Academic literature on the topic 'Divalent metal ions release'

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Journal articles on the topic "Divalent metal ions release"

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Mustafa, S., B. Dilara, A. Naeem, N. Rehana, and K. Nargis. "Temperature and pH Effect on the Sorption of Divalent Metal Ions by Silica Gel." Adsorption Science & Technology 21, no. 4 (2003): 297–307. http://dx.doi.org/10.1260/026361703322405033.

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The sorption of Zn2+, Ni2+ and Cd2+ ions by silica gel was studied as a function of ion concentration, pH and temperature. An increase in all three parameters led to an increase in the extent of sorption for all the metal cations studied. The selectivity of the solid was observed to be in the order Zn2+ > Ni2+ > Cd2+. Sorption of the metal cations was accompanied by the release of H+ ions into the bulk phase. On average two moles of H+ ions were released per mole of metal cation sorbed. The sorption data fitted the linear forms of both the Kurbatov and Langmuir adsorption equations. The
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Kim, Bongsu, and Tae Hyun Kim. "Electrochemical Studies for Cation Recognition with Diazo-Coupled Calix[4]arenes." Journal of Analytical Methods in Chemistry 2015 (2015): 1–7. http://dx.doi.org/10.1155/2015/579463.

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The electrochemical properties of diazophenylcalix[4]arenes bearingortho-carboxyl group (o-CAC) andortho-ester group (o-EAC), respectively, in the presence of various metal ions were investigated by voltammetry in CH3CN.o-CAC ando-EAC showed voltammetric changes toward divalent metal ions and no significant changes with monovalent alkali metal ions. However,o-CAC preferentially binds with alkaline earth and transition metal ions, whereas no significant changes in voltammetric signals are observed ino-EAC with alkaline earth metal ions.o-EAC only binds with other transition metal ions. This can
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Knape, Matthias J., Mike Ballez, Nicole C. Burghardt, et al. "Divalent metal ions control activity and inhibition of protein kinases." Metallomics 9, no. 11 (2017): 1576–84. http://dx.doi.org/10.1039/c7mt00204a.

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Metals like Zn<sup>2+</sup> and Mn<sup>2+</sup> can assist in the catalytic cycle of a protein kinase by facilitating substrate binding and phosphotransfer, however, in contrast to Mg<sup>2+</sup> they also hamper product release.
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Sieme, Daniel, Christian Griesinger, and Nasrollah Rezaei-Ghaleh. "Metal Binding to Sodium Heparin Monitored by Quadrupolar NMR." International Journal of Molecular Sciences 23, no. 21 (2022): 13185. http://dx.doi.org/10.3390/ijms232113185.

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Heparins and heparan sulfate polysaccharides are negatively charged glycosaminoglycans and play important roles in cell-to-matrix and cell-to-cell signaling processes. Metal ion binding to heparins alters the conformation of heparins and influences their function. Various experimental techniques have been used to investigate metal ion-heparin interactions, frequently with inconsistent results. Exploiting the quadrupolar 23Na nucleus, we herein develop a 23Na NMR-based competition assay and monitor the binding of divalent Ca2+ and Mg2+ and trivalent Al3+ metal ions to sodium heparin and the con
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Xu, Kui, Mi Zhou, Ming Li, Weizhen Chen, Yabin Zhu, and Kaiyong Cai. "Metal-phenolic networks as a promising platform for pH-controlled release of bioactive divalent metal ions." Applied Surface Science 511 (May 2020): 145569. http://dx.doi.org/10.1016/j.apsusc.2020.145569.

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Dahal, Madhav P., Geoffrey A. Lawrance, and Marcel Maeder. "Kinetics of Heavy Metal Ion Adsorption on to, and Proton Release from, Electrolytic Manganese Dioxide." Adsorption Science & Technology 16, no. 1 (1998): 39–50. http://dx.doi.org/10.1177/026361749801600106.

