Academic literature on the topic 'Metal nitrosyl complexes'

Create a spot-on reference in APA, MLA, Chicago, Harvard, and other styles

Select a source type:

Consult the lists of relevant articles, books, theses, conference reports, and other scholarly sources on the topic 'Metal nitrosyl complexes.'

Next to every source in the list of references, there is an 'Add to bibliography' button. Press on it, and we will generate automatically the bibliographic reference to the chosen work in the citation style you need: APA, MLA, Harvard, Chicago, Vancouver, etc.

You can also download the full text of the academic publication as pdf and read online its abstract whenever available in the metadata.

Journal articles on the topic "Metal nitrosyl complexes"

1

Ford, Peter C. "Photochemical reactions of metal nitrosyl complexes. Mechanisms of NO reactions with biologically relevant metal centers." International Journal of Photoenergy 3, no. 3 (2001): 161–69. http://dx.doi.org/10.1155/s1110662x01000204.

Full text
Abstract:
The discoveries that nitric oxide (a.k.a. nitrogen monoxide) serves important roles in mammalian bioregulation and immunology have stimulated intense interest in the chemistry and biochemistry of NO and derivatives such as metal nitrosyl complexes. Also of interest are strategies to deliver NO to biological targets on demand. One such strategy would be to employ a precursor which displays relatively low thermal reactivity but is photochemically active to release NO. This proposition led us to investigate laser flash and continuous photolysis kinetics of nitrosyl complexes such as the Roussin's
APA, Harvard, Vancouver, ISO, and other styles
2

Ashok, R. F. N., M. Gupta, K. S. Arulsamy та U. C. Agarwala. "Cyclopentadienyl ruthenium complexes. Part III. Reactivity of some η5-cyclopentadienylbis(triphenylphosphine)ruthenium(II) complexes with nitrosyl tribromide and dinitrogen trioxide". Canadian Journal of Chemistry 63, № 4 (1985): 963–70. http://dx.doi.org/10.1139/v85-160.

Full text
Abstract:
Mixed ruthenium(II) nitrosyls have been synthesized in yields larger than 60% by a general reaction of [Ru(η5-C5H5)(PPh3)L]+X− (L = 2,2′-bipyridine or 1,10-phenanthroline, X = Cl or Br) or [Ru(η5-C5,H5)(PPh3)(L)X] (L = PPh3, pyridine, 3-picoline, 4-picoline, [Formula: see text], or [Formula: see text]; X− = Cl−, Br−, I−, CN−, NCS−, H−, or SnCl3−) with NOBr3 and N2O3. In these complexes NO seems to bind with the metal ion as NO+. The reactions of N2O3 gave either nitrito or nitrosyl dinitrito complexes. The reactions of NOBr3 with trichlorostannate complexes did not yield nitrosyl complexes, in
APA, Harvard, Vancouver, ISO, and other styles
3

Metzker, Gustavo, Inara de Aguiar, Maykon Lima Souza, Daniel Rodrigues Cardoso, and Douglas Wagner Franco. "Reaction of ruthenium(II) complexes with 2,2-diphenyl-1-picrylhydrazyl (DPPH•) and hydroxyl radicals." Canadian Journal of Chemistry 92, no. 8 (2014): 788–93. http://dx.doi.org/10.1139/cjc-2014-0082.

Full text
Abstract:
The reaction of the complexes trans-[RuII(NO+)(NH3)4L] and [RuII(NO+)HEDTA] with 2,2-diphenyl-1-picrylhydrazyl (DPPH•) and hydroxyl (OH•) radicals has been investigated at 25.0 ± 0.1 °C using spectroscopic (UV-vis and electron paramagnetic resonance) and electrochemical techniques (differential pulse voltammetry and cyclic voltammetry). The redox potential of RuIII/RuII for the ruthenium nitrosyl complexes was determined and is in the range of +2.2 V (L = HEDTA) to +2.6 V (L = isn) versus the normal hydrogen electrode . The trans-[RuII(NO+)(NH3)4L]3+ and [RuII(NO+)HEDTA] complexes do not react
APA, Harvard, Vancouver, ISO, and other styles
4

Gäggeler, Heinz W., Ilya Usoltsev, and Robert Eichler. "Reactions of fission products from a 252Cf source with NO and mixtures of NO and CO in an inert gas." Radiochimica Acta 107, no. 7 (2019): 555–60. http://dx.doi.org/10.1515/ract-2018-3076.

