Relevant bibliographies by topics / Nitrobenzene. Chemical reactions

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Academic literature on the topic 'Nitrobenzene. Chemical reactions'

Author: Grafiati
Published: 4 June 2021
Last updated: 1 February 2022

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Journal articles on the topic "Nitrobenzene. Chemical reactions"

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Woo, Mino, Lubow Maier, Steffen Tischer, Olaf Deutschmann, and Martin Wörner. "A Qualitative Numerical Study on Catalytic Hydrogenation of Nitrobenzene in Gas-Liquid Taylor Flow with Detailed Reaction Mechanism." Fluids 5, no. 4 (2020): 234. http://dx.doi.org/10.3390/fluids5040234.

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While the number of computational studies considering two-phase flows in microfluidic systems with or without mass transfer is increasing, numerical studies incorporating chemical reactions are still rare. This study aims to simulate the catalytic hydrogenation of nitrobenzene in gas-liquid Taylor flow by combining interface-resolving numerical simulations of two-phase flow and mass transfer by a volume-of-fluid method with detailed modeling of the heterogeneous chemical reaction by software package DETCHEMTM. Practically relevant physical properties are utilized for hydrodynamic and mass tran
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2

VAN der AAR, Ellen M., Tialda BOUWMAN, Jan N. M. COMMANDEUR, and Nico P. E. VERMEULEN. "Structure-activity relationships for chemical and glutathione S-transferase-catalysed glutathione conjugation reactions of a series of 2-substituted 1-chloro-4-nitrobenzenes." Biochemical Journal 320, no. 2 (1996): 531–40. http://dx.doi.org/10.1042/bj3200531.

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Glutathione S-transferases (GSTs) constitute an important class of phase II (de)toxifying enzymes, catalysing the conjugation of glutathione (GSH) with electrophilic compounds. In the present study, Km, kcat and kcat/Km values for the rat GST 1-1-, 3-3-, 4-4- and 7-7-catalysed conjugation reactions between GSH and a series of 10 different 2-substituted 1-chloro-4-nitrobenzenes, and the second-order rate constants (ks) of the corresponding base-catalysed reactions, were correlated with nine classical physicochemical parameters (electronic, steric and lipophilic) of the substituents and with 16
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Whang, Thou-Jen, Mu-Tao Hsieh, Tjaun-En Shi, and Chun-Hsiung Kuei. "UV-Irradiated Photocatalytic Degradation of Nitrobenzene by Titania Binding on Quartz Tube." International Journal of Photoenergy 2012 (2012): 1–8. http://dx.doi.org/10.1155/2012/681941.

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A new method for UV-irradiated degradation of nitrobenzene by titania photocatalysts was proposed, titania nanoparticles were coated on a quartz tube through the introduction of tetraethyl orthosilicate into the matrix. The dependence of nitrobenzene photodegradation on pH, temperature, concentration, and air feeding was discussed, and the physical properties such as the activation energy, entropy, enthalpy, adsorption constant, and rate constant were acquired by conducting the reactions in a variety of experimental conditions. The optimum efficiency of the photodegradation with the nitrobenze
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Wang, Erkang, and Yuqing Liu. "Ion transfer with the coupled chemical reactions at the water—nitrobenzene interface." Electrochimica Acta 35, no. 11-12 (1990): 1965–69. http://dx.doi.org/10.1016/0013-4686(90)87106-c.

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Chen, Xuecheng, Chao Zhang, Ryszard J. Kalenczuk, et al. "Porous nanopeapod Pd catalyst with excellent stability and efficiency." Chemical Communications 53, no. 4 (2017): 740–42. http://dx.doi.org/10.1039/c6cc08598a.

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Mesoporous peapod structured Pd@m-C/SiO<sub>2</sub> catalyst showed high efficiency and stability for the reduction of nitrobenzene by H<sub>2</sub> and NO by NH<sub>3</sub> because of its novel nanostructure rending Pd nanoparticles highly active in these chemical reactions.
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Sun, Meng, Yong Sheng Zhao, Jun Dong, and Li Li Dong. "Study on Degradation of Nitrobenzene in Groundwater by Fenton-Like Oxidation Based on Iron in Aquifer Materials." Advanced Materials Research 183-185 (January 2011): 516–21. http://dx.doi.org/10.4028/www.scientific.net/amr.183-185.516.

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Fenton and Fenton-like reactions are regarded as high efficient methods in advanced treatment of nitrobenzene wastewater but both restrained in degradation of nitrobenzene in groundwater because of the low pH condition( less than 4 ) requirement and other problems such as secondary pollution by the irons in contaminated sites. This paper reports a new Fenton-like technology combined irons extraction from aquifer materials which were found in a nitrobenzene contaminated site in China with hydrogen peroxide catalytic oxidation. The simulate experiments were conducted to investigate the oxidation
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Makrlík, Emanuel. "Chemical equilibria including particles I-, I3-, I5-, and I2 in two-phase water-nitrobenzene extraction system." Collection of Czechoslovak Chemical Communications 55, no. 11 (1990): 2602–5. http://dx.doi.org/10.1135/cccc19902602.

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General relations among thermodynamic parameters characterizing chemical equilibria with species I-, I3-, I5-, and I2 in the two-phase water-nitrobenzene extraction system have been derived. Furthermore, these relations have been used for calculating equilibrium constants K1aq(I3-) and K2aq(I5-) corresponding to homogeneous reactions I-(aq) + I2(aq) ⇄ I3-(aq) and I3-(aq) + I2(aq) ⇄ I5-(aq) proceeding in the aqueous phase of the system under study. Finally, stability of polyiodides I3- and I5- in both phases has been discussed.
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8

Fedkiw, P. S., and J. C. Chao. "Selectivity modification in electroorganic reactions by periodic current control: Electroreduction of nitrobenzene." AIChE Journal 31, no. 9 (1985): 1578–80. http://dx.doi.org/10.1002/aic.690310925.

