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Journal articles on the topic 'Metal Complexes - Electron Transfer'

Author: Grafiati

Published: 4 June 2021

Last updated: 7 September 2023

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1

Shirai, Hirofusa, and Okikazu Hirabara. "Electron transfer in macromolecule-metal complexes." Kobunshi 38, no. 6 (1989): 436–39. http://dx.doi.org/10.1295/kobunshi.38.436.

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2

Ciarrocchi, Carlo, Guido Colucci, Massimo Boiocchi, et al. "Interligand Charge-Transfer Processes in Zinc Complexes." Chemistry 4, no. 3 (2022): 717–34. http://dx.doi.org/10.3390/chemistry4030051.

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Electron donor–acceptor (EDA) complexes are characterized by charge-transfer (CT) processes between electron-rich and electron-poor counterparts, typically resulting in a new absorption band at a higher wavelength. In this paper, we report a series of novel 2,6-di(imino)pyridine ligands with different electron-rich aromatic substituents and their 1:2 (metal/ligand) complexes with zinc(II) in which the formation of a CT species is promoted by the metal ion coordination. The absorption properties of these complexes were studied, showing the presence of a CT absorption band only in the case of ar

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3

Devi, Tarali, Yong-Min Lee, Wonwoo Nam, and Shunichi Fukuzumi. "Metal ion-coupled electron-transfer reactions of metal-oxygen complexes." Coordination Chemistry Reviews 410 (May 2020): 213219. http://dx.doi.org/10.1016/j.ccr.2020.213219.

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4

Wenger, Oliver S. "Proton-Coupled Electron Transfer with Photoexcited Metal Complexes." Accounts of Chemical Research 46, no. 7 (2013): 1517–26. http://dx.doi.org/10.1021/ar300289x.

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5

Cho, K. C., P. M. Cham, and C. M. Che. "Kinetics of electron transfer between metal hexacyanide complexes." Chemical Physics Letters 168, no. 3-4 (1990): 361–64. http://dx.doi.org/10.1016/0009-2614(90)85625-m.

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6

Ishizuka, Tomoya, Shunichi Fukuzumi, and Takahiko Kojima. "Molecular assemblies based on strong axial coordination in metal complexes of saddle-distorted dodecaphenylporphyrins." Journal of Porphyrins and Phthalocyanines 19, no. 01-03 (2015): 32–44. http://dx.doi.org/10.1142/s1088424615500273.

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In this mini-review, we have highlighted our works on metal complexes having saddle-distorted dodecaphenylporphyrin (DPP) and its derivative as ligands in the light of enhancement of the Lewis acidity of a metal center coordinated by the porphyrin. The important point through this mini-review is ill-overlap of the out-of-plane lone pairs of pyrrole nitrogen atoms with σ-orbitals of the metal center bound to the saddle-distorted porphyrin core. The enhanced Lewis acidity of the central metal ions enabled us to construct stable molecular complexes through axial coordination using metal–DPP (M(DP

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7

Bley-Escrich, Jordi, Serguei Prikhodovski, Carsten D. Brandt, Martin Bröring, and Jean-Paul Gisselbrecht. "Electrochemical investigations of tripyrrin complexes." Journal of Porphyrins and Phthalocyanines 07, no. 04 (2003): 220–26. http://dx.doi.org/10.1142/s1088424603000306.

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Electrochemical investigations on divalent transition metal complexes with a conjugated linear tripyrrole ligand, namely 3,4,8,9,13,14-hexaethyl-2,15-dimethyltripyrrin (HTrpy) are reported. This tripyrrin ligand behaves as a tridentate monoanionic ligand and forms a series of neutral metal complexes of the type TrpyMX, where M = Zn ( II ), Cu ( II ), Ni ( II ) Co ( II ) or Pd ( II ) and X is a chloride anion ( Cl -). The studied nickel, cobalt and zinc complexes undergo respectively three and two ligand-centered reversible one-electron reductions and a reversible ligand-centered one-electron o

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8

Vogler, A., A. H. Osman, and H. Kunkely. "Heterobinuclear transition-metal complexes. Synthesis and optical metal to metal electron transfer." Inorganic Chemistry 26, no. 14 (1987): 2337–40. http://dx.doi.org/10.1021/ic00261a035.

