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Journal articles on the topic 'Dicumyl peroxide'

Author: Grafiati

Published: 4 June 2021

Last updated: 13 February 2022

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1

Naskar, Kinsuk, and Jacques W. M. Noordermeer. "Dynamically Vulcanized PP/EPDM Blends: Multifunctional Peroxides as Crosslinking Agents — Part I." Rubber Chemistry and Technology 77, no. 5 (2004): 955–71. http://dx.doi.org/10.5254/1.3547862.

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Abstract Thermoplastic vulcanizates (TPVs) or dynamic vulcanizates are a special class of thermoplastic elastomers, produced by mixing and crosslinking of a rubber and a thermoplastic polymer simultaneously. In a previous study, it was demonstrated that the use of dicumyl peroxide in combination with triallyl cyanurate as crosslinking agents provides a good overall balance of physical properties of PP/EPDM TPVs. Commonly used peroxides like dicumyl peroxide generally produce volatile decomposition products, which sometimes provide a typical smell or show a blooming effect. In this paper multif

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2

Lin, Shuqiong, Behnam Ashrafi, Kurtis Laqua, Keun Su Kim, and Benoit Simard. "Covalent derivatization of boron nitride nanotubes with peroxides and their application in polycarbonate composites." New Journal of Chemistry 41, no. 15 (2017): 7571–77. http://dx.doi.org/10.1039/c7nj00193b.

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3

Kosnikov, A. Yu, V. L. Antonovskii, N. A. Turovskii, et al. "Molecular structure of dicumyl peroxide." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 37, no. 4 (1988): 674–78. http://dx.doi.org/10.1007/bf01455475.

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4

Xu, Chang Gang, Xue Gang Luo, Xiu Rong Zhuo, and Li Li Liang. "Research on Crosslinking of Polylactide Using Low Concentration of Dicumyl Peroxide." Materials Science Forum 620-622 (April 2009): 189–92. http://dx.doi.org/10.4028/www.scientific.net/msf.620-622.189.

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The effects of dicumyl peroxide (DCP) at low concentrations on initiating cross-linking of polylactide (PLA) by melt blending were investigated. Processing characteristics, morphology, thermal behavior and rheology character of PLA gel were characterized by torque rheometer, XRD, DSC and rotary rheometer. The results showed that the crosslink rate of the blends increased with dicumyl peroxide content increasing. The PLA gel with 0.73 wt% of DCP appeared obvious crystallization behavior and a new crystalline structure maybe formed as DCP was 1.4 wt%. And it was also found that the exothermal pe

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5

Timakov, Evgeny A., and Yury T. Panov. "Possibility of using the brabender plastometer to study the peroxide crosslinking of polyethylene. Part 1. Possibility of using the Brabenders plastometer to research the peroxide crosslinking of polyethylene." Butlerov Communications 61, no. 1 (2020): 40–46. http://dx.doi.org/10.37952/roi-jbc-01/20-61-1-40.

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In this work, we address the problem of processing of polyolefins in the production of which used cross-linking agents based on peroxides. The peroxide method of production of foamed polymers is one of the most popular in Russia, so the relevance of its improvement is not in doubt. The main problem with working with peroxides is the high content of by-products, which are often toxic and have a negative impact on the staff. In this article, the authors proposed to reduce the concentration of toxic peroxide used by adding a less toxic crosslinking agent – triallylcyanurate to the formulation. Th

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6

Fishwick, Tony. "A chemical fire involving dicumyl peroxide." Loss Prevention Bulletin 155, no. 1 (2000): 12. http://dx.doi.org/10.1205/026095700522949.

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7

Sapieha, S., P. Allard, and Y. H. Zang. "Dicumyl peroxide-modified cellulose/LLDPE composites." Journal of Applied Polymer Science 41, no. 910 (1990): 2039–48. http://dx.doi.org/10.1002/app.1990.070410910.

