Academic literature on the topic 'Diels Alder addition'

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Journal articles on the topic "Diels Alder addition"

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Hopf, Henning, and Marcus Theurig. "Synthesis of Enediynes by Diels-Alder Addition." Angewandte Chemie International Edition in English 33, no. 10 (1994): 1099–100. http://dx.doi.org/10.1002/anie.199410991.

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Hopf, Henning, and Marcus Theurig. "Synthese von Endiinen durch Diels-Alder-Addition." Angewandte Chemie 106, no. 10 (1994): 1173–74. http://dx.doi.org/10.1002/ange.19941061025.

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Teixeira, Filipe, André Melo, and M. Natália D. S. Cordeiro. "Aza-Diels–Alder addition of cyclopentadiene to propynyliminoglyoxylates." Computational and Theoretical Chemistry 1012 (May 2013): 54–59. http://dx.doi.org/10.1016/j.comptc.2013.02.014.

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Hamrock, Steven J., and Robert S. Sheridan. "Photochemical Diels-Alder addition of N-methyltriazolinedione to phenanthrene." Tetrahedron Letters 29, no. 43 (1988): 5509–12. http://dx.doi.org/10.1016/s0040-4039(00)80799-6.

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Donegan, Gregory, Ronald Grigg, Frances Heaney, Sivagnanasundram Surendrakumar, and William J. Warnock. "Consecutive diels-alder- michael addition - 1,3-dipolar cycloaddition processes." Tetrahedron Letters 30, no. 5 (1989): 609–12. http://dx.doi.org/10.1016/s0040-4039(00)95268-7.

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Zhang, Lei, Jianzhong Yang, Christopher L. Edwards, Lawrence B. Alemany, Valery N. Khabashesku, and Andrew R. Barron. "Diels–Alder addition to fluorinated single walled carbon nanotubes." Chemical Communications, no. 26 (2005): 3265. http://dx.doi.org/10.1039/b500125k.

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Brimble, Margaret A., John F. McEwan, and Peter Turner. "Asymmetric Diels–Alder addition of cyclopentadiene to chiral naphthoquinones." Tetrahedron: Asymmetry 9, no. 7 (1998): 1239–55. http://dx.doi.org/10.1016/s0957-4166(98)00087-1.

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Döpp, Dietrich, and Michael Pies. "High asymmetic induction in a photo-Diels–Alder addition." J. Chem. Soc., Chem. Commun., no. 22 (1987): 1734–35. http://dx.doi.org/10.1039/c39870001734.

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Miller, Bernard, and Dumitru Ionescu. "An addition—cyclization—elimination mechanism for dehydro Diels-Alder reactions." Tetrahedron Letters 35, no. 36 (1994): 6615–18. http://dx.doi.org/10.1016/s0040-4039(00)73449-6.

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ZHANG, X., Q. JIANG, Z. XIONG, J. ZOU, L. WANG, and Z. MI. "Diels-Alder Addition of Dicyclopentadiene with Cyclopentadiene in Polar Solvents." Chemical Research in Chinese Universities 24, no. 2 (2008): 175–79. http://dx.doi.org/10.1016/s1005-9040(08)60036-7.

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Dissertations / Theses on the topic "Diels Alder addition"

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Steizer, Lindsay S. "Synthesis of polysubstituted pyridines : Diels-Alder addition of 1-AZA-1, 3-dienes with acetylenic and ethylenic dienophil." Virtual Press, 1986. http://liblink.bsu.edu/uhtbin/catkey/452401.

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The synthesis of methyl 3,6-dimethylpyridine-2-carboxylate (192) by the Diels-Alder addition of 3-butene-2-one dimethylhydrazone (190) and methyl-2-butynoate (16) is described. The structure of 192 was confirmed by the synthesis of methyl 2,6-dimethylpyridine-3-carboxylate (195), the opposite regioisomer.The synthesis of methyl 3,5-dimethylpyridine-2-carboxylate (199) from [4+2] cycloaddition of 2-methyl-2-propenal dimethylhydrazone (171) and 16 is described. In addition to producing a small amount of 199 directly, the reaction produced an intermediate of possible structure 198 which yielded 1
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Tabti, Boufeldja. "Preparation de synthons lactoniques par reaction de diels-alder." Le Mans, 1987. http://www.theses.fr/1987LEMA1019.

