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Dissertations / Theses on the topic 'Copper(I) and silver(I) complexes'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

馮潔媚 and Kit-mai Wendy Fung. "Luminescent polynuclear copper(I) and silver(I) complexes of bridging acetylides and related studies on copper(I) thiolates." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1997. http://hub.hku.hk/bib/B3123687X.

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Fung, Kit-mai Wendy. "Luminescent polynuclear copper(I) and silver(I) complexes of bridging acetylides and related studies on copper(I) thiolates /." Hong Kong : University of Hong Kong, 1997. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19102665.

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3

Black, Jane R. "Group 15 and 16 donor ligand complexes of copper and silver." Thesis, University of Southampton, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.307087.

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4

李丹 and Dan Li. "Synthesis, structure and photophysical and photochemical properties ofpolynuclear copper (1), silver (1) and gold (1) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1993. http://hub.hku.hk/bib/B31233120.

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5

Li, Dan. "Synthesis, structure and photophysical and photochemical properties of polynuclear copper (1), silver (1) and gold (1) complexes /." [Hong Kong : University of Hong Kong], 1993. http://sunzi.lib.hku.hk/hkuto/record.jsp?B13385367.

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6

Davis, Harrison Olivia. "Copper, Silver, and Gold Clusters: A Synthetic and Structural Investigation." Kent State University Honors College / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=ksuhonors1557352298361181.

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7

Lam, Chi-ho Aaron. "Syntheses, characterization and photophysics of polynuclear copper (I) and silver (I) complexes containing monoynyl, diynyl and chalcogen-type ligands /." Hong Kong : University of Hong Kong, 2000. http://sunzi.lib.hku.hk/hkuto/record.jsp?B22055034.

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8

Chan, Chi-keung. "Structure, photophysical and theoretical studies of polynuclear CU(I), AG(I) and AU(I) metal complexes /." Hong Kong : University of Hong Kong, 1997. http://sunzi.lib.hku.hk/hkuto/record.jsp?B18037422.

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9

Almotawa, Ruaa Mohammed. "Silver(I) and Copper(I) Complexes from Homoleptic to Heteroleptic: Synthesis, Structure and Characterization." Thesis, University of North Texas, 2018. https://digital.library.unt.edu/ark:/67531/metadc1404512/.

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A plethora of novel scientific phenomena and practical applications, such as solid-state molecular solar cells and other optoelectronic devices for energy harvesting and lighting technologies, have catalyzed us to synthesize novel compounds with tunable properties. Synthetic routes, single crystal structures, and spectral and materials properties are described. Reactions of Ag(I) and Cu(I) precursors with various types of ligands -- including the azolates, diimines, and diiphosphines -- lead to the corresponding complexes in high yield. Varying the metal ions, ligands, synthetic methods, solve

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10

林智豪 and Chi-ho Aaron Lam. "Syntheses, characterization and photophysics of polynuclear copper (I)and silver (I) complexes containing monoynyl, diynyl and chalcogen-type ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2000. http://hub.hku.hk/bib/B31240434.

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11

Cheng, Chung-chin. "Syntheses and photophysics of luminescent polynuclear coinage metal complexes with chalcogen and pnictogen containing bridging ligands /." Hong Kong : University of Hong Kong, 2001. http://sunzi.lib.hku.hk/hkuto/record.jsp?B22956372.

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12

Esplugas, Ricardo Oliveira. "Density functional theory and time-dependent density functional theory studies of copper and silver cation complexes." Thesis, University of Sussex, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.496931.

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A particular emphasis of this thesis has been to provide insight into the underlying stability of these complexes and hence interpret experimental data, and to establish the development of solvation shell structure and its effect on reactivity and excited states. Energy decomposition analysis, fragment analysis and charge analysis has been used throughout to provide deeper insight into the nature of the bonding in these complexes. This has also been used successfully to explain observed preferential stability and dissociative loss products.

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13

Lin, Yongyue, and 林勇躍. "Luminescent platinum(II), copper(I), silver(I) and zinc(II) complexes with functional pyridyl and arylacetylide ligands: structures, spectroscopic properties and applications." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2001. http://hub.hku.hk/bib/B31243381.

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14

Lin, Yongyue. "Luminescent platinum(II), copper(I), silver(I) and zinc(II) complexes with functional pyridyl and arylacetylide ligands : structures, spectroscopic properties and applications /." Hong Kong : University of Hong Kong, 2001. http://sunzi.lib.hku.hk/hkuto/record.jsp?B25155325.