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9

Mithaishvili, Teimuraz, René Scalla, Devi Ugrekhelidze, Benedict Tsereteli, Tinatin Sadunishvili, and George Kvesitadze. "Degradation of Aromatic Compounds in Plants Grown under Aseptic Conditions." Zeitschrift für Naturforschung C 60, no. 1-2 (2005): 97–102. http://dx.doi.org/10.1515/znc-2005-1-218.

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The aim of the work is to investigate the ability of higher plants to absorb and detoxify environmental pollutants - aromatic compounds via aromatic ring cleavage. Transformation of 14C specifically labelled benzene derivatives, [1-6-14C]-nitrobenzene, [1-6-14C]-aniline, [1-14C]- and [7-14C]-benzoic acid, in axenic seedlings of maize (Zea mays L.), kidney bean (Phaseolus vulgaris L.), pea (Pisum sativum L.) and pumpkin (Cucurbita pepo L.) were studied. After penetration in plants, the above xenobiotics are transformed by oxidative or reductive reactions, conjugation with cell endogenous compou
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Vinatoru, M., E. Bartha, F. Badea, and J. L. Luche. "Sonochemical and thermal redox reactions of triphenylmethane and triphenylmethyl carbinol in nitrobenzene." Ultrasonics Sonochemistry 5, no. 1 (1998): 27–31. http://dx.doi.org/10.1016/s1350-4177(98)00004-2.

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Book chapters on the topic "Nitrobenzene. Chemical reactions"

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Iyer, S., and C. Capellos. "Transient Photochemistry of Nitrobenzene and Nitronaphthalenes." In Advances in Chemical Reaction Dynamics. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4734-4_24.

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"The Synthesis of Carbamate from the Reductive Carbonylation of Nitrobenzene Over Pd-based Catalysts Department of Chemical Engineering, The University of Akron, Akron, OH 44325-." In Catalysis of Organic Reactions. CRC Press, 2005. http://dx.doi.org/10.1201/9781420028034-67.

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Taber, Douglass F. "Flow Chemistry: The Direct Production of Drug Metabolites." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0016.

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Several overviews of flow chemistry appeared recently. Katherine S. Elvira and Andrew J. deMello of ETH Zürich wrote (Nature Chem. 2013, 5, 905) on micro­fluidic reactor technology. D. Tyler McQuade of Florida State University and the Max Planck Institute Mühlenberg reviewed (J. Org. Chem. 2013, 78, 6384) applications and equipment. Jun-ichi Yoshida of Kyoto University focused (Chem. Commun. 2013, 49, 9896) on transformations that cannot be effected under batch condi­tions. Detlev Belder of the Universität Leipzig reported (Chem. Commun. 2013, 49, 11644) flow reactions coupled to subsequent micropreparative separations. Leroy Cronin of the University of Glasgow described (Chem. Sci. 2013, 4, 3099) combin­ing 3D printing of an apparatus and liquid handling for convenient chemical synthe­sis and purification. Many of the reactions of organic synthesis have now been adapted to flow con­ditions. We will highlight those transformations that incorporate particularly useful features. One of those is convenient handling of gaseous reagents. C. Oliver Kappe of the Karl-Franzens-University Graz generated (Angew. Chem. Int. Ed. 2013, 52, 10241) diimide in situ to reduce 1 to 2. David J. Cole-Hamilton immobilized (Angew. Chem. Int. Ed. 2013, 52, 9805) Ru DuPHOS on a heteropoly acid support, allowing the flow hydrogenation of neat 3 to 4 in high ee. Steven V. Ley of the University of Cambridge added (Org. Process Res. Dev. 2013, 17, 1183) ammonia to 5 to give the thiourea 6. Alain Favre-Réguillon of the Conservatoire National des Arts et Métiers used (Org. Lett. 2013, 15, 5978) oxygen to directly oxidize the aldehyde 7 to the car­boxylic acid 8. Professor Kappe showed (J. Org. Chem. 2013, 78, 10567) that supercritical ace­tonitrile directly converted an acid 9 to the nitrile 10. Hisao Yoshida of Nagoya University added (Chem. Commun. 2013, 49, 3793) acetonitrile to nitrobenzene 11 to give the para isomer 12 with high regioselectively. Kristin E. Price of Pfizer Groton coupled (Org. Lett. 2013, 15, 4342) 13 to 14 to give 15 with very low loading of the Pd catalyst. Andrew Livingston of Imperial College demonstrated (Org. Process Res. Dev. 2013, 17, 967) the utility of nanofiltration under flow conditions to minimize Pd levels in a Heck product.
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Conference papers on the topic "Nitrobenzene. Chemical reactions"

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Feng, Hao, Xun Zhu, Rong Chen, and Qiang Liao. "Visualization Study on Two-Phase Flow Behaviors in the Gas-Liquid-Solid Microreactor for Hydrogenation of Nitrobenzene." In ASME 2016 Fluids Engineering Division Summer Meeting collocated with the ASME 2016 Heat Transfer Summer Conference and the ASME 2016 14th International Conference on Nanochannels, Microchannels, and Minichannels. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/fedsm2016-1011.

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In this study, visualization study on the gas-liquid two phase flow characteristics in a gas-liquid-solid microchannel reactor was carried out. Palladium nanocatalyst was coated onto the polydopamine functionalized surface of the microchannel through eletroless deposition. The materials characterization results indicated that palladium nanocatalyst were well dispersed on the modified surface. The effects of both the gas and liquid flow rates as well as inlet nitrobenzene concentration on the two-phase flow characteristics were studied. The experimental results revealed that owing to the chemic
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