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Dissertations / Theses on the topic 'Cyanides, chemistry'

Author: Grafiati

Published: 4 June 2021

Last updated: 29 July 2025

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1

Wei, YiQiu. "The chemistry of 2,3-unsaturated glycosyl cyanides." Scholarly Commons, 1991. https://scholarlycommons.pacific.edu/uop_etds/2225.

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Carbohydrate research remains one of the most exciting endeavors in the field of organic chemistry. The importance of carbohydrates needs little elaboration. Quite literally, without glucose, cellulose, and starch, the necessities of life such as food, clothing, and shelter would be missing. In our laboratory, we have for some time been interested in one particular class of carbohydrate derivatives - the aldohexopyranosyl cyanides.

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2

Marelli, Elena. "New chemistry and physics from transition-metal cyanides." Thesis, University of Reading, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627647.

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3

Eversfield, Sharon Gail. "An investigation of some disordered transition metal sulfides and cyanides." Thesis, University of Reading, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.288770.

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4

Knoeppel, David W. "Rare earths and transition metal cyanides: building blocks to solid state polymers /." The Ohio State University, 1995. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487868114110388.

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5

Savage, Chandra Shannon. "Ions, isotopes, and metal cyanides: Observational and laboratory studies." Diss., The University of Arizona, 2004. http://hdl.handle.net/10150/290082.

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Chemistry in the interstellar medium is very different from the processes which take place in terrestrial settings. Environments such as circumstellar envelopes, molecular clouds, and comets contain diverse and complex chemical networks. The low temperatures (10-50 K) and densities (1-10⁶ cm⁻³) allow normally unstable molecules to exist in significant quantities. At these temperatures, the rotational energy levels of molecules are populated, and thus these species can be detected by millimeter-wave radio astronomy. The detection and quantification of interstellar molecules, including metal cya

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6

Phiasivongsa, Pasit. "Synthesis of saccharomimetic fucopyranosyl -substituted urethanes and ureas from glycopyranosyl nitromethanes and cyanides." Scholarly Commons, 2002. https://scholarlycommons.pacific.edu/uop_etds/2699.

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Part I . Mechanistic intermediates were discovered in the Henry condensations of partially and non-protected pyranoses with a free anomeric hemiacetal function with nitromethane in various solvents for the syntheses of C-glycopyranosides in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)/molecular sieves catalyst system. Part II . Syntheses of glycosyl cyanides were optimized with a new catalyst system. Mechanism of cyanation with trimethylsilyl cyanide (TMS-CN) in the presence of the mild and recyclable Lewis acid HgBr 2 in nitromethane were proposed for the syntheses of 1,2-trans pe

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7

Lawrence, A. Raelene. "A computational investigation of inorganic systems using ab initio methods /." free to MU campus, to others for purchase, 2000. http://wwwlib.umi.com/cr/mo/fullcit?p9998495.

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8

Broomsgrove, Alexander Edward John. "Ferrocene based Lewis acids for anion sensing." Thesis, University of Oxford, 2010. http://ora.ox.ac.uk/objects/uuid:bfab3690-f1de-4c8d-b111-ce9083710b16.

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The synthesis, characterisation and anion binding properties of a series of mono- and bifunctional Lewis acidic borylferrocene compounds are described within this thesis. The original parent compound FcBMes₂ (3.1), revealed a versatile route for the synthesis of such borylferrocenes and subsequently the analogous compound Fc*BMes₂ (3.2) was synthesised. The anion binding properties of (3.1) and (3.2) were investigated and both were shown to bind one equivalent of cyanide. The binding event was signalled by an electrochemical shift (ca. -560 mV) and a quenching of bands at 510 or 542 nm respect

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9

Wilson, Duane C. "Synthesis, Structure, And Characterization Of Rare Earth(Iii) Transition Metal Cyanides; Lanthanide(Ii) And Metallocene Amidotrihydroborates." Columbus, Ohio : Ohio State University, 2009. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1230880974.

