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Relevant bibliographies by topics / Particle polymerization / Dissertations / Theses

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Dissertations / Theses on the topic 'Particle polymerization'

Author: Grafiati

Published: 28 June 2021

Last updated: 29 July 2025

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1

Leswin, Joost Sieger Kaspar. "Particle Formation in RAFT-mediated Emulsion Polymerization." Thesis, The University of Sydney, 2007. http://hdl.handle.net/2123/2176.

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Particle formation in RAFT-mediated emulsion polymerization has been studied using reaction calorimetry. By measuring the heat flow during controlled feed ab-initio emulsion polymerization in the presence of amphipathic RAFT agents, particle formation by self-assembly of these species could be observed. Two different monomer systems, i.e. styrene and n-butyl acrylate, and various degrees of hydrophobicity of the initial macro-RAFT agents have been studied and compared. The different macro-RAFT agents were synthesized by first forming a hydrophilic block of poly(acrylic acid) that would later o

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2

Leswin, Joost Sieger Kaspar. "Particle Formation in RAFT-mediated Emulsion Polymerization." University of Sydney, 2007. http://hdl.handle.net/2123/2176.

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Doctor of Philosophy(PhD)<br>Particle formation in RAFT-mediated emulsion polymerization has been studied using reaction calorimetry. By measuring the heat flow during controlled feed ab-initio emulsion polymerization in the presence of amphipathic RAFT agents, particle formation by self-assembly of these species could be observed. Two different monomer systems, i.e. styrene and n-butyl acrylate, and various degrees of hydrophobicity of the initial macro-RAFT agents have been studied and compared. The different macro-RAFT agents were synthesized by first forming a hydrophilic block of poly(acr

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3

Gilmore, Cheryl Matthews. "Particle nucleation and growth in a polymerically stabilized emulsion polymerization system." Diss., Georgia Institute of Technology, 1991. http://hdl.handle.net/1853/11707.

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4

Ramanathan, L. S. "Studies on particle forming polycondensation and ring opening polymerization process." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2000. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2270.

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5

Brunier, Barthélémy. "Modeling of Pickering Emulsion Polymerization." Thesis, Lyon 1, 2015. http://www.theses.fr/2015LYO10320/document.

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L’objectif du présent projet est de développer une méthodologie pour la modélisation fondamentale de procédés de polymérisation en émulsion sans tensioactif stabilisés par des particules inorganiques, dénommées "polymérisation en émulsion Pickering". La modélisation des systèmes de polymérisation en émulsion nécessite la modélisation de la distribution de taille des particules (PSD), qui est une propriété importante d'utilisation finale du latex. Cette PSD comprend des sous-modèles dédiés à la nucléation des particules, le transfert de masse entre les différentes phases (monomère, radicaux, st

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6

Roßner, Christian. "High-Precision Particle Arrangement in Gold‒Polymer-Nanocomposites using RAFT Polymerization." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://hdl.handle.net/11858/00-1735-0000-002B-7CAD-0.

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7

Rodrigues, Jeffrey Collin. "Comparison of shear stability of mini and macroemulsion latexes with respect to particle size and number distribution." Thesis, Georgia Institute of Technology, 1996. http://hdl.handle.net/1853/9136.

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8

Downey, Jeffrey S. "Precipitation polymerization of divinylbenzene to monodisperse microspheres : an investigation of the particle formation mechanism /." *McMaster only, 2000.

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9

Godin, Alexandra [Verfasser]. "Particle formation and multiphase morphologies in catalytic aqueous ethylene polymerization / Alexandra Godin, geb. Tchernook." Konstanz : Bibliothek der Universität Konstanz, 2017. http://d-nb.info/113819610X/34.

