Academic literature on the topic 'Derivatization'

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Journal articles on the topic "Derivatization"

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Halket, John M., and Vladimir G. Zaikin. "Derivatization in Mass Spectrometry—5. Specific Derivatization of Monofunctional Compounds." European Journal of Mass Spectrometry 11, no. 1 (2005): 127–60. http://dx.doi.org/10.1255/ejms.712.

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The present paper is complementary to the foregoing reviews and describes some additional methods of the derivatization of particular functional groups mainly to enhance the structural information content of electron ionization and chemical ionization mass spectra. Derivatization approaches for the modification of unsaturated compounds, alcoholic, carboxylic, carbonyl, amine and other functional groups, are discussed. Derivatization for separation and quantitative determination of chiral enantiomeric compounds is also considered. Preliminary chemical and physical–chemical degradation for struc
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Sun, Hongbao, Qinghe Xue, Chang Zhang, Haoxing Wu, and Ping Feng. "Derivatization based on tetrazine scaffolds: synthesis of tetrazine derivatives and their biomedical applications." Organic Chemistry Frontiers 9, no. 2 (2022): 481–98. http://dx.doi.org/10.1039/d1qo01324f.

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The recent advances in tetrazine scaffold-based derivatizations have been summarized. The advantages and limitations of derivatization methods and applications of the developed tetrazine derivatives in bioorthogonal chemistry have been highlighted.
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Sevillano, R. M., G. Mortha, M. Barrelle, and D. Lachenal. "19F NMR Spectroscopy for the Quantitative Analysis of Carbonyl Groups in Lignins." Holzforschung 55, no. 3 (2001): 286–95. http://dx.doi.org/10.1515/hf.2001.048.

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Summary The amount of carbonyl groups in an organosolv lignin was determined by 19F NMR spectroscopy after different derivatizations: derivatization with trifluoromethylphenylhydrazine, fluorobenzoylation of alcohol groups formed after NaBH4 reduction of lignin, fluorobenzoylation of phenolic hydroxyl groups after catalytic hydrogenation of lignin. Oximation was also used for comparison. Carbonyl group contents determined by 19F NMR after trifluoromethylphenylhydrazine derivatization were in good correlation with results from other methods. Trifluoromethylphenylhydrazine derivatization is a fa
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Suska, Hubert, and Stanisław Popiel. "Optimization of Methods for Derivatization of Sarin, Soman, and VX Hydrolysis Products in the Process of Analyzing These Compounds Using Gas Chromatography." Bulletin of the Military University of Technology 73, no. 4 (2024): 47–56. https://doi.org/10.5604/01.3001.0055.1273.

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The identification and quantification of degradation products of organophosphorus chemical warfare agents (OP-CWAs)are critical for retrospective and forensic analysis or evidence proceedings. Due to their high polarity and low volatility, direct chromatographicanalysis of these hydrolysis products is often ineffective, necessitating derivatization to enhance analytical performance.This study focuses on optimizing the derivatization conditions of sarin, soman and VX hydrolysates – O–alkylmethylphosphonic acids(methylphosphonic (MPA), ethyl methylphosphonic (EMPA), isopropyl methylphosphonic (I
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SP., Karuppiah, and Anverbasha K. "Derivatization methodology in analytical separation." Journal of Indian Chemical Society Vol. 92, Apr 2015 (2015): 447–50. https://doi.org/10.5281/zenodo.5594449.

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Department of Chemistry, Sathyabama University, Chennai-600 117, India <em>E-mail </em>: Karu70123@rediffmail.com Derivatization is the transformation of one chemical compound into another with similar chemical structure. The chemical compounds specific functional group that involves in the derivatization reaction which transforms a educt to a derivate from boiling point, melting point, solubility, reactivity and chemical composition. This results in new chemical properties is used for separation and quantification. In HPLC there are two kinds of derivatization methods such as pre-column deriv
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Soma, Yuki, Yoshihiro Izumi, Takehiko Shimohira, et al. "In-Needle Pre-Column Derivatization for Amino Acid Quantification (iPDAQ) Using HPLC." Metabolites 12, no. 9 (2022): 807. http://dx.doi.org/10.3390/metabo12090807.

