Academic literature on the topic 'Cyanides, chemistry'

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Journal articles on the topic "Cyanides, chemistry"

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Muderawan, I. Wayan, I. Wayan Karyasa, I. Nyoman Tika, and Gede Agus Beni Widana. "Chemistry and Biology of Cyanides: A Literature Review." Indonesian Journal of Chemistry and Environment 6, no. 2 (2023): 63–82. http://dx.doi.org/10.21831/ijoce.v6i2.67030.

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The term cyanide is used to describe compounds that contain the cyano, -C≡N, group. The cyanides exist in nature as inorganic as well as organic compounds in the forms of gas or liquid such as HCN, CNCl and acetonitrile, or solids such as NaCN, KCN, and Ca(CN)2. Cyanide compounds are also found in addible plants as cyanogenic glycosides. Compounds that can release cyanide are known as cyanogenic compounds. HCN has a low boiling point (25.63 oC) and is as weakly acidic with a pKa 9.2. It partially ionizes in water to give the cyanide anion, -CN. Cyanide ion from salt reacts with acid to give HC
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Usachev, Boris. "Chemistry of Fluoroalkyl Cyanides." Arkivoc 2020, no. 1 (2020): 499–577. http://dx.doi.org/10.24820/ark.5550190.p011.339.

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Szuromi, P. D. "CHEMISTRY: Oxidizing Organic Cyanides." Science 310, no. 5748 (2005): 593c. http://dx.doi.org/10.1126/science.310.5748.593c.

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Connors, Richard, Elisabeth Tran, and Tony Durst. "Acyl cyanides as carbonyl heterodienophiles: application to the synthesis of naphthols, isoquinolones, and isocoumarins." Canadian Journal of Chemistry 74, no. 2 (1996): 221–26. http://dx.doi.org/10.1139/v96-024.

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Irradiation of 2-methylbenzoyl cyanide (3a) in acetonitrile solution results in the formation of its dimer, which upon loss of HCN gives rise to the cycloadduct 7a. The dimerization also proceeds efficiently with derivatives of 3a giving adducts 7b and 7c. When 2-methylaroyl cyanides are photolyzed in the presence of a more reactive acyl cyanide the mixed adducts 8a–e are obtained in excellent yields. The cycloadducts 7a–c and 8a–e react with carbon and nitrogen nucleophiles by a tandem addition–cyclization sequence furnishing substituted naphthols (10a and 10b) and isoquinolones (11a–d), resp
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Majewski, Marek, Marc DeCaire, Pawel Nowak, and Fan Wang. "Studies on enolate chemistry of 8-thiabicyclo[3.2.1]- octan-3-one: enantioselective deprotonation and synthesis of sulfur analogs of tropane alkaloids." Canadian Journal of Chemistry 79, no. 11 (2001): 1792–98. http://dx.doi.org/10.1139/v01-157.

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Enantioselective deprotonation of 8-thiabicyclo[3.2.1]octan-3-one (1) with chiral lithium amides, followed by reactions with electrophiles affords sulfur analogs of tropane alkaloids of pyranotropane family. Thus, deprotonation of 1 with (S)-N-(diphenyl)methyl-1-phenylethylamine (11d), followed by the reaction of the resulting nonracemic enolate with benzaldehyde gives the corresponding aldol product as one diastereoisomer (exo, threo) and in high enanatiomeric purity (95% ee). Trimethylsilyl chloride, acetic anhydride, and acyl cyanides react readily with the lithium enolate to give the corre
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S., SUNITA, and K. GUPTA V. "Spectrophotometric Determination of Cyanide in Biological Samples using A New Reagent." Journal of Indian Chemical Society Vol. 64, Jul 1987 (1987): 431–33. https://doi.org/10.5281/zenodo.6196609.