Full text
Abstract:
Abstract Fission products recoiling from a 252Cf spontaneous fission source were stopped in various mixtures of inert gases containing CO and NO. For the elements of the transisition metal series Mo, Tc, Ru, and Rh previous observations of pure carbonyl complexes were reproduced. However, no formation of volatile mixed nitrosyl-carbonyl complexes or pure nitrosyl complexes for these elements have been observed. Instead, efficient production of volatile nitrosyl compounds for single iodine atoms, presumably nitrosyl iodide, NOI, was detected. This observation is of interest as potential transpo
APA, Harvard, Vancouver, ISO, and other styles
5

Li, Lijuan, and Linlin Li. "Recent advances in multinuclear metal nitrosyl complexes." Coordination Chemistry Reviews 306 (January 2016): 678–700. http://dx.doi.org/10.1016/j.ccr.2015.03.026.

Full text
APA, Harvard, Vancouver, ISO, and other styles
6

Heilman, Brandon, and Pradip K. Mascharak. "Light-triggered nitric oxide delivery to malignant sites and infection." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 371, no. 1995 (2013): 20120368. http://dx.doi.org/10.1098/rsta.2012.0368.

Full text
Abstract:
The discovery of nitric oxide (NO) as a signalling molecule in various physiological and pathological pathways has spurred research in the design of exogenous NO donors as drugs. In recent years, metal nitrosyls (NO complexes of metals) have been investigated as NO-donating agents. Results from our laboratory during the past few years have demonstrated that metal nitrosyls derived from designed ligands can deliver NO under the total control of light of various frequencies. Careful incorporation of these photoactive nitrosyls into polymer matrices has afforded a set of nitrosyl–polymer composit
APA, Harvard, Vancouver, ISO, and other styles
7

Mayer, Tobias, and Hans-Christian Böttcher. "Protonation of metal–metal bonds in nitrosyl-bridged diruthenium complexes." Polyhedron 69 (February 2014): 240–43. http://dx.doi.org/10.1016/j.poly.2013.12.009.

Full text
APA, Harvard, Vancouver, ISO, and other styles
8

Daniel, Chantal, and Christophe Gourlaouen. "Structural and Optical Properties of Metal-Nitrosyl Complexes." Molecules 24, no. 20 (2019): 3638. http://dx.doi.org/10.3390/molecules24203638.

Full text
Abstract:
The electronic, structural and optical properties (including Spin–Orbit Coupling) of metal nitrosyl complexes [M(CN)5(NO)]2− (M = Fe, Ru or Os) are investigated by means of Density Functional Theory, TD-DFT and MS-CASPT2 based on an RASSCF wavefunction. The energy profiles connecting the N-bound (η1-N), O-bound (η1-O) and side-on (η2-NO) conformations have been computed at DFT level for the closed shell singlet electronic state. For each structure, the lowest singlet and triplet states have been optimized in order to gain insight into the energy profiles describing the conformational isomerism
APA, Harvard, Vancouver, ISO, and other styles
9

Ambach, Eberhard, та Wolfgang Beck. "Metallkomplexe mit biologisch wichtigen Liganden XXVI : Reaktionen von Bis(α-aminoacidato)platin(II)-Komplexen mit Nitrosylsalzen: Nitrosylplatin-Komplexe[xxx] + X- (X = BF4 , PF6 , SbF6 )/Metal Complexes with Biologically Important Ligands XXXVI : Reaction of Bis(α-aminoacidato) Platinum(II) Complexes with Nitrosyl Salts: Nitrosyl Platinum Complexes[xxx]+X-(X = BF4 , PF6 , SbF 6)". Zeitschrift für Naturforschung B 40, № 2 (1985): 288–91. http://dx.doi.org/10.1515/znb-1985-0224.