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15

Chan, Chi-keung, and 陳志強. "Structure, photophysical and theoretical studies of polynuclear CU(I),AG(I) and AU(I) metal complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1997. http://hub.hku.hk/bib/B31235554.

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16

Castelló, Moncayo Luis Miguel. "Synthesis and Applications of Chiral Phosphoramidites Copper(II) and Silver(I) Complexes as Catalysts in Asymmetric Synthesis." Doctoral thesis, Universidad de Alicante, 2015. http://hdl.handle.net/10045/50466.

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17

鄭重展 and Chung-chin Cheng. "Syntheses and photophysics of luminescent polynuclear coinage metal complexes with chalcogen and pnictogen: containing bridging ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2001. http://hub.hku.hk/bib/B31241530.

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18

Levesque, Patrick Pierre. "Development of New Biarylphosphane Coinage Metal Complexes for the Regioselective Synthesis of Fused Carbocycles." Thèse, Université d'Ottawa / University of Ottawa, 2012. http://hdl.handle.net/10393/23367.

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In the last century, no less than five nobel prizes have been awarded for the construction of carbon-carbon bonds : The Grignard reaction (1912), the Diels-Alder reaction (1950), the Wittig reaction (1979), Olefin metathesis (2005) and palladium cross-coupling reactions (2011). The latter two are transition metal catalyzed transformations and their impact on the synthesis of pharmaceutically active compounds, bulk chemicals, fine chemicals, high tech materials as well as agricultural chemicals has been phenomenal. These reactions have changed the way the scientific community views the science

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19

Endrizzi, Francesco. "Thermodynamic studies on Cu(I) and Ag(I) phosphino complexes with potential anti-tumor activity." Doctoral thesis, Università degli studi di Padova, 2013. http://hdl.handle.net/11577/3423107.

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Some thermodynamic studies on the formation equilibria of new copper(I) and silver(I) complexes with the hydrophilic phosphine PTA (1,3,5-7-triazaphosphaadamantane) are presented. With the aim of finding new metal-based compounds with potential antitumor activity, some new copper(I) and silver(I) complexes of PTA phosphine were recently prepared. These compounds show a good cytotoxicity in-vitro against several human tumor cell lines, and their biological activity was related to the ability of copper to bind biologically important substates, after dissociation of one or more phosphines during

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20

Pedrazzini, T. "MODULAR APPROACH TO CHIRAL PYRIDINE CONTAINING MACROCYCLES: SYNTHESIS, CHARACTERIZATION, REACTIVITY AND CATALYTIC ACTIVITY OF THEIR METAL COMPLEXES." Doctoral thesis, Università degli Studi di Milano, 2014. http://hdl.handle.net/2434/243662.

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In this thesis is reported a simple, fast, economic modular approach for the synthesis of chiral tetraaza-macrocycles containing a pyridine ring (Pc-L*) starting from aminoacids. The characterization of the ligands and of their complexes with copper (I) and silver (I) salts also descrive, including several crystal suitable for X-ray determination. The organometallic reactivity and coordination behavior of these complexes with CO and acetonitrile has been studied. The complexes were succesfully applied as catalysts for cyclopropanation and A3-coupling reaction and for the synthesis of isochrom

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21

Silva, Lenilda Austrilino. "Determinação da estrutura de uma série de tri(hidroximetil) amino metano complexados com íons metálicos (Cu, Ag, Ni, Zn)." Universidade de São Paulo, 1986. http://www.teses.usp.br/teses/disponiveis/54/54132/tde-10042014-093834/.

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As estruturas do tri(hidroximetil) amino metano complexado com cobre Cu(II), Cu[NH2C(COH3)3]2+H2O e do tri(hidroximetil)amino metano dopado com prata Ag(I), Ag[NH2C(COH3)3] foram determinados por difração de raios-x. O complexo contendo íons de cobre refinou até um R de 0.034 e foram encontradas as seguintes características principais: sistema cristalino monoclínico; grupo espacial C2/c, a=12.955(2)Å b=10.793(1)Å c=10.091(2)Å &#946=116.62° V=1261.3(6)޵ Z=4; xDc=1.694(2)g/cm-3; &#955(K&#945Mo)=0.71073Å das reflexões medidas 1441 tinham I&#62 3&#948 (I). O íon de c

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22

Charra, Valentine. "Coordination of multidentate N-heterocyclic carbene ligands to nickel." Thesis, Strasbourg, 2014. http://www.theses.fr/2014STRAF019/document.

