Academic literature on the topic 'Metal Complexes - Electron Transfer'

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Journal articles on the topic "Metal Complexes - Electron Transfer"

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Shirai, Hirofusa, and Okikazu Hirabara. "Electron transfer in macromolecule-metal complexes." Kobunshi 38, no. 6 (1989): 436–39. http://dx.doi.org/10.1295/kobunshi.38.436.

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Ciarrocchi, Carlo, Guido Colucci, Massimo Boiocchi, et al. "Interligand Charge-Transfer Processes in Zinc Complexes." Chemistry 4, no. 3 (2022): 717–34. http://dx.doi.org/10.3390/chemistry4030051.

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Electron donor–acceptor (EDA) complexes are characterized by charge-transfer (CT) processes between electron-rich and electron-poor counterparts, typically resulting in a new absorption band at a higher wavelength. In this paper, we report a series of novel 2,6-di(imino)pyridine ligands with different electron-rich aromatic substituents and their 1:2 (metal/ligand) complexes with zinc(II) in which the formation of a CT species is promoted by the metal ion coordination. The absorption properties of these complexes were studied, showing the presence of a CT absorption band only in the case of ar
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Devi, Tarali, Yong-Min Lee, Wonwoo Nam, and Shunichi Fukuzumi. "Metal ion-coupled electron-transfer reactions of metal-oxygen complexes." Coordination Chemistry Reviews 410 (May 2020): 213219. http://dx.doi.org/10.1016/j.ccr.2020.213219.

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Wenger, Oliver S. "Proton-Coupled Electron Transfer with Photoexcited Metal Complexes." Accounts of Chemical Research 46, no. 7 (2013): 1517–26. http://dx.doi.org/10.1021/ar300289x.

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Cho, K. C., P. M. Cham, and C. M. Che. "Kinetics of electron transfer between metal hexacyanide complexes." Chemical Physics Letters 168, no. 3-4 (1990): 361–64. http://dx.doi.org/10.1016/0009-2614(90)85625-m.

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Ishizuka, Tomoya, Shunichi Fukuzumi, and Takahiko Kojima. "Molecular assemblies based on strong axial coordination in metal complexes of saddle-distorted dodecaphenylporphyrins." Journal of Porphyrins and Phthalocyanines 19, no. 01-03 (2015): 32–44. http://dx.doi.org/10.1142/s1088424615500273.

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In this mini-review, we have highlighted our works on metal complexes having saddle-distorted dodecaphenylporphyrin (DPP) and its derivative as ligands in the light of enhancement of the Lewis acidity of a metal center coordinated by the porphyrin. The important point through this mini-review is ill-overlap of the out-of-plane lone pairs of pyrrole nitrogen atoms with σ-orbitals of the metal center bound to the saddle-distorted porphyrin core. The enhanced Lewis acidity of the central metal ions enabled us to construct stable molecular complexes through axial coordination using metal–DPP (M(DP
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Bley-Escrich, Jordi, Serguei Prikhodovski, Carsten D. Brandt, Martin Bröring, and Jean-Paul Gisselbrecht. "Electrochemical investigations of tripyrrin complexes." Journal of Porphyrins and Phthalocyanines 07, no. 04 (2003): 220–26. http://dx.doi.org/10.1142/s1088424603000306.

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Electrochemical investigations on divalent transition metal complexes with a conjugated linear tripyrrole ligand, namely 3,4,8,9,13,14-hexaethyl-2,15-dimethyltripyrrin (HTrpy) are reported. This tripyrrin ligand behaves as a tridentate monoanionic ligand and forms a series of neutral metal complexes of the type TrpyMX, where M = Zn ( II ), Cu ( II ), Ni ( II ) Co ( II ) or Pd ( II ) and X is a chloride anion ( Cl -). The studied nickel, cobalt and zinc complexes undergo respectively three and two ligand-centered reversible one-electron reductions and a reversible ligand-centered one-electron o
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Vogler, A., A. H. Osman, and H. Kunkely. "Heterobinuclear transition-metal complexes. Synthesis and optical metal to metal electron transfer." Inorganic Chemistry 26, no. 14 (1987): 2337–40. http://dx.doi.org/10.1021/ic00261a035.

