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Relevant bibliographies by topics / Endothermic reaction

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Academic literature on the topic 'Endothermic reaction'

Author: Grafiati

Published: 14 March 2023

Last updated: 31 July 2025

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Journal articles on the topic "Endothermic reaction"

1

CONROY, DEVIN T., and STEFAN G. LLEWELLYN SMITH. "Endothermic and exothermic chemically reacting plumes." Journal of Fluid Mechanics 612 (October 10, 2008): 291–310. http://dx.doi.org/10.1017/s0022112008002917.

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We develop a model for a turbulent plume in an unbounded ambient that takes into account a general exothermic or endothermic chemical reaction. These reactions can have an important effect on the plume dynamics since the entrainment rate, which scales with the vertical velocity, will be a function of the heat release or absorption. Specifically, we examine a second-order non-reversible reaction, where one species is present in the plume from a pure source and the other is in the environment. For uniform ambient density and species fields the reaction has an important effect on the deviation fr

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Zhou, Guang Fen, Jie Ren, and Shao Wen Zhang. "Initial Surface Reactions Mechanisms of Atomic Layer Deposition TiO₂Using Ti(OCH₃)₄ and H₂O as Precursors." Advanced Materials Research 785-786 (September 2013): 832–36. http://dx.doi.org/10.4028/www.scientific.net/amr.785-786.832.

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The initial surface reaction mechanisms of atomic layer depositionTiO2using Ti (OCH3)4and H2O as the precursors are investigated by density functional theory. The ALD process is divided into two half-reactions, i.e., Ti (OCH3)4and H2O half-reactions. The adsorption of Ti (OCH3)4on OH/Si (100)2×1 surface is exothermic. However, the overall reaction of Ti (OCH3)4is endothermic. In addition, H2O half-reactions are endothermic and thermodynamically unfavorable.

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Wu, Jun-Lin, Zhi-Hui Li, Ao-Ping Peng, Xing-Cai Pi, and Xin-Yu Jiang. "Utility computable modeling of a Boltzmann model equation for bimolecular chemical reactions and numerical application." Physics of Fluids 34, no. 4 (2022): 046111. http://dx.doi.org/10.1063/5.0088440.

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A Boltzmann model equation (kinetic model) involving the chemical reaction of a multicomponent gaseous mixture is derived based on Groppi's work [“A Bhatnagar–Gross–Krook-type approach for chemically reacting gas mixtures,” Phys. Fluids 16, 4273 (2004)], in which the relaxation parameters of elastic collision frequency for rigid elastic spheres are obtained based on the collision term, and the pivotal collision frequency of the chemical reaction is deduced from the chemical reaction rate that is determined by the direct simulation Monte Carlo (DSMC) method. This kinetic model is shown to be co

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Desh, Deepak, and Jeenu R. "Endothermic fuels for supersonic ramjet." Journal of Indian Chemical Society Vol. 80, May 2003 (2003): 535–43. https://doi.org/10.5281/zenodo.5839528.

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Fluid Mechanics & Internal Ballistics Division, Propulsion Group, Vikram Sarabhai Space Centre, Trivandrum-695 022, India <em>E-mail</em> : ddeepak@vsnl.net     Fax: 91-471-562060 <em>Manuscript received 17 December 2002</em> Greater ease of use and higher density make hydrocarbon fuels an attractive option for hypersonic space transport vehicle. In addition to use of fuel for propulsive purpose, it is used for regenerative cooling of system structures. In order to achieve maximum heat sink, endothermic reactions of the hydrocarbon fuels must be employed to augme-nt fuel ent

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Sobel, D. R., and L. J. Spadaccini. "Hydrocarbon Fuel Cooling Technologies for Advanced Propulsion." Journal of Engineering for Gas Turbines and Power 119, no. 2 (1997): 344–51. http://dx.doi.org/10.1115/1.2815581.

