Relevant bibliographies by topics / Malononitrile

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Malononitrile'

Author: Grafiati
Published: 4 June 2021
Last updated: 27 July 2025

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Journal articles on the topic "Malononitrile"

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Zanardi, Franca, Claudio Curti, Andrea Sartori та Lucia Battistini. "Exploring the Remote Reactivity of π-Extended Carbonyl Compounds: The Vinylogous Alkylidene Malononitrile Activation Strategy". Synlett 29, № 03 (2017): 266–81. http://dx.doi.org/10.1055/s-0036-1589125.

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The installation of malononitrile into π-extended carbonyl compounds gives rise to vinylogous alkylidene malononitriles (also known as π-extended dicyanovinylidenes), the direct functionalization of which at remote C(sp3) pronucleophilic sites becomes possible and viable. Starting from easily accessible representative polyunsaturated malononitriles, mild conditions were found to directly couple them to complementary enal acceptors. In all cases, the malononitrile handle proved an indispensable (and optionally traceless) activating ingredient for the vinylogous reactions to proceed efficiently
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Szwed, Krystyna Bogdanowicz, Hanna Feret, and Małgorzata Lipowska. "The Reaction of Malononitrile with Some Enamines of 1-Indanone Synthesis of o-Aminonitriles of Indenopyridine and Indenothiopyran." Zeitschrift für Naturforschung B 42, no. 5 (1987): 623–27. http://dx.doi.org/10.1515/znb-1987-0518.

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(4).The reaction of enamines of 1-oxo-indan-2-carboxylic acid anilides (1) with malononitrile yielded 2-arylcarbamylindenylidene-malononitriles (3), which in alkaline solution underwent cyclization to indenopyridines Enamines of 1-oxo-indan-2-carbothionic acid anilides (2) reacted with malononitrile yielding indenothiopyrans (6), which under influence of alkalis were transformed to indenopyridines (8).
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Reddy Gajulapalli, V. Pratap, Poopathy Vinayagam, and Venkitasamy Kesavan. "Enantioselective assembly of functionalized carbocyclic spirooxindoles using anl-proline derived thiourea organocatalyst." RSC Advances 5, no. 10 (2015): 7370–79. http://dx.doi.org/10.1039/c4ra13711f.

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Dotsenko, Victor V., Inessa A. Kotlova, Nikolai A. Aksenov, and Inna V. Aksenova. "Synthesis of (3-Cyano-5,6,7,8-Tetrahydroquinolin-2(1H)-ylidene) Malononitriles." Proceedings 41, no. 1 (2019): 32. http://dx.doi.org/10.3390/ecsoc-23-06524.

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Thabet, H. Kh, Mohd Imran, Mohd Imran, Saleh Alaql, and M. H. M. Helal. "Bis(2-cyanoacetamide) in Heterocyclic Synthesis: Synthesis of Some Bis[2-oxopyridine, 2-iminochromene, Chromeno[3,4-c]pyridine, Benzochromeno[3,4-c]pyridine] Derivatives." Oriental Journal Of Chemistry 40, no. 1 (2024): 65–73. http://dx.doi.org/10.13005/ojc/400108.

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N,N'-(methylenebis(1,4-phenylene))bis-(2-cyanoacetamide) was exploited as a precursor for synthesing some bis (benzylidene 5a-c, pyridines 7, 8, 10a,b, chromene 14, benzochromene 15) derivatives containing diphenyl-methylene spacer via the reaction with each of aromatic aldehydes, pentane-2,4-dione, acetaldehyde/ malononitrile, arylidene-malononitriles, ethyl cinnamates, 2-hydroxybenzaldehyde, and 2-hydroxy-1-naphthaldehyde). Bis(chromeno[3,4-c]pyridines 16&18) were synthesized via Michael's addition of malononitrile or ethyl cyanoacetate to bis(chromene) derivative. The newly prepared com
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Dhivare, Ravindra S., and S. S. Rajput. "Malononitrile: A Versatile Active Methylene Group." International Letters of Chemistry, Physics and Astronomy 57 (August 2015): 126–44. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.57.126.