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Department of Chemistry, Ravishankar University, Ralpur-192 010 <em>Manuscript received 7 January 1987, revised 24 April 1987, accepted 6 July 1987</em> A new sensitive spectrophotometric determination of cyanide in polluted river water and biological samples is described. Cyanides con&shy;verted into cyanogenbromide reacts with pyridine to give glutaconic aldehyde which is subsequently condensed with sulphanilic acid to give a yellowish orange coloured dye. Beer&#39;s law is obeyed at 460 nm in the range of 5 - 30 <em>&micro;g</em>&nbsp;of cyanide per 10 ml of the final solution (0.5 - 3 ppm)
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Kudelska, Wieslawa. "Synthesis of Glycosyl Cyanides by the Reaction of 1-S-Phosphorothioates of Carbohydrates with Trimethylsilyl Cyanide." Zeitschrift für Naturforschung B 53, no. 11 (1998): 1277–80. http://dx.doi.org/10.1515/znb-1998-1107.

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A new procedure is described for the synthesis of α,β-glycosyl cyanides by the reaction of per-O-benzylated S-α-ᴅ-glycopyranosyl phosphorothioates with trimethylsilyl cyanide in the presence of Lewis acid. Starting S-glycosyl phosphorothioates are prepared, directly, from O-benzyl protected reducing D-hexopyranoses (gluco-, galacto-, manno-) and alkylammonium salt of phosphorothioic acid under Lewis acid catalysis.
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Kettle, Sidney F. A., Eliano Diana, Enrico Boccaleri, and Pier Luigi Stanghellini. "The Vibrational Spectra of the Cyanide Ligand Revisited. Bridging Cyanides." Inorganic Chemistry 46, no. 7 (2007): 2409–16. http://dx.doi.org/10.1021/ic0610482.

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Kettle, Sidney F. A., Gian Luca Aschero, Eliano Diana, Rosanna Rossetti, and Pier Luigi Stanghellini. "The Vibrational Spectra of the Cyanide Ligand Revisited: Terminal Cyanides." Inorganic Chemistry 45, no. 13 (2006): 4928–37. http://dx.doi.org/10.1021/ic0514041.

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Jobe, David J., and Kenneth Charles Westaway. "Fourier transform infrared spectroscopy studies of cyanide ion solutions of dimethylformamide and aqueous dimethylformamide." Canadian Journal of Chemistry 71, no. 9 (1993): 1353–61. http://dx.doi.org/10.1139/v93-175.

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Fourier transform infrared spectroscopy has been used to investigate the behaviour of HCN and alkali metal and tetraethylammonium cyanides in DMF and aqueous DMF. The cyanide ion exists as free ions and ion pairs in pure DMF but as water-solvated and DMF-solvated ions in aqueous DMF. The aqueous DMF solutions can be treated as a pseudo two-phase system with a distribution coefficient of 0.018 between the aqueous and DMF-rich pseudo phases. A kinetic analysis of the cyanide ion – benzyl chloride reaction in DMF and aqueous DMF has shown that the rate constant for the SN2 reaction is markedly de
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Dissertations / Theses on the topic "Cyanides, chemistry"

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Wei, YiQiu. "The chemistry of 2,3-unsaturated glycosyl cyanides." Scholarly Commons, 1991. https://scholarlycommons.pacific.edu/uop_etds/2225.

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Carbohydrate research remains one of the most exciting endeavors in the field of organic chemistry. The importance of carbohydrates needs little elaboration. Quite literally, without glucose, cellulose, and starch, the necessities of life such as food, clothing, and shelter would be missing. In our laboratory, we have for some time been interested in one particular class of carbohydrate derivatives - the aldohexopyranosyl cyanides.
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Marelli, Elena. "New chemistry and physics from transition-metal cyanides." Thesis, University of Reading, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627647.

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Eversfield, Sharon Gail. "An investigation of some disordered transition metal sulfides and cyanides." Thesis, University of Reading, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.288770.

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Knoeppel, David W. "Rare earths and transition metal cyanides: building blocks to solid state polymers /." The Ohio State University, 1995. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487868114110388.

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Savage, Chandra Shannon. "Ions, isotopes, and metal cyanides: Observational and laboratory studies." Diss., The University of Arizona, 2004. http://hdl.handle.net/10150/290082.