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Pre-column fluorescent derivatization has been used for the fast quantification of amino acids using high-performance liquid chromatography (HPLC) systems. However, it generally requires an offline in-vial derivatization process with multiple derivatization reagents. The offline derivatization requires the same number of reaction vials as the number of sample vials for use as a reaction chamber for the derivatization reaction in an autosampler. Therefore, the number of samples analyzed per batch using the pre-column derivatization method is halved. To benefit from the pre-column derivatization
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Bourgeois, Caroline, Nicolas Blanc, Jean-Claude Cannot, and Claire Demesmay. "Towards a Non-Biased Formaldehyde Quantification in Leather: New Derivatization Conditions before HPLC Analysis of 2,4-Dinitrophenylhydrazine Derivatives." Molecules 25, no. 23 (2020): 5765. http://dx.doi.org/10.3390/molecules25235765.

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In leathers, formaldehyde is currently analyzed according to EN ISO 17226-1 standard, by reversed phase liquid chromatography after off-line precolumn derivatization with 2,4 dinitrophenylhydrazine (DNPH) in strong acidic conditions. We first demonstrate that this standard is not adapted to leather retanned with resins likely to release formaldehyde by hydrolysis. Indeed, formaldehyde content may be largely overestimated due to concomitant resin hydrolysis (in harsh acidic conditions) that releases formaldehyde during the derivatization step and during the waiting time on autosampler before an
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Domergue, Jean-Baptiste, Julie Lalande, Cyril Abadie, and Guillaume Tcherkez. "Compound-Specific 14N/15N Analysis of Amino Acid Trimethylsilylated Derivatives from Plant Seed Proteins." International Journal of Molecular Sciences 23, no. 9 (2022): 4893. http://dx.doi.org/10.3390/ijms23094893.

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Isotopic analyses of plant samples are now of considerable importance for food certification and plant physiology. In fact, the natural nitrogen isotope composition (δ15N) is extremely useful to examine metabolic pathways of N nutrition involving isotope fractionations. However, δ15N analysis of amino acids is not straightforward and involves specific derivatization procedures to yield volatile derivatives that can be analysed by gas chromatography coupled to isotope ratio mass spectrometry (GC-C-IRMS). Derivatizations other than trimethylsilylation are commonly used since they are believed to
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Halket, John M., and Vladimir G. Zaikin. "Derivatization in Mass Spectrometry—7. On-Line Derivatization/Degradation." European Journal of Mass Spectrometry 12, no. 1 (2006): 1–13. http://dx.doi.org/10.1255/ejms.785.

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Orasche, J., J. Schnelle-Kreis, G. Abbaszade, and R. Zimmermann. "Technical Note: In-situ derivatization thermal desorption GC-TOFMS for direct analysis of particle-bound non-polar and polar organic species." Atmospheric Chemistry and Physics Discussions 11, no. 5 (2011): 15255–95. http://dx.doi.org/10.5194/acpd-11-15255-2011.

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Abstract. An in-situ derivatization thermal desorption method followed by gas chromatography and time-of-flight mass spectrometry (IDTD-GC-TOFMS) was developed for determination of polar organic compounds. Hydroxyl and carboxyl groups of compounds such as anhydrous sugars, alcohols and phenols, fatty acids and resin acids are targets of the derivatization procedure. Derivatization is based on silylation with N-Methyl-N-trimethylsilyl-trifluoroacetamide (MSTFA) during the step of thermal desorption. The high temperature of 300 °C during desorption is utilized for the in-situ derivatization on t
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Dissertations / Theses on the topic "Derivatization"

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Little, Michael J. "Single-label fluorescent derivatization of peptides." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape16/PQDD_0004/MQ40195.pdf.

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Betit, Lyanne. "Derivatization of Azomethine Imines into beta-Aminocarbonyl Motifs." Thesis, Université d'Ottawa / University of Ottawa, 2015. http://hdl.handle.net/10393/32473.

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β-Aminocarbonyl motifs are a privileged substructures in medicinal chemistry and peptidomimetics. As part of our efforts toward metal free aminations, we developed a method for intermolecular amino-carbonylation of alkenes using hydrazones. This method provides access to cyclic azomethine imines containing a β-aminocarbonyl motif. Conceptually, these dipoles can be derivatized into many bioactive compounds, such as 1,3-diamines, β-amino amides and β-amino acids. The first part of this thesis will present the results on the derivatization of our aminocarbonylation products into various nitroge
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Porche, Mya. "Spectrophotometric Determination of Nitrite by Derivatization with Captopril." Miami University / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=miami1399075201.

