Relevant bibliographies by topics / Chlorine radicals

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers

Academic literature on the topic 'Chlorine radicals'

Author: Grafiati
Published: 4 June 2021
Last updated: 1 February 2022

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Journal articles on the topic "Chlorine radicals"

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Taniguchi, Tsuyoshi. "Recent Advances in Reactions of Heteroatom-Centered Radicals." Synthesis 49, no. 16 (2017): 3511–34. http://dx.doi.org/10.1055/s-0036-1588481.

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Heteroatom-centered radicals show versatile reactivity and offer useful synthetic methods in organic chemistry. The development of new approaches for forming heteroatom-centered radicals has recently expanded the practicality of radical chemistry for synthesis. This review focuses on recent advances in reactions of representative heteroatom-centered radicals.1 Introduction2 Group 17 Elements: Chlorine and Bromine Radicals3 Group 15 and Group 16 Elements3.1 Nitrogen- and Oxygen-Centered Radicals3.2 Phosphorus- and Sulfur-Centered Radicals3.3 Other Radicals4 Group 14 Elements: Silicon-Centered R
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Rehorek, Detlef, Edward G. Janzen, and Yashige Kotake. "On the spin trapping of chlorine atoms. Competition from chloride ions." Canadian Journal of Chemistry 69, no. 7 (1991): 1131–33. http://dx.doi.org/10.1139/v91-167.

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Chlorine atoms generated by photolysis of hexachloroethane add to C-phenyl-N-tert-butyl nitrone (PBN) to form persistent spin adducts that are readily detectable by EPR spectroscopy. The presence of chloride ions reduces spin adduct formation competitively. Chlorine atoms also react with tetraphenylarsenium ions to liberate phenyl radicals by radical replacement. Key words: EPR, spin trapping, C-phenyl-N-tert-butyl nitrone, PBN, photolysis, chlorine atoms, tetraphenylarsenium ion, hexachloroethane.
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Ngai, Ming-Yu, Arghya Banerjee, and Zhen Lei. "Acyl Radical Chemistry via Visible-Light Photoredox Catalysis." Synthesis 51, no. 02 (2018): 303–33. http://dx.doi.org/10.1055/s-0037-1610329.

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Visible-light photoredox catalysis enables easy access to acyl radicals under mild reaction conditions. Reactive acyl radicals, generated from various acyl precursors such as aldehydes, α-keto acids, carboxylic acids, anhydrides, acyl thioesters, acyl chlorides, or acyl silanes, can undergo a diverse range of synthetically useful transformations, which were previously difficult or inaccessible. This review summarizes the recent progress on visible-light-driven acyl radical generation using transition-metal photoredox catalysts, metallaphotocatalysts, hypervalent iodine catalysts or organic pho
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Faxon, C. B., and D. T. Allen. "Chlorine chemistry in urban atmospheres: a review." Environmental Chemistry 10, no. 3 (2013): 221. http://dx.doi.org/10.1071/en13026.

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Environmental context Atmospheric chlorine radicals can affect the chemical composition of the atmosphere through numerous reactions with trace species. In urban atmospheres, the reactions of chlorine radicals can lead to effects such as increases in ozone production, thus degrading local and regional air quality. This review summarises the current understanding of atmospheric chlorine chemistry in urban environments and identifies key unresolved issues. Abstract Gas phase chlorine radicals (Cl•), when present in the atmosphere, react by mechanisms analogous to those of the hydroxyl radical (O
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Kawata, Hiroyuki, Masahiro Kohno, Kohei Nukina, et al. "Identifying the chloroperoxyl radical in acidified sodium chlorite solution." PLOS ONE 16, no. 5 (2021): e0252079. http://dx.doi.org/10.1371/journal.pone.0252079.

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The present study identified the active radical species in acidic sodium chlorite and investigated the feasibility of quantifying these species with the diethylphenylenediamine (DPD) method. Electron spin resonance (ESR) spectroscopy was used to identify the active species generated in solutions containing sodium chlorite (NaClO2). The ESR signal was directly observed in an acidified sodium chlorite (ASC) aqueous solution at room temperature. This ESR signal was very long-lived, indicating that the radical was thermodynamically stable. The ESR parameters of this signal did not coincide with pr
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Trukhin, Aleksei V., Evgeny V. Eliseenkov, and Aleksei S. Dneprovskii. "Cyclopropylbenzene ring opening by chlorine atom: radicals or radical ions?" Journal of Physical Organic Chemistry 16, no. 3 (2003): 189–93. http://dx.doi.org/10.1002/poc.589.