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Purugganan, MD, CV Kumar, NJ Turro, and JK Barton. "Accelerated electron transfer between metal complexes mediated by DNA." Science 241, no. 4873 (1988): 1645–49. http://dx.doi.org/10.1126/science.241.4873.1645.

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Purugganan, M., C. Kumar, N. Turro, and J. Barton. "Accelerated electron transfer between metal complexes mediated by DNA." Science 241, no. 4873 (1988): 1645–49. http://dx.doi.org/10.1126/science.3420416.

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Dissertations / Theses on the topic "Metal Complexes - Electron Transfer"

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Wilson, L. M. "Electron-transfer properties of polynuclear complexes." Thesis, University of East Anglia, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.374277.

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Poyraz, Mehmet. "Valence localisation in transition metal cluster complexes." Thesis, University of East Anglia, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.389271.

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Delony, Daniel. "Proton Coupled Electron Transfer at Heavy Metal Sites." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2020. http://hdl.handle.net/21.11130/00-1735-0000-0005-1546-5.

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Raven, S. J. "One-electron transfer reactions of low-valent transition metal complexes." Thesis, University of Bristol, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373290.

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McDonald, David Robert 1964 Carleton University Dissertation Chemistry. "Photoinduced electron transfer in chromophore-quencher complexes designed for metal centered chemistry." Ottawa.:, 1996.

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Koumousi, Evangelia S. "Synthesis and characterization of dinuclear {Fe(μ-CN)Co} complexes exhibiting metal-to-metal electron transfer properties". Thesis, Bordeaux, 2015. http://www.theses.fr/2015BORD0306/document.

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Cette thèse porte sur la synthèse de nouveaux complexes binucléaires à ponts cyanures de type {Fe(μ-CN)Co}, qui reproduisent au sein d'une seule molécule les propriétés originales du réseau de coordination d'analogue de bleu de Prusse AxCo[Fe(CN)6]y•nH2O (A=ions alcalins), i.e. un transfert d'électron intramoléculaire thermo- et photo-induit à l'état solide. Au sein de ce travail, nous nous sommes intéressés à l'étude des propriétés physiques des paires moléculaires Fe/Co, avec l’objectif de comprendre les mécanismes du phénomène de transfert d'électrons. Le chapitre I contient les exemples le
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D'Acchioli, Jason S. "On the nature of the electronics structure of metal-metal quadruply bonded complexes." Connect to resource, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1126621699.

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Thesis (Ph. D.)--Ohio State University, 2005.<br>Title from first page of PDF file. Document formatted into pages; contains xii, 286 p.; also includes graphics (some col.). Includes bibliographical references (p. 273-286). Available online via OhioLINK's ETD Center
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Reed, Carly R. "The Photophysical Properties of Multiply Bonded Metal Complexes of Molybdenum, Tungsten, and Rhenium." The Ohio State University, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=osu1309880937.

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Chatterjee, Sayandev. "Cooperative Two-Electron Reagents of Lower Transition Metals of Group 10." University of Cincinnati / OhioLINK, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1250266435.

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Walker, Glen William, and not available. "Electron Transfer Reactivity, Synthesis, Surface Chemistry and Liquid-Membrane Transport of Sarcophagine-Type Poly-Aza Cage Complexes." The Australian National University, 1997. http://thesis.anu.edu.au./public/adt-ANU20010702.124104.

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[Formulae and special characters can only be approximated here. Please see the pdf version of the Abstract for an accurate reproduction.] The kinetics for outer-sphere electron transfer between a series of cobalt(II) poly-aza cage ligand complexes and the iron(III) sarcophagine-type hexa-aza cage complex, [Fe(sar)]3+ (sar = 3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane), in aqueous solution have been investigated and the Marcus correlation is used to deduce the electron self-exchange rate constant for the [Fe(sar)]3+/2+ couple from these cross-reactions. The deduced electron self-exchange rate
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Books on the topic "Metal Complexes - Electron Transfer"

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Wilson, Ladislav Mario. Electron-transfer properties of polynuclear complexes. University of East Anglia, 1986.

