Academic literature on the topic 'Imine chemistry'

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Journal articles on the topic "Imine chemistry"

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Garrido-Castro, Alberto F., M. Carmen Maestro та José Alemán. "α-Functionalization of Imines via Visible Light Photoredox Catalysis". Catalysts 10, № 5 (2020): 562. http://dx.doi.org/10.3390/catal10050562.

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The innate electrophilicity of imine building blocks has been exploited in organic synthetic chemistry for decades. Inspired by the resurgence in photocatalysis, imine reactivity has now been redesigned through the generation of unconventional and versatile radical intermediates under mild reaction conditions. While novel photocatalytic approaches have broadened the range and applicability of conventional radical additions to imine acceptors, the possibility to use these imines as latent nucleophiles via single-electron reduction has also been uncovered. Thus, multiple research programs have c
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Laha, Joydev K., K. S. Satyanarayana Tummalapalli, and Krupal P. Jethava. "Implications of dynamic imine chemistry for the sustainable synthesis of nitrogen heterocycles via transimination followed by intramolecular cyclisation." Organic & Biomolecular Chemistry 14, no. 8 (2016): 2473–79. http://dx.doi.org/10.1039/c5ob02670a.

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Lorenzini, Fabio, Paolo Marcazzan, Brian O. Patrick та Brian R. James. "Synthesis, characterization, and X-ray structures of three iridium(III)-hydrido-cyclometallated-imine complexes, including the first reported hydrido-(η1-imine)-Ir complex". Canadian Journal of Chemistry 86, № 3 (2008): 253–60. http://dx.doi.org/10.1139/v07-153.

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Reactions of cis,trans,cis-[Ir(H)2(PPh3)2(solv)2]PF6 (solv = MeOH or Me2CO) with the imines HN=CPh2, (o-HOC6H4)C(Me)=NCH2Ph, and PhC(H)=N(p-F-C6H4) in MeOH or acetone under Ar give the complexes [IrH{NH=C(Ph)(o-C6H4)}(NH=CPh2)(PPh3)2]PF6 (3), [IrH{PhCH2N=C(Me)(o-C6H3OH)}(solv)(PPh3)2]PF6, where solv = MeOH (4) or Me2CO (4a), and [IrH{N(p-F-C6H4)=CH(o-C6H4)}(Me2CO)(PPh3)2]PF6 (5a), which have been isolated and characterized. The imine (C6F5)C(H)=NPh is unreactive toward the Ir precursors. The X-ray structures of 3, 4·2MeOH, and 5a·1/2Me2CO show an η2-N,C-imine moiety coordinated via the N atom
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Becica, Joseph, Andrew B. Jackson, William G. Dougherty, W. Scott Kassel, and Nathan M. West. "Bis-tropolonate complexes of tungsten: scaffolds for selective side-on binding of nitriles, imines and ketones." Dalton Trans. 43, no. 23 (2014): 8738–48. http://dx.doi.org/10.1039/c4dt00734d.

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The bis-tropolonate tungsten(ii) tricarbonyl compound, (trop)<sub>2</sub>W(CO)<sub>3</sub> will preferentially bind nitriles, imines, and aldehydes in a side-on fashion. Crystallographic analysis of the imine adduct supports the postulation of 4-electron donation from the imine.
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Freese, Tyll, Jan C. Namyslo, Martin Nieger, and Andreas Schmidt. "Sulfur, mercury, and boron adducts of sydnone imine derived anionic N-heterocyclic carbenes." RSC Advances 9, no. 9 (2019): 4781–88. http://dx.doi.org/10.1039/c9ra00294d.

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The sydnone imines (5-benzoylimino)-3-(2-methoxyphenyl)-sydnone imine and molsidomine were deprotonated at C4 to give sydnone imine anions which can be represented as anionic N-heterocyclic carbenes, respectively.
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Belowich, Matthew E., and J. Fraser Stoddart. "Dynamic imine chemistry." Chemical Society Reviews 41, no. 6 (2012): 2003. http://dx.doi.org/10.1039/c2cs15305j.

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Gamenara, Daniela, and Pablo Domínguez de María. "Enantioselective imine reduction catalyzed by imine reductases and artificial metalloenzymes." Org. Biomol. Chem. 12, no. 19 (2014): 2989–92. http://dx.doi.org/10.1039/c3ob42205d.