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The title role of malononitrile in the development of Knoevenagel condensation of organic synthesis and their new findings are explored in this review. The active methylene group of malononitriles is very important attacking part in the heterocyclic conversions and also having a great potency towards several microbial and biological systems.
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Dhivare, Ravindra S., and S. S. Rajput. "Malononitrile: A Versatile Active Methylene Group." International Letters of Chemistry, Physics and Astronomy 57 (August 4, 2015): 126–44. http://dx.doi.org/10.56431/p-5354je.

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The title role of malononitrile in the development of Knoevenagel condensation of organic synthesis and their new findings are explored in this review. The active methylene group of malononitriles is very important attacking part in the heterocyclic conversions and also having a great potency towards several microbial and biological systems.
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R., S. Dhivare, and S. Rajput S. "Malononitrile: A Versatile Active Methylene Group." International Letters of Chemistry, Physics and Astronomy 57 (August 4, 2015): 126–44. https://doi.org/10.18052/www.scipress.com/ilcpa.57.126.

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Abstract: The title role of malononitrile in the development of Knoevenagel condensation of organic synthesis and their new findings are explored in this review. The active methylene group of malononitriles is very important attacking part in the heterocyclic conversions and also having a great potency towards several microbial and biological systems.
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Saikia, Anil. "Malononitrile." Synlett, no. 12 (2004): 2247–48. http://dx.doi.org/10.1055/s-2004-832822.

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Kozyrod, RP, J. Morgan та JT Pinhey. "The C-Arylation of α-Cyano Esters and Malononitriles by Aryllead(IV) Triacetates". Australian Journal of Chemistry 44, № 3 (1991): 369. http://dx.doi.org/10.1071/ch9910369.

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The arylation of soft carbon nucleophiles by aryllead (IV) triacetates has been extended to α- cyano esters and malononitriles. Arylation did not occur with the parent compounds, ethyl cyanoacetate and malononitrile, but in both series monosubstituted compounds reacted to give α-aryl derivatives in synthetically useful yields. A study of the effect of some tertiary aromatic amines and dimethyl sulfoxide, substances which complex with lead(IV), has been carried out, and in two cases the influence of bulky α- substituents has been examined.
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Dissertations / Theses on the topic "Malononitrile"

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Foucat, Loïc. "Etude par rmn de la dynamique rotationnelle du malononitrile." Paris 6, 1987. http://www.theses.fr/1987PA066377.

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Etude de cette molecule de type rotateur asymetrique en solution dans ch::(2)cl::(2), tetrahydrofurane et diglyne. A l'aide de la theorie de la "relaxation couplee" determination des valeurs des trois constantes de diffusion du solute et des densites spectrales relatives aux mecanismes de relaxation dipole-dipole, intra-et intermoleculaire. Etude de l'influence du taux de deuteriation du solvant sur la relaxation du solute dans le cas de ch::(2)cl::(2). Ecart des densites spectrales par rapport aux previsions theoriques. Test de la validite de plusieurs modeles hydrodynamiques: celui de knauss
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Foucat, Loïc. "Etude par RMN de la dynamique rotationnelle du malononitrile." Grenoble 2 : ANRT, 1987. http://catalogue.bnf.fr/ark:/12148/cb376051883.

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Benkhai, Amine. "Spectrométrie infrarouge des excitons et réapparition de phase dans le cristal moléculaire de malononitrile." Poitiers, 1990. http://www.theses.fr/1990POIT2306.

