Relevant bibliographies by topics / Palladium-catalyzed cross couplings in organic synthesis

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  2. Dissertations / Theses
  3. Books
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Academic literature on the topic 'Palladium-catalyzed cross couplings in organic synthesis'

Author: Grafiati
Published: 3 June 2025
Last updated: 31 July 2025

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Journal articles on the topic "Palladium-catalyzed cross couplings in organic synthesis"

1

Collet, Jurriën W., Thomas R. Roose, Bram Weijers, Bert U. W. Maes, Eelco Ruijter, and Romano V. A. Orru. "Recent Advances in Palladium-Catalyzed Isocyanide Insertions." Molecules 25, no. 21 (2020): 4906. http://dx.doi.org/10.3390/molecules25214906.

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Isocyanides have long been known as versatile chemical reagents in organic synthesis. Their ambivalent nature also allows them to function as a CO-substitute in palladium-catalyzed cross couplings. Over the past decades, isocyanides have emerged as practical and versatile C1 building blocks, whose inherent N-substitution allows for the rapid incorporation of nitrogeneous fragments in a wide variety of products. Recent developments in palladium catalyzed isocyanide insertion reactions have significantly expanded the scope and applicability of these imidoylative cross-couplings. This review high
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Daley, Ryan A., and Joseph J. Topczewski. "Aryl-Decarboxylation Reactions Catalyzed by Palladium: Scope and Mechanism." Synthesis 52, no. 03 (2019): 365–77. http://dx.doi.org/10.1055/s-0039-1690769.

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Palladium-catalyzed cross-couplings and related reactions have enabled many transformations essential to the synthesis of pharmaceuticals, agrochemicals, and organic materials. A related family of reactions that have received less attention are decarboxylative functionalization reactions. These reactions replace the preformed organometallic precursor (e.g., boronic acid or organostannane) with inexpensive and readily available carboxylic acids for many palladium-catalyzed reactions. This review focuses on catalyzed reactions where the elementary decarboxylation step is thought to occur at a pa
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Rifhat Bibi, Rifhat Bibi, Muhammad Yaseen Muhammad Yaseen, Haseen Ahmad Haseen Ahmad, Ismat Ullah Khan Ismat Ullah Khan, Shaista Parveen Shaista Parveen, and Abbas Hassan Abbas Hassan. "Palladium Catalyzed Synthesis of Phenylquinoxaline-Alkyne Derivatives via Sonogashira Cross Coupling Reaction." Journal of the chemical society of pakistan 43, no. 1 (2021): 95. http://dx.doi.org/10.52568/000550.

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Transition metals mediated cross coupling methodologies provide an extremely powerful versatile pathway in organic syntheses undoubtedly, a facile route for syntheses and derivatization of biologically important heterocycles from easily available precursors. Sonogashira coupling reaction, a leading method to Csp-Csp2 bond formation is one of the most important and rapid pathways to couple aryl/vinyl halides with terminal alkynes. Current research study deals with the synthesis of alkyne substituted quinoxaline derivatives. The quinoxalines class of aromatic heterocycles exhibits a wide variety
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Rifhat Bibi, Rifhat Bibi, Muhammad Yaseen Muhammad Yaseen, Haseen Ahmad Haseen Ahmad, Ismat Ullah Khan Ismat Ullah Khan, Shaista Parveen Shaista Parveen, and Abbas Hassan Abbas Hassan. "Palladium Catalyzed Synthesis of Phenylquinoxaline-Alkyne Derivatives via Sonogashira Cross Coupling Reaction." Journal of the chemical society of pakistan 43, no. 1 (2021): 95. http://dx.doi.org/10.52568/000550/jcsp/43.01.2021.

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Transition metals mediated cross coupling methodologies provide an extremely powerful versatile pathway in organic syntheses undoubtedly, a facile route for syntheses and derivatization of biologically important heterocycles from easily available precursors. Sonogashira coupling reaction, a leading method to Csp-Csp2 bond formation is one of the most important and rapid pathways to couple aryl/vinyl halides with terminal alkynes. Current research study deals with the synthesis of alkyne substituted quinoxaline derivatives. The quinoxalines class of aromatic heterocycles exhibits a wide variety
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Rifhat Bibi, Rifhat Bibi, Muhammad Yaseen Muhammad Yaseen, Haseen Ahmad Haseen Ahmad, Ismat Ullah Khan Ismat Ullah Khan, Shaista Parveen Shaista Parveen, and Abbas Hassan Abbas Hassan. "Palladium Catalyzed Synthesis of Phenylquinoxaline-Alkyne Derivatives via Sonogashira Cross Coupling Reaction." Journal of the chemical society of pakistan 43, no. 1 (2021): 95. http://dx.doi.org/10.52568/000009.