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Adding value to organic synthesis. Novel imine reductases enable the enantioselective reduction of imines to afford chiral amines. Likewise, novel bioinspired artificial metalloenzymes can perform the same reaction as well. Remarkable recent examples are herein discussed.
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Wolfsberger, W. "N-(Halogendimethylsilyl)-1 -methylphospholanimine/N-(Halogenodimethylsilyl)-1 -methylphospholane Imines." Zeitschrift für Naturforschung B 55, no. 7 (2000): 557–60. http://dx.doi.org/10.1515/znb-2000-0701.

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N-Trimethylsilyl-1 -methylphospholane imine has been prepared by the Staudinger reaction of 1-methylphospholane with trimethylsilyl azide. Transsilylation reactions of the phosphine imine with dichloro or dibromodimethylsilane lead to dimeric N-(halogenodimethylsilyl)-l-methylphospholane imines with an ionic type of structure, containing a dicationic four-membered Si-N ring system. Upon heating, the chloro compound undergoes a reversible isomerization to give the corresponding covalent monomer.
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Freeman, Jared L., Freda F. Li, Daniel P. Furkert, and Margaret A. Brimble. "Synthetic Studies Towards Spirocyclic Imine Marine Toxins Using N-Acyl Iminium Ions as Dienophiles in Diels–Alder Reactions." Synlett 31, no. 07 (2020): 657–71. http://dx.doi.org/10.1055/s-0039-1691593.

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Cyclic imine marine toxins have attracted considerable attention from the synthetic community in the past two decades due to their unique chemical structures and clinically relevant biological activities. This review presents recent efforts of our group in the development of various strategies to efficiently construct the common spirocyclic imine fragments of the cyclic imine toxins. In particular, the use of α,β-unsaturated N-acyl iminium ion dienophiles in Diels–Alder reactions are highlighted, whereby direct access to spirocyclic imine motifs was obtained and important mechanistic details w
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Pająk, Agnieszka Katarzyna, Sonia Kotowicz, Paweł Gnida, et al. "Synthesis and Characterization of New Conjugated Azomethines End-Capped with Amino-thiophene-3,4-dicarboxylic Acid Diethyl Ester." International Journal of Molecular Sciences 23, no. 15 (2022): 8160. http://dx.doi.org/10.3390/ijms23158160.

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A new series of thiophene-based azomethines differing in the core structure was synthesized. The effect of the central core structure in azomethines on the thermal, optical and electrochemical properties was investigated. The obtained compounds exhibited the ability to form a stable amorphous phase with a high glass transition temperature above 100 °C. They were electrochemically active and undergo oxidation and reduction processes. The highest occupied (HOMO) and the lowest unoccupied molecular (LUMO) orbitals were in the range of −3.86–−3.60 eV and −5.46–−5.17 eV, respectively, resulting in
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Dissertations / Theses on the topic "Imine chemistry"

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Hammond, Max Leonard. "Imine catalyst stability." Thesis, University of Warwick, 2006. http://wrap.warwick.ac.uk/1172/.

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Chapter 1 presents a review of the background and current research regarding Schiff-base olefin polymerization catalysts, with special reference to the salicylaldimine species. An attempt is made to review trends within the current literature. Chapter 2 describes the synthesis and polymerization properties of tetradentate ligands with a bibenzyl backbone at titanium and zirconium centres, prepared with the intent of sterically hindering a 1,2-Migratory Insertion into the ligand imine functionality. A custom-built polymerization reactor was used to determine the stability of the catalytic syste
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Childs, Laura Jennifer. "Supramolecular assemblies based on imine and azo chemistry." Thesis, University of Warwick, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.269076.

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McMeekin, Peter. "Mechanistic aspects of imine cycloadditions." Thesis, Queen's University Belfast, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.356894.

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Rajviroongit, Shuleewan. "Cyclisation and cycloaddition of imine derivatives." Thesis, Queen's University Belfast, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.335436.

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Bhat, Shreesha V. "Synthesis of 1,2,4 oxadiazol-5-imine, 1,2,4-triazol-3-imine and derivatives : a substituted cyanamide-based strategy for heterocycle synthesis." Thesis, University of Lincoln, 2017. http://eprints.lincoln.ac.uk/28632/.

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Considering the importance of nitrogen-rich heterocycles in drug discovery, a novel strategy towards heterocycle synthesis was envisioned using cyanamide chemistry. Synthesis which involve mild conditions, avoids multi-step sequence and non-toxic reagents are desirable for generation of large combinatorial libraries of drug molecules. We envisaged that the NCN linkage of the cyanamide as well as the concomitant use of the nucleo-and electrophilic centres of the cyanamide could provide a novel synthetic route towards nitrogen heterocycles. The first part (Ch-2) constitute the bulk of the thesis
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Neshat, Abdollah. "Group V Imido Complexes Bearing Mono-Anionic Acetophenone Imine Ligands." University of Toledo / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1302269375.