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Reactions de diels alder en solution aqueuse d'alkyls-5 3h-furannones-2 et de cetosulfoxydes ou d'ester-sulfoxydes : obtention de lactones bicycliques utilisables pour la synthese de lactones sesquiterpeniques
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Goodby, Andrew James. "An investigation of Diels-Alder addition across a metal bound #eta#-C←5Me←5 group." Thesis, University of Salford, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.262647.

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Li, Mao. "Iron(III) catalyzed asymmetric Diels-Alder reaction - Iron(II) catalyzed thia-Michael addition and aldehyde allylation reactions." Doctoral thesis, Université Laval, 2019. http://hdl.handle.net/20.500.11794/34969.

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En raison de leur grande performance, leur prix peu élevé, et leur abondance sur la terre, les catalyseurs de fer ont été choisis pour être testés dans trois différentes transformations de la chimie organique. Le premier projet concerne les réactions asymétriques de Diels-Alder catalysées par Fe⁺¹¹¹ et le ligand bipyridine chiral à des dérivés α, β-insaturés de l’oxazolidin-2-one. Dans un premier temps, nous avons testé différents solvants, diverses quantités en catalyseur, temps de réaction variés et divers sels de fer tels que Fe(ClO₄)₂·6H₂O, Fe(ClO₄)₂·6H₂O, Fe(OTf)₃, Fe(OTf)₂, FeCl₂, FeCl₃,
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Modin, Stefan. "Developments in the Field of Aza-Diels-Alder Reactions, Catalytic Michael Additions and Automated Synthesis." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis, Univ.bibl. [distributör], 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-4640.

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Thadani, Avinash N. "Boron tethered intramolecular Diels-Alder cycloadditions and addition of allyl- and crotyltrifluoroborates to carbonyl compounds in biphasic media." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp05/NQ63605.pdf.

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Le, Strat Frédéric. "Addition conjuguée d'organométalliques sur des acétals propargyliques : application intramoléculaire à l'hétérocyclisation binucléaire." Rouen, 2002. http://www.theses.fr/2002ROUES027.

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Ce travail décrit l'utilisation de la réaction intramoléculaire d'addition conjuguée sur les acétals propargyliques en synthèse d'hétérocycles binucléaires. L'application de cette réaction à partir d'éthers et d'amines propargyliques permet l'accès aux vinylbenzofuranes et furopyridines par voie anionique via une cascade de cyclisation-élimination-isomérisation. La synthèse de 3-vinylindoles par cette même réaction nécessite une pré isomérisation de l'alcyne en allène. Les vinylisoquinoléinones et (iso)chromanes, qui ne peuvent être obtenus par lithiation nécessitent une étape de cyclisation p
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Minassian, Frédéric. "Réactions des [epsilon]-pentadiénylation et réactions intramoléculaires de Diels-Alder : synthèse stéréosélective de composés bicycliques." Université Joseph Fourier (Grenoble), 2000. http://www.theses.fr/2000GRE10117.

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Parmi les differents types de composes presentant des activites biologiques interessantes, les molecules possedant au moins un systeme bicyclique constituent une classe importante. Nous avons etudie une strategie de synthese de ces systemes en une etape basee sur une reaction intramoleculaire de diels-alder (ou reaction imda). Cette reaction met en jeu un precurseur lineaire comportant a ses extremites les entites diene et dienophile necessaires. Nous avons donc etudie des voies d'acces a divers precurseurs de ce type. Nous avons d'abord envisage de former des 4-azabicyclo4. 3. 0nonanes, ou in
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Stopler, Erika Brooke. "CARBON NANOTUBE REINFORCED DYNAMIC MATERIALS SYNTHESIZED BY REVERSIBLE ADDITION FRAGMENTATION CHAIN TRANSFER (RAFT) POLYMERIZATION." Miami University / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=miami1564680997583507.

