Academic literature on the topic 'Guest inclusion complexes'

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Journal articles on the topic "Guest inclusion complexes"

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Malinska, Maura. "Insights into molecular recognition from the crystal structures of p-tert-butylcalix[6]arene complexed with different solvents." IUCrJ 9, no. 1 (2021): 55–64. http://dx.doi.org/10.1107/s2052252521010678.

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Calixarenes are host molecules that can form complexes with one or more guest molecules, and molecular recognition in calixarenes can be affected by many factors. With a view to establishing molecular recognition rules, the host p-tert-butylcalix[6]arene (TBC6) was crystallized with different guest molecules (cyclohexane, anisole, heptane, toluene, benzene, methyl acetate, ethyl acetate, dichloromethane, tetrahydrofuran and pyridine) and the obtained structures were characterized by X-ray diffraction. With most solvents, 1:1 and/or 1:3 host–guest complexes were formed, although other stoichiom
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Giastas, Petros, Konstantina Yannakopoulou та Irene M. Mavridis. "Molecular structures of the inclusion complexes β-cyclodextrin–1,2-bis(4-aminophenyl)ethane and β-cyclodextrin–4,4′-diaminobiphenyl; packing of dimeric β-cyclodextrin inclusion complexes". Acta Crystallographica Section B Structural Science 59, № 2 (2003): 287–99. http://dx.doi.org/10.1107/s010876810300257x.

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The present investigation is part of an ongoing study on the influence of the long end-functonalized guest molecules DBA and BNZ in the crystal packing of β-cyclodextrin (βCD) dimeric complexes. The title compounds are 2:2 host:guest complexes showing limited host–guest hydrogen bonding at the primary faces of the βCD dimers. Within the βCD cavity the guests exhibit mutual π...π interactions and between βCD dimers perpendicular NH...π interactions. The DBA guest molecule exhibits one extended and two bent conformations in the complex. The BNZ guest molecule is not planar inside βCD, in contras
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Kadu, Rahul, Vineeta Pillai, Amrit V. та Vinay K. Singh. "Synthesis and spectral characterization of bimetallic metallomacrocyclic structures [MII2-μ2-bis-{(κ2S,S-S2CN(R)C6H4)2O}] (M = Ni/Zn/Cd): density functional theory and host–guest reactivity studies". RSC Advances 5, № 129 (2015): 106688–99. http://dx.doi.org/10.1039/c5ra22175g.

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Gómez-González, Borja, Luis García-Río, Nuno Basílio, Juan C. Mejuto, and Jesus Simal-Gandara. "Molecular Recognition by Pillar[5]arenes: Evidence for Simultaneous Electrostatic and Hydrophobic Interactions." Pharmaceutics 14, no. 1 (2021): 60. http://dx.doi.org/10.3390/pharmaceutics14010060.

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The formation of inclusion complexes between alkylsulfonate guests and a cationic pillar[5]arene receptor in water was investigated by NMR and ITC techniques. The results show the formation of host-guest complexes stabilized by electrostatic interactions and hydrophobic effects with binding constants of up to 107 M−1 for the guest with higher hydrophobic character. Structurally, the alkyl chain of the guest is included in the hydrophobic aromatic cavity of the macrocycle while the sulfonate groups are held in the multicationic portal by ionic interactions.
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Toda, Fumio. "Crystalline inclusion complexes as media of molecular recognitions and selective reactions." Pure and Applied Chemistry 73, no. 7 (2001): 1137–45. http://dx.doi.org/10.1351/pac200173071137.

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Hexaol host compounds which include guest molecules maximum in 1:6 ratio were prepared. Aromatic hexaol host, hexahydroxytriphenylene, was found to form chiral inclusion crystal by complexation with achiral guest molecules. Some interesting and important optical resolutions of rac-guests by inclusion complexation with a chiral host were described. When chemical reaction and the inclusion complexation procedures in a water suspension medium are combined, new economical and ecological method of the preparation of optically active compound can be established. When photochemical reactions are carr
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Mejuto, Juan C., and Jesus Simal-Gandara. "Host–Guest Complexes." International Journal of Molecular Sciences 23, no. 24 (2022): 15730. http://dx.doi.org/10.3390/ijms232415730.