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Transition metals mediated cross coupling methodologies provide an extremely powerful versatile pathway in organic syntheses undoubtedly, a facile route for syntheses and derivatization of biologically important heterocycles from easily available precursors. Sonogashira coupling reaction, a leading method to Csp-Csp2 bond formation is one of the most important and rapid pathways to couple aryl/vinyl halides with terminal alkynes. Current research study deals with the synthesis of alkyne substituted quinoxaline derivatives. The quinoxalines class of aromatic heterocycles exhibits a wide variety
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Sain, Shalu, Sonika Jain, Manish Srivastava, Rajendra Vishwakarma, and Jaya Dwivedi. "Application of Palladium-Catalyzed Cross-Coupling Reactions in Organic Synthesis." Current Organic Synthesis 16, no. 8 (2020): 1105–42. http://dx.doi.org/10.2174/1570179416666191104093533.

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: Palladium-catalyzed cross-coupling reactions have gained a continuously growing interest of synthetic organic chemists. The present review gives a brief account of applications of the palladium-catalyzed cross-coupling reactions in comprehensive synthesis, viz., the Heck, Stille, Suzuki–Miyaura, Negishi, Sonogashira, Buchwald–Hartwig, Ullmann and the Oxidative, decarboxylative cross-coupling reactions, with particular emphasis on the synthesis of heterocyclic compounds.
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Li, Jie, and Paul Knochel. "Chromium-Catalyzed Cross-Couplings and Related Reactions." Synthesis 51, no. 10 (2019): 2100–2106. http://dx.doi.org/10.1055/s-0037-1611756.

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Transition-metal-catalyzed cross-couplings have been recognized as a powerful tool for sustainable syntheses. Despite the fact that remarkable progress was achieved by palladium and nickel catalysis, the high price and toxicity still remained a drawback. Recently, naturally more abundant and less toxic low-valent chromium salts, such as Cr(II) and Cr(III) chlorides, displayed notable unique catalytic reactivity. Thus, recent progress in the field of chromium-catalyzed cross-couplings and related reactions are highlighted in the present short review until December­ 2018.1 Introduction and Early
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Ji, Yuan, Ning Zhong, Zinan Kang, Guobing Yan, and Ming Zhao. "Synthesis of Internal Alkynes through an Effective Tandem ­Elimination–Hydrodebromination–Cross-Coupling of gem-­Dibromoalkenes with Halobenzenes." Synlett 29, no. 02 (2017): 209–14. http://dx.doi.org/10.1055/s-0036-1590907.

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Carbon–carbon couplings are among the most important strategies for constructing functional molecules in organic synthetic chemistry, and cheap, diverse, and readily available coupling partners are crucial to these diverse reactions. In this contribution, we report the first palladium-catalyzed C–C cross-coupling reaction of two kinds of organic halide, a gem-dibromoalkene and a halobenzene, as the starting materials. Terminal alkynes were generated in situ through a tandem elimination–hydrodebromination process, and the internal alkyne final products were synthesized in one pot. The reaction
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Kanwal, Iram, Aqsa Mujahid, Nasir Rasool, et al. "Palladium and Copper Catalyzed Sonogashira cross Coupling an Excellent Methodology for C-C Bond Formation over 17 Years: A Review." Catalysts 10, no. 4 (2020): 443. http://dx.doi.org/10.3390/catal10040443.

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Sonogashira coupling involves coupling of vinyl/aryl halides with terminal acetylenes catalyzed by transition metals, especially palladium and copper. This is a well known reaction in organic synthesis and plays a role in sp2-sp C-C bond formations. This cross coupling was used in synthesis of natural products, biologically active molecules, heterocycles, dendrimers, conjugated polymers and organic complexes. This review paper focuses on developments in the palladium and copper catalyzed Sonogashira cross coupling achieved in recent years concerning substrates, different catalyst systems and r
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Zaman, Abdalhussein Ibadi Alaridhee, Hasan Nada, Dohan Abid Muhand, Jabbar Radhi Ali, and Wheed Radhi Ahmed. "Study of mechanistic pathways in cross-linking reactions with palladium." Journal of Wildlife and Biodiversity 7, Special Issue (2023): 664–75. https://doi.org/10.5281/zenodo.10307342.