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8

Timakov, Evgeny A., and Yury T. Panov. "Possibility of using the brabender plastometer to study the peroxide crosslinking of polyethylene. Part 2. Use of the mixture 1,3- and 1,4-bis(tret-butylperoxyisopropyl)benzene for crosslinking polyethylene." Butlerov Communications 61, no. 1 (2020): 47–51. http://dx.doi.org/10.37952/roi-jbc-01/20-61-1-47.

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The paper shows the possibility of using the mixture 1,3- and 1,4-bis(tert-butylperoxyisopropyl)-benzene as a cross-linking agent in the production of polyethylene foam. Most often, cross-linked polyethylene foam, which has high performance properties, is obtained by pressing, using azoicarbonamide as a foaming agent and dicumyl peroxide as a cross-linking agent. Dicumyl peroxide has a significant drawback: high toxicity of decomposition products. Using the soxlet extratctor, the optimal degree of crosslinking (57-62%) required to obtain foam with optimal performance properties was determined.

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9

Guo, Rui Bao, Jin Shui Yao, and Zhi Yong Yang. "Influence of Dicumyl Peroxide and Maleic Anhydride on the Tensile Properties of HDPE–Calcium Carbonate Composites." Advanced Materials Research 239-242 (May 2011): 1349–52. http://dx.doi.org/10.4028/www.scientific.net/amr.239-242.1349.

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PE is modified basically with inorganic matter (generally CaCO3) and some auxiliaries, but because of the interattraction of the particles, CaCO3is easy to agglomerate, so we must add some dispersants(generally stearic acid ) ,but some study suggested that, with stearic acid , tensile strength, yield strain and ultimate elongation reduced. But we find that adding dicumyl peroxide and Maleic Anhydride can make up for the defects even increase these properties. As initiator and crosslinker ,dicumyl peroxide is usually used in synthesis of polymers. And is also Maleic Anhydride. However,in this e

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10

Naskar, K., and J. W. M. Noordermeer. "Dynamically Vulcanized PP/EPDM Blends: Effects of Different Types of Peroxides on the Properties." Rubber Chemistry and Technology 76, no. 4 (2003): 1001–18. http://dx.doi.org/10.5254/1.3547766.

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Abstract Thermoplastic vulcanizates (TPVs) or dynamic vulcanizates are thermoplastic elastomers produced by simultaneous mixing and crosslinking of a rubber and a thermoplastic. The effects of different types of peroxides as curing agents on the properties of PP/EPDM TPVs were investigated at a fixed blend ratio. The mechanical properties change significantly with the chemical nature of the peroxides, the extent of crosslinking of EPDM and the extent of degradation of PP. Three main parameters have been identified governing the final mechanical properties of TPVs: the solubility parameter of a

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11

Borah, Jyoti S., Kinsuk Naskar, and Tapan K. Chaki. "Covulcanization of LLDPE/EMA blends using dicumyl peroxide." Journal of Applied Polymer Science 123, no. 1 (2011): 502–9. http://dx.doi.org/10.1002/app.34472.

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12

Wu, Jiachun, Zi Liang Wu, Hongmei Yang, and Qiang Zheng. "Crosslinking of low density polyethylene with octavinyl polyhedral oligomeric silsesquioxane as the crosslinker." RSC Adv. 4, no. 83 (2014): 44030–38. http://dx.doi.org/10.1039/c4ra04886e.

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We report a new strategy for the crosslinking of LDPE using octavinyl polyhedral oligomeric silsesquioxane as the crosslinker, which dramatically decreases the amount of dicumyl peroxide and thus avoids the chain scission, scorch, and production of small pores in the conventional peroxide crosslinking strategy.

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13

Chudzik, Joanna, Dariusz M. Bieliński, Michael Bratychak, et al. "Influence of Modified Epoxy Resins on Peroxide Curing, Mechanical Properties and Adhesion of SBR, NBR and XNBR to Silver Wires. Part I: Application of Monoperoxy Derivative of Epoxy Resin (PO)." Materials 14, no. 5 (2021): 1320. http://dx.doi.org/10.3390/ma14051320.