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The kinetics of adsorption of lead(II), as well as of copper (II), zinc(II) and thallium(I), on commercial electrolytic manganese dioxide (EMD) powder of different size fractions has been followed by a pH-stat method involving the computer-controlled neutralisation of released protons from the EMD at a fixed pH with hydroxide ion. Base uptake versus time profiles in all cases indicated a rapid initial change followed by a slower process. These can be interpreted in terms of either a solution kinetic model or an adsorption kinetic model. In the former analysis, the adsorption-time profile can b
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Chou, Chiu L., John F. Uthe, and Robert D. Guy. "Determination of Free and Bound Cd, Zn, Cu, and Ag Ions in Lobster (Homarus americanus) Digestive Gland Extracts by Gel Chromatography Followed by Atomic Absorption Spectrophotometry and Polarography." Journal of AOAC INTERNATIONAL 76, no. 4 (1993): 794–98. http://dx.doi.org/10.1093/jaoac/76.4.794.

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Abstract Gel-permeation chromatography followed by atomic absorption spectrophotometric and polarographic analyses were used to measure free and bound divalent metal ions in lobster digestive gland extracts prepared with or without oc-toluenesulfonyl fluoride, a protease inhibitor. Chromatography on Sephadex G-50 or G-100 yielded 3 UV-absorbing peaks, which corresponded, respectively, to the void volume, a medium molecular weight fraction, and a low molecular weight fraction that contained free divalent metal ions. In protease-inhibited extracts, only Zn+2 was found, whereas Cd, Cu, and Ag wer
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Facchin, F., S. Catalani, E. Bianconi, et al. "Albumin as marker for susceptibility to metal ions in metal-on-metal hip prosthesis patients." Human & Experimental Toxicology 36, no. 4 (2016): 319–27. http://dx.doi.org/10.1177/0960327116650011.

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Metal-on-metal (MoM) hip prostheses are known to release chromium and cobalt (Co), which negatively affect the health status, leading to prosthesis explant. Albumin (ALB) is the main serum protein-binding divalent transition metals. Its binding capacity can be affected by gene mutations or modification of the protein N-terminal region, giving the ischaemia-modified albumin (IMA). This study evaluated ALB, at gene and protein level, as marker of individual susceptibility to Co in MoM patients, to understand whether it could be responsible for the different management of this ion. Co was measure
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YAMADA, Masaki, Noriyuki KISHII, Koji ARAKI, and Shinsaku SHIRAISHI. "Extraction and release of divalent metal ions by 6,6'-diamino-2,2'-bipyridine supported on polymer beads." NIPPON KAGAKU KAISHI, no. 6 (1989): 988–92. http://dx.doi.org/10.1246/nikkashi.1989.988.

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Torabi, Seyed-Fakhreddin, Peiwen Wu, Claire E. McGhee, et al. "In vitro selection of a sodium-specific DNAzyme and its application in intracellular sensing." Proceedings of the National Academy of Sciences 112, no. 19 (2015): 5903–8. http://dx.doi.org/10.1073/pnas.1420361112.

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Over the past two decades, enormous progress has been made in designing fluorescent sensors or probes for divalent metal ions. In contrast, the development of fluorescent sensors for monovalent metal ions, such as sodium (Na+), has remained underdeveloped, even though Na+is one the most abundant metal ions in biological systems and plays a critical role in many biological processes. Here, we report the in vitro selection of the first (to our knowledge) Na+-specific, RNA-cleaving deoxyribozyme (DNAzyme) with a fast catalytic rate [observed rate constant (kobs) ∼0.1 min−1], and the transformatio
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Dissertations / Theses on the topic "Divalent metal ions release"

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Awassa, Jazia. "Mécanismes antibactériens des hydroxydes doubles lamellaires à base de zinc." Electronic Thesis or Diss., Université de Lorraine, 2022. http://www.theses.fr/2022LORR0155.