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Jose, Jiney. "Water-soluble benzophenoxazine dyes: syntheses, derivatization and photophysical studies." Texas A&M University, 2006. http://hdl.handle.net/1969.1/4915.

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A set of three benzophenoxazine dyes, two completely soluble and one partially soluble in aqueous media, has been prepared and their spectroscopic properties examined. These dyes can be used as either donor or acceptor in synthesis of through-bond energy transfer cassettes. Structural modifications prevented aggregation in water and improved their fluorescence properties in water. Their absorption and emission were studied in both organic and aqueous media. Two of the three dyes have superior quantum yields in aqueous media as compared to other reported dyes. Improved quantum yield makes these
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Shepherd, Micah Douglas. "COMBINATORIAL BIOSYNTHETIC DERIVATIZATION OF THE ANTITUMORAL AGENT GILVOCARCIN V." UKnowledge, 2011. http://uknowledge.uky.edu/gradschool_diss/149.

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Gilvocarcin V (GV), the principal product of Streptomyces griseoflavus Gö 3592 and other Streptomyces spp., is the most prominent member of a distinct class of antitumor antibiotics that share a polyketide derived coumarin-based aromatic core. GV and other members of this class including polycarcin V from Streptomyces polyformus, often referred to as gilvocarcin-like aryl C-glycosides, are particularly interesting because of their potent bactericidal, virucidal and antitumor activities at low concentrations while maintaining low in vivo toxicity. Although the precise molecular mechanism of GV
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Teschler, Timothy Luke. "PREPARATION AND DERIVATIZATION OF NOVEL SYDNONIMINES AND THEIR ESTERS." Wright State University / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=wright1189622838.

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Mohanty, Nihar Ranjan. "Structural and chemical derivatization of graphene for electronics and sensing." Diss., Kansas State University, 2011. http://hdl.handle.net/2097/9264.

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Doctor of Philosophy<br>Department of Chemical Engineering<br>Vikas Berry<br>Graphene - a single atom thick two dimensional sheet of sp[superscript]2 bonded carbon atoms arranged in a honeycomb lattice - has shown great promise for both fundamental research & applications because of its unique electrical, optical, thermal, mechanical and chemical properties. Derivatization of graphene unlocks a plethora of novel properties unavailable to their pristine parent “graphene”. In this dissertation we have synthesized various structural and chemical derivatives of graphene; characterized them in deta
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Bachawala, Praveen. "Large scale synthesis and derivatization of corannulene the smallest buckybowl /." Master's thesis, Mississippi State : Mississippi State University, 2006. http://sun.library.msstate.edu/ETD-db/ETD-browse/browse.

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Hoefler, Christoph. "Preparation of electron donor and acceptor molecules for porphyrin derivatization." PDXScholar, 1992. https://pdxscholar.library.pdx.edu/open_access_etds/4317.

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Porphyrins derivatized with electron donating and electron withdrawing groups can be used for artificial photosynthesis. Four new compounds, two electron donors and two electron acceptors, have been synthesized for prospective porphyrin linkages.
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ROBY, BENJAMIN JAMES. "EFFECT OF GRIT-BLASTING AND PLASMA ETCHING ON THE SURFACE COMPOSITION AND SURFACE ENERGY OF GRAPHITE/EPOXY COMPOSITES." University of Cincinnati / OhioLINK, 2005. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1131650624.

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Books on the topic "Derivatization"

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Lunn, George. Handbook of derivatization reactions for HPLC. Wiley, 1998.

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Toshimasa, Toyo'oka, ed. Modern derivatization methods for separation sciences. Wiley, 1999.

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Zaikin, V. A handbook of derivatives for mass spectrometry. IM Publications, 2009.

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Dawson, W. M. The characterisation of 2-Hydroxymethlpiperidine derivatization products by chromatographic and spectroscopic methods. UMIST, 1997.

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Marsella, Adam Manuele. A new method for the measurement of airborne formaldehyde using derivatization with 3,5-bis(trifluoromethyl)phenylhydrazine. National Library of Canada, 1999.