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10

Virtanen, Otto L. J. [Verfasser], Walter [Akademischer Betreuer] Richtering, and Sebastian [Akademischer Betreuer] Seiffert. "Insight into precipitation polymerization of N-isopropylacrylamide : reaction mechanism, particle formation and particle structure / Otto L. J. Virtanen ; Walter Richtering, Sebastian Seiffert." Aachen : Universitätsbibliothek der RWTH Aachen, 2016. http://d-nb.info/1130792501/34.

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11

Rawlston, Jonathan A. "Multiscale modeling of free-radical polymerization kinetics." Diss., Georgia Institute of Technology, 2010. http://hdl.handle.net/1853/33933.

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Polymer chain microstructure, including characteristics such as molecular weight and branch length, can impact the end-use properties of the polymer. The assumptions contained in deterministic models prevent examination of the structure of individual polymer chains, so removal of these assumptions is necessary to gain insight into molecular-level mechanisms that determine chain microstructure. The work presented here uses a combination of stochastic and deterministic models to examine two significant mechanistic issues in free radical polymerization. The zero-one assumption concerning the n

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12

Rajabi-Hamane, Mehdi [Verfasser]. "Modeling, Validation and Time Optimal Control of Particle Size Distribution in Emulsion Polymerization / Mehdi Rajabi-Hamane." Aachen : Shaker, 2007. http://d-nb.info/1166511340/34.

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13

Nazaran, Pantea. "Nucleation in emulsion polymerization : steps towards a non-micellar nucleation theory." Phd thesis, Universität Potsdam, 2008. http://opus.kobv.de/ubp/volltexte/2008/1752/.

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For more than 70 years, understanding of the mechanism of particle nucleation in emulsion polymerization has been one of the most challenging issues in heterophase polymerization research. Within this work a comprehensive experimental study of particle nucleation in emulsion polymerization of styrene at 70 °C and variety of conditions has been performed. To follow the onset of nucleation, on-line conductivity measurements were applied. This technique is highly sensitive to the mobility of conducting species and hence, it can be employed to follow aggregation processes leading to particle form

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14

Chabrol, Virginie. "Functionalized latex particles as substrates for metal mediated radical polymerization." Phd thesis, Université Claude Bernard - Lyon I, 2012. http://tel.archives-ouvertes.fr/tel-01012004.

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Le sujet de cette thèse consiste à incorporer une couronne de polymère hydrophile à la surface de particules de latex par amorçage et croissance en utilisant la polymérisation radicalaire contrôlée par transfert d'atome induite par les métaux. Les particules de latex, obtenues par, polymérisation radicalaire en émulsion ont été fonctionnalisées avec un " inimère ", monomère comportant une fonction halogénée capable de jouer le rôle d'amorceur dans l'étape de greffage. Cette étape de greffage a ensuite été effectuée en présence de CuBr2, PMDETA et d'un métal à valence zéro tel que le cuivre, àt

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15

Druma, Calin. "A particle in cell formulation for extrusion of fluoropolymers." Ohio : Ohio University, 2003. http://www.ohiolink.edu/etd/view.cgi?ohiou1178048890.

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16

Schmitt, Christian Werner. "Around the globe: New concepts for polymer microsphere design." Thesis, Queensland University of Technology, 2021. https://eprints.qut.edu.au/211293/1/Christian%20Werner_Schmitt_Thesis.pdf.

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The thesis explores critical aspects of polymeric micron- and nano-sized particle synthesis, functionalization and application. It identifies three major elements that can be utilized for the development of new and unique polymeric materials thereof: shape, composition and chemical functionality. By applying advanced macromolecular synthetic strategies on each element, the thesis establishes functional polymer micro- and nano-spheres for analytical methods and biomedical applications.

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17

Qiao, Xiaoguang. "Synthesis of silica-polymer hybrid particles via controlled radical polymerization in aqueous dispersed media." Thesis, Lyon 1, 2013. http://www.theses.fr/2013LYO10332/document.

