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Dissertations / Theses on the topic 'Fluorinated Hydrocarbons'

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1

Spink, Robert C. H. "Functionalisation of hydrocarbons using fluorinated alkenes." Thesis, Durham University, 1996. http://etheses.dur.ac.uk/5336/.

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Functionalisation of hydrocarbons is a field of continuing activity and a variety of approaches to this field, have been taken. This thesis is concerned with the functionalisation of the carbon-hydrogen bond, in hydrocarbons, using fluorinated alkenes via a free radical chain mechanism. Addition of the nucleophilic alkyl radical to the electrophilic fluorinated alkene, specifically hexafluoropropene, occurs readily to give incorporation of the polyfluoroalkyl group into a number of hydrocarbons, including aliphatic, mono-, bi- and polycyclic systems. Further chemistry of these polyfluoroalkyla
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2

Goto, Masashi. "Kinetics of atmospheric chemical reactions of fluorinated hydrocarbons." 京都大学 (Kyoto University), 2005. http://hdl.handle.net/2433/145179.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(地球環境学)<br>甲第11759号<br>地環博第1号<br>新制||地環||1(附属図書館)<br>23402<br>UT51-2005-D508<br>京都大学大学院地球環境学舎地球環境学専攻<br>(主査)教授 川崎 昌博, 教授 田村 類, 助教授 川崎 三津夫<br>学位規則第4条第1項該当
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3

Gunnare, Sara. "Fluorinated hydrocarbons used as refrigerants : toxicokinetics and effects in humans /." Stockholm, 2007. http://diss.kib.ki.se/2007/978-91-7357-231-6/.

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4

LI, ZHE. "Photocyclodehydrofluorination (PCDHF) –A synthetic method for fluorinated polynuclear aromatic hydrocarbons." Kent State University / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=kent1448814689.

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5

Sherpa, Sonam Dorje. "Preparation and characterization of plasma-fluorinated epitaxial graphene." Diss., Georgia Institute of Technology, 2013. http://hdl.handle.net/1853/47575.

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The discovery of unique properties of graphene has led to the development of graphene for a variety of applications like integrated circuits, organic electronic devices, supercapacitors, sensors, and composite materials. Fluorination of graphene enables control of its physical, chemical, and electronic properties. Our initial studies demonstrated the viability of sulfur hexafluoride plasmas to fluorinate epitaxial graphene as a safer alternative to the commonly reported techniques of fluorination that include exposures to fluorine and xenon difluoride gas. Formation of carbon-fluorine bonds af
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6

Ho, Han Kiat. "An investigation of cellular responses to tetrafluoroethylcysteine-induced mitochondrial dysfunction /." Thesis, Connect to this title online; UW restricted, 2005. http://hdl.handle.net/1773/8175.

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7

Tang, Chau N. "Copolymerization and Characterization of Vinylaromatics with Fluorinated Styrenes." University of Akron / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=akron1207773730.

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8

Adams, Michael Lynn. "The involvement of mitochondria in the cell death process : communication from mitochondria to the nucleus /." Thesis, Connect to this title online; UW restricted, 2003. http://hdl.handle.net/1773/8169.

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9

Morrell, Claire. "FTIR emission studies of chemical processes." Thesis, University of Oxford, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326026.

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10

Lu, Yangtian. "Synthesis and Properties Study of a Doubly-Crosslinked Material Based on a Hyperbranched Polyacrylate with Hydrocarbon-Fluorocarbon Ester Substituents." University of Akron / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=akron1369046926.

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11

Sankir, Mehmet. "Proton Exchange Membrane Fuel Cell Systems Based on Aromatic Hydrocarbon and Partially Fluorinated Disulfonated Poly(Arylene Ether) Copolymers." Diss., Virginia Tech, 2005. http://hdl.handle.net/10919/25945.

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This dissertation describes the past and recent progress in proton exchange membranes (PEM) for fuel cells. In particular the synthesis and characterization of materials for advanced alternative PEM were studied with an emphasis on structure-property and structure-property-performance relationships. The focus has included firstly a one-step synthesis and characterization of 3,3'-disulfonated 4,4'-dichlorodiphenyl sulfone comonomer. The procedure developed is adaptable for industrial-scale commercialization efforts. Secondly, the synthesis of aromatic nitrile containing poly (arylene ether
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12

Harrison, Kareem. "Inhibition of Hydrocarbon Autoxidation by Nitroxide Catalyzed Cross Dismutation of Alkylperoxyl and Hydroperoxyl Radicals & a Novel Approach Toward Fluorinated Polyunsaturated Lipids." Thesis, Université d'Ottawa / University of Ottawa, 2020. http://hdl.handle.net/10393/40026.

