Relevant bibliographies by topics / Pentacyanoferrate

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Academic literature on the topic 'Pentacyanoferrate'

Author: Grafiati
Published: 4 June 2021
Last updated: 26 July 2025

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Journal articles on the topic "Pentacyanoferrate"

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Shi, Cheng-Hsiang, Shiao-Tsun Wang, Shiao-Yun Yang, Andrew Yeh, and Hsien-Ju Tien. "Sydnone Complexes of Pentacyanoferrate(II)." Journal of the Chinese Chemical Society 45, no. 1 (1998): 77–81. http://dx.doi.org/10.1002/jccs.199800013.

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Bratskaya, S. Yu, Yu O. Privar, O. V. Korjakova, A. V. Mechaev, and A. V. Pestov. "Pentacyanoferrate(II) complexes with chitosan." Polymer Engineering & Science 54, no. 10 (2013): 2392–97. http://dx.doi.org/10.1002/pen.23787.

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Fuller, MW, KMF Lebrocq, E. Leslie, and IR Wilson. "The Photolysis of Aqueous-Solutions of Potassium Hexacyanoferrate(III)." Australian Journal of Chemistry 39, no. 9 (1986): 1411. http://dx.doi.org/10.1071/ch9861411.

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The photolysis of aqueous solutions of potassium hexacyanoferrate(III) at 254 and 366 nm forms aqua- or hydroxo-pentacyanoferrate(III) in both acidic and alkaline solutions, with quantum yields between 0.02 and 0.06. Subsequent thermal reactions form the decacyanodiferrate(III) and/or decacyanodiferrate(III,II) species, especially in weakly acidic solutions, and, in alkaline solutions, may precipitate hydrated iron(III) oxides.
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Tetianec, Lidija, Marius Dagys, Juozas Kulys, Arturas Ziemys, and Rolandas Meskys. "Study of the reactivity of quinohemoprotein alcohol dehydrogenase with heterocycle-pentacyanoferrate(III) complexes and the electron transfer path calculations." Open Life Sciences 2, no. 4 (2007): 502–17. http://dx.doi.org/10.2478/s11535-007-0033-y.

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AbstractThe reactivity of alcohol dehydrogenase IIG (ADH IIG) from Pseudomonas putida HK5 with new heterocycle-pentacyanoferrate(III) complexes and hexacyanoferrate(III) was determined at pH 7.2. The pentacyanoferrate(III) complexes contained imidazole, pyrazole, pyridine, their derivatives and 2-aminobenzothiazole as the sixth ligand. The largest reactivity of the complexes with ADH IIG was estimated for the complex containing pyridine. An apparent bimolecular constant (k ox) for this complex was 8.7 × 105 M−1s−1. The lowest value of k ox was estimated for the complex with benzotriazole (k ox
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Macartney, Donal Hugh, and Lauren Jean Warrack. "Ligand substitution reactions of pentacyanoferrate(II) complexes with N-heterocyclic cations in aqueous solution." Canadian Journal of Chemistry 67, no. 11 (1989): 1774–79. http://dx.doi.org/10.1139/v89-274.

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Kinetic and spectroscopic studies have been carried out in aqueous solution on the formation (from Fe(CN)5OH23−) and dissociation of pentacyanoferrate(II) complexes containing 1-(4-pyridyl)pyridinium and the neutral, protonated, and N-methylated forms of 4,4′-bipyridine (BPY), 1,2-bis(4-pyridyl)ethane (BPA), and trans-1,2-bis(4-pyridyl)ethylene (BPE). The pH dependences of the formation kinetics have been analyzed in terms of the specific rate and acid dissociation constants for these ligands. The rate constants (25.0 °C, I = 0.10 M) for the formation of the dinuclear complexes (NC)5FeLFe(CN)5
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Lopez, Vicenta, Javier Catalan, Rosa Ma Claramunt, Concepcion Lopez, Eduardo Cayon, and Jose Elguero. "On the relationship between thermodynamic pKa's of azoles and the oxidation potentials of their pentacyanoferrate(II) complexes." Canadian Journal of Chemistry 68, no. 6 (1990): 958–59. http://dx.doi.org/10.1139/v90-149.