Full text
Abstract:
AbstractThe reactions of the glycinato, alaninato, or cyclo-leucinato chelate platinum complexes trans -[xxx] with nitrosyl salts NO+X- (X = BF4, PF6, SbF6) in acetonitrile at -20 °C give the blue nitrosyl compounds {(0N)Pt [xxx] X·nCH3CN. Nitrosation at the amino group is not observed. The spectroscopic data of the nitrosyl complexes (IR, XPE) are reported. [xxx] + PF6- reacts with lithium halides or halogens in DMF to give the platinum (IV) complexes X2Pt(NH2CH2CO2)2 (X = CI, Br, I).
APA, Harvard, Vancouver, ISO, and other styles
10

Song, Wenjing, Arkady Ellern, and Andreja Bakac. "Electron-Transfer Reactions of Nitrosyl and Superoxo Metal Complexes." Inorganic Chemistry 47, no. 18 (2008): 8405–11. http://dx.doi.org/10.1021/ic800867j.

Full text
APA, Harvard, Vancouver, ISO, and other styles
More sources

Dissertations / Theses on the topic "Metal nitrosyl complexes"

1

Smith, Kevin Michael. "Pi-bonding and reactivity in transition metal nitrosyl complexes." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/NQ27249.pdf.

Full text
APA, Harvard, Vancouver, ISO, and other styles
2

Ansari, Nasrin. "Coordination properties of aminophosphine with first row transition metal nitrosyl complexes." Thesis, University of Ottawa (Canada), 1994. http://hdl.handle.net/10393/6862.

Full text
Abstract:
The synthesis of the new thermolabile ironnitrosylhydride complex FeH(NO)(CO)(dppf) is reported. (dppf = 1,1$\sp\prime$-bisdiphenyl phosphino-ferrocene). The facile decomposition of FeH(NO)(CO)(dppf) is interpreted in terms of a homolysis of the Fe-H bond and of a nitrosyl transfer reaction. The synthesis of the structurally characterized iron complex Fe(O=PPh$\sb2$(2-Py))$\sb3\sp2\sp+\cdot$2BF$\sb4\sp-$, by the reaction of Fe(NO)$\sb2$(THF)$\sb2\sp+$ with PPh$\sb2$(2-Py) is described. The proposed mechanism for the formation of Fe(O=PPh$\sb2$(2-Py))$\sb3\sp2\sp+\cdot$2BF$\sb4\sp-$ involves a
APA, Harvard, Vancouver, ISO, and other styles
3

Mougenot, Pierre. "Etude theorique ab initio scf et ci de complexes organometalliques binucleaires." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13025.

Full text
Abstract:
Analyse approfondie du spectre photoelectronique se(fe(c::(5)h::(5)))::(2)(no)::(2). Etude critique des resultats experimentaux anterieurs concernant le diamagnetisme suppose se(co(c::(5)h::(5)))::(2)(no)::(2). Bon accord avec l'experience dans l'etude theorique de l'etat fondamental du cation dirhodium tetraacetate dihydrate. Etude sur la nature de l'interaction metal-metal dans (v(c::(5)h::(5)))::(2) (c::(8)h::(8))
APA, Harvard, Vancouver, ISO, and other styles
4

Scheibel, Markus. "Metal-Nitrogen Multiple Bonds with Square-Planar Group 9 Transition Metal PNP Pincer Complexes." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://hdl.handle.net/11858/00-1735-0000-0023-9944-4.

Full text
APA, Harvard, Vancouver, ISO, and other styles
5

Hildreth, J. L. "Chemical and biological studies of technetium nitrosyl complexes." Thesis, Loughborough University, 1992. https://dspace.lboro.ac.uk/2134/33014.