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Des polymères à base de méthacrylate de poly(oxyde d'éthylène) (PEOMA) avec des chaînes pendantes PEO (Mn = 300 ou 950 g mol-1) ou des copolymères de PEOMA300 et d'acide méthacrylique (AMA) ont été synthétisés par polymérisation radicalaire contrôlée par les nitroxydes en utilisant une alkoxyamine (BlocBuilder®) comme amorceur en présence de SG1 et d'une faible quantité de styrène. Les copolymères à base de PEOMA300 et d'AMA sont thermo- et pH-sensibles. Les deux types de macroalkoxyamines ont été utilisés pour amorcer la copolymérisation en émulsion du méthacrylate de n-butyle et du styrène e

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18

Roßner, Christian [Verfasser], Philipp [Akademischer Betreuer] [Gutachter] Vana, and Alec [Gutachter] Wodtke. "High-Precision Particle Arrangement in Gold‒Polymer-Nanocomposites using RAFT Polymerization / Christian Roßner ; Gutachter: Philipp Vana, Alec Wodtke ; Betreuer: Philipp Vana." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://d-nb.info/114064193X/34.

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19

Khan, Ikram Ullah. "Microfluidic-assisted synthesis and release properties of multi-domain polymer microparticles drug carriers." Thesis, Strasbourg, 2014. http://www.theses.fr/2014STRAF042/document.

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Les caractéristiques et les propriétés de libération de microparticules chargées de médicament dépendent de la nature des matériaux employés, des propriétés physicochimiques des microparticules, du choix de la méthode de production, et enfin des propriétés des molécules encapsulées. A l'inverse de la plupart des méthodes conventionnelles, les méthodes microfluidiques présentent l’avantage de bien mieux contrôler la génération de gouttelettes, leur taille et leur distribution de tailles. Ainsi des dispositifs microfluidiques à base de capillaires ont été développés pour obtenir des microbilles

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20

Hunt, Paul Edward. "Protective colloids : understanding nucleation and grafting." Thesis, University of Manchester, 2012. https://www.research.manchester.ac.uk/portal/en/theses/protective-colloids-understanding-nucleation-and-grafting(a5f5c8c9-acc7-492b-bf81-3cf327af98cf).html.

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Alkali-soluble resins (ASRs) were prepared by (i) solution and (ii) emulsion polymerization. All ASRs were synthesized with number-average molar masses < 20,000 g mol-1 and all had 15 wt% methacrylic acid 5 wt% styrene, the remaining 80 wt% was composed of either methyl methacrylate or a combination of methyl methacrylate and ethyl acrylate. All emulsion ASRs were made to 20% solids, with volume-average particle diameters (dv) in the region 30 – 50 nm, with a glass transition temperature of 80 – 120 °C. Emulsion polymerization was the preferred route for ASR synthesis, to allow further studies

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21

Clarke, Stephen Armour. "Modeling & optimisation of coarse multi-vesiculated particles." Thesis, Stellenbosch : Stellenbosch University, 2012. http://hdl.handle.net/10019.1/20242.

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Thesis (MScEng)--Stellenbosch University, 2012.<br>ENGLISH ABSTRACT: Multi-vesiculated particles (MVP) are synthetic insoluble polymeric particles containing a multitude of vesicles (micro-voids). The particles are generally produced and used as a suspension in an aqueous fluid and are therefore readily incorporated in latex paints as opacifiers. The coarse or suede MVP have a large volume-mean diameter (VMD) generally in the range of 35-60μm, the large VMD makes them suitable for textured effect paints. The general principle behind the MVP technology is as the particles dry, the vesicles

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22

Silva, Wandeklébio Kennedy da. "Monitoramento em linha e em tempo real do diâmetro médio das partículas e dos teores de não voláteis e monômero durante a polimerização em emulsão usando espectroscopia NIR." Universidade de São Paulo, 2009. http://www.teses.usp.br/teses/disponiveis/3/3137/tde-14082009-171518/.

