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Journal articles on the topic 'Nitrobenzol'

Author: Grafiati

Published: 4 June 2021

Last updated: 19 February 2022

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1

Fahmi, A., I. V. Kityk, M. Lefkir, B. Sahraoui, M. Sylla, and G. Rivoire. "Two-photon absorption in nitrobenzol." Journal of Optics A: Pure and Applied Optics 1, no. 2 (1999): 192–96. http://dx.doi.org/10.1088/1464-4258/1/2/013.

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2

Hochstrasser, Patrick, and Albert Renken. "Nitrobenzol-Herstellung bei gleichzeitiger Azeotrop-Destillation." Chemie Ingenieur Technik 59, no. 2 (1987): 172–73. http://dx.doi.org/10.1002/cite.330590233.

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3

Bundschuh, Matthias, and Doris Klingelhöfer. "Nitrobenzol: Übersicht zu einem aktuellen Störfall." Zentralblatt für Arbeitsmedizin, Arbeitsschutz und Ergonomie 63, no. 4 (2013): 232–33. http://dx.doi.org/10.1007/bf03350857.

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4

Yu, Jian Xiang, and Tai Qi Liu. "Preparation of Palladium Nano-Particles by Electrospinning and its Application in Hydrogenations." Advanced Materials Research 217-218 (March 2011): 75–78. http://dx.doi.org/10.4028/www.scientific.net/amr.217-218.75.

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a novel fibrous catalyst containing palladium nano-particles was produced via electrospinning technique. The fibrous catalyst was characterized by scanning electron microscopy and transmission electron microscopy respectively, the results showed that the diameter of fiber was about 200 nm and the palladium (Pd) particles were in the range of 30~40 nm. The catalyst was tested in hydrogenations of α-olefins, cyclohexene and nitrobenzol in ethanol at room temperature under 1 atmosphere hydrogen. The results showed that the titled catalyst had high activity in the hydrogenations of α-olefins, cycl

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5

Kricsfalussy, Zolt�n, Guenter Stammann, and Helmut Waldmann. "Reaktionskinetische Untersuchung zur Nitrobenzol-Reduktion mit Methan." Chemie Ingenieur Technik 66, no. 6 (1994): 832–34. http://dx.doi.org/10.1002/cite.330660610.

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6

Elleuch, B., Y. Ben Taarit, J. M. Basset, and J. Kervennal. "Mechanistische Aspekte der Carbonylierung von Nitrobenzol mit Rhodiumkatalysatoren." Angewandte Chemie 94, no. 9 (2006): 722–23. http://dx.doi.org/10.1002/ange.19820940927.

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7

Zavgorodnij, I., B. Thielmann, W. Kapustnik, R. Batschinskij, and I. Böckelmann. "Wirkung von Nitrobenzol auf innere Organe unter Kältebedingungen." Zentralblatt für Arbeitsmedizin, Arbeitsschutz und Ergonomie 67, no. 6 (2017): 314–20. http://dx.doi.org/10.1007/s40664-017-0217-x.

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8

Beck, Fritz, and Wolfgang Gabriel. "Heterogene Redoxkatalyse an Ti/TiO2-Kathoden – Reduktion von Nitrobenzol." Angewandte Chemie 97, no. 9 (1985): 765–67. http://dx.doi.org/10.1002/ange.19850970912.

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9

Park, Kyoung-Ho, Chan Joo Rhu, Jin Burm Kyong, and Dennis N. Kevill. "The Effect of the ortho Nitro Group in the Solvolysis of Benzyl and Benzoyl Halides." International Journal of Molecular Sciences 20, no. 16 (2019): 4026. http://dx.doi.org/10.3390/ijms20164026.