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Storable hydrocarbon fuels that undergo endothermic reaction provide an attractive heat sink for future high-speed aircraft. An investigation was conducted to explore the endothermic potential of practical fuels, with inexpensive and readily available catalysts, under operating conditions simulative of high-speed flight applications. High heat sink capacities and desirable reaction products have been demonstrated for n-heptane and Norpar 12 fuels using zeolite catalysts in coated-tube reactor configurations. The effects of fuel composition and operating condition on extent of fuel conversion,

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Subbarao, Duvvuri, Reem Hassan Abd Elghafoor Hassan, and Marappagounder Ramasamy. "Heat Transfer with Chemical Reaction in Wall Heated Packed Bed Reactor." Applied Mechanics and Materials 625 (September 2014): 722–25. http://dx.doi.org/10.4028/www.scientific.net/amm.625.722.

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Information on wall heat transfer to packed bed reactors operating with exothermic or endothermic reactions is scarce. Overall wall heat transfer coefficients in a packed bed reactor in presence of an endothermic reaction are measured and observed to be smaller than the expected in the absence of reaction. This observation is in contrast with the reported observations with exothermic reactions in packed beds. A model equation based on energy balance is presented to explain the observations.

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Selim, Ezzat T. M., M. A. Rabbih та M. A. Fahmey. "Kinetic Energy Release and Position of the Transition State for С6Н7+ Ions Produced from Isomeric C7H8O Precursors". Zeitschrift für Naturforschung A 46, № 12 (1991): 1021–25. http://dx.doi.org/10.1515/zna-1991-1204.

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Abstract The energetic requirement and mechanisms for CHO' loss from the molecular ions of isomeric C7H8O precursors have been reported. The heat of formation of [C6H7]+ (protonated benzene) was determined and ε* evaluated. Measurement of the kinetic energy release TB gives the energy-partitioning quotients q= TB/εr* which range from 0.38 to 0.99. The energy available and TB are small for the strongly endothermic reaction of benzyl alcohol but increase sharply in the case of the weakly endothermic reaction of anisole. All reactions have "late" transition states, the position X0*of the transiti

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Stone, John Alfred, Xiaoping Li, and Patricia Anne Turner. "A high pressure mass spectrometric study of proton transfer between tri-, tetra-, penta-, and hexamethylbenzene." Canadian Journal of Chemistry 64, no. 10 (1986): 2021–30. http://dx.doi.org/10.1139/v86-334.

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The proton affinities (PA) of some methylaromatic compounds and the rates of proton transfer reactions have been measured using high pressure mass spectrometry. The equilibria studied were of the form [Formula: see text]. Van't Hoff plots yielded the following PA values (kcal mol−1) relative to PA(ethylacetate) = 200.7 as standard: mesitylene 201.0, 1,2,3,5-tetramethylbenzene 203.2, pentamethylbenzene 204.4, hexamethylbenzene 206.6. ΔS0 values for the proton transfer equilibria are not fully determined by changes in rotational symmetry numbers and it is suggested that vibrational and torsional

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Shen, Fan, Shao Long Huang, Zheng Sun, and Qing Jun Ding. "Research on Hardening Mechanism of Cement-Emulsified Asphalt-Epoxy Resin." Advanced Materials Research 430-432 (January 2012): 434–37. http://dx.doi.org/10.4028/www.scientific.net/amr.430-432.434.

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This article researched the cementation and hardening mechanisms of cement asphalt emulsion and waterborne epoxy mortar by using the XRD, and heat of hydration testing methods. The results of this study show that the mixture of cement with epoxy and cement- asphalt-epoxy are endothermic reaction. There are occurring endothermic reactions between cement with epoxy. The waterborne epoxy resin and basic structure unit of ettringite [Ca3Al(OH)6•12H2O] were reacted and formed Ca-complex at earlier period of hydration.