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A técnica de polimerização em emulsão tem sido usada cada vez mais na indústria de tintas, resinas, plásticos, entre outros. Esse crescimento se deve as razões ambientais (uma vez que se utiliza água como fase contínua desta reação), também a versatilidade e a capacidade de produzir látex com diferentes propriedades para diferentes aplicações. Polímeros em emulsão são produtos por processo, isto é, suas propriedades são definidas durante a polimerização. Por isso, é importante o adequado monitoramento da reação de modo a permitir o controle das propriedades desejadas. A técnica de espec

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23

Kozempel, Steffen. "Emulgatorfreie Emulsionspolymerisation : Monomerlösungszustand und Teilchenbildung." Phd thesis, Universität Potsdam, 2005. http://opus.kobv.de/ubp/volltexte/2005/610/.

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Polymere sind zweifelsohne der Werkstoff in unserer Zeit. Ein bedeutender Anteil der heute industriell produzierten Polymere wird durch Emulsionspolymerisation hergestellt. Obwohl die Emulsionspolymerisation breite Anwendung findet, sind die involvierten Mechanismen von Teilchenbildung und -wachstum noch heute Gegenstand heftiger Kontroversen.<br> Ein Spezialfall der Emulsionspolymerisation ist die emulgatorfreie Emulsionspolymerisation. Hierbei handelt es sich um ein scheinbar einfacheres System der Emulsionspolymerisation, weil diese Methode ohne Zusatz von Emulgatoren auskommt.<br><br> Die

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24

Sun, Wen. "A study of interacting stochastic networks : large scale, long time behavior and fluctuations, with applications in communication networks and protein polymerization." Thesis, Sorbonne université, 2018. http://www.theses.fr/2018SORUS075.

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Ce document est consacré aux analyses de grands réseaux stochastiques utilisés pour étudier des réseaux de communication et ainsi que certains phénomènes biologiques. La première partie se compose de trois modèles pour évaluer l’efficacité des algorithmes de duplication et de placement dans les grands systèmes distribués. Au chapitre 2, la dynamique du système est décrite l’aide de la mesure empirique associée à un processus de transient multidimensionnel. Une étude détaillée de ces processus est effectuée sur plusieurs échelles de temps rapides. Des principes de moyenne stochastique avec plus

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25

Storms, William Kenneth. "Polymeric Amphiphilic Nanoparticles Via Intramolecular Chain Collapse Using 1-Functionalized Vinylbenzocyclobutenes." University of Akron / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=akron1436548338.

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26

Youssef, Itab. "Polymérisation en émulsion et en miniémulsion. Influence de la combinaison de stabilisants moléculaires et macromoléculaires et suivi en situ par spectroscopie Raman." Thesis, Université de Lorraine, 2012. http://www.theses.fr/2012LORR0191/document.

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Cette thèse a pour objet la comparaison des procèdes de polymérisation en émulsion et en miniémulsion. L'influence de la combinaison de stabilisants moléculaires et macromoléculaires sur la cinétique réactionnelle et la distribution de tailles de particules sont les critères pertinents dans notre étude. Un stabilisant polymère, le poly (alcool vinylique-co-acétate de vinyle) (PVA), a été synthétisé avec différents taux d'hydrolyse par saponification directe du polyacétate de vinyle. Le taux d'hydrolyse de ce copolymère a été caractérisé par la Résonance Magnétique Nucléaire du proton (RMN 1H).

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27

Garnier, Jérôme. "Elaboration de latex nanostructurés à base de poly(chlorure de vinylidène) par polymérisation en émulsion." Thesis, Montpellier, Ecole nationale supérieure de chimie, 2012. http://www.theses.fr/2012ENCM0011.