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Le cristal moleculaire de malononitrile presente deux transitions de phase du second ordre a tc#1=294,7 et a tc#2=141 k. Les phases haute(i) et basse temperature (iv) ont la meme structure cristallographique (monoclinique), la phase intermediaire est de moindre symetrie. Le present travail etudie par spectromerie infrarouge des excitons la transition de phase iviii reentrante a tc#2=141 k et la transition de phase iiiii du premier ordre a t#t=260 k. Pour caracteriser la transition de phase a tc#2=141 k, nous avons etudie la variation de la separation des composantes excitoniques () cm##1 de la
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Hout, Joseph J. "Identification of compounds formed during the low temperature heat dispersal of o-chlorobenzylidene malononitrile (CS riot control agent) /." Download the thesis in PDF, 2006. http://www.lrc.usuhs.mil/dissertations/pdf/Hout2006.pdf.

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Tayyari, Fariba. "Efficient one-pot reductive alkylations of malononitrile with aromatic aldehydes and one-pot synthesis of new 2-amino-3-cyano-4H-chromenes." Virtual Press, 2008. http://liblink.bsu.edu/uhtbin/catkey/1399195.

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A powerful new one-pot method has been developed for the reductive alkylation of malononitrile with aromatic aldehydes. This new procedure has vastly improved the yield and efficiency and increased the scope for the aromatic aldehydes. Incorporating water as the catalyst in ethanol for the condensation step allows stoichiometric amounts of malononitrile and aldehyde to be employed. After dilution and cooling the reduction step takes place quickly and efficiently with sodium borohydride to give monosubstituted malononitriles.The product from the reductive alkylation of malononitrile with 2-quin
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Crump, P. W. "The radiosensitization of Escherichia coli by malononitriles." Thesis, University of Salford, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.353978.

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Moimare, Pierluigi. "Sintesi e caratterizzazione strutturale di derivati piperidinici e morfolinici chirali." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2019. http://amslaurea.unibo.it/19197/.

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The topic of this thesis concerns the study of catalytic processes for the synthesis of chiral 3,4,5-trisubstituted piperidine and 2,6-disubstituted morpholine. Substrates possessing an α,β-unsaturated ester and a ketone moiety, able to undergo addition/cyclization cascade reactions with different pro-nucleophiles (thiophenols, acetone cyanohydrin and malononitrile), have been evaluated. Chiral and achiral systems for phase-transfer catalysis have been applied as catalysts. Moderate enantiomeric excesses have been obtained for the morpholinic products and good to excellent values for the piper
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Chityala, Madhu. "Chemistry of Cyanoform (Tricyanomethane); and Rearrangement of 1H-1,2,3-Triazoles to the Corresponding 2H-Isomers." Doctoral thesis, Universitätsbibliothek Chemnitz, 2017. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-216192.

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Cyanoform (tricyanomethane) is one of the strongest carbon-based organic acids reported in text books of organic chemistry, which has evaded synthesis and isolation in its free state, since 120 years. In this dissertation, the acid-free synthesis of cyanoform by an absolutely new approach has been discussed. Generation of the elusive molecule, cyanoform from the photolysis and thermolysis of 2-(azidomethylidene)malononitrile, has been confirmed at very low temperatures by 1H NMR, 13C NMR, 15N NMR, and the relevant 2D NMR spectroscopic techniques. Moreover, it has been proved that cyanoform is
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Swift, Elizabeth Claire. "Development of Palladium-Catalyzed Allylation Reactions of Alkylidene Malononitriles and Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Electrophiles." Thesis, University of California, Irvine, 2013. http://pqdtopen.proquest.com/#viewpdf?dispub=3592019.

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<p> Transition-metal catalysis has enabled the development of an unprecedented number of mild and selective C-C bond-forming reactions. We sought to access the reactivity of palladium and nickel catalysts for two types of transformations: conjugate allylations and sp<sup>3</sup>-sp<sup> 3</sup> cross-coupling reactions. </p><p> Conjugate allylation of malononitriles was evaluated with N-heterocyclic carbene-ligated palladium complexes. The allylation was found to yield a variety of mono-allylated products. These results are in contrast to the bis-allylation of malononitriles using other pal
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Vergnat, Virginie. "Matériaux hybrides organiques-inorganiques par greffage covalent de polymères sur des oxydes métalliques." Strasbourg, 2011. https://publication-theses.unistra.fr/public/theses_doctorat/2011/VERGNAT_Virginie_2011.pdf.