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Palladium-catalyzed cross-coupling reactions, including the Suzuki, Stille, and Negishi couplings, have emerged as essential methodologies in contemporary organic synthesis. Nevertheless, there is still a lack of comprehensive understanding of the molecular processes involved in these significant events that lead to the formation of C-C and C-heteroatom bonds. This paper provides a complete analysis of the fundamental mechanistic investigations conducted on the primary cross-coupling processes facilitated by palladium catalysts. The present study focuses on the examination of kinetic aspects o
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Dissertations / Theses on the topic "Palladium-catalyzed cross couplings in organic synthesis"

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Marelli, Enrico. "Nickel- and palladium-catalysed deprotonative cross-couplings." Thesis, University of St Andrews, 2017. http://hdl.handle.net/10023/15603.

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Transition metal-catalysed cross coupling chemistry is a valuable tool for synthetic organic chemistry, enabling the preparation of compounds of great interest. The catalytic metal of choice is usually palladium, which generally offer better performances in term of catalytic activity and easy handling. On the other hand, the use of nickel in this class of reactions is gaining attention, as it would provide more economically and environmentally sustainable processes. Deprotonative cross couplings are a subgroup of these reactions, in which the nucleophile is generated in situ by direct deproton
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Lightowler, Stephen. "Palladium-catalysed cross-coupling reactions in the synthesis of novel organic polymers and monodisperse oligomers." Thesis, University of Hull, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.342874.

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Onuska, Nicholas Paul Ralph. "Studies Towards the Synthesis of 2,5-Disubstituted-3-Fluorothiophenes Using a Directed Ortho-Metalation/Nickel-Catalyzed Cross-Coupling Approach." Kent State University Honors College / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=ksuhonors1460652408.

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Yin, Lunxiang. "Synthesis of new calcineurin inhibitors via Pd-catalyzed cross coupling reactions." Doctoral thesis, [S.l. : s.n.], 2005. http://deposit.ddb.de/cgi-bin/dokserv?idn=975817868.

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Liang, Yong. "Novel Approaches for the Synthesis of C-5 Modified Pyrimidine Nucleosides." FIU Digital Commons, 2014. http://digitalcommons.fiu.edu/etd/1591.

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The antiviral or anticancer activities of C-5 modified pyrimidine nucleoside analogues validate the need for the development of their syntheses. In the first half of this dissertation, I explore the Pd-catalyzed cross-coupling reaction of allylphenylgermanes with aryl halides in the presence of SbF5/TBAF to give various biaryls by transferring multiple phenyl groups, which has also been applied to the 5-halo pyrimidine nucleosides for the synthesis of 5-aryl derivatives. To avoid the use of organometallic reagents, I developed Pd-catalyzed direct arylation of 5-halo pyrimidine nucleosides. It
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Black, Daniel. "Imines in copper-catalyzed cross-coupling reactions." Thesis, McGill University, 2006. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=102960.

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The purpose of this study was to develop new catalytic methods to mediate carbon-carbon bond forming reactions with imines under mild conditions and in a general manner. We found that copper catalysts were compatible in cross-coupling of a range of mild organometallic reagents, providing simple, efficient routes to alpha-substituted amides and amines.<br>Chapter 2 of this thesis describes a new copper-catalyzed multicomponent synthesis of alpha-substituted amides. This reaction was developed based upon previous work in this laboratory, which showed that palladium catalysts were competent in St
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Norinder, Jakob. "Asymmetric Synthesis and Mechanistic Studies on Copper(I)-Catalyzed Substitution of Allylic Substrates." Doctoral thesis, Stockholm : Department of Organic Chemistry, Stockholm University, 2006. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-1031.

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Zhang, Ye. "Development of amide-derived P,O-ligands for Suzuki cross-coupling of aryl chlorides and the asymmetric version /." View abstract or full-text, 2005. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202005%20ZHANG.

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Jawade, K. "Synthesis of naturally occurring polyhydroxylated δ--lactones, aryne mediated synthesis of phenyl indolines and pd-sba-tat catalyzed c-c cross coupling reactions". Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2018. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/5868.

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Emmett, Edward J. "Development of catalytic methods to exploit sulfur dioxide in organic synthesis." Thesis, University of Oxford, 2014. http://ora.ox.ac.uk/objects/uuid:be60729b-5467-4758-8d88-9dff3a2d5810.