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Chemistry in the interstellar medium is very different from the processes which take place in terrestrial settings. Environments such as circumstellar envelopes, molecular clouds, and comets contain diverse and complex chemical networks. The low temperatures (10-50 K) and densities (1-10⁶ cm⁻³) allow normally unstable molecules to exist in significant quantities. At these temperatures, the rotational energy levels of molecules are populated, and thus these species can be detected by millimeter-wave radio astronomy. The detection and quantification of interstellar molecules, including metal cya
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Phiasivongsa, Pasit. "Synthesis of saccharomimetic fucopyranosyl -substituted urethanes and ureas from glycopyranosyl nitromethanes and cyanides." Scholarly Commons, 2002. https://scholarlycommons.pacific.edu/uop_etds/2699.

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Part I . Mechanistic intermediates were discovered in the Henry condensations of partially and non-protected pyranoses with a free anomeric hemiacetal function with nitromethane in various solvents for the syntheses of C-glycopyranosides in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)/molecular sieves catalyst system. Part II . Syntheses of glycosyl cyanides were optimized with a new catalyst system. Mechanism of cyanation with trimethylsilyl cyanide (TMS-CN) in the presence of the mild and recyclable Lewis acid HgBr 2 in nitromethane were proposed for the syntheses of 1,2-trans pe
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Lawrence, A. Raelene. "A computational investigation of inorganic systems using ab initio methods /." free to MU campus, to others for purchase, 2000. http://wwwlib.umi.com/cr/mo/fullcit?p9998495.

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Broomsgrove, Alexander Edward John. "Ferrocene based Lewis acids for anion sensing." Thesis, University of Oxford, 2010. http://ora.ox.ac.uk/objects/uuid:bfab3690-f1de-4c8d-b111-ce9083710b16.

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The synthesis, characterisation and anion binding properties of a series of mono- and bifunctional Lewis acidic borylferrocene compounds are described within this thesis. The original parent compound FcBMes₂ (3.1), revealed a versatile route for the synthesis of such borylferrocenes and subsequently the analogous compound Fc*BMes₂ (3.2) was synthesised. The anion binding properties of (3.1) and (3.2) were investigated and both were shown to bind one equivalent of cyanide. The binding event was signalled by an electrochemical shift (ca. -560 mV) and a quenching of bands at 510 or 542 nm respect
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Wilson, Duane C. "Synthesis, Structure, And Characterization Of Rare Earth(Iii) Transition Metal Cyanides; Lanthanide(Ii) And Metallocene Amidotrihydroborates." Columbus, Ohio : Ohio State University, 2009. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1230880974.

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Drew, Kenneth Nickolas. "C-glycoside syntheses: (I) Henry condensations of 4,6-O-alkylidene pyranoses with a 1,3 proton transfer catalyst: A route to blocked aminomethyl-C-glycosides, and (II) Glycosyl cyanides and isocyanides from glycosyl fluorides with full acetal protection." Scholarly Commons, 1991. https://scholarlycommons.pacific.edu/uop_etds/2815.

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The goal of this research project was to develop two converging synthetic methods to form C-glycosides, specifically aminomethyl C-glycosides. Part I. A novel catalyst system consisting of 2-hydroxypyridine (2-HP)/1,8-diazabicyclo (5.4.0) undec-7-ene (DBU)/molecular sieves can catalyze 1,3 proton transfers in organic solvents under neutral or slightly basic conditions, adjustable by the 2-HP/DBU ratio. In the presence of the catalyst system, 4,6-O-benzylidene- scD-glycopyranose (1), 4,6-O-isopropylidene- scD-mannose (12), and 4,6-O-isopropylidene- scD-gluco-pyranose (16) undergo Henry condensa
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Books on the topic "Cyanides, chemistry"

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Flynn, C. M. Cyanide chemistry: Precious metals processing and waste treatment. U.S. Dept. of the Interior, Bureau of Mines, 1995.

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S, Ghosh Rajat, and Wong-Chong George M, eds. Cyanide in water and soil: Chemistry, risk, and management. Taylor & Francis, 2005.