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Suwinska, Kinga. "Intermolecular interactions in inclusion complexes." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C673. http://dx.doi.org/10.1107/s2053273314093267.

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The whole range of interactions can be found between host and guest in supramolecular assemblies from ion-ion interactions, ion-dipole interactions, dipol-dipol interactions through hydrogen bonding, cation-π interactions, π-π stacking to van der Waals forces. Additionally, the same interactions exist between the supramolecular complex and its surrounding, i.e. solvent molecules, neighboring complexes, gases, etc. Recently the interest of scientists in the field of supramolecular chemistry is focused on design and synthesis of water-soluble synthetic macrocyclic ligands which are good receptor
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Kadokawa, Jun-ichi. "Synthesis of Amylosic Supramolecular Materials by Glucan Phosphorylase-Catalyzed Enzymatic Polymerization According to the Vine-Twining Approach." Synlett 31, no. 07 (2020): 648–56. http://dx.doi.org/10.1055/s-0039-1690804.

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This article overviews the synthesis of amylosic supramolecular materials through inclusion complexation in glucan phosphorylase (GP)-catalyzed enzymatic polymerization. Amylose is a polysaccharide that is known to form inclusion complexes with a number of hydrophobic small guest molecules. A pure amylose can be synthesized by the enzymatic polymerization of α-d-glucose 1-phosphate monomer with a maltooligosaccharide primer catalyzed by GP. The author has reported that the propagating amylosic chain in the enzymatic polymerization twines around hydrophobic polymers present in aqueous reaction
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Dutta, Ashutosh, Niloy Roy, Koyeli Das, Debadrita Roy, Raja Ghosh, and Mahendra Nath Roy. "Synthesis and Characterization of Host Guest Inclusion Complexes of Cyclodextrin Molecules with Theophylline by Diverse Methodologies." Emerging Science Journal 4, no. 1 (2020): 52–72. http://dx.doi.org/10.28991/esj-2020-01210.

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Steady host–guest inclusion complexes have been produced with medicinally important guest molecule theophylline within aqueous α-Cyclodextrin and HP-β-Cyclodextrin. α-and HP-β-Cyclodextrins have been established with favorable structural features for inclusion with Theophylline which include diversified applications in modern science such as controlled delivery in the field of pharmaceuticals, food processing, pesticides, foodstuffs etc. Theophylline is one of the most widely accepted drugs for the treatment of asthma and chronic obstructive pulmonary disease (COPD) worldwide, even if it has b
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Hettiarachchi, D. Saroja N., and Donal H. Macartney. "Cucurbit[7]uril host-guest complexes with cationic bis(4,5-dihydro-1H-imidazol-2-yl) guests in aqueous solution." Canadian Journal of Chemistry 84, no. 6 (2006): 905–14. http://dx.doi.org/10.1139/v06-099.

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The host–guest interactions between cucurbit[7]uril and a series of novel cationic bis(4,5-dihydro-1H-imidazol-2-yl)arene and 1-(4,5-dihydro-1H-imidazol-2-yl)- and 1,3-bis(4,5-dihydro-1H-imidazol-2-yl)-adamantane guests have been investigated in aqueous solution using UV–vis and NMR spectroscopy, and electrospray mass spectrometry. With the exception of the 1,3-bis(4,5-dihydro-1H-imidazol-2-yl)adamantane (which binds externally to the CB[7]), these guests form very stable inclusion complexes with slow exchange on the 1H NMR timescale. The direction and magnitude of the complexation-induced shi
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Dissertations / Theses on the topic "Guest inclusion complexes"

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Bezuidenhout, Charl Xavier. "Polar ordering of guest molecules in host-guest inclusion complexes." Thesis, Stellenbosch : Stellenbosch University, 2011. http://hdl.handle.net/10019.1/18107.