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9

Purugganan, MD, CV Kumar, NJ Turro, and JK Barton. "Accelerated electron transfer between metal complexes mediated by DNA." Science 241, no. 4873 (1988): 1645–49. http://dx.doi.org/10.1126/science.241.4873.1645.

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10

Purugganan, M., C. Kumar, N. Turro, and J. Barton. "Accelerated electron transfer between metal complexes mediated by DNA." Science 241, no. 4873 (1988): 1645–49. http://dx.doi.org/10.1126/science.3420416.

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11

Song, Wenjing, Arkady Ellern, and Andreja Bakac. "Electron-Transfer Reactions of Nitrosyl and Superoxo Metal Complexes." Inorganic Chemistry 47, no. 18 (2008): 8405–11. http://dx.doi.org/10.1021/ic800867j.

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12

Fukuzumi, Shunichi. "Electron-transfer properties of high-valent metal-oxo complexes." Coordination Chemistry Reviews 257, no. 9-10 (2013): 1564–75. http://dx.doi.org/10.1016/j.ccr.2012.07.021.

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13

Lappin, A. Graham, and Rosemary A. Marusak. "Stereoselectivity in electron transfer reactions involving metal ion complexes." Coordination Chemistry Reviews 109, no. 1 (1991): 125–80. http://dx.doi.org/10.1016/0010-8545(91)80004-w.

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14

FUKUZUMI, SHUNICHI. "Electron transfer chemistry of metalloporphyrins and related metal complexes." Journal of Porphyrins and Phthalocyanines (JPP) 04, no. 04 (2000): 398–400. http://dx.doi.org/10.1002/(sici)1099-1409(200006/07)4:4<398::aid-jpp226>3.0.co;2-#.

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15

Fukuzumi, Shunichi. "Electron transfer chemistry of metalloporphyrins and related metal complexes." Journal of Porphyrins and Phthalocyanines 4, no. 4 (2000): 398–400. http://dx.doi.org/10.1002/(sici)1099-1409(200006/07)4:4<398::aid-jpp226>3.3.co;2-r.

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16

Sasmal, Ashok, Eugenio Garribba, Carlos J. Gómez-García, Cédric Desplanches, and Samiran Mitra. "Switching and redox isomerism in first-row transition metal complexes containing redox active Schiff base ligands." Dalton Trans. 43, no. 42 (2014): 15958–67. http://dx.doi.org/10.1039/c4dt01699h.

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Switching and redox isomerism in first row transition metal complexes through the metal-to-ligand or ligand-to-ligand electron transfer stabilize redox isomeric forms in transition metal complexes with redox-active ligands.

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17

Nadurata, Vincent L., and Colette Boskovic. "Switching metal complexes via intramolecular electron transfer: connections with solvatochromism." Inorganic Chemistry Frontiers 8, no. 7 (2021): 1840–64. http://dx.doi.org/10.1039/d0qi01490g.

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18

Fukuzumi, Shunichi. "Electron transfer and catalysis with high-valent metal-oxo complexes." Dalton Transactions 44, no. 15 (2015): 6696–705. http://dx.doi.org/10.1039/c5dt00204d.

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19

Sawyer, Donald T. "Electron transfer in the electrochemistry of metals, metal compounds and metal complexes." Inorganica Chimica Acta 226, no. 1-2 (1994): 99–108. http://dx.doi.org/10.1016/0020-1693(94)04075-3.

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20

Mavroyannis, Constantine. "Charge transfer electron–exciton complexes in single crystals." Canadian Journal of Chemistry 63, no. 7 (1985): 1345–48. http://dx.doi.org/10.1139/v85-229.

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We have considered the excitation spectrum arising from the coherent electron–exciton pairing in crystals at low temperatures. For the pairing processes, three different types of excitons have been considered: Frenkel excitons (tightly bound), Wannier–Mott excitons (loosely bound), and excitons of the intermediate binding. Expressions for the gap functions and transition temperatures at which metal-to-nonmetal phase transitions occur have been derived and discussed for each type of pairing. In the electron pairing with the intermediate exciton, the dispersion relations which determine the exci

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21

Rajagopal, S., C. Srinivasan, and G. Allen Gnanaraj. "Nonadiabaticity in the photoinduced electron transfer reactions of metal complexes." Proceedings / Indian Academy of Sciences 106, no. 3 (1994): 645–53. http://dx.doi.org/10.1007/bf02911095.