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Les emballages alimentaires et pharmaceutiques doivent de nos jours répondre à de nombreux critères : ils doivent non seulement préserver le produit emballé, mais également être inoffensifs, économes en énergie et jetables. Les polymères barrières ont permis de répondre à ces besoins, en offrant des alternatives à des matériaux plus demandeurs en énergie et plus lourds tels que le verre ou les métaux, tout en conservant une faible perméabilité à l’eau et/ou à l’oxygène. Parmi la grande variété de polymères barrières existants, les copolymères du poly(chlorure de vinylidène) (PVDC) offrent une

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28

Chern, Chorng-Shyan. "Polymerization in non-uniform latex particles." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/12170.

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29

Michal, Lukáš. "Zlepšení sedimentační stability MR kapalin použitím bentonitových jílů." Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2021. http://www.nusl.cz/ntk/nusl-443152.

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The diploma thesis is focused on the issue of sedimentation stability of magnetorheological fluids, whis represents one of the most important characteristics determining the reliability of these fluids. Higher sedimentation stability can by achieved in several ways. Methods that are further examined in the thesis include particle polymerization and the addition of clay mineral additives. Both achieve positive results by schowing increased sedimentation stability. However, in the case of additives, the effect is much higher. In particular, the CLAYTONE 40 additive achieves a lower particle sedi

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30

Costamagna, Federica. "Colloidal stability, intracellular fate and toxicology of drug nanocarriers - Application to polymerized micelles and organometallic nanogels Nanotoxicology at the particle/micelle frontier: influence of core-polymerization on the intracellular distribution, cytotoxicity and genotoxicity of polydiacetylene micelles." Thesis, université Paris-Saclay, 2020. http://www.theses.fr/2020UPASS128.

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Une compréhension approfondie de la stabilité colloïdale est nécessaire pour concevoir des nanoparticules pour la vectorisation de molécules actives. En particulier, prévoir le comportement in vivo des particules (désagrégation ou agrégation) est fondamental pour prédire l’efficacité et la toxicité des nanoformulations. Les objectifs de cette thèse concernaient (1) l’amélioration de la stabilité colloïdale en conditions physiologiques et (2) l’étude in vitro du comportement biologique de deux types de nanovecteurs : nanogels à base de chitosane-fer et micelles de polydiacétylène<br>A thorough

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31

Etmimi, Hussein Mohamed. "Hydrophobic core/shell particles via miniemulsion polymerization." Thesis, Stellenbosch : University of Stellenbosch, 2006. http://hdl.handle.net/10019/539.

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32

Neqal, Mehdi. "Smart polymeric materials by ring-opening metathesis polymerization." Thesis, Bordeaux, 2017. http://www.theses.fr/2017BORD0658/document.

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Ce travail de thèse consiste à combattre le développement microbien des réservoirs de carburant aéronautiques dont le métabolisme entraine la production d’acides organiques susceptibles de corroder les parois métalliques des réservoirs. Des substances biocides sont habituellement utilisées pour éliminer les populations microbiennes. Ces substances peuvent être des composés organiques ou bien de manière plus courante du chrome (VI) sous forme de revêtement à la surface des parois afin de créer une couche passive et d’empêcher la corrosion chimique. Cependant, le chrome appartient à la catégorie

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33

Marinangelo, Giovane. "Copolimerização em emulsão de estireno e acrilato de butila com alto teor de sólidos: estudo experimental e modelagem matemática do processo em reator semicontínuo." Universidade de São Paulo, 2010. http://www.teses.usp.br/teses/disponiveis/3/3137/tde-19012011-112636/.

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Neste trabalho estudou-se a copolimerização em emulsão de estireno e acrilato de butila em processo semicontínuo onde o produto final é um látex com alto teor de sólidos. Foi dado enfoque à distribuição de tamanhos de partículas do látex e seus efeitos no produto. Foi realizada uma série de experimentos de copolimerização em emulsão em um reator de vidro, empregando receitas com teores de sólidos de até 64% em massa. Durante os experimentos, amostras eram retiradas periodicamente do reator visando analisar o teor de polímeros (conversão dos monômeros) por gravimetria, a concentração de monômer

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34

Girard, Nathalie Renee Claude. "Oil-in-water microemulsions and their polymerization." Thesis, Imperial College London, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.369502.