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Les hydroxydes doubles lamellaires (HDL) sont des composés solides constitués par un ensemble de feuilles d'hydroxydes métalliques divalents M(II) et trivalents M(III) entre lesquels s’insèrent des anions et des molécules d’eau. En raison de la flexibilité des HDL en termes de propriétés physico-chimiques, l’étude des différents mécanismes antibactériens qui leurs sont associés présente un intérêt croissant. Ce travail de thèse vise à étudier différentes hypothèses proposées pour explique l'effet antibactérien des hydroxydes doubles lamellaire (HDL) à base de zinc : (1) interactions directes e
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Wang, Yu-Wen. "Substitution of Calcium with Divalent Metal Ions in Paraoxonase I." The Ohio State University, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=osu1420819949.

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Afolaranmi, Grace Ayodele. "Disposition of metal ions in patients after release from orthopaedic arthroplasties." Thesis, University of Strathclyde, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.501856.

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Bellomo, Elisa. "Divalent metal ions and the pancreatic B-cell : role in the pathogenesis of type 2 diabetes." Thesis, Imperial College London, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.526394.

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Ferko, Maxime-Alexandre. "Molecular Mechanisms Involved in Interleukin-1β Release by Macrophages Exposed to Metal Ions from Implantable Biomaterials". Thesis, Université d'Ottawa / University of Ottawa, 2018. http://hdl.handle.net/10393/37331.

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Metal ions released from implantable biomaterials have been associated with adverse biological reactions that can limit implant longevity. Previous studies have shown that, in macrophages, Co2+, Cr3+, and Ni2+ can activate the NLR family pyrin domain-containing protein 3 (NLPR3) inflammasome, which is responsible for interleukin(IL)-1β production through caspase-1. Furthermore, these ions are known to induce oxidative stress, and inflammasome priming is known to involve nuclear factor kappa-light-chain-enhancer of activated B cells (NF-κB) signaling. However, the mechanisms of inflammasome act
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Liu, Chang. "Metal ions removal from polluted waters by sorption onto exhausted coffee waste. Application to metal finishing industries wastewater treatment." Doctoral thesis, Universitat de Girona, 2014. http://hdl.handle.net/10803/283705.

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A new technology for Cr(VI) and divalent metal ions removal based on metal sorption onto exhausted coffee waste has been developed. Physical and chemical characterization of exhausted coffee waste was explored as well as the role of structural and non structural compounds of the waste in metal ions sorption. Kinetics of Cr(VI) sorption from binary mixtures containing different Cr(VI) and Cu(II) molar ratios were carried out in a batch reactor. A synergistic effect of Cu(II) in Cr(VI) reduction and sorption was found. From the kinetic sets of data a kinetic model taking into account Cr(VI) redu
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Brännvall, Mathias. "Metal ion cooperativity in Escherichia coli RNase P RNA." Doctoral thesis, Uppsala universitet, Institutionen för cell- och molekylärbiologi, 2002. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-2056.

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RNase P is an essential ribonuclease responsible for removal of the 5’ leader of tRNA precursors. Bacterial RNase P consists of an RNA subunit and a small basic protein. The catalytic activity is associated with the RNA subunit, i.e. bacterial RNase P RNA is a ribozyme. The protein subunit is, however, essential for activity in vivo. RNase P RNA, as well as the holoenzyme, requires the presence of divalent metal ions for activity. The aim of this thesis was to increase our understanding of the catalytic mechanism of RNase P RNA mediated cleavage. The importance of the nucleotides close to the
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Xiao, Lan. "Etude physico-chimique de la complexation de divers ions metalliques (cu**(2+), ni**(2+) et co**(2+)) avec des dipeptides l-l contenant des chaines laterales non-coordinantes." Paris 7, 1988. http://www.theses.fr/1988PA077170.

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Stabilite des complexes en fonction de l'interaction des chaines laterales du dipeptide et le solvant. Mesures potentiometriques calorimetriques, caracterisation spectrometrique et structure moleculaire
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Sahmoune, Amar. "Extractions synergiques de metaux divalents de transition par association d'une acyl-4-pyrazolone-5 avec des polyethers cycliques et acycliques." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13116.