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The research was aimed at checking the effect of monoperoxy derivative of epoxy resin (PO) on the possibility of rubber crosslinking and a subsequent adhesion of the modified rubber to silver wires. Three of the commonly industrially used rubbers were selected for the study: styrene-butadiene rubber (SBR), acrylonitrile-butadiene rubber (NBR) and carboxylated acrylonitrile-butadiene rubber (XNBR), together with the popular, commercially available Epidian 6 epoxy resin, subjected to the functionalization. An improvement in the adhesion of rubbers to silver wires was observed when using the modi

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14

Zhang, Dong, Zi-Liang Tang, Xuan-Hui Ouyang, Ren-Jie Song, and Jin-Heng Li. "Copper-catalyzed oxidative decarboxylative alkylation of cinnamic acids with 4-alkyl-1,4-dihydropyridines." Chemical Communications 56, no. 90 (2020): 14055–58. http://dx.doi.org/10.1039/d0cc06401g.

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15

Yue, Xiao Qin, Qi Lin Mei, Zhi Xiong Huang, Peng Wen, and Ling Huang. "Curing Reaction and Kinetic Parameters of Diallyl Orthophthalate Resin with Initiator Dicumyl Peroxide." Advanced Materials Research 160-162 (November 2010): 1366–71. http://dx.doi.org/10.4028/www.scientific.net/amr.160-162.1366.

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The curing reaction of diallyl orthophthalate(DAOP) resin, which was initiated by dicumyl peroxide(DCP), was studied by Fourier transform infrared spectroscopy(FTIR). Differential scanning calorimetry(DSC) was used to determine the curing behavior and kinetic parameters of dicumyl peroxide (DCP) / diallyl orthophthalate (DAOP) system. The results clarified that the curing reaction of DAOP resin could be initiated by DCP at 150-180°C and the reaction heat diffused slowly in curing process. The gel-temperature, curing temperature and thermal treatment temperature of the DCP(3%)/DAOP system were

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16

Li, Ze-lin, Li-kun Jin, and Chun Cai. "Efficient synthesis of 2-substituted azoles: radical C–H alkylation of azoles with dicumyl peroxide, methylarenes and cycloalkanes under metal-free condition." Organic Chemistry Frontiers 4, no. 10 (2017): 2039–43. http://dx.doi.org/10.1039/c7qo00396j.

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17

González, L., A. Rodríguez, A. Marcos, and C. Chamorro. "Crosslink Reaction Mechanisms of Diene Rubber with Dicumyl Peroxide." Rubber Chemistry and Technology 69, no. 2 (1996): 203–14. http://dx.doi.org/10.5254/1.3538365.

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Abstract The scope of this paper is to review peroxide curing of diene elastomers. At high dicumyl peroxide loading and high curing temperature, changes in the crosslinking mechanisms were observed. Both Abstraction of allylic hydrogen and addition to the double bond can act as mechanisms of crosslinking. IR spectroscopy reveals a significant decrease in double bonds, and a new relaxation at temperatures above the Tg of the elastomers is present.

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18

Kakhramanov, Najaf T., Ulviya M. Mammadli, Nushaba B. Arzumanova, Zulfira N. Huseynova, Esmira V. Dadasheva, and Bakhtiyar A. Mammadov. "PROPERTIES OF DYNAMIC THERMOPLASTIC ELASTOMERS BASED ON POLYPROPYLENE AND BUTADIEN-NITRIL RUBBER." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 62, no. 7 (2019): 107–17. http://dx.doi.org/10.6060/ivkkt.20196207.5781.

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The study results of the influence of butadiene-nitrile rubber different grades concentration, cross-linking agent type and content on the physico-mechanical and thermo-deformation properties of polymer compositions based on polypropylene are presented. Mixing of the components was carried out on hot rollers in the melt mode at 170 °C. A preliminary study of rubber concentration affect on the properties of compositions based on polypropylene showed that the introduction of an elastomeric component leads to a regular decrease in the strength and elongation at break of the compositions. The resu

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19

Lee, Seung-Hwan, Tsutomu Ohkita, and Kazuo Kitagawa. "Eco-composite from poly(lactic acid) and bamboo fiber." Holzforschung 58, no. 5 (2004): 529–36. http://dx.doi.org/10.1515/hf.2004.080.