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A kinetic study was carried out on the solvolysis of o-nitrobenzyl bromide (o-isomer, 1) and p-nitrobenzyl bromide (p-isomer, 3), and o-nitrobenzoyl chloride (o-isomer, 2) in a wide range of solvents under various temperatures. In all of the solvents without aqueous fluoroalcohol, the reactions of 1 were solvolyzed at a similar rate to those observed for 3, and the reaction rates of 2 were about ten times slower than those of the previously studied p-nitrobenzoyl chloride (p-isomer, 4). For solvolysis in aqueous fluoroalcohol, the reactivity of 2 was kinetically more reactive than 4. The l/m v

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10

Utami, Dwi, Iin Narwanti, and Jumina Jumina. "SINTESIS SENYAWA ANTIMALARIA BARU TURUNAN FENANTROLIN N-(2-NITROBENZIL)-1,10-FENANTROLINIUM IODIDA DAN (1) N-(4-NITROBENZIL)-1,10-FENANTROLINIUM IODIDA." Molekul 9, no. 1 (2014): 84. http://dx.doi.org/10.20884/1.jm.2014.9.1.153.

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Malaria is a global health problem, especially in the tropics. Efforts to decrease the incidence of malaria plagued the plasmodium resistance to existing antimalarial drugs. Benzyl Phenanthrolium Iodide derivates have been proved has antimalarial activity. The aim of this study is synthesis the nitro benzyl phenanthrolium.The research that has been done was the synthesis of (1)-N-(2-nitrobenzyl) phenantrolium iodide and(1)-N-(4-nitrobenzyl)-1,10-phenantrolium iodide. Synthesis of (1)-N-(2-nitrobenzyl)-1,10-phenantrolium iodide through a two-steps reaction SN-2 is the reaction of (1)N-(2- nitro

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11

Wijaya, Yentaria Juli, R. Rinita, Felycia Edi Soetaredjo, and Suryadi Ismadji. "Adsorpsi zat organik nitrobenzene dari larutan dengan menggunakan bubuk daun intaran." Jurnal Teknik Kimia Indonesia 7, no. 3 (2018): 844. http://dx.doi.org/10.5614/jtki.2008.7.3.5.

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Nitrobenzene is one of organic compound that usually contained in industrial wastewater, which is toxic. Nitrobenzene can be found in the chemical and pesticides industry. Nitrobenzene, which also known as nitrobenzol, is dangerous organic chemical for organism because can cause death. Organic waste in aqueous solution are usually removed by adsorption. In the adsorption process, adsorbent that usually used are carbon active and organic adsorbent. Neem leaf one of organic adsorbent that effective used in the adsorption process because it has a low cost dan easy to get. In this adsorption proce

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12

Ha-Phuong, Tran, Peter Junghans, Georg Rudakoff, and Reiner Radeglia. "Berechnung thermodynamischer Funktionen aus NMR-Daten für die Systeme N,N-Dimethylformamid-Aromat (Benzonitril, Nitrobenzol, Thiophen, Furan, Pyridin, Pyrrol)." Zeitschrift für Chemie 12, no. 6 (2010): 234–36. http://dx.doi.org/10.1002/zfch.19720120619.

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13

Meyer, Daniel, Bernard Witholt, and Andreas Schmid. "Suitability of Recombinant Escherichia coli and Pseudomonas putida Strains for Selective Biotransformation of m-Nitrotoluene by Xylene Monooxygenase." Applied and Environmental Microbiology 71, no. 11 (2005): 6624–32. http://dx.doi.org/10.1128/aem.71.11.6624-6632.2005.

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ABSTRACT Escherichia coli JM101(pSPZ3), containing xylene monooxygenase (XMO) from Pseudomonas putida mt-2, catalyzes specific oxidations and reductions of m-nitrotoluene and derivatives thereof. In addition to reactions catalyzed by XMO, we focused on biotransformations by native enzymes of the E. coli host and their effect on overall biocatalyst performance. While m-nitrotoluene was consecutively oxygenated to m-nitrobenzyl alcohol, m-nitrobenzaldehyde, and m-nitrobenzoic acid by XMO, the oxidation was counteracted by an alcohol dehydrogenase(s) from the E. coli host, which reduced m-nitrobe

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14

Voß, Gundula, and Hans Gerlach. "Regioselektiver Brom/Lithium-Austausch bei 2,5-Dibrom-1-nitrobenzol. – Eine einfache Synthese von 4-Brom-2-nitrobenzaldehyd und 6,6′-Dibromindigo." Chemische Berichte 122, no. 6 (1989): 1199–201. http://dx.doi.org/10.1002/cber.19891220628.