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35

Kim, Hong-Youl. "PMMA bone cement reinforced by plasma treated particles /." free to MU campus, to others for purchase, 1997. http://wwwlib.umi.com/cr/mo/fullcit?p9841158.

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36

Limé, Fredrik. "Synthesis and modification of monodisperse polymer particles for chromatography." Doctoral thesis, Umeå universitet, Kemi, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-1948.

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Liquid chromatography is an analytical technique that is constantly facing new challenges in the separation of small molecules and large biomacromolecules. Recently the development of ultra high pressure liquid chromatography has increased the demand on sturdy particles as stationary phase. At the same time the particle size has decreased to sub-2 µm and packed into shorter analytical columns. This thesis deals with the development of new ways of preparing particulate polymer materials using divinylbenzene (DVB) as crosslinker. It includes a novel procedure for synthesizing monodisperse polyme

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37

Dorresteijn, Robert [Verfasser]. "Particles with tunable functionality by a nonaqueous emulsion polymerization approach / Robert Dorresteijn." Mainz : Universitätsbibliothek Mainz, 2015. http://d-nb.info/1073303241/34.

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Yu, Zhou. "Surface Polymerization, Interface Structure, and Low Temperature Consolidation of Nano Ceramic Particles." University of Cincinnati / OhioLINK, 2000. http://rave.ohiolink.edu/etdc/view?acc_num=ucin971379308.

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39

Hernandez, Garcia Hugo Fernando. "Multiscale simulation of heterophase polymerization : application to the synthesis of multicomponent colloidal polymer particles." Phd thesis, Universität Potsdam, 2008. http://opus.kobv.de/ubp/volltexte/2008/2503/.

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Heterophase polymerization is a technique widely used for the synthesis of high performance polymeric materials with applications including paints, inks, adhesives, synthetic rubber, biomedical applications and many others. Due to the heterogeneous nature of the process, many different relevant length and time scales can be identified. Each of these scales has a direct influence on the kinetics of polymerization and on the physicochemical and performance properties of the final product. Therefore, from the point of view of product and process design and optimization, the understanding of each

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40

Abd, Aziz Azniwati. "Synthesis of Polymeric Janus Nanoparticles through Seeded Emulsion Polymerization." Thesis, The University of Sydney, 2014. http://hdl.handle.net/2123/14883.

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Methods to prepare anisotropic or Janus particles are well documented. However, the preparation methods available to prepare polymeric Janus nanoparticles still suffer from significant challenges. In this Thesis, three methods are explored to synthesize polymeric Janus nanoparticles with amphiphilic properties. In the Janus nanoparticles prepared, one side is hydrophilic, being coated by a “hairy” layer of poly(acrylic acid) (AA) and one side is hydrophobic, being made of styrene (Sty) or 2,2,2-triflioroethyl methacrylate (TFEMA). The first method described the synthesis of anisotropic or Janu

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WU, DAN. "LIQUID-CORE CAPSULES VIA INTERFACIAL POLYMERIZATION AND ALTERNATING COPOLYMERIZATION." University of Cincinnati / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1179427662.

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42

Huang, Yun. "Synthesis of Novel Polymer-brush-afforded Hybrid Particles for Well-organized Assemblies." 京都大学 (Kyoto University), 2014. http://hdl.handle.net/2433/189679.

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Sutrisno, Joko. "Surface polymerization of iron particles for magnetorheological elastomers (MRes) and their potential application as sensors." abstract and full text PDF (UNR users only), 2008. http://0-gateway.proquest.com.innopac.library.unr.edu/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:1453614.

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44

Abboud, Mohammed K. [Verfasser]. "Video Microscopy Studies on Growth Kinetics of Single Catalyst Particles During Olefin Polymerization / Mohammed K Abboud." Aachen : Shaker, 2005. http://d-nb.info/1186577401/34.