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Beirl, Toni Marie. "Synthesis and Characterization of Novel Imine-Linked Covalent Organic Frameworks." The Ohio State University, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=osu1437559176.

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Prema, Dipesh. "Different coordination modes of bis(imine-ridine) and bis(quinaldine) ligands." Diss., Manhattan, Kan. : Kansas State University, 2007. http://hdl.handle.net/2097/267.

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Hanton, Martin John. "Coordination complexes of bidentate phosphino-imine ligands : synthesis, characterisation and reactivity." Thesis, University of Leicester, 2003. http://hdl.handle.net/2381/33724.

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This thesis describes the synthesis, reactivity and coordination chemistry of a range of bidentate phosphino-imine ligands. The reactivity of the resultant complexes is also probed, while testing of the complexes for catalytic activity in a range of carbon-carbon bond-forming reactions is documented. Chapter 1 introduces the concepts of 'hemi-lability' and 'trans-influence', along with heteroditopic bidentate ligands, and specifically examines imine- and phosphine-based ligands, particularly aminophosphines. The nature of the phosphorus centre in terms of its steric and electronic properties i
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Stafford, Carolyne. "The sequential insertion of carbon monoxide and imines into nickel-carbon sigma-bonds and kinetic analysis of imine insertion into palladium-acyl sigma-bonds." Thesis, McGill University, 2007. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=18447.

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ABSTRACT The Sequential Insertion of Carbon Monoxide and Imines into Nickel-Carbon Sigma-Bonds and Kinetic Analysis of Imine Insertion into Palladium-Acyl Sigma-Bonds The coupling of imines and carbon monoxide mediated by late transition metals has been previously reported in the Arndtsen laboratory. The fundamental properties of 2,1-migratory insertion of imines into nickel- and palladium-acyl bonds are presented in this text. This study investigates the use of neutral eta2-N,O-salicylaldiminato nickel (II) systems (Chapter 2) as potential complexes to mediate the sequential insertion of
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Books on the topic "Imine chemistry"

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Kimpe, Norbert De. The chemistry of &-haloketones, &-haloaldehydes and &-haloimines. Wiley, 1988.

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Kimpe, Norbert de. The chemistry of [alpha]-haloketones, [alpha]-haloaldehydes, and [alpha]-haloimines. Wiley, 1988.

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Wulfsberg, Gary. Ch imie inorganique: Théories et applications. Dunod, 2002.

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M, Hergenrother P., Bass R. G, and Langley Research Center, eds. Imide/arylene ether block copolymers. National Aeronautics and Space Administration, Langley Research Center, 1991.

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M, Hergenrother P., Bass R. G, and Langley Research Center, eds. Synthesis of imide/arylene ether copolymers for adhesives and composite matrices. National Aeronautics and Space Administration, Langley Research Center, 1991.

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M, Hergenrother P., Bass R. G, and Langley Research Center, eds. Synthesis of imide/arylene ether copolymers for adhesives and composite matrices. National Aeronautics and Space Administration, Langley Research Center, 1991.

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Wolfe, J. P. (James Philip), 1943- and Larhed Mats, eds. Science of synthesis: Cross coupling and Heck-type reactions. Georg Thieme Verlag KG, 2013.

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Kimpe, Norbert De, and Roland Verhe. The Chemistry of Haloketones, Haloaldehydes and Haloimines (The Chemistry of Functional Groups). John Wiley & Sons, 1989.

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Holley, William Keith. Boron hydride chemistry of n-substituted-iminotriphenylphosphoranes. 1986.

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Science of synthesis: Stereoselective synthesis : Stereoselective reactions of carbonal and imino groups. Georg Thieme, 2011.

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Book chapters on the topic "Imine chemistry"

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Schulze, A. Carina, and Iris M. Oppel. "Container Molecules Based on Imine Type Ligands." In Topics in Current Chemistry. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/128_2011_245.

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Gundermann, Karl-Dietrich, and Frank McCapra. "Other Nitrogen-Containing Compounds — Imine Peroxides." In Reactivity and Structure: Concepts in Organic Chemistry. Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-71645-4_9.

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Tidwell, Thomas T. "Preparation of Bis-β-Lactams by Ketene–Imine Cycloadditions." In Topics in Heterocyclic Chemistry. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/7081_2012_89.

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Krasavin, Mikhail. "Amine (Imine) Component Surrogates in the Ugi Reaction and Related Isocyanide-Based Multicomponent Reactions." In Isocyanide Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, 2012. http://dx.doi.org/10.1002/9783527652532.ch6.