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15

Yang, Xue, Jinchi Wei, Zhihai Wu, and Jie Gao. "Effects of Substrate-Binding Site Residues on the Biochemical Properties of a Tau Class Glutathione S-Transferase from Oryza sativa." Genes 11, no. 1 (2019): 25. http://dx.doi.org/10.3390/genes11010025.

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Glutathione S-transferases (GSTs)—an especially plant-specific tau class of GSTs—are key enzymes involved in biotic and abiotic stress responses. To improve the stress resistance of crops via the genetic modification of GSTs, we predicted the amino acids present in the GSH binding site (G-site) and hydrophobic substrate-binding site (H-site) of OsGSTU17, a tau class GST in rice. We then examined the enzyme activity, substrate specificity, enzyme kinetics and thermodynamic stability of the mutant enzymes. Our results showed that the hydrogen bonds between Lys42, Val56, Glu68, and Ser69 of the G

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16

Quillian, Brandon, Jordan Hendricks, Matthew Trivitayakhun, and Clifford W. Padgett. "Isolation of 3-amino-4-nitrobenzyl acetate: evidence of an undisclosed impurity in 5-amino-2-nitrobenzoic acid." Acta Crystallographica Section E Crystallographic Communications 71, no. 6 (2015): 606–8. http://dx.doi.org/10.1107/s2056989015008750.

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Yellow crystals of the title compound 3-amino-4-nitrobenzyl acetate, C9H10N2O4, were isolated from the reaction of acetic anhydride with (5-amino-2-nitrophenyl)methanol, prepared from reduction of commerically available 5-amino-2-nitrobenzoic acid with borane–THF. The molecule is essentially planar (r.m.s. deviation = 0.028 Å). The molecules are linked by intermolecular N—H...O hydrogen-bonding interactions between the carbonyl and amine groups, forming a zigzag chain along theb-axis direction lying in a plane parallel to (-102). The chains are stacked along thecaxis by π–π interactions [centr

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17

Ziegler, Erich, and Helga Wittmann. "�ber Reaktionen mit Betainen, 21. Mitt. �ber die Bildung von Formazylverbindungen durch Kupplung von S-Betainen mit 4-Nitrobenzol-diazonium-tetrafluorborat." Monatshefte f�r Chemie Chemical Monthly 117, no. 5 (1986): 653–59. http://dx.doi.org/10.1007/bf00817902.

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18

Tanner, Berno, Jörg Schöneich, Edith Hüttner, and Volker Steinbicker. "Cytogenetic monitoring of chemical workers in production of the drug 1-propoxy-2-acetamino-4-nitrobenzol with reference to their smoking habits." Mutation Research/Genetic Toxicology 241, no. 3 (1990): 291–95. http://dx.doi.org/10.1016/0165-1218(90)90027-y.

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19

Kricsfalussy, Zoltan. "Reaktionskinetische Untersuchungen in Drei-Phasen-Systemen, dargestellt am Beispiel der Hydrierung von 1-Methoxy-4-methyl-2-nitrobenzol zu p-Kresidin unter Berücksichtigung der Katalysator-Desaktivierung." Chemie Ingenieur Technik 60, no. 10 (1988): 771–73. http://dx.doi.org/10.1002/cite.330601010.

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20

Białońska, Agata, and Zbigniew Ciunik. "Hydrophobic `lock and key' recognition of N-4-nitrobenzoylamino acid by strychnine." Acta Crystallographica Section B Structural Science 62, no. 6 (2006): 1061–70. http://dx.doi.org/10.1107/s0108768106025249.

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During racemic resolution of N-4-nitrobenzoyl-DL-amino acids (alanine, serine and aspartic acid) by a fractional crystallization of strychninium salts, crystals of both diastereomeric salts were grown, and the crystal structures of strychninium N-4-nitrobenzoyl-L-alaninate methanol disolvate (1a), strychninium N-4-nitrobenzoyl-D-alaninate dihydrate (1b), strychninium N-4-nitrobenzoyl-D-serinate dihydrate (2a), strychninium N-4-nitrobenzoyl-L-serinate methanol solvate hydrate (2b), strychninium hydrogen N-4-nitrobenzoyl-L-aspartate 3.75 hydrate (3a) and strychninium hydrogen N-4-nitrobenzoyl-D-

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21

Yan, Rui Yi, Pu Yang, Zeng Xi Li, et al. "Synthesis of 2-Nitrobenzaldehyde in the Presence of Ionic Liquids." Advanced Materials Research 233-235 (May 2011): 1146–51. http://dx.doi.org/10.4028/www.scientific.net/amr.233-235.1146.