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Thesis (MSc)--Stellenbosch University, 2011.<br>ENGLISH ABSTRACT: 2,7-dimethylocta-3,5-diyne-2,7-diol forms inclusion complexes with various guests molecules, where the guest molecules are polar-ordered. A Cambridge Structural Database (CSD) search revealed ten inclusion complexes where the guest molecules were polar-ordered. Using Density Functional Theory (DFT) computational methods (in the absence of the host), we evaluated the intra-channel and lateral guest-guest interactions between the guest molecules. Two polar-ordered inclusion complexes ((1,4,7-cyclohexane-1,2,4,5,7,8-hexaoxonane)·C
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Roy, Aditi. "Study to explore molecular inclusion complexes of cyclic hosts with vital guests in various environments." Thesis, University of North Bengal, 2018. http://ir.nbu.ac.in/handle/123456789/2633.

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O'Brien, Mark. "Spectroscopic Studies of Inclusion Host-Guest Complexes Between Cyclophane Corrals and Polcyclic Aromatic Hydrocarbons." TopSCHOLAR®, 2005. http://digitalcommons.wku.edu/theses/470.

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Cyclophanes are macromolecules that are known to effectively bind with molecules to form host-guest complexes. Several cyclophane molecules, referred to as corrals (1-6) by their founders, have been synthesized. The characterization of these compounds and their complexes has been investigated using combined spectroscopic and theoretical methods. Hostguest interactions of cyclophane-anthracene (C-A), cyclophane-9-fluorenone (C-F) and cyclophane-pyrene (C-P) complex systems in dichloromethane are presented in this thesis. The stability constants, log Ka, for the C-A, C-F and C-P complexes are de
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Hulushe, Siyabonga Theophillus. "Guest inclusion behaviour of zirconium(IV)- based polycarboxylate complexes: a study of metal-organic frameworks." Thesis, Rhodes University, 2018. http://hdl.handle.net/10962/63710.

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Mondal, Jaygopal. "Solvation consequences of different aqueous media on some biologically active compounds: a physico-chemical study." Thesis, University of North Bengal, 2021. http://ir.nbu.ac.in/handle/123456789/4751.

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Kundu, Mitali. "Exploration of inclusion complexes between host and guest molecules and solvation effect of some vital molecules in various environments." Thesis, University of North Bengal, 2017. http://ir.nbu.ac.in/handle/123456789/2689.

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Roy, Niloy. "Synthesis, characterization and innovative applications of inclusion complexes and nanocomposites of some biologically potent molecules." Thesis, University of North Bengal, 2022. http://ir.nbu.ac.in/handle/123456789/4754.

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Barman, Siti. "Investigation on solvation behaviour and host guest inclusion complexes of some significant molecules with diverse cyclic compounds." Thesis, University of North Bengal, 2017. http://ir.nbu.ac.in/handle/123456789/2588.

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Rahaman, Habibur. "Diverse Interactions of Some Significant Compounds Prevailing in Different Solvent Systems with the Manifestation of Solvation Consequence by Physicochemical Investigations." Thesis, University of North Bengal, 2019. http://ir.nbu.ac.in/handle/123456789/2814.

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Groom, Jazerie J. "Evaluation of Apparent Formation Constants of Host-Guest Inclusion Complexes of Solutes with Soluble Calixarenes Using High Performance Liquid Chromatography." Youngstown State University / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1389273191.

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Books on the topic "Guest inclusion complexes"

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Supramolecular Chemistry of Host-Guest Inclusion Complexes. GRIN Verlag GmbH, 2012.

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Book chapters on the topic "Guest inclusion complexes"

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Wagner, Brian D. "Host–Guest Inclusion Complexes." In Supramolecular Chemistry in Corrosion and Biofouling Protection. CRC Press, 2021. http://dx.doi.org/10.1201/9781003169130-3.

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Cheetham, A. K., and B. K. Peterson. "Computer Simulations of Host-Guest Complexes." In Inclusion Phenomena and Molecular Recognition. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4613-0603-0_29.

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Toda, Fumio. "Reaction control of guest compounds in host-guest inclusion complexes." In Topics in Current Chemistry. Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/3-540-19338-3_5.

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Yasuda, Satoshi, Yasuyuki Goto, Koji Miyake, et al. "Guest-Dependent Ordering of the Self-Assembled Cyclodextrin Inclusion Complexes Studied by Scanning Tunneling Microscopy." In Proceedings of the Ninth International Symposium on Cyclodextrins. Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4681-4_153.