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Watt, S. D., H. S. Sidhu, A. C. McIntosh, and J. Brindley. "Chaotic flow in competitive exothermic–endothermic reaction systems." Applied Mathematics Letters 115 (May 2021): 106960. http://dx.doi.org/10.1016/j.aml.2020.106960.

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Dissertations / Theses on the topic "Endothermic reaction"

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Zanfir, Monica. "Catalytic plate reactors for endothermic-exothermic reaction coupling." Thesis, University College London (University of London), 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270199.

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MONCADA, QUINTERO CARMEN WILLIANA. "Ceramic open cell foams as catalytic support for endothermic and exothermic reactions: Focus on lean methane combustion." Doctoral thesis, Politecnico di Torino, 2021. http://hdl.handle.net/11583/2929756.

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Lazarovici, Alice Ioana. "Combustion initiation influenced by endothermic reactions and by convection." Thesis, University of Leeds, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.400176.

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BabovicÌ, Mileta. "Enhanced heat transfer to endothermic reactions by catalytic combustion in small channels." Thesis, University of Newcastle Upon Tyne, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.289262.

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Smith, Bradley Joseph. "Steam-Assisted Catalysis of n-Dodecane as a Jet Fuel Analogue in a Flow Reactor System for Hypersonic Thermal Management." University of Dayton / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1577978953025703.

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Giroldo, Tatiana. "Estrutura e energética de íons a partir de processos de dissociação induzidos por radiação infravermelha." Universidade de São Paulo, 2002. http://www.teses.usp.br/teses/disponiveis/46/46132/tde-14082018-112257/.

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Processos de fragmentação são muito utilizados para identificar estruturas em espectrometria de massas. O estudo da dissociação de íons em fase gasosa induzida por radiação infravermelha adiciona dados energéticos aos processos de fragmentação desses íons. O mecanismo de dissociação induzida por radiação infravermelha envolve a absorção seqüencial de fótons, aumentando progressivamente a energia interna do íon até que o limite de dissociação seja atingido. No presente trabalho, a radiação de corpo negro emitida por um fio de tungstênio aquecido é utilizada para promover a dissociação de íons e

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Sidhu, Tejas Puneet Kaur. "Modeling the recuperative coupling of exothermic and endothermic reactions in compact ethanol reformers." Thesis, 2017. http://localhost:8080/iit/handle/2074/7475.

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Liu, Chang-Che, and 劉昌哲. "Modeling for a Catalytic Plate Reactor Coupling Endothermic Methanol Steam Reforming and Hydrogen Combustion." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/19247797344395818304.

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碩士<br>大同大學<br>化學工程學系(所)<br>99<br>In this work, tubular and plate reactors for carrying out methanol steam reforming reactions are simulated using Fluent software. The simulation results using Fluent software are confirmed by the performance of an isothermal plug flow tubular reactor in which the methanol steam reforming reactions are performed. Among the eight different reactor designs, the catalytic plate reactor packed with small catalyst particles coupling endothermic methanol steam reforming and hydrogen combustion system give the best performance. The conversion of methanol is 0.63 for th

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Books on the topic "Endothermic reaction"

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J, Spadaccini Louis, and United States. National Aeronautics and Space Administration., eds. Applications of endothermic reaction technology to the high speed civil transport. National Aeronautics and Space Administration, 1998.

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2

Sherwood, Dennis, and Paul Dalby. Enthalpy and thermochemistry. Oxford University Press, 2018. http://dx.doi.org/10.1093/oso/9780198782957.003.0006.

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Definition and mathematics of enthalpy. Definition of heat capacity at constant pressure as CP = (∂H/∂T)V. Endothermic and exothermic reactions. Role of the change in enthalpy as regards the direction and spontaneity of a change in state. Enthalpy changes and phase changes. Measuring enthalpy changes by calorimetry. Hess’s law of constant heat formation. Chemical standards and standard states. Standard enthalpies of formation, ionic enthalpies and bond energies. How the change in enthalpy varies with temperature. Kirchhoff’s equations. Applications of thermochemistry to a variety of worked exa

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Book chapters on the topic "Endothermic reaction"

1

Gooch, Jan W. "Endothermic Reaction." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_4407.