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A method for synthesizing of 2-nitrobenzaldehyde from 2-nitrobenzyl alcohol using ionic liquids (ILs) has been developed. The conversion of 2-nitrobenzyl alcohol and the selectivity of 2-nitrobenzaldehyde in the ionic liquids are higher than those in the traditional dichlorethane solvent. In addition, a reaction mechanism for the oxidation of 2-nitrobenzyl alcohol to 2-nitrobenzaldehyde is proposed.

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22

Moreno, S. N., J. Schreiber, and R. P. Mason. "Nitrobenzyl radical metabolites from microsomal reduction of nitrobenzyl chlorides." Journal of Biological Chemistry 261, no. 17 (1986): 7811–15. http://dx.doi.org/10.1016/s0021-9258(19)57473-7.

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23

Morrison, James, Peter Wan, John ET Corrie та V. Ranjit Munasinghe. "Chemistry of photogenerated α-hydroxy-p-nitrobenzyl carbanions in aqueous solution: protonation vs. disproportionation". Canadian Journal of Chemistry 81, № 6 (2003): 586–97. http://dx.doi.org/10.1139/v03-045.

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The photochemistry of p-nitrobenzyl derivatives 610 has been studied in aqueous solution as a function of pH, using product analysis, UVvis spectrophotometry, and laser flash photolysis (LFP). The compounds were chosen with the aim of further exploring the propensity of these systems to give rise to α-hydroxy-p-nitrobenzyl carbanions on photolysis, and to study their mechanisms of subsequent reaction. α-Hydroxy-substituted carbanions are anions that cannot be readily formed using thermal routes but which are believed to have some interesting chemistry. Three methods were employed for photoge

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24

Clegg, W., H. J. Pogue, M. P. Lowe, I. M. Butterfield, and R. F. W. Jackson. "p-Nitrobenzyl Trichloroacetimidate." Acta Crystallographica Section C Crystal Structure Communications 51, no. 4 (1995): 741–43. http://dx.doi.org/10.1107/s0108270194010838.

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25

Anuradha, Venkatramu, S. Madan Kumar, B. P. Siddaraju, N. K. Lokanath, and P. Nagendra. "2-Nitrobenzyl methanesulfonate." Acta Crystallographica Section E Structure Reports Online 70, no. 5 (2014): o616. http://dx.doi.org/10.1107/s160053681400899x.

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In the title compound, C8H9NO5S, the dihedral angle between the benzene ring and the nitro group is 5.86 (15)° and the C—C—O—S group adopts ananticonformation [torsion angle = −168.44 (15)°]. In the crystal, molecules are linked by C—H...O hydrogen bonds, generating a three-dimensional network.

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26

Wan, Peter, S. Muralidharan, Iain McAuley та Christopher A. Babbage. "Photooxygenation of nitrobenzyl derivatives. Mechanisms of photogeneration and hydrolysis of α-hydroperoxy nitrobenzyl ethers". Canadian Journal of Chemistry 65, № 8 (1987): 1775–83. http://dx.doi.org/10.1139/v87-299.

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The photooxygenation of nitrobenzyl derivatives 1–10 has been studied in aqueous solution as a function of pH. For m-nitrobenzyl ethers 2–4 and 9, stable α-hydroperoxy ethers (11–13) are the primary photochemical products. Acid hydrolysis of 11–13 gives m-nitrobenzaldehyde and hydrogen peroxide. Quantum yields for photooxygenation are reported for a number of derivatives as a function of pH. Acid and base catalyses of photooxygenation are observed for several compounds. A mechanism involving photogenerated nitrobenzyl carbanion intermediates is proposed.

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27

Hou, Wanting, Ruiqi Liu, Siwei Bi, Qian He, Haibo Wang, and Jun Gu. "Photo-Responsive Polymersomes as Drug Delivery System for Potential Medical Applications." Molecules 25, no. 21 (2020): 5147. http://dx.doi.org/10.3390/molecules25215147.

