Academic literature on the topic 'Dicumyl peroxide'

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Journal articles on the topic "Dicumyl peroxide"

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Naskar, Kinsuk, and Jacques W. M. Noordermeer. "Dynamically Vulcanized PP/EPDM Blends: Multifunctional Peroxides as Crosslinking Agents — Part I." Rubber Chemistry and Technology 77, no. 5 (2004): 955–71. http://dx.doi.org/10.5254/1.3547862.

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Abstract Thermoplastic vulcanizates (TPVs) or dynamic vulcanizates are a special class of thermoplastic elastomers, produced by mixing and crosslinking of a rubber and a thermoplastic polymer simultaneously. In a previous study, it was demonstrated that the use of dicumyl peroxide in combination with triallyl cyanurate as crosslinking agents provides a good overall balance of physical properties of PP/EPDM TPVs. Commonly used peroxides like dicumyl peroxide generally produce volatile decomposition products, which sometimes provide a typical smell or show a blooming effect. In this paper multif
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Lin, Shuqiong, Behnam Ashrafi, Kurtis Laqua, Keun Su Kim, and Benoit Simard. "Covalent derivatization of boron nitride nanotubes with peroxides and their application in polycarbonate composites." New Journal of Chemistry 41, no. 15 (2017): 7571–77. http://dx.doi.org/10.1039/c7nj00193b.

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Kosnikov, A. Yu, V. L. Antonovskii, N. A. Turovskii, et al. "Molecular structure of dicumyl peroxide." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 37, no. 4 (1988): 674–78. http://dx.doi.org/10.1007/bf01455475.

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Xu, Chang Gang, Xue Gang Luo, Xiu Rong Zhuo, and Li Li Liang. "Research on Crosslinking of Polylactide Using Low Concentration of Dicumyl Peroxide." Materials Science Forum 620-622 (April 2009): 189–92. http://dx.doi.org/10.4028/www.scientific.net/msf.620-622.189.

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The effects of dicumyl peroxide (DCP) at low concentrations on initiating cross-linking of polylactide (PLA) by melt blending were investigated. Processing characteristics, morphology, thermal behavior and rheology character of PLA gel were characterized by torque rheometer, XRD, DSC and rotary rheometer. The results showed that the crosslink rate of the blends increased with dicumyl peroxide content increasing. The PLA gel with 0.73 wt% of DCP appeared obvious crystallization behavior and a new crystalline structure maybe formed as DCP was 1.4 wt%. And it was also found that the exothermal pe
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Timakov, Evgeny A., and Yury T. Panov. "Possibility of using the brabender plastometer to study the peroxide crosslinking of polyethylene. Part 1. Possibility of using the Brabenders plastometer to research the peroxide crosslinking of polyethylene." Butlerov Communications 61, no. 1 (2020): 40–46. http://dx.doi.org/10.37952/roi-jbc-01/20-61-1-40.

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In this work, we address the problem of processing of polyolefins in the production of which used cross-linking agents based on peroxides. The peroxide method of production of foamed polymers is one of the most popular in Russia, so the relevance of its improvement is not in doubt. The main problem with working with peroxides is the high content of by-products, which are often toxic and have a negative impact on the staff. In this article, the authors proposed to reduce the concentration of toxic peroxide used by adding a less toxic crosslinking agent – triallylcyanurate to the formulation. Th
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Fishwick, Tony. "A chemical fire involving dicumyl peroxide." Loss Prevention Bulletin 155, no. 1 (2000): 12. http://dx.doi.org/10.1205/026095700522949.

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Sapieha, S., P. Allard, and Y. H. Zang. "Dicumyl peroxide-modified cellulose/LLDPE composites." Journal of Applied Polymer Science 41, no. 910 (1990): 2039–48. http://dx.doi.org/10.1002/app.1990.070410910.

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Timakov, Evgeny A., and Yury T. Panov. "Possibility of using the brabender plastometer to study the peroxide crosslinking of polyethylene. Part 2. Use of the mixture 1,3- and 1,4-bis(tret-butylperoxyisopropyl)benzene for crosslinking polyethylene." Butlerov Communications 61, no. 1 (2020): 47–51. http://dx.doi.org/10.37952/roi-jbc-01/20-61-1-47.

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The paper shows the possibility of using the mixture 1,3- and 1,4-bis(tert-butylperoxyisopropyl)-benzene as a cross-linking agent in the production of polyethylene foam. Most often, cross-linked polyethylene foam, which has high performance properties, is obtained by pressing, using azoicarbonamide as a foaming agent and dicumyl peroxide as a cross-linking agent. Dicumyl peroxide has a significant drawback: high toxicity of decomposition products. Using the soxlet extratctor, the optimal degree of crosslinking (57-62%) required to obtain foam with optimal performance properties was determined.
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Guo, Rui Bao, Jin Shui Yao, and Zhi Yong Yang. "Influence of Dicumyl Peroxide and Maleic Anhydride on the Tensile Properties of HDPE–Calcium Carbonate Composites." Advanced Materials Research 239-242 (May 2011): 1349–52. http://dx.doi.org/10.4028/www.scientific.net/amr.239-242.1349.