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Yeston, Jake. "A complex role for chlorine radicals." Science 372, no. 6544 (2021): 803.12–805. http://dx.doi.org/10.1126/science.372.6544.803-l.

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Jewell, Deborah Rae, Lukose Mathew, and John Warkentin. "Rate constant for chlorine abstraction from CCl4 by the 5-hexenyl radical." Canadian Journal of Chemistry 65, no. 2 (1987): 311–15. http://dx.doi.org/10.1139/v87-052.

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Cyclization of the 5-hexenyl free radical to the cyclopentylmethyl free radical was used to clock chlorine atom abstraction by 5-hexenyl from carbon tetrachloride in solution. The source of 5-hexenyl radicals was 5-hexenyl[1-hydroxy-1-methyl-ethyl]diazene ((CH3)2C(OH)N=N(CH2)4CH=CH2), which decomposes thermally in CCl4 by a radical chain mechanism to afford chloroform, acetone, nitrogen, 6-chloro-1-hexene, cyclopentylchloromethane, 1-hexene, and methylcyclopentane as primary products. 6-Chloro-1-hexene is converted, in part, to a secondary product, 1,1,1,3,7-pentachloroheptane, by radical chai
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Wojnárovits, László, and Erzsébet Takács. "Rate constants of dichloride radical anion reactions with molecules of environmental interest in aqueous solution: a review." Environmental Science and Pollution Research 28, no. 31 (2021): 41552–75. http://dx.doi.org/10.1007/s11356-021-14453-w.

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AbstractNatural waters, water droplets in the air at coastal regions and wastewaters usually contain chloride ions (Cl-) in relatively high concentrations in the milimolar range. In the reactions of highly oxidizing radicals (e.g., •OH, •NO3, or SO4•-) in the nature or during wastewater treatment in advanced oxidation processes the chloride ions easily transform to chlorine containing radicals, such as Cl•, Cl2•-, and ClO•. This transformation basically affects the degradation of organic molecules. In this review about 400 rate constants of the dichloride radical anion (Cl2•-) with about 300 o
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Liu, Yiming, Qi Fan, Xiaoyang Chen, et al. "Modeling the impact of chlorine emissions from coal combustion and prescribed waste incineration on tropospheric ozone formation in China." Atmospheric Chemistry and Physics 18, no. 4 (2018): 2709–24. http://dx.doi.org/10.5194/acp-18-2709-2018.

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Abstract. Chlorine radicals can enhance atmospheric oxidation, which potentially increases tropospheric ozone concentration. However, few studies have been done to quantify the impact of chlorine emissions on ozone formation in China due to the lack of a chlorine emission inventory used in air quality models with sufficient resolution. In this study, the Anthropogenic Chlorine Emissions Inventory for China (ACEIC) was developed for the first time, including emissions of hydrogen chloride (HCl) and molecular chlorine (Cl2) from coal combustion and prescribed waste incineration (waste incinerati
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Dissertations / Theses on the topic "Chlorine radicals"

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Pouyet, Frédéric. "Nouvelles conditions d'utilisation de l'ozone dans le blanchiment des pâtes cellulosiques. Application à la mise au point d'un procédé de blanchiment "vert"." Thesis, Grenoble, 2014. http://www.theses.fr/2014GRENI032.

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Le manque de compréhension des réactions liées à l'utilisation de l'ozone a constitué un clair frein au développement de séquences de blanchiment non-chlorées efficaces. Considéré comme un élément central des séquences TCF face aux séquences ECF comprenant du dioxyde de chlore, l'ozone ne permettait pas l'obtention de pâtes cellulosiques de qualité aussi élevée. Le but de ce travail est l'élaboration de séquences de blanchiment non-chlorées permettant l'obtention d'un produit final de haute qualité. Ce type de séquence pourrait présenter de nombreux avantages, parmi lesquels sont envisagés des
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Lauraguais, Amélie. "Contribution de la combustion du bois à la qualité de l'air et étude de la réactivité atmosphérique des méthoxyphénols en chambre de simulation." Thesis, Littoral, 2014. http://www.theses.fr/2014DUNK0364/document.

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Afin de réduire la consommation en énergie fossile et ainsi limiter les émissions de gaz à effet de serre, l’un des objectif du Grenelle de l’Environnement est de porter à 23% la part des énergies renouvelables dans la consommation d’énergie finale en France en 2020. Le bois-énergie représente une alternative à l’utilisation des énergies fossiles, mais c’est également une source de polluants dans l’atmosphère et il est essentiel de déterminer sa contribution potentielle à la dégradation de la qualité de l’air intérieur et extérieur. Au cours de cette thèse, mes travaux de recherche se sont foc
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Arlie, Natacha. "Réactivité de radicaux inorganiques, CO3 *- et Cl*/Cl2 *- en solution aqueuse." Phd thesis, Université Blaise Pascal - Clermont-Ferrand II, 2012. http://tel.archives-ouvertes.fr/tel-00973851.