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Due to a strong retardation effect of o-nitrobenzyl ester on polymerization, it is still a great challenge to prepare amphiphilic block copolymers for polymersomes with a o-nitrobenzyl ester-based hydrophobic block. Herein, we present one such solution to prepare amphiphilic block copolymers with pure poly (o-nitrobenzyl acrylate) (PNBA) as the hydrophobic block and poly (N,N’-dimethylacrylamide) (PDMA) as the hydrophilic block using bulk reversible addition-fragmentation chain transfer (RAFT) polymerization of o-nitrobenzyl acrylate using a PDMA macro-RAFT agent. The developed amphiphilic blo

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28

Pardo, Carmen, Sabine Graf, Mar Ramos, Esther Sesmilo, and José Elguero. "SYNTHESIS OF 1-(p-NITROBENZYL)AZOLES AND 1-(p-NITROBENZYL)BENZAZOLES." Organic Preparations and Procedures International 32, no. 4 (2000): 385–90. http://dx.doi.org/10.1080/00304940009355941.

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29

Prousek, Josef. "Preparation and alkylation reactions of 4-nitrobenzyl and 5-nitrofurfuryl sulfones." Collection of Czechoslovak Chemical Communications 53, no. 4 (1988): 851–56. http://dx.doi.org/10.1135/cccc19880851.

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Substitution reaction of 5-nitrofurfuryl bromide (I) with sodium thiophenoxide and 4-chlorothiophenoxide in dimethyl sulfoxide at 20 °C and oxidation with dimethyl sulfoxide in the reaction medium afforded 5-nitrofurfuryl phenyl sulfone (IVa) and 5-nitrofurfuryl 4-chlorophenyl sulfone (IVb), respectively. Similarly, 4-nitrobenzyl bromide reacted with sodium 4-chlorothiophenoxide to give 4-nitrobenzyl 4-chlorophenyl sulfone (VII) and with sodium phenylsulfinate to afford 4-nitrobenzyl phenyl sulfone (IX). The sulfide intermediates were not isolated. The sulfone IX was used as substrate in alkyl

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30

Kim, Hee Sook, and Eun Yeol Lee. "Evaluation of Microbial Epoxide Hydrolase Activity Based on Colorimetric Assay Using 4-(p-nitrobenzyl) Pyridine." Journal of Life Science 15, no. 3 (2005): 332–36. http://dx.doi.org/10.5352/jls.2005.15.3.332.

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31

Glidewell, Christopher, John N. Low, Janet M. S. Skakle, Solange M. S. V. Wardell та James L. Wardell. "Isomeric iodo-N-(nitrobenzyl)anilines: interplay of hard and soft hydrogen bonds, iodo...nitro interactions and aromatic π...π stacking interactions". Acta Crystallographica Section B Structural Science 60, № 4 (2004): 472–80. http://dx.doi.org/10.1107/s0108768104012017.

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Molecules of 2-iodo-N-(4-nitrobenzyl)aniline, 4-O2NC6H4CH2NHC6H4I-2′ (1) are linked into chains by C—H...O hydrogen bonds. In the isomeric compound 3-iodo-N-(4-nitrobenzyl)aniline (2) a combination of N—H...O and C—H...O hydrogen bonds and iodo...nitro and aromatic π...π stacking interactions links the molecules into a three-dimensional framework structure. The two-dimensional supramolecular structure of 4-iodo-N-(4-nitrobenzyl)aniline (6) is built from a combination of C—H...O and N—H...π(arene) hydrogen bonds and aromatic π...π stacking interactions. 2-Iodo-N-(2-nitrobenzyl)aniline (7) cryst

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32

Taher, Deeb, Firas F. Awwadi, and Mohammed H. Kailani. "4-(4-Nitrobenzyl)pyridine." Acta Crystallographica Section E Structure Reports Online 69, no. 7 (2013): o1164. http://dx.doi.org/10.1107/s1600536813017145.