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Le sujet de cette thèse porte sur la synthèse de ligands de type bis-NHC (carbène N-Hétérocyclique) et leur réactivité vis-À-Vis des complexes d’argent(I), de cuivre(I) et de nickel(II).Après avoir exploré les différentes méthodologies de synthèse des complexes de nickel(II) bis-NHC, le but était de tester leurs activités en catalyse d’oligomérisation de l’éthylène. Une série de nouveaux complexes d’argent(I) et de cuivre(I) fut synthétisée. Cinq voies furent testées pour la formation de complexes de nickel. Les résultats les plus probants furent obtenus par transmétallation à partir des compl

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23

Lesieur, Mathieu. "Cu and Pd complexes of N-heterocyclic carbenes : catalytic applications as single and dual systems." Thesis, University of St Andrews, 2015. http://hdl.handle.net/10023/7999.

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Nowadays, the requirement to design highly valuable compounds is undoubtedly one of the major challenges in the field of organic and organometallic chemistry. The use of the versatile and efficient N-heterocyclic carbenes (NHCs) combined with transition metals represents a key feature in modern organometallic chemistry and homogeneous catalysis. In the course of this thesis, the straightforward design and synthesis of a library of Pd(0) bearing NHC ligands was achieved. Their catalytic performances (Chapter 1) and their phosphorescence properties in solution (Chapter 2) were disclosed. Current

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24

Weske, Sebastian. "From Copper to Gold: Identification and Characterization of Coinage-Metal Ate Complexes by ESI Mass Spectrometry and Gas-Phase Fragmentation Experiments." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2019. http://hdl.handle.net/21.11130/00-1735-0000-0005-12EA-F.

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25

Castano, B. "SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY OF CHIRAL TETRAAZAMACROCYCLE - PC-L* -CU(I) AND AG (I) COMPLEXES." Doctoral thesis, Università degli Studi di Milano, 2014. http://hdl.handle.net/2434/229590.

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Homogeneous catalysis is a constantly growing and evolving area of study: in the last forty years many discoveries have been reported in both industrial and academic fields. Thanks to the use of organometallic catalysts, many inorganic and organic reactions of great importance have been revolutionized, so that homogeneous catalysis is now essential in many aspects of organic chemistry and for several industrial processes. On the other hand, heterogeneous catalysis is important because of its easier application in industry. Heterogeneous single site catalysts in many cases show superior perform

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26

Marques, Elizabete. "Proprietes complexantes de nouveaux recepteurs moleculaires : catenands et calixarenes fonctionnalises." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13105.

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Proprietes complexantes des coordinats : cat-30, de son motif constitutif m-30, de dimethyl-2,9 phenanthroline-1. 10 et de di(p-anasyl-)2,9 phenantroline-1. 10, vis a vis de cu**(+), ag, li, zu, cd. On etudie egalement les derives de calixarenes comportant des groupes ester ou cetone sur les o phenoliques-meres

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27

Tambosi, Reem. "Stress and toxicity of metal in photosynthetic bacteria : multi-scale study of the effects and the targets of metal ions and nanoparticles Silver and Copper Acute Effects on Membrane Proteins and Impact on Photosynthetic and Respiratory Complexes in Bacteria Silver Effect on Bacterial Cell Membrane Structure Investigated by Atomic Force and Scanning Electron Microscopes Cadmium and Copper Cross-tolerance. Cu+ alleviates Cd2+ toxicity, and both cations target heme and chlorophyll biosynthesis pathway in Rubrivivax gelatinosus Additive effects of metal excess and superoxide, a highly toxic mixture in bacteria." Thesis, université Paris-Saclay, 2020. http://www.theses.fr/2020UPASL070.

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L’usage intensif des métaux et des ions métalliques dans l'industrie et l'agriculture représente une menace sérieuse pour l'environnement et pour tous les êtres vivants en raison de la toxicité aiguë de ces ions. Cependant, cela peut aussi être un outil prometteur. En effet, les ions comme les nanoparticules d'argent sont très utilisés dans diverses applications médicales, industrielles et sanitaires. L'effet antimicrobien de ces nanoparticules est en partie lié aux ions Ag⁺ libérés et à leur capacité à interagir avec les membranes bactériennes. L'objectif de ce projet est d'étudier l'interact

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28

Torres, Urquidy Oscar Hernando. "Copper Resistant Bacteria Better Tolerate Commercially Available Antimicrobial Treatments Based in Silver and Silver-Copper Ions." Diss., The University of Arizona, 2011. http://hdl.handle.net/10150/202734.