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Abstract Bamboo fiber-filled poly(lactic acid) (PLA) eco-composites were prepared by mechano-chemical compositing with bamboo fiber (BF)-esterified maleic anhydride (MA) (BF-e-MA) in the presence of dicumyl peroxide as a radical initiator. Tensile properties of the composites were improved by adding BF-e-MA and the dicumyl peroxide. A sufficient effect of the addition on the tensile property of the composites was observed even in the presence of the dicumyl peroxide of 0.25%. However, the composites with BF-e-MA usually showed a higher activation energy for thermal flow, indicating that their

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20

Shangguan, Yonggang, Jie Yang, and Qiang Zheng. "Rheology of nitrile rubber with hybrid crosslinked network composed of covalent bonding and hydrogen bonding." RSC Advances 7, no. 26 (2017): 15978–85. http://dx.doi.org/10.1039/c7ra01106g.

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A hybrid crosslinked network composed of covalent bonding and non-covalent bonding was constructed in nitrile rubber (NBR) by using a compound crosslinking agents dicumyl peroxide (DCP) and N,N-methylenebis acrylamide (MBA).

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21

de Kock, R. J., and P. A. H. M. Hol. "The nature of the chemiluminescence of dicumyl peroxide decomposition." Recueil des Travaux Chimiques des Pays-Bas 85, no. 1 (2010): 102–8. http://dx.doi.org/10.1002/recl.19660850116.

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22

Zhou, Jing, Lin Hao, Hongxun Hao, Xiongtao Ji, Jun Li, and Lina Zhou. "Formation mechanism of liquid inclusions in dicumyl peroxide crystals." CrystEngComm 23, no. 23 (2021): 4214–28. http://dx.doi.org/10.1039/d1ce00437a.

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23

Standau, Tobias, Svenja Murillo Castellón, Agathe Delavoie, Christian Bonten, and Volker Altstädt. "Effects of chemical modifications on the rheological and the expansion behavior of polylactide (PLA) in foam extrusion." e-Polymers 19, no. 1 (2019): 297–304. http://dx.doi.org/10.1515/epoly-2019-0030.

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AbstractIt is well known that polylactide (PLA) is difficult to foam due to its low melt strength. Thus, many ways were described in the literature to enhance the foamability. However, the melt strength was actually determined only in a limited number of publications. In this study, the addition of chemical modifiers was used to change the rheological behavior of PLA and thereby improve its foamability in foam extrusion process. For the first time the use of dicumyl peroxide modified PLA in foam extrusion is described. Both modifications lead to a distinct increase in melt strength. Here, the

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24

Ferradino, Anthony G. "Antioxidant Selection for Peroxide Cure Elastomer Applications." Rubber Chemistry and Technology 76, no. 3 (2003): 694–718. http://dx.doi.org/10.5254/1.3547763.

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Abstract For applications demanding the best high temperature aging performance with lowest compression set, polymers are crosslinked with peroxides. The carbon-carbon bonds that are formed are more thermally stable than crosslinks containing sulfur atoms generated by conventional vulcanization by sulfur- and sulfur based cure systems. However, peroxide crosslinking requires special attention to the selection of compounding ingredients. Materials such as plasticizers, oils, and acidic materials such as silicas and air-floated clays detract from crosslinking efficiency by competing with the pol

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25

Niu, Yan-Ning, Xiao-Feng Xia, and Yuan Yuan. "Metal-Free Cascade Methylation/Cyclization of N-Alkyl-N-methacryloylbenzamides with Dicumyl Peroxide." Synlett 29, no. 05 (2017): 617–20. http://dx.doi.org/10.1055/s-0036-1591522.

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A metal-free radical cascade methylation/cyclization of a wide range of N-alkyl-N-methacryloylbenzamides by using dicumyl peroxide as the methylating reagent provides a convenient access to a series of methylated isoquinoline-1,3-diones in moderate yields.