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45

Kir, Onur [Verfasser], Wolfgang H. [Akademischer Betreuer] Binder, and Guido [Akademischer Betreuer] Kickelbick. "Surface initiated polymerization of isoprene from silica nano- and glass particles via living anionic and controlled radical polymerization techniques / Onur Kir. Betreuer: Wolfgang H. Binder ; Guido Kickelbick." Halle, Saale : Universitäts- und Landesbibliothek Sachsen-Anhalt, 2013. http://d-nb.info/1050977734/34.

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46

Anderson, Kyle D. "Functional and complex topological applications of plasma polymerized ultrathin films." Diss., Georgia Institute of Technology, 2012. http://hdl.handle.net/1853/48969.

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This study is focused on the fabrication of plasma polymerized ultrathin films and the elucidation of their unique properties with an emphasis on the solvent-less, dry polymerization process to introduce post-deposition functionality, robustness, and shape preservation. Two major classes of materials are the subject of this study: biological monomers, specifically the amino acids tyrosine and histidine and synthetic organic and inorganic monomers including acrylonitrile, 2-hydroxyethyl methacrylate, N-isopropylacrylamide, titanium isopropoxide and ferrocene. The unique chemical and physical pr

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47

Li, Keran. "Surfactant-free synthesis of magnetic latex particles." Thesis, Lyon 1, 2015. http://www.theses.fr/2015LYO10211/document.

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Ce travail de thèse décrit l'élaboration de latex hybrides oxyde de fer (OF)/polymère par polymérisation en émulsion sans tensioactif. Des nanoparticules d'OF cationiques ont été tout d'abord synthétisées par co-précipitation de sels de fer dans l'eau. Des latex hybrides magnétiques ont été ensuite obtenus par deux voies de polymérisation. La première consiste en la synthèse de particules de latex de morphologie 'carapace' par polymérisation en émulsion Pickering du styrène et du méthacrylate de méthyle (MMA). Un comonomère auxiliaire (acide (méth)acrylique ou acide 2-acrylamido-2-méthyl-1-pro

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48

Ma, Huanhuan. "Synthesis of silica/polymer hybrid particles with controlled morphologies through polymerization induced co-assembly of grafted and free block copolymers." Electronic Thesis or Diss., Lyon 1, 2024. http://www.theses.fr/2024LYO10330.

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Les colloïdes nanocomposites organiques/inorganiques suscitent une attention considérable en raison de leur large gamme d'applications potentielles. L'auto-assemblage induit par la polymérisation (PISA) de copolymères à blocs en surface de nanoparticules inorganiques est reconnu comme une stratégie particulièrement efficace pour la synthèse de ces matériaux. Cette étude vise à synthétiser des brosses de polymères hydrophiles à la surface de particules de silice en utilisant la polymérisation radicalaire contrôlée par la voie nitroxyde (NMP) et à les utiliser par la suite comme macroamorceurs p

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49

Miles, Craig. "Synthesis and Characterization of Mesoporous PMMA/POSS Particles." University of Toledo / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1305145439.

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Mathlouthi, Chourouk. "Étude des propriétés thermodynamiques et dynamiques des polymères confinés en géométrie nanoparticules." Thesis, Université Grenoble Alpes (ComUE), 2016. http://www.theses.fr/2016GREAI035/document.

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L’effet du confinement sur les propriétés physiques des polymères est un sujet d’une importance à la fois fondamentale et académique et est le centre d’un débat scientifique soutenu. La relation entre la transition vitreuse (Tg) et la dynamique des polymères en confinement est notamment le centre d’un débat controversé au sein de la communauté scientifique depuis les deux dernières décennies. Alors que la transition vitreuse mesurée par expansion thermique est diminuée de manière remarquable en films minces, sa dynamique alpha est invariante : ce phénomène est aperçu comme une rupture avec la

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