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In the current study, the antibacterial efficacy of zeolites containing silver or copper ions or a combination of these metals was assessed against several diverse copper resistant (CuR) and copper sensitive (CuS) strains of clinically relevant bacterial species. CuR Pseudomonas putida was significantly reduced in comparison to the unamended zeolite control. Unexpectedly, a CuS P. putida strain with no reported metal resistance appeared to be more resistant to the zeolite containing either Ag or Ag/Cu than the CuR strain. Contrary to expectations, after three and six hours of exposure, the CuS

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29

Speed, David John. "Symmetry in copper and silver cryptates." Thesis, Open University, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.252338.

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The cryptand ligands imBT (l,4,7,10,13,16,21,24-0ctaaza-bicyclo[8.8.8]hexacosa- 4,6,13,15,21,23-hexaene) and amBT (1,4,7,10,13,16,21 ,24-0ctaazabicyc10[ 8.8.8]hexacosane) form interesting disilver(I) and trisilver(I) cryptates, as well as a dicopper(I) and a well studied average valence dicopper(1.5) cryptate. Detailed structural and spectroscopic studies of the silver cryptates show that complex equilibria exist in solution, and the trisilver form appears to be thermodynamically favoured, the additional stabilisation apparently being due to argentophilic interactions. An optically pure form o

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30

Westlake, Michael Angelo 1966. "The oxidation of copper and silver plated copper lead frames." Thesis, The University of Arizona, 1993. http://hdl.handle.net/10150/278279.

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The effects of thin silver films (15-210 angstroms) on the oxidation of copper alloy lead frames has been characterized. Silver films were deposited onto copper lead frames by immersion plating in a bath containing potassium silver cyanide, potassium cyanide, and a mercaptan inhibitor. The thickness of films was measured by microfocus x-ray fluorescence and cross-checked by Rutherford backscattering spectrometry. Lead frames coated with silver films were oxidized at 150 to 200°C in a controlled humidity oven. The amount of oxide formed was measured by an electrolytic reduction technique and cr

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31

Dearling, Jason L. J. "Hypoxia targeting copper complexes." Thesis, University of Kent, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297352.

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32

Lu, Qin. "Copper complexes of polyazacryptands." Thesis, Open University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.298997.

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33

Amaral, Carlos Henrique Oliveira do. "Síntese e cristaloquímica do 1-(4-carboxifenil)-3-(4-acetilamidofenil)triazeno e complexos de cobre(i), prata(I) e ouro(I) com o ligante 1-(4-nitrofenil)-3-(4-etoxicarboxifenil)triazenido." Universidade Federal de Santa Maria, 2007. http://repositorio.ufsm.br/handle/1/10414.

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This work deals with the determination of the single crystal structure analysis of four triazenido complexes including gold(I), copper(I), silver(I), and the crystal structure of a free triazene molecule. Crystal data and refinement indices of 1-(4-carboxyphenyl)-3-(4- acetylamidophenyl)triazene (1) are: monoclinic system, space group P21/n, cell parameters a = 7.772(1), b = 9.7365(2), c = 19.55(3) Å, β = 93.435(1)º, Z = 4, R1 = 0.0394, wR2 = 0.0632. The crystal structure show that the molecule deviates significantly from planarity (r.m.s. 0.342 Å). The molecules of (1) are associated to a bi-

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34

Golder, Ryan. "Silver Complexes of Azobenzene and Derivatives." Thesis, University of Canterbury. Chemistry, 2012. http://hdl.handle.net/10092/9353.

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Thirty four silver(I) complexes of azobenzene and derivatives have been synthesised, only two of which have been previously published. The azobenzene derivatives used are 2-bromo, 3-bromo, 4-bromo, 3,4’-dibromo, 2,4’-dibromo, 3-nitro, 4-dimethylamino, 4-methoxy, 2,6-dimethyl-4’-chloro, 2,6,2’,6’-tetramethyl and 2,2’-ethyleneazobenzene. 2,2’- and 4,4’-azobispyridine were also used along with diphenyltriazine. Six different silver(I) salts were used to make the complexes; they are tetrafluoroborate, hexafluorophosphate, perchlorate, nitrate, triflate and trifluoroacetate. All of the complexes we

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35

Mardani, Shabnam. "Copper and Silver Metallization for High Temperature Applications." Doctoral thesis, Uppsala universitet, Fasta tillståndets elektronik, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-300796.