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The comparison between thermodynamic pKa values and oxidation potentials of the pentacyanoferrate(II) complexes of a series of azoles shows the existence of two parallel lines: one for pyrazoles and another one for benzazoles. Using the equation corresponding to the second one, the pKa value of 1-methylbenzotriazole (2.49) can be estimated from the E1/2 value of its complex. Keywords: azole basicity, oxidation potentials, pyrazoles, benzotriazoles.
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Cvijanović, D., V. Damjanović, I. Picek, and B. Foretić. "Spectroscopic Studies of Methimazole Reactivity toward the Aquapentacyanoferrate (II) Ion in Aqueous Solutions." Spectroscopy: An International Journal 27 (2012): 509–14. http://dx.doi.org/10.1155/2012/136058.

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Methimazole (2-mercapto-1-methylimidazole, MMI) and its pentacyanoferrate (II) complex have been characterized by means of UV/Vis, Raman, and NMR spectroscopy. The reaction of MMI with aquapentacyanoferrate (II), [Fe(CN)5(H2O)]3−, in buffered aqueous solutions yielded the [Fe(CN)5(MMI)]3−complex. It was found that only thione tautomer of MMI coordinates to the iron (II). The exceptionally stabile and inert complex was produced.
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Parwate, D. V., and A. N. Garg. "Unusual Quadrupole Splitting in D i- and Trialkylamine Substituted Pentacyanoferrate(II) Complexes." Zeitschrift für Naturforschung B 40, no. 11 (1985): 1495–99. http://dx.doi.org/10.1515/znb-1985-1113.

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A series of pentacyanoferrate complexes, Na3[Fe(CN)5L] ·nH2O, where L = (CH3)2NH, (C2H5)2NH, (C2H5)3N, (C3H7)2NH, (C4H9)2NH, (C4H9)3N and (C6H5)2NH were studied by Mössbauer and infrared spectroscopy. All the complexes exhibited two line spectra with ⊿ EQ = 0.73-1.92 mms-1 and δ = −0.04−0.49 mms-1 (w.r.t. SNP) and can be divided into two groups with well defined parameters. Partial isomer shift and partial quadrupole splitting values were correlated with bonding characteristics.
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Funai, Irene A., Miguel A. Blesa, and José A. Olabe. "Hydrazine autoxidation in solution: catalysis by pentacyanoferrate(II)." Polyhedron 8, no. 4 (1989): 419–26. http://dx.doi.org/10.1016/s0277-5387(00)80736-6.

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Macartney,, D. H. "Properties and Reactions of Substituted Pentacyanoferrate (II) Complexes." Reviews in Inorganic Chemistry 9, no. 2-3 (1988): 101–52. http://dx.doi.org/10.1515/revic.1988.9.2-3.101.

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Dissertations / Theses on the topic "Pentacyanoferrate"

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Nieh, Chi-Hua. "Study on Oxidase/Peroxidase-based Biosensors with Pentacyanoferrate-bound Polymer." Kyoto University, 2013. http://hdl.handle.net/2433/180512.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(農学)<br>甲第17895号<br>農博第2018号<br>新制||農||1017(附属図書館)<br>学位論文||H25||N4791(農学部図書室)<br>30715<br>京都大学大学院農学研究科応用生命科学専攻<br>(主査)教授 加納 健司, 教授 三芳 秀人, 教授 小川 順<br>学位規則第4条第1項該当
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Jin, Victor Xinhua. "Syntheses and characterization of Ã- and ß-cyclodextrin rotaxanes with dinuclear platinum(II) and pentacyanoferrate(II) stoppers." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/NQ56083.pdf.

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Santiago, Marcelo Oliveira. "SÃntese e caracterizaÃÃo de compostos mono e binucleares de rutÃnio e ferro com o LIGANTE 1,3-BIS(3-PIRIDILMETIL)2-TIOURÃIA (BPMT)." Universidade Federal do CearÃ, 1998. http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=1420.