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United States. Environmental Protection Agency. Office of Ground Water and Drinking Water. Technical Support Center. Method 531.2: Measurement of N-Methylcarbamoyloximes and N-Methylcarbamates in water by direct aqueous injection HPLC with postcolumn derivatization. United States Environmental Protection Agency, Office of Ground Water and Drinking Water, Technical Support Center, 2001.

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Lingeman, Hendrik. Selective pre-chromatographic derivatization methods for carboxylic acids: (high-performance liquid chromatography with fluorescence detection and gas-liquid chromatography with nitrogen-phosphorous detection). [s.n.], 1986.

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Karl, Blau, and Halket John M, eds. Handbook of derivatives for chromatography. 2nd ed. Wiley, 1993.

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"Li shi yu she hui" yan jiu sheng gong zuo fang 2nd 2016 Beijing da xue). Cheng shi: Sheng huo kong jian, quan li jie gou yu wen hua yan sheng = Modern Chinese cities : living space, authority structure and cultural derivatization. Jiangsu ren min chu ban she, 2018.

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Tzanavaras, Paraskevas D., ed. Derivatization in Analytical Chemistry. MDPI, 2022. http://dx.doi.org/10.3390/books978-3-0365-4255-3.

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Book chapters on the topic "Derivatization"

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Glicksberg, Lindsay, and Sarah Kerrigan. "Derivatization." In Principles of Forensic Toxicology. Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-42917-1_12.

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Bada, Jeffrey. "Derivatization." In Encyclopedia of Astrobiology. Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-662-44185-5_415.

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Dettmer-Wilde, Katja. "Derivatization." In Practical Gas Chromatography. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-54640-2_17.

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Bada, Jeffrey. "Derivatization." In Encyclopedia of Astrobiology. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-11274-4_415.

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Cahill, Ann J. "Derivatization." In Overcoming Objectification, 2nd ed. Routledge, 2024. https://doi.org/10.4324/9781003486145-2.

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Bada, Jeffrey. "Derivatization." In Encyclopedia of Astrobiology. Springer Berlin Heidelberg, 2023. http://dx.doi.org/10.1007/978-3-662-65093-6_415.

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Bada, Jeffrey. "Derivatization." In Encyclopedia of Astrobiology. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-27833-4_415-2.

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Ahnoff, M., and S. Einarsson. "Chiral derivatization." In Chiral Liquid Chromatography. Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-0861-1_4.

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Ahnoff, M., and S. Einarsson. "Chiral derivatization." In Chiral Liquid Chromatography. Springer US, 1989. http://dx.doi.org/10.1007/978-1-4613-0699-3_4.

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Telepchak, Michael J., Thomas F. August, and Glynn Chaney. "Chemical Derivatization." In Forensic and Clinical Applications of Solid Phase Extraction. Humana Press, 2004. http://dx.doi.org/10.1007/978-1-59259-292-0_12.

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Conference papers on the topic "Derivatization"

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Little, Brenda, Pat Wagner, and John Jacobus. "The Impact of Sulfate-Reducing Bacteria on Welded Copper-Nickel Seawater Piping Systems." In CORROSION 1988. NACE International, 1988. https://doi.org/10.5006/c1988-88081.

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Abstract Field and laboratory experiments were designed to evaluate corrosion in welds and heat-affected zones in Cu/Ni seawater piping systems exposed to estuarine water and seawater. The localized corrosion was shown to be due to the following sequence of events: (1) metal segregation during heating processes; (2) settlement of sulfide-producing bacteria in welds; (3) sulfide derivatization; (4) disruption of the surface films by turbulence and (4) formation of adjacent cathodic and anodic areas. Metallic segregation in welded areas was detected by EDAX before the welds were exposed to estua
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Bhatia, Sangeeta N., Martin L. Yarmush, and Mehmet Toner. "Engineered Substrates for Controlling Cell-Cell Interactions." In ASME 1997 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 1997. http://dx.doi.org/10.1115/imece1997-1319.

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Abstract Biomaterials have been previously engineered to serve a variety of different functions: precise degradation in vivo (Kimura, 1993), modulation of cell physiology via binding to specific ligands (Hubbell et al, 1992), and selective permeability of certain solutes (Lysaght et al, 1994). However, in complex tissues, where cell-cell interactions strongly influence tissue function, biomaterials which modulate this fundamental parameter have not been available. In this study, we describe a technique which allows control over cell-cell interactions by using semiconductor-based microfabricati
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Santos, Francisca, Valentina Domingues, Cristina Soares, and Cristina Delerue-Matos. "Optimizing Amino Acid Derivatization in Food Matrices." In International Electronic Conference on Processes. MDPI, 2024. http://dx.doi.org/10.3390/proceedings2024105104.