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Dey, Debasish, and Barbie Chutia. "Modelling and Analysis of Dusty Fluid Flow Past a Vertical Surface with Exothermic and Endothermic Kind of Chemical Reactions." In Lecture Notes in Mechanical Engineering. Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-16-3497-0_4.

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"endothermic reaction." In Dictionary Geotechnical Engineering/Wörterbuch GeoTechnik. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-41714-6_51115.

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"Endothermic reaction." In Encyclopedic Dictionary of Polymers. Springer New York, 2007. http://dx.doi.org/10.1007/978-0-387-30160-0_4347.

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Metcalfe, Ian S. "The energy balance and temperature effects." In Chemical Reaction Engineering. Oxford University Press, 1997. http://dx.doi.org/10.1093/hesc/9780198565383.003.0009.

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This chapter demonstrates how reactors need not be isothermal. It looks at how reaction rate depends upon temperature for different classes of reaction, including irreversible reactions, reversible endothermic reactions, and reversible exothermic reactions. The chapter then formulates the energy balance for given reactors and uses this to investigate the variation of temperature and therefore reaction rate with time or position in the reactor. This, in turn, can be used to calculate reactor volumes and residence times for a given duty. The chapter also considers steady-state multiplicity in co

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Keeler, James, and Peter Wothers. "What makes a reaction go?" In Why chemical reactions happen. Oxford University Press, 2003. http://dx.doi.org/10.1093/hesc/9780199249732.003.0002.

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This chapter looks into the process of a reaction. It explains the equations used to derive changes to chemical reactions. The chapter explores energy changes by referencing how temperature plays a big role in line with endothermic, exothermic, entropy, and the Second Law of Thermodynamics. It discusses the chemical process of generating ice. Energy change is due to the making and breaking of chemical bonds alongside their links to a reaction. In addition, the chapter uses Gibbs energy to compute the entropy change of systems in terms of quantity. It highlights the significance of achieving eq

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Oriakhi, Christopher O. "Thermochemistry." In Chemistry in Quantitative Language. Oxford University Press, 2021. http://dx.doi.org/10.1093/oso/9780198867784.003.0020.

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Thermochemistry explores the basic principles of energy changes in chemical reactions. Calorimetry is described as a tool to measure the quantity of heat involved in a chemical or physical change. Quantitative overviews of enthalpy and the stoichiometry of thermochemical equations are provided, including the concepts of endothermic and exothermic reactions. Standard conditions are defined to allow comparison of enthalpies of reactions and determine how the enthalpy change for any reaction can be obtained. Hess"s Law, which allows the enthalpy change of any reaction to be calculated, is discuss

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Elliott, Mark C. "Calculating Enthalpy of Reaction from Bond Dissociation Energy." In How to Succeed in Organic Chemistry. Oxford University Press, 2020. http://dx.doi.org/10.1093/hesc/9780198851295.003.0030.

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The Purpose of The Exercise In my experience, it is pretty rare for an organic chemist to carry out one of these calculations. However, they will look at a reaction and intuitively know whether it is likely to be endothermic or exothermic... They can...

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Hanlon, Robert T. "The 2nd Law, entropy, and the chemists." In Block by Block: The Historical and Theoretical Foundations of Thermodynamics. Oxford University Press, 2020. http://dx.doi.org/10.1093/oso/9780198851547.003.0039.