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10

Drew, Kenneth Nickolas. "C-glycoside syntheses: (I) Henry condensations of 4,6-O-alkylidene pyranoses with a 1,3 proton transfer catalyst: A route to blocked aminomethyl-C-glycosides, and (II) Glycosyl cyanides and isocyanides from glycosyl fluorides with full acetal protection." Scholarly Commons, 1991. https://scholarlycommons.pacific.edu/uop_etds/2815.

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The goal of this research project was to develop two converging synthetic methods to form C-glycosides, specifically aminomethyl C-glycosides. Part I. A novel catalyst system consisting of 2-hydroxypyridine (2-HP)/1,8-diazabicyclo (5.4.0) undec-7-ene (DBU)/molecular sieves can catalyze 1,3 proton transfers in organic solvents under neutral or slightly basic conditions, adjustable by the 2-HP/DBU ratio. In the presence of the catalyst system, 4,6-O-benzylidene- scD-glycopyranose (1), 4,6-O-isopropylidene- scD-mannose (12), and 4,6-O-isopropylidene- scD-gluco-pyranose (16) undergo Henry condensa

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11

Wingstrand, Erica. "New Methods for Chiral Cyanohydrin Synthesis." Doctoral thesis, KTH, Kemi, 2009. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-10205.

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This thesis deals with method development in asymmetric catalysis and specifically syntheses of enantioenriched O-functionalized cyanohydrins. The first part describes the development of a method for the synthesis of O‑alkoxycarbonylated and O-acylated cyanohydrins. Ethyl cyanoformate and acyl cyanides were added to aldehydes in a reaction catalyzed by a chiral dimeric Ti-salen complex together with a tertiary amine. High yields and enantioselectivities were in most cases obtained. Mechanistic studies were performed and a reaction mechanism was proposed. The second part describes a method in

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12

Hovstadius, Peter. "Preclinical and Clinical Development of the Novel Cyanoguanidine CHS 828 for Cancer Treatment." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis : Univ.-bibl. [distributör], 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-6178.

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13

Kurnia, Drs. "The analytical chemistry of cyanide in acetonitrile-water mixtures." Thesis, Drs Kurnia, (1995) The analytical chemistry of cyanide in acetonitrile-water mixtures. PhD thesis, Murdoch University, 1995. https://researchrepository.murdoch.edu.au/id/eprint/51574/.

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A method for the simultaneous determination of total gold and available cyanide in gold cyanidation solutions has been investigated. Total gold and available cyanide in cyanidation solutions are determined by ion exchange chromatography-HPLC under slightly acidic conditions. Cyanide is determined by measuring the peak height associated with the formation of the nickel-cyanide complex which is formed by adding an excess of nickel(II) to the gold cyanidation solution. The nickel(D)-cyanide complex is not strong enough to dissociate the very strong dicyanoaurate(I). Anion exchange is used for the

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14

Llamas-Rey, Estefania. "Redox-active cyanide-bridged dimanganese complexes." Thesis, University of Bristol, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.390645.

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15

Liau, Ruei-Yang. "Contributions to the chemistry of gold(I) cyanide, isocyanide and acetylide complexes." [S.l. : s.n.], 2003. http://deposit.ddb.de/cgi-bin/dokserv?idn=969392613.

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16

Jonas, David Michael. "Spectroscopy of vibrationally hot molecules : hydrogen cyanide and acetylene." Thesis, Massachusetts Institute of Technology, 1992. http://hdl.handle.net/1721.1/117236.

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17

Hodgson, Martin. "Studies of the catalysis of cyanide addition and substitution." Thesis, Durham University, 1988. http://etheses.dur.ac.uk/6409/.

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The chiral diphenylphosphinites of menthol and binaphthol have been prepared. The zerovalent palladium complexes of these phosphinites were found to be poor catalysts for the hydrocyanation of alkenes. The enantiomeric purity of the exo-norbornane carbonitrile produced from the hydrocyanation of norbornene catalysed by Pd(DI0P)(_2) was found to be considerably lower than originally surmised. In the same reaction, the zerovalent palladium complexes of BPPM and BINAP were found to give the highest reported enantiomeric purities for a transition metal catalysed hydrocyanation reaction. The mechan

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18

Westwood, Aidan Vincent Kevin. "The reactions of methysilylcyanides with Lewis acids." Thesis, University of Liverpool, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.316897.