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Nitroxides are intermediates in the accepted reaction mechanisms of the antioxidant activity of diarylamines and hindered alkyl amines. The parent amines are used as additives to preserve synthetic and natural hydrocarbon-based materials from oxidative degradation. New methodology which enables monitoring of hydrocarbon autoxidations at low rates of radical generation has revealed that diarylnitroxides and hindered nitroxides are far better inhibitors of unsaturated hydrocarbon autoxidation than their precursor amines, implying intervention of a previously overlooked mechanism. Experimental a
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13

May, Nathanael Henderson. "A Morphological Study of PFCB-Ionomer/ PVdF Copolymer Blend Membranes For Fuel Cell Application." Thesis, Virginia Tech, 2011. http://hdl.handle.net/10919/76853.

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A new material for use as a proton exchange membrane in fuel cells has been developed: a blend of a perfluorocyclobutane-based block ionomer (S-PFCB) and Poly (vinylidene-co-hexafluoropropylene) (Kynar Flex, KF). This thesis details the work done thus far to characterize the morphology of this material, using small angle x-ray scattering, differential scanning calorimetry, atomic force micrscopy, and some other techniques to a lesser extent. Small angle x-ray scattering (SAXS) of pure S-PFCB showed a strong block copolymer- associated phase separation, on the order of 25 nm. Differential sca
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14

Sölter, Lars. "Experimentelle und theoretische Untersuchungen der Dissoziationen von Tetrafluorethen, Hexafluorpropen und Hexafluorcyclopropan." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://hdl.handle.net/11858/00-1735-0000-0022-5F20-0.

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15

Chiyen, Kaleng Jim. "Modification and commissioning of a static high pressure apparatus and phase equilibria measurements for fluorinated hydrocarbons." Thesis, 2010. http://hdl.handle.net/10413/3695.

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Modifications were undertaken to a static high pressure vapour-liquid equilibrium (VLE) apparatus described by Naidoo [2004]. The alterations were made to improve the sample analysis technique. These modifications included the incorporation of the ROLSITM sampling device into the equilibrium cell, a re-design of the air bath which improved the temperature profile and further alterations described in the text. The equipment has an operating temperature range of 278.15 K to 473.15 K and pressure range of absolute vacuum to 150 bars. The apparatus consisted of an agitated cell in an air-bath. The
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16

Yang, Chung-Ling, and 楊宗霖. "Controlled oxidation of aliphatic C-H bonds in metallo-monooxygenases: Mechanistic insights derived from studies on deuterated and fluorinated hydrocarbons by Cytochrome P450 BM3." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/t2uwv5.

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博士<br>國立臺灣科技大學<br>應用科技研究所<br>103<br>The control oxidation of aliphatic C-H bonds in regio- and/or stereo-selective manner by metalloenzymes is of great interest to scientists. Cytochrome P450 BM3 from Bacillus megaterium oxidizes C12-C20 fatty acids at the ω-1, ω-2, or ω-3 position of the C?{H bond, respectively. We employ the molecular manipulation techniques to overexpress the recombinant BM3 strain and carry out its site-directed mutagenesis study for generation of a variety of strains towards variable selective oxidation with different substrates. In my study, strain 3mt, A74G F87V L188Q i
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17

Rimal, SANTOSH. "Ageing of HDPE Geomembranes Used to Contain Landfill Leachate or Hydrocarbon Spills." Thesis, 2009. http://hdl.handle.net/1974/1658.

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The ageing of high density polyethylene geomembrane (GM) liners used to minimize advection and diffusion of contaminants in municipal solid waste landfill leachate and in hydrocarbon spills to the environment is examined. The evaluation of the ageing of GMs used in landfills involved four components. First, a laboratory-accelerated ageing investigation of a GM exposed to air, water and leachate at elevated temperatures. Service life of a GM (Stage I: Antioxidant depletion, Stage II: Induction, and Stage III: Polymer degradation) is examined. The results demonstrate the critical role of antiox
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