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Simpson, W. W. Calcium sulfide precipitation of mercury from gold-silver-cyanide leach slurries. U.S. Dept. of the Interior, Bureau of Mines, 1986.

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Simpson, W. W. Calcium sulfide precipitation of mercury from gold-silver-cyanide leach slurries. U.S. Bureau of Mines, 1986.

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Roald, Dahl. The Collected Short Stories of Roald Dahl: Volume I. Charnwood, 1994.

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Dahl, Roald. The complete tales of the unexpected and other stories. Folio Society, 2001.

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Roald, Dahl. The Collected Short Stories. 3rd ed. Penguin Books, 1992.

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Roald, Dahl. The Collected Short Stories of Roald Dahl: An omnibus volume containing: ; Kiss, kiss ; Over to you ; Switch bitch ; Someone like you ; and eight further tales of the unexpected. Michael Joseph, 1991.

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Roald, Dahl. The Collected Short Stories of Roald Dahl: An omnibus volume containing Kiss, kiss, Over to you, Switch bitch, Someone like you, and eight further tales of the unexpected. M. Joseph, 1991.

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Roald, Dahl. Collected Stories. Edited by Jeremy Treglown. Alfred A. Knopf, 2006.

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Book chapters on the topic "Cyanides, chemistry"

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Socha, A., E. Kuśmierek, and M. Kaźmierczak. "Simultaneous Electrooxidation of Cyanides and Recovery of Copper on Carbon Fibre." In Chemistry for the Protection of the Environment 3. Springer US, 1998. http://dx.doi.org/10.1007/978-1-4757-9664-3_19.

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Korzeniak, Tomasz, Beata Nowicka, and Barbara Sieklucka. "Hybrid Organic–Inorganic Cyanide-Bridged Networks." In Topics in Organometallic Chemistry. Springer International Publishing, 2018. http://dx.doi.org/10.1007/3418_2018_2.

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Andraos, John, and Albert S. Matlack. "Doing without Phosgene, Hydrogen Cyanide, and Formaldehyde." In Introduction to Green Chemistry, 3rd ed. CRC Press, 2022. http://dx.doi.org/10.1201/9781003033615-2.

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Dunbar, Kim R., and Robert A. Heintz. "Chemistry of Transition Metal Cyanide Compounds: Modern Perspectives." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166468.ch4.

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Armitage, Bruce A. "Cyanine Dye–Nucleic Acid Interactions." In Topics in Heterocyclic Chemistry. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/7081_2007_109.

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Shatruk, Michael, Carolina Avendano, and Kim R. Dunbar. "Cyanide-Bridged Complexes of Transition Metals: A Molecular Magnetism Perspective." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2009. http://dx.doi.org/10.1002/9780470440124.ch3.

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Armitage, Bruce A. "Cyanine Dye–DNA Interactions: Intercalation, Groove Binding, and Aggregation." In Topics in Current Chemistry. Springer Berlin Heidelberg, 2005. http://dx.doi.org/10.1007/b100442.

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Larivé, Henri, and René Dennilauler. "Cyanine Dyes Derived from Thiazolium Salts." In Chemistry of Heterocyclic Compounds: A Series Of Monographs. John Wiley & Sons, Inc., 2008. http://dx.doi.org/10.1002/9780470187074.ch2.

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Patsenker, Leonid D., Anatoliy L. Tatarets, Oleksii P. Klochko, and Ewald A. Terpetschnig. "Conjugates, Complexes, and Interlocked Systems Based on Squaraines and Cyanines." In Advanced Fluorescence Reporters in Chemistry and Biology II. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-04701-5_5.

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Socha, A., and E. Kuśmierek. "Electrochemical Oxidation of Cyanide Complexes with Copper at Carbon Fibre." In Chemistry for the Protection of the Environment 2. Springer US, 1996. http://dx.doi.org/10.1007/978-1-4613-0405-0_31.

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Conference papers on the topic "Cyanides, chemistry"

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Li, H., P. Constantineau, C. Zhuang, and Y. H. Hou. "Real Time Sour Water Corrosion Prediction for Fluid Catalytic Cracking Overhead System." In CONFERENCE 2023. AMPP, 2023. https://doi.org/10.5006/c2023-18785.