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33

Jones, P. G. "Bis(m-nitrobenzyl) ether." Acta Crystallographica Section C Crystal Structure Communications 43, no. 2 (1987): 364–66. http://dx.doi.org/10.1107/s0108270187095787.

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34

Zhu, Kai, Hui Liu, Yan-Hua Wang, Ping-Fang Han, and Ping Wei. "2-Nitrobenzyl 2-chloroacetate." Acta Crystallographica Section E Structure Reports Online 65, no. 10 (2009): o2319. http://dx.doi.org/10.1107/s1600536809031444.

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35

Jin, Wei-Wei, Cai-Bao Chen, and Xin-Yong Li. "2-Nitrobenzyl diphenyl phosphate." Acta Crystallographica Section E Structure Reports Online 63, no. 6 (2007): o3016. http://dx.doi.org/10.1107/s1600536807023379.

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36

Yang, Sen-Lin, and Zhi-Gang Luo. "N′-(2-Nitrobenzoyl)benzohydrazide." Acta Crystallographica Section E Structure Reports Online 63, no. 7 (2007): o3208. http://dx.doi.org/10.1107/s1600536807028024.

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37

Thompson, S., J. A. Spoors, M. C. Fawcett, and C. H. Self. "Photocleavable Nitrobenzyl-Protein Conjugates." Biochemical and Biophysical Research Communications 201, no. 3 (1994): 1213–19. http://dx.doi.org/10.1006/bbrc.1994.1834.

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38

Zhu, Kai, Yan-Hua Wang, Hui Liu, Ping-Fang Han, and Ping Wei. "4-Nitrobenzyl 2-chloroacetate." Acta Crystallographica Section E Structure Reports Online 65, no. 6 (2009): o1423. http://dx.doi.org/10.1107/s1600536809019278.

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In the molecule of the title compound, C9H8ClNO4, the nearly planar acetate moiety [maximum deviation = 0.015 (3) Å for an O atom] is oriented with respect to the plane of the aromatic ring at a dihedral angle of 73.03 (3)°. In the crystal structure, intermolecular C—H...O interactions link molecules into a network. π–π contacts between benzene rings [centroid–centroid distance = 4.000 (1) Å] may further stabilize the structure.

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39

Zhu, Kai, Hui Liu, Yan-Hua Wang, Ping-Fang Han, and Ping Wei. "4-Nitrobenzyl 2-bromoacetate." Acta Crystallographica Section E Structure Reports Online 65, no. 7 (2009): o1522. http://dx.doi.org/10.1107/s1600536809021187.

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40

Yang, Ling-Ling, Ren-Lin Zheng, Guo-Bo Li, Qi-Zheng Sun, and Yong-Mei Xie. "4-(4-Nitrobenzyl)morpholine." Acta Crystallographica Section E Structure Reports Online 67, no. 4 (2011): o754. http://dx.doi.org/10.1107/s1600536811005964.

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41

Suchetan, P. A., Sabine Foro, and B. Thimme Gowda. "N-(3-Nitrobenzoyl)benzenesulfonamide." Acta Crystallographica Section E Structure Reports Online 68, no. 5 (2012): o1507. http://dx.doi.org/10.1107/s1600536812016765.

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42

Hökelek, T., E. Kiliç, and S. Aktan. "1-Nitrobenzo[c]cinnoline." Acta Crystallographica Section C Crystal Structure Communications 55, no. 3 (1999): 383–85. http://dx.doi.org/10.1107/s0108270198013560.

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43

Park, Jung Hye, and Byung Hyun Ahn. "Synthesis of Polyimides Derived from 2,2-Bis[4-(4-aminobenzoyl)phenoxy]hexafluoropropane and Aromatic Dianhydrides." Applied Chemistry for Engineering 27, no. 1 (2016): 50–55. http://dx.doi.org/10.14478/ace.2015.1121.

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44

Wan, Peter, and S. Muralidharan. "Photochemical retro-aldol type reactions of nitrobenzyl derivatives. Mechanistic variations in the elimination of nitrobenzyl carbanions from nitrobenzyl derivatives on photolysis." Canadian Journal of Chemistry 64, no. 9 (1986): 1949–51. http://dx.doi.org/10.1139/v86-321.

