were compared and correlated with the catalytic activities. It was found that the surface area and the metal co
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Johansson, E. Magnus, K. M. Jonny Danielsson, Anders G. Ersson, and Sven G. Järås. "Development of Hexaaluminate Catalysts for Combustion of Gasified Biomass in Gas Turbines." In ASME 1998 International Gas Turbine and Aeroengine Congress and Exhibition. American Society of Mechanical Engineers, 1998. http://dx.doi.org/10.1115/98-gt-338.

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There is an increasing interest in catalytic combustors fuelled by low-heating value (LHV) gases, with a LHV of 5–7 MJ/Nm3. This is because catalytic combustion could be advantageous compared to flame combustion with respect to stable combustion of LHV-gases and low conversions of fuel-N (mainly NH3) to NOx. In the present project, funded by the EU Joule Programme, catalytic combustion of gasified wood for gas turbine applications is studied. A synthetic gas mixture of H2, CO, CO2, H2O, CH4, N2 and NH3, that resembles the output from a fluidized bed gasifier using biomass as raw material, is u
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Furey, Michael J., Czeslaw Kajdas, Gustavo J. Molina, and Brian Vick. "A Critical Assessment of Tribopolymerization as an Antiwear Mechanism." In World Tribology Congress III. ASMEDC, 2005. http://dx.doi.org/10.1115/wtc2005-63308.

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By tribopolymerization, we mean the planned, intentional, and continuous formation of protective polymeric films on tribological surfaces by the use of minor concentrations of selected monomers capable of forming polymer films “in situ” by polycondensation or addition polymerization. The approach involves the design of molecules which will form polymeric surface films in critical regions of boundary lubrication. The concept has been shown to be effective in reducing wear with ceramics as well as metals in both liquid and vapor phase applications. The purpose of this paper is threefold, namely:
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MOISEEV, ILYA I. "METAL COMPLEX CATALYSIS OF OXIDATION REACTIONS: CATALYSIS WITH PALLADIUM COMPLEXES." In Proceedings of the NIOK (Netherlands Institute for Catalysis Research) Course on Catalytic Oxidation. WORLD SCIENTIFIC, 1995. http://dx.doi.org/10.1142/9789814503884_0010.

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JONES, CHRISTOPHER W., LALIT DARUNTE, KIWON EUM, et al. "CATALYSIS BY MICROPOROUS METAL ORGANIC FRAMEWORKS." In 24th International Solvay Conference on Chemistry. WORLD SCIENTIFIC, 2018. http://dx.doi.org/10.1142/9789813237179_0027.

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Reports on the topic "Catalysis of metal compounds"

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Berry, John F. Studies of Metal-Metal Bonded Compounds in Catalysis. Office of Scientific and Technical Information (OSTI), 2018. http://dx.doi.org/10.2172/1417486.

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Rillema, D. Oligomer and mixed-metal compounds potential multielectron transfer catalysts. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/5573583.

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Rothwell, I. P. Catalytic arene hydrogenation using early transition metal hydride compounds. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/6443562.

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Rothwell, I. P. Catalytic arene hydrogenation using early transition metal hydride compounds. Progress report. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10159596.

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Dumesic, James A. Fundamental Studies of the Reforming of Oxygenated Compounds over Supported Metal Catalysts. Office of Scientific and Technical Information (OSTI), 2016. http://dx.doi.org/10.2172/1233553.

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Rillema, D. P. Oligomer and mixed-metal compounds, potential multielectron transfer catalysts. Progress report, January 1, 1990--January 1, 1993. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10174894.

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Rillema, D. Paul. Oligomer and mixed-metal compounds: potential multielectron transfer catalysts. Final progress report, January 1, 1990 - January 1, 1993. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/761800.

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Cutler, A. R. Metal Carbonyl-Hydrosilane Reactions and Hydrosilation Catalysis. Office of Scientific and Technical Information (OSTI), 2001. http://dx.doi.org/10.2172/833810.

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Metiu, Horia. Theoretical Studies of Catalysis on Supported Metal Clusters. Defense Technical Information Center, 2005. http://dx.doi.org/10.21236/ada442760.

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Henderson, Michael A. Ionizing Radiation Induced Catalysis on Metal Oxide Particles. Office of Scientific and Technical Information (OSTI), 1999. http://dx.doi.org/10.2172/827293.

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