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PE is modified basically with inorganic matter (generally CaCO3) and some auxiliaries, but because of the interattraction of the particles, CaCO3is easy to agglomerate, so we must add some dispersants(generally stearic acid ) ,but some study suggested that, with stearic acid , tensile strength, yield strain and ultimate elongation reduced. But we find that adding dicumyl peroxide and Maleic Anhydride can make up for the defects even increase these properties. As initiator and crosslinker ,dicumyl peroxide is usually used in synthesis of polymers. And is also Maleic Anhydride. However,in this e
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Naskar, K., and J. W. M. Noordermeer. "Dynamically Vulcanized PP/EPDM Blends: Effects of Different Types of Peroxides on the Properties." Rubber Chemistry and Technology 76, no. 4 (2003): 1001–18. http://dx.doi.org/10.5254/1.3547766.

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Abstract Thermoplastic vulcanizates (TPVs) or dynamic vulcanizates are thermoplastic elastomers produced by simultaneous mixing and crosslinking of a rubber and a thermoplastic. The effects of different types of peroxides as curing agents on the properties of PP/EPDM TPVs were investigated at a fixed blend ratio. The mechanical properties change significantly with the chemical nature of the peroxides, the extent of crosslinking of EPDM and the extent of degradation of PP. Three main parameters have been identified governing the final mechanical properties of TPVs: the solubility parameter of a
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Dissertations / Theses on the topic "Dicumyl peroxide"

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Sun, Yu. "Tearing of Carbon Black-filled and Gum Natural Rubber Vulcanizates Cured with Dicumyl Peroxide (DCP)." University of Akron / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=akron1380201814.

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Li, Zhenpeng. "Effect of Carbon Black on the Tearing of Dicumyl Peroxide (DCP)-cured Natural Rubber Vulcanizates." University of Akron / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=akron1398358292.

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Li, Yanxiao. "Effect of Crosslink Density on the Tearing of Gum Natural Rubber Cured with Dicumyl Peroxide (DCP)." University of Akron / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=akron1366737854.

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Holden, Gavin. "Cross-linking of polyethylene and ethylene/ #alpha#-olefin copolymers, initiated by dicumyl peroxide : a study of new polymers and the effects of molecular structure." Thesis, Lancaster University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.322818.

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Zysk, Jaroslaw Grzegorz. "Composites thermoplastiques du LLDPE ou LLDPE/PP et Switch Grass : effets du polybutadiène diisocyanate et du peroxyde dicumyle sur les propriétés finales /." Trois-Rivières : Université du Québec à Trois-Rivières, 2004. http://www.uqtr.ca/biblio/notice/resume/24102831R.pdf.

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Zysk, Jaroslaw Grzegorz. "Composites thermoplastiques du LLDPE ou LLDPE/PP et Switch Grass : effets du polybutadiène diisocyanate et du peroxyde dicumyle sur les propriétés finales." Thèse, Université du Québec à Trois-Rivières, 2004. http://depot-e.uqtr.ca/1261/1/000123407.pdf.

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Liao, Tsang-sheng, and 廖蒼生. "Thermal Hazard Studies of Dicumyl Peroxide." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/87493972452171193647.

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碩士<br>國立雲林科技大學<br>環境與安全工程系碩士班<br>92<br>The aim of this paper is to study the sensitivity of related safety properties of dicumyl peroxide (DCPO) during manufacturing process. Its inherent thermal hazards were studied as well. Differential scanning calorimetry (DSC) and thermal activity monitor (TAM) were used to search for the thermo-kinetic parameters for DCPO at various concentrations. The potential thermal hazards of intermediates and end products whose concentrations were at approximately 50, 70, 94, 99.3 wt%, respectively, in the process of operating DCPO were investigated. Thermograms in
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Hu, Wen-neng, and 胡文能. "Thermal Hazard Studies of Dicumyl Peroxide in the Manufacturing." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/43687107749244494485.

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碩士<br>國立雲林科技大學<br>環境與安全工程系碩士班<br>95<br>Dicumyl peroxide was usually employed as an initiator for polymerization, a source of free radicals, a hardener, and a linking agent. In Asia, due to its unstably reactive nature, DCPO has caused many thermal explosions and runaway reaction incidents in the manufacturing process. To analyze runaway behaviors of DCPO in the batch reactor, we attempted that thermokinetic parameters, such as heat of reaction (ΔH), exothermic onset temperature (T0), maximum temperature rise , maximum pressure rise , and self-heating rate etc. via differential scanning calor
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Hyslop, David. "Delayed-onset Polymer Cross-linking using Functional Nitroxyls." Thesis, 2012. http://hdl.handle.net/1974/7275.

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New polymer cure chemistry is described, wherein the onset of free radical cross-linking is delayed without compromising cure yields. The addition of an acrylate-functionalized nitroxyl, 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-N-oxyl (AOTEMPO), to a peroxide-cure formulation quenches free radical activity during the initial stages of the cross-linking process, trapping alkyl radicals as alkoxyamines that bear acrylate functionality. Polymer cross-linking by macro-radical combination is suppressed until all nitroxyl is consumed, at which point radical oligomerization of polymer-bound acryla
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Shen, Sun-Ju, and 沈孫儒. "Assessment for the thermal runaway reaction of dicumyl peroxideby calorimeter." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/66046162519851395122.