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Espinosa, Rodriguez Edgar. "Préparation de polyéthylènes portant des fonctions réactives en extrémité de chaînes et leur utilisation en tant qu’agents de couplage pour la conception de matériaux originaux à base de polyéthylène." Thesis, Lyon 1, 2011. http://www.theses.fr/2011LYO10292/document.

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Le polyéthylène (PE) est omniprésent dans notre vie de tous les jours et ce principalement car il présente des propriétés thermiques et mécaniques qu’on ne retrouve pas d’autres polymères. Cependant, sa très faible réactivité chimique fait qu’il est difficile de l’incorporer dans des architectures macromoléculaires plus complexes qui pourraient profiter de ses propriétés uniques. La modification de polymères fonctionnels en extrémité de chaîne par des réactions de couplage efficaces est un outil très utilisé pour la conception d’architectures macromoléculaires. Parmi les différentes réactions
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Books on the topic "Diels Alder addition"

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Goodby, Andrew James. An investigation of Diels-Alder addition across a metal bound n5-C5Me5 group. University of Salford, 1995.

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Thadani, Avinash N. Boron tethered intramolecular Diels-Alder cycloadditions and addition of allyl- and crotyltrifluoroborates to carbonyl compounds in biphasic media. 2001.

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Dockendorff, Christopher James. New methods for carbon-carbon bond formation and application to organic synthesis: Metal-catalyzed additions of organoborons to activated alkenes and aryne Diels-Alder reactions with acyclic dienes: Y Christopher James Dockendorff. 2006.

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Book chapters on the topic "Diels Alder addition"

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Döpp, Dietrich, and Hamid Reza Memarian. "Photo-Diels-Alder Addition of two Captodative Alkenes to 1-Acetonaphthone." In Substituent Effects in Radical Chemistry. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4758-0_35.

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Bauld, N. L. "Direct and Indirect Diels-Alder Additions to Electron Rich Dienophiles." In Organic Free Radicals. Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_4.

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Vogel, Pierre. "Combinatorial Synthesis of Linearly Condensed Polycyclic Compounds, Including Anthracyclinones, Through Tandem Diels–Alder Additions." In Anthracycline Chemistry and Biology I. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/128_2007_148.

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Garbaccio, R. M., and S. E. Wolkenberg. "Catalytic Asymmetric Diels–Alder Addition to Chiral Imino Esters." In Three Carbon-Heteroatom Bonds: Acid Halides; Carboxylic Acids and Acid Salts. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-020-01097.

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Taber, Douglass F. "Diels–Alder Cycloaddition: Nicolaioidesin B (Coster), Lycorine (Cho), Bucidirasin A (Nakada), Maoecrystal V (Thomson), Kuwanon J (Wulff/Lei), Vinigrol (Kaliappan)." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0079.

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β-Ocimene 2 is an inexpensive Diels–Alder diene. En route to nicolaioidesin B 4, Mark J. Coster of Griffith University showed (Tetrahedron Lett. 2014, 55, 6864) that the Weinreb amide 1 added to the E isomer of 2 with high selectivity, to give 3. The alkaloid lycorine 8 is found throughout the Amaryllidaceae. Cheon-Gyu Cho of Hanyang University developed (Org. Lett. 2014, 16, 5718) a succinct route to 8 based on the use of the boryl styrene 5 as a Diels–Alder dienophile. Masahisa Nakada of Waseda University (Org. Lett. 2014, 16, 4734) prepared the enantiomerically-pure enone 9 by way of a baker’s yeast reduction of a prochiral dik­etone. Diels–Alder addition to 10 led to 11, that was carried on to bucidirasin A 12. Regan J. Thomson of Northwestern University prepared (J. Am. Chem. Soc. 2014, 136, 17750) the triene 13 by asymmetric epoxidation of a prochiral enone. Diels–Alder addition of the very reactive nitroethylene to give 14 completed the carbon skel­eton of maoecrystal V 15. William D. Wulff of Michigan State University and Xiaoguang Lei of Peking University optimized (Angew. Chem. Int. Ed. 2014, 53, 9257) the organocatalyzed Diels–Alder cycloaddition of 17 to the diene 16. Deprotection then completed the synthesis of the prenylflavonoid kuwanon J 18. In 2012, Barriault described (OHL 20121224) the conversion of 20 to the com­plex diterpene vinigrol 21. Krishna P. Paliappan of the Indian Institute of Technology Bombay showed (Org. Lett. 2014, 16, 5540) that the triene precursor to 20 could be prepared by ring-closing metathesis of 19. In the absence of ethylene, a different product was formed.
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"Preparation, Characterization and Selective Solubility of Diels–Alder Addition Polyimides." In Polyimides and Other High Temperature Polymers: Synthesis, Characterization and Applications, Volume 5. CRC Press, 2009. http://dx.doi.org/10.1201/b12248-4.