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In the following thesis, new methodologies towards the synthesis of a range of sulfonyl (-SO<sub>2</sub>-) containing functional groups are documented. These methods utilise easy-to-handle sulfur dioxide surrogates, such as DABSO (vide infra), and exploit palladium catalysis as a new mechanistic protocol for the incorporation of the -SO2- unit. <b>Chapter 1</b> is a literature review surveying sulfur dioxide in organic synthesis, the established uses of SO<sub>2</sub> surrogates and the importance of the sulfonyl moiety in chemistry. Palladium-catalysed (carbonylative) cross-couplings are also
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Books on the topic "Palladium-catalyzed cross couplings in organic synthesis"

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Diederich, François. Metal-catalyzed cross-coupling reactions. Wiley-VCH, 1998.

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Melchor, Max Garcia. Theoretical Study of Pd-Catalyzed C-C Cross-Coupling Reactions. Springer International Publishing AG, 2016.

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Meijere, Armin de, and Fran�ois Diederich. Metal-Catalyzed Cross-Coupling Reactions. Wiley & Sons, Limited, John, 2008.

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Stang, Peter J., and Fran�ois Diederich. Metal-Catalyzed Cross-coupling Reactions. Wiley & Sons, Incorporated, John, 2008.

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Meijere, Armin de, Martin Oestreich, and Stefan Bräse. Metal Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag GmbH, 2014.

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Meijere, Armin de, Martin Oestreich, and Stefan Bräse. Metal Catalyzed Cross-Coupling Reactions and More. Wiley & Sons, Incorporated, John, 2013.

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Meijere, Armin de, Martin Oestreich, and Stefan Bräse. Metal Catalyzed Cross-Coupling Reactions and More. Wiley & Sons, Limited, John, 2013.

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Meijere, Armin de, Martin Oestreich, and Stefan Bräse. Metal Catalyzed Cross-Coupling Reactions and More. Wiley & Sons, Incorporated, John, 2013.

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Meijere, Armin de, Martin Oestreich, and Stefan Bräse. Metal Catalyzed Cross-Coupling Reactions and More. Wiley & Sons, Incorporated, John, 2013.

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(Editor), Armin de Meijere, and François Diederich (Editor), eds. Metal-Catalyzed Cross-Coupling Reactions (2 Volume Set). 2nd ed. Wiley-VCH, 2004.

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Book chapters on the topic "Palladium-catalyzed cross couplings in organic synthesis"

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Seo, Tamae. "Tackling Solubility Issues in Organic Synthesis: Solid-State Cross-Coupling of Insoluble Aryl Halides." In Palladium-Catalyzed Mechanochemical Cross-Coupling Reactions. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1991-4_4.

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Nguyen, Remi, Virinder S. Parmar, and Christophe Len. "Palladium-Catalyzed Suzuki–Miyaura Cross-Coupling in Continuous Flows." In Greener Synthesis of Organic Compounds, Drugs and Natural Products. CRC Press, 2022. http://dx.doi.org/10.1201/9781003089162-7.

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Brandsma, L., H. D. Verkruijsse, and S. F. Vasilevsky. "Nickel- and Palladium-Catalyzed Cross-Coupling Reactions with Organometallic Intermediates." In Application of Transition Metal Catalysts in Organic Synthesis. Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/978-3-642-60328-0_11.

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"Synthetic Methods for Diaryl Ether Preparation Using Arylating Reagents." In Methodologies in Ether Synthesis. Royal Society of Chemistry, 2024. http://dx.doi.org/10.1039/9781837675166-00078.

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Diaryl ethers are one of the most essential intermediates for organic synthesis in the fields of medicine, agrochemistry, and polymer sciences. There are many naturally occurring biologically active compounds bearing a diaryl ether group including the antibiotic vancomycin, perrottetines, and chloropeptins (anti-HIV agents). This chapter presents efficient and practical synthetic methods for the synthesis of diaryl ethers including Ullmann-type reactions of aryl halides which are achieved using copper catalysts, Buchwald–Hartwig cross-couplings of aryl halides in the presence of palladium cata
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Kumar, Ajeet, Vineet Jakhar, Debabrata Konar, Nidhi Kalia, and Archa Gulati. "Ionic Liquid Assisted Cross-Coupling Reactions: Recent Advances and Challenges." In Ionic Liquids for Organic Synthesis. BENTHAM SCIENCE PUBLISHERS, 2025. https://doi.org/10.2174/9789815313413125010005.

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Ionic liquids (ILs) are of sustained interest in synthetic organic chemistry due to their unique properties. The unique properties involve high thermal stability and ionic conductivity, and tunable solvation properties due to tunable cationic and anionic counterparts. There are a variety of cross-coupling reactions present in organic chemistry, which facilitate new carbon-carbon and carbon-heteroatom bond formation. Ionic liquids play various crucial roles in cross-coupling reactions. First, ILs are a greener alternative to flammable and hazardous volatile organic solvents (VOCs). Second, ILs
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Seibel, Zara M., and Tristan H. Lambert. "Construction of Alkylated Stereocenters." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0035.