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L’objectif de cette thèse est d’élaborer des matériaux hybrides polymères/oxydes métalliques à nanostructure contrôlée et d’étudier leurs propriétés physiques. Pour préparer ces matériaux, nous avons choisi la méthode « grafting from » qui consiste dans un premier temps à greffer de manière covalente un amorceur de polymérisation à la surface des nanoparticules. La polymérisation est ensuite conduite depuis la surface de ces nanoparticules. Tout d’abord, nous présentons les nanoparticules d’oxydes métalliques utilisées: la ferrite de cobalt synthétisée par coprécipitation, l’oxyde de fer non a
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Books on the topic "Malononitrile"

1

Crump, Paul William. The radiosensitization of Escherichia coli by malononitriles. University of Salford, 1985.

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Book chapters on the topic "Malononitrile"

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Howard, Philip H., Edward M. Michalenko, William M. Meylan, et al. "Malononitrile." In Handbook of Environmental Fate and Exposure Data for Organic Chemicals, Volume IV. CRC Press, 2023. http://dx.doi.org/10.1201/9781003418887-59.

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Chanana, Garima, and Kriti Batra. "Modelling Novel Organic Molecule 2-(4-Ethylbenzylidene) Malononitrile (EBM) for Nonlinear Optical (NLO) Applications." In Springer Proceedings in Physics. Springer Singapore, 2022. http://dx.doi.org/10.1007/978-981-16-7691-8_42.

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Singh, Ruby, and K. L. Ameta. "Malononitrile: A Key Reagent for the Synthesis of Medicinally Promising Fused and Spiro Pyridine Derivatives in Multicomponent Reactions." In Multicomponent Reactions. CRC Press, 2017. http://dx.doi.org/10.1201/9781315369754-12.

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AHMED, AHMED E., and GAMAL I. HUSSEIN. "Malononitrile." In Nitrogen and Phosphorus Solvents. Elsevier, 1990. http://dx.doi.org/10.1016/b978-0-444-81316-9.50058-x.

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von Angerer, S. "Reaction of Malononitrile." In Six-Membered Hetarenes with Two Identical Heteroatoms. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-016-00492.

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Schmidbaur, H., and A. Schier. "Auration of Malononitrile." In Compounds of Groups 12 and 11 (Zn, Cd, Hg, Cu, Ag, Au). Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-003-00487.

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Etemad, Leila, Mahdi Balali-Mood, and Mohammad Moshiri. "o-Chlorobenzylidene malononitrile (CS)." In Reference Module in Biomedical Sciences. Elsevier, 2022. http://dx.doi.org/10.1016/b978-0-12-824315-2.00214-1.

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Spitzner, D. "From Oxazoles and Malononitrile." In Six-Membered Hetarenes with One Nitrogen or Phosphorus Atom. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-015-00185.

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Sako, M. "Cycloamination of Malononitrile Dimers." In Six-Membered Hetarenes with Two Identical Heteroatoms. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-016-01564.

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Ishikawa, T. "From Malononitrile and Guanidine." In Six-Membered Hetarenes with Two Identical Heteroatoms. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-016-01794.

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Conference papers on the topic "Malononitrile"

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Deore, Nitin R., Tushar Janardan Pawar, Yadav K. Nagare, and Sachin V. Patil. "Electrochemical Synthesis of Imidazopyridine and Benzylidene Malononitrile." In International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2022. http://dx.doi.org/10.3390/ecsoc-26-13567.

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Touati, Yousseuf, Mohammed Benabdallah, Julio A. Seijas, Noureddine Choukchou-Braham, and M. Pilar Vázquez-Tato. "Reactivity of 2-aminothiazole with benzaldehyde and malononitrile." In The 23rd International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2019. http://dx.doi.org/10.3390/ecsoc-23-06699.