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26

Zhang, Pei-Zhi, Jian-An Li, Ling Zhang, Adedamola Shoberu, Jian-Ping Zou, and Wei Zhang. "Metal-free radical C–H methylation of pyrimidinones and pyridinones with dicumyl peroxide." Green Chemistry 19, no. 4 (2017): 919–23. http://dx.doi.org/10.1039/c6gc03355e.

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A method for free radical methylation of pyrimidinones and pyridinones with dicumyl peroxide under metal-free conditions is introduced. A 50 g-scale reaction could be performed safely. The product was separated by crystallization and the byproducts were recovery by distillation.

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27

Šimǔnková, D., R. Rado, and J. Letz. "Interpolymer transformations in polymer mixtures initiated by peroxides: The system polyethylene-polyisobutylene-dicumyl peroxide." Journal of Polymer Science Part C: Polymer Symposia 16, no. 2 (2007): 693–704. http://dx.doi.org/10.1002/polc.5070160210.

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28

Tian, Yunfei, and Zhong-Quan Liu. "Metal-free radical cascade dichloromethylation of activated alkenes using CH2Cl2: highly selective activation of the C–H bond." RSC Adv. 4, no. 110 (2014): 64855–59. http://dx.doi.org/10.1039/c4ra12032a.

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A dicumyl peroxide-initiated highly selective activation of the (sp<sup>3</sup>)C–H bond in dichloromethane (DCM, CH<sub>2</sub>Cl<sub>2</sub>) has been achieved, which allows efficient access to dichloronated oxindoles via a free-radical cascade process.

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29

Xiao, Yong Shan, Li Yu Chen, Run Xia Lu, and Cheng Qian Tang. "Selective Oxidation of Methane to Methanol with Organic Oxidants Catalyzed by Iodine in Non-Aqueous Acetic Acid Medium." Applied Mechanics and Materials 723 (January 2015): 624–28. http://dx.doi.org/10.4028/www.scientific.net/amm.723.624.

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Various organic oxidants including tert-butyl peroxybenzoate, tert-butyl hydroperioxide (TBHP), hydrogen peroxide-urea adduct, dicumyl peroxyide and peracetic acid solution were studied for the oxidation of methane to methanol via methyl acetate catalyzed by iodine in non-aqueous acetic acid medium. Among these organic oxidants investigated, tert-butyl hydroperioxide (TBHP) exhibited the highest methane conversion. The effects of various kinetic factors on the catalytic behavior of the TBHP-I2 system were investigated, and a quantitative yield of methyl acetate (18.9%) based on methane has bee

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30

Liu, Lu, Jiarui Hou, Liping Wang, Jianming Zhang, and Yongxin Duan. "Role of Dicumyl Peroxide on Toughening PLLA via Dynamic Vulcanization." Industrial & Engineering Chemistry Research 55, no. 37 (2016): 9907–14. http://dx.doi.org/10.1021/acs.iecr.6b02122.

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31

Zaitseva, Svetlana V., Olga R. Simonova, Sergei A. Zdanovich, Evgeniy V. Kudrik та Oscar I. Koifman. "Reaction of μ-Nitrido Diiron(IV) Phthalocyanine and Dicumyl Peroxide". Macroheterocycles 7, № 1 (2014): 55–59. http://dx.doi.org/10.6060/mhc140486z.

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32

Greszta, Dorota, and Krzysztof Matyjaszewski. "TEMPO-mediated polymerization of styrene: Rate enhancement with dicumyl peroxide." Journal of Polymer Science Part A: Polymer Chemistry 35, no. 9 (1997): 1857–61. http://dx.doi.org/10.1002/(sici)1099-0518(19970715)35:9<1857::aid-pola27>3.0.co;2-3.

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33

Yang, Tao, Wen-Jin Xia, Bin Zhou, Yangchun Xin, Yuehai Shen, and Ya-Min Li. "The Cascade Methylation/Cyclization of ortho -Cyanoarylacrylamides with Dicumyl Peroxide." European Journal of Organic Chemistry 2019, no. 33 (2019): 5749–55. http://dx.doi.org/10.1002/ejoc.201900918.