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Wagner, Brian D. "Fluorescence Studies of the Hydrogen Bonding of Excited-State Molecules within Supramolecular Host-Guest Inclusion Complexes." In Hydrogen Bonding and Transfer in the Excited State. John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470669143.ch8.

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González-Gaitano, G., T. Sanz, R. Gabarró, J. A. Rodríguez-Cheda, M. C. Sáez, and G. Tardajos. "Molar Partial Properties in Host-Guest Systems: Application to the Inclusion Complexes between β- Cyclodextrin and Sodium Alkanoates." In Proceedings of the Ninth International Symposium on Cyclodextrins. Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4681-4_158.

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Ballester, Pablo, and Shannon M. Biros. "CH-π and π-π Interactions as Contributors to the Guest Binding in Reversible Inclusion and Encapsulation Complexes." In The Importance of Pi-Interactions in Crystal Engineering. John Wiley & Sons, Ltd, 2012. http://dx.doi.org/10.1002/9781119945888.ch3.

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Vitale, Rosa Maria, and Pietro Amodeo. "Self-Inclusion Complexes of Monofunctionalized Beta-Cyclodextrins as Host–Guest Interaction Model Systems and Simple and Sensitive Testbeds for Implicit Solvation Methods." In Computational Electrostatics for Biological Applications. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-12211-3_14.

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Harata, Kazuaki. "Recent advances in the X-ray analysis of cyclodextrin complexes." In Inclusion Compounds. Oxford University PressOxford, 1991. http://dx.doi.org/10.1093/oso/9780198552932.003.0009.

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Abstract Cyclodextrins are cyclic oligosaccharides consisting of six or more a-1,4-linked o-glucose units. These bucket-shaped macrocyclic molecules have a cylindrical cavity with a diameter larger than 5 A and a depth of7-8 A. The inside wall of the macrocycle is comprised of many methylene and methine groups, whereas at both ends of the cavity hydroxy groups are found in a circular arrangement. Therefore, the cyclodextrin cavity exhibits hydrophobic character and favourably accommodates the hydrophobic portion of the guest. Cyclodextrins form inclusion complexes rather nonspecifically with a
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Katz, Howard E. "Recent advances in multidentate anion complexation." In Inclusion Compounds. Oxford University PressOxford, 1991. http://dx.doi.org/10.1093/oso/9780198552925.003.0009.

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Abstract Organic chemists in general, and readers of previous chapters of this series in particular, are well aware of the dramatic advances that have been made in host-guest chemistry. Besides the substantial synthetic challenges that have been posed and met, a wide range of applications have been profitably investigated. The fundamental trait of recognition inherent in the interaction between hosts and guests enables selective sensing, separation, and transport. Altered properties of complexed species relative to separated entities include improved solubility in otherwise incompatible media,
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Conference papers on the topic "Guest inclusion complexes"

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Kaneko, Takuma, Hirokazu Takahashi, Kenryo Ohminami та ін. "Host-Guest Interaction in α-Cyclodextrin Inclusion Complexes". У X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference. AIP, 2007. http://dx.doi.org/10.1063/1.2644519.

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Caira, Mino. "Supramolecular chemistry of cyclodextrins and their inclusion complexes containing bioactive guest compounds." In The 1st International Electronic Conference on Pharmaceutics. MDPI, 2020. http://dx.doi.org/10.3390/iecp2020-08915.

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Hu, Shenshui, Cuiling Xu, Lingzi Meng, Yongbin He, and Dafu Cui. "Electrochemical oxygen sensor based on host-guest inclusion complex of calixarene and methyl viologen." In International Conference on Sensors and Control Techniques (ICSC2000), edited by Desheng Jiang and Anbo Wang. SPIE, 2000. http://dx.doi.org/10.1117/12.385597.

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Vázquez Tato, José, Víctor Soto Tellini, Aida Ramos, Juan Trillo Novo, Francisco Meijide, and Jorge Carrazana G. "Can Guest Hydrophobicity Guide the Entrance into the Host in the Formation of an Inclusion Complex?" In The 8th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2004. http://dx.doi.org/10.3390/ecsoc-8-01996.

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