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FundaÃÃo de Amparo a Pesquisa do Estado de SÃo Paulo<br>Os complexos mononucleares, formados a partir das reaÃÃes do 1,3-bis(3-piridilmetil)-2-tiourÃia (BPMT) com os Ãons [Ru(NH3)5OH2]2+ e [Fe(CN)5NH3]3-, foram isolados e caracterizados por microanÃlise, espectroscopia eletrÃnica, vibracional na regiÃo do infravermelho, MÃssbauer e por tÃcnicas eletroquÃmicas (Voltametria cÃclica e voltametria de pulso diferencial). Nos complexos de pentaaminas de rutÃnio, foram evidenciadas maiores interaÃÃes de retrodoaÃÃo, d&#960;(M) &#8594; p&#960;*BPMT, que nos complexos de pentacianoferrato sendo justifi
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Winnischofer, Herbert. "Porfirinas pentacianoferrato e estruturas supramoleculares auto-organizadas." Universidade de São Paulo, 2000. http://www.teses.usp.br/teses/disponiveis/46/46134/tde-22062009-085859/.

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No presente trabalho estão descritas a síntese e as propriedades espectroscópicas e eletroquímicas da meso-{tetrakis-(3-piridilpentacianoferrato)} porfirinato e dos materiais do tipo Azul da Prússia, obtidos pela reação de \"auto-formação\" da nova porfirina com íons de metais de transição. Os novos materiais foram caracterizados por espectroscopia de massa, UV -Vis, Infravermelho, Raman ressonante e Mossbauer de 57Fe, cronoamperometria, voltametria cíclica e de pulso diferencial, espectroscopia de impedância eletroquímica e espectroeletroquímica. A PPCF foi obtida através da reação do 3-TPyP
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Frin, Karina Passalacqua Morelli. "Propriedades fotoquímicas de alguns complexos de ferro(II) e rênio(I)." Universidade de São Paulo, 2008. http://www.teses.usp.br/teses/disponiveis/46/46134/tde-17052016-143939/.

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Neste trabalho, foram estudadas as propriedades fotoquímica e/ou fotofísica de alguns compostos de coordenação de rênio(l) e ferro(I I). A irradiação dos complexos fac-[Re(CO)3(NN)(trans-L)]+, NN= 4,7-difenil-1,10- fenantrolina (ph2phen) ou 5-cloro-1,10-fenantrolina (Clphen) e L = 1,2-bis(4-piridil)etileno (bpe) ou 4-estirilpiridina (stpy), em acetonitrila ou em filme de poli(metacrilato de metila) (PMMA) resulta em variações espectrais condizentes com a fotoisomerização trans-cis do ligante coordenado. A determinação dos rendimentos quânticos para a fotorreação pela variação espectral resulto
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Sai, Jen-Shing, and 施振祥. "Pentacyanoferrate of Sydnone Derivatives." Thesis, 1993. http://ndltd.ncl.edu.tw/handle/14928984590939571158.

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碩士<br>中原大學<br>化學學系<br>81<br>3-甲基及3-苯基雪梨酮五氰鐵錯合物,有很明顯的金屬至配位基之電荷轉 移吸收, 分別在 λmax=442nm(3360/莫耳/公分,3-甲基雪梨酮)及λmax= 494nm(9530/莫耳/公分,3-苯基雪梨酮)。 3-甲基及3-苯基雪梨酮五氰鐵 錯合物之還原電位分別為 0.67Volts 及 0.65Volts v.s N.H.E.(μ=0.10 M過.blksq.酸鋰, pH=5(acetate)。電化學結果顯示, 3-甲基雪梨酮五氰 鐵(Ⅱ)錯合物被氧化成三價時,金屬中心有自雪梨酮 N-2 位置轉移至 C= O 之氧原子的結合異構化現象 , 當Fe(Ⅲ)還原成 Fe(Ⅱ) 時 ,金屬中心 又再度回至 N-2 位置, 此為五氰鐵錯合物第一個具結合異構化現象的例 子。五氰鐵(Ⅱ)錯合物的取代反應屬解離機構,形成及水離反應速率常數, 在25℃,pH=5,0.10M 過.blksq.酸鋰條件下分別為kf=(5.4±0.2) ×0.01
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Wu, Ming-Chu, and 吳明珠. "Pentacyanoferrate(II,III) Complexes of Nucleic Acids." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/46856761573728400342.