Full text
Abstract:
A simple and widely applicable method for the synthesis of technetium nitrosyl complexes containing either [99Tc] or [99mTc] has been developed using hydroxylamine as a reducing agent. A number of readily available complexes such as [TcO4]- or [TcX6]2- (X = Cl, Br, I) may be employed as the starting material.
APA, Harvard, Vancouver, ISO, and other styles
6

Fegy, Karine. "Ingénierie de matériaux moléculaires magnétiques : complexes de radicaux libres nitronyl nitroxydes bis-bidentes ; synthèse, structure et magnétisme." Université Joseph Fourier (Grenoble ; 1971-2015), 1997. http://www.theses.fr/1997GRE10197.

Full text
Abstract:
La chimie de coordination des radicaux libres nitronyl nitroxydes est propice aux composes moleculaires magnetiques (aimants moleculaires ou transitions de spin). Cependant le caractere base de lewis faible du groupe nitroxyde >n-o limite dans de nombreux cas leur utilisation aux ions metalliques porteurs de ligands attracteurs. Pour eviter ce probleme, nous avons choisi de substituer les radicaux par des groupes donneurs. Ce travail concerne la synthese, la caracterisation structurale et l'etude des proprietes magnetiques de complexes d'ions metalliques avec les radicaux nitronyl nitroxydes p
APA, Harvard, Vancouver, ISO, and other styles
7

Sayers, Stephen F. "Synthetic investigations toward metal nitrosyl complexes." Thesis, 1996. http://hdl.handle.net/2429/6167.

Full text
Abstract:
Reaction of Cp*W(NO)(CH₂SiMe₃)Cl with AgBF4 in MeCN leads to isolation of [Cp*W(NO)(CH₂SiMe₃)(NCMe)₂]BF₄, 2.1. The reactivity of this complex is explored, in particular, the reaction of 2.1 with H₂0 which results in stepwise hydrolysis of the nitrosyl ligand. Labelling studies with D₂0 and H₂¹⁸O are performed which give some insight into the mechanism of the transformation of 2.1 to Cp*W0₂(CH₂SiMe₃) and the fate of the NO ligand. The synthesis and characterisation of a range of carboxylate-containing nitrosyl complexes of the general class Cp*W(NO)(0₂CR')X [X = CH₂SiMe₃ , CI] and attempt
APA, Harvard, Vancouver, ISO, and other styles
8

Barr, Mary E. "Syntheses and stereophysical analyses of several metal polyphosphide and triangular iron nitrosyl complexes." 1991. http://catalog.hathitrust.org/api/volumes/oclc/24358734.html.

Full text
Abstract:
Thesis (Ph. D.)--University of Wisconsin--Madison, 1991.<br>Vita. Typescript. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.
APA, Harvard, Vancouver, ISO, and other styles
9

Menglet, Dmitri. "Nitrosyl halides and bis-acetylacetonates of ruthenium and osmium : synthetic and spectro-electrochemical investigation of ligand addivity in redox-active transition metal complexes." Phd thesis, 1996. http://hdl.handle.net/1885/144252.

Full text
APA, Harvard, Vancouver, ISO, and other styles
10

Polaczek, Justyna. "NO versus HNO chemistry : studies on the formation, stability and reactivity of nitrosylcobalamin and model complexes." Praca doktorska, 2019. https://ruj.uj.edu.pl/xmlui/handle/item/74789.

Full text
APA, Harvard, Vancouver, ISO, and other styles
More sources

Book chapters on the topic "Metal nitrosyl complexes"

1

Holloway, Lauren R., and Lijuan Li. "The Preparation, Structural Characteristics, and Physical Chemical Properties of Metal-Nitrosyl Complexes." In Nitrosyl Complexes in Inorganic Chemistry, Biochemistry and Medicine II. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/430_2013_101.

Full text
APA, Harvard, Vancouver, ISO, and other styles
2

Ford, Peter C., Jose Clayston Melo Pereira, and Katrina M. Miranda. "Mechanisms of Nitric Oxide Reactions Mediated by Biologically Relevant Metal Centers." In Nitrosyl Complexes in Inorganic Chemistry, Biochemistry and Medicine II. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/430_2013_117.