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The photochemical retro-aldol type reactions of several nitrobenzyl derivatives are reported. The reactions are observed only in aqueous solution with quantum efficiencies being pH dependent for several derivatives, consistent with the existence of several mechanistic pathways for reaction. The primary photochemical event is believed to involve the generation of a nitrobenzyl carbanion, which acts as a photolabile leaving group in these reactions, and the generation of an oxocarbocation (or oxocarbocation-derived) fragment.

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45

Yang, Xu, Zhiwei Wang, and Jing Sun. "Morphological Transitions of Photoresponsive Vesicles from Amphiphilic Polypeptoid Copolymers for Controlled Release." Polymers 12, no. 4 (2020): 798. http://dx.doi.org/10.3390/polym12040798.

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Photoresponsive polymers have attracted increasing interest for a variety of applications. Here, we report a family of photoresponsive polypeptoid-based copolymer poly(ethylene glycol)-b-poly(N-(S-(o-nitrobenzyl)-thioethyl) glycine)-co-poly(N-(2-phenylethyl) glycine) (PEG-b-PNSN-co-PNPE) synthesized by the controlled ring-opening polymerization (ROP) technique. The key feature of the design is to incorporate both o-nitrobenzyl group moiety to offer the photoresponsive property and phenethyl residues to tune the structural and amphiphilic property of the system. We demonstrate that the cleavage

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46

Grung, Knut Erik, Christian Rømming, Jon Songstad, Henning Lund, Lija Tekenbergs-Hjelte, and Kristina Ohlson. "Substitution Reactions of 2-Nitrobenzyl Pseudohalides. The Crystal Structure of 2-Nitrobenzyl Tellurocyanate." Acta Chemica Scandinavica 43 (1989): 518–26. http://dx.doi.org/10.3891/acta.chem.scand.43-0518.

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47

Pardo, Carmen, Sabine Graf, Mar Ramos, Esther Sesmilo, and Jose Elguero. "ChemInform Abstract: Synthesis of 1-(p-Nitrobenzyl)azoles and 1-(p-Nitrobenzyl)benzazoles." ChemInform 31, no. 52 (2000): no. http://dx.doi.org/10.1002/chin.200052054.

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48

Saršūns, Kristaps, and Agris Bērziņš. "Prediction of Solid Solution Formation among Chemically Similar Molecules Using Calculation of Lattice and Intermolecular Interaction Energy." Key Engineering Materials 850 (June 2020): 54–59. http://dx.doi.org/10.4028/www.scientific.net/kem.850.54.

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Abstract:

Several 2-substituted 4-nitrobenzoic acid (NBA) derivatives such as 2-chloro-4-nitrobenzoic acid (2C4NBA), 2-methyl-4-nitrobenzoic acid (2CH34NBA) and 2-hydroxy-4-nitrobenzoic acid (2OH4NBA) were selected as model compounds because of their availability and chemically similar structures, in which the different group/atom (R) does not significantly affect the dominant intermolecular interactions – hydrogen bonds formed by the carboxylic group [1]. Quantum chemical calculations of lattice and intermolecular interaction energy were carried out to identify possible factors, which could be, used in

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Bujok, Robert, and Mieczysław Mąkosza. "Synthesis of Diarylacetylenes Bearing Electron-Withdrawing Groups via the Smiles Rearrangement." Synthesis 51, no. 16 (2019): 3109–16. http://dx.doi.org/10.1055/s-0037-1612423.

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Abstract:

Nitrobenzyl benzothiazol-2-yl sulfones and nitrobenzyl 1-phenyl-1H-tetrazol-5-yl sulfones react with chlorides of aromatic acids to form β-acyl derivatives. These products undergo the Smiles rearrangement resulting in the formation of the corresponding nitrophenyl arylacetylenes in 50–60% overall yields (approx. 75% per step). Sulfones bearing CF3 or CN groups instead of a NO2 substituent form mixtures of the acetylenes in moderate yields and benzyl aryl ketones in yields above 40%.

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Saeed, Aamer, and Michael Bolte. "1-(4-Nitrobenzoyl)-3-phenylthiourea." Acta Crystallographica Section E Structure Reports Online 63, no. 8 (2007): o3553. http://dx.doi.org/10.1107/s1600536807034587.

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