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High-temperature electrical- and morphological-stability of interconnect is critical for electronic systems based on wide band gap (WBG) semiconductors. In this context, the thermal stability of both Ag and Cu films with Ta and TaN films as diffusion barriers and/or surface-capping layers at high temperatures up to 800 oC is investigated in this thesis. The investigation of un-capped Ag films with either Ta or TaN diffusion barrier layers shows electrical stability upon annealing up to 600 °C. Degradation occurs above 600 °C mainly as a result of void formation and Ag agglomeration. Sandwichin

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36

Salaudeen, Abibat Abisola. "Switchable iron and copper complexes." Thesis, University of Leeds, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.522980.

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37

Botez, Cristian E. "Synchrotron x-ray scattering studies of metallic surfaces /." free to MU campus, to others for purchase, 2002. http://wwwlib.umi.com/cr/mo/fullcit?p3052151.

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38

Madkhali, Osama. "Structural, optical and electrical properties of copper and silver-copper iodide thin films." Electronic Thesis or Diss., Université de Lorraine, 2021. http://www.theses.fr/2021LORR0253.

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Dans cette thèse, nous avons étudié la formation de couches minces d'iodure de cuivre (CuI) et d'iodure de cuivre argent (Ag,Cu)I à partir d'une procédure en deux étapes : dépôt d'un film métallique par pulvérisation magnétron et ioduration dans de la vapeur d'iode. De nombreuses techniques ont été utilisées pour déterminer les propriétés des films telles que : diffraction des rayons X, microscopie électronique à transmission, effet Hall, spectroscopie UV-visible… Pour les films CuI, nous avons obtenu des films semi- conducteurs transparents de type p cristallisant dans une structure type γ-Cu

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39

Bolger, Paul Thomas. "The electrochemistry of silver co-ordination complexes." Thesis, Queen's University Belfast, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.287292.

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40

Lamontagne, Marc Philip. "The effect of impurities on the distribution of silver between copper and copper selenide." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1996. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/nq20567.pdf.

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41

Schwaiger, Ruth. "Fatigue behavior of sub-micron silver and copper films." Stuttgart : Max-Planck-Inst. für Metallforschung, 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=964216345.

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42

Schwaiger, Ruth. "Fatigue behavior of sub-micron silver and copper films." [S.l. : s.n.], 2001. http://www.bsz-bw.de/cgi-bin/xvms.cgi?SWB9803839.

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43

Heslop, Julia M. "Copper complexes with potential radiopharmaceutical applications." Thesis, University of Oxford, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.418800.

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44

Ashfield, Laura. "Copper complexes with potential biomedical applications." Thesis, University of Oxford, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.426384.

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45

Trotter, Katherine D. "Copper complexes as putative contrast agents." Thesis, University of Strathclyde, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.538815.

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46

Taylor, Michelle K. "Copper complexes as putative imaging agents." Thesis, University of Strathclyde, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.424316.

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47

Hueting, Rebekka. "Radiolabelled copper complexes for cancer imaging." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:47438968-6aa3-41f5-82b4-9121dc327b53.

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Chapter One introduces molecular irnaging and the modalities available for oncological irnaging. The radioisotopes and imaging agents for Positron Emission Tomography (PET) and Single Photon Emission Computed Tomography (SPECT) are discussed together with the bifunctional chelator approach for radio labelling of biomolecules. Finally, the chemistry and radioisotopes of copper are described, and copper bis(thiosemicarbazonato) complexes introduced in the context of PET irnaging. Chapter Two describes the synthesis and characterisation of novel carboxylate- and maleirnide- functionalised bis(thi

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48

Karabaeva, Kanykey E. "Photochemistry of dipyridyl-phenanthrenedioxin-copper complexes." Bowling Green State University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1530026213399288.

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49

Pateman, Andrew Glen. "Copper catalysed aziridination reactions." Thesis, University College London (University of London), 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.314288.

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50

Mat-Zain, Norashikin. "Development of antimicrobial fabrics based on silver and copper nanoparticles." Thesis, Loughborough University, 2015. https://dspace.lboro.ac.uk/2134/16611.

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With growing public unease surrounding the extent of microbial infections, there is a demand for antimicrobial materials including antimicrobial textiles. Nanotechnology has provided new solutions for the development of antimicrobial fabrics. In this study, nanoparticles of silver (Ag) and copper (Cu) and alloy nanoparticles of Ag and Cu (Ag/Cu) have been synthesized by reduction of their respective nitrates by ascorbic acid, using chitosan as a stabilising agent and microwave heating. UV-vis spectrophotometry indicated the presence of the alloy by a single peak (500 nm) for Ag/Cu nanoparticle

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