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22

Carlin, Richard T., Paul C. Trulove, Robert A. Mantz, John J. O'Dea, and Robert A. Osteryoung. "Electron transfer kinetics for weakly bonded, labile metal–ligand complexes." J. Chem. Soc., Faraday Trans. 92, no. 20 (1996): 3969–73. http://dx.doi.org/10.1039/ft9969203969.

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23

Willner, Itamar, Evgeny Kaganer, Ernesto Joselevich, et al. "Photoinduced electron transfer in supramolecular assemblies of transition metal complexes." Coordination Chemistry Reviews 171 (April 1998): 261–85. http://dx.doi.org/10.1016/s0010-8545(98)90041-8.

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24

Kojima, Takahiko. "Study on Proton-Coupled Electron Transfer in Transition Metal Complexes." Bulletin of the Chemical Society of Japan 93, no. 12 (2020): 1571–82. http://dx.doi.org/10.1246/bcsj.20200213.

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25

Endicott, John F., Xiaoqing Song, Murielle A. Watzky, and Tione Buranda. "Photoinduced electron transfer in linked transition metal donor—acceptor complexes." Journal of Photochemistry and Photobiology A: Chemistry 82, no. 1-3 (1994): 181–90. http://dx.doi.org/10.1016/1010-6030(94)02002-7.

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26

Osvath, Peter, and A. Graham Lappin. "Conformational effects in stereoselective electron transfer between metal ion complexes." Journal of the Chemical Society, Chemical Communications, no. 14 (1986): 1056. http://dx.doi.org/10.1039/c39860001056.

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27

Formosinho, S. J. "Electron transfer reactions in coordination metal complexes. Structure-reactivity relationships." Pure and Applied Chemistry 61, no. 5 (1989): 891–96. http://dx.doi.org/10.1351/pac198961050891.

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28

Vlcek Antonin, Jr. "ChemInform Abstract: Electron-Transfer Processes in Mononuclear Polypyridine Metal Complexes." ChemInform 33, no. 49 (2010): no. http://dx.doi.org/10.1002/chin.200249261.

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29

Fedoseeva, Marina, Milan Delor, Simon C. Parker, et al. "Vibrational energy transfer dynamics in ruthenium polypyridine transition metal complexes." Physical Chemistry Chemical Physics 17, no. 3 (2015): 1688–96. http://dx.doi.org/10.1039/c4cp04166f.

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Understanding vibrational energy propagation pathways during and following electron transfer in transition metal complexes, which are of interest for solar cell applications, can provide new insights on the interplay between electronic and vibrational movement within the molecule.

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30

de Aguirre, Adiran, Ignacio Funes-Ardoiz, and Feliu Maseras. "Computational Characterization of Single-Electron Transfer Steps in Water Oxidation." Inorganics 7, no. 3 (2019): 32. http://dx.doi.org/10.3390/inorganics7030032.

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The presence of single-electron transfer (SET) steps in water oxidation processes catalyzed by first-row transition metal complexes has been recently recognized, but the computational characterization of this type of process is not trivial. We report a systematic theoretical study based on density functional theory (DFT) calculations on the reactivity of a specific copper complex active in water oxidation that reacts through two consecutive single-electron transfers. Both inner-sphere (through transition state location) and outer-sphere (through Marcus theory) mechanisms are analyzed. The firs

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31

Pierpont, C. G., S. K. Larsen, and S. R. Boone. "Transition metal complexes containing quinone ligands: studies on intramolecular metal-ligand electron transfer." Pure and Applied Chemistry 60, no. 8 (1988): 1331–36. http://dx.doi.org/10.1351/pac198860081331.

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32

Kojima, Takahiko. "Development of functionality of metal complexes based on proton-coupled electron transfer." Dalton Transactions 49, no. 22 (2020): 7284–93. http://dx.doi.org/10.1039/d0dt00898b.

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Proton-coupled electron transfer (PCET) is ubiquitous and fundamental in many kinds of redox reactions. In this paper, are described PCET reactions in metal complexes to highlight their useful and unique properties and functionalities.