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19

Kazee, Beth E. "The hydration of naphthalene-2,3-dicarboxaldehyde and the reaction with cyanide ion /." The Ohio State University, 1988. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487591658172729.

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20

Zhao, Xiaodong. "Studies of extended cyanines and related mixed valence compounds." Diss., Georgia Institute of Technology, 1995. http://hdl.handle.net/1853/28001.

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21

Abdelhameed, Ahmed M. "THE DESIGN AND SYNTHESIS OF CYANINES AND ARYLIMIDAMIDE AZOLE HYBRIDS AS ANTILESIHMANAIAL AGENTS." The Ohio State University, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=osu1525738213459762.

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22

Sevim, Ilhan. "Reactions Of Diethylaluminum Cyanide With Acyl Phosphonates." Master's thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/3/12611557/index.pdf.

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This thesis includes reaction of diethylaluminum cyanide with acyl phosphonates. Cyanohidrin O-phosphates are synthesized from easily available acyl phosphonates and diethylaluminum cyanide. Synthesis of cross-benzoin product of acyl phosphonate, &amp<br>#945<br>-hydroxy phosphonate and tertiary carbinol are synthesized from the reaction of diethylaluminum cyanide with acyl phosphonates, representatively. Asymmetric syntheses of cyanohydrin and benzoin type reaction of acyl phoshonate are also investigated representatively.

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23

Du, Bin. "Syntheses and structure characterizations of multi-dimensional cyanide bridged lanthanide-transition metal arrays : studies on their magnetic properties /." The Ohio State University, 2000. http://rave.ohiolink.edu/etdc/view?acc_num=osu1488195154359587.

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24

Eseonu, Dorothy N. "Reactions of Substituted Pyridinium Salts with Cyanide; Formation and Metal Complexes of 2,2'bis (hydroxymethyl)-4,-4'bipyridine." VCU Scholars Compass, 1989. http://scholarscompass.vcu.edu/etd/4549.

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The unique combination of properties of bipyridinium salts and their use in biological systems, chemical reactions, and as herbicides in agriculture have made them a discovery of major international importance. The controversy about the position of attack of the cyanide ion on the pyridine ring and the discovery of the formation of unsubstituted bipyridinium salts from the reaction of pyridinium salt with cyanide ion opened a new area of research. The current work involved a study of reactions of substituted pyridinium salts with cyanide ion. The substituted pyridinium salts were prepared by t

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25

Elsegood, Simon Edward. "Some kinetic mechanistic and synthetic studies of the reactions of cyanide ions with aromatic nitro-compounds." Thesis, Durham University, 1991. http://etheses.dur.ac.uk/6161/.

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The reactions of cyanide ions with some benzene derivatives activated with electron-withdrawing groups have been studied in methanol, and in DMSO, and in mixtures of these solvents. The studies have involved spectroscopic measurements of reactants, intermediates and products together with kinetic measurements and the isolation of reaction products. The techniques used include uv/visible spectrophotometry, proton N.M.R. spectroscopy, e.s.r. spectroscopy, polarography and H.P.L.C. There is evidence from the reaction of 1,3,5-trinitrobenzene with excess cyanide in methanol that methanolysis of th

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26

Chingakule, Dicky Dunn Kanakholeya. "Ion-association and complexation by cyanide, thiocyanate and azide anions in liquid ammonia and other non-aqueous media." Thesis, University of Leeds, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.277394.

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27

Leeming, S. W. "An investigation of those structural features necessary for copper-promoted nucleophilic substitution of aromatic halogen compounds by cyanide ion." Thesis, University of Kent, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373239.

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28

King, Harry M. Jr. "Spectral and Kinetic Studies of the Interaction of Cyanide and Detergents with Cobalt (II) Phthalocyanine in DMSO." TopSCHOLAR®, 1988. http://digitalcommons.wku.edu/theses/1765.