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碩士<br>中原大學<br>化學學系<br>82<br>3-,4-羥基▋啶及肌▋五氰鐵二價錯合物可以Fe(CN)5OH23-與過量配位基 在水溶液中直接作用而得.在T=25C,pH=5.0(acetate),μ=0.1MLiClO4條件 下,3-,4-羥基▋啶及肌▋五氰鐵錯合物分別在λmax=363nm(3960cm-1 M-1),414nm(4360cm-1M- 1)及320nm(1950cm-1M-1)有MLCT吸收.而其三價 錯合物則在λmax=503nm( 132cm-1M-1),565nm(500cm-1M-1),497nm(324 cm-1M-1)分別有LMCT吸收.五氰鐵二價錯合物取代反應動力學的結果顯示 不論形成或水離反應,均屬解離機構.其中4-羥基▋啶錯合物之形成反應速 率較其它配位之錯合物慢約三次冪,乃由於4-羥基▋啶之醇酮異構平衡的 影響,而非反應機構的差異, 若考慮羥基▋啶之醇酮異構平衡的因素,則 在 T=25C, pH=5.0 ( acetate),μ=0.1MLiClO4條件下,五氰鐵二價
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Wu, Ming-Zhu, and 吳明珠. "Pentacyanoferrate (II,III) complexes of nucleic acidszeng." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/64178377235083835165.

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LU, GING-BAO, and 呂清保. "Imidazolate bridged binuclear complex of pentacyanoferrate and pentaammineruthenium." Thesis, 1987. http://ndltd.ncl.edu.tw/handle/30460127669012279729.

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碩士<br>中原大學<br>化學研究所<br>75<br>[(CN)FeNONRu (NH)](I) 及[(CN)FeNONRu (NH)(OH)〕(II) 錯合物可由Fe（CN）OH與Ru（NH）Im ／ 直接作用而得， 可見光譜：λmax （ε）＝３６３nm（３１００），５７２nm（８０８）及紅外光 譜νcn＝ ２０５０ｃｍ，σ（NH）ym ＝１３１０ ｃｍ 的鑑定均顯 示混價分子（Ⅱ）屬於定域性，其金屬價數為 （Ⅱ）及（Ⅲ）。 混價分子（Ⅱ）之水離反應速率的探討，證明錯合經由Fe（Ⅱ）-L鍵結斷裂，其反 應速率常數為６．５４×１０sec ，在PH＝１０，μ＝０．１０ ＭＬｉＣｌＯ條件下，電化學結果亦顯示，雙核錯合物（Ⅱ）有兩組環路電位波 在－０．２０３V 及０．３１２V 分別屬於〔２，２〕→〔２，３〕＋e 及〔２， ３〕→〔３，３〕＋e 之氧化電位電化學結果可供我們進一步求得反應〔２，２〕 ＋〔３，３〕 ２〔２，３〕
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Sun, Bin-Guo, and 孫彬國. "Hydroxypyridine and inosine of pentacyanoferrate (II,III) complexes." Thesis, 1991. http://ndltd.ncl.edu.tw/handle/97369842777031371727.

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Book chapters on the topic "Pentacyanoferrate"

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Cvijanović D., Damjanović V., Picek I., and Foretić B. "Spectroscopic studies of methimazole reactivity toward the aquapentacyanoferrate(II) ion in aqueous solutions." In Advances in Biomedical Spectroscopy. IOS Press, 2013. https://doi.org/10.3233/978-1-61499-184-7-085.

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Methimazole (2-mercapto-1-methylimidazole, MMI) and its pentacyanoferrate(II) complex have been characterized by means of UV/Vis, Raman and NMR spectroscopy. The reaction of MMI with aquapentacyanoferrate(II), [Fe(CN)5(H2O)]3&amp;minus;, in buffered aqueous solutions yielded the [Fe(CN)5(MMI)]3&amp;minus;complex. It was found that only thione tautomer of MMI coordinates to the iron(II). The exceptionally stabile and inert complex was produced.
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