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Hellman, Anders. Electron transfer and molecular dynamics at metal surfaces. Dept. of Applied Physics, Chalmers University of Technology, Göteborg University, 2003.

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1908-, Gutmann Felix, ed. Charge transfer complexes in biological systems. M. Dekker, 1997.

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Kinzoku sakutai no denshi idō to denki kagaku. Sankyō Shuppan, 2013.

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Astruc, Didier. Electron transfer and radical processes in transition-metal chemistry. Wiley-VCH, 1995.

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Astruc, D. Electron transfer and radical processes in transition-metal chemistry. VCH, 1995.

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Joshua, Jortner, Bixon M, Prigogine I, and Rice Stuart Alan 1932-, eds. Electron transfer- from isolated molecules to biomolecules. J. Wiley, 1999.

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Jezierska, Julia. Badanie metodą elektronowego rezonansu paramagnetycznego struktury kompleksów miedzi (II) ze szczególnym uwzględnieniem procesów polimeryzacji i ligandów polimerycznych. Wydawn. Uniwersytetu Wrocławskiego, 1993.

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Anderson, Kim A. Kinetics of outer-sphere electron transfer reactions in non-aqueous solvents. 1989.

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Gribble, Jacquelin D. Kinetics of outer-sphere electron transfer reactions in non-aqueous solutions. 1989.

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Book chapters on the topic "Metal Complexes - Electron Transfer"

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Balzani, V., and M. Maestri. "Intermolecular Energy and Electron Transfer Processes." In Catalysis by Metal Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-017-2626-9_2.

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Bockman, T. M., and J. K. Kochi. "Electron Donor-Acceptor Interactions and Photo-Induced Electron Transfer of Organometallic Compounds." In Catalysis by Metal Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-017-2626-9_14.

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Scandola, F., C. A. Bignozzi, and M. T. Indelli. "Intramolecular Energy and Electron Transfer in Polynuclear Metal Complexes." In Catalysis by Metal Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-017-2626-9_6.

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Mesmaeker, Andrée Kirsch-De, Jean-Paul Lecomte, and John M. Kelly. "Photoreactions of metal complexes with DNA, especially those involving a primary photo-electron transfer." In Electron Transfer II. Springer Berlin Heidelberg, 1996. http://dx.doi.org/10.1007/3-540-60110-4_2.

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Kostić, Nenad M. "Dynamic Aspects of Electron-Transfer Reactions in Metalloprotein Complexes." In Metal-Containing Polymeric Materials. Springer US, 1996. http://dx.doi.org/10.1007/978-1-4613-0365-7_37.

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Hoffman, Brian M., Michael J. Natan, Judith M. Nocek, and Sten A. Wallin. "Long-range electron transfer within metal-substituted protein complexes." In Long-Range Electron Transfer in Biology. Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/3-540-53260-9_3.

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Kandoth, Noufal, Miguel Claros, Nuria Rodriguez, and Julio Lloret-Fillol. "Photoinduced Electron-Transfer in First-Row Transition Metal Complexes." In Springer Handbook of Inorganic Photochemistry. Springer International Publishing, 2022. http://dx.doi.org/10.1007/978-3-030-63713-2_20.

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Marusak, Rosemary A., Thomas P. Shields, and A. Graham Lappin. "Chiral Recognition by Metal-Ion Complexes in Electron-Transfer Reactions." In Electron Transfer in Biology and the Solid State. American Chemical Society, 1989. http://dx.doi.org/10.1021/ba-1990-0226.ch013.

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Scandola, F., R. Argazzi, C. A. Bignozzi, C. Chiorboli, M. T. Indelli, and M. A. Rampi. "Antenna Effects and Photoinduced Electron Transfer in Polynuclear Metal Complexes." In Supramolecular Chemistry. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2492-8_15.

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Jørgensen, Karl Anker. "On the Electronic Structure of Oxo-Metalloporphyrins and Mechanistic Aspects of Oxygen-Transfer Reactions." In Catalysis by Metal Complexes. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-017-2247-6_7.