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Spectral and kinetic studies made on CoPc over a concentration range of 1.72 x 10-6M – 1.00 x 10-5M in DMSO are consistent with a monomer-dimer equilibrium at 303 K. The dimerization constant obtained at 303 K is 1.67 x 104M-1 and is two to three orders of magnitude smaller than those of several tetrasulfonated metallophthalocyanines in aqueous solution. The rate constants for the formation and dissociation of the CoPc dimer in DMSO at 303 K are 1.29 x 102M-1s-1 and 7.20 x 10-3s-1, respectively. The low dimerization constant for CoPc in DMSO is attributed to its relatively slow rate of dimer f

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29

Lim, Soyoung. "Part I. Syntheses and characterization of hydrogen-bridged Lanthanide(II)-Boron complexes ; Part II. Syntheses and characterization of Cyanide-bridged Lanthanide (III)-Palladium complexes /." The Ohio State University, 2001. http://rave.ohiolink.edu/etdc/view?acc_num=osu1486399451960783.

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30

Davies, Graham M. "The coordination chemistry of functionalised poly(pyrazol-1-yl)borate ligands and the photophysical properties of cyanide-bridged d-f hybrids." Thesis, University of Sheffield, 2006. http://etheses.whiterose.ac.uk/3584/.

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The content of this thesis is concerned with two distinctly independent areas of research: (i) the synthesis and study of new poly(pyrazol-1-yl)borate ligands and their metal complexes; (ii) crystallographic and photophysical studies of new d-f hybrid complexes. Chapter One is divided into three parts: Part one gives a general introduction to poly(pyrazol-1-yl)borate chemistry along with a concise and up-to-date review of those ligands containing substituents in the C3 position of the pyrazolyl ring; part two provides a brief introduction into the physical properties of lanthanide(III) metal i

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31

Sturgeon, Matthew Robert. "Cyanide Bridged Multimetallics Derived From Extended Arrays of Alkaline Earth, Rare Earth, and Transition Metals: A Study From Complexes To Catalysts." The Ohio State University, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=osu1250009077.

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32

Donnart, Anna-Mélodie. "Molecular engineering of cyanide-bridged cubic complexes for molecular materials." Electronic Thesis or Diss., Sorbonne université, 2025. https://accesdistant.sorbonne-universite.fr/login?url=https://theses-intra.sorbonne-universite.fr/2025SORUS033.pdf.

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Les commutateurs moléculaires sont une famille de molécules capable de transiter de manière réversible entre deux (ou plus) états aux propriétés physiques différentes grâce à un stimuli (température, lumière, pression, électricité). Cette propriété particulière les rend très intéressants pour un grand nombre d'applications, des capteurs aux dispositifs pour l'électronique moléculaire. Cependant, l'intégration de ces molécules dans des matériaux est complexe car une perte des propriétés commutables est souvent observée. De nouveaux types de switches moléculaires pensés pour leur intégration dan

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33

Hallworth, Georgina Louise. "Exploring the influence of structural variation on the solution and solid-state behaviour of cyanine dyes." Thesis, University of Southampton, 2009. https://eprints.soton.ac.uk/72960/.

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Cyanine dyes are well known and extensively studied molecules. The preparations and investigations of a wide range of dyes have been previously reported. Here several novel and known compounds have been synthesised to investigate the effect molecular structure has on their bulk-solution and solid-state behaviour. The preparations of sulfur-containing tri- and monomethine dyes were more reliable, hence the majority of these studies concerned sulfur analogues. Successful crystallisation of these products resulted in many novel crystal structures being obtained and compared. The monomethine dyes

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34

Van, Wyk Andries Pieter. "Flowsheet development and comparison for the recovery of precious metals from cyanide leach solutions." Thesis, Stellenbosch : Stellenbosch University, 2014. http://hdl.handle.net/10019.1/86302.

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Thesis (MEng)--Stellenbosch University, 2014.<br>ENGLISH ABSTRACT: The Platreef ore deposit, situated in the Bushveld Igneous Complex, is one of the world’s largest platinum group metal (PGM) resources. The mineralogy of this resource is, however, unique as it consists of complex PGM mineralization with mainly copper and nickel, at very low PGM grades. The PGMs are mainly present in the ore as slow floating refractory minerals resulting in marginal process economics when processing via traditional mill-float-smelt processes. A new process is currently being investigated to extract PGMs from l

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35

Fernando, Nilmi T. "Novel Near-Infrared Cyanine Dyes for Fluorescence Imaging in Biological Systems." Digital Archive @ GSU, 2011. http://digitalarchive.gsu.edu/chemistry_diss/57.