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Extractions de co. Zu. Cd et cu divalents par les melanges phenyl-1 methyl-3 benzoyl-4 pyrazolone-5 ethers crown. La coextraction alcalins-alcalinoterreux complexes par les composes crown et des metaux divalents est possible quand la taille de la cavite de l'ether-crown est voisine de celle de l'alcalin (ou alcalino-terreux) et quand l'ion ml::(3)**(-) est suffisamment stable
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Dearden, David Vernell Beauchamp Jesse L. Beauchamp Jesse L. "Experimental probes of gas phase ions and molecules : I. Product kinetic energy release measurements as a probe of reaction thermochemistry, dynamics, and chemical structure in systems containing transition metal ions. II. Photoelectron and optical studies of organic transient species /." Diss., Pasadena, Calif. : California Institute of Technology, 1989. http://resolver.caltech.edu/CaltechETD:etd-02082007-130036.

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Book chapters on the topic "Divalent metal ions release"

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Rani, Pooja. "Fluorescence Characteristics of Coumarin Derivatives with Divalent Metal Ions." In Computational and Experimental Methods in Mechanical Engineering. Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-16-2857-3_26.

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Gwizdala, Celina, and Shawn C. Burdette. "Photo-release of Metal Ions in Living Cells." In Inorganic Chemical Biology. John Wiley & Sons, Ltd, 2014. http://dx.doi.org/10.1002/9781118682975.ch9.

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Huang, Charles Y., Marina Lanciotti, and Aile Zhang. "Mechanism of Activation of Calmodulin-Dependent Phosphatase by Divalent Metal Ions." In Enzyme Dynamics and Regulation. Springer New York, 1988. http://dx.doi.org/10.1007/978-1-4612-3744-0_5.

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Kornilova, Svetlana, Valery Andrushchenko, and Yurij Blagoi. "Spectroscopic studies of divalent metal ions effect on DNA and polynucleotides structural transitions." In Spectroscopy of Biological Molecules: New Directions. Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4479-7_102.

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Sorokin, Victor A., Vladimir A. Valeev, Marina V. Degtyar, Galina O. Gladchenko, and Yuri P. Blagoi. "Effects of divalent metal ions on secondary and tertiary structures of polyriboinosinic acid." In Spectroscopy of Biological Molecules: New Directions. Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4479-7_110.

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Tabak, Marcel, Maria H. Tinto, Hidetake Imasato, and Janice R. Perussi. "Interaction of Divalent Metal Ions with the Hemoglobin of Glossoscolex paulistus: an EPR Study." In Structure and Function of Invertebrate Oxygen Carriers. Springer New York, 1991. http://dx.doi.org/10.1007/978-1-4612-3174-5_16.

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Loder, Merewyn K., Takashi Tsuboi, and Guy A. Rutter. "Live-Cell Imaging of Vesicle Trafficking and Divalent Metal Ions by Total Internal Reflection Fluorescence (TIRF) Microscopy." In Nanoimaging. Humana Press, 2012. http://dx.doi.org/10.1007/978-1-62703-137-0_2.

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Behrendt, H., M. Wieczorek, S. Wellner, and A. Winzer. "Effect of Some Metal Ions (Cd++, Pb++, Mn++) on Mediator Release from Mast Cells in Vivo and in Vitro." In Environmental Hygiene. Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73766-4_23.

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Stephan, Udo W., Ilka Schmidke, and Axel Pich. "Phloem translocation of Fe, Cu, Mn, and Zn in Ricinus seedlings in relation to the concentrations of nicotianamine, an endogenous chelator of divalent metal ions, in different seedling parts." In Iron Nutrition in Soils and Plants. Springer Netherlands, 1995. http://dx.doi.org/10.1007/978-94-011-0503-3_7.

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Glover, Robert. "Corrosion Processes of Steel-Hulled Potentially Polluting Wrecks." In Threats to Our Ocean Heritage: Potentially Polluting Wrecks. Springer Nature Switzerland, 2024. http://dx.doi.org/10.1007/978-3-031-57960-8_4.