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Dotsenko, Victor, Vyacheslav Muraviev, Ludmila Dyadyuchenko, and Nicolai Aksenov. "The reaction of malononitrile dimer with 4-methyl-2,6-dichloronicotinonitrile." In The 24th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2020. http://dx.doi.org/10.3390/ecsoc-24-08418.

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Du, Juan, Yu Wang, Yuxia Zhao, and Feipeng Wu. "Synthesis and structure property relationship of several dicyanomethylene malononitrile derivatives." In Eighth International Symposium on Advanced Optical Manufacturing and Testing Technology (AOMATT2016), edited by Yadong Jiang, Bernard Kippelen, and Junsheng Yu. SPIE, 2016. http://dx.doi.org/10.1117/12.2241720.

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"Insights into the Crystal Structure, Hirshfeld Surface, and Void Analysis of a Malononitrile Derivative Compound." In 2nd International Conference on Contemporary Academic Research ICCAR 2023. All Sciences Academy, 2023. http://dx.doi.org/10.59287/as-proceedings.240.

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"Quantum Chemical Insights into 2-[2-(Benzyloxy)benzylidene] malononitrile: DFT Analysis, MEP Surface Mapping, and HOMO-LUMO Energies." In 4th International Conference on Engineering and Applied Natural Sciences ICEANS 2023. All Sciences Academy, 2023. http://dx.doi.org/10.59287/as-proceedings.348.

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Grinev, Vyacheslav S., Ilya A. Demeshko, Anna E. Sklyar, and Alevtina Yu Yegorova. "Crystal Structure of 2-(Ethoxymethylene)malononitrile and DFT Evaluation of the C-H···N≡C Close Contacts Energy." In ECSOC 2023. MDPI, 2023. http://dx.doi.org/10.3390/ecsoc-27-16052.

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Choi, Dong Hoon, Jung Eun Lee, Young-Wan Kwon, et al. "Optical properties of DNA-CTMA and PA-CTMA doped with (E)-2-(2-(4-(diethylamino)styryl)-4H-pyan-4-ylidene)malononitrile (DCM)." In SPIE Europe Security and Defence, edited by James G. Grote, Francois Kajzar, and Mikael Lindgren. SPIE, 2008. http://dx.doi.org/10.1117/12.801711.

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Pogrebnoi, Vsevolod, Natalia Sucman, and Fliur Macaev. "The amides of dehydroabietic acid in synthesys of spiropyranes with the participation of carbonyl compounds." In Scientific seminar with international participation "New frontiers in natural product chemistry". Institute of Chemistry, Republic of Moldova, 2023. http://dx.doi.org/10.19261/nfnpc.2023.ab16.

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The abstract presents the synthesis of new spiropyranes from substituted 5-aminoisatin 6 in multicomponent reaction with different carbonyl compounds. It is known that spiropyranes have various activities, which depend from spatial structure and substituents [1]. From the other side, previously mentioned dehydroabietic acid 1 [2] is interesting object to study due to its molecular structure, chemical and biological properties.Initially, our strategy was to obtain the substituted isatine 6 from easily accessible isatine 3. To implement that approach, previously obtained [2] 5-nitroisatine react
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Reports on the topic "Malononitrile"

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Archuleta, M. M., and W. E. Stocum. Toxicity evaluation and hazard review for o-Chlorobenzylidene Malononitrile. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10113359.

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Johnson-Kanapathy, Erin. Quantification of Hydrogen Cyanide Generated at Low Temperature O-Chlorobenzylidene Malononitrile (CS) Dispersal. Defense Technical Information Center, 2013. http://dx.doi.org/10.21236/ad1012989.

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Hout, Joseph J. O-Chlorobenzylidene Malononitrile (CS Riot Control Agent) Exposures and Associated Acute Respiratory Illnesses in a United States Army Basic Combat Training Cohort. Defense Technical Information Center, 2014. http://dx.doi.org/10.21236/ad1012835.

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