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34

Liao, Hsin-Tzu, and Chin-San Wu. "Study on Crosslinking of Polyethylene–Octene Elastomer with Dicumyl Peroxide." Polymer-Plastics Technology and Engineering 42, no. 1 (2003): 1–16. http://dx.doi.org/10.1081/ppt-120016332.

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35

Hou, H. Y., T. S. Liao, Y. S. Duh, and C. M. Shu. "Thermal hazard studies for dicumyl peroxide by DSC and TAM." Journal of Thermal Analysis and Calorimetry 83, no. 1 (2006): 167–71. http://dx.doi.org/10.1007/s10973-005-7054-4.

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36

Zedler, Łukasz, Marta Przybysz-Romatowska, Józef Haponiuk, Shifeng Wang, and Krzysztof Formela. "Modification of Ground Tire Rubber—Promising Approach for Development of Green Composites." Journal of Composites Science 4, no. 1 (2019): 2. http://dx.doi.org/10.3390/jcs4010002.

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Ground tire rubber (GTR) was mechano-chemically modified using a road bitumen 100/150 and two types of organic peroxides: di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB) and dicumyl peroxide (DCP). The impact of used additives on reactive sintering efficiency and physico-mechanical properties of modified GTR was investigated using oscillating disc rheometer measurements, followed by tensile tests and swelling behavior studies. It was found that the application of bitumen and both used peroxides (DCP/BIB) improves processing and reactive sintering efficiency better than untreated GTR. However,

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37

Kiyotsukuri, Tsuyoshi, Li Kong, and Naoto Tsutsumi. "Crosslinking of Synthetic Fibers by Peroxide (Part1). Crosslinking of Nylon 66 Fiber by Dicumyl Peroxide and Benzoyl Peroxide." Sen'i Gakkaishi 49, no. 4 (1993): 163–68. http://dx.doi.org/10.2115/fiber.49.4_163.

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38

Kakhramanov, N. T., A. J. Guliyev, M. I. Abdullin, and Kh V. Allahverdiyeva. "Thermodeformation properties of dynamically volcanized thermoplastic elastomers based on random polypropylene and nitrile butadiene rubber." Perspektivnye Materialy 7 (2021): 49–55. http://dx.doi.org/10.30791/1028-978x-2021-7-49-55.

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The paper presents the results of a study of the thermodefomational characteristics of dynamically vulcanized thermoplastic elastomers based on random polypropylene and nitrile butadiene rubber (SKN). In order to improve the compatibility of polymer mixtures, Exxelor PO1200, a grafted copolymer of polypropylene with maleic anhydride, was used as a compatibilizer. The concentration of maleic anhydride in the composition of the grafted copolymer was 3.0 wt. %. It was shown that as a result of the loading of the compatibilizer, it seemed possible to improve the compatibility of bipolar mixtures,

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39

Lv, Jiayu, Liping Chen, Wanghua Chen, Haisu Gao, and Minjun Peng. "Kinetic analysis and self-accelerating decomposition temperature (SADT) of dicumyl peroxide." Thermochimica Acta 571 (November 2013): 60–63. http://dx.doi.org/10.1016/j.tca.2013.08.029.

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40

Di Somma, Ilaria, Raffaele Marotta, Roberto Andreozzi, and Vincenzo Caprio. "Dicumyl Peroxide Thermal Decomposition in Cumene: Development of a Kinetic Model." Industrial & Engineering Chemistry Research 51, no. 22 (2011): 7493–99. http://dx.doi.org/10.1021/ie201659a.

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41

Svoboda, Petr, Sameepa Poongavalappil, Rajesh Theravalappil, et al. "Cross-linking of ethylene-octene copolymer (EOC) by dicumyl peroxide (DCP)." Journal of Applied Polymer Science 121, no. 1 (2011): 521–30. http://dx.doi.org/10.1002/app.33655.

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42

Duh, Yih-Shing, Chen-San Kao, and Wen-Lian William Lee. "Chemical kinetics on thermal decompositions of dicumyl peroxide studied by calorimetry." Journal of Thermal Analysis and Calorimetry 127, no. 1 (2016): 1089–98. http://dx.doi.org/10.1007/s10973-016-5797-8.