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Barker, Susan L. R., Michael J. Tarlov, David Ross, Timothy Johnson, Emanuel Waddell, and Laurie E. Locascio. "Fabrication, derivatization, and applications of plastic microfluidic devices." In Environmental and Industrial Sensing, edited by Tuan Vo-Dinh and Stephanus Buettgenbach. SPIE, 2001. http://dx.doi.org/10.1117/12.417439.

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Cen, Jian-Wei, Shao-Ping Xin, Ya Wei, et al. "A New Fluorimetric Derivatization Reaction to Detect Tetrodotoxin." In 2015 International Conference on Medicine and Biopharmaceutical. WORLD SCIENTIFIC, 2016. http://dx.doi.org/10.1142/9789814719810_0173.

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Beacham, D. "395. Analysis of Low Molecular Weight Amines Using Nitc Derivatization." In AIHce 1996 - Health Care Industries Papers. AIHA, 1999. http://dx.doi.org/10.3320/1.2765074.

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Wang, Bin, Fang Yu, and Xuejun Pan. "An Improved Method for the Derivatization of Phenolic Endocrine Disrupting Chemicals." In 2012 2nd International Conference on Remote Sensing, Environment and Transportation Engineering (RSETE). IEEE, 2012. http://dx.doi.org/10.1109/rsete.2012.6260385.

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Heflin, James R., Daniela Marciu, Charles Figura, S. Wang, R. Yordanov, and James C. Withers. "Optical limiting over an extended spectral region by derivatization of C60." In Optical Science, Engineering and Instrumentation '97, edited by Christopher M. Lawson. SPIE, 1997. http://dx.doi.org/10.1117/12.284160.

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Holzinger, Michael. "Novel purification procedure and derivatization method of single-walled carbon nanotubes (SWNTs)." In The 14th international winterschool on electronic properties of novel materials - molecular nanostructures. AIP, 2000. http://dx.doi.org/10.1063/1.1342510.

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Karnes, H. T., Sadayappan V. Rahavendran, and Min Gui. "Long-wavelength derivatization reagents for use in diode laser-induced fluorescence detection." In Photonics West '95, edited by Joseph R. Lakowicz. SPIE, 1995. http://dx.doi.org/10.1117/12.208489.

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Reports on the topic "Derivatization"

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Park, Su-Moon. Electrochemical characterization and derivatization of coal. Office of Scientific and Technical Information (OSTI), 1989. http://dx.doi.org/10.2172/5514100.

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Park, Su-Moon. Electrochemical characterization and derivatization of coal. Office of Scientific and Technical Information (OSTI), 1989. http://dx.doi.org/10.2172/5514100.

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Hoefler, Christoph. Preparation of electron donor and acceptor molecules for porphyrin derivatization. Portland State University Library, 2000. http://dx.doi.org/10.15760/etd.6201.

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Park, S. M. Electrochemical characterization and derivatization of coal: Technical progress report, December 15, 1988--March 14, 1989. Office of Scientific and Technical Information (OSTI), 1989. http://dx.doi.org/10.2172/6443728.

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Schulz, J. G., E. N. Porowski, and A. M. Straub. Oxidative derivatization and solubilization of coal. Final report. Period: October 1, 1986 - April 30, 1988. Office of Scientific and Technical Information (OSTI), 1988. http://dx.doi.org/10.2172/799247.

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Malhotra, R., D. F. McMillen, F. P. Burke, R. A. Winschel, and S. D. Brandes. Coal liquefaction process streams characterization and evaluation:. Characterization of coal liquids by field ionization mass spectrometry and iodotrimethylsilane derivatization. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/10139458.

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Boris, Alexandra. Toward the Complete Characterization of Atmospheric Organic Particulate Matter: Derivatization and Two-Dimensional Comprehensive Gas Chromatography/Time of Flight Mass Spectrometry as a Method for the Determination of Carboxylic Acids. Portland State University Library, 2000. http://dx.doi.org/10.15760/etd.544.

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