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Conference papers on the topic "Metal Complexes - Electron Transfer"

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Stoutland, Page O., Stephen K. Doom, R. Brian Dyer, and William H. Woodruff. "Ultrafast Vibrational Energy Relaxation in [(NC)5MIICNMIII(NH3)5]1-(M = Ru, Os) Studied by Picosecond Infrared Spectroscopy." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1994. http://dx.doi.org/10.1364/up.1994.thd.13.

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Mixed-valence transition metal complexes have long been used to study electron transfer reactions due to the availability of well-defined complexes with favorable spectroscopic properties.1 These studies have resulted in a plethora of information concerning the fundamental aspects of electron transfer reactions. We have recently used complexes of this type to investigate ultrafast electron transfer and vibrational energy relaxation dynamics in cyanide-bridged mixed-valence transition metal dimers. These studies have allowed us to observe, for the first time in the solution phase, the vibration
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Nagamura, T., H. Kawai, T. Ichihara, and H. Sakaguchi. "Photoinduced electron transfer and charge resonance band in ion-pair charge-transfer complexes of styrylpyridinium tetraphenylborate." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835503.

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Kliner, D. A. V., K. Tominaga, and P. F. Barbara. "Ultrafast Studies on Intervalence Charge Transfera." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/up.1992.mc13.

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Mixed-valence metal complexes have played a central role in the development of the theory of electron-transfer (ET) reactions.1 These compounds contain two metal atoms in different oxidation states, typically +2 and +3. An absorption band is often observed in the near IR or visible, corresponding to the transfer of an electron between the two metal centers. Much theoretical work has addressed the connection between this photoinduced charge transfer and the analogous thermal ET reaction.
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Dyer, R. Brian, Kristen A. Peterson, Keith C. Gordon, et al. "Picosecond Infrared Study of Intramolecular Energy Transfer in [(phen)(CO)3ReI(NC)RuII(CN)(bpy)2]+." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/up.1992.tuc12.

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Significant advances have been made in the design and characterization of molecular assemblies which, upon photoexcitation, undergo intramolecular electron or energy transfer.1 These reactions have typically been followed by transient electronic absorption spectroscopy. This technique, however, suffers from the disadvantage that absorption bands tend to be broad and featureless which can lead to ambiguous interpretation in complex assemblies, especially where there is more than one absorbing chromophore. Time-resolved resonance Raman spectroscopy has been applied to the study of excited states
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Marciu, D., C. Figura, S. Wang, et al. "Enhanced Degenerate Four-Wave Mixing in an Endohedral Metallofullerene Through Metal-to-Cage Charge-Transfer." In Organic Thin Films for Photonic Applications. Optica Publishing Group, 1997. http://dx.doi.org/10.1364/otfa.1997.the.15.

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Since the initial discovery and development of a technique for macroscopic preparation of the archetypal and most abundant fullerene C60, a wealth of fullerene-based structures have been produced including higher fullerenes, charge-transfer complexes, fullerene derivatives, superconducting exohedral-doped fullerenes, and carbon nanotubes. One of the most intriguing fullerene classes is the endohedral fullerene in which the spheroidal molecular structure is employed to encapsulate a small number of atoms (one to four) internal to the cage.1,2 Until recently, the difficult separation process of
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Rovira, C., J. Veciana, J. Tarres, et al. "Towards tridimensional organic metals. synthesis and study of mlrlti sulfur /spl pi/-electron donors and their charge transfer complexes and salts." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835659.

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Greve, Daniel R., Tommy Geisler, Thomas Bjørnholm, and Jan C. Petersen. "Third-Order Nonlinear Optical Effects in Organic Nickel Complexes and Triarylmethyl Cations." In Organic Thin Films for Photonic Applications. Optica Publishing Group, 1995. http://dx.doi.org/10.1364/otfa.1995.md.23.

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The second molecular hyperpolarizability, γ, has been determined at 1064 nm by Third- Harmonic Generation (THG) using the Maker fringe technique, for a family of triarylmethyl cations and for a familiy of organic Nickel complexes as guests in PMMA thin films. For the metal complexes it is a well established notion that the low-lying transition with ligand to metal charge transfer character is important for the nonlinear optical properties(1). However, ambiguity arises due to large discrepancies between different measurements(2-5), as well as difficulties in assessing the exact contribution to
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Hormann, A., E. J. C. Olson, P. F. Barbara, et al. "Time Resolved Electron Transfer Studies Between Metallointercalators in DNA." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1996. http://dx.doi.org/10.1364/up.1996.sab.6.