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Heptamethine cyanine dyes are attractive compounds for imaging purposes in biomedical applications because of their chemical and photophysical properties exhibited in the near-infrared region. A series of meso amino-substituted heptamethine cyanine dyes with indolenine, benz[e]indolenine and benz[c,d]indolenine heterocyclic moieties were synthesized and their spectral properties including fluorescence quntum yield were investigated in ethanol and ethanol/water mixture. Upon substitution with amines, the absorption maxima of the dyes shifted to the lower wavelength region (~600 nm), showed lar

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36

Liu, Jianping. "Part I. Self-assembled, low-dimensional materials composed of both lanthanides and transition metals bridged by cyanate or cyanide groups. Part II. Syntheses and reactivity studies of cyclic organohydroborate anions in organic and organometallic.. /." The Ohio State University, 1997. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487943341528842.

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37

Chiu, Ching-Wen. "Synthesis, characterization, anion complexation and electrochemistry of cationic Lewis acids." [College Station, Tex. : Texas A&M University, 2008. http://hdl.handle.net/1969.1/ETD-TAMU-2672.

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38

Fu, Ruiling. "Using High-Field NMR to Identify the Bioactive Compounds in Extracts of Black Raspberry." University of Akron / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=akron1185892825.

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39

Dahal, Dipendra Dahal. "SYNTHESIS AND CHARACTERIZATION OF NOVEL EXCITED STATE INTRAMOLECULAR PROTON TRANSFER (ESIPT) CYANINE DYES WITH NEAR INFRARED (NIR) EMISSION FOR BIOLOGICAL APPLICATIONS." University of Akron / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=akron1567644552737644.

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40

Nabiyeva, Svetlana. "Water-based headspace single-drop microextraction and capillary electrophoresis for the determination of volatile inorganic compounds in complex matrices." Doctoral thesis, Lithuanian Academic Libraries Network (LABT), 2010. http://vddb.laba.lt/obj/LT-eLABa-0001:E.02~2010~D_20101214_103540-08331.

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The objective of the present work was systematic investigation of water-based headspace single-drop microextraction (SDME) technique, its conjunction with capillary electrophoresis, and application for the analysis of volatile inorganic compounds (cyanide and ammonium) in biomedical and environmental samples. Theoretically evaluated and experimentally confirmed that the manipulation in the volatility of the analyte by its chemical modification in the sample and/or in the acceptor phase is the most effective way to enhance the extraction performance in headspace SDME. Maximum extraction efficie

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41

Watson, Amy Dawn. "Binding Studies of Near Infrared Cyanine Dyes with Human Serum Albumin and Poly-L-Lysine Using Optical Spectroscopy Methods." Digital Archive @ GSU, 2008. http://digitalarchive.gsu.edu/chemistry_diss/15.

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The sensitivity of biological studies performed between 190 and 650 nm is greatly reduced due to the autofluorescence of biomolecules and impurities in this region. Therefore, the enhanced signal-to-noise ratios encountered at longer wavelengths makes biological analysis within the near infrared (NIR) region from 650 nm to 1100 nm far more advantageous. This dissertation describes the noncovalent binding interactions of near-infrared (NIR) carbocyanine dyes with human serum albumin (HSA) and poly-L-lysine (PLL) using UV-Vis/NIR absorption spectroscopy, emission spectroscopy, circular dichro

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42

Tikhomirova, Anastasiia. "Studies of Photoinduced DNA Damage by Phenanthrene Dihydrodioxin and Light-driven Electron Delocalization in Pyridinium Molecules." Bowling Green State University / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1561918589357022.

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43

Córdova, Carlos Martín Infante. "Desenvolvimento de sistemas de análises em fluxo por multicomutação para determinação de poluentes ambientais." Universidade de São Paulo, 2008. http://www.teses.usp.br/teses/disponiveis/46/46133/tde-27112008-153916/.