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33

Zhu, Chen, Serik Zhumagazy, Huifeng Yue, and Magnus Rueping. "Metal-free C–Se cross-coupling enabled by photoinduced inter-molecular charge transfer." Chemical Communications 58, no. 1 (2022): 96–99. http://dx.doi.org/10.1039/d1cc06152f.

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34

Xia, Bin, Yu Zhou, Qing-Lun Wang, et al. "Photoinduced electron transfer and remarkable enhancement of magnetic susceptibility in bridging pyrazine complexes." Dalton Transactions 47, no. 44 (2018): 15888–96. http://dx.doi.org/10.1039/c8dt03422b.

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35

Zhou, Meng, Chenjie Zeng, Qi Li, Tatsuya Higaki, and Rongchao Jin. "Gold Nanoclusters: Bridging Gold Complexes and Plasmonic Nanoparticles in Photophysical Properties." Nanomaterials 9, no. 7 (2019): 933. http://dx.doi.org/10.3390/nano9070933.

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Recent advances in the determination of crystal structures and studies of optical properties of gold nanoclusters in the size range from tens to hundreds of gold atoms have started to reveal the grand evolution from gold complexes to nanoclusters and further to plasmonic nanoparticles. However, a detailed comparison of their photophysical properties is still lacking. Here, we compared the excited state behaviors of gold complexes, nanolcusters, and plasmonic nanoparticles, as well as small organic molecules by choosing four typical examples including the Au10 complex, Au25 nanocluster (1 nm me

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36

Shankar Kumar, Ch Ravi, S. Deepthi, and Anjali Jha. "Charge Transfer Interactions of p-Azoxyanisole Complexes for Electrooptical Activity." Asian Journal of Chemistry 32, no. 7 (2020): 1603–8. http://dx.doi.org/10.14233/ajchem.2020.22624.

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In particular interactions due to organic-inorganic molecules results self assembled structures organize supramolecular structures for molecular, electronic and electrooptical properties. Supramolecular structures originated are complexes with organic (p-azoxyanisole) molecule, synthesized with metal nanoparticles (iron, copper and aluminium.) Spectroscopic studies interpret infrared spectra with wavenumbers of characteristic bands in assigned regions; wavenumbers with reduced intensity in Raman spectra attribute metal-organic framework with charge transfer. Designed frame work with dense part

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37

Edwards, Marcus J., Gaye F. White, Colin W. Lockwood, et al. "Structural modeling of an outer membrane electron conduit from a metal-reducing bacterium suggests electron transfer via periplasmic redox partners." Journal of Biological Chemistry 293, no. 21 (2018): 8103–12. http://dx.doi.org/10.1074/jbc.ra118.001850.

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Many subsurface microorganisms couple their metabolism to the reduction or oxidation of extracellular substrates. For example, anaerobic mineral-respiring bacteria can use external metal oxides as terminal electron acceptors during respiration. Porin–cytochrome complexes facilitate the movement of electrons generated through intracellular catabolic processes across the bacterial outer membrane to these terminal electron acceptors. In the mineral-reducing model bacterium Shewanella oneidensis MR-1, this complex is composed of two decaheme cytochromes (MtrA and MtrC) and an outer-membrane β-barr

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38

Loukova, Galina V., and Vladimir V. Strelets. "A Review on Molecular Electrochemistry of Metallocene Dichloride and Dimethyl Complexes of Group 4 Metals: Redox Properties and Relation with Optical Ligand-to-Metal Charge Transfer Transitions." Collection of Czechoslovak Chemical Communications 66, no. 2 (2001): 185–206. http://dx.doi.org/10.1135/cccc20010185.

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Emphasis is given to redox, photophysical, and photochemical properties of homologous bent metallocenes of group 4 transition metals. Comparative analysis of a variety of electron-transfer induced transformations and ligand-to-metal charge-transfer excited states is performed for bent metallocene complexes upon systematic variation of the identity of the metal ion (Ti, Zr or Hf), ancillary π- and monodentate σ- (Cl, Me) ligands. For such organometallic π-complexes, linear correlations exist between energies of optical and redox HOMO-to-LUMO electron transitions. It is suggested that combinatio

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39

Nielsen, Kim T., Pernille Harris, Klaus Bechgaard, and Frederik C. Krebs. "Structural study of four complexes of the M-N2S2 type derived from diethylphenylazothioformamide and the metals palladium, platinum, copper and nickel." Acta Crystallographica Section B Structural Science 63, no. 1 (2007): 151–56. http://dx.doi.org/10.1107/s0108768106047306.