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Dans les eaux naturelles ou bien dans les eaux en cours de traitement, de nombreux processus peuvent générer des espèces réactives telles que de l'oxygène singulet, des ions superoxydes,des radicaux hydroxyles, ou bien d'autres oxydants. Dans les eaux naturelles, ces processus impliquent les substances humiques ou les ions nitrates en présence de lumière et d'oxygène. Dans les eaux en cours de traitement, les procédés d'oxydation avancée sont une source de production de radicaux hydroxyle. D'autres radicaux peuvent ensuite être formés par des réactions secondaires avec la matrice inorganique d
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Hamdi, El Najjar Nasma. "Cinétiques et mécanismes d'oxydation de composés pharmaceutiques par le chlore, l'ozone et les radicaux hydroxyle." Thesis, Poitiers, 2012. http://www.theses.fr/2012POIT2264/document.

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La présence dans les eaux de composés pharmaceutiques constitue de nos jours une préoccupation croissante. Une grande variété de composés pharmaceutiques a récemment été mise en évidence dans les eaux de surface. La chloration, l'ozonation et l'oxydation radicalaire sont fréquemment employés au cours de la filière de traitement des eaux pour leurs propriétés désinfectante et oxydante. Toutefois, des sous-produits d'oxydation peuvent être rémanents. Dans ce contexte, il est important de connaître la réactivité de ces procédés oxydants sur ces composés. Pour cela, l'étude de l'effet du chlore, d
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Marcon, Jennifer. "Pâtes lignocellulosiques : étude d'un nouveau stade de blanchiment ECF à faible impact environnemental." Thesis, Université Grenoble Alpes (ComUE), 2016. http://www.theses.fr/2016GREAI104.

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Le dioxyde de chlore est l’agent de blanchiment le plus utilisé pour le blanchiment des pâtes chimiques lignocellulosiques. Son utilisation s’accompagne malheureusement de la formation d’ions chlorates, composés inefficaces pour le blanchiment, ainsi que d’importants rejets de DCO et d’organo-chlorés (AOX), nuisibles pour l’environnement. Cette étude a consisté à concevoir un nouveau stade de blanchiment au dioxyde de chlore (stade D) à pH non-conventionnel, économe en réactifs, et visant à réduire l’impact environnemental d’une séquence classique. Le travail a été effectué sur des pâtes kraft
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Laine, Patrick L. "Laser flash photolysis studies of halogen atom reactions of atmospheric interest." Diss., Georgia Institute of Technology, 2011. http://hdl.handle.net/1853/42817.

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The Earth's atmosphere is a large photochemical reactor consisting primarily of N2 (~78%) and O2 (~21%) with Ar and water vapor being the next most abundant constituents. All of the remaining gases in the atmosphere are referred to as 'trace gases', and they play a critical role in understanding climate change, urban air quality, ozone production and depletion, and in determining the overall 'health' of the atmosphere. These trace components are present in our atmosphere with mixing ratios, i.e., mole fractions, ranging from sub parts per trillion to several hundred parts per million. One c
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LEÃO, CLÁUDIO. "Desenvolvimento e validação de metodologia para a determinação de monocloroacetato de sódio e dicloroacetato de sódio em cocoamido,N-[(3-dimetilamino)propil],betaína via cromatografia a gás: GC/FID, GC/ECD e GC/MS." reponame:Repositório Institucional do IPEN, 2016. http://repositorio.ipen.br:8080/xmlui/handle/123456789/26796.

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Submitted by Claudinei Pracidelli (cpracide@ipen.br) on 2016-11-11T09:28:13Z No. of bitstreams: 0<br>Made available in DSpace on 2016-11-11T09:28:13Z (GMT). No. of bitstreams: 0<br>O monocloroacetato de sódio (MCAS) e o dicloroacetato de sódio (DCAS) são compostos tóxicos e irritantes ao ser humano e nocivos ao meio ambiente, sendo impurezas indesejáveis na cocoamido propil betaína (CAPB), que é um surfactante anfótero utilizado em produtos de consumo dos segmentos cosmético e domiciliar. Diante dos requisitos de concentração em nível de mg/kg exigidos pelos órgãos reguladores de saúde do gov
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Al, Kazzaz Marwan. "Pyrolyse du chlorure de méthyle induite par le chlore : une nouvelle voie de valorisation du méthane." Vandoeuvre-les-Nancy, INPL, 1995. http://www.theses.fr/1995INPL024N.