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博士<br>國立雲林科技大學<br>工程科技研究所博士班<br>99<br>Dicumyl peroxide (DCPO) is usually employed as an initiator for polymerization, a source of free radicals, a hardener, and a linking agent in chemical process. In Asia, due to its unstable reactive nature, DCPO has caused many thermal explosions and runaway reaction incidents in the manufacturing process. This study was conducted to elucidate its essentially thermal hazard characteristics. In order to analyze the runaway behavior of DCPO in a batch reactor, thermokinetic parameters, such as heat of decomposition (ΔHd) and exothermic onset temperature (T0),
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Books on the topic "Dicumyl peroxide"

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Zawadiak, Jan. Dwuetapowa technologia otrzymywania nadtlenku dikumylowego z wodoronadtlenku kumenu i kumenu. Wydawn. Politechniki Śląskiej, 1991.

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Book chapters on the topic "Dicumyl peroxide"

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Gooch, Jan W. "Dicumyl Peroxide." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_3555.

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Na, Zang. "Thermal Stability Analysis of Dicumyl Peroxide." In Lecture Notes in Electrical Engineering. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-26007-0_35.

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Gaylord, Norman G., Mahendra Mehta, and Rajendra Mehta. "Cross-Linking of Ethylene—Propylene Copolymer Rubber with Dicumyl Peroxide—Maleic Anhydride." In ACS Symposium Series. American Chemical Society, 1988. http://dx.doi.org/10.1021/bk-1988-0364.ch031.

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Na, Zang. "Time to Maximum Rate Calculation of Dicumyl Peroxide Based on Thermal Experimental Analysis." In Lecture Notes in Electrical Engineering. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-26007-0_34.

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"Dicumyl peroxide." In Encyclopedic Dictionary of Polymers. Springer New York, 2007. http://dx.doi.org/10.1007/978-0-387-30160-0_3502.

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Conference papers on the topic "Dicumyl peroxide"

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Na Zang. "Reaction hazard analysis for dicumyl peroxide with phenol." In 2011 International Conference on Remote Sensing, Environment and Transportation Engineering (RSETE). IEEE, 2011. http://dx.doi.org/10.1109/rsete.2011.5966173.

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Poornima, R., S. Malathi, T. Narayani, S. Sobana, and R. C. Panda. "Identification of temperature of a Dicumyl peroxide reaction process in CSTR." In 2015 IEEE Technological Innovation in ICT for Agriculture and Rural Development (TIAR). IEEE, 2015. http://dx.doi.org/10.1109/tiar.2015.7358552.

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Xu Zhang, Fusheng Zhou, Zhimin Yan, Mengjia Liu, Huan Li, and JianYing Li. "Effect of dicumyl peroxide on space charge accumulation characteristics of cross-linked polyethylene." In 2016 IEEE International Conference on Dielectrics (ICD). IEEE, 2016. http://dx.doi.org/10.1109/icd.2016.7547578.

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Aritonang, Barita, Tamrin, Basuki Wirjosentono, and Eddiyanto. "Grafting copolymer cylic natural rubber with oleic acid using dicumyl peroxide as initiator." In 3RD INTERNATIONAL POSTGRADUATE CONFERENCE ON MATERIALS, MINERALS & POLYMER (MAMIP) 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0025153.

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Aritonang, Barita, Tamrin, Basuki Wirjosentono, and Eddiyanto. "Modification and Characterization Natural Cycle Rubber (Resipren-35) with Oleat Acid using Dicumyl Peroxide and Divinilbenzena as Compatibility." In International Conference on Chemical Science and Technology Innovation. SCITEPRESS - Science and Technology Publications, 2019. http://dx.doi.org/10.5220/0008859701450151.

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Cao, L., L. Zhong, Y. Li, W. Li, J. Gao, and G. Chen. "Effects of dicumyl peroxide content on DC properties of polystyrene pinning crosslinked polyethylene for potential application in HVDC cable insulation." In The 16th IET International Conference on AC and DC Power Transmission (ACDC 2020). Institution of Engineering and Technology, 2021. http://dx.doi.org/10.1049/icp.2020.0141.

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Samat, Asmak Abdul, Zuratul Ain Abdul Hamid, Mariatti Jaafar, and Badrul Hisham Yahaya. "Preliminary study on reactive compatibilisation of poly-lactic acid with maleic anhydride and dicumyl peroxide for fabrication of 3D printed filaments." In 3RD INTERNATIONAL POSTGRADUATE CONFERENCE ON MATERIALS, MINERALS & POLYMER (MAMIP) 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0016426.

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Cao, Liang, Lisheng Zhong, Yinge Li, et al. "Influence of Dicumy1 Peroxide Content on DC Performance of Polyethylene for DC Cables." In 2018 IEEE Conference on Electrical Insulation and Dielectric Phenomena (CEIDP). IEEE, 2018. http://dx.doi.org/10.1109/ceidp.2018.8544884.

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