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Taber, Douglass F. "The Nakada Synthesis of (-)-FR182877." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0084.

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The Streptomyces metabolite (-)-FR182877 3 binds to and stabilizes microtubules, showing the same potency of anticancer activity as Taxol (paclitaxel). Masahisa Nakada of Waseda University assembled (Angew. Chem. Int. Ed. 2009, 48, 2580) the hexacyclic ring system of 3 by the tandem intramolecular Diels-Alder–intramolecular hetero Diels-Alder cyclization of 1, generating seven new stereogenic centers in a single step. The construction of the pentaene substrate 1 started with the known aldehyde 4, prepared by homologation of commercial ethyl 3-methyl-4-oxocrotonate. Addition of the propionyl oxazolidine anion 5 proceeded with high diastereocontrol, to give 6. The acyl oxazolidinone was not an efficient acylating agent, so it was converted to the Weinreb amide. Protection and deprotection then delivered the allylic acetate 7. The key step in the pentaene assembly was the carefully optimized Negishi-Wipf methylation of 8, followed by Pd-mediated coupling of the alkenyl organometallic so generated with the allylic acetate, to give 9. Condensation of the derived keto phosphonate 11 with the known aldehyde 12 then delivered the enone 13. The Nakada group has worked extensively on the intramolecular Diels-Alder reaction of substrates such as 1. They have shown that protected anti diols such as 1 cyclize with substantial diastereocontrol and in the desired sense. In contrast, cyclizations of protected syn diols proceed with poor diastereocontrol. The enone 13 was therefore reduced to the anti diol and protected, leading to 14 . Oxidation of 14 at room temperature led to a complex mixture, but slow oxidation at elevated temperature delivered 2 . Although the yield of 2 was not much better than if the reactions were carried out sequentially, first the intramolecular Diels-Alder cyclization, then the intramolecular hetero Diels-Alder cyclization, with the cascade protocol pure 2 was more readily separated from the reaction matrix. With 2 in hand, there was still the challenge of assembling the seven-membered ring. Cyclization was effected with an intramolecular Heck protocol. The two diastereomers of the allylic alcohol 15 cyclized with comparable efficiency. Ir-catalyzed alkene migration then converted the allylic alcohols to a mixture of ketones, which was equilibrated to give the more stable diasteromer.
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Garbaccio, R. M., and S. E. Wolkenberg. "Asymmetric Diels–Alder Addition to Chiral Imino Esters; Chiral Menthyl ­Derivatives." In Three Carbon-Heteroatom Bonds: Acid Halides; Carboxylic Acids and Acid Salts. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-020-01098.

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Taber, Douglass. "Intermolecular and Intramolecular Diels-Alder Reactions: Platencin (Banwell), Platensimycin (Matsuo), (-)-Halenaquinone (Trauner), ( + )-Cassaine (Deslongchamps)." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0079.