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O presente trabalho teve como objetivo o desenvolvimento de procedimentos analíticos baseados na análise em fluxo com multicomutação, acoplada à detecção por fluorescência, espectrofotometria com longo caminho óptico ou quimiluminescência em guias de ondas (LCW), para a determinação de poluentes ambientais. Os procedimentos desenvolvidos atendem aos requisitos de sensibilidade e limite de detecção impostos pela legislação ambiental vigente e as características analíticas encontram-se em concordância com as tendências atuais de redução do consumo de amostras e reagentes, da geração de resíduos

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44

Schröder, Benjamin. "Theoretical high-resolution spectroscopy for reactive molecules in astrochemistry and combustion processes." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2019. http://hdl.handle.net/21.11130/00-1735-0000-0005-12DA-1.

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45

Luschtinetz, Franziska. "Cyaninfarbstoffe als Fluoreszenzsonden in biomimetischen und biologischen Systemen : Fluoreszenz-Korrelations-Spektroskopie und Fluoreszenzanisotropie-Untersuchungen." Phd thesis, Universität Potsdam, 2010. http://opus.kobv.de/ubp/volltexte/2010/4847/.

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Um Prozesse in biologischen Systemen auf molekularer Ebene zu untersuchen, haben sich vor allem fluoreszenzspektroskopische Methoden bewährt. Die Möglichkeit, einzelne Moleküle zu beobachten, hat zu einem deutlichen Fortschritt im Verständnis von elementaren biochemischen Prozessen geführt. Zu einer der bekanntesten Methoden der Einzelmolekülspektroskopie zählt die Fluoreszenz-Korrelations-Spektroskopie (FCS), mit deren Hilfe intramolekulare und diffusionsgesteuerte Prozesse in einem Zeitbereich von µs bis ms untersucht werden können. Durch die Verwendung von sog. Fluoreszenzsonden können Info

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46

MacMillar, Susanna. "Isotopes as Mechanism Spies : Nucleophilic Bimolecular Substitution and Monoamine Oxidase B Catalysed Amine Oxidation Probed with Heavy Atom Kinetic Isotope Effects." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis (AUU), 2006. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-7441.

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47

Parrish, Douglas K. "Application of solid phase microextraction with gas chromatography-mass spectrometry as a rapid, reliable, and safe method for field sampling and analysis of chemical warfare agent precursors /." Download the dissertation in PDF, 2005. http://www.lrc.usuhs.mil/dissertations/pdf/Parrish2005.pdf.

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48

Paulson, Tracie Lee. "The fate of the cyanide ion in the aquatic environment." 2008. http://hdl.rutgers.edu/1782.2/rucore10005600001.ETD.17620.

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49

Summo, Kathryn Eva. "The development of a practical catalytic Petasus reaction of glycolaldehyde and the asymmetric allylboration of acyl cyanides." Thesis, 2016. https://hdl.handle.net/2144/19734.

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Asymmetric nucleophilic boronate reactions have been developed using organic chiral diols, specifically binaphthols, as catalysts. A highly enantioselective allylboration of acyl cyanides under solvent-free conditions was catalyzed by (S)-Br2BINOL. The reaction proceeds through single exchange of boronate with the chiral catalyst, promoted by tert-butanol. Allylation products were obtained in yields up to 97% and enantioselectivities up to 99:1 er. Syn- and anti-crotylborations of benzoyl cyanide were also performed, and the corresponding a-methyl products were isolated in good yields and mode

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50

Mullins, Barbara A. "Photocatalytic destruction of some transition metal cyanide complexes." Thesis, 1996. http://hdl.handle.net/1911/14046.

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The oxidation of several transition metal cyanides by illuminated colloidal titanium dioxide has been studied with attention to end products and rate of reaction. Tetracyanozinc, a weak complex, and ferricyanide, a stable complex were the primary focus. The rate of complex dissociation of ferricyanide was found to depend on pH. The rate of oxidation of cyanide was found to be the same both complexed and as alkali cyanide. Although the precipitation of metal oxide onto the catalyst occurred, there was no evidence that it interfered in the oxidation of cyanide.

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