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Abstract Crude feed often contains contaminants such as sulfur and nitrogen compounds, which can react with hydrogen to form hydrogen sulfide (H2S) and ammonia (NH3) and can lead to formation of ammonium bisulfide salts (NH4HS) when cooled. Water washing ahead of NH4HS salt formation is a common practice to prevent wet salt corrosion. However, the dissolved ammonium bisulfide (in the aqueous phase) can still cause significant corrosion across equipment exposed to alkaline sour water. Such corrosion may be exacerbated by presence of cyanides, high levels of wall shear stress as well as high ope
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Gupta, Harshal, Michael McCarthy, Stephan Schlemmer, Oskar Asvany, Sven Thorwirth, and Kelvin Lee. "PROTONATED ETHYL CYANIDE: QUANTUM CHEMISTRY AND ROTATIONAL SPECTROSCOPY." In 2022 International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2022. http://dx.doi.org/10.15278/isms.2022.fg08.

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Pattipeilohy, Merry, Anthonia Raturenan Ditimasa Lakfo, and Th Watiguly. "Reduction of cyanide acid content of black cassava based on soaking and boiling time." In 1ST INTERNATIONAL SEMINAR ON CHEMISTRY AND CHEMISTRY EDUCATION (1st ISCCE-2021). AIP Publishing, 2023. http://dx.doi.org/10.1063/5.0124615.

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Schnermann, Martin. "Cyanine fluorophore chemistry to enable dynamic and multicolor in vivo imaging." In Molecular-Guided Surgery: Molecules, Devices, and Applications VII, edited by Summer L. Gibbs, Brian W. Pogue, and Sylvain Gioux. SPIE, 2021. http://dx.doi.org/10.1117/12.2595594.

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Darmajana, Doddy Andy, and Novianti Wulandari. "The reduction of hydrogen cyanide (HCN) and the measurement of antioxidant activity in bamboo shoot as the raw material for cookies." In PROCEEDINGS OF THE 5TH INTERNATIONAL SYMPOSIUM ON APPLIED CHEMISTRY 2019. AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5134600.

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Wardani, Nila, Meidaliyantisyah, Danarsi Diptaningsari, Ratna Wylis Arief, and Robet Asnawi. "Determination of cyanide content in ten cassava varieties and its influence on infestation of the invasive cassava mealybug, Phenacoccus manihoti in Lampung, Indonesia." In INTERNATIONAL CONFERENCE ON ORGANIC AND APPLIED CHEMISTRY (ICOAC) 2022. AIP Publishing, 2024. http://dx.doi.org/10.1063/5.0184058.

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SI, SHU-FENG, QING-LUN WANG, and DAI-ZHENG LIAO. "[Mn(salAren)(H2O)]2[Fe(CN)5(NO)]·2CH3OH·3H2O: A NEW TRINUCLEAR COMPLEX WITH CYANIDE BRIDGES AND HYDROGEN BONDS." In Proceedings of the International Symposium on Solid State Chemistry in China. WORLD SCIENTIFIC, 2002. http://dx.doi.org/10.1142/9789812776846_0042.

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Bethge, Lucas, and Oliver Seitz. "New cyanine dyes as base surrogates in peptide nucleic acid (PNA): extending the utility of forced intercalation probes (FIT-probes)." In XIVth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2008. http://dx.doi.org/10.1135/css200810317.

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Markov, Roman V., Alexander I. Plekhanov, Sergei G. Rautian, Zoya M. Ivanova, Natalja A. Orlova, and Vladimir V. Shelkovnikov. "Nonlinear optical properties of cyanine dye J-aggregates in thin films measured by Z-scan technique." In ICONO '98: Laser Spectroscopy and Optical Diagnostics--Novel Trends and Applications in Laser Chemistry, Biophysics, and Biomedicine, edited by Konstantin N. Drabovich, V. I. Emelyanova, and Vladimir A. Makarov. SPIE, 1999. http://dx.doi.org/10.1117/12.342359.

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