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AbstractSubmerged metals are continuously affected by the chemical processes of corrosion, the destructive degradation of metal by chemical or electrochemical reactions within the marine environment (Valenca et al., 2022:2–3; Venugopal, 1994:35). Over time, metal ions at anodic sites defuse into electrolytic solutions from the oxidising reactions occurring at cathodic sites, causing the creation of corrosion byproducts, like rust on iron, and the loss of structural mass. The different reduction reactions in the microstructures of alloys and the imperfections found within refined materials, lik
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Conference papers on the topic "Divalent metal ions release"

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Wyman, Donald P., Richard D. Moll, and D. R. Dunbar. "Factors Influencing the Use of Turbidity for Process Control of a Commonly Used Heavy Metal Precipitant." In CORROSION 1993. NACE International, 1993. https://doi.org/10.5006/c1993-93385.

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ABSTRACT The effects of pH and certain chelants on the precipitation of low concentrations of divalent copper, nickel and cadmium ions with sodium N, N-dimethyldithiocarbamate are described. Conditions under which turbidometry (nephelometry) may be used to monitor the precipitation reactions are also described. Speculation is offered concerning how equilibria and kinetic factors may explain the observed results.
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Kan, A. T., A. J. Gerbino, J. E. Oddo, and M. B. Tomson. "A Mechanistic Interpretation of the Precipitation and Dissolution of Divalent Metal Phosphonate." In CORROSION 1993. NACE International, 1993. https://doi.org/10.5006/c1993-93459.

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Abstract An electrostatic model is developed to model the pH, temperature, and ionic strength dependence of phosphonate ionization and complex formation. Using the approach, two calcium phosphonate precipitates have been studied. The initial calcium phosphonate phase formed is an amorphous material. Using a dialysis process, the amorphous solid gradually transforms into a crystalline solid via removal of phosphonate. The solubility product of the amorphous phase is 10−49.4. The crystalline material is three orders' magnitudes less soluble than the amorphous phase. The pH, temperature, and ioni
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Amjad, Zahid. "Gypsum Scale Inhibitors Performance in the Presence of Impurities." In CORROSION 2021. AMPP, 2021. https://doi.org/10.5006/c2021-16707.

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Abstract In the present work a variety of polymers with different functional groups and molecular weight (MW) were tested as gypsum scale inhibitors. The polymers tested include: poly(acrylic acid) PAA; poly(maleic acid), PMA; poly(aspartic acid), PASP; poly(epoxysuccinic acid), PESA; carboxymethyl inulin (CMI-25); copolymers of maleic acid:sulfonated styrene, PMAS); maleic acid:vinyl pyrrolidone, PMVP. The results indicated that performance of polymers strongly depends on the polymer architecture. Based on the data collected, the polymers may be ranked as follows: PAA &amp;gt; PMA &amp;gt; PA
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Amjad, Zahid, Libardo Perez, and Robert W. Zuhl. "Water Chemistry Impacts on Cooling Water System Iron Oxide Dispersants." In CORROSION 2015. NACE International, 2015. https://doi.org/10.5006/c2015-05996.

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Abstract The effects of water chemistry such as total dissolved solids, polyvalent metal ions, pH, and temperature on particulate iron oxide dispersion by a variety of polymeric additives have been investigated. The deposit control polymers (DCPs) evaluated include synthetic polymers (of varying composition and molecular weight). Results reveal that DCP iron oxide dispersant performance strongly depends on dosage and architecture (e.g., type and amount of monomers, monomer functional group ionic charge, molecular weight). Data show that pH changes cause varying but relatively small changes in
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Honda, T., K. Ohashi, A. Minato, and Y. Furutani. "Suppression of Radiation Buildup on Stainless Steel in a Boiling Water Reactor." In CORROSION 1986. NACE International, 1986. https://doi.org/10.5006/c1986-86261.