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The Thomsen–Berthelot principle together with the thermal theory of affinity theorized that the change in enthalpy of a reaction (dH<sub>rxn</sub>) is the sole determiner of reaction spontaneity. Exothermic reactions are spontaneous. This theory worked well except for the fact that some endothermic reations are also spontaneous. Gibbs’ work incorporating entropy showed that the true determiner of reaction spontaneity, as well demonstrated in the electrochemical cell, is the change in Gibbs free energy (dG<sub>rxn</sub>) as quantified by dH<sub>rxn</sub> − TdS<sub>rxn</sub>. Included is a discu

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Oriakhi, Christopher O. "Chemical Thermodynamics." In Chemistry in Quantitative Language. Oxford University Press, 2021. http://dx.doi.org/10.1093/oso/9780198867784.003.0021.

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Chemical Thermodynamics discusses the fundamental laws of thermodynamics along with their relationships to heat, work, enthalpy, entropy, and temperature. Predicting the direction of a spontaneous change and calculating the change in entropy of a reaction are core concepts. The relationship between entropy, free energy and work is covered. The Gibbs free energy is used quantitatively to predict if reactions or processes are going to be exothermic and spontaneous or endothermic under the stated conditions. Also explored are the enthalpy and entropy changes during a phase change. Finally the Gib

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Conference papers on the topic "Endothermic reaction"

1

Sempuga, Baraka C., and Selusiwe Ncube. "Biogas Valorization from a Process Synthesis Perspective: Heat and Work Integration to Maximize CO2 Conversion." In Foundations of Computer-Aided Process Design. PSE Press, 2024. http://dx.doi.org/10.69997/sct.129660.

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Biogas is often considered as a source of renewable energy, for heat and power production. However, biogas has greater promise as a source of concentrated CO2 in addition to methane, making it a rich supply of carbon and hydrogen for the generation of fuel and chemicals. In this work, we use the concept of attainable region in the enthalpy-Gibbs free energy space to identify opportunities for effective biogas valorization that maximizes the conversion of CO2. The AR concept allows us to study a chemical process without knowing the exact reaction mechanism that the species in the process use. D

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Sobel, David R., and Louis J. Spadaccini. "Hydrocarbon Fuel Cooling Technologies for Advanced Propulsion." In ASME 1995 International Gas Turbine and Aeroengine Congress and Exposition. American Society of Mechanical Engineers, 1995. http://dx.doi.org/10.1115/95-gt-226.

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Storable hydrocarbon fuels that undergo endothermic reaction provide an attractive heat sink for future high-speed aircraft. An investigation was conducted to explore the endothermic potential of practical fuels, with inexpensive and readily available catalysts, under operating conditions simulative of high-speed flight applications. High heat sink capacities and desirable reaction products have been demonstrated for n-heptane and Norpar 12 fuels using zeolite catalysts in coated-tube reactor configurations. The effects of fuel composition and operating condition on extent of fuel conversion,

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"Analysis of a competitive exothermic-endothermic reaction scheme." In 19th International Congress on Modelling and Simulation. Modelling and Simulation Society of Australia and New Zealand (MSSANZ), Inc., 2011. http://dx.doi.org/10.36334/modsim.2011.a3.sharples.

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Yang Chen, Zhijiang Shao, Jixin Qian, Kexin Wang, Zhiliang Zhan, and Zuhua Xu. "Dynamic optimization of multivariable endothermic reaction in cascade CSTR." In 2010 8th World Congress on Intelligent Control and Automation (WCICA 2010). IEEE, 2010. http://dx.doi.org/10.1109/wcica.2010.5553780.

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"Combustion waves from a sequential exothermic and endothermic reaction." In 19th International Congress on Modelling and Simulation. Modelling and Simulation Society of Australia and New Zealand (MSSANZ), Inc., 2011. http://dx.doi.org/10.36334/modsim.2011.aa.qian.

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Rubini, Dylan, Nikolas Karefyllidis, Liping Xu, Budimir Rosic, and Elina Nauha. "Decarbonisation of high-temperature endothermic chemical reaction processes using a novel turbomachine: robustness of the concept to feed variability." In GPPS Hong Kong24. GPPS, 2023. http://dx.doi.org/10.33737/gpps23-tc-245.