Full text
APA, Harvard, Vancouver, ISO, and other styles
3

Heilman, Brandon J., Margarita A. Gonzalez, and Pradip K. Mascharak. "Photoactive Metal Nitrosyl and Carbonyl Complexes Derived from Designed Auxiliary Ligands: An Emerging Class of Photochemotherapeutics." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2014. http://dx.doi.org/10.1002/9781118792797.ch03.

Full text
APA, Harvard, Vancouver, ISO, and other styles
4

Caneschi, A., D. Gatteschi, and P. Rey. "The Chemistry and Magnetic Properties of Metal Nitronyl Nitroxide Complexes." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166406.ch6.

Full text
APA, Harvard, Vancouver, ISO, and other styles
5

Michael, D., P. Mingos, and Darren J. Sherman. "Transition Metal Nitrosyl Complexes." In Advances in Inorganic Chemistry. Elsevier, 1989. http://dx.doi.org/10.1016/s0898-8838(08)60019-7.

Full text
APA, Harvard, Vancouver, ISO, and other styles
6

Mutoh, Yuichiro. "Chalcogenocarbonyl and Chalcogenonitrosyl Metal Complexes." In Chalcogen Chemistry: Fundamentals and Applications. The Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/bk9781839167386-00027.

Full text
Abstract:
Compared to the well-known chemistry of carbonyl (CO) and thiocarbonyl (CS) as well as nitrosyl (NO) complexes of transition-metals, the chemistry of their heavier chalcogen isologues, i.e., selenocarbonyl (CSe) and tellurocarbonyl (CTe) as well as thionitrosyl (NS) and selenonitrosyl (NSe) complexes, still remain in the early stages of development. The limited availability of these heavier carbonyl and nitrosyl compounds has hampered our understanding of a series of chalcogenocarbonyl (CE; E = O, S, Se, Te) and chalcogenonitrosyl (NE; E = O, S, Se, Te) ligands. In this chapter, a comparative
APA, Harvard, Vancouver, ISO, and other styles
7

WILLIAMS, D. L. H. "Nitrosation involving metal-nitrosyl complexes." In Nitrosation Reactions and the Chemistry of Nitric Oxide. Elsevier, 2004. http://dx.doi.org/10.1016/b978-044451721-0/50010-4.

Full text
APA, Harvard, Vancouver, ISO, and other styles
8

Henderson, Richard A. "Substitution at four- coordinate sites." In The Mechanisms of Reactions at Transition Metal Sites. Oxford University Press, 1993. http://dx.doi.org/10.1093/hesc/9780198557463.003.0004.

Full text
Abstract:
This chapter refers to transition metal sites associated with a coordination number of four, focusing on substitution mechanism by looking at tetrahedral metal sites. It explains that the reactions of the coordinately saturated, tetrahedral complexes exhibit very simple kinetics—a first order dependence on the concentration of the metal complex and independence of the concentration and nature of the reacting nucleophile. The chapter reviews the interpretation of these simple kinetics in terms of a dissociative mechanism, which is further substantiated by extra kinetic parameters. The chapter m
APA, Harvard, Vancouver, ISO, and other styles
9

Bertotti, Mauro, Vânia Mori, Patrícia Zanichelli, José Carlos Toledo, and Douglas Wagner Franco. "Electrochemical and Spectrophotometric Methods for Evaluation of NO Dissociation Rate Constants from Nitrosyl Metal Complexes Activated through Reduction." In Methods in Enzymology. Elsevier, 2005. http://dx.doi.org/10.1016/s0076-6879(05)96004-7.

Full text
APA, Harvard, Vancouver, ISO, and other styles
10

"1.3: 1.3.5 Nitrosyl Complexes from Carbonyl Complexes." In Transition Metals Part 1, edited by Wolfgang A. Herrmann. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-108410.

Full text
APA, Harvard, Vancouver, ISO, and other styles
We offer discounts on all premium plans for authors whose works are included in thematic literature selections. Contact us to get a unique promo code!