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43

Msakni, A., P. Chaumont, and P. Cassagnau. "Diffusion of the dicumyl peroxide in molten polymer probed by rheology." Rheologica Acta 46, no. 7 (2007): 933–43. http://dx.doi.org/10.1007/s00397-007-0176-9.

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44

Wu, S. H., Y. W. Wang, T. C. Wu, W. N. Hu, and C. M. Shu. "Evaluation of thermal hazards for dicumyl peroxide by DSC and VSP2." Journal of Thermal Analysis and Calorimetry 93, no. 1 (2008): 189–94. http://dx.doi.org/10.1007/s10973-007-8874-1.

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45

Wu, K. W., H. Y. Hou, and C. M. Shu. "Thermal phenomena studies for dicumyl peroxide at various concentrations by DSC." Journal of Thermal Analysis and Calorimetry 83, no. 1 (2006): 41–44. http://dx.doi.org/10.1007/s10973-005-6983-2.

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46

Shao, Hui Ju, Jian Bing Guo, Yang Jun Li, Jie Yu, and Shu Hao Qin. "Reactive Grafting of Glycidyl Methacrylate onto Poly (Ethylene-1-Octene)." Advanced Materials Research 239-242 (May 2011): 1153–58. http://dx.doi.org/10.4028/www.scientific.net/amr.239-242.1153.

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Poly (ethylene-1-octene) (POE) was functionalized to varying degrees with glycidyl methacrylate (GMA) by melt grafting processes. Fourier transform infrared spectra (FT-IR) and 1H NMR spectra confirmed that glycidyl methacrylate was successfully grafted onto the POE. When dicumyl peroxide(DCP)concentration was around 4‰ high graft degree was obtained. The data from GPC measure demonstrates that POE chains degraded during grafting process.

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47

Zedler, Łukasz, Xavier Colom, Javier Cañavate, and Krzysztof Formela. "GTR/NBR/Silica Composites Performance Properties as a Function of Curing System: Sulfur versus Peroxides." Materials 14, no. 18 (2021): 5345. http://dx.doi.org/10.3390/ma14185345.

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In this work, conventional sulfur and two types of organic peroxides (dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB)) curing systems were used to investigate the possibility for tailoring of the performance properties of GTR/NBR blends reinforced with a variable content of highly dispersive silica (0–30 phr). The curing characteristics, static mechanical and acoustical properties, swelling behavior, thermal stability, and microstructure of the prepared composites were investigated. The results show that regardless of the curing system used, increasing the content of

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Ushmarin, Nikolay F., Lyudmila Yu Tsareva, Ksenia A. Konnova, Maria V. Yakimova, and Nikolay I. Koltsov. "The influence of technological additives and peroxides on the properties of rubber mixtures based on ethylene propylene caoutchouc." Butlerov Communications 60, no. 10 (2019): 81–87. http://dx.doi.org/10.37952/roi-jbc-01/19-60-10-81.

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The article investigates the influence of technological additives and peroxides on the properties of two rubber mixtures based on ethylene-propylene caoutchouc of marking SKEPT-40. The main properties were: rheometric (maximum and minimum torques; start, optimum and maximum vulcanization rates; maximum vulcanization rates), physical and mechanical (conditional tensile strength, elongation at break, hardness) and operational (changes in conditional strength at tensile, elongation at break and hardness after aging in air). The resistance of rubbers to the action of high temperatures by methods o

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Hirai, Naoshi, Ryotaro Minami, Yoshimichi Ohki, Minoru Okashita, and Takashi Maeno. "Effects of Byproducts of Dicumyl Peroxide on Space Charge Formation in Polyethylene." IEEJ Transactions on Fundamentals and Materials 122, no. 3 (2002): 308–14. http://dx.doi.org/10.1541/ieejfms.122.308.

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Rytlewski, P., M. Żenkiewicz, and R. Malinowski. "Influence of Dicumyl Peroxide Content on Thermal and Mechanical Properties of Polylactide." International Polymer Processing 26, no. 5 (2011): 580–86. http://dx.doi.org/10.3139/217.2521.

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