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This paper presents a revolutionary turbomachinery concept, referred to as the turbo-reactor, which has the potential to replace gas-fired radiant furnaces and decarbonise a wide range of hard-to-abate, high-temperature endothermic chemical reaction processes. While previous studies by the authors have confirmed the feasibility of using a turbo-reactor for steam cracking reactions, the numerical investigation presented in this work demonstrates its potential for eliminating emissions from a variety of energy-intensive chemical processes, including those used in the hydrogen industry. This step

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Li, Jing, Shuanshi Fan, Zemin Yao, Jing Li, and Xinli Wei. "Fast Transient and Intensified Heat Dissipation Applicable to High Heat Flux Density." In ASME 2011 Power Conference collocated with JSME ICOPE 2011. ASMEDC, 2011. http://dx.doi.org/10.1115/power2011-55408.

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In this paper, in order to solve the problem of intensified heat dissipation in high power electronic devices, a fast transient and intensified heat dissipation technology was put forward by comparing many heat transfer modes based on the analytical study on the existing technologies about heat dissipation at high heat flux density and about fast heat transport. This technology combined spray cooling technology with fast endothermic chemical reaction processes; we summarized the characteristics of media applicable to an environment with transient high heat flux density by comparing various par

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Vishnevetsky, Irina, Michael Epstein, and Rahamim Rubin. "Simulation of Thermal and Chemical Processes in Annular Layer of ZnO-C Mixtures." In ASME 2004 International Solar Energy Conference. ASMEDC, 2004. http://dx.doi.org/10.1115/isec2004-65013.

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A special setup, electrically heated, is described, enabling the simulation of the process conditions encountered in a solar chemical reactor. The setup allows studying of the thermal and chemical processes in different solid (powder or granules) reactant layers from the beginning of the heating until the reaction is completed, in heating condition typical for indirectly, externally heated solar reactors. Tests were executed with ZnO carboreduction process, using different powder mixtures of ZnO-C to demonstrate the layer-wise character of the reaction. The results show that the reactivity and

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Fukiba, Katsuyoshi, Nobuyuki Tsuboi, and Ryojiro Minato. "Numerical Study on the Heat Transfer of the Flow with Endothermic Chemical Reaction." In 45th AIAA/ASME/SAE/ASEE Joint Propulsion Conference & Exhibit. American Institute of Aeronautics and Astronautics, 2009. http://dx.doi.org/10.2514/6.2009-5461.

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Yu, Sang-Phil, Seung-Jae Lee, and Kwang-Sup Song. "Micro Heat Exchanger for Gas Phase Reaction." In ASME 3rd International Conference on Microchannels and Minichannels. ASMEDC, 2005. http://dx.doi.org/10.1115/icmm2005-75213.

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Each microstructured stainless steel foil was brazed in vacuum for stacking. Inner surface of micro channels was coated with Al2O3 layer to support Pt catalyst by sol-gel method. The stack was designed like a cross-flow type heat exchanger to perform the combination of exothermic and endothermic reactions simultaneously. It is expected to apply to the micro reformer which produces hydrogen for micro PEMFC (Proton Exchange Membrane Fuel Cell). As the first step in our study, we measured experimentally the heat transfer rate and the spatial temperature distribution of the stack. An then, the rea

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Reports on the topic "Endothermic reaction"

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Prengle, H. W. Jr, W. E. Wentworth, K. C. Polonczyk, M. Saghafi, J. A. Wilking, and K. S. Kramer. Endothermic photo-catalytic reactions. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/5284884.

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Prengle, H. W. Jr, W. E. Wentworth, K. C. Polonczyk, M. Saghafi, J. A. Wilking, and K. S. Kramer. Endothermic photo-catalytic reactions. Final report. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/10147020.

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Brown, L. F. Simple relationships for estimating intraparticle transport effects for catalytically promoted endothermic reactions. Office of Scientific and Technical Information (OSTI), 1998. http://dx.doi.org/10.2172/307875.

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