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Abstract Deposition of radioactive corrosion products, such as Co-60, causes radiation field buildup in BWR plants. In this study, deposition kinetics of Co-60 and elemental cobalt ions on stainless steel and effects of pre-oxidation on the suppression were evaluated in actual reactor water and laboratory autoclaves. Cobalt ions are incorporated as divalent cobalt oxides such as CoFe2O4 at the oxide/metal interface through corrosion. Therefore, a protective oxide film, which is pre-formed under suitable circumstances such as high temperature water with a certain amount of dissolved oxygen, can
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Kasperski, K. L., and R. J. Mikula. "Water Treatment in Oil Sands: A Novel Approach to Calcium Control." In CORROSION 2003. NACE International, 2003. https://doi.org/10.5006/c2003-03065.

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Abstract The extraction of bitumen from surface-mined oil sands in Alberta, Canada is a water-based process that involves making an ore-water slurry and then recovering the bitumen product as a froth. Water from the tailings is recycled to the plant. Soluble ions in the recycle water, particularly divalent cations at high levels, can hurt the extraction process and contribute to heat-exchanger scaling. A tailings treatment known as the consolidated tailings (CT) process was developed that uses soluble calcium but results in elevated calcium concentrations in the release water. In order to appl
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Li, Wenyan, and Luz M. Calle. "Controlled Release Microcapsules for Smart Coatings." In CORROSION 2007. NACE International, 2007. https://doi.org/10.5006/c2007-07228.

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Abstract Corrosion in service is a serious problem for most military operations. The cost of corrosion includes manpower, materials used to repair corrosion damage, equipment downtime, and reduced capacity due to corrosion damage. A considerable number of corrosion problems can be solved by coatings. However, even the best protective coatings can fail by allowing the slow diffusion of oxygen and moisture to the metal surface. Corrosion accelerates when a coating delaminates. Often, the problems start when microscopic nicks or pits on the surface develop during manufacturing or through wear and
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Paudyal, Samridhdi, and Chunfang Fan. "Development of Inorganic Scale Inhibitors for Ultrahigh-Temperatures Geothermal and HPHT Applications." In CONFERENCE 2024. AMPP, 2024. https://doi.org/10.5006/c2024-20727.

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Abstract With the advancement in green technology-based energy generation to achieve net-zero emissions, geothermal energy has been considered one of the options to reduce the carbon footprint from oil/gas production. In this paper, geothermal energy refers to energy generation that involves a high-pressure, high-temperature (HPHT) environment. Both geothermal energy generation and oil and gas production in such environments—which includes the use of steam-flooded wells and geothermal wells are always challenging as a result of operational issues caused by inorganic scale formation. Changes in
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Yan, Y., A. Neville, D. Dowson, S. Williams, and J. Fisher. "In Situ Electrochemical Study of the Interaction of Tribology and Corrosion in Artificial Hip Prosthesis Simulators." In CORROSION 2009. NACE International, 2009. https://doi.org/10.5006/c2009-09465.

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Abstract The second generation Metal-on-Metal (MoM) hip replacements have been considered as an alternative to commonly used Polyethylene-on-Metal (PoM) joint prostheses due to polyethylene wear debris induced osteolysis. However, the role of corrosion and the biofilm formed under tribological contact are still not fully understood. Enhanced metal ion concentrations have been reported widely from hair, blood and urine samples of patients who received metal hip replacements and in isolated cases when abnormally high levels have caused adverse local tissue reactions. An understanding of the orig
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Yan, Yu, Zhongwei Wang, Gang Han, and Lijie Qiao. "Study of Nanocrystallines on Artificial Hip Implants Surfaces Induced by Biotribocorrosion Processes." In CORROSION 2015. NACE International, 2015. https://doi.org/10.5006/c2015-05523.

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Abstract Metal-on-metal (MoM) hip joints are recommended in modern total hip replacement surgery for their excellent wear resistance. But they still suffer the result from biotribocorrosion processes which lead to the release of metal ions and debris. The microstructure of the joint surface is a key factor for the safety of MoM joints. In this study, a layered structure that formed on the MoM joint surface under simulated conditions was found. The layered structure was investigated by SEM, TEM and EDX. The result shows that the layered structure contain a carbon-rich film, a organometallic fil
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