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The four electron-transfer complexes trans-(di(N,N-diethyl-(2-phenyldiazenyl)thioformamide-κS,κN 2))nickel, trans-(di(N,N-diethyl-(2-phenyldiazenyl)thioformamide-κS,κN 2))copper, trans-(di(N,N-diethyl-(2-phenyldiazenyl)thioformamide-κS,κN 2))palladium and trans-(di(N,N-diethyl-(2-phenyldiazenyl)thioformamide-κS,κN 2))platinum have been crystallized, and their structures have been determined at low temperature. All the complexes are of the M-N2S2 type. The crystals of both the nickel and the copper complex belong to the tetragonal P41212 system, in which the central metal ion lies on a twofold

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40

Wenger, Oliver S. "Photoinduced Electron and Proton Transfer with Metal Complexes and Organic Molecules." CHIMIA International Journal for Chemistry 67, no. 5 (2013): 337–39. http://dx.doi.org/10.2533/chimia.2013.337.

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41

Orman, L. K., Y. J. Chang, D. R. Anderson, et al. "Picosecond Raman investigations of interligand electron transfer in transition metal complexes." Journal of Chemical Physics 90, no. 3 (1989): 1469–77. http://dx.doi.org/10.1063/1.456089.

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42

Suzuki, Masahiro, Satoshi Kobayashi, Toshiki Koyama, et al. "Kinetics of intra-polymer electron-transfer reactions in macromolecule–metal complexes." J. Chem. Soc., Faraday Trans. 91, no. 17 (1995): 2877–80. http://dx.doi.org/10.1039/ft9959102877.

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43

Grechnikov, A. A., V. Georgieva, A. S. Borodkov, et al. "Laser-induced electron transfer desorption/ionization of metal complexes on TiO2films." Journal of Physics: Conference Series 558 (December 3, 2014): 012035. http://dx.doi.org/10.1088/1742-6596/558/1/012035.

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44

Fukuzumi, Shunichi, Hideki Ohtsu, Kei Ohkubo, Shinobu Itoh, and Hiroshi Imahori. "Formation of superoxide–metal ion complexes and the electron transfer catalysis." Coordination Chemistry Reviews 226, no. 1-2 (2002): 71–80. http://dx.doi.org/10.1016/s0010-8545(01)00435-0.

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45

Bernauer, Klaus, Simona Ghizdavu, and Luca Verardo. "Chiral metal complexes as probes in electron-transfer reactions involving metalloproteins." Coordination Chemistry Reviews 190-192 (September 1999): 357–69. http://dx.doi.org/10.1016/s0010-8545(99)00094-6.

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46

Goldman, Alan S., and David R. Tyler. "Photochemically initiated electron transfer catalyzed substitution reactions of metal carbonyl complexes." Inorganica Chimica Acta 98, no. 2 (1985): L47—L48. http://dx.doi.org/10.1016/s0020-1693(00)84912-9.

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47

Akibo-Betts, Glen, Perdita E. Barran, and Anthony J. Stace. "Cluster-to-metal electron transfer in [Mn·(pyridine)n]2+ complexes." Chemical Physics Letters 329, no. 5-6 (2000): 431–36. http://dx.doi.org/10.1016/s0009-2614(00)01036-8.

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48

Dennany, Lynn, Gordon G. Wallace, and Robert J. Forster. "Luminescent Metal Complexes within Polyelectrolyte Layers: Tuning Electron and Energy Transfer†." Langmuir 25, no. 24 (2009): 14053–60. http://dx.doi.org/10.1021/la901661v.

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49

Miller, Stephen A., and Andrew M. Moran. "Nonlinear Optical Detection of Electron Transfer Adiabaticity in Metal Polypyridyl Complexes." Journal of Physical Chemistry A 114, no. 5 (2010): 2117–26. http://dx.doi.org/10.1021/jp9092145.

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50

Wherland, Scot. "Non-aqueous, outer-sphere electron transfer kinetics of transition metal complexes." Coordination Chemistry Reviews 123, no. 1-2 (1993): 169–99. http://dx.doi.org/10.1016/0010-8545(93)85055-9.

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