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La conversion du méthane, principal constituant du gaz naturel, en produits valorisables et facilement transportables constitue un enjeu économique important, et un défi pour la recherche. Une étude théorique conduit à une nouvelle voie de conversion du méthane en chlorure de vinyle par chloro-pyrolyse du chlorure de méthyle. La réaction CH3Cl/Cl2 en phase gazeuse a été étudiée entre 500 et 1000°C. À basse température, on observe la réaction de chloration bien connue qui produit CH2Cl2. À haute température, on observe une nouvelle réaction: la chloro-pyrolyse qui produit principalement du chlo
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Lendar, Maria. "Dégradation atmosphérique d’une série d’alcools, d’esters et de l’hexafluoroisobutène." Thesis, Orléans, 2012. http://www.theses.fr/2012ORLE2042/document.

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Cette thèse présente le devenir atmosphérique de trois alcools saturés CH3(CH2)4OH, CH3CH2CH2CH(OH)CH3 et (C2H5)2CHOH, de trois esters CH3CH2CH2C(O)OC2H5, CH3CH2C(O)OC2H5 et CH3CH2C(O)OCH2CH2CH3 ainsi que d’un HFC insaturé (CF3)2C=CH2 avec OH et Cl. La constante de vitesse de la réaction avec OH de ces composés a été déterminée en fonction de la température (253 – 373 K), en utilisant la technique Photolyse Laser Pulsée couplée à la Fluorescence Induite par Laser (PLP-FIL). La constante de vitesse de la réaction de OH et de Cl avec les alcools, les esters et l’hexafluoroisobutène (HFIB) a été
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McGinty, Kathryn Mary. "Surface Modification of Poly(vinyl chloride) by Physisorbed Free Radical Initiation for Reduced Plasticizer Migration and Antimicrobial Properties." University of Akron / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=akron1226615844.

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Books on the topic "Chlorine radicals"

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Carr, Sinéad. Kinetics and mechanisms of the reactions of chlorine atoms and hydroxyl radicals with a series of halogenated ketones and carboxylic acids. University College Dublin, 1996.

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Manning, Marcus. Kinetics and mechanisms for hydroxyl radical and chlorine atom initiated oxidation of a series of chloroethanes, chloroethenes and 2-chloroethanols. University College Dublin, 1999.

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Krosley, Kevin W. Part I. The identity of the chain propagating radical(s) in photoinitiated benzylic bromination by bromotrichloromethane ; Part II. Chlorine atom abstraction from Ü- and Ý-chloroepoxides by the triphenyltin radical. 1991.

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J, Salawitch R., and United States. National Aeronautics and Space Administration., eds. The diurnal variation of hydrogen, nitrogen, and chlorine radicals: Implications for the heterogeneous production of HNO₂. National Aeronautics and Space Administration, 1994.

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Achi, Samuel Sofa. Bulk polymerisation of some azo-monomers: Anion and free radical initiated polymerisation of acryloyl amino azo colours, and condensation of amino azo compounds with cyanuric chloride. 1985.

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Book chapters on the topic "Chlorine radicals"

1

Claridge, R. F. C. "1.16 Chlorine-centered radicals." In Inorganic Radicals, Metal Complexes and Nonconjugated Carbon Centered Radicals. Part 1. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-48466-0_18.

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Sarel, S., Ch Rav-Acha, and E. Choshen. "Chlorine-Dioxide as an Electron Transfer Oxidant of Olefins." In Organic Free Radicals. Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_89.

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Abreu, Carlos M. R., Ana C. Fonseca, Nuno M. P. Rocha, James T. Guthrie, Arménio C. Serra, and Jorge F. J. Coelho. "Reversible Deactivation Radical Polymerization of Vinyl Chloride." In ACS Symposium Series. American Chemical Society, 2018. http://dx.doi.org/10.1021/bk-2018-1284.ch010.

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Quehenberger, Oswald, Günther Jürgens, Silvia Zadravec, and Hermann Esterbauer. "Oxidation of Human Low Density Lipoprotein Initiated by Copper(II)Chloride." In Oxygen Radicals in Biology and Medicine. Springer US, 1988. http://dx.doi.org/10.1007/978-1-4684-5568-7_60.