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Wicks, Douglas A., and Philip E. Yeske. "Imine—Isocyanate Chemistry: New Technology for Environmentally Friendly, High-Solids Coatings." In ACS Symposium Series. American Chemical Society, 1996. http://dx.doi.org/10.1021/bk-1996-0640.ch012.

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Wills, Martin. "Imino Transfer Hydrogenation Reductions." In Topics in Current Chemistry Collections. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-43051-5_2.

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Keohan, Frank L., and John E. Hallgren. "Novel Poly(imide—siloxane) Polymers and Copolymers." In Advances in Chemistry. American Chemical Society, 1989. http://dx.doi.org/10.1021/ba-1990-0224.ch009.

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Marra, Alberto, and Renaud Zelli. "Synthesis and biological properties of imino-disaccharides and -oligosaccharides." In Carbohydrate Chemistry. Royal Society of Chemistry, 2017. http://dx.doi.org/10.1039/9781788010641-00001.

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Weinreb, Steven M. "N-sulfonyl imines — Useful synthons in stereoselective organic synthesis." In Topics in Current Chemistry. Springer Berlin Heidelberg, 1997. http://dx.doi.org/10.1007/bfb0119248.

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Sharp, John T. "Nitrile Ylides and Nitrile Imines." In Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products. John Wiley & Sons, Inc., 2003. http://dx.doi.org/10.1002/0471221902.ch7.

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Conference papers on the topic "Imine chemistry"

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García-Deibe, Ana, Matilde Fondo, Jesús Sanmartín, and Cristina Portela. "Imine-tetrahydroquinazoline tautomerism in a tosilated Schiff base." In The 14th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2010. http://dx.doi.org/10.3390/ecsoc-14-00426.

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Al Janabi, Basma, Juan M. Ortigueira, and Jose Manuel Vila. "Synthesis and X-ray Diffraction of Cyclopalladated Compounds Derived from Imine Ligands." In International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2022. http://dx.doi.org/10.3390/ecsoc-26-13699.

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Chung, Yi-Chen, and Tai-Horng Young. "The exhibition of polyethylene imine/DNA coated with oligonucleotides for gene delivery." In 2010 International Conference on Chemistry and Chemical Engineering (ICCCE). IEEE, 2010. http://dx.doi.org/10.1109/iccceng.2010.5560372.

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Sanmartín-Matalobos, Jesús, Ana García-Deibe, Cristina Portela-García, Lucía Briones-Miguéns, and Matilde Fondo. "Controlling the ring-chain tautomeric equilibrium of a tetrahydroquinazoline/imine system by steric hindrance." In The 17th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2013. http://dx.doi.org/10.3390/ecsoc-17-a023.

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Seijas, Julio, M. Pilar Vázquez-Tato, and José Crecente-Campo. "Synthesis of 4-phenylcoumarin from 2-hydroxybenzophenone imine and diethyl malonate by microwave assisted Knoevenagel condensation." In The 13th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2009. http://dx.doi.org/10.3390/ecsoc-13-00161.

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Romero, María J., Luis M. González-Barcia, Manuel R. Bermejo, M. Isabel Fernández, and Esther Gómez-Fórneas. "Supramolecular self-assembly of a symmetric imine ligand functionalized with a dansyl fluorophore moiety." In The 20th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2016. http://dx.doi.org/10.3390/ecsoc-20-d002.

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Ye, Zhuoliang, Mi Tang, and Jingyi Song XSong. "Fast removal of concentrated heavy metal ions using an alginate-poly(ethylene imine) biological adsorbent." In 2017 5th International Conference on Mechatronics, Materials, Chemistry and Computer Engineering (ICMMCCE 2017). Atlantis Press, 2017. http://dx.doi.org/10.2991/icmmcce-17.2017.82.

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Romero, María J., Sandra Fernández-Fariña, Luis M. González-Barcia, Rosa Pedrido, Ana M. González-Noya, and Marcelino Maneiro. "Synthesis of two asymmetric half-salen imine-type ligands as precursors of polynuclear metal complexes." In The 21st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2017. http://dx.doi.org/10.3390/ecsoc-21-04752.

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Couture, Axel, Eric Deniau, Pierre Grandclaudon, and Marc Lamblin. "First Total Synthesis of Narceine Imide." In The 10th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2006. http://dx.doi.org/10.3390/ecsoc-10-01386.

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Pinho e Melo, Teresa, Ana Cabral, and António d'A Rocha Gonsalves. "Intramolecular Cycloaddition of Imines of Cysteine Derivatives." In The 1st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02044.

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