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José Barluenga of the Universidad de Oviedo described (Organic Lett. 2008, 10, 4469) a powerful route from lithiated arenes such as 1 to the benzocyclobutane 3, the immediate precursor to the powerful o-quinone methide Diels-Alder diene. Michael E. Jung of UCLA developed (Organic Lett. 2008, 10, 3647) a triflimide catalyst for the inverse electron demand coupling of the highly substituted diene 4 with the enol ether 5 to give 6 with high diastereocontrol. Joseph M. Fox of the University of Delaware showed (J. Org. Chem. 2008, 73, 4283) that the cyclopropene carboxylate 8 was a powerful and selective dienophile. Richard P. Hsung and Kevin P. Cole of the University of Wisconsin finally (Adv. Synth. Cat. 2008, 350, 2885) reduced to practice the long-sought enantioselective Diels-Alder cycloaddition of a trisubstituted aldehyde, 11. Li Deng of Brandeis University devised (J. Am. Chem. Soc. 2008, 130, 2422) a Cinchona -derived catalyst for Diels-Alder cycloaddition to the diene 13 with high ee. Miguel Á. Sierra of the Universidad Complutense, Madrid, and Alejandra G. Suárez of the Universidad Nacional de Rosario described (Organic Lett. 2008, 10, 3389) a clever switchable chiral auxiliary 16 that favored diastereomer S-18 on thermal addition, but R-18 with EtAlCl2. New approaches to the intramolecular Diels-Alder reaction continue to be introduced. Mathias Christmann, now at the TU Dortmund, showed (Angew. Chem. Int. Ed. 2008, 47, 1450) that a secondary amine organocatalyst converted the prochiral dialdehyde 19 into the bicyclic diene 20 with high de and ee. Martin G. Banwell of the Australian National University prepared (Organic Lett. 2008, 10, 4465) the triene 21 in high ee by microbiological oxidation of iodobenzene. On warming, 21 was converted smoothly into 22, which was carried on in a formal synthesis of platencin. Jun-ichi Matsuo of Kanazawa University was able (Organic Lett. 2008, 10, 4049) to induce (neat, 180 °C) the intermolecular Diels-Alder cycloaddition of 23 with 24, delivering the cycloadduct 25 with 11:1 diastereocontrol.
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Garbaccio, R. M., and S. E. Wolkenberg. "Asymmetric Diels–Alder Addition to Chiral Imino Esters; Chiral 1-Phenylethylamine Derivatives." In Three Carbon-Heteroatom Bonds: Acid Halides; Carboxylic Acids and Acid Salts. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-020-01099.

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Conference papers on the topic "Diels Alder addition"

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Herdewijn, Piet. "The Diels–Alder cyclo addition as key reaction for the synthesis of cyclohexenyl nucleosides." In XIIIth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2005. http://dx.doi.org/10.1135/css200507029.

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Li, Ming, Tae-Ho Yoon, and Dong-Pyo Kim. "Novel Inorganic Polymer Derived Microfluidic Devices: Materials, Fabrication, Microchemical Performance." In ASME 2009 7th International Conference on Nanochannels, Microchannels, and Minichannels. ASMEDC, 2009. http://dx.doi.org/10.1115/icnmm2009-82136.

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We introduce the successful fabrication of inorganic polymer derived microchannels with organic solvent resistance and optical transparency, via economic micro-molding process by using two types of source materials: commercial polyvinylsilazane (HTT1800 Kion Corp.), or allylhydropolycarbosilane (SMP-10, Starfire Co.). And we demonstrated the reliable microchemical performance in various organic solvents such as THF, DMF and acetonitrile at elevated temperatures. Knovenagel and Diels-Alder reactions were successfully run by pressured-driven flow in 2 cm and 16 cm long channel, respectively. It
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Heo, Yunseon, and Henry A. Sodano. "Thermo-Responsive Shape Memory Self-Healing Polyurethanes and Composites With Continuous Carbon Fiber Reinforcement." In ASME 2015 Conference on Smart Materials, Adaptive Structures and Intelligent Systems. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/smasis2015-8916.

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Thermally responsive self-healing polyurethanes (1DA1T, 1.5DA1T, and 2DA1H) with shape memory property were developed and the fully reversible Diels-Alder (DA) and retro Diels-Alder (rDA) reactions were employed for the healing mechanism. The transition temperatures of the DA and rDA reactions were confirmed through a differential scanning calorimetry and the molecular level of analysis on the reversibility and the repeatability between the DA and rDA reactions were completed though a variable temperature proton nuclear magnetic resonance at the reaction temperatures. Also, compact tension spe
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