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Capek, I. "Kinetics of the free-radical emulsion polymerization of vinyl chloride." In Physical Properties of Polymers. Springer Berlin Heidelberg, 1995. http://dx.doi.org/10.1007/3-540-58704-7_3.

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Hüttner, W. "79 BrCl+ X 2П3/2 Bromine chloride(1+) radical ion." In Diamagnetic Diatomic Molecules. Part 1. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-540-69954-5_81.

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Alia, P. Pardha Saradhi, and Prasanna Mohanty. "Proline in relation to free radical production in seedlings of Brassica juncea raised under sodium chloride stress." In Plant Nutrition — from Genetic Engineering to Field Practice. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1880-4_161.

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d'Hennezel, Olga, and David F. Ollis. "Photocatalytic oxidation of air contaminants by chlorine (Cl) or hydroxyl (OH) radicals or holes (h+): Mechanistic correlations." In 11th International Congress On Catalysis - 40th Anniversary, Proceedings of the 11th ICC. Elsevier, 1996. http://dx.doi.org/10.1016/s0167-2991(96)80254-0.

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Härtinger, S. "Alkoxyl-Radical-Mediated Reactions." In Chlorine, Bromine, and Iodine. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-035-00516.

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Roy, K. M. "Using Hydrogen Bromide and a Radical Source." In Chlorine, Bromine, and Iodine. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-035-00362.

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Conference papers on the topic "Chlorine radicals"

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Barari, Ghazal, Batikan Koroglu, Artëm E. Masunov, and Subith Vasu. "Combustion of Aldehydes in the Negative Temperature Coefficient Region: Products and Pathways." In ASME Turbo Expo 2016: Turbomachinery Technical Conference and Exposition. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/gt2016-58025.

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Aldehydes are major intermediates in oxidation and pyrolysis of hydrocarbons and particularly biofuels. While the high temperature oxidation chemistry of C3-C5 aldehydes have been studied in the literature, a comprehensive low temperature kinetics remains unaddressed. In this work, acetaldehyde, propanal, and 2-propenal (acrolein) oxidation was investigated at low-temperature combustion condition (500–700 K). The isomer specific products concentrations as well as the time-resolved profiles were studied using Sandia’s multiplexed photoionization mass spectroscopy (MPIMS) with synchrotron radiat
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Hudgens, Jeffrey W., Karl K. Irikura, and Russell D. Johnson III. "New spectroscopy of free radicals produced by the reactions of fluorine and chlorine with diborane." In OE/LASE '94, edited by John W. Hepburn. SPIE, 1994. http://dx.doi.org/10.1117/12.178120.

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Rodríguez-Ramírez, Juan, Irene Chaparro-Hernández, Lilia L. Méndez-Lagunas, and Luis Gerardo Barriada-Bernal. "Effect of spray drying conditions on antioxidants activity, flavonoids and total phenolic compounds of stevia rebaudiana." In 21st International Drying Symposium. Universitat Politècnica València, 2018. http://dx.doi.org/10.4995/ids2018.2018.7518.

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In this work the spray drying of the fresh stevia leaves aqueous extract without encapsulating agents was carried out. The effect of the inlet air temperature (160-200 ºC) and the feed flow rate (2-3 kg/h) on the total phenolic content, the total flavonoid content and the antioxidant capacity were evaluated using Folin-Ciocalteau, aluminum chloride and DPPH methods respectively. The inlet air temperature had a significant effect on all parameters evaluated that showed a decrease when increasing the inlet air temperature, the feed flow rate had a significant effect on total flavonoids content a
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Bolotov, Vasiliy Alexandrovich, Serguei Fedorovich Tikhov, Konstantin Radikovich Valeev, Vladimir Timurovich Shamirzaev, and Valentin Nikolaevich Parmon. "SELECTIVE FORMATION OF LINEAR ALPHA-OLEFINS VIA MICROWAVE CATALYTIC CRACKING OF LIQUID STRAIGHT-CHAIN ALKANES." In Ampere 2019. Universitat Politècnica de València, 2019. http://dx.doi.org/10.4995/ampere2019.2019.9894.

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Linear even-carbon-number alpha-olefins (LAO) with four or more carbon atoms are important compounds of high demand in chemical industry as precursors of a wide range of value-added chemicals [1]. LAO are used as co-monomers for polyethylene production, for the production of alcohols (mainly in detergents and plasticizers) and for synthesis of polyalphaolefins (used in synthetic lubricants). Alpha-olefins (C4, C6, C8 and C10) are mainly used to produce poly(vinyl chloride) plasticizers, high-density and linear low-density polyethylene to impart the stress-crack resistance. C10–C14 alpha-olefin
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