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This paper reports the first ultrafast studies on the rates of DNA-mediated forward and reverse electron transfer between photoexcited [M(phen)2dppz]2+ (M=Ru or Os, phen =1,10-phenanthroline, dppz = dipyrido[3,2:a-2′,3′:c]-phenazine) and various electron acceptors in order to ultimately determine the distance dependence of electron transfer kinetics with DNA as an environment.1,2 Previously Barton, Turro, and coworkers have presented evidence that electron transfer in DNA can occur rapidly over an extraordinarily large distance3 with a more shallow distance dependence than that for other media
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WATSON, DAVID F., ANDREW B. BOCARSLY, and ELMAR SCHREIBER. "PUMP-PROBE SPECTROSCOPY OF A TRINUCLEAR TRANSITION METAL MIXED-VALENCE COMPLEX: SOLVENT DEPENDENCE OF BACK ELECTRON TRANSFER RATE." In With Foreword by Prof A H Zewail, Nobel Laureate in Chemistry, 1999. WORLD SCIENTIFIC, 2002. http://dx.doi.org/10.1142/9789812777980_0064.

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Eom, Hyo Soon, Cheon Min Kim, Sae Chae Jeoung, and Dongho Kim. "Ultrafast Vibrational Relaxation and Ligand Photodissociation/Photoassociation Processes of Nickel(II) Porphyrins." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1996. http://dx.doi.org/10.1364/up.1996.fe.54.

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The nickel(II) porphyrins have been well suited for an ideal system for investigating electronic decay, axial ligand photodissociation and photoassociation dynamics.1Of great significance in governing photophysics of the four- and six-coordinate nickel(II) complexes is the presence of a low-lying metal excited (dz2,dx2−y2) state having ~250 ps lifetme below porphyrin ring (π,π*) states.1 The (d,d) excited state shows characteristic sharply featured absorption difference spectra, compared to the broader featured more diffuse spectra of the ring (π,π*) and metal⇔ring charge transfer excited stat
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Reports on the topic "Metal Complexes - Electron Transfer"

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Matsunaga, P. T. Bis(pentamethylcyclopentadienyl) ytterbium: Electron-transfer reactions with organotransition metal complexes. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/5698904.

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Matsunaga, Phillip Thomas. Bis(pentamethylcyclopentadienyl) ytterbium: Electron-transfer reactions with organotransition metal complexes. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/10132965.

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Schmehl, Russell H. Energy, Electron Transfer and Photocatalytic Reactions of Visible Light Absorbing Transition Metal Complexes. Office of Scientific and Technical Information (OSTI), 2016. http://dx.doi.org/10.2172/1240023.

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Isied, Stephan S. Transition Metal Donor-Peptide-Acceptor Complexes: From Intramolecular Electron Transfer Reactions to the Study of Reactive Intermediates. Office of Scientific and Technical Information (OSTI), 2003. http://dx.doi.org/10.2172/899301.

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Atwood, J. D. Group transfer and electron transfer reactions of organometallic complexes. Office of Scientific and Technical Information (OSTI), 1994. http://dx.doi.org/10.2172/10105478.

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Peterson, J. D. Intramolecular energy- and electron-transfer reactions in polymetallic complexes. Annual report. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/34192.

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Mukamel, Shaul. Nonlinear Ultrafast Spectroscopy of Electron and Energy Transfer in Molecule Complexes. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/875998.

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Atwood, J. (Comparison of group transfer, inner sphere and outer sphere electron transfer mechanisms of organometallic complexes). Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6286368.

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Nesterov, Alexander, and Gennady Berman. The Role of Protein Fluctuation Correlations in Electron Transfer in Photosynthetic Complexes. Office of Scientific and Technical Information (OSTI), 2014. http://dx.doi.org/10.2172/1164449.

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Bataineh, Hajem. Solvento iron(IV) oxo complexes in catalytic oxidations and electron transfer reactions. Office of Scientific and Technical Information (OSTI), 2015. http://dx.doi.org/10.2172/1417989.

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