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Hirohisa Ohmiya and Masaya Sawamura at Hokkaido University reported (Angew. Chem. Int. Ed. 2013, 52, 5350) the copper-catalyzed, γ-selective allylation of terminal alkyne 1 to produce the chiral skipped enyne 3 with high ee. A method to synthe­size asymmetric skipped diene 6 via copper-catalyzed allylic allylation of diene 4 was developed (Chem. Commun. 2013, 49, 3309) by Ben L. Feringa at the University of Groningen. Prof. Feringa also disclosed (J. Am. Chem. Soc. 2013, 135, 2140) the regi­oselective and enantioselective allyl–allyl coupling of bromide 7 with allyl Grignard under Cu catalysis
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Muto, K., and J. Yamaguchi. "6.1 Palladium-Catalyzed Dearomative Functionalization of Arenes." In Dearomatizations. Georg Thieme Verlag KG, 2025. https://doi.org/10.1055/sos-sd-245-00075.

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Abstract Palladium catalysis plays a pivotal role in organic synthesis, encompassing applications in cross-couplings and hydrogenations, among other transformations. Recent progress in palladium chemistry has helped enable catalytic dearomative functionalizations. In particular, catalysis involving benzyl–palladium species has been applied to achieve dearomative functionalization of a wide range of aromatic systems, including challenging substrates such as electronically unbiased benzenes, without the need to use an excess amount of the arene starting materials. This review primarily focuses o
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Spivey, A. C., and C. C. Tseng. "Applications in Palladium(0)-Catalyzed Cross Coupling of Organic Halides." In Science of Synthesis Knowledge Updates KU 2010/4. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-105-00051.

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García-Garrido, S. E., A. Presa Soto, and J. García-Álvarez. "8.1.36 Organolithium Compounds and Related Reagents in Unconventional Reaction Media." In Knowledge Updates 2025/2. Georg Thieme Verlag KG, 2025. https://doi.org/10.1055/sos-sd-108-00532.

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AbstractChallenging the conventional need for inert atmospheres, dry solvents, and strict temperature control when using s-block organometallic reagents (such as Grignard reagents or organolithium/sodium compounds), this Science of Synthesis review highlights recent advances that enable their operation under air, at room temperature, and in the presence of moisture. Success has been driven by using sustainable protic solvents, such as water and deep eutectic solvents (DESs). These protocols have proven versatile for key organic transformations, including nucleophilic additions to unsaturated m
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Spivey, A. C., and C. C. Tseng. "Application of α-Halovinylgermanes in Palladium-Catalyzed Cross Coupling with Organic Halides." In Science of Synthesis Knowledge Updates KU 2010/4. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-105-00021.

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Conference papers on the topic "Palladium-catalyzed cross couplings in organic synthesis"

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Silva, Márcio S., and João V. Comasseto. "Cross-Coupling Reaction of Organotellurolates with Aryl Iodides Catalyzed by CuI." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0136-2.

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Silva, Márcio S., Renan S. Ferrarini, Bruno A. Souza, Rogério A. Gariani, Fabiano T. Toledo, and João V. Comasseto. "Cross-Coupling Reaction of Organotellurides with Grignard Compounds Catalyzed by MnCl2/CuI." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0136-1.

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Ganapathy, D., and G. Sekar. "An efficient and reusable palladium nanocatalyst in C-C bond forming cross-coupling reactions." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201386477.

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da Silva, A. J. M., C. Schneider, and V. Snieckus. "Construction of Polyarylated Fluorenones via chemoselective Ru- and Pd-Catalyzed Suzuki Cross-Coupling Reactions." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0007-1.

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Bohner, Tanja, and Andrea Vasella. "Optimization of the PdII/CuI-catalyzed Cross-Coupling of Alkynylglucopyranoses." In The 1st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02018.

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Nunes, Vanessa Lóren, (PG) Ingryd Cristina de Oliveira, and Olga S. do Rêgo Barros. "Copper(I)-Senelenophene-2-carboxylate Catalyzed Cross- Coupling of Aryl or alkyl Thiols And Aryl Halides." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0177-1.

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Beller, Matthias, and Alexander Zapf. "A Survey of Palladium Catalyst Systems for Cross Coupling Reactions of Aryl Chlorides and Olefins." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01870.

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